A kind of soldering steel plate in high intensity in use for ocean by large line energy and manufacture method thereof
Technical field:
The invention belongs to the Hi-Stren steel technical field.Relate in particular to a kind of can Chinese People's Anti-Japanese Military and Political College's heat input (the low-alloy high-strength marine steel plate and the manufacture method thereof of 150~600kJ/cm) welding.
Background technology
Storing abundant oil and Sweet natural gas around the ocean, as far back as the seventies in 20th century Britain and Norway just at North Sea regional development oil-gas field, along with the mankind to the continually developing of ocean, the large ocean production vessel has obtained developing rapidly.Ocean platform has the working conditions lotus to be carved, and safe reliability is strict, long service life, and characteristics such as maintaining difficulty have proposed very high requirement to the performance and the metallurgical quality of steel.
Ocean platform environment of living in is abominable, except that bearing gravity loading, also to consider the influence of wind loading, wave loading, current load, ice load, earthquake load etc., this has just determined the singularity of platform with steel, particularly the platform node requires high strength, high tenacity, antifatigue, corrosion-resistant, anti-lamellar tearing and good weldability with Z to steel, requires to take low P, low S on metallurgical quality, lowly is mingled with, measure of control such as crystal grain thinning.Especially for high-intensity Plate Steel, in order to improve welding efficiency, its welding property requires higher.
In the last thirty years, in order to improve the welding efficiency of heavy construction structure, guarantee the safe reliability of its use, large-line energy welding technique such as the single face union-melt weld that welding efficiency is high, electro-gas welding, electroslag welding are used in succession, this has come problem newly for traditional low alloy high strength steel strip, promptly weld the intensity and the toughness variation of coarse-grain heat affected zone (HAZ), and easily produce defectives such as welding cold cracking.Therefore, the HAZ flexible improves the focus and emphasis that becomes Hi-Stren steel large-line energy welding research and development.
The low-alloy high-strength ocean platform must fully be taken all factors into consideration mother metal and welded heat affecting zone tissue thereof with the structural transformation behavior and the control of steel under the large-line energy welding conditions forming process and control method thereof.Because the embrittlement of the welded heat affecting zone that softens and cause therefrom of the alligatoring of the welded heat affecting zone tissue under the big welding heat initial conditions, heat affected zone and the reduction of strength of joint are the subject matter in the Hi-Stren steel welding.
For this reason, a large amount of research and discoveries has been carried out, high-strength steel and manufacture method thereof under the large-line energy welding conditions that research and design make new advances in aspects such as domestic and international welded heat affecting zone structure property feature to Hi-Stren steel, austenite crystal growth dynamics.As steel series with high linear energy and low weld crack sensitivity and production method thereof " (ZL 02115877.0); " high-performance refractory weather-resisting building steel and production method thereof " (ZL 01133562.9); " unmodified high-toughness low-temp steel for high-energy line welding and production method thereof " (ZL 01128316.5); large-line energy welding high tenacity molten zinc corrosion resistant steel and production method (ZL01128476.5) thereof; " but Plate Steel and manufacture method of the welding of a kind of large-line energy " (CN 200510023216.0); " steel in use for soldering pressure pipe in hydraulic power station under large line energy and production method thereof " (CN 200510019165.4), " but the superstrength Plate Steel and the manufacture method thereof of large-line energy welding " (ZL 200410017255.5), as " steel series with high linear energy and low weld crack sensitivity and production method thereof " (ZL02115877.0), but also there are the following problems:
1, weld heat input is low, is generally 50~150kJ/cm;
2, the content of oxygen is not made clear and definite regulation, be difficult to improve the quality of products and weld heat input;
3, Si content is higher, because of the Si of high level can promote the formation of M/A, reduces the toughness of HAZ;
4, contain the expensive metal vanadium, the cost of product is improved;
5, the employing hardening and tempering process production that has, thereby the production process complexity, link is many, production cost is high, owing to adopt hardening and tempering process production, carbon content is unfavorable for anti-bigger heat input welding and realizes controlled rolling and controlled chilling and mechanical thermal treatment process (TMCP) in general than non-tempering process height;
6, contain rare earth element in the steel, rare earth element is very active element, is not easy control, and pollutes molten steel easily, is unfavorable for the raising of quality product.
Summary of the invention
The purpose of this invention is to provide a kind of chemical ingredients simple, be easy to control, production cost is low, the manufacture method of the simple soldering steel plate in high intensity in use for ocean by large line energy of technological process.Manufactured steel plates can be welded by large-line energy, the intensity height, and crack sensitivity is low, and low-temperature flexibility is good.
For achieving the above object, the technical solution adopted in the present invention is: the chemical ingredients and the content thereof of this slab are: C be 0.01~0.25wt%, Si be 0.05~0.5wt%, Mn be 0.5~1.8wt%, Ni be 0.1~1.5wt%, Cu be 0.1~1.5wt%, Als be 0.001~0.06wt%, Nb be 0.01~0.08wt%, Ti be 0.01~0.08wt%, N be 0.002~0.012wt%, B be 0.0001~0.003wt%, P for<0.010wt%, S be<0.005wt%, all the other are Fe and unavoidable impurities;
Its manufacturing process is: adopt converter or electric arc furnace that molten iron or steel scrap or molten iron are carried out refining with steel scrap after making steel, refinery practice is the oxygen level of measuring earlier in the molten steel, oxygen level in the maintenance molten steel is at 10~600ppm, carry out deoxidation with Fe-Ti alloy or metal Ti, carry out final deoxidation with the Al line again.According to the chemical ingredients and the content thereof of slab, add B after the final deoxidation, carry out continuous casting, hot rolling then.
Hot rolling technology is: earlier strand is heated to 1100~1320 ℃, hot rolling is carried out in soaking after 2~4 hours again, and rolling is 20~100mm Plate Steel, rolls back control relaxation 5~300s, gets final product with online cooling of the speed of cooling of 1~30 ℃/s then.
Because the present invention adopts the microalloy control techniques of science and advanced TMCP technology, therefore have chemical ingredients simple, be easy to control, low, the characteristic of simple process of production cost.The tensile strength of the marine steel plate of manufacturing is 600~1000MPa, can weld under the heat input of 150~600kJ/cm, need not heat-treat after the welding, and the ballistic work of welded H AZ is not less than 2/3 of mother metal ballistic work.So steel plate welding quality height, crack sensitivity is low, and low-temperature flexibility is good, and the tensile strength height can reduce welding procedure intensity effectively, improves and makes efficient, reduces manufacturing cost, economizes on resources and the energy.
Therefore, the marine steel plate of manufacturing can be widely used in large scale structure, equipment, facilities etc. such as ocean platform, boats and ships warship, especially is fit to various welding such as union-melt weld, gas guarantor weldering, electro-gas welding, electroslag welding.
Embodiment
Below in conjunction with embodiment, the present invention is further described:
Embodiment 1
A kind of soldering steel plate in high intensity in use for ocean by large line energy and manufacture method thereof.The chemical ingredients and the content thereof of this slab are: C be 0.04~0.08wt%, Si be 0.2~0.4wt%, Mn be 1.2~1.8wt%, Ni be 0.2~0.4wt%, Cu be 0.4~0.8wt%, Als be 0.03~0.05wt%, Nb be 0.03~0.07wt%, Ti be 0.01~0.05wt%, N be 0.006~0.010wt%, B be 0.0010~0.0020wt%, P for<0.009wt%, S be<0.005wt%, all the other are Fe and unavoidable impurities.
Its manufacturing process is: with converter molten iron is carried out refining after steel-making, refinery practice is first with the oxygen level in the quick Determining oxygen probe mensuration steel, and the oxygen level in the maintenance molten steel is carried out deoxidation at 500ppm with the Fe-Ti alloy, carries out final deoxidation with the Al line again; According to the chemical ingredients and the content thereof of strand, add B after the final deoxidation, carry out continuous casting, hot rolling then.Slab thickness is 210mm.
Its hot rolling technology is: earlier strand is heated to 1150~1250 ℃, hot rolling is carried out in soaking after 2~3 hours again, and rolling is the thick steel plate of 40mm.Roll back control relaxation 5~10s, get final product with the online cooling of the speed of cooling of 8~15 ℃/s then.
Present embodiment manufactured steel plates tensile strength is 550MPa, can weld under the heat input of 400~600kJ/cm, need not heat-treat after the welding, and the ballistic work of welded H AZ is not less than 2/3 of mother metal ballistic work.
Embodiment 2
A kind of soldering steel plate in high intensity in use for ocean by large line energy and manufacture method thereof.The chemical ingredients and the content thereof of this slab are: C be 0.03~0.07wt%, Si be 0.2~0.4wt%, Mn be 1.0~1.4wt%, Ni be 0.3~0.5wt%, Cu be 0.1~1.5wt%, Als be 0.04~0.06wt%, Nb be 0.02~0.06wt%, Ti be 0.01~0.05wt%, N be 0.002~0.010wt%, B be 0.001~0.003wt%, P for<0.010wt%, S be<0.005wt%, all the other are Fe and unavoidable impurities.
Its manufacturing process is: adopt converter that molten iron and steel scrap are carried out refining after steel-making, refinery practice is earlier with the oxygen level in the quick Determining oxygen probe mensuration steel, oxygen level in the maintenance molten steel is carried out deoxidation at 300ppm with the Fe-Ti alloy, carries out final deoxidation with the Al line again.According to the chemical ingredients and the content thereof of slab, add B after the final deoxidation, carry out continuous casting, hot rolling then.The strand thickness of slab is 230mm.
Hot rolling technology is: earlier strand is heated to 1200~1300 ℃, hot rolling is carried out in soaking after 2.5~3.5 hours again, and rolling is the thick steel plate of 50mm.Roll back control relaxation 10~20s, get final product with the online cooling of the speed of cooling of 10~15 ℃/s then.
The tensile strength of present embodiment manufactured steel plates is 520MPa, can weld under the heat input of 400~600kJ/cm, can not heat-treat after the welding.The ballistic work of welded H AZ is not less than 2/3 of mother metal ballistic work.
Embodiment 3
A kind of soldering steel plate in high intensity in use for ocean by large line energy and manufacture method thereof.The chemical ingredients and the content thereof of this slab are: C be 0.03~0.05wt%, Si be 0.1~0.3wt%, Mn be 1.3~1.5wt%, Ni be 0.4~0.5wt%, Cu be 0.4~0.8t%, Als be 0.01~0.05wt%, Nb be 0.02~0.06wt%, Ti be 0.02~0.04wt%, N be 0.006~0.010wt%, B be 0.0010~0.0025wt%, P for<0.009wt%, S be<0.004wt%, all the other are Fe and unavoidable impurities.
Its manufacturing process is: adopt converter that steel scrap is carried out refining after steel-making, refinery practice is to measure oxygen level in the steel with quick Determining oxygen probe earlier, and the oxygen level in the maintenance molten steel is carried out deoxidation at 400ppm with metal Ti, carries out final deoxidation with the Al line again.According to the chemical ingredients and the content thereof of slab, add B after the final deoxidation, carry out continuous casting, hot rolling then.The strand thickness of slab is 250mm.
Hot rolling technology is: earlier strand is heated to 1220~1280 ℃, hot rolling is carried out in soaking after 2~3 hours again, and rolling is the thick steel plate of 60mm.Roll back control relaxation 15~30s, get final product with online cooling of the speed of cooling of 10~20 ℃/s then.
The tensile strength of present embodiment manufactured steel plates is 550MPa, can weld under the heat input of 400~600kJ/cm, can not heat-treat after the welding.The ballistic work of welded H AZ is not less than 2/3 of mother metal ballistic work.
This embodiment have chemical ingredients and technology simple, be easy to control, characteristics that production cost is low.Manufactured steel plates can be widely used in large scale structure, equipment, facilities etc. such as ocean platform, boats and ships warship, be fit to the various welding of 400~600kJ/cm large-line energies inputs such as union-melt weld, gas guarantor weldering, electro-gas welding, electroslag welding, so the welding quality height, crack sensitivity is low, low-temperature flexibility good, tensile strength is high, can reduce welding procedure intensity effectively, improve and make efficient, reduce manufacturing cost, economize on resources and the energy.