CN100360022C - Germicide composition containing propiconazol and thiram and its application - Google Patents
Germicide composition containing propiconazol and thiram and its application Download PDFInfo
- Publication number
- CN100360022C CN100360022C CNB2005100943783A CN200510094378A CN100360022C CN 100360022 C CN100360022 C CN 100360022C CN B2005100943783 A CNB2005100943783 A CN B2005100943783A CN 200510094378 A CN200510094378 A CN 200510094378A CN 100360022 C CN100360022 C CN 100360022C
- Authority
- CN
- China
- Prior art keywords
- propiconazole
- tmtd
- bactericidal composition
- thiram
- propiconazol
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 31
- STJLVHWMYQXCPB-UHFFFAOYSA-N propiconazole Chemical compound O1C(CCC)COC1(C=1C(=CC(Cl)=CC=1)Cl)CN1N=CN=C1 STJLVHWMYQXCPB-UHFFFAOYSA-N 0.000 title claims abstract description 30
- 239000005843 Thiram Substances 0.000 title abstract description 4
- KUAZQDVKQLNFPE-UHFFFAOYSA-N thiram Chemical compound CN(C)C(=S)SSC(=S)N(C)C KUAZQDVKQLNFPE-UHFFFAOYSA-N 0.000 title abstract description 4
- 229960002447 thiram Drugs 0.000 title abstract description 4
- 230000002070 germicidal effect Effects 0.000 title abstract 2
- 239000005822 Propiconazole Substances 0.000 claims description 27
- 230000000844 anti-bacterial effect Effects 0.000 claims description 14
- 239000000843 powder Substances 0.000 claims description 6
- 238000009472 formulation Methods 0.000 claims description 5
- 238000009736 wetting Methods 0.000 claims description 5
- 239000003905 agrochemical Substances 0.000 claims description 3
- 239000012752 auxiliary agent Substances 0.000 claims description 3
- 239000000839 emulsion Substances 0.000 claims description 3
- 239000000546 pharmaceutical excipient Substances 0.000 claims description 3
- 239000000725 suspension Substances 0.000 claims description 2
- 239000008187 granular material Substances 0.000 claims 1
- 201000010099 disease Diseases 0.000 abstract description 11
- 208000037265 diseases, disorders, signs and symptoms Diseases 0.000 abstract description 11
- 241000196324 Embryophyta Species 0.000 abstract description 4
- 241000219112 Cucumis Species 0.000 abstract description 3
- 235000015510 Cucumis melo subsp melo Nutrition 0.000 abstract description 3
- 230000001276 controlling effect Effects 0.000 abstract 2
- 230000003405 preventing effect Effects 0.000 abstract 2
- 235000012055 fruits and vegetables Nutrition 0.000 abstract 1
- -1 diffusant Substances 0.000 description 8
- 240000007594 Oryza sativa Species 0.000 description 7
- 235000007164 Oryza sativa Nutrition 0.000 description 7
- 235000009566 rice Nutrition 0.000 description 7
- 239000003814 drug Substances 0.000 description 6
- 241000221785 Erysiphales Species 0.000 description 4
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 4
- 239000004495 emulsifiable concentrate Substances 0.000 description 4
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 3
- 241000233866 Fungi Species 0.000 description 3
- 235000013339 cereals Nutrition 0.000 description 3
- 239000002270 dispersing agent Substances 0.000 description 3
- 235000013399 edible fruits Nutrition 0.000 description 3
- 230000000855 fungicidal effect Effects 0.000 description 3
- 239000000417 fungicide Substances 0.000 description 3
- 230000001225 therapeutic effect Effects 0.000 description 3
- 235000013311 vegetables Nutrition 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- OILXMJHPFNGGTO-UHFFFAOYSA-N (22E)-(24xi)-24-methylcholesta-5,22-dien-3beta-ol Natural products C1C=C2CC(O)CCC2(C)C2C1C1CCC(C(C)C=CC(C)C(C)C)C1(C)CC2 OILXMJHPFNGGTO-UHFFFAOYSA-N 0.000 description 2
- RQOCXCFLRBRBCS-UHFFFAOYSA-N (22E)-cholesta-5,7,22-trien-3beta-ol Natural products C1C(O)CCC2(C)C(CCC3(C(C(C)C=CCC(C)C)CCC33)C)C3=CC=C21 RQOCXCFLRBRBCS-UHFFFAOYSA-N 0.000 description 2
- DMAXMXPDVWTIRV-UHFFFAOYSA-N 2-(2-phenylethyl)phenol Chemical compound OC1=CC=CC=C1CCC1=CC=CC=C1 DMAXMXPDVWTIRV-UHFFFAOYSA-N 0.000 description 2
- RNMDNPCBIKJCQP-UHFFFAOYSA-N 5-nonyl-7-oxabicyclo[4.1.0]hepta-1,3,5-trien-2-ol Chemical compound C(CCCCCCCC)C1=C2C(=C(C=C1)O)O2 RNMDNPCBIKJCQP-UHFFFAOYSA-N 0.000 description 2
- OQMZNAMGEHIHNN-UHFFFAOYSA-N 7-Dehydrostigmasterol Natural products C1C(O)CCC2(C)C(CCC3(C(C(C)C=CC(CC)C(C)C)CCC33)C)C3=CC=C21 OQMZNAMGEHIHNN-UHFFFAOYSA-N 0.000 description 2
- 239000005995 Aluminium silicate Substances 0.000 description 2
- DNVPQKQSNYMLRS-NXVQYWJNSA-N Ergosterol Natural products CC(C)[C@@H](C)C=C[C@H](C)[C@H]1CC[C@H]2C3=CC=C4C[C@@H](O)CC[C@]4(C)[C@@H]3CC[C@]12C DNVPQKQSNYMLRS-NXVQYWJNSA-N 0.000 description 2
- 235000021307 Triticum Nutrition 0.000 description 2
- 244000098338 Triticum aestivum Species 0.000 description 2
- FJJCIZWZNKZHII-UHFFFAOYSA-N [4,6-bis(cyanoamino)-1,3,5-triazin-2-yl]cyanamide Chemical compound N#CNC1=NC(NC#N)=NC(NC#N)=N1 FJJCIZWZNKZHII-UHFFFAOYSA-N 0.000 description 2
- 235000012211 aluminium silicate Nutrition 0.000 description 2
- 125000003368 amide group Chemical group 0.000 description 2
- 239000003599 detergent Substances 0.000 description 2
- 235000014113 dietary fatty acids Nutrition 0.000 description 2
- DNVPQKQSNYMLRS-SOWFXMKYSA-N ergosterol Chemical compound C1[C@@H](O)CC[C@]2(C)[C@H](CC[C@]3([C@H]([C@H](C)/C=C/[C@@H](C)C(C)C)CC[C@H]33)C)C3=CC=C21 DNVPQKQSNYMLRS-SOWFXMKYSA-N 0.000 description 2
- 239000000194 fatty acid Substances 0.000 description 2
- 229930195729 fatty acid Natural products 0.000 description 2
- 150000004665 fatty acids Chemical class 0.000 description 2
- 238000011835 investigation Methods 0.000 description 2
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 2
- LCRMGUFGEDUSOG-UHFFFAOYSA-N naphthalen-1-ylsulfonyloxymethyl naphthalene-1-sulfonate;sodium Chemical compound [Na].C1=CC=C2C(S(=O)(OCOS(=O)(=O)C=3C4=CC=CC=C4C=CC=3)=O)=CC=CC2=C1 LCRMGUFGEDUSOG-UHFFFAOYSA-N 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- MZSDGDXXBZSFTG-UHFFFAOYSA-M sodium;benzenesulfonate Chemical compound [Na+].[O-]S(=O)(=O)C1=CC=CC=C1 MZSDGDXXBZSFTG-UHFFFAOYSA-M 0.000 description 2
- 238000001238 wet grinding Methods 0.000 description 2
- 241000198596 Alternaria tomatophila Species 0.000 description 1
- 241000235349 Ascomycota Species 0.000 description 1
- 241000221198 Basidiomycota Species 0.000 description 1
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 1
- 235000002566 Capsicum Nutrition 0.000 description 1
- 229920002134 Carboxymethyl cellulose Polymers 0.000 description 1
- 240000008067 Cucumis sativus Species 0.000 description 1
- 235000010799 Cucumis sativus var sativus Nutrition 0.000 description 1
- 240000005979 Hordeum vulgare Species 0.000 description 1
- 235000007340 Hordeum vulgare Nutrition 0.000 description 1
- 240000006240 Linum usitatissimum Species 0.000 description 1
- 235000004431 Linum usitatissimum Nutrition 0.000 description 1
- 244000302512 Momordica charantia Species 0.000 description 1
- 235000009811 Momordica charantia Nutrition 0.000 description 1
- 235000009812 Momordica cochinchinensis Nutrition 0.000 description 1
- 235000018365 Momordica dioica Nutrition 0.000 description 1
- 239000006002 Pepper Substances 0.000 description 1
- 235000016761 Piper aduncum Nutrition 0.000 description 1
- 235000017804 Piper guineense Nutrition 0.000 description 1
- 244000203593 Piper nigrum Species 0.000 description 1
- 235000008184 Piper nigrum Nutrition 0.000 description 1
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 1
- 241000918585 Pythium aphanidermatum Species 0.000 description 1
- 206010039509 Scab Diseases 0.000 description 1
- 244000000231 Sesamum indicum Species 0.000 description 1
- 235000003434 Sesamum indicum Nutrition 0.000 description 1
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 1
- 241000607479 Yersinia pestis Species 0.000 description 1
- 150000008052 alkyl sulfonates Chemical class 0.000 description 1
- 150000003851 azoles Chemical class 0.000 description 1
- 239000003899 bactericide agent Substances 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000001851 biosynthetic effect Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 210000000481 breast Anatomy 0.000 description 1
- 238000009395 breeding Methods 0.000 description 1
- 230000001488 breeding effect Effects 0.000 description 1
- OOCMUZJPDXYRFD-UHFFFAOYSA-L calcium;2-dodecylbenzenesulfonate Chemical compound [Ca+2].CCCCCCCCCCCCC1=CC=CC=C1S([O-])(=O)=O.CCCCCCCCCCCCC1=CC=CC=C1S([O-])(=O)=O OOCMUZJPDXYRFD-UHFFFAOYSA-L 0.000 description 1
- 150000004657 carbamic acid derivatives Chemical class 0.000 description 1
- 239000001768 carboxy methyl cellulose Substances 0.000 description 1
- 235000010948 carboxy methyl cellulose Nutrition 0.000 description 1
- 239000008112 carboxymethyl-cellulose Substances 0.000 description 1
- 210000000170 cell membrane Anatomy 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 239000013530 defoamer Substances 0.000 description 1
- 239000008367 deionised water Substances 0.000 description 1
- 229910021641 deionized water Inorganic materials 0.000 description 1
- 238000010520 demethylation reaction Methods 0.000 description 1
- FPAFDBFIGPHWGO-UHFFFAOYSA-N dioxosilane;oxomagnesium;hydrate Chemical compound O.[Mg]=O.[Mg]=O.[Mg]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O FPAFDBFIGPHWGO-UHFFFAOYSA-N 0.000 description 1
- 239000007884 disintegrant Substances 0.000 description 1
- 230000000857 drug effect Effects 0.000 description 1
- 239000004497 emulsifiable granule Substances 0.000 description 1
- 239000003995 emulsifying agent Substances 0.000 description 1
- 230000008686 ergosterol biosynthesis Effects 0.000 description 1
- 230000002538 fungal effect Effects 0.000 description 1
- 239000003112 inhibitor Substances 0.000 description 1
- 238000007689 inspection Methods 0.000 description 1
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 244000052769 pathogen Species 0.000 description 1
- 229940088417 precipitated calcium carbonate Drugs 0.000 description 1
- 230000002265 prevention Effects 0.000 description 1
- 230000003449 preventive effect Effects 0.000 description 1
- ULWHHBHJGPPBCO-UHFFFAOYSA-N propane-1,1-diol Chemical class CCC(O)O ULWHHBHJGPPBCO-UHFFFAOYSA-N 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- 239000002689 soil Substances 0.000 description 1
- 238000001228 spectrum Methods 0.000 description 1
- 230000001954 sterilising effect Effects 0.000 description 1
- 238000004659 sterilization and disinfection Methods 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 230000002195 synergetic effect Effects 0.000 description 1
- 230000009885 systemic effect Effects 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- 239000000080 wetting agent Substances 0.000 description 1
Landscapes
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The present invention discloses one kind of germicide composition containing propiconazol and thiram and its application. The composition contains propiconazol and thiram in the weight ratio of 5-50 to 5-40. The composition may be used in preventing and controlling diseases of grain crop, melons, fruits and vegetable, and has wide application range, low cost and high plant disease preventing and controlling effect.
Description
Technical field
The present invention relates to a kind of bactericidal composition and uses thereof, especially a kind of is the bactericidal composition and the application thereof of main active with propiconazole and tmtd.
Technical background
Propiconazole (Propiconazole) is the systemic fungicide with protection and therapeutic action.Belong to the biosynthetic inhibitor of ergosterol.Ergosterol plays an important role in the formation of fungal cell membrane, and propiconazole is by disturbing C
14-demethylation and hinder the biosynthesis of ergosterol in the fungus body, thus the fungi growth breeding destroyed, play protection and therapeutic action.Can be absorbed by root, stem, leaf portion, and can be soon in the plant strain body on conduction, the control sac fungi, the disease that basidiomycetes and imperfect fungus cause, can prevent and treat root rotof flax, powdery mildew especially, bakanae disease of rice, various rust, leaf spot, glume blight, net smut etc.
Propiconazole has certain therapeutic action for most of pathogens, but single use propiconazole can not reach high-efficiency prevention and control sigatoka, bakanae disease of rice etc.
Tmtd (thiram) is the protective fungicide of a kind wide spectrum, and the longevity of residure reaches about 7d.Be mainly used in and handle seed and soil, control cereal crop powdery mildew, smut, rice sprouts damping off also can be used for some fruit trees, vegetable disease.Can prevent and treat rice blast. rice oriental sesame leaf pinta, barley, wheat smut.At home and abroad not seeing has it to be used to prevent and treat diseases such as sigatoka and bakanae disease of rice.
Summary of the invention
The objective of the invention is at above-mentioned technical problem provide a kind of applied widely, cost is low, the effective plant sterilization composition that contains propiconazole and tmtd.
A further object of the invention provides the purposes of this bactericidal composition.
The objective of the invention is to realize by following measures:
A kind of bactericidal composition is characterized in that containing propiconazole and tmtd, and the weight ratio of propiconazole and tmtd is 5～50: 5～40.
Described bactericidal composition, the weight ratio that it is characterized in that propiconazole and tmtd is 10～40: 10～30.
Described bactericidal composition, wherein propiconazole and tmtd and known auxiliary agent and excipient are re-dubbed any one formulation that allows on the agricultural chemicals.These known auxiliary agents, excipients have dispersant, diffusant, defoamer, wetting agent, disintegrant etc.
Described bactericidal composition is characterized in that its formulation is pulvis, wetting powder, suspension emulsion, emulsifiable concentrate or granule.
The application of described bactericidal composition aspect control cereal class, melon and fruit or vegetable crop disease.
Beneficial effect of the present invention:
1, the used propiconazole of the present invention is an azoles fungicide, and tmtd is a Carbamates bactericidal agent, and both are mixed mutually and can not produce low touching, but Synergistic reduces dosage, reduces cost.
2, the present composition scope of application increases, be applicable to crop pests such as control cereal class, various melon and fruit, vegetables, as wheat powdery mildew, pepper anthracnose, sigatoka, bakanae disease of rice, balsam pear scab, scutellum rot of orange, powdery mildew of cucumber, early blight of tomato and late blight.
Embodiment
The invention will be further described below in conjunction with embodiment.The preparation method of formulation is conventional method among the embodiment.
Embodiment 1:
With propiconazole 20g, tmtd 5g, calcium dodecyl benzene sulfonate 4g, phenethyl phenol polyethenoxy ether 2g, peaceful newborn 33# (polyoxyethylene polyoxy third rare block compound) 2g, dimethylbenzene 52g are mixed to homogeneous phase liquid, obtain composition missible oil.
Embodiment 2:
With propiconazole 10g, tmtd 15g, detergent LS (to methoxyl group fatty acid amido benzene sulfonic acid sodium salt) 3g, dispersing agent NNO (sodium methylene bis-naphthalene sulfonate) 2g, white carbon 5g, kaolin adds to the 100g mixture and carries out comminution by gas stream, makes wetting powder.
Embodiment 3:
With propiconazole 5g, tmtd 20g, phenethyl phenol polyethenoxy ether phosphonate ester 3g, polyoxyethylene nonylphenol ether 2g, propane diols 5g, deionized water add to 100g, utilize high-shear homogenizer to stir, and make aqueous emulsion.
Embodiment 4:
Propiconazole 25g, tmtd 25g, talcum powder 50g are mixed, make pulvis.
Embodiment 5:
With propiconazole 5g, tmtd 5g, emulsifier 700
#4g, peaceful breast 33
#3g, polyoxyethylene nonylphenol ether 2g, all the other add to 100g with dimethylbenzene, and mixing is even, makes missible oil.
Embodiment 6:
With propiconazole 5g, tmtd 40g, draw back powder LS (alkylsulfonate) 5g, carboxymethyl cellulose 5g, precipitated calcium carbonate 45g mix, and make wetting powder.
Embodiment 7:
Propiconazole 10g, tmtd 40g, detergent LS (to methoxyl group fatty acid amido benzene sulfonic acid sodium salt) 3g, dispersing agent NNO (sodium methylene bis-naphthalene sulfonate) 2g, kaolin are added to 100g mix, make wetting powder.
Application Example:
Prevent and treat the sigatoka test with the preparation that the foregoing description makes.
1, test is handled: field trial is chosen in the plot of morbidity over the years and carries out, this test medicine consumption is established three concentration of treatment respectively according to the difference of each composition, but the contrast medicament is respectively commercially available agricultural chemicals 50% tmtd wet-milling and 25% propiconazole emulsifiable concentrate (EC) and the test of blank clear water.
2, have 5～10 strain Jiao Shu at least in each sub-district of test method, repeat 3 times; Inspection drug effect method before the dispenser after investigation and the control is: random searching 2～3 strains in the test treatment region, and every strain any of several broadleaf plants grove top is down investigated 5～13 leaves, and the total number of sheets and the sick number of sheets at different levels of record investigation are checked the leaf spot occurrence degree.
3, result of the test sees the following form:
| Handle (g/ mu) | Disease index (%) before the medicine | Preventive effect (%) | |||
| Behind the medicine 5 days | Behind the medicine 10 days | Behind the medicine 14 days | |||
| Embodiment 1 | 60 | 45.6 | 72.3ab | 79.2ab | 73.4ab |
| 80 | 49.3 | 86.4a | 90.5a | 81.3a | |
| 100 | 39.2 | 88.3a | 92.4a | 83.2a | |
| Embodiment 2 | 60 | 48.3 | 69.7ab | 77.4b | 70.5b |
| 80 | 50.1 | 79.6a | 83.2a | 80.4a | |
| 90 | 34.2 | 83.1a | 93.4a | 89.9a | |
| Embodiment 3 | 60 | 47.9 | 63.2ab | 71.9b | 69.3b |
| 80 | 51.2 | 79.5a | 85.2a | 84.2ab | |
| 100 | 49.9 | 83.3a | 89.4a | 86.9a | |
| But 50% tmtd wet-milling | 200 | 51.2 | 62.2c | 65.2c | 49.1c |
| 25% propiconazole emulsifiable concentrate | 120 | 38.3 | 63.7c | 65.8c | 59.9c |
| Blank clear water contrast | 41.8 | - | - | - | |
Annotate: a is illustrated on α=0.05 level remarkable, and b is illustrated on α=0.05 level variant, and c is illustrated on α=0.05 level not remarkable.
Field efficacy is the result show, propiconazole and tmtd composition have good control efficiency to sigatoka, and control efficiency all is better than single agent kind.
Claims (5)
1, a kind of bactericidal composition is characterized in that containing propiconazole and tmtd, and wherein the weight ratio of propiconazole and tmtd is 5～50: 5～40.
2, bactericidal composition according to claim 1, the weight ratio that it is characterized in that propiconazole and tmtd is 10～40: 10～30.
3, bactericidal composition according to claim 1 and 2 is characterized in that propiconazole and tmtd and known auxiliary agent and excipient are re-dubbed any one formulation that allows on the agricultural chemicals.
4, bactericidal composition according to claim 3 is characterized in that its formulation is pulvis, wetting powder, suspension emulsion, missible oil or granule.
5, the described bactericidal composition of claim 1 is in the application that prevents and treats aspect the sigatoka.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB2005100943783A CN100360022C (en) | 2005-09-15 | 2005-09-15 | Germicide composition containing propiconazol and thiram and its application |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB2005100943783A CN100360022C (en) | 2005-09-15 | 2005-09-15 | Germicide composition containing propiconazol and thiram and its application |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1930979A CN1930979A (en) | 2007-03-21 |
| CN100360022C true CN100360022C (en) | 2008-01-09 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CNB2005100943783A Expired - Fee Related CN100360022C (en) | 2005-09-15 | 2005-09-15 | Germicide composition containing propiconazol and thiram and its application |
Country Status (1)
| Country | Link |
|---|---|
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Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102308821B (en) * | 2007-10-15 | 2013-11-27 | 张少武 | Bactericide composition containing metiram active ingredient |
| CN102696648A (en) * | 2012-04-23 | 2012-10-03 | 广东中迅农科股份有限公司 | Pesticidal composition comprising prothioconazole and thiram |
| CN106962379A (en) * | 2017-05-08 | 2017-07-21 | 广西南宁益土生物科技有限责任公司 | A kind of bactericidal composition containing Chinese yam polysaccharide and thiram |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1268292A (en) * | 1999-03-31 | 2000-10-04 | 江苏诺华农化有限公司 | Propiconazol and triadimefon compounded preparation |
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2005
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Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1268292A (en) * | 1999-03-31 | 2000-10-04 | 江苏诺华农化有限公司 | Propiconazol and triadimefon compounded preparation |
Non-Patent Citations (1)
| Title |
|---|
| 植物生长调节剂与杀菌剂互作对棉苗病害的作用机理. 蒋家珍等.湖北农业科学，第5期. 2004 * |
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|---|---|
| CN1930979A (en) | 2007-03-21 |
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