CN107410326A - A kind of agricultural chemicals transparency liquid preparation and preparation method thereof - Google Patents
A kind of agricultural chemicals transparency liquid preparation and preparation method thereof Download PDFInfo
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- CN107410326A CN107410326A CN201710377801.3A CN201710377801A CN107410326A CN 107410326 A CN107410326 A CN 107410326A CN 201710377801 A CN201710377801 A CN 201710377801A CN 107410326 A CN107410326 A CN 107410326A
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- Prior art keywords
- liquid preparation
- transparency liquid
- agricultural chemicals
- component
- oil
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- 239000007788 liquid Substances 0.000 title claims abstract description 44
- 238000002360 preparation method Methods 0.000 title claims abstract description 40
- 239000003905 agrochemical Substances 0.000 title claims abstract description 22
- FFSJPOPLSWBGQY-UHFFFAOYSA-N triazol-4-one Chemical compound O=C1C=NN=N1 FFSJPOPLSWBGQY-UHFFFAOYSA-N 0.000 claims abstract description 26
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 25
- 241000894006 Bacteria Species 0.000 claims abstract description 22
- 150000003851 azoles Chemical class 0.000 claims abstract description 22
- 150000002825 nitriles Chemical class 0.000 claims abstract description 21
- 239000000203 mixture Substances 0.000 claims abstract description 14
- JTXMVXSTHSMVQF-UHFFFAOYSA-N 2-acetyloxyethyl acetate Chemical compound CC(=O)OCCOC(C)=O JTXMVXSTHSMVQF-UHFFFAOYSA-N 0.000 claims abstract description 13
- 239000004530 micro-emulsion Substances 0.000 claims abstract description 11
- 239000003595 mist Substances 0.000 claims abstract description 10
- 239000000779 smoke Substances 0.000 claims abstract description 8
- 239000004550 soluble concentrate Substances 0.000 claims abstract description 8
- 239000000546 pharmaceutical excipient Substances 0.000 claims abstract 3
- 239000002904 solvent Substances 0.000 claims description 42
- 239000003921 oil Substances 0.000 claims description 22
- 235000019198 oils Nutrition 0.000 claims description 22
- -1 finish Substances 0.000 claims description 19
- 239000005820 Prochloraz Substances 0.000 claims description 7
- 239000004094 surface-active agent Substances 0.000 claims description 7
- 235000015112 vegetable and seed oil Nutrition 0.000 claims description 7
- 239000008158 vegetable oil Substances 0.000 claims description 7
- 239000003849 aromatic solvent Substances 0.000 claims description 6
- TVLSRXXIMLFWEO-UHFFFAOYSA-N prochloraz Chemical compound C1=CN=CN1C(=O)N(CCC)CCOC1=C(Cl)C=C(Cl)C=C1Cl TVLSRXXIMLFWEO-UHFFFAOYSA-N 0.000 claims description 6
- 239000005822 Propiconazole Substances 0.000 claims description 5
- 150000001336 alkenes Chemical class 0.000 claims description 5
- 239000002480 mineral oil Substances 0.000 claims description 5
- 235000010446 mineral oil Nutrition 0.000 claims description 5
- STJLVHWMYQXCPB-UHFFFAOYSA-N propiconazole Chemical compound O1C(CCC)COC1(C=1C(=CC(Cl)=CC=1)Cl)CN1N=CN=C1 STJLVHWMYQXCPB-UHFFFAOYSA-N 0.000 claims description 5
- 238000006243 chemical reaction Methods 0.000 claims description 4
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 claims description 4
- 239000007787 solid Substances 0.000 claims description 4
- 238000003756 stirring Methods 0.000 claims description 4
- 239000000470 constituent Substances 0.000 claims description 2
- 239000003945 anionic surfactant Substances 0.000 claims 1
- 210000000481 breast Anatomy 0.000 claims 1
- 239000002563 ionic surfactant Substances 0.000 claims 1
- 239000007921 spray Substances 0.000 abstract description 3
- 229920000742 Cotton Polymers 0.000 abstract description 2
- 240000007594 Oryza sativa Species 0.000 abstract description 2
- 235000007164 Oryza sativa Nutrition 0.000 abstract description 2
- 235000021307 Triticum Nutrition 0.000 abstract description 2
- 240000008042 Zea mays Species 0.000 abstract description 2
- 235000005824 Zea mays ssp. parviglumis Nutrition 0.000 abstract description 2
- 235000002017 Zea mays subsp mays Nutrition 0.000 abstract description 2
- 235000013339 cereals Nutrition 0.000 abstract description 2
- 235000005822 corn Nutrition 0.000 abstract description 2
- 201000010099 disease Diseases 0.000 abstract description 2
- 208000037265 diseases, disorders, signs and symptoms Diseases 0.000 abstract description 2
- 239000003814 drug Substances 0.000 abstract description 2
- 229940079593 drug Drugs 0.000 abstract description 2
- 235000013399 edible fruits Nutrition 0.000 abstract description 2
- 238000002483 medication Methods 0.000 abstract description 2
- 235000009566 rice Nutrition 0.000 abstract description 2
- 235000013311 vegetables Nutrition 0.000 abstract description 2
- 241000209140 Triticum Species 0.000 abstract 1
- ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 description 15
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 12
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 12
- 239000000575 pesticide Substances 0.000 description 11
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 8
- 238000009472 formulation Methods 0.000 description 8
- 239000003899 bactericide agent Substances 0.000 description 7
- 230000000361 pesticidal effect Effects 0.000 description 7
- HZJKXKUJVSEEFU-UHFFFAOYSA-N 2-(4-chlorophenyl)-2-(1H-1,2,4-triazol-1-ylmethyl)hexanenitrile Chemical compound C=1C=C(Cl)C=CC=1C(CCCC)(C#N)CN1C=NC=N1 HZJKXKUJVSEEFU-UHFFFAOYSA-N 0.000 description 6
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 6
- 239000005811 Myclobutanil Substances 0.000 description 6
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 6
- 231100001261 hazardous Toxicity 0.000 description 6
- 150000004996 alkyl benzenes Chemical class 0.000 description 5
- 239000011575 calcium Substances 0.000 description 5
- 229910052791 calcium Inorganic materials 0.000 description 5
- 239000004495 emulsifiable concentrate Substances 0.000 description 5
- 239000000463 material Substances 0.000 description 5
- 229940051841 polyoxyethylene ether Drugs 0.000 description 5
- 229920000056 polyoxyethylene ether Polymers 0.000 description 5
- 239000000047 product Substances 0.000 description 5
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 description 5
- 150000003852 triazoles Chemical class 0.000 description 5
- 241001272567 Hominoidea Species 0.000 description 4
- 239000004480 active ingredient Substances 0.000 description 4
- 238000007792 addition Methods 0.000 description 4
- 230000000844 anti-bacterial effect Effects 0.000 description 4
- 229940125773 compound 10 Drugs 0.000 description 4
- 239000007859 condensation product Substances 0.000 description 4
- QYDYPVFESGNLHU-UHFFFAOYSA-N elaidic acid methyl ester Natural products CCCCCCCCC=CCCCCCCCC(=O)OC QYDYPVFESGNLHU-UHFFFAOYSA-N 0.000 description 4
- ZLVXBBHTMQJRSX-VMGNSXQWSA-N jdtic Chemical compound C1([C@]2(C)CCN(C[C@@H]2C)C[C@H](C(C)C)NC(=O)[C@@H]2NCC3=CC(O)=CC=C3C2)=CC=CC(O)=C1 ZLVXBBHTMQJRSX-VMGNSXQWSA-N 0.000 description 4
- QYDYPVFESGNLHU-KHPPLWFESA-N methyl oleate Chemical compound CCCCCCCC\C=C/CCCCCCCC(=O)OC QYDYPVFESGNLHU-KHPPLWFESA-N 0.000 description 4
- 229940073769 methyl oleate Drugs 0.000 description 4
- 238000012545 processing Methods 0.000 description 4
- 241000196324 Embryophyta Species 0.000 description 3
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 3
- 150000001875 compounds Chemical class 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 description 2
- 241001465754 Metazoa Species 0.000 description 2
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 description 2
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 2
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 2
- 235000019484 Rapeseed oil Nutrition 0.000 description 2
- 239000012752 auxiliary agent Substances 0.000 description 2
- 239000000969 carrier Substances 0.000 description 2
- 239000004359 castor oil Substances 0.000 description 2
- 235000019438 castor oil Nutrition 0.000 description 2
- 229940125898 compound 5 Drugs 0.000 description 2
- 230000007797 corrosion Effects 0.000 description 2
- 238000005260 corrosion Methods 0.000 description 2
- 239000006184 cosolvent Substances 0.000 description 2
- 238000002425 crystallisation Methods 0.000 description 2
- 239000000839 emulsion Substances 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 230000002708 enhancing effect Effects 0.000 description 2
- 230000000855 fungicidal effect Effects 0.000 description 2
- 239000000417 fungicide Substances 0.000 description 2
- ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 description 2
- 239000004521 hot fogging concentrate Substances 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 239000001301 oxygen Substances 0.000 description 2
- 229910052760 oxygen Inorganic materials 0.000 description 2
- 229920000728 polyester Polymers 0.000 description 2
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 2
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 2
- 238000003860 storage Methods 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- 239000008096 xylene Substances 0.000 description 2
- SAJGCUXAHBJVRH-VFQQELCFSA-N (2r,3r,4r,5s)-hexane-1,2,3,4,5,6-hexol;hydrate Chemical compound O.OC[C@H](O)[C@@H](O)[C@H](O)[C@H](O)CO SAJGCUXAHBJVRH-VFQQELCFSA-N 0.000 description 1
- KHBQMWCZKVMBLN-UHFFFAOYSA-N Benzenesulfonamide Chemical compound NS(=O)(=O)C1=CC=CC=C1 KHBQMWCZKVMBLN-UHFFFAOYSA-N 0.000 description 1
- OORIKNJWZHTXDC-UHFFFAOYSA-N CCCC(CC)C(CC)(C(=O)OCC)N Chemical compound CCCC(CC)C(CC)(C(=O)OCC)N OORIKNJWZHTXDC-UHFFFAOYSA-N 0.000 description 1
- 239000004215 Carbon black (E152) Substances 0.000 description 1
- FBPFZTCFMRRESA-FSIIMWSLSA-N D-Glucitol Natural products OC[C@H](O)[C@H](O)[C@@H](O)[C@H](O)CO FBPFZTCFMRRESA-FSIIMWSLSA-N 0.000 description 1
- 239000005760 Difenoconazole Substances 0.000 description 1
- 239000001293 FEMA 3089 Substances 0.000 description 1
- 244000068988 Glycine max Species 0.000 description 1
- 235000010469 Glycine max Nutrition 0.000 description 1
- 235000019483 Peanut oil Nutrition 0.000 description 1
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 1
- 244000098338 Triticum aestivum Species 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 150000001450 anions Chemical class 0.000 description 1
- 150000004945 aromatic hydrocarbons Chemical class 0.000 description 1
- 229960003237 betaine Drugs 0.000 description 1
- 239000010495 camellia oil Substances 0.000 description 1
- 150000004649 carbonic acid derivatives Chemical class 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 229940125904 compound 1 Drugs 0.000 description 1
- 229940125810 compound 20 Drugs 0.000 description 1
- 238000013329 compounding Methods 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 235000012343 cottonseed oil Nutrition 0.000 description 1
- 239000002385 cottonseed oil Substances 0.000 description 1
- 230000008025 crystallization Effects 0.000 description 1
- 230000018044 dehydration Effects 0.000 description 1
- 238000006297 dehydration reaction Methods 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- BQYJATMQXGBDHF-UHFFFAOYSA-N difenoconazole Chemical compound O1C(C)COC1(C=1C(=CC(OC=2C=CC(Cl)=CC=2)=CC=1)Cl)CN1N=CN=C1 BQYJATMQXGBDHF-UHFFFAOYSA-N 0.000 description 1
- 238000004090 dissolution Methods 0.000 description 1
- 239000008157 edible vegetable oil Substances 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- KWIUHFFTVRNATP-UHFFFAOYSA-N glycine betaine Chemical compound C[N+](C)(C)CC([O-])=O KWIUHFFTVRNATP-UHFFFAOYSA-N 0.000 description 1
- JAXFJECJQZDFJS-XHEPKHHKSA-N gtpl8555 Chemical compound OC(=O)C[C@H](N)C(=O)N[C@@H](CCC(O)=O)C(=O)N[C@@H](C(C)C)C(=O)N[C@@H](C(C)C)C(=O)N1CCC[C@@H]1C(=O)N[C@H](B1O[C@@]2(C)[C@H]3C[C@H](C3(C)C)C[C@H]2O1)CCC1=CC=C(F)C=C1 JAXFJECJQZDFJS-XHEPKHHKSA-N 0.000 description 1
- 230000002363 herbicidal effect Effects 0.000 description 1
- 239000004009 herbicide Substances 0.000 description 1
- 125000000623 heterocyclic group Chemical group 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 150000002596 lactones Chemical class 0.000 description 1
- 230000002045 lasting effect Effects 0.000 description 1
- 208000032839 leukemia Diseases 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 231100000053 low toxicity Toxicity 0.000 description 1
- 230000035800 maturation Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 description 1
- 238000004806 packaging method and process Methods 0.000 description 1
- 238000012856 packing Methods 0.000 description 1
- 230000001717 pathogenic effect Effects 0.000 description 1
- 239000000312 peanut oil Substances 0.000 description 1
- 150000003014 phosphoric acid esters Chemical class 0.000 description 1
- 239000005648 plant growth regulator Substances 0.000 description 1
- 229920001451 polypropylene glycol Polymers 0.000 description 1
- 230000000750 progressive effect Effects 0.000 description 1
- 150000004040 pyrrolidinones Chemical class 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 238000009738 saturating Methods 0.000 description 1
- 239000008159 sesame oil Substances 0.000 description 1
- 235000011803 sesame oil Nutrition 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- 239000000600 sorbitol Substances 0.000 description 1
- 238000009331 sowing Methods 0.000 description 1
- 239000003549 soybean oil Substances 0.000 description 1
- 235000012424 soybean oil Nutrition 0.000 description 1
- 241000894007 species Species 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- 239000000341 volatile oil Substances 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- 239000000080 wetting agent Substances 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/64—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with three nitrogen atoms as the only ring hetero atoms
- A01N43/647—Triazoles; Hydrogenated triazoles
- A01N43/653—1,2,4-Triazoles; Hydrogenated 1,2,4-triazoles
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
- A01N25/02—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests containing liquids as carriers, diluents or solvents
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
- A01N25/02—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests containing liquids as carriers, diluents or solvents
- A01N25/04—Dispersions, emulsions, suspoemulsions, suspension concentrates or gels
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N37/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
- A01N37/02—Saturated carboxylic acids or thio analogues thereof; Derivatives thereof
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
- A01N47/08—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
- A01N47/28—Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N<
- A01N47/38—Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N< containing the group >N—CO—N< where at least one nitrogen atom is part of a heterocyclic ring; Thio analogues thereof
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Health & Medical Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Dentistry (AREA)
- Plant Pathology (AREA)
- Engineering & Computer Science (AREA)
- Pest Control & Pesticides (AREA)
- Agronomy & Crop Science (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Toxicology (AREA)
- Chemical & Material Sciences (AREA)
- Dispersion Chemistry (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention discloses a kind of agricultural chemicals transparency liquid preparation, and containing component A and B component, nitrile bacterium azoles and/or the triazolone that wherein component A is 1%~30%, B component is 2%~70% ethylene acetate, and remaining is other compositions and/or excipient.The transparency liquid preparation is missible oil, finish, mist of oil agent, thermal fog, smoke agent, ultra low volume liquids, soluble concentrate or microemulsion.Transparency liquid preparation of the present invention can be used as progress constant, low capacity and ultra-low volume spray agent to use, for preventing and treating the control of crop disease medications such as the crop field cereal crops such as wheat, rice, corn and fruit tree, vegetables and cotton.
Description
Technical field
The invention belongs to pesticide processing technical field, more particularly to the processing of agricultural chemicals transparency liquid preparation.
Background technology
Agricultural chemicals transparency liquid preparation refers to visually observe in the normal use temperature range of agricultural chemicals as transparency liquid (agricultural chemicals
Preparation use temperature range is commonly considered as at 0 DEG C~50 DEG C), even if be at other temperatures solid, semisolid, turbid solution or
Emulsion, once temperature, which reaches normal operating range preparation, should recover transparent.This kind of pesticidal preparations include missible oil, finish, can
Solution, ultra low volume liquids (ultra-low volume spray agent, ultra-low-volume formulation, ULV), microemulsion, mist of oil agent, thermal fog, aqua
Deng.
Triazole bactericidal agent has the characteristics that efficient, low toxicity, low-residual, the lasting period is long, absorbability is strong, is using earliest
Heterocyclic nitrogen-group fungicide.Nitrile bacterium azoles, triazolone be developed in triazole bactericidal agent compared with it is early, price is relatively low, using universal, technology maturation
Kind.In the market triazolone, nitrile bacterium azoles are mainly met the needs of the market with missible oil product, and finish, thermal fog, microemulsion is made in small part
Etc. the formulations of pesticide.These kinds are all transparent liquid pesticide preparations, and are oiliness mostly or aqueous less, are the formulations of pesticide
In pesticide active ingredient is played a role optimal formulation.There are many pesticide active ingredients now due to the architectural characteristic of itself
And stability in the environment, such preparation can only be processed into and used.Most selective herbicide is gone back when in use
Many oiliness auxiliary agents are additionally added, to aid in active ingredient further to play its effect.Therefore it is saturating including missible oil
Prescribed liquid pesticidal preparations are being still over a long time very much normal use and are needing pesticide agent that is progressive and developing instantly or even from now on
Type.But domestic many emulsifiable concentrates for agricultural chemicals, finish, microemulsion are still using light aromatic solvent as main carriers, light virtue at present
Hydrocarbon solvent has proven to produce animals and plants one of main pathogenic of deformity and human leukemia.With people's environmental protection
The enhancing of consciousness and the needs of Sustainable Development of Modern Agriculture, develop safe and environment-friendly, efficient transparency liquid pesticidal preparations meaning
Justice is particularly significant.China comes into effect for 2014《Hazardous solvent is limited the quantity in emulsifiable concentrates for agricultural chemicals》HG/T 4576-2013 standards, have
Evil solvent light aromatic hydrocarbons etc. are further used by limitation.Triazolone, nitrile bacterium azoles be produced into transparent liquid pesticidal formulations have it is following this
A little formulations：Missible oil, finish, mist of oil agent, thermal fog, smoke agent, ultra low volume liquids, soluble concentrate, microemulsion etc..These formulations
Be required for triazole type active compound has certain solubility in a solvent, and at present triazolone, nitrile bacterium azoles etc. be all using methanol,
The hazardous solvents such as benzene,toluene,xylene, dimethylformamide as main carriers solvent, these solvents with apply sprinkle sowing into
Enter field, flow into rivers,lakes and seas, seriously pollute environment, threat is produced to animals and plants.
The agriculture chemicals fungicide kind that it is solid forms at normal temperatures in triazole bactericidal agent that nitrile bacterium azoles, triazolone, which are, due to
Nitrile bacterium azoles, triazolone special construction and cause its solubility very little in many solvents, therefore the production commercially sold
Product majority, which is to rely on the hazardous solvents such as light aromatic solvent, methanol, dimethylformamide, can just be produced into transparent liquid pesticidal
Formulation products.This kind of solvent has just been forbidden using on pesticidal preparations in developed countries such as the U.S., European Union a long time ago.China exists
Also the national standard for issuing emulsifiable concentrates for agricultural chemicals hazardous solvent limitation in 2014.With light aromatic solvent, methanol, dimethylformamide etc.
Hazardous solvent exits to be used using or by limitation, the processing of nitrile bacterium azoles or triazolone and its bactericide transparency liquid preparation of compounding
Problem has been produced into, main cause is that solubility of this kind of pesticide species in other solvents is very low, or even at normal temperatures
Can dissolving, but will be crystallized out in slightly lower temperature, and it is extremely difficult to recover to be dissolved into transparency liquid, therefore, many feelings
Some special solvents such as pyrrolidinone compounds, amide-type or carbonates will be used under condition as cosolvent, but these solvents are not
But price is high, and poor with the compatibility stability of other solvents or auxiliary agent, very strong to Packaging Bottle corrosivity, causes triazolone, nitrile
Bacterium azoles manufacture liquid-transparent preparation is relatively difficult.In view of such circumstances, it is necessary to find out one kind and can solve the problem that triazolone, nitrile bacterium azoles
Dissolving and the brilliant cosolvent of resistive connection, on bottle material without influence, it is good with existing additive compatibility stability and its produce transparency liquid preparation
Method.
The content of the invention
The present invention observes by substantial amounts of experiment and long-term storage, it was found that a kind of flash-point is high and to nitrile bacterium azoles, triazole
Ketone have excellent dissolution performance and good low temperature anti-crystallization can solvent, this solvent and other environment-friendly pesticide solvents and help
Agent has good compatibility stability, and to the packing material of agricultural chemicals, burn into is not environmentally friendly, abundant raw material, moderate.
The present invention is by selecting a kind of ethylene acetate (EGDA) to be used as the solvent of triazolone or nitrile bacterium azoles or help
Solvent, other environmentally friendly solvents are coordinated to use, without light aromatic solvent (benzene,toluene,xylene), methanol, dimethylformamide
(DMF) hazardous solvent such as, solve solvent flash-point low-security is poor, solubility is small, low temperature crystallization separates out, compatibility stability is poor,
To problems such as bottle material corrosion.
Tested vegetable oil solvent includes common vegetable oil and esterified vegetable oil, common vegetable oil such as peanut oil, soybean
The plants essential oil such as the edible oils such as oil, rapeseed oil, sesame oil, tea-seed oil and castor oil, turpentine oil, cottonseed oil.
Other environmentally friendly solvents of compatibility mechanism also include esterified vegetable oil, mineral oil, heavy aromatics etc..
It is result of the test under normal temperature below：
The solubility property of table 1 compares (agricultural chemicals: solvent=1: 20)
The triazolone of table 2 20% is compared with different proportion EGDA solubility properties
The nitrile bacterium azoles of table 3 25% are compared with different proportion EGDA solubility properties
The different solvents of table 4 are to the corrosion tests of common pesticides bottle material polyester bottles (54 DEG C ± 2 DEG C 14 days)
EGDA and triazolone, nitrile bacterium azoles, Prochloraz, propiconazole, olefin conversion compatibility stability are tested, and respectively take 20 grams of active compounds
Dissolved and mended to 100 grams with EGDA, stored 14 days under 54 DEG C of ± 2 DEG C of environment, determined active ingredient resolution ratio, as a result all reach
The index (relative rate of resolution≤5%) of Pesticidal products requirement.
The thermal storage stability of the triazole pesticide of table 5 in a solvent
Except addition heavy aromatic solvent, vegetable oil are molten in the transparency liquid preparation that triazolone or nitrile bacterium azoles and EGDA form
Outside agent, mineral oil solvent equal solvent, surfactant, including nonionic, anion, the work of amphoteric ion type surface can also be added
Property agent and its mixture；Predominantly be configured to emulsifiable concentrates for agricultural chemicals, finish, mist of oil agent, thermal fog, smoke agent, ultra low volume liquids,
The conventional surfactant of soluble concentrate, microemulsion, such as AEO, castor oil polyoxyethylene ether, styryl
Phenol APEO, styrylphenol polyoxyethylene poly-oxygen propylene aether, APES, alkylphenol-polyethenoxy
Ether formaldehyde condensation products, anhydrous sorbitol APEO, sorbitan fatty ester etc. and its phosphoric acid ester, benzene sulfonamide
Hydrochlorate, organic silicon wetting agent, fast T, glycine betaine etc..
In transparent liquid preparation, other bactericide can be added, such as propiconazole, Difenoconazole, Prochloraz, alkene azoles
Alcohol etc. and plant growth regulator, such as brassin lactones, diethyl aminoethyl hexanoate；Addition adds according to the enhancing proportions of composite bactericide
Enter, as triazolone transparency liquid preparation in, the ratios of other bactericide of addition is 1:10~10:1.
Transparency liquid preparation, missible oil, finish, mist of oil agent, thermal fog, smoke agent, ultra-low volume can be made as needed
Liquor, soluble concentrate, microemulsion.
The transparency liquids such as missible oil, finish, mist of oil agent, thermal fog, smoke agent, ultra low volume liquids, soluble concentrate, microemulsion
The preparation method of preparation：
Component B is well mixed with other solvents first；
Add component A, stirring and dissolving；
The solid constituent added in remaining other components, stirring and dissolving；
Surfactant is added, is mixed evenly as transparency liquid preparation.
Prepare the missible oil of processing, finish, mist of oil agent, thermal fog, smoke agent, ultra low volume liquids, soluble concentrate, micro-
The transparency liquid such as emulsion preparation can use polyester bottles, bucket, kettle etc. to pack, and not have corrosivity to bottle material.
Missible oil, finish, mist of oil agent, thermal fog, smoke agent, ultra low volume liquids, soluble concentrate, the microemulsion of completion, can
To be used as progress constant, low capacity and ultra-low volume spray agent, for preventing and treating the crop field such as wheat, rice, corn grain
The control of crop disease medications such as crop and fruit tree, vegetables and cotton.Through overtesting, with the same amount sold currently on the market
Product has consistent effect, and some performs better than.
Embodiment 1~6 (%)
Embodiment 7~12 (%)
Embodiment 13
30% triazolone propiconazole emulsifiable concentrate
Triazolone active compound 20%, propiconazole 10%, EGDA30%, styrylphenol polyoxyethylene poly-oxygen propylene aether
5%, APES formaldehyde condensation products 1%, alkyl benzene calcium sulfonate 4.5%, S-200# solvents 10%, methyl oleate
19.5%.
Embodiment 14
1% triazolone ultra low volume liquids
Triazolone active compound 1%, EGDA5%, AEO 2.5%, ethanol 5%, soybean oil 86.5%.
Embodiment 15
10% Triadmefon Hot Fogging Concentrate
Triazolone active compound 10%, EGDA20%, sorbitan fatty ester 1.5%, heavy aromatics S-200# solvents
68.5%.
Embodiment 16
5% triazolone microemulsion
Triazolone active compound 5%, EGDA15%, heavy aromatics S-200# solvents 5%, styrylphenol polyoxypropylene polyoxy second
Alkene ether 10%, dehydration water sorbitol polyoxyethylene ether 2%, alkyl benzene calcium sulfonate 7.5%, n-butanol 3%, water 52.5%.
Embodiment 17
12% nitrile bacterium azoles triazolone missible oil
Triazolone active compound 10%, bulk myclobutanil 2%, EGDA24%, styrylphenol polyoxyethylene ether 5%, alkyl
Phenol polyethenoxy ether 1.5%, alkyl benzene calcium sulfonate 4.5%, methyl oleate 53%.
Embodiment 18
15% olefin conversion Triadmefon Hot Fogging Concentrate
Triazolone active compound 10%, olefin conversion active compound 5%, EGDA 25%, AEO 2.5%, mineral oil
57.5%.
Embodiment 19
25% nitrile bacterium azoles missible oil
Bulk myclobutanil 25%, EGDA38%, styrylphenol polyoxyethylene ether 5.5%, APES
Formaldehyde condensation products 1.5%, alkyl benzene calcium sulfonate 5.3%, S-200# solvents 15%, methyl oleate 9.7%.
Embodiment 20
12.5% nitrile bacterium azoles Prochloraz missible oil
Bulk myclobutanil 2.5%, Prochloraz active compound 10%, EGDA 25%, styrylphenol polyoxyethylene ether 5.6%,
APES formaldehyde condensation products 1.5%, alkyl benzene calcium sulfonate 5.3%, methyl oleate 50.1%.
Embodiment 21
10% Prochloraz nitrile bacterium azoles thermal fog
Prochloraz active compound 5.5%, bulk myclobutanil 4.5%, EGDA 20%, AEO 1%, mineral oil
69%.
Embodiment 22
2% nitrile bacterium azoles ultra low volume liquids
Bulk myclobutanil 2%, EGDA 5%, AEO 1.5%, rapeseed oil 91.5%.
Embodiment 23
10% nitrile bacterium azoles mist of oil agent
Bulk myclobutanil 10%, EGDA20%, AEO 0.8%, S-200# solvents 69.2%.
It is limitation of the present invention that described above and embodiment, which are not, and the present invention is also not limited to the example above, this skill
The variations, modifications, additions or substitutions that the those of ordinary skill in art field is made in the essential scope of the present invention, should also belong to
Protection scope of the present invention.
Claims (8)
- A kind of 1. agricultural chemicals transparency liquid preparation, it is characterised in that：The agricultural chemicals transparency liquid preparation contains component A and B component, its Nitrile bacterium azoles and/or the triazolone that middle component A is 1%~30%, B component are 2%~70% ethylene acetate, and remaining is Other compositions and/or excipient.
- 2. agricultural chemicals transparency liquid preparation according to claim 1, it is characterised in that：Described component A ratio is 2%- 25%, B component ratio is 4%~50%.
- 3. agricultural chemicals transparency liquid preparation according to claim 1, it is characterised in that：Described other compositions be propiconazole, Prochloraz or olefin conversion.
- 4. agricultural chemicals transparency liquid preparation according to claim 1, it is characterised in that：Described excipient be solvent and/or Surfactant.
- 5. agricultural chemicals transparency liquid preparation according to claim 4, it is characterised in that：Described solvent be heavy aromatic solvent, Any of vegetable oil solvent, mineral oil solvent or two or more mixtures.
- 6. agricultural chemicals transparency liquid preparation according to claim 4, it is characterised in that：Described surfactant is nonionic Any of surfactant, anion surfactant, amphoteric ionic surfactant or two or more mixtures.
- 7. the preparation method of agricultural chemicals transparency liquid preparation according to claim 1, it is characterised in that：Component B is well mixed with other solvents first；Add component A, stirring and dissolving；Add other solid constituents, stirring and dissolving；Surfactant is added, is mixed evenly as transparency liquid preparation.
- 8. agricultural chemicals transparency liquid preparation according to claim 1, it is characterised in that：Described transparency liquid preparation is breast Oil, finish, mist of oil agent, thermal fog, smoke agent, ultra low volume liquids, soluble concentrate or microemulsion.
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109601531A (en) * | 2019-01-23 | 2019-04-12 | 中化化工科学技术研究总院有限公司 | One kind is multi-functional to fly anti-auxiliary agent and its preparation method and application |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1268292A (en) * | 1999-03-31 | 2000-10-04 | 江苏诺华农化有限公司 | Propiconazol and triadimefon compounded preparation |
| CN103155926A (en) * | 2011-12-18 | 2013-06-19 | 深圳诺普信农化股份有限公司 | Sterilization composite based on phenazino-1-carboxylicacid |
| CN104145950A (en) * | 2014-07-21 | 2014-11-19 | 浙江省诸暨合力化学对外贸易有限公司 | Novel carfentrazone-ethyl missible oil and preparation method thereof |
-
2017
- 2017-05-25 CN CN201710377801.3A patent/CN107410326A/en not_active Withdrawn
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1268292A (en) * | 1999-03-31 | 2000-10-04 | 江苏诺华农化有限公司 | Propiconazol and triadimefon compounded preparation |
| CN103155926A (en) * | 2011-12-18 | 2013-06-19 | 深圳诺普信农化股份有限公司 | Sterilization composite based on phenazino-1-carboxylicacid |
| CN104145950A (en) * | 2014-07-21 | 2014-11-19 | 浙江省诸暨合力化学对外贸易有限公司 | Novel carfentrazone-ethyl missible oil and preparation method thereof |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109601531A (en) * | 2019-01-23 | 2019-04-12 | 中化化工科学技术研究总院有限公司 | One kind is multi-functional to fly anti-auxiliary agent and its preparation method and application |
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Application publication date: 20171201 |