CN204596884U - Acid-base resonance battery device with damping function - Google Patents
Acid-base resonance battery device with damping function Download PDFInfo
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- CN204596884U CN204596884U CN201520184334.9U CN201520184334U CN204596884U CN 204596884 U CN204596884 U CN 204596884U CN 201520184334 U CN201520184334 U CN 201520184334U CN 204596884 U CN204596884 U CN 204596884U
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- 238000013016 damping Methods 0.000 title claims abstract description 42
- 230000002378 acidificating effect Effects 0.000 claims abstract description 115
- 230000000694 effects Effects 0.000 claims abstract description 12
- 239000002253 acid Substances 0.000 claims description 8
- GELKBWJHTRAYNV-UHFFFAOYSA-K lithium iron phosphate Chemical compound [Li+].[Fe+2].[O-]P([O-])([O-])=O GELKBWJHTRAYNV-UHFFFAOYSA-K 0.000 claims description 6
- QELJHCBNGDEXLD-UHFFFAOYSA-N nickel zinc Chemical compound [Ni].[Zn] QELJHCBNGDEXLD-UHFFFAOYSA-N 0.000 claims description 5
- 208000014617 hemorrhoid Diseases 0.000 abstract 1
- 238000007599 discharging Methods 0.000 description 11
- 230000010355 oscillation Effects 0.000 description 6
- 238000010586 diagram Methods 0.000 description 5
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 3
- 230000009286 beneficial effect Effects 0.000 description 3
- 239000003792 electrolyte Substances 0.000 description 3
- 238000000034 method Methods 0.000 description 3
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
- 238000004146 energy storage Methods 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 230000002159 abnormal effect Effects 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- OJIJEKBXJYRIBZ-UHFFFAOYSA-N cadmium nickel Chemical compound [Ni].[Cd] OJIJEKBXJYRIBZ-UHFFFAOYSA-N 0.000 description 1
- 230000005611 electricity Effects 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- WJZHMLNIAZSFDO-UHFFFAOYSA-N manganese zinc Chemical compound [Mn].[Zn] WJZHMLNIAZSFDO-UHFFFAOYSA-N 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 238000006479 redox reaction Methods 0.000 description 1
- 230000001172 regenerating effect Effects 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
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- Y02E60/10—Energy storage using batteries
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P70/00—Climate change mitigation technologies in the production process for final industrial or consumer products
- Y02P70/50—Manufacturing or production processes characterised by the final manufactured product
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Abstract
Description
技术领域 technical field
本实用新型涉及一种将酸性二次电堆组与碱性电堆组以电性并联连接的方式组成的具有阻尼功能的酸碱共振二次电池装置。 The utility model relates to an acid-base resonance secondary battery device with a damping function, which is composed of an acidic secondary electric stack group and an alkaline electric stack group in the form of electrical parallel connection.
背景技术 Background technique
电堆(cell)是构成电池的基本单元。二次电堆依照电解液种类的不同可分为酸性电池与碱性电池。所述酸性电池的电解液可以是硫酸水溶液,例如铅酸电池。所述铅酸电池的体积大、重量重、有污染问题、氧化还原反应慢,已被一种磷酸锂铁电池所取代。所述酸性二次电堆储存电流型态的电能,当放电到电流为零(I=0)时,电池就会损坏。 A cell is the basic unit of a battery. Secondary stacks can be divided into acidic batteries and alkaline batteries according to the type of electrolyte. The electrolyte of the acid battery can be an aqueous sulfuric acid solution, such as a lead-acid battery. The lead-acid battery has a large volume, heavy weight, pollution problems, and slow redox reaction, and has been replaced by a lithium iron phosphate battery. The acidic secondary battery stores electric energy in the form of current, and when the current is discharged to zero (I=0), the battery will be damaged.
所述碱性二次电堆的电解液是以氢氧化钾水溶液为主,例如:碱性锌锰电池、镉镍电池、氢镍电池。所述碱性二次电堆储存电压型态的电能,当放电到电压为零(V=0,一般电压放电到1.0V以下,电池就失效,无法再放电)时,电池就会损坏。碱性二次电堆必须用相当小的电流充电,往往需要超过24小时的时间才能充满,而且可再充电的次数不多,使用不便。所述碱性二次电堆在充电、放电的过程中容易发生升温现象。 The electrolyte of the alkaline secondary stack is mainly potassium hydroxide aqueous solution, for example: alkaline zinc-manganese batteries, cadmium-nickel batteries, and nickel-hydrogen batteries. The alkaline secondary stack stores electric energy in a voltage form, and when the voltage is discharged to zero (V=0, generally the voltage is discharged below 1.0V, the battery will fail and cannot be discharged again), the battery will be damaged. The alkaline secondary battery must be charged with a relatively small current, and it often takes more than 24 hours to be fully charged, and the rechargeable times are not many, which is inconvenient to use. The alkaline secondary stack is prone to temperature rise during charging and discharging.
使用二次电堆为电源的电器设备中都设置有电池管理系统(Battery Management System,简称BMS),用于对电池进行管理。电池管理系统(BMS)通常具有测量电池电压的功能,防止或避免电池过放电、过充电、温度过高等异常状况出现。某一电气设备中的电源为多个并联的二次电堆,且在该电池管理系统(BMS)侦测出只有其中一个二次电堆的电压不足时,整个电池装置就会停止供电。对消费者而言,无法理解为何电池明明储存 有电能,却无法放电,而且有可能会造成负载端宕机。此种负载端机具的宕机有时会造成危险,例如会造成行驶中的电动车忽然失去电力。 The electrical equipment that uses the secondary stack as the power supply is equipped with a battery management system (Battery Management System, referred to as BMS) to manage the battery. A battery management system (BMS) usually has the function of measuring battery voltage to prevent or avoid abnormal conditions such as battery over-discharge, over-charge, and over-temperature. The power supply in an electrical device is a plurality of secondary stacks connected in parallel, and when the battery management system (BMS) detects that only one of the secondary stacks is insufficient in voltage, the entire battery device will stop supplying power. For consumers, it is impossible to understand why the battery can store electric energy, but it cannot be discharged, and it may cause the load end to go down. The downtime of such load-side equipment sometimes causes danger, for example, it may cause a running electric vehicle to suddenly lose power.
实用新型内容 Utility model content
本实用新型的主要目的在于提供一种具有阻尼功能的酸碱共振电池装置,其可由多个相同的电池电堆(cell)串/并联组成,其中每一个电池电堆内部具有自体共振的阻尼效应,以达到快充、快放的目的。 The main purpose of the utility model is to provide an acid-base resonance battery device with a damping function, which can be composed of a plurality of identical battery stacks (cells) connected in series/parallel, wherein each battery stack has a damping effect of self-resonance inside , in order to achieve the purpose of fast charging and fast discharging.
本实用新型的再一目的在于提供一种具有阻尼功能的酸碱共振电池装置,其具有内部电位自动平衡的作用,从而无须使用电池管理系统(BMS)。 Another object of the present invention is to provide an acid-base resonance battery device with a damping function, which has the function of internal potential automatic balance, thereby eliminating the need for a battery management system (BMS).
本实用新型提供一种具有阻尼功能的酸碱共振电池装置由多个相同的电池电堆(cell)串/并联组成。每一电池电堆包含有一酸性二次电堆组和一碱性二次电堆组。通过该酸性二次电堆组与该碱性二次电堆组之间的共振作用自动达到电位平衡,利于充电与放电。 The utility model provides an acid-base resonance battery device with a damping function, which is composed of a plurality of identical battery stacks (cells) connected in series/parallel. Each battery stack includes an acidic secondary stack group and an alkaline secondary stack group. The potential balance is automatically achieved through the resonance between the acidic secondary stack group and the alkaline secondary stack group, which is beneficial to charging and discharging.
所述该酸性二次电堆组包含至少一个酸性二次电堆。所述碱性二次电堆组包含至少一个碱性二次电堆,各碱性二次电堆之间为串联连接。该酸性二次电堆组与该一碱性二次电堆组之间为并联连接。该酸性二次电堆组的电位接近或等于该碱性二次电堆组的电位,且该酸性二次电堆组的容量接近或等于该碱性二次电堆组的容量,从而能够令该酸性二次电堆组与该碱性二次电堆组之间产生共振的阻尼作用。 The acidic secondary stack group includes at least one acidic secondary stack. The alkaline secondary stack group includes at least one alkaline secondary stack, and each alkaline secondary stack is connected in series. The acidic secondary stack group is connected in parallel with the alkaline secondary stack group. The potential of the acidic secondary stack group is close to or equal to the potential of the alkaline secondary stack group, and the capacity of the acidic secondary stack group is close to or equal to the capacity of the alkaline secondary stack group, so that the A resonance damping effect is generated between the acidic secondary stack group and the alkaline secondary stack group.
在本实用新型的一实施例中,所述酸性二次电堆可以是磷酸锂铁酸性二次电池。 In an embodiment of the present utility model, the acidic secondary battery stack may be a lithium iron phosphate acidic secondary battery.
在本实用新型的一实施例中,所述碱性二次电堆可以是锌镍碱性二次电池。 In an embodiment of the present invention, the alkaline secondary battery stack may be a zinc-nickel alkaline secondary battery.
所述酸性二次电堆组中的各酸性二次电堆可以通过并联连接的方式来提高容量。所述碱性二次电堆组的各碱性二次电堆可以通过串联连接的方式来提高容量。 Each acidic secondary stack in the acidic secondary stack group can be connected in parallel to increase capacity. Each alkaline secondary stack of the alkaline secondary stack group can be connected in series to increase capacity.
在本实用新型的一实施例中,该酸性二次电堆组由一个电位为3.3~3.4V的酸性二次电堆组成;该碱性二次电堆组由两个电位为1.6~1.8V的碱性二次电堆组成;该酸性二次电堆的容量为该碱性二次电堆的容量的90~110%。 In one embodiment of the present invention, the acidic secondary stack group consists of an acidic secondary stack with a potential of 3.3-3.4V; the alkaline secondary stack group consists of two potentials with a potential of 1.6-1.8V The composition of the alkaline secondary stack; the capacity of the acidic secondary stack is 90% to 110% of the capacity of the alkaline secondary stack.
在本实用新型的一实施例中,该酸性二次电堆组由两个电位为3.2~3.6V的酸性二次电堆并联连接组成;该碱性二次电堆组由两个电位为1.6~1.8V的碱性二次电堆组成;该酸性二次电堆的容量为该碱性二次电堆的容量的45~55%。 In one embodiment of the present utility model, the acidic secondary stack group is composed of two acidic secondary stacks with a potential of 3.2 to 3.6V connected in parallel; the alkaline secondary stack group is composed of two potentials with a potential of 1.6V ~1.8V alkaline secondary electric stack; the capacity of the acidic secondary electric stack is 45-55% of the capacity of the alkaline secondary electric stack.
本实用新型还提供了另一种具有阻尼功能的酸碱共振电池装置,其包含一酸性二次电堆组和一碱性二次电堆组;该酸性二次电堆组包含至少一个酸性二次电堆;该碱性二次电堆组包含至少一个碱性二次电堆,各碱性二次电堆之间为串联连接;该酸性二次电堆组与该一碱性二次电堆组之间为并联连接;该酸性二次电堆组的电位为该碱性二次电堆组的电位的90~110%;该酸性二次电堆组的容量为该碱性二次电堆组的容量的90~110%;则该酸性二次电堆组与该碱性二次电堆组之间因电位平衡关系产生共振的阻尼作用。 The utility model also provides another acid-base resonance battery device with a damping function, which includes an acidic secondary stack group and an alkaline secondary stack group; the acidic secondary stack group includes at least one acidic secondary stack The secondary stack; the alkaline secondary stack group includes at least one alkaline secondary stack, and each alkaline secondary stack is connected in series; the acidic secondary stack group and the alkaline secondary stack The stack groups are connected in parallel; the potential of the acidic secondary stack group is 90% to 110% of the potential of the alkaline secondary stack group; the capacity of the acidic secondary stack group is the 90% to 110% of the capacity of the stack group; the acidic secondary stack group and the alkaline secondary stack group have a resonance damping effect due to the potential balance relationship.
在本实用新型的一实施例中,该酸性二次电堆为磷酸锂铁酸性二次电堆电池。 In one embodiment of the present invention, the acidic secondary stack is a lithium iron phosphate acidic secondary stack battery.
在本实用新型的一实施例中,该碱性二次电堆为锌镍碱性二次电堆电池。 In one embodiment of the present invention, the alkaline secondary stack is a zinc-nickel alkaline secondary stack battery.
在本实用新型的一实施例中,该酸性二次电堆组由一个电位为3.2~3.6V的酸性二次电堆组成;该碱性二次电堆组由两个电位为1.6~1.8V的碱性二次电堆组成;该酸性二次电堆的容量为该碱性二次电堆的容量90~110%。 In one embodiment of the present invention, the acidic secondary stack group consists of an acidic secondary stack with a potential of 3.2-3.6V; the alkaline secondary stack group consists of two potentials with a potential of 1.6-1.8V The composition of the basic secondary electric pile; the capacity of the acidic secondary electric pile is 90-110% of the capacity of the alkaline secondary electric pile.
在本实用新型的一实施例中,该酸性二次电堆组由两个电位为 3.2~3.6V的酸性二次电堆并联连接组成;该碱性二次电堆组由两个电位为1.6~1.8V的碱性二次电堆组成;该酸性二次电堆的容量为该碱性二次电堆的容量的45~55%。 In one embodiment of the present invention, the acidic secondary stack group is composed of two acidic secondary stacks with a potential of 3.2 to 3.6V connected in parallel; the alkaline secondary stack group is composed of two potentials with a potential of 1.6V ~1.8V alkaline secondary electric stack; the capacity of the acidic secondary electric stack is 45-55% of the capacity of the alkaline secondary electric stack.
本实用新型提供的具有阻尼功能的酸碱共振电池装置通过酸性二次电堆组与碱性二次电堆组之间的共振阻尼效应实现了以下有益效果: The acid-base resonance battery device with damping function provided by the utility model realizes the following beneficial effects through the resonance damping effect between the acidic secondary stack group and the alkaline secondary stack group:
1.可令该酸性二次电堆组与碱性二次电堆组之间自动达到电位平衡,无须设置电池管理系统(BMS)。 1. The potential balance between the acidic secondary stack group and the alkaline secondary stack group can be automatically achieved without setting up a battery management system (BMS).
2.该酸性二次电堆组与碱性二次电堆组之间的内阻低,不会发生温度升高的情形,稳定性高。 2. The internal resistance between the acidic secondary stack group and the alkaline secondary stack group is low, no temperature rise occurs, and the stability is high.
3.可通过多组电池电堆的串/并联组成的电池装置10来提升储能电压与放电电流,更能构成多组充、放电路径,以提升充、放电速度。 3. The battery device 10 composed of multiple sets of battery stacks in series/parallel can be used to increase the energy storage voltage and discharge current, and can also form multiple sets of charging and discharging paths to increase the charging and discharging speed.
附图说明 Description of drawings
图1为本实用新型实施例的结构图; Fig. 1 is the structural diagram of the utility model embodiment;
图2为图1所示实施例中电池电堆的结构图; Fig. 2 is a structural diagram of the battery cell stack in the embodiment shown in Fig. 1;
图3为阻尼充电装置对图1所示实施例进行充电的电路方块图; Fig. 3 is a circuit block diagram of charging the embodiment shown in Fig. 1 by the damping charging device;
图4为本实用新型第二实施例的结构图; Fig. 4 is the structural diagram of the second embodiment of the utility model;
图5为图4所示实施例中电池电堆的结构图。 FIG. 5 is a structural diagram of the battery cell stack in the embodiment shown in FIG. 4 .
附图标记说明:10-电池装置;11-电池电堆;12-酸性二次电堆组;121-酸性二次电堆;122-酸性二次电堆;13-碱性二次电堆组;131-碱性二次电堆;132-碱性二次电堆;20-充电装置;21-电源输出装置;22-控制电路;23-阻尼电感;24-高频振荡开关;30-电能产生装置;40-负载。 Description of reference signs: 10-battery device; 11-battery stack; 12-acidic secondary stack; 121-acidic secondary stack; 122-acidic secondary stack; 13-alkaline secondary stack ;131-alkaline secondary stack; 132-alkaline secondary stack; 20-charging device; 21-power output device; 22-control circuit; 23-damping inductance; 24-high frequency oscillation switch; 30-electric energy generating means; 40-load.
具体实施方式 detailed description
如图1、图2所示。本实用新型提供的具有阻尼功能的酸碱共振电池装置10由多个相同的电池电堆11(cell)串/并联组成。每一电池电堆11包含 一酸性二次电堆组12和一碱性二次电堆组13。该酸性二次电堆组12与该碱性二次电堆组13之间为电性并联连接。 As shown in Figure 1 and Figure 2. The acid-base resonance battery device 10 with damping function provided by the utility model is composed of a plurality of identical battery stacks 11 (cells) connected in series/parallel. Each cell stack 11 includes an acidic secondary stack group 12 and an alkaline secondary stack group 13. The acidic secondary stack group 12 and the alkaline secondary stack group 13 are electrically connected in parallel.
所述酸性二次电堆组12包含至少一个酸性二次电堆121。所述碱性二次电堆组13包含至少一个碱性二次电堆131,各碱性二次电堆131之间为串联连接。该酸性二次电堆组12与该一碱性二次电堆组13之间为电性并联连接。该酸性二次电堆组12的电位接近或等于该碱性二次电堆组13的电位。其接近程度以该酸性二次电堆组12的电位为该碱性二次电堆组13的电位的90~110%为较佳。当该酸性二次电堆组12的电位等于该碱性二次电堆组13的电位时,可达到最好的实施效果。就一般市售酸性二次电堆121的电位约为3.3~3.4V,碱性二次电堆131的电位约为1.8V,目前尚无法组合成酸性二次电堆组12的电位等于碱性二次电堆组13的电位的电池装置10。 The acidic secondary stack group 12 includes at least one acidic secondary stack 121 . The alkaline secondary stack group 13 includes at least one alkaline secondary stack 131 , and each alkaline secondary stack 131 is connected in series. The acidic secondary stack group 12 and the alkaline secondary stack group 13 are electrically connected in parallel. The potential of the acidic secondary stack group 12 is close to or equal to the potential of the alkaline secondary stack group 13 . The closeness is preferably when the potential of the acidic secondary stack group 12 is 90-110% of the potential of the alkaline secondary stack group 13 . When the potential of the acidic secondary stack group 12 is equal to the potential of the alkaline secondary stack group 13, the best implementation effect can be achieved. Generally, the potential of the acidic secondary stack 121 on the market is about 3.3-3.4V, and the potential of the alkaline secondary stack 131 is about 1.8V. At present, it is not possible to combine the potential of the acidic secondary stack group 12 to be equal to that of the alkaline The battery device 10 of the potential of the secondary stack group 13 .
所述该酸性二次电堆121与该碱性二次电堆131的材料不同,进而造成二者的能阶不同。其中,该酸性二次电堆组12利于储存电流型态的电能,该碱性二次电堆组13利于储存电压型态的电能。 The materials of the acidic secondary stack 121 and the alkaline secondary stack 131 are different, which results in different energy levels of the two. Wherein, the acidic secondary stack group 12 is good for storing electric energy in current type, and the alkaline secondary stack group 13 is good for storing electric energy in voltage type.
该酸性二次电堆组12的容量接近或等于该二碱性二次电堆组13的容量。其接近程度以该酸性二次电堆组的容量为该碱性二次电堆组的容量的90~110%为较佳。当该酸性二次电堆组12的容量等于该二碱性二次电堆组13的容量时,可达到最好的实施效果。但电池121、131的实际容量是指电池121、131所容纳的功(W)。功(W)=电压(V)×电流(I)×时间(T),所以不易令该酸性二次电堆组12的实际功容量等于该二碱性二次电堆组13的实际功容量。 The capacity of the acidic secondary stack group 12 is close to or equal to the capacity of the dibasic secondary stack group 13 . The close degree is preferably when the capacity of the acidic secondary stack is 90-110% of the capacity of the alkaline secondary stack. When the capacity of the acidic secondary stack group 12 is equal to the capacity of the dibasic secondary stack group 13, the best implementation effect can be achieved. However, the actual capacity of the batteries 121 and 131 refers to the work (W) contained in the batteries 121 and 131 . Work (W)=voltage (V)×current (I)×time (T), so it is not easy to make the actual work capacity of the acidic secondary stack group 12 equal to the actual work capacity of the two alkaline secondary stack group 13 .
因为该酸性二次电堆12与该碱性二次电堆13的能阶不同,以及该酸性二次电堆组12与该碱性二次电堆组13之间必须达到电位完全相等的平衡关系,令该电池电堆11在充电、放电过程中,该酸性二次电堆组12与碱性二次电堆组13之间所造成的瞬间电压失衡(有较大的电压差别),则瞬间电 位偏高的该碱性二次电堆组13自动将电能传输到电位相对偏低的该酸性二次电堆组12内;或者,令瞬间电位偏高的该酸性二次电堆组12自动将电能传输到电位相对偏低的该碱性二次电堆组13内,使该酸性二次电堆组12与该碱性二次电堆组13之间的电位趋向相等的完全平衡状态。这种会自动做自体内部共振的现象即称为阻尼效应(Damping effect)。即使在该电池电堆11未做充电、放电时,其内部也会出现自体共振的阻尼效应,使该酸性二次电堆组12与该碱性二次电堆组13之间的电位趋向等于或接近相等的平衡状态。 Because the energy levels of the acidic secondary stack 12 and the alkaline secondary stack 13 are different, and the balance between the acidic secondary stack group 12 and the alkaline secondary stack group 13 must reach a completely equal potential relationship, so that the battery stack 11 is in the process of charging and discharging, the instantaneous voltage imbalance (there is a large voltage difference) caused between the acidic secondary stack group 12 and the alkaline secondary stack group 13, then The alkaline secondary stack group 13 with a relatively high instantaneous potential automatically transmits electric energy to the acidic secondary stack group 12 with a relatively low potential; or, the acidic secondary stack group with a relatively high instantaneous potential 12 Automatically transmit electric energy to the alkaline secondary stack group 13 with a relatively low potential, so that the potentials between the acidic secondary stack group 12 and the alkaline secondary stack group 13 tend to be equal to a complete balance state. This phenomenon of automatic self-internal resonance is called the damping effect. Even when the battery cell stack 11 is not being charged or discharged, there will be a damping effect of self-resonance inside it, so that the potential between the acidic secondary cell stack 12 and the alkaline secondary cell stack 13 tends to be equal to or a nearly equal equilibrium state.
图1、图2所示的实施例中,该酸性二次电堆组12由一个电位为3.3~3.4V的酸性二次电堆121构成。该碱性二次电堆组13由两个电位为1.6~1.8V的碱性二次电堆131串联组成。该酸性二次电堆121的电位为3.3~3.4V,接近于该二碱性二次电堆131的总电位3.2~3.6V。则该酸性二次电堆组12的电位在该碱性二次电堆组13的电位的90~110%的范围内。该酸性二次电堆121的容量为20Ah。该碱性二次电堆131的容量为20Ah。则该酸性二次电堆组12的容量在该碱性二次电堆组13的容量的90~110%的范围内。则该酸性二次电堆组12的实际功容量也就能够接近于该二碱性二次电堆组13的实际功容量。 In the embodiment shown in FIG. 1 and FIG. 2 , the acidic secondary stack group 12 is composed of an acidic secondary stack 121 with a potential of 3.3-3.4V. The alkaline secondary stack group 13 is composed of two alkaline secondary stacks 131 connected in series with a potential of 1.6-1.8V. The potential of the acidic secondary stack 121 is 3.3-3.4V, which is close to the total potential of the di-alkaline secondary stack 131 of 3.2-3.6V. Then the potential of the acidic secondary stack group 12 is in the range of 90-110% of the potential of the alkaline secondary stack group 13 . The acidic secondary stack 121 has a capacity of 20Ah. The alkaline secondary stack 131 has a capacity of 20Ah. Then the capacity of the acidic secondary stack group 12 is in the range of 90-110% of the capacity of the alkaline secondary stack group 13 . Then the actual work capacity of the acidic secondary stack group 12 can be close to the actual work capacity of the di-alkaline secondary stack group 13 .
前述的酸性二次电堆121可以是磷酸锂铁酸性二次电池。所述的碱性二次电堆131可以是锌镍碱性二次电池。 The aforementioned acidic secondary battery stack 121 may be a lithium iron phosphate acidic secondary battery. The alkaline secondary battery stack 131 may be a zinc-nickel alkaline secondary battery.
前述具有阻尼功能的酸碱共振电池装置必须使用具有阻尼功能的充电装置来充电,例如已授权的新型第M484854号“阻尼充电装置”。如图3所示。所述充电装置20包含一电源输出装置21、一控制电路22、一阻尼电感23及一高频振荡开关24。该电源输出装置21能够与一电能产生装置30连接,其主要将电能产生装置30输出的电能做升压或降压后输出电源。该酸碱共振电池装置的正极端与该阻尼电感23连接,负极端与该高频振荡开关 24连接。该电能产生装置30可以是再生能产生装置,也可以是家用电源。该充电装置20通过该高频振荡开关24使该阻尼电感23进行高频率的储电和放电。该高频振荡开关24在ON的状态下,该阻尼电感23会储存电能。该高频振荡开关24在OFF的状态下,该阻尼电感23会将所储存的电能释放出来对该酸碱共振电池装置充电。因此该充电装置20可放出的电能是具有频率响应的电能,对电池装置10充电。该电池装置10可放电供负载40作功。 The aforementioned acid-base resonance battery device with damping function must be charged with a charging device with damping function, such as the authorized new No. M484854 "damping charging device". As shown in Figure 3. The charging device 20 includes a power output device 21 , a control circuit 22 , a damping inductor 23 and a high frequency oscillation switch 24 . The power output device 21 can be connected with an electric energy generating device 30 , which mainly boosts or reduces the voltage output by the electric energy generating device 30 to output power. The positive end of the acid-base resonance battery device is connected to the damping inductance 23, and the negative end is connected to the high-frequency oscillation switch 24. The electric energy generating device 30 may be a regenerative energy generating device, or a household power supply. The charging device 20 enables the damping inductor 23 to store and discharge electricity at a high frequency through the high frequency oscillation switch 24 . When the high frequency oscillation switch 24 is ON, the damping inductor 23 will store electric energy. When the high-frequency oscillation switch 24 is in the OFF state, the damping inductor 23 will release the stored electric energy to charge the acid-base resonance battery device. Therefore, the electric energy that can be released by the charging device 20 is electric energy with a frequency response to charge the battery device 10 . The battery device 10 can be discharged to provide work for the load 40 .
该酸性二次电堆组12与与碱性二次电堆组13之间以瞬间快速的共振型态来达到电压平衡,是一种阻尼效应。由于该电池装置10中的每一电池电堆11在充电、放电过程中会产生自体共振,从而不会造成升温现象,并能够提高电池装置10的使用寿命。由于该酸性二次电堆组12与该碱性二次电堆组13之间的电位会自动趋向等于或接近相等的平衡状态,所以无须使用电池管理系统(BMS),则电器内无需装设电池管理系统(BMS)电路板可降低电器的生产成本,以及降低机体的重量。 The voltage balance between the acidic secondary stack group 12 and the alkaline secondary stack group 13 is achieved in an instantaneous and rapid resonance mode, which is a damping effect. Since each battery stack 11 in the battery device 10 will generate self-resonance during charging and discharging, it will not cause temperature rise, and the service life of the battery device 10 can be improved. Since the potential between the acidic secondary stack group 12 and the alkaline secondary stack group 13 will automatically tend to be equal to or close to the equal equilibrium state, so there is no need to use a battery management system (BMS), and there is no need to install The battery management system (BMS) circuit board can reduce the production cost of electrical appliances and reduce the weight of the body.
因为该电池装置10的每一电池电堆11都具有自体共振的阻尼特性,则构成电池装置的电池电堆11数量愈多,其充电与放电的路径就愈多,就能使充电与放电的速度加快。 Because each battery stack 11 of the battery device 10 has the damping characteristic of self-resonance, the more battery stacks 11 that constitute the battery device, the more paths for charging and discharging, and the charging and discharging process can be made more efficient. Speed up.
图4、图5所示为本实用新型的另一实施例。该电池装置10中的每一电池电堆11的酸性二次电堆组12由两个电位为3.2~3.6V的酸性二次电堆122并联连接组成。该碱性二次电堆组13由两个电位为1.6~1.8V的碱性二次电堆132组成。该酸性二次电堆组12的电位在该碱性二次电堆组13的电位的90~110%的范围内。该酸性二次电堆122的容量为1250mAh,是该碱性电池132的容量2500mAh的二分之一,亦即,该酸性二次电堆122的容量在该碱性电池132的容量45~55%的范围内。该酸性二次电堆组12的容量为1250mAh×2=2500mAh,在该碱性二次电堆组13的电容的90~110%的范围内。故可将两个酸性二次电堆122并联连接,以提高该酸性二次电堆组12 的容量,以接近于该碱性二次电堆组13的容量。 Shown in Fig. 4, Fig. 5 is another embodiment of the present utility model. The acidic secondary stack group 12 of each battery stack 11 in the battery device 10 is composed of two acidic secondary stacks 122 connected in parallel with a potential of 3.2-3.6V. The alkaline secondary stack group 13 is composed of two alkaline secondary stacks 132 with a potential of 1.6-1.8V. The potential of the acidic secondary stack group 12 is within the range of 90-110% of the potential of the alkaline secondary stack group 13 . The capacity of the acidic secondary stack 122 is 1250mAh, which is 1/2 of the capacity of the alkaline battery 132, 2500mAh. %In the range. The capacity of the acidic secondary stack group 12 is 1250mAh×2=2500mAh, which is within the range of 90-110% of the capacity of the alkaline secondary stack group 13 . Therefore, two acidic secondary stacks 122 can be connected in parallel to increase the capacity of the acidic secondary stack group 12 to be close to the capacity of the alkaline secondary stack group 13.
综上所陈,本实用新型提供的具有阻尼功能的酸碱共振电池装置通过酸性二次电堆组与碱性二次电堆组之间的共振阻尼效应实现了以下有益效果: In summary, the acid-base resonance battery device with damping function provided by the utility model realizes the following beneficial effects through the resonance damping effect between the acidic secondary stack group and the alkaline secondary stack group:
1.可令该酸性二次电堆组与碱性二次电堆组之间自动达到电位平衡,无须设置电池管理系统(BMS)。 1. The potential balance between the acidic secondary stack group and the alkaline secondary stack group can be automatically achieved without setting up a battery management system (BMS).
2.该酸性二次电堆组与碱性二次电堆组之间的内阻低,不会发生温度升高的情形,稳定性高。 2. The internal resistance between the acidic secondary stack group and the alkaline secondary stack group is low, no temperature rise occurs, and the stability is high.
3.可通过多组电池电堆的串/并联组成的电池装置10来提升储能电压与放电电流,更能构成多组充、放电路径,以提升充、放电速度。 3. The battery device 10 composed of multiple sets of battery stacks in series/parallel can be used to increase the energy storage voltage and discharge current, and can also form multiple sets of charging and discharging paths to increase the charging and discharging speed.
以上所述为利用较佳实施例详细说明本实用新型,而非限制本实用新型的范围。大凡熟知此类技艺人士皆能明了,适当而作些微的改变及调整,仍将不失本实用新型的要义所在,亦不脱离本实用新型的精神和范围。 The above description is to use the preferred embodiments to describe the utility model in detail, but not to limit the scope of the utility model. Generally, those who are familiar with this type of art can understand that it is appropriate to make slight changes and adjustments without losing the gist of the present utility model, nor departing from the spirit and scope of the present utility model.
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