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DE1141932B - Process for the production of a fiber-reinforced building material from cement, water, sand and foam-generating and foam-stabilizing substances - Google Patents

Process for the production of a fiber-reinforced building material from cement, water, sand and foam-generating and foam-stabilizing substances

Info

Publication number
DE1141932B
DE1141932B DEC19533A DEC0019533A DE1141932B DE 1141932 B DE1141932 B DE 1141932B DE C19533 A DEC19533 A DE C19533A DE C0019533 A DEC0019533 A DE C0019533A DE 1141932 B DE1141932 B DE 1141932B
Authority
DE
Germany
Prior art keywords
foam
fiber
cement
sand
production
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
DEC19533A
Other languages
German (de)
Inventor
Heinz Mueller
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Chemieprodukte GmbH
Original Assignee
Chemieprodukte GmbH
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Chemieprodukte GmbH filed Critical Chemieprodukte GmbH
Priority to DEC19533A priority Critical patent/DE1141932B/en
Publication of DE1141932B publication Critical patent/DE1141932B/en
Pending legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B28/00—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
    • C04B28/02—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing hydraulic cements other than calcium sulfates
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B20/00—Use of materials as fillers for mortars, concrete or artificial stone according to more than one of groups C04B14/00 - C04B18/00 and characterised by shape or grain distribution; Treatment of materials according to more than one of the groups C04B14/00 - C04B18/00 specially adapted to enhance their filling properties in mortars, concrete or artificial stone; Expanding or defibrillating materials
    • C04B20/10—Coating or impregnating
    • C04B20/1055—Coating or impregnating with inorganic materials

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Ceramic Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Structural Engineering (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Surface Treatment Of Glass Fibres Or Filaments (AREA)

Description

Verfahren zur Herstellung eines faserverstärkten Baumaterials aus Zement, Wasser, Sand und schaumerzeugenden und schaumstabilisierenden Stoffen Zusatz zur Patentanmeldung C 19353 VI b/ 80 b (Auslegeschrift 1124 415) In der Patentanmeldung C 19353 VIb/80b ist die Herstellung eines faserverstärkten, zementhaltigen Baumaterials, insbesondere von faserverstärktem Leichtbeton beschrieben worden, die nach der Erfindung unter Zuhilfenahme von Mineralfasern, wie z. B. Basaltwolle, mit einfachen Mitteln bei hoher Wirtschaftlichkeit möglich ist, wenn man eine wäßrige, schaumerzeugende und schaumstabilisierende Stoffe und vorzugsweise außerdem Alginate enthaltende Harzlösung oder -emulsion, vorzugsweise auf der Basis von klebenden Harzen, wie z. B. Kolophonium, Zement, Sand und Wasser unter Zusatz von Mineralfasern, vorzugsweise Basaltfasern, für wenige Minuten kräftig durchmischt.Process for the production of a fiber-reinforced building material from cement, water, sand and foam-producing and foam-stabilizing substances Addition to patent application C 19353 VI b / 80 b (Auslegeschrift 1 124 415) In patent application C 19353 VIb / 80b, the production of a fiber-reinforced, cement-containing building material, in particular of fiber-reinforced lightweight concrete has been described, which according to the invention with the aid of mineral fibers, such as. B. basalt wool, is possible with simple means with high economic efficiency if you have an aqueous, foam-producing and foam-stabilizing substances and preferably also alginates-containing resin solution or emulsion, preferably based on adhesive resins, such as. B. rosin, cement, sand and water with the addition of mineral fibers, preferably basalt fibers, vigorously mixed for a few minutes.

Es hat sich nunmehr weiterhin herausgestellt, daß man eine besonders vollkommene und innige Verbindung der gleichmäßig verteilten mineralischen Fasern, vorzugsweise Basaltfasern, mit den Betonbestandteilen, d. h. dem Zement und Sand, .dann erreicht, wenn man auf der Faser aus einer wäßrigen Lösung von Alkalisilikaten mit Hilfe von Säuren Kieselsäure niederschlägt. Derartige Fasern besitzen eine hochaktive, vorzugsweise aus Kieselsäure bestehende, fest mit der Faser verbundene Belagschicht. Durch Vorbehandlung der Faser mit Säuren kann ihr zusätzlich eine unregelmäßige und vergrößerte Oberflächenstruktur gegeben werden, die nach der Erzeugung des Kieselsäureniederschlages eine besonders innige Verzahnung und feste Bindung mit den Betonteilen herbeiführt.It has now also turned out that one special perfect and intimate connection of the evenly distributed mineral fibers, preferably basalt fibers, with the concrete components, d. H. the cement and sand, .then achieved when one on the fiber from an aqueous solution of alkali silicates with the help of acids silicic acid precipitates. Such fibers have a highly active, The covering layer is preferably made of silica and is firmly connected to the fiber. By pretreating the fiber with acids you can also get an irregular and increased surface structure are given after the formation of the silica precipitate brings about a particularly close interlocking and firm bond with the concrete parts.

ES ist schon bekannt, auf Faserstoffen Siliciumdioxyd zur Aufrauhung der Oberfläche niederzuschlagen. Mit Siliciumdioxyd können die vorteilhaften Effekte der Niederschlagung von Kieselsäure, nämlich die innige Verbindung zwischen Mineralfaser und Zement, nicht erreicht werden.It is already known to use silicon dioxide on fiber materials for roughening knock down on the surface. Using silica can have beneficial effects the precipitation of silica, namely the intimate connection between mineral fibers and cement, cannot be achieved.

Zur Erzeugung des Kieselsäureniederschlags auf der Mineralfaser kann man z. B. in folgender Weise vorgehen: Kieselgar wird in Natronlauge gekocht, wobei die kieselsäurehaltigen Anteile der Infusorienerde (Diatomeenschalen) in Lösung gehen. Man trägt in diese Lösung die vorzubehandelnden Fasern ein, gibt eine Säure, z. B. Salzsäure oder Kohlensäure, zu und fällt hierdurch die Kieselsäure auf der von der Säure benetzten Faser aus.To generate the silica precipitate on the mineral fiber can one z. B. proceed in the following way: Kieselgar is boiled in sodium hydroxide solution, whereby the silica-containing parts of the infusor earth (diatom shells) in solution walk. The fibers to be pretreated are added to this solution, an acid is added, z. B. hydrochloric acid or carbonic acid, and thereby falls the silica on the fiber wetted by the acid.

Die Alkalisilikatlösung, aus der die als Niederschlagsschicht für die Faser bestimmte Kieselsäure gefällt wird, kann auch auf andere Weise gewonnen werden.The alkali silicate solution that is used as a precipitation layer for The fiber certain silica is precipitated can also be obtained in other ways will.

Claims (2)

PATENTANSPRÜCHE: 1. Verfahren zur Herstellung eines faserverstärkten, zementhaltigen Baumaterials durch kräftiges Vermischen einer wäßrigen Schaumerzeugende und schaumstabilisierende Stoffe und vorzugsweise außerdem Alginate enthaltenden Harzlösung oder -emulsion, vorzugsweise auf der Basis von klebenden Harzen, wie z. B. Kolophonium, und eines Gemisches von Zement, Sand und Wasser unter Zusatz von Mineralfasern, vorzugsweise Basaltfasern, gemäß Patentanmeldung C 19353 VI b/ 80b, dadurch gekennzeichnet, daß auf der Mineralfaser, gegebenenfalls nach Vorbehandlang mit Säuren, aus -einer wäßrigen Lösung von Alkalisilikaten mit Hilfe von Säuren, vorzugsweise Salzsäure oder Kohlensäure, Kieselsäure niedergeschlagen wird. PATENT CLAIMS: 1. A process for the production of a fiber-reinforced, cement-containing building material by vigorously mixing an aqueous foam-producing and foam-stabilizing substances and preferably also alginates-containing resin solution or emulsion, preferably based on adhesive resins, such as. B. rosin, and a mixture of cement, sand and water with the addition of mineral fibers, preferably basalt fibers, according to patent application C 19353 VI b / 80b, characterized in that on the mineral fiber, optionally after pretreatment with acids, from an aqueous solution of Alkali silicates with the help of acids, preferably hydrochloric acid or carbonic acid, silicic acid is precipitated. 2. Verfahren gemäß Anspruch 1, dadurch gekennzeichnet, daß bei Anwesenheit von bekannten Betonzusatzmitteln gearbeitet wird, die eine plastifizierende und/oder hydrophobierende Wirkung zur Folge haben. In Betracht gezogene Druckschriften: Deutsche Auslegeschrift Nr. 1004134.2. The method according to claim 1, characterized in that in the presence known concrete admixtures are used that have a plasticizing and / or have a hydrophobic effect. Publications considered: German Interpretation document no.1004134.
DEC19533A 1959-08-01 1959-08-01 Process for the production of a fiber-reinforced building material from cement, water, sand and foam-generating and foam-stabilizing substances Pending DE1141932B (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
DEC19533A DE1141932B (en) 1959-08-01 1959-08-01 Process for the production of a fiber-reinforced building material from cement, water, sand and foam-generating and foam-stabilizing substances

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DEC19533A DE1141932B (en) 1959-08-01 1959-08-01 Process for the production of a fiber-reinforced building material from cement, water, sand and foam-generating and foam-stabilizing substances

Publications (1)

Publication Number Publication Date
DE1141932B true DE1141932B (en) 1962-12-27

Family

ID=7016640

Family Applications (1)

Application Number Title Priority Date Filing Date
DEC19533A Pending DE1141932B (en) 1959-08-01 1959-08-01 Process for the production of a fiber-reinforced building material from cement, water, sand and foam-generating and foam-stabilizing substances

Country Status (1)

Country Link
DE (1) DE1141932B (en)

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE1004134B (en) * 1951-02-07 1957-03-14 Traitement Et L Amelioration D Process for treating fibrous materials

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE1004134B (en) * 1951-02-07 1957-03-14 Traitement Et L Amelioration D Process for treating fibrous materials

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