[go: up one dir, main page]

DE1720277A1 - Verfahren zur Herstellung von filmbildenden waessrigen Copolymerdispersionen - Google Patents

Verfahren zur Herstellung von filmbildenden waessrigen Copolymerdispersionen

Info

Publication number
DE1720277A1
DE1720277A1 DE19671720277 DE1720277A DE1720277A1 DE 1720277 A1 DE1720277 A1 DE 1720277A1 DE 19671720277 DE19671720277 DE 19671720277 DE 1720277 A DE1720277 A DE 1720277A DE 1720277 A1 DE1720277 A1 DE 1720277A1
Authority
DE
Germany
Prior art keywords
octene
vinyl
film
preparation
amounts
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
DE19671720277
Other languages
English (en)
Inventor
Ritchie Douglas Ian
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
BP Chemicals Ltd
Original Assignee
BP Chemicals Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by BP Chemicals Ltd filed Critical BP Chemicals Ltd
Publication of DE1720277A1 publication Critical patent/DE1720277A1/de
Pending legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F218/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an acyloxy radical of a saturated carboxylic acid, of carbonic acid or of a haloformic acid
    • C08F218/02—Esters of monocarboxylic acids
    • C08F218/04—Vinyl esters
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Polymerisation Methods In General (AREA)
  • Processes Of Treating Macromolecular Substances (AREA)
  • Paints Or Removers (AREA)

Description

PATENTANWÄLTE
DR.-ING. VON KREISLER DR.-ING. SCHÖNWALD 1720277 DR.-ING. TH. MEYER DR. FUES
KÖLN 1, DEICHMANNHAUS
Köln, den 1.6,1967 Ke/Ax
BP Chemicals (U.K.) Limited, Devonshire House. Mayfair Place, Piccadilly, London, W«1 (England).
Verfahren zur Herstellung von filmbildenden wäßrigen Copolymerdispersionen
Die Erfindung betrifft ein Verfahren zur Herstellung von filmbildenden wässrigen Dispersionen von Oopolymeren von Vinylestern von organischen Säuren. Sie betrifft insbesondere wässrige Dispersionen von Copolymeren von Vinylestern von organischen Säuren mit Octen-1, die so hergestellten Dispersionen und die daraus gebildeten Filme.
Das Verfahren gemäß der Erfindung zur Herstellung von filmbildenden wässrigen Dispersionen von Oopolymeren von Vinylestern von organischen Säuren ist dadurch gekennzeichnet, daß man einen Vinylester einer gesättigten Monocarbonsäure und Octen-1 in wässriger Dispersion in Gegenwart eines freie Radikale bildenden Katalysators und eines oberflächenaktiven Mittels und/oder eines Schutzkolloids copolymerisiert.
Die Säurekomponente des Vinylesters ist am vorteilhaftesten von einer linearen oder verzweigten aliphatischen Monocarbonsäure abgeleitet. Bevorzugt werden Säuren mit 1-7 C-Atomen. Einige Beispiele dieser Ester sind Vinylacetat, Vinylpropionat, Vinylbutyrat und Vinylbenzoat. Die Erfindung ist insbesondere auf die Vinylester von Essigsäure oder substituierter Essigsäure, z.B. Vinylester von Trimethylessig-
209813/1321
mm 2 —
säure, gerichtet. Gemische von Vinylestern oder Gemische . mit anderen copolymerisierbaren ungesättigten Verbindungen, z.B. Acrylsäure, Methacrylsäure, Fumarsäure oder Itaconsäure, oder mit Estern dieser Säuren oder Viny!halogeniden sind ebenfalls geeignet.
Freie Radikale bildende Katalysatoren sind allgemein bekannt. Alle diese Katalysatoren können für das Verfahren gemäß der Erfindung verwendet werden. Der Katalysator kann aus einer Einzelverbindung oder aus mehreren Verbindungen, die in Kombination als System wirksam sind, bestehen und wasserlöslich oder öllöslich sein. Einige Beispiele sind die organischen und anorganischen Peroxyde, Persulfate und Peroxycarbonate, z.B. Ammoniumpersulfat, und die Dialkylpercarbonate, z.B. Diisopropylperoxydicarbonat, Azoverbindungen, z.B. Azo-bis-isobutyronitril, und Redoxsysteme, z.B. Ammoniumpersulfat/Natriummetabisulfit, a-Cumolhydroperöxyd/ Eisen(II)-Komplex, Benzoylperoxyd/Eisen(Il)-Komplex und Alkalichlorat/Alkalisulfit.
Als oberflächenaktive Mittel eignen sich beliebige handelsübliche ionaktive oder nichtionogene oberflächenaktive Produkte, die allein oder als Gemische verwendet werden können. Einige Beispiele von ionischen oberflächenaktiven Mitteln sind die anionaktiven Mittel, z.B. die Alkalisalze von Alkarylsulfonsäuren (z.B. Natriumdodecyldiphenylätherdisulfonat), Alkalisalze von Sulfaten von langkettigen Fettsäuren (z.B. Natriumlaurylsulfat) und Ester von Natriumsulf obernsteinsäure (z.B. Natriumdioctylsulf osuccinat),und abs nichtionogenenoberflächenaktivenMittel, z.B. Äthylenoxyd-Nonylphenol-Kondensate, und Monoester von langkettigen Fettsäuren mit mehrwertigen Alkoholen (z.B. Sorbitmonooleat).
Die Verwendung von Schutzkolloiden in wässrigen freiradikalischen Polymerisationssystemen ist allgemein bekannt. Alle diese Schutzkolloide können für die Zwecke der Erfindung
209813/1321
verwendet werden. Geeignet sind beispielsweise Polyvinylalkohole und wasserlösliche Cellulosederivate (z.B. Celluloseäther, wie Ä'thylcellulose).
Aktivatoren für den Katalysator können anwesend sein. Geeignet als Aktivatoren sind beispielsweise Spuren von Übergangsmetallsalzen, z.B. Eisen(II)-sulfat.
Im Polymerisationsgemisch kann ein Kettenüberträger vorhanden sein. Geeignet als Kettenüberträger sind langkettige wasserunlösliche aliphatische Mercaptane, z.B. n- oder tert-Dodecylmercaptan.
Die Polymerisation kann durchgeführt werden, indem die Reaktionsteilnehmer unter Bildung einer Emulsion oder Suspension in Wasser dispergiert werden. Das Gewichtsverhältnis von Wasser zum Gesamtgewicht der eingesetzten Monomeren liegt zweckmäßig im Bereich von 10:1 bis 1:2, vorzugsweise bei etwa 1:1. Das Gewichtsverhältnis des Vinylesters zum eingesetzten Octen-1 sollte im Bereich von 99s1 bis 70:30, vorzugsweise im Bereich von 90:10 bis 70:30 liegen. Am vorteilhaftesten beträgt die Katalysatormenge 0,1-2,0%, vorzugsweise 0,5—1,0$, bezogen auf das Gewicht der eingesetzten Monomeren. Das Gewicht des oberflächenaktiven Mittels und/ oder Schutzkolloids liegt vorzugsweise im Bereich von 0,5 bis 6$, bezogen auf das Gewicht der Monomeren, und das Gewicht des Aktivators des Katalysators liegt vorzugsweise im Bereich von 0,01-1,0>fc.
Das Verfahren kann chargenweise, halbkontinuierlich oder kontinuierlich durchgeführt werden, wobei der Vinylester oder das Octen-1 oder beide zudosiert werden.
Der Druck, bei dem die Polymerisation durchgeführt wird, ist nicht entscheidend wichtig, jedoch muß er so hoch sein, dal? die Reaktionsteilnehmer in der Flüssigphase gehalten worden. Bevorzugt wird Kormaldruck, um die Notwendigkeit der Verwendung teurer Druckapparaturen zu vermeiden.
209813/1321
Die Temperatur ist ebenfalls nicht entscheidend wichtig. Geeignet sind beliebige Temperaturen, bei denen die Reaktion mit genügender Geschwindigkeit verläuft· Diese Temperatur hängt von dem verwendeten Katalysatorsystem ab und liegt vorzugsweise im Bereich von 40-100°C·
Copolymere, die 10 bis etwa 15 Grew#~56 Octen-1 enthalten» können hergestellt werden, wenn die Polymerisation bei einer Temperatur im Bereich von 75-950C, vorzugsweise von 80-850C durchgeführt wird. .
Der pg-Wert der Dispersion sollte im Bereich von 4,0-7»5 gehalten werden, um eine Hydrolyse des Vinylesters zu ver«r melden* Zu diesem Zweck kann ein geeigneter Puffer, z.B» Kalium- oder Natriumbicarbonat, zugesetzt werden«
Die Polymerisation wird zweckmäßig unter Ausschluß von Sauerstoff durchgeführt· Nicht polymerisierter Vinylester und Octen-1 können nach der Polymerisation entfernt werden, indem man beispielsweise den Latex destilliert oder ein Inertgas, z.B. Stickstoff, durch den Latex bläst, während dieser bei erhöhter Temperatur gehalten wird·
Ein Umsatz von Monomeren zu Polymerisat über 75?6 kann erreicht werden, wenn bei den bevorzugten Bedingungen, insbesondere bei den bevorzugten Verhältnissen der Monomeren und Katalysatorkonzentrationen gearbeitet wird. .
Stabile wässrige filmbildende Dispersionen von Copolymeren des Vinylesters mit Octen-1 mit einem Feststoffgehalt von mehr als 25$ können durch entsprechende Einstellung der Anteile des Vinylesters und des Octen-1 zum vorhandenen Wasser und der Polymerisationsbedingungen erhalten werden.
209813/1321
Beispiel
Vinylacetat
Octen-1
Natriumlaurylsulfat ("Empicol LXV") Ä'thylenoxyd-Nonylphenol-Kondensat (»lergitol NP 40»)
A*thy1enoxyd-NonyIpheno1-Kondensat (»Dergitol NP 14")
675 g
225 g
18 g
18 g >A
Kaliumbicarbonat
Destilliertes Wasser
18 g
4,5g 1150 ml
6,0 g Ammoniumpersulfat in 100 ml destilliertem Wasser B 6,0 g Ammoniumpersulfat in 100 ml destilliertem Wasser C
Versuchsdurchführung
Der Ansatz A wurde in das Polymerisationsgefäß gegeben und 30 Minuten bei 600O unter Stickstoff gerührt. Die Otemperatur wurde dann auf 850C erhöht, worauf der Katalysator B zugesetzt wurde. Nach 7-stündigem Erhitzen wurde die Lösung C in den Reaktor gegeben. Die Polymerisation wurde weitere 16 Stunden bei 85°0 durchgeführt. Das nicht umgesetzte Monomere wurde dann unter vermindertem Druck abdestilliert und der Einsatz der Abkühlung überlassen. Der Umsatz von Monomeren zu Polymerisat betrug 87,5 Gew.-^, Die Analyse des Copolymeren durch kernmagnetische Resonanz ergab, daß es 19,0 Gew.-Teile Octen-1 und 81,0 G-ew.-Teile Vinylacetat enthielt.
Die erhaltene Oopolymerdispersion hatte einen Feststoffgehalt von 34»89έ und trocknete nach dem Auftrag auf eine Glasfläche an der Luft unter Bildung eines Films.
209813/ 1321

Claims (8)

Patentansprüche
1.) Verfahren zur Herstellung von fUmbildenden wäßrigen Copolymerdispersionen, dadurch gekennzeichnet, daß man Vinylester gesättigter Monocarbonsäuren und Octen-1, gegebenenfalls im Gemisch mit anderen copolymerislerbaren ungesättigten Verbindungen, in wäßriger Dispersion in Gegenwart von freie Radikale bildenden Katalysatoren und oberflächenaktiven Mitteln und/oder Schutzkolloiden copolymerisiert.
2.) Verfahren nach Anspruch 1, dadurch gekennzeichnet« daß man Vinylacetat und Octen-1 copolymerisiert.
j5.) Verfahren nach Anspruch 1 oder 2, dadurch gekennzeichnet« daß man das Gewichtsverhältnis des Vinylesters zum Octen-1 im Bereich von 90:10 bis 70OO wählt.
4.) Verfahren nach Anspruch 1 bis J, dadurch gekennzeichnet« daß man die Copolymerisation mit Katalysatormengen von 0,5 bis 1 %, Mengen des oberflächenaktiven Mittels und/oder Schutzkolloids von 0,5 bis 6 % und Aktivatormengen von 0,01 bis 1 %, jeweils bezogen auf das Gewicht der Monomeren« durchführt.
5.) Verfahren nach Anspruch 1 bis 4« dadurch gekennzeichnet« daß man im Temperaturbereich zwischen 40 und 1000C arbeitet.
6.) Verfahren nach Anspruch 1 bis 5, dadurch gekennzeichnet, daß man unter Ausschluß von Sauerstoff arbeitet.
7.) Filmformende wäßrige Dispersion von Copolymeren von Vinylestern gesättigter Monocarbonsäuren mit Octen-1.
8.) Copolymere aus Vinylestern gesättigter Monocarbonsäuren und Octen-1.
209813/1321
DE19671720277 1966-06-10 1967-06-07 Verfahren zur Herstellung von filmbildenden waessrigen Copolymerdispersionen Pending DE1720277A1 (de)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
GB2585966A GB1104536A (en) 1966-06-10 1966-06-10 A process for the production of film forming aqueous dispersions of copolymers of vinyl esters of organic acids

Publications (1)

Publication Number Publication Date
DE1720277A1 true DE1720277A1 (de) 1972-03-23

Family

ID=10234515

Family Applications (1)

Application Number Title Priority Date Filing Date
DE19671720277 Pending DE1720277A1 (de) 1966-06-10 1967-06-07 Verfahren zur Herstellung von filmbildenden waessrigen Copolymerdispersionen

Country Status (2)

Country Link
DE (1) DE1720277A1 (de)
GB (1) GB1104536A (de)

Cited By (134)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP1900756A1 (de) * 2006-09-14 2008-03-19 Basf Se Verfahren zur Herstellung einer wässrigen Polymerisatdispersion
EP2147717A1 (de) 2008-07-25 2010-01-27 Basf Se Dispergierhilfsmittel für die Emulsions- und Suspensionspolymerisation
EP2177563A1 (de) 2008-10-15 2010-04-21 Basf Se Wässriges Bindemittel für körnige und/oder faserförmige Substrate
WO2013067109A1 (en) 2011-11-01 2013-05-10 Lubrizol Advanced Materials, Inc. Acrylate-olefin copolymers, methods for producing same and compositions utilizing same
US9185120B2 (en) 2013-05-23 2015-11-10 Palo Alto Research Center Incorporated Method and system for mitigating interest flooding attacks in content-centric networks
US9203885B2 (en) 2014-04-28 2015-12-01 Palo Alto Research Center Incorporated Method and apparatus for exchanging bidirectional streams over a content centric network
US9276840B2 (en) 2013-10-30 2016-03-01 Palo Alto Research Center Incorporated Interest messages with a payload for a named data network
US9276751B2 (en) 2014-05-28 2016-03-01 Palo Alto Research Center Incorporated System and method for circular link resolution with computable hash-based names in content-centric networks
US9282050B2 (en) 2013-10-30 2016-03-08 Palo Alto Research Center Incorporated System and method for minimum path MTU discovery in content centric networks
US9280546B2 (en) 2012-10-31 2016-03-08 Palo Alto Research Center Incorporated System and method for accessing digital content using a location-independent name
US9311377B2 (en) 2013-11-13 2016-04-12 Palo Alto Research Center Incorporated Method and apparatus for performing server handoff in a name-based content distribution system
US9363179B2 (en) 2014-03-26 2016-06-07 Palo Alto Research Center Incorporated Multi-publisher routing protocol for named data networks
US9379979B2 (en) 2014-01-14 2016-06-28 Palo Alto Research Center Incorporated Method and apparatus for establishing a virtual interface for a set of mutual-listener devices
US9391777B2 (en) 2014-08-15 2016-07-12 Palo Alto Research Center Incorporated System and method for performing key resolution over a content centric network
US9390289B2 (en) 2014-04-07 2016-07-12 Palo Alto Research Center Incorporated Secure collection synchronization using matched network names
US9391896B2 (en) 2014-03-10 2016-07-12 Palo Alto Research Center Incorporated System and method for packet forwarding using a conjunctive normal form strategy in a content-centric network
US9401864B2 (en) 2013-10-31 2016-07-26 Palo Alto Research Center Incorporated Express header for packets with hierarchically structured variable-length identifiers
US9400800B2 (en) 2012-11-19 2016-07-26 Palo Alto Research Center Incorporated Data transport by named content synchronization
US9407549B2 (en) 2013-10-29 2016-08-02 Palo Alto Research Center Incorporated System and method for hash-based forwarding of packets with hierarchically structured variable-length identifiers
US9407432B2 (en) 2014-03-19 2016-08-02 Palo Alto Research Center Incorporated System and method for efficient and secure distribution of digital content
US9426113B2 (en) 2014-06-30 2016-08-23 Palo Alto Research Center Incorporated System and method for managing devices over a content centric network
US9444722B2 (en) 2013-08-01 2016-09-13 Palo Alto Research Center Incorporated Method and apparatus for configuring routing paths in a custodian-based routing architecture
US9451032B2 (en) 2014-04-10 2016-09-20 Palo Alto Research Center Incorporated System and method for simple service discovery in content-centric networks
US9455835B2 (en) 2014-05-23 2016-09-27 Palo Alto Research Center Incorporated System and method for circular link resolution with hash-based names in content-centric networks
US9462006B2 (en) 2015-01-21 2016-10-04 Palo Alto Research Center Incorporated Network-layer application-specific trust model
US9467377B2 (en) 2014-06-19 2016-10-11 Palo Alto Research Center Incorporated Associating consumer states with interests in a content-centric network
US9467492B2 (en) 2014-08-19 2016-10-11 Palo Alto Research Center Incorporated System and method for reconstructable all-in-one content stream
US9473475B2 (en) 2014-12-22 2016-10-18 Palo Alto Research Center Incorporated Low-cost authenticated signing delegation in content centric networking
US9473576B2 (en) 2014-04-07 2016-10-18 Palo Alto Research Center Incorporated Service discovery using collection synchronization with exact names
US9473405B2 (en) 2014-03-10 2016-10-18 Palo Alto Research Center Incorporated Concurrent hashes and sub-hashes on data streams
US9497282B2 (en) 2014-08-27 2016-11-15 Palo Alto Research Center Incorporated Network coding for content-centric network
US9503365B2 (en) 2014-08-11 2016-11-22 Palo Alto Research Center Incorporated Reputation-based instruction processing over an information centric network
US9503358B2 (en) 2013-12-05 2016-11-22 Palo Alto Research Center Incorporated Distance-based routing in an information-centric network
US9516144B2 (en) 2014-06-19 2016-12-06 Palo Alto Research Center Incorporated Cut-through forwarding of CCNx message fragments with IP encapsulation
US9531679B2 (en) 2014-02-06 2016-12-27 Palo Alto Research Center Incorporated Content-based transport security for distributed producers
US9536059B2 (en) 2014-12-15 2017-01-03 Palo Alto Research Center Incorporated Method and system for verifying renamed content using manifests in a content centric network
US9535968B2 (en) 2014-07-21 2017-01-03 Palo Alto Research Center Incorporated System for distributing nameless objects using self-certifying names
US9537719B2 (en) 2014-06-19 2017-01-03 Palo Alto Research Center Incorporated Method and apparatus for deploying a minimal-cost CCN topology
US9552493B2 (en) 2015-02-03 2017-01-24 Palo Alto Research Center Incorporated Access control framework for information centric networking
US9553812B2 (en) 2014-09-09 2017-01-24 Palo Alto Research Center Incorporated Interest keep alives at intermediate routers in a CCN
US9590948B2 (en) 2014-12-15 2017-03-07 Cisco Systems, Inc. CCN routing using hardware-assisted hash tables
US9602596B2 (en) 2015-01-12 2017-03-21 Cisco Systems, Inc. Peer-to-peer sharing in a content centric network
US9609014B2 (en) 2014-05-22 2017-03-28 Cisco Systems, Inc. Method and apparatus for preventing insertion of malicious content at a named data network router
US9621354B2 (en) 2014-07-17 2017-04-11 Cisco Systems, Inc. Reconstructable content objects
US9626413B2 (en) 2014-03-10 2017-04-18 Cisco Systems, Inc. System and method for ranking content popularity in a content-centric network
US9660825B2 (en) 2014-12-24 2017-05-23 Cisco Technology, Inc. System and method for multi-source multicasting in content-centric networks
US9678998B2 (en) 2014-02-28 2017-06-13 Cisco Technology, Inc. Content name resolution for information centric networking
US9686194B2 (en) 2009-10-21 2017-06-20 Cisco Technology, Inc. Adaptive multi-interface use for content networking
US9699198B2 (en) 2014-07-07 2017-07-04 Cisco Technology, Inc. System and method for parallel secure content bootstrapping in content-centric networks
US9716622B2 (en) 2014-04-01 2017-07-25 Cisco Technology, Inc. System and method for dynamic name configuration in content-centric networks
US9729616B2 (en) 2014-07-18 2017-08-08 Cisco Technology, Inc. Reputation-based strategy for forwarding and responding to interests over a content centric network
US9729662B2 (en) 2014-08-11 2017-08-08 Cisco Technology, Inc. Probabilistic lazy-forwarding technique without validation in a content centric network
US9794238B2 (en) 2015-10-29 2017-10-17 Cisco Technology, Inc. System for key exchange in a content centric network
US9800637B2 (en) 2014-08-19 2017-10-24 Cisco Technology, Inc. System and method for all-in-one content stream in content-centric networks
US9807205B2 (en) 2015-11-02 2017-10-31 Cisco Technology, Inc. Header compression for CCN messages using dictionary
US9832123B2 (en) 2015-09-11 2017-11-28 Cisco Technology, Inc. Network named fragments in a content centric network
US9832116B2 (en) 2016-03-14 2017-11-28 Cisco Technology, Inc. Adjusting entries in a forwarding information base in a content centric network
US9832291B2 (en) 2015-01-12 2017-11-28 Cisco Technology, Inc. Auto-configurable transport stack
US9836540B2 (en) 2014-03-04 2017-12-05 Cisco Technology, Inc. System and method for direct storage access in a content-centric network
US9846881B2 (en) 2014-12-19 2017-12-19 Palo Alto Research Center Incorporated Frugal user engagement help systems
US9882964B2 (en) 2014-08-08 2018-01-30 Cisco Technology, Inc. Explicit strategy feedback in name-based forwarding
US9912776B2 (en) 2015-12-02 2018-03-06 Cisco Technology, Inc. Explicit content deletion commands in a content centric network
US9916601B2 (en) 2014-03-21 2018-03-13 Cisco Technology, Inc. Marketplace for presenting advertisements in a scalable data broadcasting system
US9916457B2 (en) 2015-01-12 2018-03-13 Cisco Technology, Inc. Decoupled name security binding for CCN objects
US9930146B2 (en) 2016-04-04 2018-03-27 Cisco Technology, Inc. System and method for compressing content centric networking messages
US9935791B2 (en) 2013-05-20 2018-04-03 Cisco Technology, Inc. Method and system for name resolution across heterogeneous architectures
US9949301B2 (en) 2016-01-20 2018-04-17 Palo Alto Research Center Incorporated Methods for fast, secure and privacy-friendly internet connection discovery in wireless networks
US9946743B2 (en) 2015-01-12 2018-04-17 Cisco Technology, Inc. Order encoded manifests in a content centric network
US9954678B2 (en) 2014-02-06 2018-04-24 Cisco Technology, Inc. Content-based transport security
US9954795B2 (en) 2015-01-12 2018-04-24 Cisco Technology, Inc. Resource allocation using CCN manifests
US9959156B2 (en) 2014-07-17 2018-05-01 Cisco Technology, Inc. Interest return control message
US9977809B2 (en) 2015-09-24 2018-05-22 Cisco Technology, Inc. Information and data framework in a content centric network
US9978025B2 (en) 2013-03-20 2018-05-22 Cisco Technology, Inc. Ordered-element naming for name-based packet forwarding
US9986034B2 (en) 2015-08-03 2018-05-29 Cisco Technology, Inc. Transferring state in content centric network stacks
US9992281B2 (en) 2014-05-01 2018-06-05 Cisco Technology, Inc. Accountable content stores for information centric networks
US9992097B2 (en) 2016-07-11 2018-06-05 Cisco Technology, Inc. System and method for piggybacking routing information in interests in a content centric network
US10003520B2 (en) 2014-12-22 2018-06-19 Cisco Technology, Inc. System and method for efficient name-based content routing using link-state information in information-centric networks
US10003507B2 (en) 2016-03-04 2018-06-19 Cisco Technology, Inc. Transport session state protocol
US10009446B2 (en) 2015-11-02 2018-06-26 Cisco Technology, Inc. Header compression for CCN messages using dictionary learning
US10009266B2 (en) 2016-07-05 2018-06-26 Cisco Technology, Inc. Method and system for reference counted pending interest tables in a content centric network
US10021222B2 (en) 2015-11-04 2018-07-10 Cisco Technology, Inc. Bit-aligned header compression for CCN messages using dictionary
US10027578B2 (en) 2016-04-11 2018-07-17 Cisco Technology, Inc. Method and system for routable prefix queries in a content centric network
US10033639B2 (en) 2016-03-25 2018-07-24 Cisco Technology, Inc. System and method for routing packets in a content centric network using anonymous datagrams
US10043016B2 (en) 2016-02-29 2018-08-07 Cisco Technology, Inc. Method and system for name encryption agreement in a content centric network
US10051071B2 (en) 2016-03-04 2018-08-14 Cisco Technology, Inc. Method and system for collecting historical network information in a content centric network
US10063414B2 (en) 2016-05-13 2018-08-28 Cisco Technology, Inc. Updating a transport stack in a content centric network
US10067948B2 (en) 2016-03-18 2018-09-04 Cisco Technology, Inc. Data deduping in content centric networking manifests
US10069933B2 (en) 2014-10-23 2018-09-04 Cisco Technology, Inc. System and method for creating virtual interfaces based on network characteristics
US10069729B2 (en) 2016-08-08 2018-09-04 Cisco Technology, Inc. System and method for throttling traffic based on a forwarding information base in a content centric network
US10075521B2 (en) 2014-04-07 2018-09-11 Cisco Technology, Inc. Collection synchronization using equality matched network names
US10075402B2 (en) 2015-06-24 2018-09-11 Cisco Technology, Inc. Flexible command and control in content centric networks
US10075401B2 (en) 2015-03-18 2018-09-11 Cisco Technology, Inc. Pending interest table behavior
US10078062B2 (en) 2015-12-15 2018-09-18 Palo Alto Research Center Incorporated Device health estimation by combining contextual information with sensor data
US10084764B2 (en) 2016-05-13 2018-09-25 Cisco Technology, Inc. System for a secure encryption proxy in a content centric network
US10089651B2 (en) 2014-03-03 2018-10-02 Cisco Technology, Inc. Method and apparatus for streaming advertisements in a scalable data broadcasting system
US10091330B2 (en) 2016-03-23 2018-10-02 Cisco Technology, Inc. Interest scheduling by an information and data framework in a content centric network
US10089655B2 (en) 2013-11-27 2018-10-02 Cisco Technology, Inc. Method and apparatus for scalable data broadcasting
US10097521B2 (en) 2015-11-20 2018-10-09 Cisco Technology, Inc. Transparent encryption in a content centric network
US10097346B2 (en) 2015-12-09 2018-10-09 Cisco Technology, Inc. Key catalogs in a content centric network
US10098051B2 (en) 2014-01-22 2018-10-09 Cisco Technology, Inc. Gateways and routing in software-defined manets
US10101801B2 (en) 2013-11-13 2018-10-16 Cisco Technology, Inc. Method and apparatus for prefetching content in a data stream
US10103989B2 (en) 2016-06-13 2018-10-16 Cisco Technology, Inc. Content object return messages in a content centric network
US10104041B2 (en) 2008-05-16 2018-10-16 Cisco Technology, Inc. Controlling the spread of interests and content in a content centric network
US10116605B2 (en) 2015-06-22 2018-10-30 Cisco Technology, Inc. Transport stack name scheme and identity management
US10122624B2 (en) 2016-07-25 2018-11-06 Cisco Technology, Inc. System and method for ephemeral entries in a forwarding information base in a content centric network
US10129365B2 (en) 2013-11-13 2018-11-13 Cisco Technology, Inc. Method and apparatus for pre-fetching remote content based on static and dynamic recommendations
US10135948B2 (en) 2016-10-31 2018-11-20 Cisco Technology, Inc. System and method for process migration in a content centric network
US10148572B2 (en) 2016-06-27 2018-12-04 Cisco Technology, Inc. Method and system for interest groups in a content centric network
US10172068B2 (en) 2014-01-22 2019-01-01 Cisco Technology, Inc. Service-oriented routing in software-defined MANETs
US10204013B2 (en) 2014-09-03 2019-02-12 Cisco Technology, Inc. System and method for maintaining a distributed and fault-tolerant state over an information centric network
US10212196B2 (en) 2016-03-16 2019-02-19 Cisco Technology, Inc. Interface discovery and authentication in a name-based network
US10237189B2 (en) 2014-12-16 2019-03-19 Cisco Technology, Inc. System and method for distance-based interest forwarding
US10243851B2 (en) 2016-11-21 2019-03-26 Cisco Technology, Inc. System and method for forwarder connection information in a content centric network
US10257271B2 (en) 2016-01-11 2019-04-09 Cisco Technology, Inc. Chandra-Toueg consensus in a content centric network
US10263965B2 (en) 2015-10-16 2019-04-16 Cisco Technology, Inc. Encrypted CCNx
US10305865B2 (en) 2016-06-21 2019-05-28 Cisco Technology, Inc. Permutation-based content encryption with manifests in a content centric network
US10305864B2 (en) 2016-01-25 2019-05-28 Cisco Technology, Inc. Method and system for interest encryption in a content centric network
US10313227B2 (en) 2015-09-24 2019-06-04 Cisco Technology, Inc. System and method for eliminating undetected interest looping in information-centric networks
US10320760B2 (en) 2016-04-01 2019-06-11 Cisco Technology, Inc. Method and system for mutating and caching content in a content centric network
US10320675B2 (en) 2016-05-04 2019-06-11 Cisco Technology, Inc. System and method for routing packets in a stateless content centric network
US10333840B2 (en) 2015-02-06 2019-06-25 Cisco Technology, Inc. System and method for on-demand content exchange with adaptive naming in information-centric networks
US10355999B2 (en) 2015-09-23 2019-07-16 Cisco Technology, Inc. Flow control with network named fragments
US10404450B2 (en) 2016-05-02 2019-09-03 Cisco Technology, Inc. Schematized access control in a content centric network
US10425503B2 (en) 2016-04-07 2019-09-24 Cisco Technology, Inc. Shared pending interest table in a content centric network
US10447805B2 (en) 2016-10-10 2019-10-15 Cisco Technology, Inc. Distributed consensus in a content centric network
US10454820B2 (en) 2015-09-29 2019-10-22 Cisco Technology, Inc. System and method for stateless information-centric networking
US10469378B2 (en) 2016-03-04 2019-11-05 Cisco Technology, Inc. Protocol to query for historical network information in a content centric network
US10547589B2 (en) 2016-05-09 2020-01-28 Cisco Technology, Inc. System for implementing a small computer systems interface protocol over a content centric network
US10610144B2 (en) 2015-08-19 2020-04-07 Palo Alto Research Center Incorporated Interactive remote patient monitoring and condition management intervention system
US10701038B2 (en) 2015-07-27 2020-06-30 Cisco Technology, Inc. Content negotiation in a content centric network
US10742596B2 (en) 2016-03-04 2020-08-11 Cisco Technology, Inc. Method and system for reducing a collision probability of hash-based names using a publisher identifier
US10897518B2 (en) 2016-10-03 2021-01-19 Cisco Technology, Inc. Cache management on high availability routers in a content centric network
US10956412B2 (en) 2016-08-09 2021-03-23 Cisco Technology, Inc. Method and system for conjunctive normal form attribute matching in a content centric network
US11436656B2 (en) 2016-03-18 2022-09-06 Palo Alto Research Center Incorporated System and method for a real-time egocentric collaborative filter on large datasets

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP2108662A1 (de) 2008-04-10 2009-10-14 Hexion Specialty Chemicals Research Belgium S.A. Copolymerisierungsverfahren in 1-Alkene- und Vinylester-Emulsion mit hoher Konvertierung

Cited By (157)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2008031790A1 (de) * 2006-09-14 2008-03-20 Basf Se Verfahren zur herstellung einer wässrigen polymerisatdispersion
EP1900756A1 (de) * 2006-09-14 2008-03-19 Basf Se Verfahren zur Herstellung einer wässrigen Polymerisatdispersion
US10104041B2 (en) 2008-05-16 2018-10-16 Cisco Technology, Inc. Controlling the spread of interests and content in a content centric network
EP2147717A1 (de) 2008-07-25 2010-01-27 Basf Se Dispergierhilfsmittel für die Emulsions- und Suspensionspolymerisation
EP2177563A1 (de) 2008-10-15 2010-04-21 Basf Se Wässriges Bindemittel für körnige und/oder faserförmige Substrate
US9686194B2 (en) 2009-10-21 2017-06-20 Cisco Technology, Inc. Adaptive multi-interface use for content networking
WO2013067109A1 (en) 2011-11-01 2013-05-10 Lubrizol Advanced Materials, Inc. Acrylate-olefin copolymers, methods for producing same and compositions utilizing same
US9303111B2 (en) 2011-11-01 2016-04-05 Lubrizol Advanced Materials, Inc. Acrylate-olefin copolymers, methods for producing same and compositions utilizing same
US9280546B2 (en) 2012-10-31 2016-03-08 Palo Alto Research Center Incorporated System and method for accessing digital content using a location-independent name
US9400800B2 (en) 2012-11-19 2016-07-26 Palo Alto Research Center Incorporated Data transport by named content synchronization
US9978025B2 (en) 2013-03-20 2018-05-22 Cisco Technology, Inc. Ordered-element naming for name-based packet forwarding
US9935791B2 (en) 2013-05-20 2018-04-03 Cisco Technology, Inc. Method and system for name resolution across heterogeneous architectures
US9185120B2 (en) 2013-05-23 2015-11-10 Palo Alto Research Center Incorporated Method and system for mitigating interest flooding attacks in content-centric networks
US9444722B2 (en) 2013-08-01 2016-09-13 Palo Alto Research Center Incorporated Method and apparatus for configuring routing paths in a custodian-based routing architecture
US9407549B2 (en) 2013-10-29 2016-08-02 Palo Alto Research Center Incorporated System and method for hash-based forwarding of packets with hierarchically structured variable-length identifiers
US9276840B2 (en) 2013-10-30 2016-03-01 Palo Alto Research Center Incorporated Interest messages with a payload for a named data network
US9282050B2 (en) 2013-10-30 2016-03-08 Palo Alto Research Center Incorporated System and method for minimum path MTU discovery in content centric networks
US9401864B2 (en) 2013-10-31 2016-07-26 Palo Alto Research Center Incorporated Express header for packets with hierarchically structured variable-length identifiers
US10101801B2 (en) 2013-11-13 2018-10-16 Cisco Technology, Inc. Method and apparatus for prefetching content in a data stream
US10129365B2 (en) 2013-11-13 2018-11-13 Cisco Technology, Inc. Method and apparatus for pre-fetching remote content based on static and dynamic recommendations
US9311377B2 (en) 2013-11-13 2016-04-12 Palo Alto Research Center Incorporated Method and apparatus for performing server handoff in a name-based content distribution system
US10089655B2 (en) 2013-11-27 2018-10-02 Cisco Technology, Inc. Method and apparatus for scalable data broadcasting
US9503358B2 (en) 2013-12-05 2016-11-22 Palo Alto Research Center Incorporated Distance-based routing in an information-centric network
US9379979B2 (en) 2014-01-14 2016-06-28 Palo Alto Research Center Incorporated Method and apparatus for establishing a virtual interface for a set of mutual-listener devices
US10172068B2 (en) 2014-01-22 2019-01-01 Cisco Technology, Inc. Service-oriented routing in software-defined MANETs
US10098051B2 (en) 2014-01-22 2018-10-09 Cisco Technology, Inc. Gateways and routing in software-defined manets
US9954678B2 (en) 2014-02-06 2018-04-24 Cisco Technology, Inc. Content-based transport security
US9531679B2 (en) 2014-02-06 2016-12-27 Palo Alto Research Center Incorporated Content-based transport security for distributed producers
US10706029B2 (en) 2014-02-28 2020-07-07 Cisco Technology, Inc. Content name resolution for information centric networking
US9678998B2 (en) 2014-02-28 2017-06-13 Cisco Technology, Inc. Content name resolution for information centric networking
US10089651B2 (en) 2014-03-03 2018-10-02 Cisco Technology, Inc. Method and apparatus for streaming advertisements in a scalable data broadcasting system
US10445380B2 (en) 2014-03-04 2019-10-15 Cisco Technology, Inc. System and method for direct storage access in a content-centric network
US9836540B2 (en) 2014-03-04 2017-12-05 Cisco Technology, Inc. System and method for direct storage access in a content-centric network
US9391896B2 (en) 2014-03-10 2016-07-12 Palo Alto Research Center Incorporated System and method for packet forwarding using a conjunctive normal form strategy in a content-centric network
US9473405B2 (en) 2014-03-10 2016-10-18 Palo Alto Research Center Incorporated Concurrent hashes and sub-hashes on data streams
US9626413B2 (en) 2014-03-10 2017-04-18 Cisco Systems, Inc. System and method for ranking content popularity in a content-centric network
US9407432B2 (en) 2014-03-19 2016-08-02 Palo Alto Research Center Incorporated System and method for efficient and secure distribution of digital content
US9916601B2 (en) 2014-03-21 2018-03-13 Cisco Technology, Inc. Marketplace for presenting advertisements in a scalable data broadcasting system
US9363179B2 (en) 2014-03-26 2016-06-07 Palo Alto Research Center Incorporated Multi-publisher routing protocol for named data networks
US9716622B2 (en) 2014-04-01 2017-07-25 Cisco Technology, Inc. System and method for dynamic name configuration in content-centric networks
US10075521B2 (en) 2014-04-07 2018-09-11 Cisco Technology, Inc. Collection synchronization using equality matched network names
US9390289B2 (en) 2014-04-07 2016-07-12 Palo Alto Research Center Incorporated Secure collection synchronization using matched network names
US9473576B2 (en) 2014-04-07 2016-10-18 Palo Alto Research Center Incorporated Service discovery using collection synchronization with exact names
US9451032B2 (en) 2014-04-10 2016-09-20 Palo Alto Research Center Incorporated System and method for simple service discovery in content-centric networks
US9203885B2 (en) 2014-04-28 2015-12-01 Palo Alto Research Center Incorporated Method and apparatus for exchanging bidirectional streams over a content centric network
US9992281B2 (en) 2014-05-01 2018-06-05 Cisco Technology, Inc. Accountable content stores for information centric networks
US10158656B2 (en) 2014-05-22 2018-12-18 Cisco Technology, Inc. Method and apparatus for preventing insertion of malicious content at a named data network router
US9609014B2 (en) 2014-05-22 2017-03-28 Cisco Systems, Inc. Method and apparatus for preventing insertion of malicious content at a named data network router
US9455835B2 (en) 2014-05-23 2016-09-27 Palo Alto Research Center Incorporated System and method for circular link resolution with hash-based names in content-centric networks
US9276751B2 (en) 2014-05-28 2016-03-01 Palo Alto Research Center Incorporated System and method for circular link resolution with computable hash-based names in content-centric networks
US9537719B2 (en) 2014-06-19 2017-01-03 Palo Alto Research Center Incorporated Method and apparatus for deploying a minimal-cost CCN topology
US9516144B2 (en) 2014-06-19 2016-12-06 Palo Alto Research Center Incorporated Cut-through forwarding of CCNx message fragments with IP encapsulation
US9467377B2 (en) 2014-06-19 2016-10-11 Palo Alto Research Center Incorporated Associating consumer states with interests in a content-centric network
US9426113B2 (en) 2014-06-30 2016-08-23 Palo Alto Research Center Incorporated System and method for managing devices over a content centric network
US9699198B2 (en) 2014-07-07 2017-07-04 Cisco Technology, Inc. System and method for parallel secure content bootstrapping in content-centric networks
US10237075B2 (en) 2014-07-17 2019-03-19 Cisco Technology, Inc. Reconstructable content objects
US9959156B2 (en) 2014-07-17 2018-05-01 Cisco Technology, Inc. Interest return control message
US9621354B2 (en) 2014-07-17 2017-04-11 Cisco Systems, Inc. Reconstructable content objects
US10305968B2 (en) 2014-07-18 2019-05-28 Cisco Technology, Inc. Reputation-based strategy for forwarding and responding to interests over a content centric network
US9729616B2 (en) 2014-07-18 2017-08-08 Cisco Technology, Inc. Reputation-based strategy for forwarding and responding to interests over a content centric network
US9535968B2 (en) 2014-07-21 2017-01-03 Palo Alto Research Center Incorporated System for distributing nameless objects using self-certifying names
US9882964B2 (en) 2014-08-08 2018-01-30 Cisco Technology, Inc. Explicit strategy feedback in name-based forwarding
US9729662B2 (en) 2014-08-11 2017-08-08 Cisco Technology, Inc. Probabilistic lazy-forwarding technique without validation in a content centric network
US9503365B2 (en) 2014-08-11 2016-11-22 Palo Alto Research Center Incorporated Reputation-based instruction processing over an information centric network
US9391777B2 (en) 2014-08-15 2016-07-12 Palo Alto Research Center Incorporated System and method for performing key resolution over a content centric network
US10367871B2 (en) 2014-08-19 2019-07-30 Cisco Technology, Inc. System and method for all-in-one content stream in content-centric networks
US9467492B2 (en) 2014-08-19 2016-10-11 Palo Alto Research Center Incorporated System and method for reconstructable all-in-one content stream
US9800637B2 (en) 2014-08-19 2017-10-24 Cisco Technology, Inc. System and method for all-in-one content stream in content-centric networks
US9497282B2 (en) 2014-08-27 2016-11-15 Palo Alto Research Center Incorporated Network coding for content-centric network
US11314597B2 (en) 2014-09-03 2022-04-26 Cisco Technology, Inc. System and method for maintaining a distributed and fault-tolerant state over an information centric network
US10204013B2 (en) 2014-09-03 2019-02-12 Cisco Technology, Inc. System and method for maintaining a distributed and fault-tolerant state over an information centric network
US9553812B2 (en) 2014-09-09 2017-01-24 Palo Alto Research Center Incorporated Interest keep alives at intermediate routers in a CCN
US10715634B2 (en) 2014-10-23 2020-07-14 Cisco Technology, Inc. System and method for creating virtual interfaces based on network characteristics
US10069933B2 (en) 2014-10-23 2018-09-04 Cisco Technology, Inc. System and method for creating virtual interfaces based on network characteristics
US9536059B2 (en) 2014-12-15 2017-01-03 Palo Alto Research Center Incorporated Method and system for verifying renamed content using manifests in a content centric network
US9590948B2 (en) 2014-12-15 2017-03-07 Cisco Systems, Inc. CCN routing using hardware-assisted hash tables
US10237189B2 (en) 2014-12-16 2019-03-19 Cisco Technology, Inc. System and method for distance-based interest forwarding
US9846881B2 (en) 2014-12-19 2017-12-19 Palo Alto Research Center Incorporated Frugal user engagement help systems
US10003520B2 (en) 2014-12-22 2018-06-19 Cisco Technology, Inc. System and method for efficient name-based content routing using link-state information in information-centric networks
US9473475B2 (en) 2014-12-22 2016-10-18 Palo Alto Research Center Incorporated Low-cost authenticated signing delegation in content centric networking
US10091012B2 (en) 2014-12-24 2018-10-02 Cisco Technology, Inc. System and method for multi-source multicasting in content-centric networks
US9660825B2 (en) 2014-12-24 2017-05-23 Cisco Technology, Inc. System and method for multi-source multicasting in content-centric networks
US9602596B2 (en) 2015-01-12 2017-03-21 Cisco Systems, Inc. Peer-to-peer sharing in a content centric network
US9946743B2 (en) 2015-01-12 2018-04-17 Cisco Technology, Inc. Order encoded manifests in a content centric network
US9832291B2 (en) 2015-01-12 2017-11-28 Cisco Technology, Inc. Auto-configurable transport stack
US9954795B2 (en) 2015-01-12 2018-04-24 Cisco Technology, Inc. Resource allocation using CCN manifests
US10440161B2 (en) 2015-01-12 2019-10-08 Cisco Technology, Inc. Auto-configurable transport stack
US9916457B2 (en) 2015-01-12 2018-03-13 Cisco Technology, Inc. Decoupled name security binding for CCN objects
US9462006B2 (en) 2015-01-21 2016-10-04 Palo Alto Research Center Incorporated Network-layer application-specific trust model
US9552493B2 (en) 2015-02-03 2017-01-24 Palo Alto Research Center Incorporated Access control framework for information centric networking
US10333840B2 (en) 2015-02-06 2019-06-25 Cisco Technology, Inc. System and method for on-demand content exchange with adaptive naming in information-centric networks
US10075401B2 (en) 2015-03-18 2018-09-11 Cisco Technology, Inc. Pending interest table behavior
US10116605B2 (en) 2015-06-22 2018-10-30 Cisco Technology, Inc. Transport stack name scheme and identity management
US10075402B2 (en) 2015-06-24 2018-09-11 Cisco Technology, Inc. Flexible command and control in content centric networks
US10701038B2 (en) 2015-07-27 2020-06-30 Cisco Technology, Inc. Content negotiation in a content centric network
US9986034B2 (en) 2015-08-03 2018-05-29 Cisco Technology, Inc. Transferring state in content centric network stacks
US10610144B2 (en) 2015-08-19 2020-04-07 Palo Alto Research Center Incorporated Interactive remote patient monitoring and condition management intervention system
US10419345B2 (en) 2015-09-11 2019-09-17 Cisco Technology, Inc. Network named fragments in a content centric network
US9832123B2 (en) 2015-09-11 2017-11-28 Cisco Technology, Inc. Network named fragments in a content centric network
US10355999B2 (en) 2015-09-23 2019-07-16 Cisco Technology, Inc. Flow control with network named fragments
US10313227B2 (en) 2015-09-24 2019-06-04 Cisco Technology, Inc. System and method for eliminating undetected interest looping in information-centric networks
US9977809B2 (en) 2015-09-24 2018-05-22 Cisco Technology, Inc. Information and data framework in a content centric network
US10454820B2 (en) 2015-09-29 2019-10-22 Cisco Technology, Inc. System and method for stateless information-centric networking
US10263965B2 (en) 2015-10-16 2019-04-16 Cisco Technology, Inc. Encrypted CCNx
US10129230B2 (en) 2015-10-29 2018-11-13 Cisco Technology, Inc. System for key exchange in a content centric network
US9794238B2 (en) 2015-10-29 2017-10-17 Cisco Technology, Inc. System for key exchange in a content centric network
US10009446B2 (en) 2015-11-02 2018-06-26 Cisco Technology, Inc. Header compression for CCN messages using dictionary learning
US9807205B2 (en) 2015-11-02 2017-10-31 Cisco Technology, Inc. Header compression for CCN messages using dictionary
US10021222B2 (en) 2015-11-04 2018-07-10 Cisco Technology, Inc. Bit-aligned header compression for CCN messages using dictionary
US10681018B2 (en) 2015-11-20 2020-06-09 Cisco Technology, Inc. Transparent encryption in a content centric network
US10097521B2 (en) 2015-11-20 2018-10-09 Cisco Technology, Inc. Transparent encryption in a content centric network
US9912776B2 (en) 2015-12-02 2018-03-06 Cisco Technology, Inc. Explicit content deletion commands in a content centric network
US10097346B2 (en) 2015-12-09 2018-10-09 Cisco Technology, Inc. Key catalogs in a content centric network
US10078062B2 (en) 2015-12-15 2018-09-18 Palo Alto Research Center Incorporated Device health estimation by combining contextual information with sensor data
US10257271B2 (en) 2016-01-11 2019-04-09 Cisco Technology, Inc. Chandra-Toueg consensus in a content centric network
US10581967B2 (en) 2016-01-11 2020-03-03 Cisco Technology, Inc. Chandra-Toueg consensus in a content centric network
US9949301B2 (en) 2016-01-20 2018-04-17 Palo Alto Research Center Incorporated Methods for fast, secure and privacy-friendly internet connection discovery in wireless networks
US10305864B2 (en) 2016-01-25 2019-05-28 Cisco Technology, Inc. Method and system for interest encryption in a content centric network
US10043016B2 (en) 2016-02-29 2018-08-07 Cisco Technology, Inc. Method and system for name encryption agreement in a content centric network
US10469378B2 (en) 2016-03-04 2019-11-05 Cisco Technology, Inc. Protocol to query for historical network information in a content centric network
US10051071B2 (en) 2016-03-04 2018-08-14 Cisco Technology, Inc. Method and system for collecting historical network information in a content centric network
US10003507B2 (en) 2016-03-04 2018-06-19 Cisco Technology, Inc. Transport session state protocol
US10742596B2 (en) 2016-03-04 2020-08-11 Cisco Technology, Inc. Method and system for reducing a collision probability of hash-based names using a publisher identifier
US9832116B2 (en) 2016-03-14 2017-11-28 Cisco Technology, Inc. Adjusting entries in a forwarding information base in a content centric network
US10129368B2 (en) 2016-03-14 2018-11-13 Cisco Technology, Inc. Adjusting entries in a forwarding information base in a content centric network
US10212196B2 (en) 2016-03-16 2019-02-19 Cisco Technology, Inc. Interface discovery and authentication in a name-based network
US11436656B2 (en) 2016-03-18 2022-09-06 Palo Alto Research Center Incorporated System and method for a real-time egocentric collaborative filter on large datasets
US10067948B2 (en) 2016-03-18 2018-09-04 Cisco Technology, Inc. Data deduping in content centric networking manifests
US10091330B2 (en) 2016-03-23 2018-10-02 Cisco Technology, Inc. Interest scheduling by an information and data framework in a content centric network
US10033639B2 (en) 2016-03-25 2018-07-24 Cisco Technology, Inc. System and method for routing packets in a content centric network using anonymous datagrams
US10320760B2 (en) 2016-04-01 2019-06-11 Cisco Technology, Inc. Method and system for mutating and caching content in a content centric network
US9930146B2 (en) 2016-04-04 2018-03-27 Cisco Technology, Inc. System and method for compressing content centric networking messages
US10348865B2 (en) 2016-04-04 2019-07-09 Cisco Technology, Inc. System and method for compressing content centric networking messages
US10425503B2 (en) 2016-04-07 2019-09-24 Cisco Technology, Inc. Shared pending interest table in a content centric network
US10027578B2 (en) 2016-04-11 2018-07-17 Cisco Technology, Inc. Method and system for routable prefix queries in a content centric network
US10841212B2 (en) 2016-04-11 2020-11-17 Cisco Technology, Inc. Method and system for routable prefix queries in a content centric network
US10404450B2 (en) 2016-05-02 2019-09-03 Cisco Technology, Inc. Schematized access control in a content centric network
US10320675B2 (en) 2016-05-04 2019-06-11 Cisco Technology, Inc. System and method for routing packets in a stateless content centric network
US10547589B2 (en) 2016-05-09 2020-01-28 Cisco Technology, Inc. System for implementing a small computer systems interface protocol over a content centric network
US10063414B2 (en) 2016-05-13 2018-08-28 Cisco Technology, Inc. Updating a transport stack in a content centric network
US10084764B2 (en) 2016-05-13 2018-09-25 Cisco Technology, Inc. System for a secure encryption proxy in a content centric network
US10404537B2 (en) 2016-05-13 2019-09-03 Cisco Technology, Inc. Updating a transport stack in a content centric network
US10693852B2 (en) 2016-05-13 2020-06-23 Cisco Technology, Inc. System for a secure encryption proxy in a content centric network
US10103989B2 (en) 2016-06-13 2018-10-16 Cisco Technology, Inc. Content object return messages in a content centric network
US10305865B2 (en) 2016-06-21 2019-05-28 Cisco Technology, Inc. Permutation-based content encryption with manifests in a content centric network
US10581741B2 (en) 2016-06-27 2020-03-03 Cisco Technology, Inc. Method and system for interest groups in a content centric network
US10148572B2 (en) 2016-06-27 2018-12-04 Cisco Technology, Inc. Method and system for interest groups in a content centric network
US10009266B2 (en) 2016-07-05 2018-06-26 Cisco Technology, Inc. Method and system for reference counted pending interest tables in a content centric network
US9992097B2 (en) 2016-07-11 2018-06-05 Cisco Technology, Inc. System and method for piggybacking routing information in interests in a content centric network
US10122624B2 (en) 2016-07-25 2018-11-06 Cisco Technology, Inc. System and method for ephemeral entries in a forwarding information base in a content centric network
US10069729B2 (en) 2016-08-08 2018-09-04 Cisco Technology, Inc. System and method for throttling traffic based on a forwarding information base in a content centric network
US10956412B2 (en) 2016-08-09 2021-03-23 Cisco Technology, Inc. Method and system for conjunctive normal form attribute matching in a content centric network
US10897518B2 (en) 2016-10-03 2021-01-19 Cisco Technology, Inc. Cache management on high availability routers in a content centric network
US10447805B2 (en) 2016-10-10 2019-10-15 Cisco Technology, Inc. Distributed consensus in a content centric network
US10721332B2 (en) 2016-10-31 2020-07-21 Cisco Technology, Inc. System and method for process migration in a content centric network
US10135948B2 (en) 2016-10-31 2018-11-20 Cisco Technology, Inc. System and method for process migration in a content centric network
US10243851B2 (en) 2016-11-21 2019-03-26 Cisco Technology, Inc. System and method for forwarder connection information in a content centric network

Also Published As

Publication number Publication date
GB1104536A (en) 1968-02-28

Similar Documents

Publication Publication Date Title
DE1720277A1 (de) Verfahren zur Herstellung von filmbildenden waessrigen Copolymerdispersionen
DE2542280C3 (de) Verfahren zur Polymerisation von Vinylidenfluorid
DE2256154C3 (de) Verfahren zur Herstellung von wäßrigen Dispersionen von Polymerisaten monoolefinisch ungesättigter Carbonsäureester
DE1595680A1 (de) Sulfonsaeuregruppen enthaltende Polymerisate
CH515941A (de) Verfahren zur Mischpolymerisation von Monoolefinen
DE2358270B2 (de) Verfahren zur kontinuierlichen Copolymerisation von Vinylidenfluorid mit mindestens einem anderen, ungesättigten fluorierten Monomeren
DE1165856B (de) Verfahren zur Polymerisation von radikalisch polymerisierbaren ungesaettigten Verbindungen
GB940366A (en) Process for preparing a freeze-thaw stable acrylate latex
DE1770231A1 (de) Filmbildende waessrige Dispersionen von Copolymeren und Verfahren zu ihrer Herstellung
DE2840502A1 (de) Verfahren zur herstellung von terpolymeren
DE1520549A1 (de) Verfahren zur Herstellung von Pfropfpolymerisaten
US3925327A (en) Method for producing vinyl acetate-ethylene-dicarboxylic acid diallyl ester copolymer
DE2701147C2 (de) Verfahren zur Herstellung von Vinylchlorid-Copolymerisaten mit niedrigem Restmonomergehalt
US2739136A (en) Synthetic rubber latices
US3049522A (en) Formation of bead polymers in presence of catalyst containing dicyclopentadienyliron
US3172876A (en) Process for the manufacture of modified polyvinyl alcohols
US3637621A (en) Process for the polymerization of vinyl chloride
DE1016443B (de) Verfahren zur Herstellung von waessrigen Dispersionen von Polymerisationsprodukten des AEthylens
GB578849A (en) Improved polymerisation process
US3219609A (en) Aqueous dispersions of vinyl chloride-acrylic ester copolymers
DE1229730B (de) Verfahren zur Herstellung von Acrylnitril-Mischpolymerisaten
DE968650C (de) Verwendung von Emulgiermitteln bei der Emulsionspolymerisation
DE1022796B (de) Verfahren zur Herstellung waessriger Dispersionen von Mischpolymerisaten des AEthylens
DE1301084B (de) Verfahren zur Herstellung von Mischpolymerisaten
DE1088230B (de) Verfahren zur Herstellung von Polymerisaten und Mischpolymerisaten