CN1268292A - Propiconazol and triadimefon compounded preparation - Google Patents
Propiconazol and triadimefon compounded preparation Download PDFInfo
- Publication number
- CN1268292A CN1268292A CN 99113587 CN99113587A CN1268292A CN 1268292 A CN1268292 A CN 1268292A CN 99113587 CN99113587 CN 99113587 CN 99113587 A CN99113587 A CN 99113587A CN 1268292 A CN1268292 A CN 1268292A
- Authority
- CN
- China
- Prior art keywords
- propiconazole
- triazolone
- weight
- complex preparation
- preparation
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- STJLVHWMYQXCPB-UHFFFAOYSA-N propiconazole Chemical compound O1C(CCC)COC1(C=1C(=CC(Cl)=CC=1)Cl)CN1N=CN=C1 STJLVHWMYQXCPB-UHFFFAOYSA-N 0.000 title claims abstract description 26
- 238000002360 preparation method Methods 0.000 title claims abstract description 21
- WURBVZBTWMNKQT-UHFFFAOYSA-N 1-(4-chlorophenoxy)-3,3-dimethyl-1-(1,2,4-triazol-1-yl)butan-2-one Chemical compound C1=NC=NN1C(C(=O)C(C)(C)C)OC1=CC=C(Cl)C=C1 WURBVZBTWMNKQT-UHFFFAOYSA-N 0.000 title claims abstract description 5
- 239000005822 Propiconazole Substances 0.000 claims abstract description 25
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 claims abstract description 12
- 241000209140 Triticum Species 0.000 claims abstract description 9
- 235000021307 Triticum Nutrition 0.000 claims abstract description 9
- 239000003995 emulsifying agent Substances 0.000 claims abstract description 9
- 240000007594 Oryza sativa Species 0.000 claims abstract description 8
- 235000007164 Oryza sativa Nutrition 0.000 claims abstract description 8
- 235000009566 rice Nutrition 0.000 claims abstract description 8
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 claims abstract description 7
- OOCMUZJPDXYRFD-UHFFFAOYSA-L calcium;2-dodecylbenzenesulfonate Chemical compound [Ca+2].CCCCCCCCCCCCC1=CC=CC=C1S([O-])(=O)=O.CCCCCCCCCCCCC1=CC=CC=C1S([O-])(=O)=O OOCMUZJPDXYRFD-UHFFFAOYSA-L 0.000 claims abstract description 4
- 239000004615 ingredient Substances 0.000 claims abstract description 4
- FFSJPOPLSWBGQY-UHFFFAOYSA-N triazol-4-one Chemical compound O=C1C=NN=N1 FFSJPOPLSWBGQY-UHFFFAOYSA-N 0.000 claims description 20
- 241001530056 Athelia rolfsii Species 0.000 claims description 11
- 241000221785 Erysiphales Species 0.000 claims description 9
- 201000010099 disease Diseases 0.000 claims description 9
- 208000037265 diseases, disorders, signs and symptoms Diseases 0.000 claims description 9
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 claims description 7
- 239000003960 organic solvent Substances 0.000 claims description 6
- 239000003921 oil Substances 0.000 claims description 4
- 239000004359 castor oil Substances 0.000 claims description 3
- 235000019438 castor oil Nutrition 0.000 claims description 3
- ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 claims description 3
- -1 polyoxy ethyl ether Polymers 0.000 claims description 3
- 239000003849 aromatic solvent Substances 0.000 claims description 2
- 230000000694 effects Effects 0.000 abstract description 4
- 239000002904 solvent Substances 0.000 abstract description 3
- 238000001228 spectrum Methods 0.000 abstract description 3
- 208000031888 Mycoses Diseases 0.000 abstract description 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 abstract 2
- 235000003846 Ricinus Nutrition 0.000 abstract 1
- 241000322381 Ricinus <louse> Species 0.000 abstract 1
- 230000000749 insecticidal effect Effects 0.000 abstract 1
- 239000008096 xylene Substances 0.000 abstract 1
- FRXSZNDVFUDTIR-UHFFFAOYSA-N 6-methoxy-1,2,3,4-tetrahydroquinoline Chemical compound N1CCCC2=CC(OC)=CC=C21 FRXSZNDVFUDTIR-UHFFFAOYSA-N 0.000 description 4
- 241000233866 Fungi Species 0.000 description 4
- OILXMJHPFNGGTO-UHFFFAOYSA-N (22E)-(24xi)-24-methylcholesta-5,22-dien-3beta-ol Natural products C1C=C2CC(O)CCC2(C)C2C1C1CCC(C(C)C=CC(C)C(C)C)C1(C)CC2 OILXMJHPFNGGTO-UHFFFAOYSA-N 0.000 description 3
- RQOCXCFLRBRBCS-UHFFFAOYSA-N (22E)-cholesta-5,7,22-trien-3beta-ol Natural products C1C(O)CCC2(C)C(CCC3(C(C(C)C=CCC(C)C)CCC33)C)C3=CC=C21 RQOCXCFLRBRBCS-UHFFFAOYSA-N 0.000 description 3
- OQMZNAMGEHIHNN-UHFFFAOYSA-N 7-Dehydrostigmasterol Natural products C1C(O)CCC2(C)C(CCC3(C(C(C)C=CC(CC)C(C)C)CCC33)C)C3=CC=C21 OQMZNAMGEHIHNN-UHFFFAOYSA-N 0.000 description 3
- DNVPQKQSNYMLRS-NXVQYWJNSA-N Ergosterol Natural products CC(C)[C@@H](C)C=C[C@H](C)[C@H]1CC[C@H]2C3=CC=C4C[C@@H](O)CC[C@]4(C)[C@@H]3CC[C@]12C DNVPQKQSNYMLRS-NXVQYWJNSA-N 0.000 description 3
- 230000000844 anti-bacterial effect Effects 0.000 description 3
- 239000003899 bactericide agent Substances 0.000 description 3
- DNVPQKQSNYMLRS-SOWFXMKYSA-N ergosterol Chemical compound C1[C@@H](O)CC[C@]2(C)[C@H](CC[C@]3([C@H]([C@H](C)/C=C/[C@@H](C)C(C)C)CC[C@H]33)C)C3=CC=C21 DNVPQKQSNYMLRS-SOWFXMKYSA-N 0.000 description 3
- 239000000203 mixture Substances 0.000 description 3
- 244000141359 Malus pumila Species 0.000 description 2
- 235000011430 Malus pumila Nutrition 0.000 description 2
- 235000015103 Malus silvestris Nutrition 0.000 description 2
- 206010027146 Melanoderma Diseases 0.000 description 2
- 244000061176 Nicotiana tabacum Species 0.000 description 2
- 235000002637 Nicotiana tabacum Nutrition 0.000 description 2
- 244000046052 Phaseolus vulgaris Species 0.000 description 2
- 235000010627 Phaseolus vulgaris Nutrition 0.000 description 2
- 235000009754 Vitis X bourquina Nutrition 0.000 description 2
- 235000012333 Vitis X labruscana Nutrition 0.000 description 2
- 240000006365 Vitis vinifera Species 0.000 description 2
- 235000014787 Vitis vinifera Nutrition 0.000 description 2
- 210000000170 cell membrane Anatomy 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 238000004945 emulsification Methods 0.000 description 2
- 230000002538 fungal effect Effects 0.000 description 2
- 230000000855 fungicidal effect Effects 0.000 description 2
- 230000002045 lasting effect Effects 0.000 description 2
- 239000000575 pesticide Substances 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 150000003852 triazoles Chemical class 0.000 description 2
- 241000235349 Ascomycota Species 0.000 description 1
- 241000221198 Basidiomycota Species 0.000 description 1
- 241000196324 Embryophyta Species 0.000 description 1
- 241000510928 Erysiphe necator Species 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 244000052616 bacterial pathogen Species 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 230000006378 damage Effects 0.000 description 1
- 230000002950 deficient Effects 0.000 description 1
- 230000000857 drug effect Effects 0.000 description 1
- 230000002401 inhibitory effect Effects 0.000 description 1
- 231100000053 low toxicity Toxicity 0.000 description 1
- 230000003641 microbiacidal effect Effects 0.000 description 1
- 229940124561 microbicide Drugs 0.000 description 1
- 239000002855 microbicide agent Substances 0.000 description 1
- 230000028070 sporulation Effects 0.000 description 1
- 230000002195 synergetic effect Effects 0.000 description 1
Landscapes
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
A compounded preparation of propiconazole and triadimefon for preventing and treating fungus diseases of wheat, rice etc, is composed of (by wt.%) effective ingredient propiconazole 10-25, triadimefan 10-25, and the rest including emulsifier calcium dodecylbenzene sulfonate, ricinus oil polyethenoxy ether 8-12, and the rest solvent xylene and toluene. Its advantages include broad insecticidal spectrum, good effect, etc.
Description
The present invention relates to a kind of composition pesticide, relate in particular to a kind of be used to prevent and treat the microbicide compositions propiconazole of farm crop fungus diseases such as wheat, paddy rice and the complex preparation of triazolone.
Triazolone (triadimefon) is a kind of triazole bactericidal agent of interior absorption; Mainly be the biosynthesis that suppresses the thalline ergosterol, thereby disturb thalline growth, growth and sporulation, make thalline death.Be mainly used in control wheat powdery mildew, rust and leaf blight; Cucurbits powdery mildew; The beans rust; The powdery mildew of apple, grape and tobacco.It is a kind of efficient, low toxicity, long bactericide of lasting period, but relatively poor to wheat class banded sclerotial blight and disease-controlling effects such as bakanae disease of rice, banded sclerotial blight.
The purpose of this invention is to provide a kind of fungicidal spectrum wide, the composition pesticide propiconazole of big synergy complementation and the complex preparation of triazolone arranged.
The interior suction triazole bactericidal agent that propiconazole (propiconazole) Switzerland Novartis Co.,Ltd (NOVARTIS) develops can be absorbed by plant roots, cauline leaf, and very fast upwards conduction.Main synthetic by the ergosterol that suppresses fungi, the physiological action of destruction fungal cell membrane causes fungi death.Propiconazole can be prevented and treated the disease that sac fungi, basidiomycetes and imperfect fungus cause, is used in particular for preventing and treating wheat class banded sclerotial blight, powdery mildew, rust; Bakanae disease of rice, banded sclerotial blight, grape powdery mildew, black spot and sigatoka etc.The drug effect lasting period reached about 30 days.The chemical structural formula of propiconazole is:
The chemical structural formula of triazolone is:
The present invention is achieved in that the complex preparation of a kind of propiconazole and triazolone, be characterized in that complex preparation is a missible oil, wherein effective ingredient is propiconazole (propiconazole) and triazolone (triadimefon), propiconazole is 10%～25% (weight), triazolone is 10%～25% (weight), and all the other add to 100% (weight) for emulsifier and organic solvent.
Emulsifier among the present invention is calcium dodecyl benzene sulfonate, castor oil polyoxy ethyl ether, accounts for 8～12% of preparation.
Organic solvent among the present invention is that dimethylbenzene, toluene and other aromatic solvent are added to 100% (weight).
Propiconazole of the present invention and triazolone complex preparation are used to prevent and treat wheat class banded sclerotial blight, powdery mildew, rust and bakanae disease of rice, banded sclerotial blight.
Preparation process of the present invention be with the propiconazole in the above-mentioned prescription, triazolone and emulsifier in the emulsification pot, emulsification under normal temperature adds organic solvent then and makes the missible oil that contains propiconazole 10%～25% (weight) and triazolone 10%～25% (weight).
The present invention makes the physiologically active that complex preparation has propiconazole and triazolone concurrently with propiconazole, triazolone, emulsifier and solvent, suppress the synthetic of thalline ergosterol, destroy the physiological action of fungal cell membrane, cause fungi death, improve bactericidal effect, enlarged fungicidal spectrum.Be specially adapted to prevent and treat wheat sharp eyespot, powdery mildew, rust; Bakanae disease of rice, banded sclerotial blight are measured through indoor antibacterial test, and said preparation has very strong inhibitory action to above several germs, and its effect is better than single agent propiconazole, triazolone, and certain synergistic effect is arranged.Said preparation also is applicable to the control cucurbits powdery mildew; The beans rust; The powdery mildew of apple, grape and tobacco, black spot.Overcome single agent triazolone missible oil to wheat class banded sclerotial blight and the relatively poor defective of disease-controlling effects such as bakanae disease of rice, banded sclerotial blight.
Be embodiments of the invention below:
Each component ratio (weight %) among the present invention
| The prescription scheme | Propiconazole | Triazolone | Emulsifier | Solvent |
| ????1 | ????10 | ????10 | ????8 | ????72 |
| ????2 | ????10 | ????15 | ????8 | ????67 |
| ????3 | ????10 | ????25 | ????10 | ????55 |
| ????4 | ????15 | ????10 | ????8 | ????67 |
| ????5 | ????15 | ????15 | ????8 | ????62 |
| ????6 | ????15 | ????25 | ????10 | ????50 |
| ????7 | ????20 | ????10 | ????10 | ????60 |
| ????8 | ????20 | ????15 | ????10 | ????55 |
| ????9 | ????20 | ????25 | ????12 | ????43 |
| ????10 | ????25 | ????10 | ????10 | ????55 |
| ????11 | ????25 | ????15 | ????12 | ????48 |
| ????12 | ????25 | ????25 | ????12 | ????38 |
The listed prescription of the foregoing description is not the restriction to aforementioned each component proportioning of the present invention, but content of the present invention is described further.
The effective ingredient of the complex preparation among the above-mentioned embodiment 1-12 is propiconazole and triazolone; Emulsifier is calcium dodecyl benzene sulfonate, castor oil polyoxy ethyl ether; Organic solvent is dimethylbenzene, toluene.
Claims (4)
1, the complex preparation of a kind of propiconazole and triazolone, it is characterized in that complex preparation is a missible oil, wherein effective ingredient is propiconazole (propiconazole) and triazolone (triadimefon), propiconazole is 10%～25% (weight), triazolone is 10%～25% (weight), and all the other add to 100% (weight) for emulsifier and organic solvent.
2, complex preparation according to claim 1 is characterized in that described emulsifier is calcium dodecyl benzene sulfonate, castor oil polyoxy ethyl ether, accounts for 8～12% of preparation.
3, complex preparation according to claim 1 is characterized in that described organic solvent is that dimethylbenzene, toluene and other aromatic solvent are added to 100% (weight).
4,, it is characterized in that complex preparation is used to prevent and treat wheat class banded sclerotial blight, powdery mildew, rust and bakanae disease of rice, banded sclerotial blight according to claim 1,2 or 3 described complex preparations.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 99113587 CN1268292A (en) | 1999-03-31 | 1999-03-31 | Propiconazol and triadimefon compounded preparation |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 99113587 CN1268292A (en) | 1999-03-31 | 1999-03-31 | Propiconazol and triadimefon compounded preparation |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN1268292A true CN1268292A (en) | 2000-10-04 |
Family
ID=5276761
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 99113587 Pending CN1268292A (en) | 1999-03-31 | 1999-03-31 | Propiconazol and triadimefon compounded preparation |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN1268292A (en) |
Cited By (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2006084615A1 (en) | 2005-02-12 | 2006-08-17 | Lanxess Deutschland Gmbh | Fungicidal mixtures for wood preservation |
| CN100360019C (en) * | 2005-09-15 | 2008-01-09 | 南京第一农药有限公司 | Germicide composition containing trichlamide and propiconazol and its application |
| CN100360022C (en) * | 2005-09-15 | 2008-01-09 | 南京第一农药有限公司 | Germicide composition containing propiconazol and thiram and its application |
| CN102659468A (en) * | 2012-04-23 | 2012-09-12 | 赵国彬 | Bactericide containing triazoles |
| CN103891731A (en) * | 2012-12-31 | 2014-07-02 | 江苏丰登农药有限公司 | Bactericidal composition containing isopyrazam and propiconazole and application thereof |
| CN107410326A (en) * | 2017-05-25 | 2017-12-01 | 深圳诺普信农化股份有限公司 | A kind of agricultural chemicals transparency liquid preparation and preparation method thereof |
| CN108782570A (en) * | 2018-08-31 | 2018-11-13 | 中国热带农业科学院环境与植物保护研究所 | Triazolone propiconazole polylactic acid microsphere and preparation method thereof |
| CN113100245A (en) * | 2021-04-06 | 2021-07-13 | 兰州大学 | Compound bactericide for preventing and controlling buddleia and preparation method thereof |
| CN116874439A (en) * | 2023-06-21 | 2023-10-13 | 甘肃皓天科技股份有限公司 | Triazolone compound with dual functions of antifungal and antitumor and application thereof |
-
1999
- 1999-03-31 CN CN 99113587 patent/CN1268292A/en active Pending
Cited By (15)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101115391B (en) * | 2005-02-12 | 2013-06-05 | 朗盛德国有限责任公司 | Fungicidal mixtures for wood preservation |
| JP2008530041A (en) * | 2005-02-12 | 2008-08-07 | ランクセス・ドイチュランド・ゲーエムベーハー | Bactericidal mixture for wood protection |
| AU2006212438B2 (en) * | 2005-02-12 | 2011-02-24 | Lanxess Deutschland Gmbh | Fungicidal mixtures for wood preservation |
| RU2432743C2 (en) * | 2005-02-12 | 2011-11-10 | ЛЕНКСЕСС Дойчланд ГмбХ | Fungicidal mixtures for protecting wood |
| WO2006084615A1 (en) | 2005-02-12 | 2006-08-17 | Lanxess Deutschland Gmbh | Fungicidal mixtures for wood preservation |
| US8334312B2 (en) | 2005-02-12 | 2012-12-18 | Lanxess Deutschland Gmbh | Fungicidal mixtures for wood preservation |
| CN100360019C (en) * | 2005-09-15 | 2008-01-09 | 南京第一农药有限公司 | Germicide composition containing trichlamide and propiconazol and its application |
| CN100360022C (en) * | 2005-09-15 | 2008-01-09 | 南京第一农药有限公司 | Germicide composition containing propiconazol and thiram and its application |
| CN102659468A (en) * | 2012-04-23 | 2012-09-12 | 赵国彬 | Bactericide containing triazoles |
| CN103891731A (en) * | 2012-12-31 | 2014-07-02 | 江苏丰登农药有限公司 | Bactericidal composition containing isopyrazam and propiconazole and application thereof |
| CN103891731B (en) * | 2012-12-31 | 2015-06-17 | 江苏丰登作物保护股份有限公司 | Bactericidal composition containing isopyrazam and propiconazole and application thereof |
| CN107410326A (en) * | 2017-05-25 | 2017-12-01 | 深圳诺普信农化股份有限公司 | A kind of agricultural chemicals transparency liquid preparation and preparation method thereof |
| CN108782570A (en) * | 2018-08-31 | 2018-11-13 | 中国热带农业科学院环境与植物保护研究所 | Triazolone propiconazole polylactic acid microsphere and preparation method thereof |
| CN113100245A (en) * | 2021-04-06 | 2021-07-13 | 兰州大学 | Compound bactericide for preventing and controlling buddleia and preparation method thereof |
| CN116874439A (en) * | 2023-06-21 | 2023-10-13 | 甘肃皓天科技股份有限公司 | Triazolone compound with dual functions of antifungal and antitumor and application thereof |
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