CN205506741U - AlN thermal insulation bilateral structure low -grade fever board gas sensor - Google Patents
AlN thermal insulation bilateral structure low -grade fever board gas sensor Download PDFInfo
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- 230000002146 bilateral effect Effects 0.000 title claims 6
- 238000009413 insulation Methods 0.000 title 1
- 208000030208 low-grade fever Diseases 0.000 title 1
- 239000000758 substrate Substances 0.000 claims abstract description 28
- 239000000919 ceramic Substances 0.000 claims abstract description 23
- WYTGDNHDOZPMIW-RCBQFDQVSA-N alstonine Natural products C1=CC2=C3C=CC=CC3=NC2=C2N1C[C@H]1[C@H](C)OC=C(C(=O)OC)[C@H]1C2 WYTGDNHDOZPMIW-RCBQFDQVSA-N 0.000 claims abstract description 6
- 238000000034 method Methods 0.000 claims description 18
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- 239000012528 membrane Substances 0.000 claims 2
- 239000007769 metal material Substances 0.000 claims 2
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- 238000007669 thermal treatment Methods 0.000 claims 1
- 238000002955 isolation Methods 0.000 abstract description 13
- 239000004065 semiconductor Substances 0.000 abstract description 7
- 238000010438 heat treatment Methods 0.000 abstract description 6
- 230000035945 sensitivity Effects 0.000 abstract description 4
- 239000007789 gas Substances 0.000 description 18
- 239000000463 material Substances 0.000 description 13
- 238000005516 engineering process Methods 0.000 description 5
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- 238000011161 development Methods 0.000 description 4
- 238000004519 manufacturing process Methods 0.000 description 4
- 238000001514 detection method Methods 0.000 description 3
- 238000010586 diagram Methods 0.000 description 3
- 238000001755 magnetron sputter deposition Methods 0.000 description 3
- 239000002184 metal Substances 0.000 description 3
- 229910044991 metal oxide Inorganic materials 0.000 description 3
- 150000004706 metal oxides Chemical class 0.000 description 3
- 238000000206 photolithography Methods 0.000 description 3
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 2
- 238000013461 design Methods 0.000 description 2
- 229910052710 silicon Inorganic materials 0.000 description 2
- 239000010703 silicon Substances 0.000 description 2
- 229910006404 SnO 2 Inorganic materials 0.000 description 1
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- 238000001179 sorption measurement Methods 0.000 description 1
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Abstract
一种AlN热隔离双面结构微热板气体传感器,包括AlN陶瓷基片、加热器、加热器焊盘、信号电极、信号电极焊盘、焊盘通孔、梯形热隔离槽、敏感膜,基片正面设置有信号电极、信号电极焊盘、加热器焊盘、敏感膜,信号电极采用叉指电极结构,敏感膜附在信号电极上;基片背面设置有加热器、加热器焊盘、信号电极焊盘,加热器采用蛇形排列结构;基片正面与背面的焊盘通过刻蚀的焊盘通孔相连接;基片中心加热区四周刻蚀有梯形热隔离槽,作用是减少传感器的热量损失。传感器整体尺寸约为3.2mm*3.2mm*0.2mm。本实用新型的气体传感器具有体积小、功耗低、灵敏度高等优点,可以作为半导体式Cl2、NO2、CH4等气体传感器。
A micro-hot plate gas sensor with AlN thermal isolation double-sided structure, including AlN ceramic substrate, heater, heater pad, signal electrode, signal electrode pad, pad through hole, trapezoidal thermal isolation groove, sensitive film, substrate The front of the chip is provided with signal electrodes, signal electrode pads, heater pads, and sensitive films. The signal electrodes adopt an interdigital electrode structure, and the sensitive film is attached to the signal electrodes; The electrode pads and the heater adopt a serpentine arrangement structure; the pads on the front and back of the substrate are connected through etched pad through holes; trapezoidal thermal isolation grooves are etched around the central heating area of the substrate to reduce the sensor’s heat loss. The overall size of the sensor is about 3.2mm*3.2mm*0.2mm. The gas sensor of the utility model has the advantages of small size, low power consumption, high sensitivity, etc., and can be used as a semiconductor gas sensor for Cl 2 , NO 2 , CH 4 , etc.
Description
技术领域 technical field
本发明涉及传感器技术领域,特别是涉及一种AlN基底热隔离双面结构的微热板气体传感器。 The invention relates to the technical field of sensors, in particular to a micro-hot plate gas sensor with an AlN base thermally isolated double-sided structure.
背景技术 Background technique
近年来,大气雾霾污染日益严重,各类气体泄漏爆炸等恶性事故频发,给人们的生活带来了极大的不便,因此对气体的检测显得尤为重要。目前,在各类气体检测领域中,半导体式气体传感器被广泛应用,它具有灵敏度高、成本低、重复性好、易于批量生产等优点。半导体气体传感器的工作原理,是金属氧化物敏感材料在一定的温度下,气体分子在传感器表面与材料发生吸附、脱附反应,引起材料电导率的变化,从而实现对气体的探测。但是,为了使半导体气体敏感材料达到最适工作温度,传统的分立式气体传感器往往会消耗较大的功耗,造成系统功耗过大。 In recent years, atmospheric smog pollution has become more and more serious, and vicious accidents such as various gas leakage and explosions have occurred frequently, which has brought great inconvenience to people's lives, so the detection of gases is particularly important. At present, in various gas detection fields, semiconductor gas sensors are widely used, which have the advantages of high sensitivity, low cost, good repeatability, and easy mass production. The working principle of the semiconductor gas sensor is that the metal oxide sensitive material undergoes adsorption and desorption reactions on the surface of the sensor and the material at a certain temperature, causing a change in the conductivity of the material, thereby realizing the detection of the gas. However, in order to make the semiconductor gas sensitive material reach the optimum working temperature, traditional discrete gas sensors often consume large power consumption, resulting in excessive power consumption of the system.
随着MEMS技术的飞速发展,体积小、功耗低的微热板气体传感器越来越受到重视。但是,采用硅衬底制作的微热板传感器,又存在膜基热匹配差,导致温度稳定性差,制作工艺复杂等缺点,这制约了气体传感器的发展。AlN陶瓷材料由于其较高的传热能力,稳定的介电特性和良好膜基结合特性,被大量应用于微电子领域。而随着MEMS技术的不断成熟,非硅基陶瓷等作为微结构传感器的衬底材料,具有广阔的应用发展前景。 With the rapid development of MEMS technology, micro hot plate gas sensors with small size and low power consumption have been paid more and more attention. However, micro-hotplate sensors made of silicon substrates have disadvantages such as poor thermal matching of the film base, resulting in poor temperature stability and complicated manufacturing processes, which restrict the development of gas sensors. AlN ceramic materials are widely used in the field of microelectronics due to their high heat transfer capacity, stable dielectric properties and good film-base bonding properties. With the continuous maturity of MEMS technology, non-silicon-based ceramics, etc., as substrate materials for microstructure sensors, have broad application prospects.
发明内容 Contents of the invention
本发明的目的在于解决现有的气体传感器热量损失过大、工艺复杂等缺点,提出一种AlN热隔离双面结构微热板气体传感器。本发明传感器具有体积小、功耗低、灵敏度高等优点。本发明传感器采用微热板双面结构,将信号电极与加热器分别设计在微热板不同平面上,敏感膜溅射方式镀在信号电极中间位置,焊盘采用上下通孔设计,加热区周围采用热隔离槽结构,有效解决了传感器在使用过程中存在的功耗过高、热量损失过大及连接可靠性等问题。 The purpose of the present invention is to solve the shortcomings of the existing gas sensor such as excessive heat loss and complicated process, and propose an AlN heat-isolated double-sided structure micro-hot plate gas sensor. The sensor of the invention has the advantages of small size, low power consumption, high sensitivity and the like. The sensor of the present invention adopts the double-sided structure of the micro-hot plate, and the signal electrode and the heater are respectively designed on different planes of the micro-hot plate. The sensitive film is sputtered and plated at the middle position of the signal electrode. The heat isolation groove structure is adopted to effectively solve the problems of excessive power consumption, excessive heat loss and connection reliability of the sensor during use.
本发明通过以下技术方案实现。 The present invention is realized through the following technical solutions.
AlN热隔离双面结构微热板气体传感器,包括:AlN陶瓷基片、加热器、加热器焊盘、信号电极、信号电极焊盘、焊盘通孔、梯形热隔离槽、敏感膜,在所述的AlN陶瓷基片的正面设置有信号电极、信号电极焊盘、加热器焊盘,敏感膜,信号电极采用叉指电极结构;所述的AlN陶瓷基片的背面设有加热器、加热器焊盘,信号电极焊盘、加热器为中间带有间隙的蛇形排列结构, AlN陶瓷基片正面的加热器焊盘与背面的加热器焊盘、正面的信号电极焊盘与背面的信号焊盘均采用焊盘通孔结构连接,以提高封装工艺中引线的稳定性。在所述的AlN陶瓷基片中心加热区四周的方位上刻蚀四个梯形热隔离槽,起到降低热传导损耗作用。 AlN thermally isolated double-sided structure micro-hot plate gas sensor, including: AlN ceramic substrate, heater, heater pad, signal electrode, signal electrode pad, pad through hole, trapezoidal thermal isolation groove, sensitive film, in the The front of the AlN ceramic substrate is provided with a signal electrode, a signal electrode pad, a heater pad, a sensitive film, and the signal electrode adopts an interdigital electrode structure; the back of the AlN ceramic substrate is provided with a heater, a heater Pads, signal electrode pads, and heaters are arranged in a serpentine structure with gaps in the middle. The heater pads on the front side of the AlN ceramic substrate and the heater pads on the back side, and the signal electrode pads on the front side and the signal pads on the back side The pads are connected by pad through-hole structure to improve the stability of the leads in the packaging process. Four trapezoidal heat isolation grooves are etched in the directions around the central heating area of the AlN ceramic substrate to reduce heat conduction loss.
所述的加热器与加热器焊盘,采用金属Pt材料。加热器采用蛇形排列结构,加热器焊盘平面采用正方形结构,其厚度与加热器厚度保持一致。主要采用磁控溅射法将Pt材料溅射到AlN陶瓷基片上,然后采用光刻剥离工艺制作出所需要的加热器及焊盘结构。 The heater and the heater pad are made of metal Pt material. The heater adopts a serpentine arrangement structure, and the heater pad plane adopts a square structure, and its thickness is consistent with that of the heater. Mainly use the magnetron sputtering method to sputter the Pt material onto the AlN ceramic substrate, and then use the photolithography stripping process to manufacture the required heater and pad structure.
所述的信号电极与信号电极焊盘采用金属Pt材料。信号电极采用叉指电极结构,信号电极焊盘平面采用正方形结构,其厚度与信号电极厚度一致。同样采用磁控溅射法将Pt材料溅射到AlN陶瓷基片上,然后采用光刻剥离工艺制作出所需要的信号电极以及焊盘结构。 The signal electrodes and the signal electrode pads are made of metal Pt material. The signal electrode adopts an interdigitated electrode structure, and the pad plane of the signal electrode adopts a square structure, and its thickness is consistent with that of the signal electrode. The magnetron sputtering method is also used to sputter the Pt material onto the AlN ceramic substrate, and then the required signal electrode and pad structure is produced by a photolithographic lift-off process.
所述的焊盘通孔为圆柱形,其孔深与上下两片焊盘厚度和AlN陶瓷基片厚度之和一致,制作工艺采用激光微加工工艺刻蚀而成。 The pad through hole is cylindrical, and its hole depth is consistent with the sum of the thickness of the upper and lower pads and the thickness of the AlN ceramic substrate. The manufacturing process is etched by laser micromachining technology.
所述的敏感膜为SnO2、In2O3等金属氧化物半导体材料。 The sensitive film is metal oxide semiconductor material such as SnO 2 , In 2 O 3 .
所述的热隔离槽为梯形结构,槽深与AlN陶瓷基片厚度一致。采用激光微加工工艺刻蚀而成。 The thermal isolation groove has a trapezoidal structure, and the depth of the groove is consistent with the thickness of the AlN ceramic substrate. It is etched by laser micromachining process.
本发明与现有技术相比,具有以下有益的效果。 Compared with the prior art, the present invention has the following beneficial effects.
(1) 本发明采用光刻剥离工艺与激光微加工工艺制备的AlN热隔离双面结构微热板气体传感器,采用蛇形加热器与叉指信号电极结构设计,提高加热效率与传感器的灵敏度。 (1) The AlN thermally isolated double-sided structure micro-hot plate gas sensor prepared by photolithography stripping process and laser micromachining process adopts the structure design of serpentine heater and interdigital signal electrode to improve the heating efficiency and the sensitivity of the sensor.
(2) 本发明采用激光微加工工艺刻蚀热隔离槽,减少热量损失,降低传感器的加热功耗。 (2) The present invention adopts the laser micromachining process to etch the thermal isolation groove to reduce the heat loss and the heating power consumption of the sensor.
(3) 本发明所设计的传感器,具有体积小、功耗低、工艺简单、开发成本低等优点,可以作为半导体式Cl2、NO2、CH4等气体传感器,就有广阔的开发前景。 (3) The sensor designed in the present invention has the advantages of small size, low power consumption, simple process, and low development cost, and can be used as a semiconductor gas sensor for Cl 2 , NO 2 , CH 4 , etc., and has broad development prospects.
(4) 本发明采用带有通孔的焊盘设计,通过焊接方式在焊盘上引出引线,便于采用电子封装技术,将传感器封装成芯片,提高引线封装的稳定性。 (4) The present invention adopts the pad design with through holes, leads the lead wires on the pads by welding, facilitates the use of electronic packaging technology, packages the sensors into chips, and improves the stability of the lead package.
附图说明。Description of drawings.
图1 为本发明的传感器拼装图。 Figure 1 is an assembly diagram of the sensor of the present invention.
图2 为本发明的传感器正面结构示意图。 Fig. 2 is a schematic diagram of the front structure of the sensor of the present invention.
图3 为本发明的传感器背面结构示意图。 Fig. 3 is a schematic diagram of the back structure of the sensor of the present invention.
图4为沿图2所示A-A剖面图。 Fig. 4 is a sectional view along A-A shown in Fig. 2 .
图1中:1为加热器,2为加热器焊盘,3为信号电极焊盘,4为AlN陶瓷基片,5为信号电极,6为焊盘通孔,7为敏感膜,8为梯形热隔离槽。 In Figure 1: 1 is the heater, 2 is the heater pad, 3 is the signal electrode pad, 4 is the AlN ceramic substrate, 5 is the signal electrode, 6 is the through hole of the pad, 7 is the sensitive film, and 8 is the trapezoid Thermal isolation slot.
具体实施方式。detailed description.
下面结合附图对本发明的实施例作详细说明:本实施例在以本发明技术方案为前提下进行实施,给出了详细的实施方式和具体的操作过程,但本发明的保护范围不限于下述的实施例。 The embodiments of the present invention are described in detail below in conjunction with the accompanying drawings: this embodiment is implemented on the premise of the technical solution of the present invention, and detailed implementation methods and specific operating procedures are provided, but the protection scope of the present invention is not limited to the following the described embodiment.
如图1~4所示,本实施例包括加热器1,加热器焊盘2,信号电极焊盘3,AlN陶瓷衬底4,信号电极5,焊盘通孔6,敏感膜7,梯形热隔离槽8;加热器焊盘2由焊盘2-1、焊盘2-2、焊盘2-3、焊盘2-4组成,信号电极焊盘3由焊盘3-1、焊盘3-2、焊盘3-3、焊盘3-4组成,信号电极5由电极5-1、电极5-2两部分组成,焊盘通孔6由通孔6-1、通孔6-2、通孔6-3、通孔6-4、通孔6-5、通孔6-6、通孔6-7、通孔6-8、通孔6-9、通孔6-10、通孔6-11、通孔6-12组成,梯形热隔离槽8由梯形槽8-1、梯形槽8-2、梯形槽8-3、梯形槽8-4组成,焊盘2-1与焊盘2-3由通孔6-1、通孔6-5、通孔6-9相连接,焊盘2-2与焊盘2-4由通孔6-3、通孔6-7、通孔6-11相连接,焊盘3-2与焊盘3-4由通孔6-4、通孔6-8、通孔6-12相连接,焊盘3-1与焊盘3-3由通孔6-2、通孔6-6、通孔6-10相连接,信号电极5位于AlN陶瓷衬底4上,信号电极5与信号电极焊盘3相连接,敏感膜7位于信号电极5上;加热器1位于AlN陶瓷基底4下,加热器1与加热器焊盘2相连接。 As shown in Figures 1 to 4, this embodiment includes a heater 1, a heater pad 2, a signal electrode pad 3, an AlN ceramic substrate 4, a signal electrode 5, a pad through hole 6, a sensitive film 7, and a trapezoidal thermal pad. Isolation groove 8; heater pad 2 is composed of pad 2-1, pad 2-2, pad 2-3, and pad 2-4; signal electrode pad 3 is composed of pad 3-1, pad 3 -2. Composed of pad 3-3 and pad 3-4, signal electrode 5 is composed of electrode 5-1 and electrode 5-2, pad through hole 6 is composed of through hole 6-1 and through hole 6-2 , through hole 6-3, through hole 6-4, through hole 6-5, through hole 6-6, through hole 6-7, through hole 6-8, through hole 6-9, through hole 6-10, through hole Hole 6-11, through hole 6-12, trapezoidal thermal isolation groove 8 is composed of trapezoidal groove 8-1, trapezoidal groove 8-2, trapezoidal groove 8-3, trapezoidal groove 8-4, pad 2-1 and welding The plate 2-3 is connected by the through hole 6-1, the through hole 6-5, and the through hole 6-9, and the pad 2-2 and the pad 2-4 are connected by the through hole 6-3, the through hole 6-7, and the through hole 6-7. The holes 6-11 are connected, the pad 3-2 is connected with the pad 3-4 by the through hole 6-4, the through hole 6-8, and the through hole 6-12, and the pad 3-1 is connected with the pad 3-3 Connected by the through hole 6-2, the through hole 6-6, and the through hole 6-10, the signal electrode 5 is located on the AlN ceramic substrate 4, the signal electrode 5 is connected to the signal electrode pad 3, and the sensitive film 7 is located on the signal electrode 5; the heater 1 is located under the AlN ceramic substrate 4, and the heater 1 is connected to the heater pad 2.
本实施例中,气体传感器工作时,在加热器1与加热器焊盘2中通入直流电压,由于加热器1与加热器焊盘2采用的金属Pt材料有一定的电阻值,在直流电压的作用下,加热器1会产生热量,经过AlN陶瓷基底4的热传导作用,这一热量会传递到信号电极5与敏感膜7中,这样,金属氧化物半导体气敏材料就会获得200-400℃的工作温度。 In this embodiment, when the gas sensor is working, a DC voltage is applied to the heater 1 and the heater pad 2. Since the metal Pt material used in the heater 1 and the heater pad 2 has a certain resistance value, the DC voltage Under the action of the heater 1, heat will be generated, and through the heat conduction of the AlN ceramic substrate 4, this heat will be transferred to the signal electrode 5 and the sensitive film 7, so that the metal oxide semiconductor gas sensitive material will obtain 200-400 °C working temperature.
本实施例中,所述的传感器外形为正方形,其边长为3.2mm,衬底4厚度为0.2mm,衬底材料AlN陶瓷基片4的尺寸为3.2mm*3.2mm*0.2mm。 In this embodiment, the shape of the sensor is a square with a side length of 3.2 mm, a thickness of the substrate 4 of 0.2 mm, and a size of the substrate material AlN ceramic substrate 4 of 3.2 mm*3.2 mm*0.2 mm.
本实施例中,所述的焊盘平面为正方形,尺寸为0.5mm*0.5mm*500nm。 In this embodiment, the pad plane is a square with a size of 0.5mm*0.5mm*500nm.
本实施例中,所述的加热器1的线条宽度为0.1mm,间距为0.05mm,厚度为0.5um;中心加热区面积为1mm*1mm。 In this embodiment, the line width of the heater 1 is 0.1mm, the spacing is 0.05mm, and the thickness is 0.5um; the area of the central heating zone is 1mm*1mm.
本实施例中,所述的信号电极5的线条宽度最大为0.1mm,最小为0.05mm,线条厚度为500nm;电极5-1与电极5-2的间距最大为0.1mm,最小为0.05mm。 In this embodiment, the line width of the signal electrode 5 is at most 0.1mm, at least 0.05mm, and the line thickness is 500nm; the distance between the electrode 5-1 and the electrode 5-2 is at most 0.1mm, at least 0.05mm.
本实施例中,所述的梯形热隔离槽8的梯形通孔,上底尺寸0.8mm、下底尺寸1.7mm、高0.45mm的等腰梯形,其厚度为0.2mm。 In this embodiment, the trapezoidal through hole of the trapezoidal thermal isolation groove 8 is an isosceles trapezoid with an upper bottom size of 0.8 mm, a lower bottom size of 1.7 mm, and a height of 0.45 mm, and its thickness is 0.2 mm.
本实施例中,所述的焊接通孔6为圆柱体,其底面半径为0.1mm,高为201um。 In this embodiment, the welding through hole 6 is a cylinder with a bottom radius of 0.1mm and a height of 201um.
本实施例采用 MEMS工艺技术制备,采用磁控溅射工艺与光刻剥离工艺制备信号电极与加热电极、焊盘;采用激光微加工工艺刻蚀焊盘通孔与梯形热隔离槽,解决了传感器引线封装稳定性差、热量损失过大的问题。 This embodiment adopts MEMS process technology to prepare, adopts magnetron sputtering process and photolithography stripping process to prepare signal electrode, heating electrode and pad; adopts laser micromachining process to etch pad through hole and trapezoidal thermal isolation groove, solves the problem of sensor The lead package has poor stability and excessive heat loss.
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