CS214763B2 - Method of making the polymerous materials by water emulsion/suspension polymeration - Google Patents
Method of making the polymerous materials by water emulsion/suspension polymeration Download PDFInfo
- Publication number
- CS214763B2 CS214763B2 CS793796A CS379679A CS214763B2 CS 214763 B2 CS214763 B2 CS 214763B2 CS 793796 A CS793796 A CS 793796A CS 379679 A CS379679 A CS 379679A CS 214763 B2 CS214763 B2 CS 214763B2
- Authority
- CS
- Czechoslovakia
- Prior art keywords
- reactor
- emulsion
- polymerization
- reaction
- suspension
- Prior art date
Links
- 239000000839 emulsion Substances 0.000 title claims abstract description 26
- 239000000463 material Substances 0.000 title claims abstract description 7
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 title claims description 40
- 238000004519 manufacturing process Methods 0.000 title claims description 10
- 239000000725 suspension Substances 0.000 title description 5
- 238000007720 emulsion polymerization reaction Methods 0.000 claims abstract description 34
- 238000000034 method Methods 0.000 claims abstract description 32
- 238000010557 suspension polymerization reaction Methods 0.000 claims abstract description 24
- 239000000376 reactant Substances 0.000 claims abstract description 16
- 238000000265 homogenisation Methods 0.000 claims abstract description 15
- 239000000178 monomer Substances 0.000 claims description 25
- 238000006243 chemical reaction Methods 0.000 abstract description 24
- 238000006116 polymerization reaction Methods 0.000 abstract description 17
- 239000000375 suspending agent Substances 0.000 abstract description 14
- 239000003995 emulsifying agent Substances 0.000 abstract description 12
- 238000010586 diagram Methods 0.000 abstract description 2
- 239000000243 solution Substances 0.000 description 23
- 239000008367 deionised water Substances 0.000 description 22
- 229910021641 deionized water Inorganic materials 0.000 description 22
- 229920000642 polymer Polymers 0.000 description 22
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 21
- 239000004816 latex Substances 0.000 description 21
- 229920000126 latex Polymers 0.000 description 21
- 239000003999 initiator Substances 0.000 description 17
- 229920001577 copolymer Polymers 0.000 description 15
- GLDOVTGHNKAZLK-UHFFFAOYSA-N octadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCCCO GLDOVTGHNKAZLK-UHFFFAOYSA-N 0.000 description 14
- 239000000203 mixture Substances 0.000 description 12
- 239000002245 particle Substances 0.000 description 12
- 239000000047 product Substances 0.000 description 12
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 description 11
- 239000012071 phase Substances 0.000 description 11
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 10
- ROOXNKNUYICQNP-UHFFFAOYSA-N ammonium persulfate Chemical compound [NH4+].[NH4+].[O-]S(=O)(=O)OOS([O-])(=O)=O ROOXNKNUYICQNP-UHFFFAOYSA-N 0.000 description 10
- OZAIFHULBGXAKX-UHFFFAOYSA-N 2-(2-cyanopropan-2-yldiazenyl)-2-methylpropanenitrile Chemical compound N#CC(C)(C)N=NC(C)(C)C#N OZAIFHULBGXAKX-UHFFFAOYSA-N 0.000 description 9
- 229920001971 elastomer Polymers 0.000 description 9
- 239000011541 reaction mixture Substances 0.000 description 8
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 7
- GOQYKNQRPGWPLP-UHFFFAOYSA-N n-heptadecyl alcohol Natural products CCCCCCCCCCCCCCCCCO GOQYKNQRPGWPLP-UHFFFAOYSA-N 0.000 description 7
- UIIMBOGNXHQVGW-UHFFFAOYSA-M Sodium bicarbonate Chemical compound [Na+].OC([O-])=O UIIMBOGNXHQVGW-UHFFFAOYSA-M 0.000 description 6
- DBMJMQXJHONAFJ-UHFFFAOYSA-M Sodium laurylsulphate Chemical compound [Na+].CCCCCCCCCCCCOS([O-])(=O)=O DBMJMQXJHONAFJ-UHFFFAOYSA-M 0.000 description 6
- 229920000036 polyvinylpyrrolidone Polymers 0.000 description 6
- 239000001267 polyvinylpyrrolidone Substances 0.000 description 6
- 235000013855 polyvinylpyrrolidone Nutrition 0.000 description 6
- 235000019333 sodium laurylsulphate Nutrition 0.000 description 6
- 239000003153 chemical reaction reagent Substances 0.000 description 5
- 229910001873 dinitrogen Inorganic materials 0.000 description 5
- 239000000314 lubricant Substances 0.000 description 5
- 229920000609 methyl cellulose Polymers 0.000 description 5
- 239000001923 methylcellulose Substances 0.000 description 5
- 229920005989 resin Polymers 0.000 description 5
- 239000011347 resin Substances 0.000 description 5
- 239000002002 slurry Substances 0.000 description 5
- 238000003756 stirring Methods 0.000 description 5
- MYRTYDVEIRVNKP-UHFFFAOYSA-N 1,2-Divinylbenzene Chemical compound C=CC1=CC=CC=C1C=C MYRTYDVEIRVNKP-UHFFFAOYSA-N 0.000 description 4
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 description 4
- 239000000443 aerosol Substances 0.000 description 4
- 229910001870 ammonium persulfate Inorganic materials 0.000 description 4
- CQEYYJKEWSMYFG-UHFFFAOYSA-N butyl acrylate Chemical compound CCCCOC(=O)C=C CQEYYJKEWSMYFG-UHFFFAOYSA-N 0.000 description 4
- 238000002156 mixing Methods 0.000 description 4
- 239000012429 reaction media Substances 0.000 description 4
- GEHJYWRUCIMESM-UHFFFAOYSA-L sodium sulfite Chemical compound [Na+].[Na+].[O-]S([O-])=O GEHJYWRUCIMESM-UHFFFAOYSA-L 0.000 description 4
- 238000012360 testing method Methods 0.000 description 4
- 229920002554 vinyl polymer Polymers 0.000 description 4
- AZUZXLJWMIQRKG-UHFFFAOYSA-N 2-(8-methylnonyl)-2-sulfobutanedioic acid Chemical compound CC(C)CCCCCCCC(S(O)(=O)=O)(C(O)=O)CC(O)=O AZUZXLJWMIQRKG-UHFFFAOYSA-N 0.000 description 3
- JHWGFJBTMHEZME-UHFFFAOYSA-N 4-prop-2-enoyloxybutyl prop-2-enoate Chemical compound C=CC(=O)OCCCCOC(=O)C=C JHWGFJBTMHEZME-UHFFFAOYSA-N 0.000 description 3
- DWAQJAXMDSEUJJ-UHFFFAOYSA-M Sodium bisulfite Chemical compound [Na+].OS([O-])=O DWAQJAXMDSEUJJ-UHFFFAOYSA-M 0.000 description 3
- BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 description 3
- 239000008346 aqueous phase Substances 0.000 description 3
- 230000015572 biosynthetic process Effects 0.000 description 3
- 238000004132 cross linking Methods 0.000 description 3
- 239000012065 filter cake Substances 0.000 description 3
- 230000009477 glass transition Effects 0.000 description 3
- 229920002285 poly(styrene-co-acrylonitrile) Polymers 0.000 description 3
- SCUZVMOVTVSBLE-UHFFFAOYSA-N prop-2-enenitrile;styrene Chemical compound C=CC#N.C=CC1=CC=CC=C1 SCUZVMOVTVSBLE-UHFFFAOYSA-N 0.000 description 3
- 229910000030 sodium bicarbonate Inorganic materials 0.000 description 3
- 235000017557 sodium bicarbonate Nutrition 0.000 description 3
- 235000010267 sodium hydrogen sulphite Nutrition 0.000 description 3
- 229920000638 styrene acrylonitrile Polymers 0.000 description 3
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 3
- 239000004160 Ammonium persulphate Substances 0.000 description 2
- QXNVGIXVLWOKEQ-UHFFFAOYSA-N Disodium Chemical compound [Na][Na] QXNVGIXVLWOKEQ-UHFFFAOYSA-N 0.000 description 2
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 2
- 239000004141 Sodium laurylsulphate Substances 0.000 description 2
- 235000019395 ammonium persulphate Nutrition 0.000 description 2
- 239000012736 aqueous medium Substances 0.000 description 2
- 239000000872 buffer Substances 0.000 description 2
- 239000012986 chain transfer agent Substances 0.000 description 2
- 239000013530 defoamer Substances 0.000 description 2
- WNAHIZMDSQCWRP-UHFFFAOYSA-N dodecane-1-thiol Chemical compound CCCCCCCCCCCCS WNAHIZMDSQCWRP-UHFFFAOYSA-N 0.000 description 2
- -1 for example Chemical class 0.000 description 2
- 238000002347 injection Methods 0.000 description 2
- 239000007924 injection Substances 0.000 description 2
- 239000002609 medium Substances 0.000 description 2
- SSDSCDGVMJFTEQ-UHFFFAOYSA-N octadecyl 3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoate Chemical compound CCCCCCCCCCCCCCCCCCOC(=O)CCC1=CC(C(C)(C)C)=C(O)C(C(C)(C)C)=C1 SSDSCDGVMJFTEQ-UHFFFAOYSA-N 0.000 description 2
- 230000000704 physical effect Effects 0.000 description 2
- 239000003505 polymerization initiator Substances 0.000 description 2
- USHAGKDGDHPEEY-UHFFFAOYSA-L potassium persulfate Chemical compound [K+].[K+].[O-]S(=O)(=O)OOS([O-])(=O)=O USHAGKDGDHPEEY-UHFFFAOYSA-L 0.000 description 2
- 238000005086 pumping Methods 0.000 description 2
- 238000007873 sieving Methods 0.000 description 2
- 239000011734 sodium Substances 0.000 description 2
- 229910052708 sodium Inorganic materials 0.000 description 2
- 235000010265 sodium sulphite Nutrition 0.000 description 2
- 239000003381 stabilizer Substances 0.000 description 2
- GOXQRTZXKQZDDN-UHFFFAOYSA-N 2-Ethylhexyl acrylate Chemical compound CCCCC(CC)COC(=O)C=C GOXQRTZXKQZDDN-UHFFFAOYSA-N 0.000 description 1
- 239000004322 Butylated hydroxytoluene Substances 0.000 description 1
- NLZUEZXRPGMBCV-UHFFFAOYSA-N Butylhydroxytoluene Chemical compound CC1=CC(C(C)(C)C)=C(O)C(C(C)(C)C)=C1 NLZUEZXRPGMBCV-UHFFFAOYSA-N 0.000 description 1
- QNEORXSPWPAYLI-UHFFFAOYSA-L C(CCCCCCC(C)C)C(C(C(=O)[O-])S(=O)(=O)O)(C(=O)[O-])CCCCCCCC(C)C.[Na+].[Na+] Chemical compound C(CCCCCCC(C)C)C(C(C(=O)[O-])S(=O)(=O)O)(C(=O)[O-])CCCCCCCC(C)C.[Na+].[Na+] QNEORXSPWPAYLI-UHFFFAOYSA-L 0.000 description 1
- XZMCDFZZKTWFGF-UHFFFAOYSA-N Cyanamide Chemical compound NC#N XZMCDFZZKTWFGF-UHFFFAOYSA-N 0.000 description 1
- CERQOIWHTDAKMF-UHFFFAOYSA-M Methacrylate Chemical compound CC(=C)C([O-])=O CERQOIWHTDAKMF-UHFFFAOYSA-M 0.000 description 1
- XBDQKXXYIPTUBI-UHFFFAOYSA-M Propionate Chemical compound CCC([O-])=O XBDQKXXYIPTUBI-UHFFFAOYSA-M 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
- 150000008360 acrylonitriles Chemical class 0.000 description 1
- 150000001336 alkenes Chemical class 0.000 description 1
- 239000007900 aqueous suspension Substances 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 235000010354 butylated hydroxytoluene Nutrition 0.000 description 1
- 229940095259 butylated hydroxytoluene Drugs 0.000 description 1
- 238000005119 centrifugation Methods 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000011109 contamination Methods 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 239000003431 cross linking reagent Substances 0.000 description 1
- 230000008021 deposition Effects 0.000 description 1
- 230000001627 detrimental effect Effects 0.000 description 1
- YVIGPQSYEAOLAD-UHFFFAOYSA-L disodium;dodecyl phosphate Chemical compound [Na+].[Na+].CCCCCCCCCCCCOP([O-])([O-])=O YVIGPQSYEAOLAD-UHFFFAOYSA-L 0.000 description 1
- REKIIORBDNDRPO-UHFFFAOYSA-N dodecane-1-thiol;prop-2-enenitrile Chemical compound C=CC#N.CCCCCCCCCCCCS REKIIORBDNDRPO-UHFFFAOYSA-N 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000004945 emulsification Methods 0.000 description 1
- 230000001804 emulsifying effect Effects 0.000 description 1
- 239000007970 homogeneous dispersion Substances 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 238000001746 injection moulding Methods 0.000 description 1
- 238000007689 inspection Methods 0.000 description 1
- 230000002452 interceptive effect Effects 0.000 description 1
- 125000005395 methacrylic acid group Chemical group 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 238000011020 pilot scale process Methods 0.000 description 1
- 229920002587 poly(1,3-butadiene) polymer Polymers 0.000 description 1
- 229920001485 poly(butyl acrylate) polymer Polymers 0.000 description 1
- 238000012216 screening Methods 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 125000004079 stearyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 239000011145 styrene acrylonitrile resin Substances 0.000 description 1
- 239000006228 supernatant Substances 0.000 description 1
- WCTAGTRAWPDFQO-UHFFFAOYSA-K trisodium;hydrogen carbonate;carbonate Chemical compound [Na+].[Na+].[Na+].OC([O-])=O.[O-]C([O-])=O WCTAGTRAWPDFQO-UHFFFAOYSA-K 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
- C08F2/12—Polymerisation in non-solvents
- C08F2/16—Aqueous medium
- C08F2/22—Emulsion polymerisation
- C08F2/24—Emulsion polymerisation with the aid of emulsifying agents
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F291/00—Macromolecular compounds obtained by polymerising monomers on to macromolecular compounds according to more than one of the groups C08F251/00 - C08F289/00
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Polymerisation Methods In General (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Graft Or Block Polymers (AREA)
- Acyclic And Carbocyclic Compounds In Medicinal Compositions (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US92059978A | 1978-06-29 | 1978-06-29 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CS214763B2 true CS214763B2 (en) | 1982-05-28 |
Family
ID=25444038
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CS793796A CS214763B2 (en) | 1978-06-29 | 1979-06-01 | Method of making the polymerous materials by water emulsion/suspension polymeration |
Country Status (13)
| Country | Link |
|---|---|
| EP (1) | EP0006697B2 (el) |
| JP (1) | JPS557881A (el) |
| CA (1) | CA1144295A (el) |
| CS (1) | CS214763B2 (el) |
| DD (1) | DD144672A5 (el) |
| DE (1) | DE2965273D1 (el) |
| GR (1) | GR73523B (el) |
| IL (1) | IL57233A (el) |
| IN (1) | IN151179B (el) |
| MX (1) | MX5820E (el) |
| NO (1) | NO792169L (el) |
| PT (1) | PT69741A (el) |
| YU (1) | YU148379A (el) |
Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS59189153A (ja) * | 1983-04-11 | 1984-10-26 | Terumo Corp | 樹脂組成物 |
| JPS59189154A (ja) * | 1983-04-11 | 1984-10-26 | Terumo Corp | 樹脂組成物 |
| US7525462B2 (en) | 2006-08-25 | 2009-04-28 | Broadcom Corporation | Gain control for interleaved analog-to-digital conversion for electronic dispersion compensation |
| US7830987B2 (en) | 2006-08-25 | 2010-11-09 | Broadcom Corporation | Electronic dispersion compensation utilizing interleaved architecture and channel identification for assisting timing recovery |
Family Cites Families (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4011283A (en) * | 1970-02-06 | 1977-03-08 | Bp Chemicals Limited | Polymerization process |
| US3887652A (en) * | 1970-11-09 | 1975-06-03 | Dart Ind Inc | Process for producing transparent graft polymer compositions |
| US3832318A (en) * | 1971-09-20 | 1974-08-27 | Stauffer Chemical Co | Suspension emulsion interpolymers |
| US3944631A (en) * | 1974-02-01 | 1976-03-16 | Stauffer Chemical Company | Acrylate-styrene-acrylonitrile composition and method of making the same |
| US4076920A (en) * | 1976-11-02 | 1978-02-28 | The B. F. Goodrich Company | Process for producing homo- or copolymerization of vinyl or vinylidene halides having reduced polymer build-up in the reactor |
| FR2401174A1 (fr) * | 1977-08-26 | 1979-03-23 | Continental Oil Co | Procede pour preparer des polymeres de composes ethyleniques avec preagitation du melange reactionnel |
-
1979
- 1979-05-07 IL IL57233A patent/IL57233A/xx unknown
- 1979-05-09 GR GR59056A patent/GR73523B/el unknown
- 1979-05-10 CA CA000327352A patent/CA1144295A/en not_active Expired
- 1979-05-23 JP JP6377179A patent/JPS557881A/ja active Granted
- 1979-06-01 CS CS793796A patent/CS214763B2/cs unknown
- 1979-06-06 PT PT69741A patent/PT69741A/pt unknown
- 1979-06-06 EP EP79301070A patent/EP0006697B2/en not_active Expired
- 1979-06-06 DE DE7979301070T patent/DE2965273D1/de not_active Expired
- 1979-06-22 YU YU01483/79A patent/YU148379A/xx unknown
- 1979-06-28 DD DD79213968A patent/DD144672A5/de unknown
- 1979-06-28 MX MX798119U patent/MX5820E/es unknown
- 1979-06-28 NO NO792169A patent/NO792169L/no unknown
- 1979-06-29 IN IN669/CAL/79A patent/IN151179B/en unknown
Also Published As
| Publication number | Publication date |
|---|---|
| MX5820E (es) | 1984-07-27 |
| DD144672A5 (de) | 1980-10-29 |
| IL57233A (en) | 1981-12-31 |
| GR73523B (el) | 1984-03-09 |
| EP0006697A3 (en) | 1980-06-11 |
| JPS557881A (en) | 1980-01-21 |
| CA1144295A (en) | 1983-04-05 |
| JPH0146522B2 (el) | 1989-10-09 |
| PT69741A (en) | 1979-07-01 |
| EP0006697A2 (en) | 1980-01-09 |
| EP0006697B2 (en) | 1986-12-03 |
| DE2965273D1 (en) | 1983-06-01 |
| NO792169L (no) | 1980-01-03 |
| YU148379A (en) | 1982-10-31 |
| IL57233A0 (en) | 1979-09-30 |
| EP0006697B1 (en) | 1983-04-27 |
| IN151179B (el) | 1983-03-05 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| JP2971351B2 (ja) | グラフト、転相および架橋を制御したａｂｓグラフトコポリマー製造用多段塊状プロセス | |
| AU594318B2 (en) | Process for making polymer particles, polymer particles and their use | |
| EP0073529B1 (en) | Preparation of sequential polymers and use thereof in coating compositions and as thickening agents | |
| CA1173589A (en) | Making impact-resistant core-shell resins | |
| CN1124743A (zh) | 透明的橡胶改性苯乙烯树脂及其生产方法 | |
| US4277574A (en) | Process for preparing ABS polyblends | |
| JPS63118346A (ja) | 耐衝撃ポリスチレンの連続的製造方法 | |
| US4680335A (en) | Polymer compositions | |
| US4640959A (en) | ABS type resin having disperse particles of a rubber exhibiting a high solution viscosity and a method for its preparation | |
| CN101360767B (zh) | 透明的橡胶改性的苯乙烯树脂以及通过连续的本体聚合制备它的方法 | |
| US4515914A (en) | Crosslinked latexes encapsulated with linear polymers | |
| US4421895A (en) | Process for the manufacture of ABS polymers and use thereof in preparation of molded parts | |
| JP2606895B2 (ja) | ブロック共重合ゴム変性スチレン系共重合体 | |
| US4631307A (en) | Heat-resistant high impact styrene resin, process for production thereof, and resin composition comprising said styrene resin | |
| US3102050A (en) | Method of coating particulated resinous material by polymerization technique | |
| US5306763A (en) | Process for the preparation of rubber-containing graft copolymer particles | |
| CS214763B2 (en) | Method of making the polymerous materials by water emulsion/suspension polymeration | |
| CA1188839A (en) | Production of rubber powder by polymerizing vinyl monomer in presence of broken latex of acrylate rubber | |
| JPH0629301B2 (ja) | 高い溶液粘度を示すゴムの分散粒子をもつａｂｓ型樹脂の製造法 | |
| US5112910A (en) | Mixtures of thermoplastic polymers in powder form | |
| US4525545A (en) | Homogenizer process for forming emulsion/suspension polymers | |
| Vázquez et al. | Reactive blends of thermoplastics and latex particles | |
| US3751526A (en) | Process for producing impact resistant thermoplastic resins | |
| EP0510805A1 (en) | Non-agglomerating suspension polymers | |
| KR830002496B1 (ko) | 유화/현탁중합체의 형성을 위한 균질화방법 |