CN1865422A - Detergent for washing dishware with hand and its preparation method - Google Patents
Detergent for washing dishware with hand and its preparation method Download PDFInfo
- Publication number
- CN1865422A CN1865422A CN 200610012549 CN200610012549A CN1865422A CN 1865422 A CN1865422 A CN 1865422A CN 200610012549 CN200610012549 CN 200610012549 CN 200610012549 A CN200610012549 A CN 200610012549A CN 1865422 A CN1865422 A CN 1865422A
- Authority
- CN
- China
- Prior art keywords
- dishwashing detergent
- surfactant
- hand dishwashing
- alkyl
- hand
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000003599 detergent Substances 0.000 title claims abstract description 37
- 238000002360 preparation method Methods 0.000 title claims abstract description 19
- 238000005406 washing Methods 0.000 title claims description 14
- 239000002736 nonionic surfactant Substances 0.000 claims abstract description 37
- 239000003945 anionic surfactant Substances 0.000 claims abstract description 33
- 238000004851 dishwashing Methods 0.000 claims abstract description 32
- 239000003792 electrolyte Substances 0.000 claims abstract description 22
- 238000003756 stirring Methods 0.000 claims abstract description 14
- 239000002888 zwitterionic surfactant Substances 0.000 claims abstract description 13
- 239000007788 liquid Substances 0.000 claims abstract description 12
- 235000013599 spices Nutrition 0.000 claims abstract description 12
- 239000000203 mixture Substances 0.000 claims description 44
- 239000002904 solvent Substances 0.000 claims description 27
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 25
- 125000000217 alkyl group Chemical group 0.000 claims description 22
- 239000008367 deionised water Substances 0.000 claims description 22
- 229910021641 deionized water Inorganic materials 0.000 claims description 22
- -1 2-hydroxypropyl Chemical group 0.000 claims description 20
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 claims description 18
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 claims description 15
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 claims description 14
- 239000002280 amphoteric surfactant Substances 0.000 claims description 12
- 150000002430 hydrocarbons Chemical group 0.000 claims description 10
- 235000002639 sodium chloride Nutrition 0.000 claims description 10
- 239000011780 sodium chloride Substances 0.000 claims description 9
- 125000004432 carbon atom Chemical group C* 0.000 claims description 8
- 239000004519 grease Substances 0.000 claims description 8
- 239000003240 coconut oil Substances 0.000 claims description 7
- 235000019864 coconut oil Nutrition 0.000 claims description 7
- 229940051841 polyoxyethylene ether Drugs 0.000 claims description 7
- 229920000056 polyoxyethylene ether Polymers 0.000 claims description 7
- 239000003549 soybean oil Substances 0.000 claims description 7
- 235000012424 soybean oil Nutrition 0.000 claims description 7
- WCUXLLCKKVVCTQ-UHFFFAOYSA-M Potassium chloride Chemical compound [Cl-].[K+] WCUXLLCKKVVCTQ-UHFFFAOYSA-M 0.000 claims description 6
- 150000001412 amines Chemical class 0.000 claims description 6
- 238000001816 cooling Methods 0.000 claims description 6
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical group [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 claims description 5
- KWIUHFFTVRNATP-UHFFFAOYSA-N Betaine Natural products C[N+](C)(C)CC([O-])=O KWIUHFFTVRNATP-UHFFFAOYSA-N 0.000 claims description 5
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 claims description 5
- 150000001875 compounds Chemical group 0.000 claims description 4
- 239000003205 fragrance Substances 0.000 claims description 4
- 125000002768 hydroxyalkyl group Chemical group 0.000 claims description 4
- 229910052938 sodium sulfate Inorganic materials 0.000 claims description 4
- 235000011152 sodium sulphate Nutrition 0.000 claims description 4
- 235000019484 Rapeseed oil Nutrition 0.000 claims description 3
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 claims description 3
- 229960003237 betaine Drugs 0.000 claims description 3
- 239000004202 carbamide Substances 0.000 claims description 3
- 150000007942 carboxylates Chemical class 0.000 claims description 3
- 125000001301 ethoxy group Chemical group [H]C([H])([H])C([H])([H])O* 0.000 claims description 3
- 235000013305 food Nutrition 0.000 claims description 3
- 239000001103 potassium chloride Substances 0.000 claims description 3
- 235000011164 potassium chloride Nutrition 0.000 claims description 3
- 239000001509 sodium citrate Substances 0.000 claims description 3
- NLJMYIDDQXHKNR-UHFFFAOYSA-K sodium citrate Chemical compound O.O.[Na+].[Na+].[Na+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O NLJMYIDDQXHKNR-UHFFFAOYSA-K 0.000 claims description 3
- 125000000954 2-hydroxyethyl group Chemical group [H]C([*])([H])C([H])([H])O[H] 0.000 claims description 2
- QOXOZONBQWIKDA-UHFFFAOYSA-N 3-hydroxypropyl Chemical group [CH2]CCO QOXOZONBQWIKDA-UHFFFAOYSA-N 0.000 claims description 2
- BVKZGUZCCUSVTD-UHFFFAOYSA-M Bicarbonate Chemical compound OC([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-M 0.000 claims description 2
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims description 2
- 239000005977 Ethylene Substances 0.000 claims description 2
- WQZGKKKJIJFFOK-GASJEMHNSA-N Glucose Natural products OC[C@H]1OC(O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-GASJEMHNSA-N 0.000 claims description 2
- VMHLLURERBWHNL-UHFFFAOYSA-M Sodium acetate Chemical compound [Na+].CC([O-])=O VMHLLURERBWHNL-UHFFFAOYSA-M 0.000 claims description 2
- 125000001931 aliphatic group Chemical group 0.000 claims description 2
- 229910000288 alkali metal carbonate Inorganic materials 0.000 claims description 2
- 150000008041 alkali metal carbonates Chemical class 0.000 claims description 2
- 125000003545 alkoxy group Chemical group 0.000 claims description 2
- 150000008055 alkyl aryl sulfonates Chemical class 0.000 claims description 2
- 150000008051 alkyl sulfates Chemical class 0.000 claims description 2
- 125000002947 alkylene group Chemical group 0.000 claims description 2
- 229910052799 carbon Inorganic materials 0.000 claims description 2
- 239000000969 carrier Substances 0.000 claims description 2
- 150000001768 cations Chemical class 0.000 claims description 2
- 150000002009 diols Chemical class 0.000 claims description 2
- 150000002170 ethers Chemical class 0.000 claims description 2
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 claims description 2
- 239000008103 glucose Substances 0.000 claims description 2
- 125000002791 glucosyl group Chemical group C1([C@H](O)[C@@H](O)[C@H](O)[C@H](O1)CO)* 0.000 claims description 2
- 125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 claims description 2
- 229910021645 metal ion Chemical group 0.000 claims description 2
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 2
- 125000000325 methylidene group Chemical group [H]C([H])=* 0.000 claims description 2
- 150000007522 mineralic acids Chemical class 0.000 claims description 2
- 238000002156 mixing Methods 0.000 claims description 2
- 150000007524 organic acids Chemical class 0.000 claims description 2
- 238000006116 polymerization reaction Methods 0.000 claims description 2
- 229920005862 polyol Polymers 0.000 claims description 2
- 150000003077 polyols Chemical class 0.000 claims description 2
- OTYBMLCTZGSZBG-UHFFFAOYSA-L potassium sulfate Chemical compound [K+].[K+].[O-]S([O-])(=O)=O OTYBMLCTZGSZBG-UHFFFAOYSA-L 0.000 claims description 2
- 229910052939 potassium sulfate Inorganic materials 0.000 claims description 2
- 235000011151 potassium sulphates Nutrition 0.000 claims description 2
- 125000002572 propoxy group Chemical group [*]OC([H])([H])C(C([H])([H])[H])([H])[H] 0.000 claims description 2
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 claims description 2
- 229920006395 saturated elastomer Polymers 0.000 claims description 2
- 239000001632 sodium acetate Substances 0.000 claims description 2
- 235000017281 sodium acetate Nutrition 0.000 claims description 2
- 235000011083 sodium citrates Nutrition 0.000 claims description 2
- QULKDBMYSOOKMH-UHFFFAOYSA-N sulfo hydrogen carbonate Chemical compound OC(=O)OS(O)(=O)=O QULKDBMYSOOKMH-UHFFFAOYSA-N 0.000 claims description 2
- 239000000126 substance Substances 0.000 claims 2
- KWIUHFFTVRNATP-UHFFFAOYSA-O N,N,N-trimethylglycinium Chemical group C[N+](C)(C)CC(O)=O KWIUHFFTVRNATP-UHFFFAOYSA-O 0.000 claims 1
- 150000004945 aromatic hydrocarbons Chemical class 0.000 claims 1
- 239000003002 pH adjusting agent Substances 0.000 claims 1
- 125000001273 sulfonato group Chemical group [O-]S(*)(=O)=O 0.000 claims 1
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 32
- 239000011734 sodium Substances 0.000 description 28
- 229910052708 sodium Inorganic materials 0.000 description 27
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 26
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 19
- 235000005979 Citrus limon Nutrition 0.000 description 13
- 244000131522 Citrus pyriformis Species 0.000 description 13
- 230000000052 comparative effect Effects 0.000 description 10
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 9
- 150000004996 alkyl benzenes Chemical class 0.000 description 9
- 229940048848 lauryl glucoside Drugs 0.000 description 9
- 125000000129 anionic group Chemical group 0.000 description 8
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 7
- 230000000694 effects Effects 0.000 description 7
- 229910052700 potassium Inorganic materials 0.000 description 7
- 239000011591 potassium Substances 0.000 description 7
- 239000004094 surface-active agent Substances 0.000 description 7
- 239000006260 foam Substances 0.000 description 6
- 238000005187 foaming Methods 0.000 description 6
- PYIDGJJWBIBVIA-UYTYNIKBSA-N lauryl glucoside Chemical compound CCCCCCCCCCCCO[C@@H]1O[C@H](CO)[C@@H](O)[C@H](O)[C@H]1O PYIDGJJWBIBVIA-UYTYNIKBSA-N 0.000 description 6
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 5
- 238000005238 degreasing Methods 0.000 description 5
- 230000007794 irritation Effects 0.000 description 5
- 239000003921 oil Substances 0.000 description 5
- 235000019198 oils Nutrition 0.000 description 5
- 125000003438 dodecyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 4
- SYELZBGXAIXKHU-UHFFFAOYSA-N dodecyldimethylamine N-oxide Chemical group CCCCCCCCCCCC[N+](C)(C)[O-] SYELZBGXAIXKHU-UHFFFAOYSA-N 0.000 description 4
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 3
- 125000000913 palmityl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 3
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 2
- FKNQFGJONOIPTF-UHFFFAOYSA-N Sodium cation Chemical compound [Na+] FKNQFGJONOIPTF-UHFFFAOYSA-N 0.000 description 2
- 239000013543 active substance Substances 0.000 description 2
- 150000001335 aliphatic alkanes Chemical class 0.000 description 2
- 229940047662 ammonium xylenesulfonate Drugs 0.000 description 2
- 239000007864 aqueous solution Substances 0.000 description 2
- 125000002029 aromatic hydrocarbon group Chemical group 0.000 description 2
- IHRIVUSMZMVANI-UHFFFAOYSA-N azane;2-methylbenzenesulfonic acid Chemical compound [NH4+].CC1=CC=CC=C1S([O-])(=O)=O IHRIVUSMZMVANI-UHFFFAOYSA-N 0.000 description 2
- 239000003925 fat Substances 0.000 description 2
- 235000019197 fats Nutrition 0.000 description 2
- 238000009472 formulation Methods 0.000 description 2
- 239000008233 hard water Substances 0.000 description 2
- HESSGHHCXGBPAJ-UHFFFAOYSA-N n-[3,5,6-trihydroxy-1-oxo-4-[3,4,5-trihydroxy-6-(hydroxymethyl)oxan-2-yl]oxyhexan-2-yl]acetamide Chemical compound CC(=O)NC(C=O)C(O)C(C(O)CO)OC1OC(CO)C(O)C(O)C1O HESSGHHCXGBPAJ-UHFFFAOYSA-N 0.000 description 2
- DVEKCXOJTLDBFE-UHFFFAOYSA-N n-dodecyl-n,n-dimethylglycinate Chemical compound CCCCCCCCCCCC[N+](C)(C)CC([O-])=O DVEKCXOJTLDBFE-UHFFFAOYSA-N 0.000 description 2
- 231100000252 nontoxic Toxicity 0.000 description 2
- 230000003000 nontoxic effect Effects 0.000 description 2
- 239000010865 sewage Substances 0.000 description 2
- 229910001415 sodium ion Inorganic materials 0.000 description 2
- QUCDWLYKDRVKMI-UHFFFAOYSA-M sodium;3,4-dimethylbenzenesulfonate Chemical compound [Na+].CC1=CC=C(S([O-])(=O)=O)C=C1C QUCDWLYKDRVKMI-UHFFFAOYSA-M 0.000 description 2
- 238000005063 solubilization Methods 0.000 description 2
- 230000007928 solubilization Effects 0.000 description 2
- 239000000243 solution Substances 0.000 description 2
- 239000002562 thickening agent Substances 0.000 description 2
- HVYJSOSGTDINLW-UHFFFAOYSA-N 2-[dimethyl(octadecyl)azaniumyl]acetate Chemical compound CCCCCCCCCCCCCCCCCC[N+](C)(C)CC([O-])=O HVYJSOSGTDINLW-UHFFFAOYSA-N 0.000 description 1
- SDGNNLQZAPXALR-UHFFFAOYSA-N 3-sulfophthalic acid Chemical class OC(=O)C1=CC=CC(S(O)(=O)=O)=C1C(O)=O SDGNNLQZAPXALR-UHFFFAOYSA-N 0.000 description 1
- LSNNMFCWUKXFEE-UHFFFAOYSA-M Bisulfite Chemical compound OS([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-M 0.000 description 1
- FEWJPZIEWOKRBE-JCYAYHJZSA-N Dextrotartaric acid Chemical compound OC(=O)[C@H](O)[C@@H](O)C(O)=O FEWJPZIEWOKRBE-JCYAYHJZSA-N 0.000 description 1
- AOMUHOFOVNGZAN-UHFFFAOYSA-N N,N-bis(2-hydroxyethyl)dodecanamide Chemical compound CCCCCCCCCCCC(=O)N(CCO)CCO AOMUHOFOVNGZAN-UHFFFAOYSA-N 0.000 description 1
- QZXSMBBFBXPQHI-UHFFFAOYSA-N N-(dodecanoyl)ethanolamine Chemical compound CCCCCCCCCCCC(=O)NCCO QZXSMBBFBXPQHI-UHFFFAOYSA-N 0.000 description 1
- 235000019482 Palm oil Nutrition 0.000 description 1
- NPYPAHLBTDXSSS-UHFFFAOYSA-N Potassium ion Chemical compound [K+] NPYPAHLBTDXSSS-UHFFFAOYSA-N 0.000 description 1
- XBDQKXXYIPTUBI-UHFFFAOYSA-N Propionic acid Chemical class CCC(O)=O XBDQKXXYIPTUBI-UHFFFAOYSA-N 0.000 description 1
- 208000003251 Pruritus Diseases 0.000 description 1
- FEWJPZIEWOKRBE-UHFFFAOYSA-N Tartaric acid Natural products [H+].[H+].[O-]C(=O)C(O)C(O)C([O-])=O FEWJPZIEWOKRBE-UHFFFAOYSA-N 0.000 description 1
- 150000001242 acetic acid derivatives Chemical class 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 235000011037 adipic acid Nutrition 0.000 description 1
- 150000001279 adipic acids Chemical class 0.000 description 1
- 229910052783 alkali metal Inorganic materials 0.000 description 1
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 1
- 150000003863 ammonium salts Chemical class 0.000 description 1
- 239000012752 auxiliary agent Substances 0.000 description 1
- ICZCGYVEJDDKLM-UHFFFAOYSA-N azane;naphthalene-2-sulfonic acid Chemical compound [NH4+].C1=CC=CC2=CC(S(=O)(=O)[O-])=CC=C21 ICZCGYVEJDDKLM-UHFFFAOYSA-N 0.000 description 1
- 229940077388 benzenesulfonate Drugs 0.000 description 1
- 238000006065 biodegradation reaction Methods 0.000 description 1
- 125000002091 cationic group Chemical group 0.000 description 1
- 150000001860 citric acid derivatives Chemical class 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- MRUAUOIMASANKQ-UHFFFAOYSA-N cocamidopropyl betaine Chemical compound CCCCCCCCCCCC(=O)NCCC[N+](C)(C)CC([O-])=O MRUAUOIMASANKQ-UHFFFAOYSA-N 0.000 description 1
- 229940073507 cocamidopropyl betaine Drugs 0.000 description 1
- 238000013329 compounding Methods 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 125000000118 dimethyl group Chemical group [H]C([H])([H])* 0.000 description 1
- 230000001804 emulsifying effect Effects 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 150000002169 ethanolamines Chemical class 0.000 description 1
- 238000007046 ethoxylation reaction Methods 0.000 description 1
- 150000002191 fatty alcohols Chemical class 0.000 description 1
- 239000000796 flavoring agent Substances 0.000 description 1
- 235000019634 flavors Nutrition 0.000 description 1
- 239000000499 gel Substances 0.000 description 1
- 229930182478 glucoside Natural products 0.000 description 1
- 150000002311 glutaric acids Chemical class 0.000 description 1
- 239000003752 hydrotrope Substances 0.000 description 1
- 230000002401 inhibitory effect Effects 0.000 description 1
- 230000007803 itching Effects 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 125000001421 myristyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 231100000344 non-irritating Toxicity 0.000 description 1
- 235000014593 oils and fats Nutrition 0.000 description 1
- 239000002540 palm oil Substances 0.000 description 1
- XAEFZNCEHLXOMS-UHFFFAOYSA-M potassium benzoate Chemical compound [K+].[O-]C(=O)C1=CC=CC=C1 XAEFZNCEHLXOMS-UHFFFAOYSA-M 0.000 description 1
- 229910001414 potassium ion Inorganic materials 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 230000001953 sensory effect Effects 0.000 description 1
- 238000002791 soaking Methods 0.000 description 1
- 150000003385 sodium Chemical class 0.000 description 1
- 229940048842 sodium xylenesulfonate Drugs 0.000 description 1
- KVCGISUBCHHTDD-UHFFFAOYSA-M sodium;4-methylbenzenesulfonate Chemical compound [Na+].CC1=CC=C(S([O-])(=O)=O)C=C1 KVCGISUBCHHTDD-UHFFFAOYSA-M 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 150000003890 succinate salts Chemical class 0.000 description 1
- 150000003444 succinic acids Chemical class 0.000 description 1
- 150000003871 sulfonates Chemical class 0.000 description 1
- 230000002459 sustained effect Effects 0.000 description 1
- 239000003760 tallow Substances 0.000 description 1
- 239000011975 tartaric acid Substances 0.000 description 1
- 235000002906 tartaric acid Nutrition 0.000 description 1
- 230000008719 thickening Effects 0.000 description 1
Landscapes
- Detergent Compositions (AREA)
Abstract
一种手洗餐具洗涤剂重量百分比组成是：阴离子表面活性剂1～20％，非离子表面活性剂1～20％，两性离子表面活性剂0～4％，液体载体60～85％，电解质0～5％，香料0.05～0.1％。制备方法是将阴离子表面活性剂、非离子表面活性剂、两性离子表面活性剂、液体载体在搅拌下，于40～50℃下混匀后、在同一温度、搅拌下加入电解质混合均匀，冷却至30℃后加入香料混匀，制得产品。本发明具有对皮肤无伤害、温和、去油污能力强的优点。A hand dishwashing detergent is composed by weight percentage: 1-20% of anionic surfactant, 1-20% of non-ionic surfactant, 0-4% of zwitterionic surfactant, 60-85% of liquid carrier, and 0-20% of electrolyte 5%, spices 0.05 ~ 0.1%. The preparation method is to mix anionic surfactant, nonionic surfactant, zwitterionic surfactant, and liquid carrier at 40-50°C under stirring, then add electrolyte at the same temperature and mix evenly under stirring, and cool to After 30°C, add spices and mix well to obtain the product. The invention has the advantages of no harm to the skin, mildness and strong oil removal ability.
Description
技术领域technical field
本发明涉及一种适用于手洗餐具洗涤剂及制备方法。The invention relates to a detergent suitable for hand-washing tableware and a preparation method.
发明背景Background of the invention
手洗餐具洗涤剂在本领域是公知的，可以是粉状、凝胶状或块状等形式，但最一般的形式是液体。此类产品最主要的功能是有优异的去除餐具表面油污的性能，这种性能通常由表面活性剂提供，该表面活性剂提供一定的增溶作用，并将食物污垢，尤其是油脂污垢从被清洗餐具上或在此类产品形成的水溶液中清除掉，其次手洗餐具洗涤剂还应该具有对皮肤的低刺激性或无刺激性，由于可能在餐具表面的极少量残留，这种手洗餐具洗涤剂还应是无毒产品，此外，这种产品由于是要排放到生活污水体系中的，因此其组分都应是可以快速生物降解的。这种手洗餐具洗涤剂还要具有令消费者可接受的外观和操作时令消费者满意的感官操作效果，因此手洗餐具洗涤剂应具有一定的黏度和起泡性。合适的黏度可以避免一次使用量过大，合适的起泡性要求在最初的洗涤水中产生适量的泡沫以及泡沫形式可以在整个洗餐具过程中持续。随着社会经济的发展，人们已经认识到泡沫并不一定是餐具洗涤剂有效性的指示，也不一定是餐具洗涤剂使用量是否充足的指示，因此过于丰富的泡沫从环境保护的角度来说是不被消费者期望的，一方面是节水的要求，另一方面增加了生活污水的处理要求。Hand dishwashing detergents are well known in the art and may be in the form of powders, gels or bars, etc., but are most commonly in liquid form. The main function of this type of product is to have excellent performance in removing oil stains on the surface of tableware, which is usually provided by surfactants, which provide a certain solubilization effect and remove food stains, especially grease stains, from being removed Clean the tableware or remove it in the aqueous solution formed by such products. Secondly, the hand-washing dishwashing detergent should also have low or no irritation to the skin. It should also be a non-toxic product. In addition, since this product is to be discharged into the domestic sewage system, its components should be rapidly biodegradable. The hand-washing dishwashing detergent also needs to have an acceptable appearance for consumers and a sensory operation effect satisfying consumers during operation, so the hand-washing dishwashing detergent should have a certain viscosity and foaming property. Appropriate viscosity can avoid excessive use at one time. Appropriate foaming performance requires the generation of appropriate foam in the initial wash water and the foam form can be sustained throughout the dishwashing process. With the development of society and economy, people have realized that foam is not necessarily an indicator of the effectiveness of dishwashing detergent, nor is it necessarily an indication of whether the amount of dishwashing detergent used is sufficient. Therefore, too rich foam is from the perspective of environmental protection. It is not expected by consumers. On the one hand, it is the requirement of water saving, and on the other hand, it increases the treatment requirements of domestic sewage.
一般而言，没有一种表面活性剂具有上述手洗餐具洗涤剂所要求的所有性能，因此需要选择几种不同的表面活性剂加以复配，另外，还加入一些增稠剂，增溶剂和其它辅助物。Generally speaking, none of the surfactants has all the properties required by the above-mentioned hand dishwashing detergents, so several different surfactants need to be selected for compounding. In addition, some thickeners, solubilizers and other auxiliary agents are added. things.
目前市售的手洗餐具洗涤剂主要以阴离子表面活性剂为主，它们可以提供较好的去油污作用以及较高的发泡力，但是阴离子表面活性剂也存在刺激性较高的问题，尤其是对皮肤的脱脂力较强。高浓度下或较长时间浸泡于其中，会造成皮肤发红、发痒、粗糙等现象。Currently commercially available hand dishwashing detergents are mainly anionic surfactants, which can provide better degreasing effect and higher foaming power, but anionic surfactants also have the problem of high irritation, especially Strong degreasing power on the skin. High concentration or soaking in it for a long time will cause skin redness, itching, roughness and so on.
发明内容Contents of the invention
本发明的目的是提供一种对皮肤无伤害、温和的、去油污能力强的手洗餐具洗涤剂及制备方法。The object of the present invention is to provide a hand-washing tableware detergent which is harmless to the skin, mild and has strong degreasing ability and its preparation method.
本发明的手洗餐具洗涤剂重量百分比组成包括：Hand dishwashing detergent weight percentage composition of the present invention comprises:
(a)阴离子表面活性剂1～20％(a) Anionic surfactant 1～20%
(b)非离子表面活性剂1～20％(b) 1-20% non-ionic surfactant
(c)两性离子表面活性剂0～4％(c) Zwitterionic surfactant 0~4%
(d)液体载体60～85％(d) Liquid carrier 60-85%
(e)电解质0～5％(e) Electrolyte 0~5%
(f)香料0.05～0.1％(f) Fragrance 0.05～0.1%
如上所述的阴离子表面活性剂是含磺酸盐型阴离子表面活性剂和/或硫酸盐阴离子表面活性剂。The anionic surfactants as described above are sulfonate-containing anionic surfactants and/or sulfate anionic surfactants.
如上所述的磺酸盐型阴离子表面活性剂是水溶性的，有如下形式：RSO3M，其中R为C6～20直链或支链烃基、芳烃基或其混合物，优选含有C10～ 18的烷基、芳烃基、羟烷基或其混合物；M为阳离子，如碱金属阳离子、铵或取代铵，优选钠离子或钾离子。这类表面活性剂是C6～20烷基苯磺酸钠、C6～20烷基苯磺酸钾、C6～20烷基苯磺酸铵、C6～20烷基苯磺酸乙醇胺盐等，C8～18链烷基磺酸盐，C10～24 α-烯基磺酸盐。较为理想的磺酸盐型阴离子表面活性剂是C12链烷基苯磺酸钠盐或钾盐。The above-mentioned sulfonate-type anionic surfactant is water-soluble and has the following form: RSO 3 M, wherein R is a C 6-20 straight chain or branched hydrocarbon group, an aromatic hydrocarbon group or a mixture thereof, preferably containing C 10- 18 is an alkyl group, an aromatic hydrocarbon group, a hydroxyalkyl group or a mixture thereof; M is a cation, such as an alkali metal cation, ammonium or substituted ammonium, preferably a sodium ion or a potassium ion. Such surfactants are sodium C 6~20 alkylbenzene sulfonate, potassium C 6~20 alkylbenzene sulfonate, ammonium C 6~20 alkylbenzene sulfonate, ethanolamine salt of C 6~20 alkylbenzene sulfonate etc., C 8~18 alkane sulfonate, C 10~24 α-alkenyl sulfonate. The more ideal sulfonate type anionic surfactant is C 12 sodium or potassium salt of alkane benzene sulfonate.
如上所述的硫酸盐阴离子表面活性剂包括水溶性的烷基硫酸盐或烷基聚氧乙烯醚硫酸盐阴离子表面活性剂，有如下形式：R-0(A)nSO- 3M+，其中R为未取代的直链或支链C6～20的烷基或羟烷基基团，优选C12～20的烷基或羟烷基，更优选C12～15或者C12～14的烷基；A为乙氧基或丙氧基单元，优选乙氧基单元；n为0.5～5，优选0.5～3；M为铵离子或一金属离子，更优选是钠离子。烷基醚硫酸盐一般以包含不同链长的R和不同乙氧基化度的混合物形式存在，理想的硫酸盐型表面活性剂是C12～14聚氧乙烯(3)醚硫酸钠，C12～15聚氧乙烯(2)醚硫酸钠。Sulfate anionic surfactants as mentioned above include water-soluble alkyl sulfate or alkyl polyoxyethylene ether sulfate anionic surfactants, which have the following form: R-0(A) n SO - 3 M + , wherein R is an unsubstituted linear or branched C 6-20 alkyl or hydroxyalkyl group, preferably a C 12-20 alkyl or hydroxyalkyl group, more preferably a C 12-15 or C 12-14 alkane A group; A is an ethoxy or propoxy unit, preferably an ethoxy unit; n is 0.5-5, preferably 0.5-3; M is an ammonium ion or a metal ion, more preferably a sodium ion. Alkyl ether sulfate generally exists in the form of a mixture containing R of different chain lengths and different degrees of ethoxylation. The ideal sulfate-type surfactant is C 12-14 polyoxyethylene (3) ether sulfate sodium, C 12 ~15 Sodium polyoxyethylene(2) ether sulfate.
如上所述的非离子表面活性剂含：Nonionic surfactants as described above contain:
(a)油脂乙氧基化物非离子表面活性剂1～100％(a) Grease ethoxylate nonionic surfactant 1～100%
(b)烷基聚氧乙烯醚非离子表面活性剂0～99％(b) Alkyl polyoxyethylene ether nonionic surfactant 0-99%
(c)烷基多苷非离子表面活性剂0～99％(c) Alkyl polyglycoside nonionic surfactant 0-99%
(d)烷醇酰胺非离子表面活性剂0～99％(d) Alkanolamide nonionic surfactant 0-99%
如上所述的油脂乙氧基化物是水溶性，具有如下通式：Fat ethoxylates as described above are water soluble and have the general formula:
其中R为C1～30烃基或它们的混合物，优选C8～18烃基或它们的混合物，x、y、z可以相同或不同，x+y+z＝n，n为1～180，优选12～90，更优选18～60。典型的油脂乙氧基化物有：大豆油乙氧基化物(单链平均EO加合数14～20)、椰油乙氧基化物(单链平均EO加合数6～12)、菜籽油乙氧基化物(单链平均EO加合数14～20)，具体的制备方法见中国专利申请号为200510012771.3的专利。Wherein R is C 1-30 hydrocarbon group or their mixture, preferably C 8-18 hydrocarbon group or their mixture, x, y, z can be the same or different, x+y+z=n, n is 1-180, preferably 12 ~90, more preferably 18~60. Typical oil ethoxylates are: soybean oil ethoxylate (average single-chain EO adduct number 14-20), coconut oil ethoxylate (single-chain average EO adduct number 6-12), rapeseed oil Ethoxylates (average single-chain EO adduct number 14-20), the specific preparation method can be found in the Chinese patent application No. 200510012771.3.
如上所述的烷基聚氧乙烯醚(或称脂肪醇聚氧乙烯醚)非离子表面活性剂有如下形式：R-O-(C2H4O)n-H，其中R为C8～22烷基或其混合物，可以是直链或支链、伯烷基或仲烷基，优选C12～14，C12～15或C12～16烷基；n为1～22，优选7～10。较为理想的是十二烷基聚氧乙烯(9)醚，十二、十四烷基聚氧乙烯(9)醚，十二烷基聚氧乙烯(7)醚。The above-mentioned alkyl polyoxyethylene ether (or fatty alcohol polyoxyethylene ether) nonionic surfactant has the following form: RO-(C 2 H 4 O) n -H, wherein R is C 8-22 alkane The group or its mixture can be straight or branched, primary or secondary, preferably C 12-14 , C 12-15 or C 12-16 ; n is 1-22, preferably 7-10. More ideal is lauryl polyoxyethylene (9) ether, lauryl, tetradecyl polyoxyethylene (9) ether, lauryl polyoxyethylene (7) ether.
如上所述的烷基多苷非离子表面活性剂，有如下通式：RO(Z)x，其中Z是葡萄糖基，R是烷基，含有8～22个碳原子，优选8～14个碳原子；x是葡萄糖的平均聚合度，x为1.0～3.0，优选1.2～1.8。较为理想的是十二烷基葡萄糖苷酯、椰油烷基葡萄糖苷酯。The above-mentioned alkyl polyglycoside nonionic surfactant has the following general formula: RO(Z) x , wherein Z is a glucose group, R is an alkyl group, and contains 8 to 22 carbon atoms, preferably 8 to 14 carbon atoms atom; x is the average degree of polymerization of glucose, and x is 1.0-3.0, preferably 1.2-1.8. More ideal are lauryl glucoside and coconut oil alkyl glucoside.
如上所述的烷醇酰胺非离子表面活性剂是C8～18烷醇酰胺，可用作增稠剂，具有以下通式：R1-CO-N(H)m(R2OH)3-m，，其中，R1是含有7～21，优选11～17个碳原子的饱和或不饱和无羟基脂族烃基或它们的混合物；R2表示亚甲基或亚乙基；m是1或2，优选1。具体实例是椰油酸单乙醇酰胺或/和十二烷基二乙醇酰胺。The alkanolamide nonionic surfactants mentioned above are C 8 ~ 18 alkanolamides, which can be used as thickeners and have the following general formula: R 1 -CO-N(H) m (R 2 OH) 3- m , wherein, R 1 is a saturated or unsaturated hydroxyl-free aliphatic hydrocarbon group or a mixture thereof containing 7 to 21, preferably 11 to 17 carbon atoms; R 2 represents methylene or ethylene; m is 1 or 2, preferably 1. Specific examples are cocoic acid monoethanolamide or/and lauryldiethanolamide.
如上所述的两性表面活性剂是甜菜碱型两性表面活性剂和/或氧化胺两性表面活性剂。The amphoteric surfactants as described above are betaine-type amphoteric surfactants and/or amine oxide amphoteric surfactants.
如上所述的水溶性的两性表面活性剂在本发明配方中具有良好的发泡性能和洗涤能力，对硬水稳定，是一类温和的表面活性剂。The above-mentioned water-soluble amphoteric surfactants in the formulation of the present invention have good foaming performance and cleaning ability, are stable to hard water, and are a kind of mild surfactants.
如上所述的甜菜碱型两性表面活性剂有如下通式：The above-mentioned betaine type amphoteric surfactant has following general formula:
其中R1为C10～20烃基或它们的混合物，优选C12～18烃基，R2、R3为C1～3烃基，优选CH3 -，R4为具有1～6个碳原子的亚烷基。典型的甜菜碱实例包括十二烷基二甲基甜菜碱，棕榈油基、月桂基、十六烷基、硬脂基二甲基甜菜碱。Wherein R 1 is a C 10-20 hydrocarbon group or a mixture thereof, preferably a C 12-18 hydrocarbon group, R 2 and R 3 are a C 1-3 hydrocarbon group, preferably CH 3 - , and R 4 is an alkylene group having 1 to 6 carbon atoms. alkyl. Typical examples of betaines include lauryl dimethyl betaine, palmityl, lauryl, cetyl, stearyl dimethyl betaine.
如上所述的作为增泡剂/稳定剂的氧化胺两性表面活性剂包括具有下式的化合物或其混合物：Amine oxide amphoteric surfactants as suds boosters/stabilizers as described above include compounds of the formula or mixtures thereof:
其中R1是烷基、2-羟基烷基、3-羟基烷基或3-烷氧基-2-羟丙基，其中烷基和烷氧基分别含有约8～18个碳原子，R2和R3是甲基、乙基、丙基、异丙基、2-羟乙基、2-羟丙基或3-羟基丙基。较为理想的是十二烷基二甲基氧化胺。Wherein R 1 is alkyl, 2-hydroxyalkyl, 3-hydroxyalkyl or 3-alkoxy-2-hydroxypropyl, wherein the alkyl and alkoxy groups contain about 8 to 18 carbon atoms respectively, and R 2 and R3 is methyl, ethyl, propyl, isopropyl, 2-hydroxyethyl, 2-hydroxypropyl or 3-hydroxypropyl. More desirable is lauryl dimethyl amine oxide.
如上所述的液体载体的作用是将其它必要的和任选的组份溶解、分散或悬浮于其中，该液体载体除主要是去离子水外，还包括增溶剂(也称水溶助长剂)、溶剂、pH调节剂。The effect of the above-mentioned liquid carrier is to dissolve, disperse or suspend other necessary and optional components therein, and the liquid carrier also includes a solubilizing agent (also called a hydrotrope), except mainly deionized water, Solvents, pH regulators.
如上所述的液体载体含：The liquid carrier as described above contains:
(a)去离子水80～100％(a) Deionized water 80-100%
(b)溶剂或增溶剂0～20％(b) Solvent or solubilizer 0～20%
(c)pH调节剂0～10％(c) pH regulator 0-10%
如上所述的液体载体可包含一种或多种为溶剂或增溶剂的材料。适用于本发明配方的有：低碳醇、二醇、其它多元醇、醚、胺、C1～3烷基芳基磺酸盐、C6～12烷醇、C1～6羧基硫酸盐和磺酸盐、尿素、C1～6氢化羧酸盐、C1～4羧酸盐、C2～4有机二酸及其混合物。典型的有：C1～4烷醇、甲苯磺酸钠、钾和铵，二甲苯磺酸钠、钾和铵，取代或未取代的萘磺酸钠、钾和铵及它们的混合物；磺基琥珀酸盐、磺基苯二甲酸盐；乙酸盐、丙酸盐和柠檬酸盐；琥珀酸、戊二酸和己二酸。用于本发明优选的溶剂或增溶剂是乙醇、乙二醇、二甲苯磺酸钠、钾、铵，甲苯磺酸钠、钾、铵和它们的混合物。A liquid carrier as described above may contain one or more materials that are solvents or solubilizers. Those suitable for the formulation of the present invention are: low-carbon alcohols, diols, other polyols, ethers, amines, C 1-3 alkyl aryl sulfonates, C 6-12 alkanols, C 1-6 carboxysulfates and Sulfonates, urea, C 1-6 hydrocarboxylates, C 1-4 carboxylates, C 2-4 organic diacids and mixtures thereof. Typical ones are: C 1～4 alkanol, sodium, potassium and ammonium toluenesulfonate, sodium, potassium and ammonium xylenesulfonate, substituted or unsubstituted sodium, potassium and ammonium naphthalenesulfonate and their mixtures; Succinates, sulfophthalates; acetates, propionates, and citrates; succinic, glutaric, and adipic acids. Preferred solvents or solubilizers for use in the present invention are ethanol, ethylene glycol, sodium, potassium, ammonium xylene sulfonate, sodium, potassium, ammonium toluene sulfonate, and mixtures thereof.
本发明配方还可含一些pH调节剂，包括碱金属碳酸盐或碳酸氢盐溶液和有机或无机酸溶液，如Na2CO3、NaHCO3、K2CO3、KHCO3及柠檬酸、酒石酸、磺酸、磷酸等的水溶液，根据配方要求的pH值选择合适的加入量。The formula of the present invention can also contain some pH regulators, including alkali metal carbonate or bicarbonate solution and organic or inorganic acid solution, such as Na 2 CO 3 , NaHCO 3 , K 2 CO 3 , KHCO 3 and citric acid, tartaric acid , Sulfonic acid, phosphoric acid and other aqueous solutions, choose the appropriate amount according to the pH value required by the formula.
如上所述的电解质包括氯化钠、氯化钾、柠檬酸钠、乙酸钠、硫酸钠或硫酸钾等盐。最优选的电解质是氯化钠或氯化钾。Electrolytes as mentioned above include salts such as sodium chloride, potassium chloride, sodium citrate, sodium acetate, sodium sulfate or potassium sulfate. The most preferred electrolytes are sodium chloride or potassium chloride.
如上所述的香料为安全的水溶性的食用香料，如食用柠檬香精。The spices mentioned above are safe water-soluble food flavors, such as edible lemon essence.
本发明的制备方法：Preparation method of the present invention:
本发明手洗餐具洗涤剂可通过将上述发明配方中阴离子、非离子、阳离子、两性离子表面活性剂及液体载体在搅拌下，于40～50℃下混匀后，在同一温度、搅拌下加入电解质混合均匀，冷却至30～35℃后加入香料混匀，制得产品。The hand-washing tableware detergent of the present invention can be obtained by mixing the anionic, nonionic, cationic, amphoteric surfactants and liquid carriers in the above-mentioned inventive formula under stirring at 40-50°C, and then adding the electrolyte at the same temperature under stirring. Mix evenly, cool to 30-35°C, add spices and mix evenly to obtain the product.
本发明与现有技术相比具有如下优点：Compared with the prior art, the present invention has the following advantages:
本发明在手洗餐具洗涤剂配方中加入一种新的系列表面活性剂——油脂乙氧基化物，产品无毒，无刺激，皮肤相容性好，有较好的富脂作用，可降低配方产品的刺激性。此外由于相似相溶原理，天然油脂的乙氧基化物还具有优异的油污增溶能力和乳化力；对阴离子体系增稠效果明显，本身属于中等发泡产品，对配方体系泡沫无明显抑制作用，HLB值随意可调，低温溶解性好，抗硬水，易生物降解等特性，是一类综合性能较高的表面活性剂。在手洗餐具洗涤剂配方中加入油脂乙氧基化物后，产品去油污率可提高20～80％，而且配方黏度在不加电解质的情况下可提高3～60倍，此外由于油脂乙氧基化物的低刺激性和富脂作用，因此用于手洗餐具洗涤剂配方后，可以有效改善配方的刺激性和脱脂性，洗后皮肤光滑、柔嫩、有弹性。The present invention adds a new series of surfactants—grease ethoxylates to the formula of hand-washing tableware detergent. The product is non-toxic, non-irritating, and has good skin compatibility. Product irritation. In addition, due to the principle of similar miscibility, ethoxylates of natural oils and fats also have excellent oil stain solubilization and emulsifying power; they have obvious thickening effects on anionic systems, and they are medium foaming products, and have no obvious inhibitory effect on the foam of formula systems. HLB value can be adjusted at will, good low temperature solubility, hard water resistance, easy biodegradation and other characteristics, it is a kind of surfactant with high comprehensive performance. After adding grease ethoxylates to the formula of hand-washing dishwashing detergent, the degreasing rate of the product can be increased by 20-80%, and the viscosity of the formula can be increased by 3-60 times without adding electrolytes. It has low irritation and fat-rich effect, so when it is used in the formula of hand-washing dish detergent, it can effectively improve the irritation and degreasing properties of the formula, and the skin is smooth, soft and elastic after washing.
具体实施方式：Detailed ways:
对比例1：Comparative example 1:
(1)阴离子表面活性剂：C12～14链烷基苯磺酸钠(以100％活性物计)140g，C12～15醇醚硫酸钠(以100％活性物计)30g。(1) Anionic surfactant: 140 g of C 12-14 sodium alkylbenzene sulfonate (calculated as 100% active matter), 30 g of C 12-15 sodium alcohol ether sulfate (calculated as 100% active matter).
(2)非离子表面活性剂：十二烷基葡萄糖苷酯10g。(2) Nonionic surfactant: 10 g of lauryl glucoside ester.
(3)两性离子表面活性剂：十二烷基二甲基甜菜碱10g。(3) Zwitterionic surfactant: 10 g of dodecyl dimethyl betaine.
(4)去离子水：799g。(4) Deionized water: 799g.
(5)电解质：氯化钠10g。(5) Electrolyte: sodium chloride 10g.
(6)柠檬香精1g。(6) Lemon essence 1g.
(7)制法：将阴离子、非离子、两性离子表面活性剂及去离子水在搅拌下，于40～50℃下混匀后，在同一温度、搅拌下加入电解质混合均匀，冷却至30℃后加入香料混匀，制得产品。(7) Preparation method: Mix anionic, nonionic, zwitterionic surfactants and deionized water at 40-50°C under stirring, then add electrolyte and mix evenly at the same temperature, and cool to 30°C Then add the spices and mix well to obtain the product.
对比例2：Comparative example 2:
(1)阴离子表面活性剂：C12～14链烷基苯磺酸钠(以100％活性物计)140g，C12～15醇醚硫酸钠(以100％活性物计)30g。(1) Anionic surfactant: 140 g of C 12-14 sodium alkylbenzene sulfonate (calculated as 100% active matter), 30 g of C 12-15 sodium alcohol ether sulfate (calculated as 100% active matter).
(2)非离子表面活性剂：椰油二乙醇酰胺(1∶1)10g。(2) Nonionic surfactant: 10 g of coconut oil diethanolamide (1:1).
(3)两性离子表面活性剂：十二烷基二甲基氧化胺10g。(3) Zwitterionic surfactant: 10 g of dodecyl dimethyl amine oxide.
(4)去离子水：799g。(4) Deionized water: 799g.
(5)电解质：氯化钠10g。(5) Electrolyte: sodium chloride 10g.
(6)柠檬香精1g。(6) Lemon essence 1g.
(7)制法同对比例1。(7) The preparation method is the same as that of Comparative Example 1.
实施例1：Example 1:
(1)阴离子表面活性剂：C12～14链烷基苯磺酸钠(以100％活性物计)130g，C12～15醇醚硫酸钠(以100％活性物计)30g。(1) Anionic surfactant: 130 g of sodium C 12-14 alkanylbenzene sulfonate (calculated as 100% active matter), 30 g of sodium C 12-15 alcohol ether sulfate (calculated as 100% active matter).
(2)非离子表面活性剂：豆油乙氧基化物(n＝48)10g，十二烷基葡萄糖苷酯10g。(2) Nonionic surfactant: 10 g of soybean oil ethoxylate (n=48), 10 g of lauryl glucoside.
(3)去离子水：814g。(3) Deionized water: 814g.
(4)电解质：氯化钠5g。(4) Electrolyte: 5g of sodium chloride.
(5)柠檬香精1g。(5) Lemon essence 1g.
(6)制法：将阴离子、非离子表面活性剂及去离子水在搅拌下，于40～50℃下混匀后，在同一温度、搅拌下加入电解质混合均匀，冷却至30℃后加入香料混匀，制得产品。(6) Preparation method: Mix anionic, nonionic surfactants and deionized water at 40-50°C under stirring, then add electrolyte at the same temperature and mix evenly under stirring, add spices after cooling to 30°C Mix well to obtain the product.
实施例2：Example 2:
(1)阴离子表面活性剂：C12～14链烷基苯磺酸钠(以100％活性物计)100g，C12～15醇醚硫酸钠(以100％活性物计)30g。(1) Anionic surfactant: 100 g of C 12-14 sodium alkylbenzene sulfonate (calculated as 100% active matter), 30 g of C 12-15 sodium alcohol ether sulfate (calculated as 100% active matter).
(2)非离子表面活性剂：豆油乙氧基化物(n＝54)40g，十二烷基葡萄糖苷酯10g。(2) Nonionic surfactant: 40 g of soybean oil ethoxylate (n=54), 10 g of lauryl glucoside.
(3)去离子水：814g。(3) Deionized water: 814g.
(4)电解质：氯化钠5g。(4) Electrolyte: 5g of sodium chloride.
(5)柠檬香精1g。(5) Lemon essence 1g.
(6)制法同实施例1。(6) The preparation method is the same as in Example 1.
实施例3：Example 3:
(1)阴离子表面活性剂：C12～14链烷基苯磺酸钠(以100％活性物计)80g，C12～15醇醚硫酸钠(以100％活性物计)30g。(1) Anionic surfactant: 80 g of C 12-14 sodium alkylbenzene sulfonate (calculated as 100% active matter), 30 g of C 12-15 sodium alcohol ether sulfate (calculated as 100% active matter).
(2)非离子表面活性剂：椰油乙氧基化物(n＝24)60g，十二烷基葡萄糖苷酯10g。(2) Nonionic surfactant: 60 g of coconut oil ethoxylate (n=24), 10 g of lauryl glucoside.
(3)去离子水814g。(3) 814g of deionized water.
(4)电解质：氯化钠5g。(4) Electrolyte: 5g of sodium chloride.
(5)柠檬香精1g。(5) Lemon essence 1g.
(6)制法同实施例1。(6) The preparation method is the same as in Example 1.
实施例4：Example 4:
(1)阴离子表面活性剂：C12～14链烷基苯磺酸钠(以100％活性物计)50g，C12～15醇醚硫酸钠(以100％活性物计)30g。(1) Anionic surfactant: 50 g of C 12-14 sodium alkylbenzene sulfonate (calculated as 100% active matter), 30 g of C 12-15 sodium alcohol ether sulfate (calculated as 100% active matter).
(2)非离子表面活性剂：棕榈油乙氧基化物(n＝42)90g，十二烷基葡萄糖苷酯10g。(2) Nonionic surfactant: 90 g of palm oil ethoxylate (n=42), 10 g of lauryl glucoside.
(3)去离子水：819g。(3) Deionized water: 819g.
(4)柠檬香精1g。(4) Lemon essence 1g.
(5)制法：将阴离子、非离子表面活性剂及去离子水在搅拌下，于40～50℃下混匀，冷却至30℃后加入香料混匀，制得产品。(5) Preparation method: Mix anionic, nonionic surfactants and deionized water at 40-50°C under stirring, add spices and mix evenly after cooling to 30°C to obtain the product.
实施例5：Example 5:
(1)阴离子表面活性剂：C12～14链烷基苯磺酸钠(以100％活性物计)30g，C12～15醇醚硫酸钠(以100％活性物计)30g。(1) Anionic surfactant: 30 g of C 12-14 sodium alkylbenzene sulfonate (calculated as 100% active matter), 30 g of C 12-15 sodium alcohol ether sulfate (calculated as 100% active matter).
(2)非离子表面活性剂：菜籽油乙氧基化物(n＝48)110g，十二烷基葡萄糖苷酯10g。(2) Nonionic surfactant: 110 g of rapeseed oil ethoxylate (n=48), 10 g of lauryl glucoside.
(3)去离子水：819g。(3) Deionized water: 819g.
(4)柠檬香精1g。(4) Lemon essence 1g.
(5)制法同实施例4。(5) The preparation method is the same as in Example 4.
对比例3：Comparative example 3:
(1)阴离子表面活性剂：C12～14链烷基苯磺酸钠(以100％活性物计)140g，C12～15醇醚硫酸钠(以100％活性物计)30g。(1) Anionic surfactant: 140 g of C 12-14 sodium alkylbenzene sulfonate (calculated as 100% active matter), 30 g of C 12-15 sodium alcohol ether sulfate (calculated as 100% active matter).
(2)溶剂：95％乙醇50g。(2) Solvent: 50 g of 95% ethanol.
(3)去离子水：779g。(3) Deionized water: 779g.
(4)柠檬香精1g。(4) Lemon essence 1g.
(5)制法：将阴离子表面活性剂、溶剂及去离子水在搅拌下，于40～50℃下混匀，冷却至30℃后加入香料混匀，制得产品。(5) Preparation method: Mix anionic surfactant, solvent and deionized water under stirring at 40-50°C, cool to 30°C, add spices and mix evenly to obtain the product.
实施例6：Embodiment 6:
(1)阴离子表面活性剂：C12～14链烷基苯磺酸钠(以100％活性物计)40g，C12～15醇醚硫酸钠(以100％活性物计)30g。(1) Anionic surfactant: 40 g of C 12-14 sodium alkylbenzene sulfonate (calculated as 100% active matter), 30 g of C 12-15 sodium alcohol ether sulfate (calculated as 100% active matter).
(2)非离子表面活性剂：豆油乙氧基化物(n＝54)100g。(2) Nonionic surfactant: 100 g of soybean oil ethoxylate (n=54).
(3)溶剂：95％乙醇50g。(3) Solvent: 50 g of 95% ethanol.
(4)去离子水：779g。(4) Deionized water: 779g.
(5)柠檬香精1g。(5) Lemon essence 1g.
(6)制法：将阴离子、非离子表面活性剂、溶剂及去离子水在搅拌下，于40～50℃下混匀，冷却至30℃后加入香料混匀，制得产品。(6) Preparation method: Mix anionic, nonionic surfactant, solvent and deionized water at 40-50°C under stirring, add spices and mix evenly after cooling to 30°C to obtain the product.
实施例7：Embodiment 7:
(1)阴离子表面活性剂：C12～14链烷基苯磺酸钾(以100％活性物计)100g，C12～15醇醚硫酸钠(以100％活性物计)20g。(1) Anionic surfactant: 100 g of potassium C 12-14 alkylbenzene sulfonate (calculated as 100% active matter), 20 g of sodium sulfate of C 12-15 alcohol ether (calculated as 100% active matter).
(2)非离子表面活性剂：豆油乙氧基化物(n＝48)10g，十二烷基葡萄糖苷酯20g，AEO9 20g，椰油二乙醇酰胺(1∶1)10g。(2) Nonionic surfactant: soybean oil ethoxylate (n=48) 10g, lauryl glucoside ester 20g, AEO 9 20g, coconut oil diethanolamide (1:1) 10g.
(3)两性离子表面活性剂：十二烷基二甲基氧化胺10g。(3) Zwitterionic surfactant: 10 g of dodecyl dimethyl amine oxide.
(4)增溶剂：二甲苯磺酸钠10g。(4) Solubilizer: 10 g of sodium xylene sulfonate.
(5)溶剂：95％乙醇20g。(5) Solvent: 20 g of 95% ethanol.
(6)去离子水：774.5g。(6) Deionized water: 774.5g.
(7)电解质：柠檬酸钠5g。(7) Electrolyte: 5 g of sodium citrate.
(8)柠檬香精0.5g。(8) Lemon essence 0.5g.
(9)制法：将阴离子、非离子、两性离子表面活性剂及去离子水、溶剂和增溶剂在搅拌下，于40～50℃下混匀后，在同一温度、搅拌下加入电解质混合均匀，冷却至35℃后加入香料混匀，制得产品。(9) Preparation method: Mix anionic, nonionic, zwitterionic surfactants, deionized water, solvents and solubilizers at 40-50°C under stirring, then add electrolytes at the same temperature and mix well , after cooling to 35°C, add spices and mix well to obtain the product.
实施例8：Embodiment 8:
(1)阴离子表面活性剂：C12～14链烷基苯磺酸氨(以100％活性物计)10g，C12～15醇醚硫酸钠(以100％活性物计)10g。(1) Anionic surfactant: 10 g of C 12-14 ammonium alkylbenzene sulfonate (calculated as 100% active matter), 10 g of C 12-15 alcohol ether sodium sulfate (calculated as 100% active matter).
(2)非离子表面活性剂：豆油乙氧基化物(n＝48)60g，十二烷基葡萄糖苷酯10g，AEO9 20g，椰油二乙醇酰胺(1∶1)10g。(2) Nonionic surfactant: soybean oil ethoxylate (n=48) 60g, lauryl glucoside ester 10g, AEO 9 20g, coconut oil diethanolamide (1:1) 10g.
(3)两性离子表面活性剂：十六烷基二甲基甜菜碱20g，十二烷基二甲基氧化胺20g。(3) Zwitterionic surfactant: 20 g of cetyl dimethyl betaine and 20 g of dodecyl dimethyl amine oxide.
(4)增溶剂：甲苯磺酸钠20g。(4) Solubilizer: 20 g of sodium toluenesulfonate.
(5)溶剂：乙二醇30g。(5) Solvent: 30 g of ethylene glycol.
(6)去离子水：788g。(6) Deionized water: 788g.
(7)电解质：氯化钠1g。(7) Electrolyte: sodium chloride 1g.
(8)柠檬香精1g。(8) Lemon essence 1g.
(9)制法：将阴离子、非离子、两性离子表面活性剂及去离子水、溶剂和增溶剂在搅拌下，于40～50℃下混匀后，在同一温度、搅拌下加入电解质混合均匀，冷却至35℃后加入香料混匀，制得产品。(9) Preparation method: Mix anionic, nonionic, zwitterionic surfactants, deionized water, solvents and solubilizers at 40-50°C under stirring, then add electrolytes at the same temperature and mix well , after cooling to 35°C, add spices and mix well to obtain the product.
实施例9：Embodiment 9:
(1)阴离子表面活性剂：C12～14链烷基苯磺酸钠(以100％活性物计)10g。(1) Anionic surfactant: 10 g of sodium C 12-14 alkanylbenzene sulfonate (calculated as 100% active substance).
(2)非离子表面活性剂：牛油乙氧基化物(n＝54)60g，AEO9 30g，AE07 20g，椰油单乙醇酰胺10g。(2) Nonionic surfactants: tallow ethoxylate (n=54) 60g, AEO 9 30g, AE0 7 20g, coconut oil monoethanolamide 10g.
(3)两性离子表面活性剂：椰油酰胺基丙基甜菜碱20g。(3) Zwitterionic surfactant: 20 g of cocamidopropyl betaine.
(4)增溶剂：尿素20g。(4) Solubilizer: 20 g of urea.
(5)溶剂：乙二醇30g。(5) Solvent: 30 g of ethylene glycol.
(6)去离子水799g。(6) 799g of deionized water.
(7)柠檬香精1g。(7) Lemon essence 1g.
(8)制法同实施例8。(8) The preparation method is the same as in Example 8.
对比例1～3及实施例1～5的性能比较见表1：The performance comparison of comparative examples 1～3 and embodiments 1～5 is shown in Table 1:
表1 产品的性能
表1可见，实施例1～5与不加油脂乙氧基化物的对比例1、2相比，活性物含量相同，去油率提高了20～80％，发泡力没有明显减少。It can be seen from Table 1 that, compared with Comparative Examples 1 and 2 without adding grease ethoxylate, Examples 1-5 have the same active matter content, and the oil removal rate has increased by 20-80%, and the foaming power has not decreased significantly.
对比例3及实施例6均未加任一电解质且活性物含量相当，在同一条件下(25℃，剪切速率100秒-1)后者的黏度是前者的63倍，可见油脂乙氧基化物有较好的增黏作用。Both Comparative Example 3 and Example 6 did not add any electrolyte and had the same content of active substances. Under the same conditions (25°C, shear rate 100 seconds -1 ), the viscosity of the latter was 63 times that of the former. Compounds have a better viscosity-increasing effect.
Claims (19)
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Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101019815B (en) * | 2007-03-20 | 2010-05-19 | 中国日用化学工业研究院 | A kind of bath liquid containing natural oil ethoxylate and preparation method thereof |
| CN103897882A (en) * | 2012-12-28 | 2014-07-02 | 青岛锦涟鑫商贸有限公司 | Preparation method of fruit and vegetable washing agent |
| CN109181894A (en) * | 2018-09-30 | 2019-01-11 | 北京洛娃日化有限公司 | A kind of hyperconcetration dish washing liquid and preparation method |
| CN110236971A (en) * | 2019-04-17 | 2019-09-17 | 中国日用化学研究院有限公司 | A kind of antibacterial hand sanitizer containing counter ion quaternary ammonium salt and preparation method thereof |
Family Cites Families (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB8705601D0 (en) * | 1987-03-10 | 1987-04-15 | Erba Farmitalia | Oxo-isoindolinyl derivatives |
| GB9302710D0 (en) * | 1993-02-11 | 1993-03-24 | Procter & Gamble | Cleansing compositions |
| RU2179999C2 (en) * | 1997-05-16 | 2002-02-27 | Дзе Проктер Энд Гэмбл Компани | Washing condition facilitating liquid and gel-like dishwashing detergent compositions with controlled ph value and required foaming and food soiling- removal characteristics |
| EP0988359A1 (en) * | 1997-06-13 | 2000-03-29 | The Procter & Gamble Company | Light-duty liquid dishwashing detergent compositions which have desirable low temperature stability and desirable greasy soil removal and sudsing characteristics |
| BR9916934A (en) * | 1999-01-20 | 2001-11-20 | Procter & Gamble | Compositions for washing dishes containing alkylbenzenesulfonate |
| ES2220436T3 (en) * | 1999-03-15 | 2004-12-16 | THE PROCTER & GAMBLE COMPANY | PERFUME COMPOSITIONS AND METHODS TO MASK BAD ODORS OF AMINES. |
| WO2002044311A2 (en) * | 2000-11-29 | 2002-06-06 | The Procter & Gamble Company | Hand dishwashing composition containing a suds suppresser and a method of use therefor |
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2006
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Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101019815B (en) * | 2007-03-20 | 2010-05-19 | 中国日用化学工业研究院 | A kind of bath liquid containing natural oil ethoxylate and preparation method thereof |
| CN103897882A (en) * | 2012-12-28 | 2014-07-02 | 青岛锦涟鑫商贸有限公司 | Preparation method of fruit and vegetable washing agent |
| CN109181894A (en) * | 2018-09-30 | 2019-01-11 | 北京洛娃日化有限公司 | A kind of hyperconcetration dish washing liquid and preparation method |
| CN109181894B (en) * | 2018-09-30 | 2020-07-03 | 北京洛娃日化有限公司 | Super-concentrated detergent and preparation method thereof |
| CN110236971A (en) * | 2019-04-17 | 2019-09-17 | 中国日用化学研究院有限公司 | A kind of antibacterial hand sanitizer containing counter ion quaternary ammonium salt and preparation method thereof |
| CN110236971B (en) * | 2019-04-17 | 2022-05-20 | 中国日用化学研究院有限公司 | Antibacterial hand sanitizer containing counter ion quaternary ammonium salt and preparation method thereof |
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Application publication date: 20061122 Assignee: China Light Technology Co., Ltd. Assignor: Chinese Daily Use Chemical Industry Research Inst. Contract record no.: 2013310000091 Denomination of invention: Detergent for washing dishware with hand and its preparation method Granted publication date: 20080709 License type: Exclusive License Record date: 20130807 |
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