CN100376158C - Germicide composition containing azoxystrobin and thiophanate-methyl and its application - Google Patents
Germicide composition containing azoxystrobin and thiophanate-methyl and its application Download PDFInfo
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- CN100376158C CN100376158C CNB2005100943872A CN200510094387A CN100376158C CN 100376158 C CN100376158 C CN 100376158C CN B2005100943872 A CNB2005100943872 A CN B2005100943872A CN 200510094387 A CN200510094387 A CN 200510094387A CN 100376158 C CN100376158 C CN 100376158C
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- thiophanate
- methyl
- fluoxastrobin
- bactericidal composition
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- 239000000203 mixture Substances 0.000 title claims abstract description 30
- 239000005842 Thiophanate-methyl Substances 0.000 title claims abstract description 27
- QGHREAKMXXNCOA-UHFFFAOYSA-N thiophanate-methyl Chemical compound COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC QGHREAKMXXNCOA-UHFFFAOYSA-N 0.000 title claims abstract description 27
- 239000005730 Azoxystrobin Substances 0.000 title abstract description 4
- WFDXOXNFNRHQEC-GHRIWEEISA-N azoxystrobin Chemical compound CO\C=C(\C(=O)OC)C1=CC=CC=C1OC1=CC(OC=2C(=CC=CC=2)C#N)=NC=N1 WFDXOXNFNRHQEC-GHRIWEEISA-N 0.000 title abstract description 4
- 230000002070 germicidal effect Effects 0.000 title abstract 2
- 239000005784 Fluoxastrobin Substances 0.000 claims description 23
- UFEODZBUAFNAEU-NLRVBDNBSA-N fluoxastrobin Chemical compound C=1C=CC=C(OC=2C(=C(OC=3C(=CC=CC=3)Cl)N=CN=2)F)C=1C(=N/OC)\C1=NOCCO1 UFEODZBUAFNAEU-NLRVBDNBSA-N 0.000 claims description 23
- 230000000844 anti-bacterial effect Effects 0.000 claims description 15
- 241000221785 Erysiphales Species 0.000 claims description 6
- 238000009472 formulation Methods 0.000 claims description 6
- 235000004936 Bromus mango Nutrition 0.000 claims description 4
- 240000007228 Mangifera indica Species 0.000 claims description 4
- 235000014826 Mangifera indica Nutrition 0.000 claims description 4
- 235000009184 Spondias indica Nutrition 0.000 claims description 4
- 239000000843 powder Substances 0.000 claims description 4
- 238000009736 wetting Methods 0.000 claims description 4
- 239000003905 agrochemical Substances 0.000 claims description 3
- 239000012752 auxiliary agent Substances 0.000 claims description 3
- 239000000546 pharmaceutical excipient Substances 0.000 claims description 3
- 230000000443 biocontrol Effects 0.000 claims description 2
- 239000000839 emulsion Substances 0.000 claims description 2
- 239000000725 suspension Substances 0.000 claims description 2
- 239000008187 granular material Substances 0.000 claims 1
- 201000010099 disease Diseases 0.000 abstract description 10
- 208000037265 diseases, disorders, signs and symptoms Diseases 0.000 abstract description 10
- 241000219112 Cucumis Species 0.000 abstract description 3
- 235000015510 Cucumis melo subsp melo Nutrition 0.000 abstract description 3
- 241000196324 Embryophyta Species 0.000 abstract description 3
- 230000001276 controlling effect Effects 0.000 abstract 2
- 230000003405 preventing effect Effects 0.000 abstract 2
- 235000012055 fruits and vegetables Nutrition 0.000 abstract 1
- 239000003814 drug Substances 0.000 description 8
- -1 methoxyl group Chemical group 0.000 description 5
- 238000012360 testing method Methods 0.000 description 5
- 240000007594 Oryza sativa Species 0.000 description 4
- 235000007164 Oryza sativa Nutrition 0.000 description 4
- 239000002270 dispersing agent Substances 0.000 description 4
- 235000013399 edible fruits Nutrition 0.000 description 4
- 235000009566 rice Nutrition 0.000 description 4
- 235000013311 vegetables Nutrition 0.000 description 4
- 235000021307 Triticum Nutrition 0.000 description 3
- 244000098338 Triticum aestivum Species 0.000 description 3
- 235000013339 cereals Nutrition 0.000 description 3
- 239000003795 chemical substances by application Substances 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- 239000005995 Aluminium silicate Substances 0.000 description 2
- 240000002791 Brassica napus Species 0.000 description 2
- 235000006008 Brassica napus var napus Nutrition 0.000 description 2
- 235000002566 Capsicum Nutrition 0.000 description 2
- 240000008067 Cucumis sativus Species 0.000 description 2
- 235000010799 Cucumis sativus var sativus Nutrition 0.000 description 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 2
- 241000221662 Sclerotinia Species 0.000 description 2
- UIIMBOGNXHQVGW-UHFFFAOYSA-M Sodium bicarbonate Chemical compound [Na+].OC([O-])=O UIIMBOGNXHQVGW-UHFFFAOYSA-M 0.000 description 2
- 241000607479 Yersinia pestis Species 0.000 description 2
- FJJCIZWZNKZHII-UHFFFAOYSA-N [4,6-bis(cyanoamino)-1,3,5-triazin-2-yl]cyanamide Chemical compound N#CNC1=NC(NC#N)=NC(NC#N)=N1 FJJCIZWZNKZHII-UHFFFAOYSA-N 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 150000001336 alkenes Chemical class 0.000 description 2
- 235000012211 aluminium silicate Nutrition 0.000 description 2
- 239000007900 aqueous suspension Substances 0.000 description 2
- 230000000857 drug effect Effects 0.000 description 2
- 238000007689 inspection Methods 0.000 description 2
- 238000011835 investigation Methods 0.000 description 2
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 2
- 150000002632 lipids Chemical class 0.000 description 2
- 235000019198 oils Nutrition 0.000 description 2
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- 230000003449 preventive effect Effects 0.000 description 2
- 230000001954 sterilising effect Effects 0.000 description 2
- 238000004659 sterilization and disinfection Methods 0.000 description 2
- HYZJCKYKOHLVJF-UHFFFAOYSA-N 1H-benzimidazole Chemical compound C1=CC=C2NC=NC2=C1 HYZJCKYKOHLVJF-UHFFFAOYSA-N 0.000 description 1
- DMAXMXPDVWTIRV-UHFFFAOYSA-N 2-(2-phenylethyl)phenol Chemical compound OC1=CC=CC=C1CCC1=CC=CC=C1 DMAXMXPDVWTIRV-UHFFFAOYSA-N 0.000 description 1
- RNMDNPCBIKJCQP-UHFFFAOYSA-N 5-nonyl-7-oxabicyclo[4.1.0]hepta-1,3,5-trien-2-ol Chemical compound C(CCCCCCCC)C1=C2C(=C(C=C1)O)O2 RNMDNPCBIKJCQP-UHFFFAOYSA-N 0.000 description 1
- 241000198596 Alternaria tomatophila Species 0.000 description 1
- 244000099147 Ananas comosus Species 0.000 description 1
- 235000007119 Ananas comosus Nutrition 0.000 description 1
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 1
- 240000008574 Capsicum frutescens Species 0.000 description 1
- KXDHJXZQYSOELW-UHFFFAOYSA-M Carbamate Chemical compound NC([O-])=O KXDHJXZQYSOELW-UHFFFAOYSA-M 0.000 description 1
- 229920002134 Carboxymethyl cellulose Polymers 0.000 description 1
- 229920000742 Cotton Polymers 0.000 description 1
- 241000223218 Fusarium Species 0.000 description 1
- 240000005979 Hordeum vulgare Species 0.000 description 1
- 235000007340 Hordeum vulgare Nutrition 0.000 description 1
- 244000017020 Ipomoea batatas Species 0.000 description 1
- 235000002678 Ipomoea batatas Nutrition 0.000 description 1
- 235000007688 Lycopersicon esculentum Nutrition 0.000 description 1
- 235000009811 Momordica charantia Nutrition 0.000 description 1
- 235000009812 Momordica cochinchinensis Nutrition 0.000 description 1
- 240000001740 Momordica dioica Species 0.000 description 1
- 235000018365 Momordica dioica Nutrition 0.000 description 1
- 240000005561 Musa balbisiana Species 0.000 description 1
- 235000018290 Musa x paradisiaca Nutrition 0.000 description 1
- 244000061176 Nicotiana tabacum Species 0.000 description 1
- 235000002637 Nicotiana tabacum Nutrition 0.000 description 1
- 239000006002 Pepper Substances 0.000 description 1
- 235000016761 Piper aduncum Nutrition 0.000 description 1
- 240000003889 Piper guineense Species 0.000 description 1
- 235000017804 Piper guineense Nutrition 0.000 description 1
- 235000008184 Piper nigrum Nutrition 0.000 description 1
- 239000004372 Polyvinyl alcohol Substances 0.000 description 1
- 206010039509 Scab Diseases 0.000 description 1
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 1
- 240000003768 Solanum lycopersicum Species 0.000 description 1
- 241001250070 Sporisorium reilianum Species 0.000 description 1
- 240000008042 Zea mays Species 0.000 description 1
- 235000005824 Zea mays ssp. parviglumis Nutrition 0.000 description 1
- 235000002017 Zea mays subsp mays Nutrition 0.000 description 1
- 125000003368 amide group Chemical group 0.000 description 1
- 239000003899 bactericide agent Substances 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 239000000440 bentonite Substances 0.000 description 1
- 229910000278 bentonite Inorganic materials 0.000 description 1
- SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 description 1
- OOCMUZJPDXYRFD-UHFFFAOYSA-L calcium;2-dodecylbenzenesulfonate Chemical compound [Ca+2].CCCCCCCCCCCCC1=CC=CC=C1S([O-])(=O)=O.CCCCCCCCCCCCC1=CC=CC=C1S([O-])(=O)=O OOCMUZJPDXYRFD-UHFFFAOYSA-L 0.000 description 1
- 239000001390 capsicum minimum Substances 0.000 description 1
- 239000001768 carboxy methyl cellulose Substances 0.000 description 1
- 235000010948 carboxy methyl cellulose Nutrition 0.000 description 1
- 239000008112 carboxymethyl-cellulose Substances 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 235000005822 corn Nutrition 0.000 description 1
- 239000013530 defoamer Substances 0.000 description 1
- 239000003599 detergent Substances 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 235000014113 dietary fatty acids Nutrition 0.000 description 1
- FPAFDBFIGPHWGO-UHFFFAOYSA-N dioxosilane;oxomagnesium;hydrate Chemical compound O.[Mg]=O.[Mg]=O.[Mg]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O FPAFDBFIGPHWGO-UHFFFAOYSA-N 0.000 description 1
- 239000007884 disintegrant Substances 0.000 description 1
- 229940079593 drug Drugs 0.000 description 1
- 239000004495 emulsifiable concentrate Substances 0.000 description 1
- 239000004497 emulsifiable granule Substances 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 239000000194 fatty acid Substances 0.000 description 1
- 229930195729 fatty acid Natural products 0.000 description 1
- 150000004665 fatty acids Chemical class 0.000 description 1
- 230000000855 fungicidal effect Effects 0.000 description 1
- 239000000417 fungicide Substances 0.000 description 1
- 238000005469 granulation Methods 0.000 description 1
- 230000003179 granulation Effects 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 231100000053 low toxicity Toxicity 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- LCRMGUFGEDUSOG-UHFFFAOYSA-N naphthalen-1-ylsulfonyloxymethyl naphthalene-1-sulfonate;sodium Chemical compound [Na].C1=CC=C2C(S(=O)(OCOS(=O)(=O)C=3C4=CC=CC=C4C=CC=3)=O)=CC=CC2=C1 LCRMGUFGEDUSOG-UHFFFAOYSA-N 0.000 description 1
- 230000000361 pesticidal effect Effects 0.000 description 1
- 229920002451 polyvinyl alcohol Polymers 0.000 description 1
- 229940088417 precipitated calcium carbonate Drugs 0.000 description 1
- 230000002265 prevention Effects 0.000 description 1
- 238000010298 pulverizing process Methods 0.000 description 1
- 230000029058 respiratory gaseous exchange Effects 0.000 description 1
- 238000005070 sampling Methods 0.000 description 1
- 229910000030 sodium bicarbonate Inorganic materials 0.000 description 1
- 235000017557 sodium bicarbonate Nutrition 0.000 description 1
- MZSDGDXXBZSFTG-UHFFFAOYSA-M sodium;benzenesulfonate Chemical compound [Na+].[O-]S(=O)(=O)C1=CC=CC=C1 MZSDGDXXBZSFTG-UHFFFAOYSA-M 0.000 description 1
- 235000014347 soups Nutrition 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 239000000375 suspending agent Substances 0.000 description 1
- 230000002195 synergetic effect Effects 0.000 description 1
- 230000009885 systemic effect Effects 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- 238000001238 wet grinding Methods 0.000 description 1
- 239000000080 wetting agent Substances 0.000 description 1
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- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The present invention discloses one kind of germicide composition containing azoxystrobin and thiophanate-methyl and its application. The composition contains azoxystrobin and thiophanate-methyl in the weight ratio of 2-30 to 10-70. The composition may be used in preventing and controlling diseases of grain crop, melons, fruits and vegetable, and has wide application range, low cost and high plant disease preventing and controlling effect.
Description
Technical field
The present invention relates to a kind of bactericidal composition and uses thereof, especially a kind of is the bactericidal composition and the application thereof of main active with Fluoxastrobin and thiophanate-methyl.
Background technology
Fluoxastrobin (Azoxystrobin) is a kind of brand-new bright olefin(e) acid lipid of β methoxyl group bactericide, and triple function is protected, treated and root out to tool, and the energy that destroys germ by the respiration that suppresses germ synthesizes and loss of life power.Crop safety that the Fluoxastrobin tool is good and very outstanding Environmental compatibility.For obtaining best preventive effect, in the dispenser of disease initial stage of origination, should note filling up the water yield during spraying, the crop surface soup is fully covered.
Fluoxastrobin is by Syngenta Co.,Ltd's development, and formulation products is that 25% Amici reaches suspending agent, is mainly used in control vegetables, diseases of garden stuff, because its drug cost height uses not extensive.
Thiophanate-methyl (thiophanate-methyl) is a kind of efficient, low toxicity sterilization punishment, and tool prevention and systemic action are because of medicament can change into the spirit of many mattresses after entering in the plant corpus, so also belong to benzimidazole.Can be widely used in multiple diseases such as grain, cotton, oil, vegetables, fruit tree.Can prevent and treat gibberella zeaze petch of wheat and barley, stinking smut, wheat powdery mildew, leaf blast disease, the rice sheath blight, sclerotinia rot of colza etc.Can be used for sweet potato black rot, the big leaf spot of corn, rice purple stalk disease, head smut of sorghum in addition.Thiophanate-methyl for a long time, repeatedly uses on Crop in China, and this makes the target germ strengthen gradually its resistance, and the cost that makes thiophanate-methyl prevent and treat disease increases and drug effect reduces greatly.
Summary of the invention
The objective of the invention is provides a kind of applied widely, plant sterilization composition that contains Fluoxastrobin and thiophanate-methyl that cost is low, effective at above-mentioned technical problem.
A further object of the invention provides the purposes of this bactericidal composition.
The objective of the invention is to realize by following measures:
A kind of bactericidal composition, it contains Fluoxastrobin and thiophanate-methyl, and wherein the weight ratio of Fluoxastrobin and thiophanate-methyl is 2～30: 10～70.
Described bactericidal composition, wherein the weight ratio of Fluoxastrobin and thiophanate-methyl is 10～25: 15～60.
Described bactericidal composition, wherein Fluoxastrobin and thiophanate-methyl and known auxiliary agent and excipient are re-dubbed any one formulation that allows on the agricultural chemicals.These known auxiliary agents, excipients have dispersant, diffusant, defoamer, wetting agent, disintegrant etc.
Described bactericidal composition, its formulation are pulvis, wetting powder, suspension emulsion, emulsifiable concentrate or granule.
The application of described bactericidal composition aspect control cereal class, melon and fruit or vegetable crop disease.
Beneficial effect of the present invention:
1, the used Fluoxastrobin of the present invention is the bright olefin(e) acid lipid of β methoxyl group, and thiophanate-methyl is a kind of carbamate fungicide, and both are mixed mutually and can produce conflict, but Synergistic reduces dosage, reduces cost.
2, the present composition scope of application increases, be applicable to the crop pest of control cereal class, various melon and fruit, vegetables, particularly prevent and treat crop pests such as paddy rice, wheat, capsicum, banana, mango, pineapple, cucumber, tomato, tobacco, as rice blast, sheath and culm blight, sclerotinia rot of colza, pepper anthracnose, balsam pear scab, scutellum rot of orange, powdery mildew of cucumber, early blight of tomato and late blight.
Embodiment
The invention will be further described below in conjunction with embodiment.The preparation method of formulation is conventional method among the embodiment.
Embodiment 1:
With Fluoxastrobin 2g, thiophanate-methyl 20g, calcium dodecyl benzene sulfonate 3g, phenethyl phenol polyethenoxy ether 2g, dimethylbenzene adds to 100g, is mixed to homogeneous phase liquid, makes composition missible oil.
Embodiment 2:
With Fluoxastrobin 5g, thiophanate-methyl 35g, detergent LS (to methoxyl group fatty acid amido benzene sulfonic acid sodium salt) 2g, dispersing agent NNO (sodium methylene bis-naphthalene sulfonate) 4g, white carbon 5g, kaolin adds to 100g, and mixture carries out comminution by gas stream, makes wetting powder.
Embodiment 3:
Fluoxastrobin 5g, thiophanate-methyl 50g, talcum powder 45g are mixed, make pulvis.
Embodiment 4:
Fluoxastrobin 3g, thiophanate-methyl 50g, dispersing agent NNO 5g, carboxymethyl cellulose 5g, precipitated calcium carbonate 37g are mixed, make wetting powder.
Embodiment 5:
Fluoxastrobin 5g, thiophanate-methyl 45g, polyoxyethylene nonylphenol ether 4g, dispersing agent NNO 3g, polyvinyl alcohol 1.2g, sodium bicarbonate 1g, bentonite 30g, kaolin are added to 100g, make the dispersibility granula through pulverizing granulation.
Application Example:
Test with the pesticidal preparations biocontrol of mango powdery mildew that the foregoing description makes.
1, test is handled: this test medicine consumption is established three concentration of treatment respectively according to the difference of each composition, but the contrast medicament is respectively commercially available agricultural chemicals 70% thiophanate-methyl wet-milling (WP) and 25% Fluoxastrobin aqueous suspension agent and the test of blank clear water.
2, each sub-district area of test method is no less than 2 strains for becoming the age fruit tree, repeats 3 times; Inspection drug effect method before the dispenser after investigation and the control is: investigation two strains every sub-district in, every strain by east, south, west, north, in 5 samplings, investigate 2 fringes at every, write down total spike number and sick spike number at different levels, inspection powdery mildew occurrence degree.
3, result of the test sees the following form:
| Handle (g/ mu) | Disease index (%) before the medicine | Preventive effect (%) | |||
| Behind the medicine 5 days | Behind the medicine 10 days | Behind the medicine 14 days | |||
| Embodiment 1 | 70 | 72.0 | 72.3ab | 79.2ab | 73.4ab |
| 80 | 78.6 | 86.4a | 90.5a | 81.3a | |
| 120 | 69.4 | 88.3a | 92.4a | 83.2a | |
| Embodiment 2 | 80 | 72.9 | 69.7ab | 77.4b | 70.5b |
| 90 | 50.8 | 79.6a | 83.2a | 80.4a | |
| 120 | 59.3 | 83.1a | 93.4a | 89.9a | |
| Embodiment 3 | 80 | 61.0 | 63.2ab | 71.9b | 69.3b |
| 100 | 57.3 | 79.5a | 85.2a | 84.2ab | |
| 130 | 56.6 | 83.3a | 89.4a | 86.9a | |
| 70% thiophanate-methyl WP | 200 | 62.3 | 62.2c | 65.2c | 49.1c |
| 25% Fluoxastrobin aqueous suspension agent | 100 | 60.3 | 63.7c | 65.8c | 59.9c |
| Blank clear water contrast | 63.2 | - | - | - | |
Annotate: a is illustrated on α=0.05 level remarkable, and b is illustrated on α=0.05 level variant, and c is illustrated on α=0.05 level not remarkable.
Field efficacy is the result show, Fluoxastrobin and thiophanate-methyl composition have good control efficiency to the mango powdery mildew, and control efficiency all is better than single agent kind.
Claims (5)
1. a bactericidal composition is characterized in that containing Fluoxastrobin and thiophanate-methyl, and wherein the weight ratio of Fluoxastrobin and thiophanate-methyl is 2～30: 10～70.
2. bactericidal composition according to claim 1, the weight ratio that it is characterized in that Fluoxastrobin and thiophanate-methyl is 10～25: 15～60.
3. bactericidal composition according to claim 1 and 2 is characterized in that Fluoxastrobin and thiophanate-methyl and known auxiliary agent and excipient are re-dubbed any one formulation that allows on the agricultural chemicals.
4. bactericidal composition according to claim 3 is characterized in that formulation is pulvis, wetting powder, suspension emulsion, missible oil or granule.
5. the application of the described bactericidal composition of claim 1 aspect the biocontrol of mango powdery mildew.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB2005100943872A CN100376158C (en) | 2005-09-15 | 2005-09-15 | Germicide composition containing azoxystrobin and thiophanate-methyl and its application |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB2005100943872A CN100376158C (en) | 2005-09-15 | 2005-09-15 | Germicide composition containing azoxystrobin and thiophanate-methyl and its application |
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| Publication Number | Publication Date |
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| CN1930983A CN1930983A (en) | 2007-03-21 |
| CN100376158C true CN100376158C (en) | 2008-03-26 |
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| CNB2005100943872A Expired - Fee Related CN100376158C (en) | 2005-09-15 | 2005-09-15 | Germicide composition containing azoxystrobin and thiophanate-methyl and its application |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103120170A (en) * | 2011-11-18 | 2013-05-29 | 深圳诺普信农化股份有限公司 | Bactericidal composition |
Families Citing this family (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2010015578A1 (en) * | 2008-08-04 | 2010-02-11 | Basf Se | Method for controlling fungal diseases in legumes |
| CN101647441B (en) * | 2009-07-31 | 2012-10-03 | 深圳诺普信农化股份有限公司 | Sterilization combination containing azoxystrobin and application thereof |
| CN101884334A (en) * | 2010-04-20 | 2010-11-17 | 陕西美邦农药有限公司 | Amistar and thiophanate methyl-containing bactericide composition |
| AU2015203091C1 (en) * | 2015-06-10 | 2016-03-31 | Rotam Agrochem International Company Limited | A synergistic composition comprising insecticides and fungicides |
| CN112136815A (en) * | 2020-10-27 | 2020-12-29 | 中诚国联（河南）生物科技有限公司 | Preparation and application of pesticide-fertilizer granules containing metalaxyl-M and azoxystrobin |
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|---|---|---|---|---|
| CN1157098A (en) * | 1996-02-16 | 1997-08-20 | 王学仁 | Compound ichthyodin, thiophanate-methyl mixture |
| CN1165617A (en) * | 1996-11-28 | 1997-11-26 | 江苏省新沂农药厂 | Jiameiling powder for prevention and treatment of multiple kinds of gray mold |
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2005
- 2005-09-15 CN CNB2005100943872A patent/CN100376158C/en not_active Expired - Fee Related
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1157098A (en) * | 1996-02-16 | 1997-08-20 | 王学仁 | Compound ichthyodin, thiophanate-methyl mixture |
| CN1165617A (en) * | 1996-11-28 | 1997-11-26 | 江苏省新沂农药厂 | Jiameiling powder for prevention and treatment of multiple kinds of gray mold |
| CN1211390A (en) * | 1998-08-19 | 1999-03-24 | 李景茹 | Compound bactericide 'Qubingte' and its preparation method |
Non-Patent Citations (1)
| Title |
|---|
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103120170A (en) * | 2011-11-18 | 2013-05-29 | 深圳诺普信农化股份有限公司 | Bactericidal composition |
| CN103120170B (en) * | 2011-11-18 | 2014-07-16 | 深圳诺普信农化股份有限公司 | Bactericidal composition |
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| Publication number | Publication date |
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| CN1930983A (en) | 2007-03-21 |
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