CN118389957A - Light high-corrosion-resistance steel bar and preparation method thereof - Google Patents
Light high-corrosion-resistance steel bar and preparation method thereof Download PDFInfo
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- 229910000831 Steel Inorganic materials 0.000 title claims abstract description 70
- 239000010959 steel Substances 0.000 title claims abstract description 70
- 238000002360 preparation method Methods 0.000 title abstract description 7
- 238000005260 corrosion Methods 0.000 claims abstract description 66
- 230000007797 corrosion Effects 0.000 claims abstract description 65
- 239000010935 stainless steel Substances 0.000 claims abstract description 45
- 238000005096 rolling process Methods 0.000 claims abstract description 39
- 238000000034 method Methods 0.000 claims abstract description 30
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 claims abstract description 19
- 238000009749 continuous casting Methods 0.000 claims abstract description 19
- 238000001816 cooling Methods 0.000 claims abstract description 19
- 239000012535 impurity Substances 0.000 claims abstract description 5
- 238000007670 refining Methods 0.000 claims abstract description 5
- 239000004567 concrete Substances 0.000 claims description 23
- 238000010438 heat treatment Methods 0.000 claims description 18
- 230000008569 process Effects 0.000 claims description 17
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 claims description 16
- 229910045601 alloy Inorganic materials 0.000 claims description 15
- 239000000956 alloy Substances 0.000 claims description 15
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 claims description 12
- XEEYBQQBJWHFJM-UHFFFAOYSA-N iron Substances [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 12
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 claims description 12
- 239000000243 solution Substances 0.000 claims description 11
- 238000002161 passivation Methods 0.000 claims description 9
- 238000010079 rubber tapping Methods 0.000 claims description 9
- 229910052782 aluminium Inorganic materials 0.000 claims description 8
- 238000005098 hot rolling Methods 0.000 claims description 8
- 229910052750 molybdenum Inorganic materials 0.000 claims description 8
- 239000011780 sodium chloride Substances 0.000 claims description 8
- 229910052786 argon Inorganic materials 0.000 claims description 6
- 238000007664 blowing Methods 0.000 claims description 6
- 229910052799 carbon Inorganic materials 0.000 claims description 6
- 229910052804 chromium Inorganic materials 0.000 claims description 6
- 229910052698 phosphorus Inorganic materials 0.000 claims description 6
- 230000001681 protective effect Effects 0.000 claims description 6
- 229910052717 sulfur Inorganic materials 0.000 claims description 6
- 238000005275 alloying Methods 0.000 claims description 5
- 238000005266 casting Methods 0.000 claims description 4
- 238000007654 immersion Methods 0.000 claims description 4
- 229910052742 iron Inorganic materials 0.000 claims description 4
- 239000012085 test solution Substances 0.000 claims description 4
- 229910000838 Al alloy Inorganic materials 0.000 claims description 3
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 3
- 229910000599 Cr alloy Inorganic materials 0.000 claims description 3
- 229910000640 Fe alloy Inorganic materials 0.000 claims description 3
- 229910000914 Mn alloy Inorganic materials 0.000 claims description 3
- 229910001182 Mo alloy Inorganic materials 0.000 claims description 3
- 238000005261 decarburization Methods 0.000 claims description 3
- 238000007872 degassing Methods 0.000 claims description 3
- 229910052748 manganese Inorganic materials 0.000 claims description 3
- 229910000604 Ferrochrome Inorganic materials 0.000 claims description 2
- 229910000616 Ferromanganese Inorganic materials 0.000 claims description 2
- 229910000519 Ferrosilicon Inorganic materials 0.000 claims description 2
- 229910000805 Pig iron Inorganic materials 0.000 claims description 2
- 241001062472 Stokellia anisodon Species 0.000 claims description 2
- UPHIPHFJVNKLMR-UHFFFAOYSA-N chromium iron Chemical compound [Cr].[Fe] UPHIPHFJVNKLMR-UHFFFAOYSA-N 0.000 claims description 2
- 239000002131 composite material Substances 0.000 claims description 2
- 230000003009 desulfurizing effect Effects 0.000 claims description 2
- 238000000265 homogenisation Methods 0.000 claims description 2
- 230000006698 induction Effects 0.000 claims description 2
- DALUDRGQOYMVLD-UHFFFAOYSA-N iron manganese Chemical compound [Mn].[Fe] DALUDRGQOYMVLD-UHFFFAOYSA-N 0.000 claims description 2
- 238000002844 melting Methods 0.000 claims description 2
- 230000008018 melting Effects 0.000 claims description 2
- 239000002893 slag Substances 0.000 claims description 2
- 238000005406 washing Methods 0.000 claims description 2
- 230000009467 reduction Effects 0.000 abstract description 6
- 238000003723 Smelting Methods 0.000 abstract description 4
- 238000004519 manufacturing process Methods 0.000 abstract description 4
- 238000004134 energy conservation Methods 0.000 abstract description 3
- 230000001737 promoting effect Effects 0.000 abstract description 3
- 239000000203 mixture Substances 0.000 description 9
- 238000013461 design Methods 0.000 description 7
- 230000000694 effects Effects 0.000 description 7
- 238000012360 testing method Methods 0.000 description 7
- 239000013535 sea water Substances 0.000 description 6
- 230000008901 benefit Effects 0.000 description 5
- 239000004576 sand Substances 0.000 description 5
- 239000011159 matrix material Substances 0.000 description 4
- 230000002411 adverse Effects 0.000 description 3
- 238000012423 maintenance Methods 0.000 description 3
- 150000001247 metal acetylides Chemical class 0.000 description 3
- 238000009628 steelmaking Methods 0.000 description 3
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 2
- 229910001566 austenite Inorganic materials 0.000 description 2
- 238000010276 construction Methods 0.000 description 2
- 229910052593 corundum Inorganic materials 0.000 description 2
- 238000011161 development Methods 0.000 description 2
- 230000018109 developmental process Effects 0.000 description 2
- SZVJSHCCFOBDDC-UHFFFAOYSA-N ferrosoferric oxide Chemical compound O=[Fe]O[Fe]O[Fe]=O SZVJSHCCFOBDDC-UHFFFAOYSA-N 0.000 description 2
- 229910052739 hydrogen Inorganic materials 0.000 description 2
- 150000004679 hydroxides Chemical class 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 239000011148 porous material Substances 0.000 description 2
- 239000000047 product Substances 0.000 description 2
- 239000011150 reinforced concrete Substances 0.000 description 2
- 150000003839 salts Chemical class 0.000 description 2
- 230000035945 sensitivity Effects 0.000 description 2
- 239000006104 solid solution Substances 0.000 description 2
- 229910001220 stainless steel Inorganic materials 0.000 description 2
- 238000005728 strengthening Methods 0.000 description 2
- 230000009466 transformation Effects 0.000 description 2
- 238000003466 welding Methods 0.000 description 2
- 229910001845 yogo sapphire Inorganic materials 0.000 description 2
- 229910000859 α-Fe Inorganic materials 0.000 description 2
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- 101100012902 Saccharomyces cerevisiae (strain ATCC 204508 / S288c) FIG2 gene Proteins 0.000 description 1
- 229910000870 Weathering steel Inorganic materials 0.000 description 1
- 230000032683 aging Effects 0.000 description 1
- 229910052787 antimony Inorganic materials 0.000 description 1
- 229910052785 arsenic Inorganic materials 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 229910052797 bismuth Inorganic materials 0.000 description 1
- 238000004210 cathodic protection Methods 0.000 description 1
- 150000001768 cations Chemical class 0.000 description 1
- 150000001805 chlorine compounds Chemical class 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
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- 238000009792 diffusion process Methods 0.000 description 1
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- 238000005516 engineering process Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
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- 230000005484 gravity Effects 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 238000009440 infrastructure construction Methods 0.000 description 1
- 230000009545 invasion Effects 0.000 description 1
- 229910052745 lead Inorganic materials 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 230000010534 mechanism of action Effects 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 229910001562 pearlite Inorganic materials 0.000 description 1
- 239000002244 precipitate Substances 0.000 description 1
- 238000010791 quenching Methods 0.000 description 1
- 230000000171 quenching effect Effects 0.000 description 1
- 230000005855 radiation Effects 0.000 description 1
- 230000004044 response Effects 0.000 description 1
- 238000005204 segregation Methods 0.000 description 1
- 238000005496 tempering Methods 0.000 description 1
- 229910052718 tin Inorganic materials 0.000 description 1
- 229910006540 α-FeOOH Inorganic materials 0.000 description 1
Classifications
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- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
- C22C38/22—Ferrous alloys, e.g. steel alloys containing chromium with molybdenum or tungsten
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21C—PROCESSING OF PIG-IRON, e.g. REFINING, MANUFACTURE OF WROUGHT-IRON OR STEEL; TREATMENT IN MOLTEN STATE OF FERROUS ALLOYS
- C21C7/00—Treating molten ferrous alloys, e.g. steel, not covered by groups C21C1/00 - C21C5/00
- C21C7/0006—Adding metallic additives
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21C—PROCESSING OF PIG-IRON, e.g. REFINING, MANUFACTURE OF WROUGHT-IRON OR STEEL; TREATMENT IN MOLTEN STATE OF FERROUS ALLOYS
- C21C7/00—Treating molten ferrous alloys, e.g. steel, not covered by groups C21C1/00 - C21C5/00
- C21C7/0075—Treating in a ladle furnace, e.g. up-/reheating of molten steel within the ladle
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21C—PROCESSING OF PIG-IRON, e.g. REFINING, MANUFACTURE OF WROUGHT-IRON OR STEEL; TREATMENT IN MOLTEN STATE OF FERROUS ALLOYS
- C21C7/00—Treating molten ferrous alloys, e.g. steel, not covered by groups C21C1/00 - C21C5/00
- C21C7/04—Removing impurities by adding a treating agent
- C21C7/06—Deoxidising, e.g. killing
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21C—PROCESSING OF PIG-IRON, e.g. REFINING, MANUFACTURE OF WROUGHT-IRON OR STEEL; TREATMENT IN MOLTEN STATE OF FERROUS ALLOYS
- C21C7/00—Treating molten ferrous alloys, e.g. steel, not covered by groups C21C1/00 - C21C5/00
- C21C7/04—Removing impurities by adding a treating agent
- C21C7/068—Decarburising
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21C—PROCESSING OF PIG-IRON, e.g. REFINING, MANUFACTURE OF WROUGHT-IRON OR STEEL; TREATMENT IN MOLTEN STATE OF FERROUS ALLOYS
- C21C7/00—Treating molten ferrous alloys, e.g. steel, not covered by groups C21C1/00 - C21C5/00
- C21C7/10—Handling in a vacuum
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D8/00—Modifying the physical properties by deformation combined with, or followed by, heat treatment
- C21D8/06—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of rods or wires
- C21D8/08—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of rods or wires for concrete reinforcement
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C33/00—Making ferrous alloys
- C22C33/04—Making ferrous alloys by melting
- C22C33/06—Making ferrous alloys by melting using master alloys
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- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/02—Ferrous alloys, e.g. steel alloys containing silicon
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- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/04—Ferrous alloys, e.g. steel alloys containing manganese
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- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/06—Ferrous alloys, e.g. steel alloys containing aluminium
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- Chemical & Material Sciences (AREA)
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- Metallurgy (AREA)
- Organic Chemistry (AREA)
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- Thermal Sciences (AREA)
- Crystallography & Structural Chemistry (AREA)
- Heat Treatment Of Steel (AREA)
Abstract
Description
技术领域Technical Field
本发明涉及建筑结构用钢筋制造技术领域,尤其涉及在深远海严酷海洋环境建筑结构用钢筋。The invention relates to the technical field of manufacturing steel bars for building structures, in particular to steel bars for building structures in deep sea and harsh marine environments.
背景技术Background technique
海洋具有丰富的资源,加快海洋开发将缓解陆地资源的不断消耗。钢筋混凝土结构是基础设施建设中应用最为广泛的结构形式,海洋的特定环境因素对建筑结构的服役性能提出很多特殊要求。特别在高盐雾、高湿热、强辐射等严酷环境下,嵌入在混凝土结构中的普通钢筋很容易受到氯化物引起的损害,不仅会增加维护费用而且存在结构失效的风险。针对钢筋锈蚀问题,阴极保护、表面改性处理、镀层保护等防护措施和技术存在施工困难、易老化失效、维护成本高等一系列问题。因此,综合考虑服役性能及综合成本,提高钢筋基体的耐蚀能力是解决问题的根本途径。不锈钢筋具有优异的耐蚀性能,可保证钢筋混凝土结构长期使用寿命。但是不锈钢因含有过多合金元素、存在可焊接性差、初期生产成本高昂的问题,因此难以进行大规模工程应用。The ocean is rich in resources, and accelerating the development of the ocean will ease the continuous consumption of land resources. Reinforced concrete structure is the most widely used structural form in infrastructure construction. The specific environmental factors of the ocean put forward many special requirements for the service performance of building structures. Especially in harsh environments such as high salt fog, high humidity and heat, and strong radiation, ordinary steel bars embedded in concrete structures are easily damaged by chlorides, which not only increases maintenance costs but also poses a risk of structural failure. In response to the problem of steel corrosion, protective measures and technologies such as cathodic protection, surface modification, and coating protection have a series of problems such as construction difficulties, easy aging and failure, and high maintenance costs. Therefore, considering the service performance and comprehensive cost, improving the corrosion resistance of the steel matrix is the fundamental way to solve the problem. Stainless steel bars have excellent corrosion resistance and can ensure the long-term service life of reinforced concrete structures. However, stainless steel is difficult to be applied in large-scale engineering projects because it contains too many alloy elements, has poor weldability, and has high initial production costs.
开发和应用轻质高耐蚀钢筋可以在保证建筑结构用钢筋质量安全的基础上,不仅可以延长建筑物的使用寿命和减少维护成本,而且有利于节省施工工作量及物质资源消耗,对促进相关产业的节能、降耗和减排具有重要的实际意义。The development and application of lightweight and highly corrosion-resistant steel bars can not only extend the service life of buildings and reduce maintenance costs while ensuring the quality and safety of steel bars used in building structures, but also help save construction workload and material resource consumption. It has important practical significance for promoting energy conservation, consumption reduction and emission reduction in related industries.
因此,为克服现有技术的不足,有必要研究轻质高耐蚀钢筋及其制备方法来解决或减轻上述一个或多个问题。Therefore, in order to overcome the deficiencies of the prior art, it is necessary to study lightweight and highly corrosion-resistant steel bars and preparation methods thereof to solve or alleviate one or more of the above problems.
发明内容Summary of the invention
本发明旨在提供一种轻质高耐蚀钢筋及其制备方法,通过添加Cr、Al和Mo等元素,设计开发出轻质高耐蚀钢筋,在满足严酷海洋环境建筑结构用钢使用性能的条件下尽可能降低密度进而缩减成本。The present invention aims to provide a lightweight and highly corrosion-resistant steel bar and a preparation method thereof. By adding elements such as Cr, Al and Mo, a lightweight and highly corrosion-resistant steel bar is designed and developed, and the density is reduced as much as possible while meeting the performance requirements of steel used in building structures in harsh marine environments, thereby reducing costs.
为达到上述目的,本发明采用如下的技术方案:In order to achieve the above object, the present invention adopts the following technical solution:
一种轻质高耐蚀钢筋,其特征在于,各成分的质量百分比为:C≤0.05%,Cr 4.5~8.5%,Al 2.0~6.0%,Mo 0.5~0.8%,Mn 1.0~1.2%,Si 0.2~0.4%,P≤0.006%,S≤0.006%,其余为Fe及不可避免的杂质。A lightweight and highly corrosion-resistant steel bar, characterized in that the mass percentages of the components are: C≤0.05%, Cr 4.5-8.5%, Al 2.0-6.0%, Mo 0.5-0.8%, Mn 1.0-1.2%, Si 0.2-0.4%, P≤0.006%, S≤0.006%, and the rest are Fe and unavoidable impurities.
进一步地,所述钢筋密度可降低3~9%,力学性能指标为:屈服强度≥500 MPa,抗拉强度≥630 MPa,断后伸长率A≥20%,最大力下总伸长率Agt≥10.0%。Furthermore, the density of the steel bar can be reduced by 3-9%, and the mechanical performance indicators are: yield strength ≥500 MPa, tensile strength ≥630 MPa, elongation after fracture A ≥20%, and total elongation under maximum force Agt ≥10.0%.
进一步地,所述钢筋耐腐蚀性能指标为:在碱度为pH=13.0±0.2的典型混凝土中,所述的轻质高耐蚀钢筋的临界氯离子浓度为3.20~3.80 mol/L,其抗氯离子能力是普通钢筋HRB500的16~20倍。Furthermore, the corrosion resistance index of the steel bar is: in a typical concrete with an alkalinity of pH=13.0±0.2, the critical chloride ion concentration of the lightweight and highly corrosion-resistant steel bar is 3.20-3.80 mol/L, and its chloride ion resistance is 16-20 times that of ordinary steel bar HRB500.
进一步地,所述钢筋耐腐蚀性能指标为:在预含氯化物的混凝土环境中(例如用海水拌合的海砂混凝土),所述的轻质高耐蚀钢筋仍能保持稳定的钝化。Furthermore, the corrosion resistance performance index of the steel bar is: in a concrete environment pre-containing chloride (such as sea sand concrete mixed with seawater), the lightweight and highly corrosion-resistant steel bar can still maintain stable passivation.
进一步地,所述钢筋耐腐蚀性能指标为:按照YB/T 4367对高耐蚀钢筋进行检验,试验溶液采用高于标准的初始浓度为5.0%的氯化钠溶液、YB/T 4367规定的质量分数为2.00%±0.05%,溶液温度为45℃±2℃,湿度为70%RH±10%RH,循环周期为60min±5min,其中浸润时间为12min±2min; 依据GB/T 34206-2017计算相对腐蚀速率,相对腐蚀速率是GB/T 1499.2-2018中HRB500的8.0%以下。Furthermore, the corrosion resistance performance index of the steel bar is: the high corrosion resistant steel bar is inspected according to YB/T 4367, the test solution adopts a sodium chloride solution with an initial concentration of 5.0% higher than the standard, the mass fraction specified in YB/T 4367 is 2.00%±0.05%, the solution temperature is 45°C±2°C, the humidity is 70%RH±10%RH, the cycle period is 60min±5min, and the immersion time is 12min±2min; the relative corrosion rate is calculated according to GB/T 34206-2017, and the relative corrosion rate is less than 8.0% of HRB500 in GB/T 1499.2-2018.
进一步地,所述钢筋耐腐蚀性能指标为:腐蚀360h后锈层平均厚度低于100μm,与HRB500平均厚度300μm的锈层相比具有很小的体积膨胀。Furthermore, the steel bar corrosion resistance index is: the average thickness of the rust layer after 360 hours of corrosion is less than 100 μm, and the volume expansion is very small compared with the average thickness of the rust layer of HRB500 of 300 μm.
一种如权利要求上所述的轻质高耐蚀钢筋的制备方法,包括以下步骤:A method for preparing a lightweight and highly corrosion-resistant steel bar as claimed in claim 1, comprising the following steps:
S1、采用真空感应炉按既定的元素质量百分比进行冶炼;S1. Use vacuum induction furnace to smelt according to the established element mass percentage;
S2、LF-RH精炼;S2, LF-RH refining;
S3、热连轧或连铸控轧;S3, hot rolling or continuous casting controlled rolling;
S4、控温冷却。S4, temperature control cooling.
进一步地,所述S1的具体过程包括:将铁水进行预脱硫,之后将废钢、铁水及生铁加入转炉进行顶底复合吹炼;出钢时采用渣洗及全程底吹氩,出钢温度>1600 ℃;之后向钢包中加入脱氧剂、高碳锰铁、硅铁和铬铁完成初步脱氧合金化以提高效率。Furthermore, the specific process of S1 includes: pre-desulfurizing the molten iron, then adding scrap steel, molten iron and pig iron into the converter for top and bottom composite blowing; using slag washing and bottom argon blowing throughout the steelmaking process, and the steelmaking temperature is greater than 1600°C; then adding deoxidizer, high carbon ferromanganese, ferrosilicon and ferrochrome into the ladle to complete preliminary deoxidation and alloying to improve efficiency.
进一步地,所述S2的具体过程包括:LF炉的钢包加入Cr、Al、Mn和Mo合金元素,以100~120 L/min的氩气流量进行全程底吹,保证钢包内合金熔解及均匀化,出钢温度为>1550 ℃;在RH炉中进行脱气脱碳,同时加入微碳铬铁合金以对钢水进一步合金化调控使得各元素含量控制到合适范围内;当真空度<2 mbar时进行>10 min净循环处理,出钢温度>1550 ℃。Furthermore, the specific process of S2 includes: adding Cr, Al, Mn and Mo alloy elements to the ladle of the LF furnace, and performing bottom blowing throughout the process with an argon flow rate of 100-120 L/min to ensure the melting and homogenization of the alloy in the ladle, and the steel-out temperature is >1550°C; degassing and decarburization are carried out in the RH furnace, and at the same time, micro-carbon chromium-iron alloy is added to further alloy the molten steel so that the content of each element is controlled within an appropriate range; when the vacuum degree is <2 mbar, a net circulation treatment of >10 min is carried out, and the steel-out temperature is >1550°C.
进一步地,所述S3的具体过程包括:将所述RH炉精炼后的钢水在保护浇注条件下通过连铸机浇注成铸坯;连铸过程中温度控制在1540~1560 ℃,拉速控制在2.0~2.5 m/min;所述S3的热连轧工序,加热炉温度>1150℃,开轧温度960~1100℃;控制轧制过程包括粗轧和精轧,将连铸所得钢坯在加热炉中进行加热,加热温度>1150℃,加热时间>2 h以保证合金元素得到充分回溶;轧制过程中粗轧温度960~1050 ℃,精轧温度830~940℃,轧制速度为15~20 m/s,而后轧制成直径为10~40 mm的钢筋。Furthermore, the specific process of S3 includes: casting the molten steel refined by the RH furnace into a cast billet through a continuous casting machine under protective casting conditions; during the continuous casting process, the temperature is controlled at 1540-1560°C, and the pulling speed is controlled at 2.0-2.5 m/min; in the hot rolling process of S3, the heating furnace temperature is greater than 1150°C, and the start rolling temperature is 960-1100°C; the rolling process is controlled to include rough rolling and finish rolling, and the billet obtained by continuous casting is heated in a heating furnace, the heating temperature is greater than 1150°C, and the heating time is greater than 2 h to ensure that the alloy elements are fully dissolved back; during the rolling process, the rough rolling temperature is 960-1050°C, the finish rolling temperature is 830-940°C, the rolling speed is 15-20 m/s, and then rolled into steel bars with a diameter of 10-40 mm.
进一步地,所述S4的具体过程包括:将轧制而成的钢筋以>5 ℃/s的冷速加速冷却至400 ℃以下,之后在冷床上进行自然冷却。Furthermore, the specific process of S4 includes: accelerating cooling the rolled steel bar to below 400° C. at a cooling rate of >5° C./s, and then cooling it naturally on a cooling bed.
与现有技术相比,本发明可以获得以下技术效果:本发明的轻质高耐蚀钢筋可降低3%~9%的密度,在典型混凝土环境中,抗氯离子能力是普通钢筋HRB500的16~20倍;在预含氯化物的混凝土环境中(例如用海水拌合的海砂混凝土),所述的轻质高耐蚀钢筋仍能保持稳定的钝化;在严苛的5.0%的氯化钠环境中相对HRB500腐蚀速率低于8%,且腐蚀360h后锈层平均厚度低于100μm,与HRB500平均厚度300μm的锈层相比具有很小的体积膨胀。在保证服役性能要求的同时不仅可以实现长使用寿命周期,而且能实现整体成本的最小化。对促进相关产业的节能、降耗及减排具有重要的实际意义,在近远海等严酷海洋环境海上工程中具有广阔的应用前景。Compared with the prior art, the present invention can obtain the following technical effects: the lightweight high corrosion resistant steel bar of the present invention can reduce the density by 3% to 9%, and in a typical concrete environment, the chloride ion resistance is 16 to 20 times that of ordinary steel bar HRB500; in a concrete environment containing chloride (such as sea sand concrete mixed with seawater), the lightweight high corrosion resistant steel bar can still maintain stable passivation; in a harsh 5.0% sodium chloride environment, the relative corrosion rate of HRB500 is less than 8%, and the average thickness of the rust layer after corrosion for 360 hours is less than 100μm, which has a very small volume expansion compared with the average thickness of 300μm of the rust layer of HRB500. While ensuring the service performance requirements, it can not only achieve a long service life cycle, but also minimize the overall cost. It has important practical significance for promoting energy conservation, consumption reduction and emission reduction in related industries, and has broad application prospects in offshore engineering in harsh marine environments such as near and far seas.
当然,实施本发明的任一产品并不一定需要同时达到以上所述的所有技术效果。Of course, any product implementing the present invention does not necessarily need to achieve all of the above-mentioned technical effects at the same time.
附图说明BRIEF DESCRIPTION OF THE DRAWINGS
图1为本发明工艺流程图;Fig. 1 is a process flow chart of the present invention;
图2在混凝土孔隙液体(pH=13.5±0.2)钝化后加入1.0mol/L氯化钠浸泡半年后拍摄的试样表面,(a-实施例1,b-实施例2,C-HRB500)。FIG2 is a photograph of the sample surface after being passivated by the concrete pore liquid (pH=13.5±0.2) and immersed for half a year in 1.0 mol/L sodium chloride (a-Example 1, b-Example 2, C-HRB500).
具体实施方式Detailed ways
为了使本发明的技术方案和优点更加清晰,下面结合图表对本发明的具体实施例进行详细描述。应当指出,本说明书中提及的任一特征描述均可被其他等效或类似的替代特征描述加以替换,除非特别描述,否则任一特征描述仅是整个系列等效或具有类似目的特征描述的个例。所述的实施例仅用以解释和帮助理解本发明,并不用于具体限定本发明。In order to make the technical solutions and advantages of the present invention clearer, the specific embodiments of the present invention are described in detail below in conjunction with the diagrams. It should be noted that any feature description mentioned in this specification can be replaced by other equivalent or similar alternative feature descriptions. Unless otherwise specified, any feature description is only an example of the entire series of equivalent or similar purpose feature descriptions. The embodiments described are only used to explain and help understand the present invention, and are not used to specifically limit the present invention.
本发明运用低碳合金化原理设计钢种成分,采用转炉冶炼-精炼-热连轧或连铸控轧工艺制备成型,并加以合适的控温冷却工艺使钢筋具有良好的力学性能和耐蚀性能。The present invention adopts the low-carbon alloying principle to design the steel composition, adopts converter smelting-refining-hot rolling or continuous casting controlled rolling process to prepare and shape, and adds a suitable temperature control cooling process to make the steel bar have good mechanical properties and corrosion resistance.
一种轻质高耐蚀钢筋,所述高耐蚀钢筋各成分的质量百分比为:C≤0.05%,Cr 4.5~8.5%,Al 2.0~6.0%,Mo 0.5~0.8%,Mn 1.0~1.2%,Si 0.2~0.4%,P≤0.006%,S≤0.006%,其余为Fe及杂质;A lightweight high-corrosion-resistant steel bar, wherein the mass percentages of the components of the high-corrosion-resistant steel bar are: C≤0.05%, Cr 4.5-8.5%, Al 2.0-6.0%, Mo 0.5-0.8%, Mn 1.0-1.2%, Si 0.2-0.4%, P≤0.006%, S≤0.006%, and the rest are Fe and impurities;
上述轻质高耐蚀钢筋的制备方法,步骤包括:The method for preparing the above-mentioned lightweight and highly corrosion-resistant steel bar comprises the following steps:
步骤1、按上述设计成分进行冶炼;Step 1, smelting according to the above designed composition;
步骤2、对钢水进行LF-RH精炼,LF炉的钢包加入Cr、Al、Mn和Mo合金元素,在RH炉中进行脱气脱碳,并加入微铬铁合金以对钢水进一步合金化调控,将各元素含量控制在所需范围内,出钢温度>1550 ℃。Step 2: LF-RH refining is performed on the molten steel. Cr, Al, Mn and Mo alloy elements are added to the ladle of the LF furnace, and degassing and decarburization are performed in the RH furnace. Micro-chromium-iron alloy is added to further alloy the molten steel, and the content of each element is controlled within the required range. The tapping temperature is greater than 1550°C.
步骤3、连铸工艺包括:连铸过程中温度控制在1540~1560 ℃,拉速控制在2.0~2.5 m/min;热连轧工序包括:加热炉温度>1150℃,开轧温度960~1100℃;控制轧制过程:加热温度>1150℃,加热时间>2 h以保证合金元素得到充分回溶;轧制过程中粗轧温度960~1050 ℃,精轧温度830~940 ℃,轧制速度为15~20 m/s,而后轧制成直径为10~40mm的钢筋。Step 3, the continuous casting process includes: the temperature during the continuous casting process is controlled at 1540-1560°C, and the pulling speed is controlled at 2.0-2.5 m/min; the hot rolling process includes: the heating furnace temperature is greater than 1150°C, and the start rolling temperature is 960-1100°C; the rolling process is controlled: the heating temperature is greater than 1150°C, and the heating time is greater than 2 h to ensure that the alloy elements are fully dissolved back; during the rolling process, the rough rolling temperature is 960-1050°C, the finishing rolling temperature is 830-940°C, and the rolling speed is 15-20 m/s, and then rolled into steel bars with a diameter of 10-40 mm.
步骤4、轧后钢筋需进行控温冷却。综合考虑性能指标要求,将轧制而成的钢筋以>5 ℃/s的冷速加速冷却至400 ℃以下,之后在冷床上进行自然冷却。Step 4: The rolled steel bars need to be cooled under controlled temperature. Taking into account the performance index requirements, the rolled steel bars are cooled at a cooling rate of >5°C/s to below 400°C, and then cooled naturally on the cooling bed.
制备的轻质高耐蚀钢筋,密度可降低3%~9%的密度,其屈服强度≥500 MPa,抗拉强度≥630 MPa,断后伸长率A≥20%,最大力下总伸长率Agt≥10.0%。在典型混凝土环境中,抗氯离子能力是普通钢筋HRB500的16~20倍;在预含氯化物的混凝土环境中(例如用海水拌合的海砂混凝土),所述的轻质高耐蚀钢筋仍能保持稳定的钝化;在严苛的5.0%的氯化钠环境中相对HRB500腐蚀速率低于8%,且腐蚀360h后锈层平均厚度低于100μm,与HRB500平均厚度300μm的锈层相比具有很小的体积膨胀。The prepared lightweight and highly corrosion-resistant steel bar can reduce the density by 3% to 9%, and its yield strength is ≥500 MPa, tensile strength is ≥630 MPa, elongation after fracture A is ≥20%, and total elongation under maximum force Agt is ≥10.0%. In a typical concrete environment, the chloride ion resistance is 16 to 20 times that of ordinary steel bar HRB500; in a concrete environment containing chloride (such as sea sand concrete mixed with seawater), the lightweight and highly corrosion-resistant steel bar can still maintain stable passivation; in a harsh 5.0% sodium chloride environment, the corrosion rate relative to HRB500 is less than 8%, and the average thickness of the rust layer after 360 hours of corrosion is less than 100μm, which has a very small volume expansion compared with the average thickness of 300μm of the rust layer of HRB500.
本发明的轻质高耐蚀钢筋中各合金成分的作用机理如下:The mechanism of action of each alloy component in the lightweight and highly corrosion-resistant steel bar of the present invention is as follows:
C:钢筋的力学性能和耐蚀性能均受C元素的影响。C元素含量过高会以碳化物的形式析出。碳化物不仅会降低延伸率和冲击塑性等对力学性能产生不利影响,而且会诱发晶间腐蚀。而且,碳含量较高会消耗基体中的Cr形成含Cr碳化物,不仅降低合金化的效果,而且会显著降低钢材的抗腐蚀能力。因此,在耐蚀性钢种的成分设计过程中要严格控制基体中C含量。C: The mechanical properties and corrosion resistance of steel bars are affected by the C element. If the C content is too high, it will precipitate in the form of carbides. Carbides will not only reduce the elongation and impact plasticity and have an adverse effect on mechanical properties, but also induce intergranular corrosion. Moreover, a high carbon content will consume the Cr in the matrix to form Cr-containing carbides, which will not only reduce the alloying effect, but also significantly reduce the corrosion resistance of the steel. Therefore, the C content in the matrix must be strictly controlled during the composition design of corrosion-resistant steel grades.
Cr: Cr含量越高钢的钝化能力和耐腐蚀性能显著增强。稳定的Cr氧化物或氢氧化物具有优异的钝化性能,不仅可以保护基体免受介质侵蚀,而且具有阳离子选择性,能进一步抑制Cl-的侵入。同时,在例如混凝土环境碱性条件下Cr氧化物或氢氧化物能促进体积膨胀较大的α-FeOOH向体积膨胀较小的Fe3O4的转变。钢筋即使发生腐蚀,也能实现在混凝土中较小的腐蚀膨胀,降低了结构腐蚀失效的破坏程度。Cr: The higher the Cr content, the more significantly the passivation ability and corrosion resistance of the steel are enhanced. Stable Cr oxides or hydroxides have excellent passivation properties, which can not only protect the matrix from medium corrosion, but also have cation selectivity, which can further inhibit the invasion of Cl- . At the same time, under alkaline conditions such as concrete environment, Cr oxides or hydroxides can promote the transformation of α-FeOOH with larger volume expansion to Fe3O4 with smaller volume expansion. Even if the steel bar corrodes, it can achieve smaller corrosion expansion in the concrete, reducing the degree of damage caused by structural corrosion failure.
Al:Al的添加能够显著降低钢的密度,将Al含量增加1wt.%,比重可减少约1.5%。电化学稳定性更高的Al2O3不仅可以延长钢筋的钝化时间,而且能有效阻止腐蚀的进一步发生。典型的耐海水腐蚀钢10CrMoAl证明Al2O3保护膜既防腐又耐腐。Al: The addition of Al can significantly reduce the density of steel. Increasing the Al content by 1wt.% can reduce the specific gravity by about 1.5%. Al2O3 with higher electrochemical stability can not only prolong the passivation time of steel bars, but also effectively prevent further corrosion. The typical seawater corrosion-resistant steel 10CrMoAl proves that the Al2O3 protective film is both anti-corrosion and corrosion-resistant.
Mo:Mo具有优异的耐点蚀能力,会生成含Mo不溶性盐富集在腐蚀产物膜中会促进非晶态氧化膜形成进而抑制点蚀。Mo含量过低,提高钢的耐点蚀性能效果不明显;Mo含量过高,钢的耐点蚀性能提高,但会增加成本。Mo: Mo has excellent pitting corrosion resistance. It will generate Mo-containing insoluble salts that are enriched in the corrosion product film, promote the formation of amorphous oxide film, and then inhibit pitting corrosion. If the Mo content is too low, the effect of improving the pitting corrosion resistance of steel is not obvious; if the Mo content is too high, the pitting corrosion resistance of steel is improved, but the cost will increase.
Mn: Mn是奥氏体形成和固溶强化元素,可以提高强度。但是,Mn含量过高会与S结合形成MnS夹杂物不仅会影响钢筋的塑性、冲击韧性、焊接性能,而且会增加点蚀的敏感性。因此,应适当控制Mn含量在合理范围。Mn: Mn is an austenite forming and solid solution strengthening element, which can improve strength. However, if the Mn content is too high, it will combine with S to form MnS inclusions, which will not only affect the plasticity, impact toughness and welding performance of the steel bar, but also increase the sensitivity to pitting corrosion. Therefore, the Mn content should be properly controlled within a reasonable range.
Si:Si固溶于铁素体能起到固溶强化作用,同时能抑制C元素在奥氏体中的扩散、延迟铁素体和珠光体相变,提升钢筋的屈服强度和抗拉强度;然而Si含量过高会降低钢材的塑性,劣化钢筋的焊接性能,因此其含量应控制在合理范围。Si: Si dissolved in ferrite can play a role in solid solution strengthening. At the same time, it can inhibit the diffusion of C element in austenite, delay the phase transformation of ferrite and pearlite, and improve the yield strength and tensile strength of steel bars. However, too high Si content will reduce the plasticity of steel and deteriorate the welding performance of steel bars, so its content should be controlled within a reasonable range.
P和S:从力学性能角度来看,P会降低钢的塑性和韧性,而且会导致调质回火脆性、冷脆等问题,并且对热加工性和焊接性也有不利影响。S会增加冷热裂纹敏感性从而对抗氢脆能力产生不利影响。从大气腐蚀角度看,P是阳极去极化剂,能加速钢的均匀溶解和Fe2+的氧化速度,进而显著提高耐候钢的耐蚀性。但是,此外,P和S易导致成分偏析,含P、S元素的夹杂物会诱发点蚀等局部腐蚀,因此需要尽可能降低其在钢中的含量。P and S: From the perspective of mechanical properties, P will reduce the plasticity and toughness of steel, and will cause problems such as quenching and tempering brittleness and cold brittleness, and will also have an adverse effect on hot workability and weldability. S will increase the sensitivity to hot and cold cracks, thereby adversely affecting the ability to resist hydrogen embrittlement. From the perspective of atmospheric corrosion, P is an anodic depolarizer that can accelerate the uniform dissolution of steel and the oxidation rate of Fe 2+ , thereby significantly improving the corrosion resistance of weathering steel. However, in addition, P and S are prone to cause component segregation, and inclusions containing P and S elements will induce localized corrosion such as pitting corrosion, so it is necessary to reduce its content in steel as much as possible.
不可避免的杂质元素主要指 O、H和Pb、Sn、As、Sb、Bi等有害元素。The inevitable impurity elements mainly refer to O, H and harmful elements such as Pb, Sn, As, Sb, and Bi.
本发明通过添加Cr、Al和Mo等元素,设计开发出轻质高耐蚀钢筋,在满足海严酷海洋环境用高耐蚀钢筋使用性能的条件下尽可能缩减整体工程成本。The present invention designs and develops lightweight high corrosion-resistant steel bars by adding elements such as Cr, Al and Mo, thereby reducing the overall engineering cost as much as possible while meeting the performance requirements of high corrosion-resistant steel bars for harsh marine environments.
本发明提供一种轻质高耐蚀钢筋制造方法,本方法各实施例制备步骤包括:炼钢、LF-RH精炼、热连轧或连铸控轧、控温冷却。The present invention provides a method for manufacturing lightweight and highly corrosion-resistant steel bars. The preparation steps of each embodiment of the method include: steelmaking, LF-RH refining, hot rolling or continuous casting controlled rolling, and temperature-controlled cooling.
实施例1、2,具体包括以下步骤:Embodiment 1 and 2 specifically include the following steps:
步骤1、按表1中的成分进行冶炼,出钢温度为>1610 ℃,优选出钢温度为1610℃。Step 1: Smelting is performed according to the composition in Table 1, and the tapping temperature is > 1610°C, preferably 1610°C.
步骤2、LF炉的钢包中以100~120 L/min的氩气流量进行全程底吹,优选100 L/min,出钢温度为>1550 ℃,优选1560 ℃;在RH炉中当真空度<2 mbar时进行>5 min净循环处理,优选8 min,出钢温度>1550 ℃,优选1560 ℃。此步骤要保证钢包内合金溶解及均匀化,将各元素含量控制在设计范围内。Step 2: In the ladle of the LF furnace, the argon flow rate is 100-120 L/min, preferably 100 L/min, and the tapping temperature is >1550°C, preferably 1560°C; in the RH furnace, when the vacuum degree is <2 mbar, a net circulation treatment is performed for >5 min, preferably 8 min, and the tapping temperature is >1550°C, preferably 1560°C. This step is to ensure that the alloy in the ladle is dissolved and homogenized, and the content of each element is controlled within the design range.
步骤3、在保护浇注条件下将钢水通过连铸机浇注成连铸坯,温度控制在1540~1560 ℃,优选1540 ℃,拉速控制在2.0~2.5 m/min,优选2.5 m/min。将连铸所得钢坯在加热炉中进行加热,加热温度>1150℃,优选1150 ℃,加热时间>2.0 h以保证合金元素得到充分回溶,优选2.0 h。轧制过程中轧制过程中粗轧温度960~1050 ℃,优选1050 ℃,精轧温度830~940 ℃,优选900 ℃,轧制速度控制在15~20 m/s,优选15 m/s。Step 3: Under protective pouring conditions, the molten steel is poured into a continuous casting billet through a continuous casting machine, the temperature is controlled at 1540-1560 ° C, preferably 1540 ° C, and the pulling speed is controlled at 2.0-2.5 m/min, preferably 2.5 m/min. The billet obtained by continuous casting is heated in a heating furnace, the heating temperature is greater than 1150 ° C, preferably 1150 ° C, and the heating time is greater than 2.0 h to ensure that the alloy elements are fully dissolved, preferably 2.0 h. During the rolling process, the rough rolling temperature is 960-1050 ° C, preferably 1050 ° C, the finishing rolling temperature is 830-940 ° C, preferably 900 ° C, and the rolling speed is controlled at 15-20 m/s, preferably 15 m/s.
步骤4、对轧后钢筋需进行控温冷却处理。将轧制而成的钢筋以>5 ℃/s的冷速加速冷却至400 ℃以下,之后在冷床上进行自然冷却。Step 4: The rolled steel bars need to be cooled under controlled temperature. The rolled steel bars are cooled at a cooling rate of >5°C/s to below 400°C, and then cooled naturally on a cooling bed.
根据上述实施方法的轻质高耐蚀钢筋其强度、塑性测试结果如表2所示。The strength and plasticity test results of the lightweight and highly corrosion-resistant steel bars according to the above implementation method are shown in Table 2.
对实施例1和2进行耐蚀性测试,在典型混凝土(pH=13.5±0.2)中,实施例1的临界氯离子浓度为4.0 mol/L,实施例2的临界氯离子浓度为3.70 mol/L。在预含氯化物的混凝土环境中(例如用海水拌合的海砂混凝土),实施例1和2仍能保持稳定的钝化。依据GB/T33953-2017中对钢筋耐腐蚀性能要求,试验溶液采用高于标准(规定的质量分数为2.00%±0.05%)的初始浓度为5.0%的氯化钠溶液,溶液温度为45℃±2℃,湿度为70%RH±10%RH,循环周期为60min±5min,其中浸润时间为12min±2min;对比钢筋HRB500在72h的腐蚀速率为4.81 g/m2·h,在168h的腐蚀速率为5.23g/m2·h,在360h的腐蚀速率为6.38g/m2·h;耐蚀钢筋以实施例2为例,在72h的腐蚀速率为0.08 g/m2·h,在168h的腐蚀速率为0.25g/m2·h,在360h的腐蚀速率为0.49g/m2·h,依据GB/T 34206-2017,相对腐蚀速率分别是HRB500的1.7%(72h)、4.8%(168h)和7.7%(360h)。实施例1和2的相对腐蚀速率是HRB500的8.0%以下。腐蚀360h后锈层平均厚度为92μm,与HRB500平均厚度286μm的锈层相比具有很小的体积膨胀。The corrosion resistance test of Examples 1 and 2 was carried out. In typical concrete (pH=13.5±0.2), the critical chloride ion concentration of Example 1 was 4.0 mol/L, and the critical chloride ion concentration of Example 2 was 3.70 mol/L. In a concrete environment containing chloride (such as sea sand concrete mixed with seawater), Examples 1 and 2 can still maintain stable passivation. According to the requirements for steel corrosion resistance in GB/T33953-2017, the test solution uses a sodium chloride solution with an initial concentration of 5.0% higher than the standard (the specified mass fraction is 2.00%±0.05%), the solution temperature is 45°C±2°C, the humidity is 70%RH±10%RH, the cycle period is 60min±5min, and the immersion time is 12min±2min; the corrosion rate of the comparison steel bar HRB500 is 4.81 g/m2·h at 72h, 5.23g/m2·h at 168h, and 6.38g/m2·h at 360h; taking Example 2 as an example, the corrosion rate of the corrosion-resistant steel bar is 0.08 g/m2·h at 72h, 0.25g/m2·h at 168h, and 0.49g/m2·h at 360h. According to GB/T 34206-2017, the relative corrosion rates are 1.7% (72h), 4.8% (168h) and 7.7% (360h) of HRB500 respectively. The relative corrosion rates of Examples 1 and 2 are less than 8.0% of HRB500. After 360h of corrosion, the average thickness of the rust layer is 92μm, which has a very small volume expansion compared with the average thickness of 286μm of the rust layer of HRB500.
由试验结果可知,实施例1和2的综合力学性能良好并具有优异的耐蚀性能。图2a和2b为实施例1和实施例2在混凝土孔隙液体(pH=13.5±0.2)钝化后加入1.0mol/L氯化钠浸泡半年后拍摄的试样表面,未发现点蚀等腐蚀特征,表明钢筋仍在钝化状态。实施例1的Cr含量在所设计成分范围的下限处,Al和Mo含量在上限处,实施例2中Cr含量在上限处,Al和Mo含量接近下限,结果显示两者耐Cl-腐蚀性能良好,且耐蚀性随耐蚀合金元素含量的增加均有所增强。It can be seen from the test results that Examples 1 and 2 have good comprehensive mechanical properties and excellent corrosion resistance. Figures 2a and 2b show the sample surfaces of Examples 1 and 2 taken after being passivated in the concrete pore liquid (pH = 13.5 ± 0.2) and soaked for half a year with 1.0 mol/L sodium chloride. No corrosion characteristics such as pitting were found, indicating that the steel bars are still in a passivated state. The Cr content of Example 1 is at the lower limit of the designed composition range, and the Al and Mo contents are at the upper limit. In Example 2, the Cr content is at the upper limit, and the Al and Mo contents are close to the lower limit. The results show that both have good Cl- corrosion resistance, and the corrosion resistance is enhanced with the increase of the corrosion-resistant alloy element content.
实施例3和4,具体包括以下步骤:Embodiments 3 and 4 specifically include the following steps:
步骤1、按表1中的成分进行冶炼,出钢温度为>1600 ℃,优选出钢温度为1610℃。Step 1: Smelting is performed according to the composition in Table 1, and the tapping temperature is > 1600°C, preferably 1610°C.
步骤2、LF炉的钢包中以100~120 L/min的氩气流量进行全程底吹,优选100 L/min,出钢温度为>1550 ℃,优选1560 ℃;在RH炉中当真空度<2 mbar时进行>5 min净循环处理,优选8 min,出钢温度>1550 ℃,优选1560 ℃。此步骤要保证钢包内合金溶解及均匀化,将各元素含量控制在设计范围内。Step 2: In the ladle of the LF furnace, the argon flow rate is 100-120 L/min, preferably 100 L/min, and the tapping temperature is >1550°C, preferably 1560°C; in the RH furnace, when the vacuum degree is <2 mbar, a net circulation treatment is performed for >5 min, preferably 8 min, and the tapping temperature is >1550°C, preferably 1560°C. This step is to ensure that the alloy in the ladle is dissolved and homogenized, and the content of each element is controlled within the design range.
步骤3、在保护浇注条件下将钢水通过连铸机浇注成连铸坯,温度控制在1540~1560 ℃,优选1540 ℃,拉速控制在2.0~2.5 m/min,优选2.5 m/min。将连铸所得钢坯在加热炉中进行加热,加热温度>1150℃,优选1150 ℃,加热时间>2.0 h以保证合金元素得到充分回溶,优选2.0 h。实施例3轧制过程中轧制过程中粗轧温度960~1050 ℃,优选960℃,精轧温度830~940 ℃,优选870 ℃,轧制速度控制在15~20 m/s,优选20 m/s。实施例4热连轧工序,加热炉温度>1150℃,优选1200℃,开轧温度960~1100℃,优选1100℃。Step 3, under protective pouring conditions, the molten steel is poured into a continuous casting billet through a continuous casting machine, the temperature is controlled at 1540-1560 ° C, preferably 1540 ° C, and the pulling speed is controlled at 2.0-2.5 m/min, preferably 2.5 m/min. The billet obtained by continuous casting is heated in a heating furnace, the heating temperature is greater than 1150 ° C, preferably 1150 ° C, and the heating time is greater than 2.0 h to ensure that the alloy elements are fully dissolved, preferably 2.0 h. Example 3 During the rolling process, the rough rolling temperature is 960-1050 ° C, preferably 960 ° C, the finishing rolling temperature is 830-940 ° C, preferably 870 ° C, and the rolling speed is controlled at 15-20 m/s, preferably 20 m/s. Example 4 Hot rolling process, the heating furnace temperature is greater than 1150 ° C, preferably 1200 ° C, and the start rolling temperature is 960-1100 ° C, preferably 1100 ° C.
步骤4、对轧后钢筋需进行控温冷却处理。将轧制而成的钢筋以>5 ℃/s的冷速加速冷却至400 ℃以下,之后在冷床上进行自然冷却。Step 4: The rolled steel bars need to be cooled under controlled temperature. The rolled steel bars are cooled at a cooling rate of >5°C/s to below 400°C, and then cooled naturally on a cooling bed.
根据上述实施方法的轻质高耐蚀钢筋其强度、塑性测试结果如表4所示。The strength and plasticity test results of the lightweight and highly corrosion-resistant steel bars produced according to the above implementation method are shown in Table 4.
对实施例3和4进行耐蚀性测试,在典型混凝土(pH=13.5±0.2)中,实施例3的临界氯离子浓度为3.80 mol/L,实施例4的临界氯离子浓度为3.60 mol/L。在预含氯化物的混凝土环境中(例如用海水拌合的海砂混凝土),实施例3和4仍能保持稳定的钝化。依据GB/T33953-2017中对钢筋耐腐蚀性能要求,试验溶液采用高于标准(规定的质量分数为2.00%±0.05%)的初始浓度为5.0%的氯化钠溶液,溶液温度为45℃±2℃,湿度为70%RH±10%RH,循环周期为60min±5min,其中浸润时间为12min±2min;以实施例3为例,在72h的腐蚀速率为0.09 g/m2·h,在168h的腐蚀速率为0.27g/m2·h,在360h的腐蚀速率为0.50g/m2·h,依据GB/T 34206-2017,相对腐蚀速率分别是HRB500的1.9%(72h)、5.2%(168h)和7.8%(360h)。实施例3和4相对腐蚀速率是HRB500的8.0%以下。腐蚀360h后锈层平均厚度为97μm,与HRB500锈层厚度相比具有很小的体积膨胀。The corrosion resistance test of Examples 3 and 4 was carried out. In typical concrete (pH=13.5±0.2), the critical chloride ion concentration of Example 3 was 3.80 mol/L, and the critical chloride ion concentration of Example 4 was 3.60 mol/L. In a concrete environment containing chloride (e.g., sea sand concrete mixed with seawater), Examples 3 and 4 can still maintain stable passivation. According to the requirements for steel bar corrosion resistance in GB/T33953-2017, the test solution uses a sodium chloride solution with an initial concentration of 5.0% higher than the standard (the specified mass fraction is 2.00%±0.05%), the solution temperature is 45°C±2°C, the humidity is 70%RH±10%RH, the cycle period is 60min±5min, and the immersion time is 12min±2min; taking Example 3 as an example, the corrosion rate at 72h is 0.09 g/m2·h, the corrosion rate at 168h is 0.27g/m2·h, and the corrosion rate at 360h is 0.50g/m2·h. According to GB/T 34206-2017, the relative corrosion rates are 1.9% (72h), 5.2% (168h) and 7.8% (360h) of HRB500 respectively. The relative corrosion rates of Examples 3 and 4 are less than 8.0% of HRB500. After 360 hours of corrosion, the average thickness of the rust layer is 97 μm, which has a very small volume expansion compared with the thickness of the HRB500 rust layer.
实施例3采用控轧制备,实施例4采用热连轧工艺,由力学试验结果可知实施例3和4的综合力学性能良好。由腐蚀试验结果可知,制备工艺对腐蚀性能影响较小,实施例3和4具有优异的耐蚀性能。Example 3 is prepared by controlled rolling, and Example 4 is prepared by hot continuous rolling. The mechanical test results show that the comprehensive mechanical properties of Examples 3 and 4 are good. The corrosion test results show that the preparation process has little effect on the corrosion performance, and Examples 3 and 4 have excellent corrosion resistance.
综上所述,在本发明所设计的成分范围和工艺范围内,方案能够达到预计的效果。In summary, within the composition range and process range designed by the present invention, the solution can achieve the expected effect.
本发明与现有技术相比:Compared with the prior art, the present invention has the following advantages:
本发明充分利用合金化设计理念的优点,通过添加Cr、Al和Mo等元素,设计开发出轻质高耐蚀钢筋,钢筋密度可降低3~9%,力学性能指标为:屈服强度≥500 MPa,抗拉强度≥630 MPa,断后伸长率A≥20%,最大力下总伸长率Agt≥10.0%。在碱度为pH=13.0±0.2的典型混凝土中,所述的轻质高耐蚀钢筋的临界氯离子浓度为3.20~3.80 mol/L,其抗氯离子能力是普通钢筋HRB500的16~20倍,相对腐蚀速率是GB/T 1499.2-2018中HRB500的8.0%以下。The present invention makes full use of the advantages of the alloying design concept, and designs and develops lightweight and highly corrosion-resistant steel bars by adding elements such as Cr, Al and Mo. The steel bar density can be reduced by 3-9%, and the mechanical performance indicators are: yield strength ≥500 MPa, tensile strength ≥630 MPa, elongation after fracture A ≥20%, and total elongation under maximum force Agt ≥10.0%. In typical concrete with an alkalinity of pH=13.0±0.2, the critical chloride ion concentration of the lightweight and highly corrosion-resistant steel bars is 3.20-3.80 mol/L, and its chloride ion resistance is 16-20 times that of ordinary steel bars HRB500, and the relative corrosion rate is less than 8.0% of HRB500 in GB/T 1499.2-2018.
本发明中的轻质高耐蚀钢筋,在满足严酷海洋环境建筑结构工程服役性能要求的同时,兼具可持续和经济性的优势,能够有效节省成本从而带来更大的经济效益。The lightweight and highly corrosion-resistant steel bars of the present invention not only meet the service performance requirements of building structure engineering in harsh marine environments, but also have the advantages of sustainability and economy, and can effectively save costs and thus bring greater economic benefits.
表1 实施例1和2元素成分(wt%)Table 1 Elemental composition of Examples 1 and 2 (wt%)
表2 实施例1和2力学性能Table 2 Mechanical properties of Examples 1 and 2
表3 实施例3和4元素成分(wt%)Table 3 Elemental composition of Examples 3 and 4 (wt%)
表4 实施例3和4力学性能Table 4 Mechanical properties of Examples 3 and 4
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