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CN101050505A - Soldering steel plate in high intensity in use for ocean by large line energy, and manufacturing method - Google Patents

Soldering steel plate in high intensity in use for ocean by large line energy, and manufacturing method Download PDF

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Publication number
CN101050505A
CN101050505A CNA2007100521352A CN200710052135A CN101050505A CN 101050505 A CN101050505 A CN 101050505A CN A2007100521352 A CNA2007100521352 A CN A2007100521352A CN 200710052135 A CN200710052135 A CN 200710052135A CN 101050505 A CN101050505 A CN 101050505A
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steel
ocean
steel plate
high intensity
line energy
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CN100523255C (en
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吴开明
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Wuhan University of Science and Technology WHUST
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Wuhan University of Science and Technology WHUST
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    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P10/00Technologies related to metal processing
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Abstract

本发明涉及一种大线能量焊接高强度海洋用钢板及其制造方法。该板坯的化学成分及其含量是:C为0.01~0.25wt%、Si为0.05~0.5wt%、Mn为0.5~1.8wt%、Ni为0.1~1.5wt%、Cu为0.1~1.5wt%、Als为0.001~0.06wt%、Nb为0.01~0.08wt%、Ti为0.01~0.08wt%、N为0.002~0.012wt%、B为0.0001~0.003wt%、P为<0.010wt%、S为<0.005wt%,其余为Fe及不可避免的杂质。制造工艺是:经炼钢后用Fe-Ti合金或者金属Ti进行脱氧,用Al线进行最终脱氧后加入B。再经连铸、均热、控制轧制、轧后弛豫控制、在线冷却即可。本发明可有效地降低焊接施工强度,提高制造效率,减少成本,节约资源和能源,适用于海洋平台、船舶军舰等大型结构、设备、设施等。The invention relates to a high-strength marine steel plate welded with large input energy and a manufacturing method thereof. The chemical composition and content of the slab are: C is 0.01-0.25wt%, Si is 0.05-0.5wt%, Mn is 0.5-1.8wt%, Ni is 0.1-1.5wt%, and Cu is 0.1-1.5wt%. , Als is 0.001-0.06wt%, Nb is 0.01-0.08wt%, Ti is 0.01-0.08wt%, N is 0.002-0.012wt%, B is 0.0001-0.003wt%, P is <0.010wt%, S is <0.005wt%, the rest is Fe and unavoidable impurities. The manufacturing process is: after steelmaking, Fe-Ti alloy or metal Ti is used for deoxidation, and Al wire is used for final deoxidation, and then B is added. After continuous casting, soaking, controlled rolling, relaxation control after rolling, and online cooling. The invention can effectively reduce the strength of welding construction, improve manufacturing efficiency, reduce costs, save resources and energy, and is suitable for large structures, equipment and facilities such as ocean platforms, ships and warships.

Description

A kind of soldering steel plate in high intensity in use for ocean by large line energy and manufacture method thereof
Technical field:
The invention belongs to the Hi-Stren steel technical field.Relate in particular to a kind of can Chinese People's Anti-Japanese Military and Political College's heat input (the low-alloy high-strength marine steel plate and the manufacture method thereof of 150~600kJ/cm) welding.
Background technology
Storing abundant oil and Sweet natural gas around the ocean, as far back as the seventies in 20th century Britain and Norway just at North Sea regional development oil-gas field, along with the mankind to the continually developing of ocean, the large ocean production vessel has obtained developing rapidly.Ocean platform has the working conditions lotus to be carved, and safe reliability is strict, long service life, and characteristics such as maintaining difficulty have proposed very high requirement to the performance and the metallurgical quality of steel.
Ocean platform environment of living in is abominable, except that bearing gravity loading, also to consider the influence of wind loading, wave loading, current load, ice load, earthquake load etc., this has just determined the singularity of platform with steel, particularly the platform node requires high strength, high tenacity, antifatigue, corrosion-resistant, anti-lamellar tearing and good weldability with Z to steel, requires to take low P, low S on metallurgical quality, lowly is mingled with, measure of control such as crystal grain thinning.Especially for high-intensity Plate Steel, in order to improve welding efficiency, its welding property requires higher.
In the last thirty years, in order to improve the welding efficiency of heavy construction structure, guarantee the safe reliability of its use, large-line energy welding technique such as the single face union-melt weld that welding efficiency is high, electro-gas welding, electroslag welding are used in succession, this has come problem newly for traditional low alloy high strength steel strip, promptly weld the intensity and the toughness variation of coarse-grain heat affected zone (HAZ), and easily produce defectives such as welding cold cracking.Therefore, the HAZ flexible improves the focus and emphasis that becomes Hi-Stren steel large-line energy welding research and development.
The low-alloy high-strength ocean platform must fully be taken all factors into consideration mother metal and welded heat affecting zone tissue thereof with the structural transformation behavior and the control of steel under the large-line energy welding conditions forming process and control method thereof.Because the embrittlement of the welded heat affecting zone that softens and cause therefrom of the alligatoring of the welded heat affecting zone tissue under the big welding heat initial conditions, heat affected zone and the reduction of strength of joint are the subject matter in the Hi-Stren steel welding.
For this reason, a large amount of research and discoveries has been carried out, high-strength steel and manufacture method thereof under the large-line energy welding conditions that research and design make new advances in aspects such as domestic and international welded heat affecting zone structure property feature to Hi-Stren steel, austenite crystal growth dynamics.As steel series with high linear energy and low weld crack sensitivity and production method thereof " (ZL 02115877.0); " high-performance refractory weather-resisting building steel and production method thereof " (ZL 01133562.9); " unmodified high-toughness low-temp steel for high-energy line welding and production method thereof " (ZL 01128316.5); large-line energy welding high tenacity molten zinc corrosion resistant steel and production method (ZL01128476.5) thereof; " but Plate Steel and manufacture method of the welding of a kind of large-line energy " (CN 200510023216.0); " steel in use for soldering pressure pipe in hydraulic power station under large line energy and production method thereof " (CN 200510019165.4), " but the superstrength Plate Steel and the manufacture method thereof of large-line energy welding " (ZL 200410017255.5), as " steel series with high linear energy and low weld crack sensitivity and production method thereof " (ZL02115877.0), but also there are the following problems:
1, weld heat input is low, is generally 50~150kJ/cm;
2, the content of oxygen is not made clear and definite regulation, be difficult to improve the quality of products and weld heat input;
3, Si content is higher, because of the Si of high level can promote the formation of M/A, reduces the toughness of HAZ;
4, contain the expensive metal vanadium, the cost of product is improved;
5, the employing hardening and tempering process production that has, thereby the production process complexity, link is many, production cost is high, owing to adopt hardening and tempering process production, carbon content is unfavorable for anti-bigger heat input welding and realizes controlled rolling and controlled chilling and mechanical thermal treatment process (TMCP) in general than non-tempering process height;
6, contain rare earth element in the steel, rare earth element is very active element, is not easy control, and pollutes molten steel easily, is unfavorable for the raising of quality product.
Summary of the invention
The purpose of this invention is to provide a kind of chemical ingredients simple, be easy to control, production cost is low, the manufacture method of the simple soldering steel plate in high intensity in use for ocean by large line energy of technological process.Manufactured steel plates can be welded by large-line energy, the intensity height, and crack sensitivity is low, and low-temperature flexibility is good.
For achieving the above object, the technical solution adopted in the present invention is: the chemical ingredients and the content thereof of this slab are: C be 0.01~0.25wt%, Si be 0.05~0.5wt%, Mn be 0.5~1.8wt%, Ni be 0.1~1.5wt%, Cu be 0.1~1.5wt%, Als be 0.001~0.06wt%, Nb be 0.01~0.08wt%, Ti be 0.01~0.08wt%, N be 0.002~0.012wt%, B be 0.0001~0.003wt%, P for<0.010wt%, S be<0.005wt%, all the other are Fe and unavoidable impurities;
Its manufacturing process is: adopt converter or electric arc furnace that molten iron or steel scrap or molten iron are carried out refining with steel scrap after making steel, refinery practice is the oxygen level of measuring earlier in the molten steel, oxygen level in the maintenance molten steel is at 10~600ppm, carry out deoxidation with Fe-Ti alloy or metal Ti, carry out final deoxidation with the Al line again.According to the chemical ingredients and the content thereof of slab, add B after the final deoxidation, carry out continuous casting, hot rolling then.
Hot rolling technology is: earlier strand is heated to 1100~1320 ℃, hot rolling is carried out in soaking after 2~4 hours again, and rolling is 20~100mm Plate Steel, rolls back control relaxation 5~300s, gets final product with online cooling of the speed of cooling of 1~30 ℃/s then.
Because the present invention adopts the microalloy control techniques of science and advanced TMCP technology, therefore have chemical ingredients simple, be easy to control, low, the characteristic of simple process of production cost.The tensile strength of the marine steel plate of manufacturing is 600~1000MPa, can weld under the heat input of 150~600kJ/cm, need not heat-treat after the welding, and the ballistic work of welded H AZ is not less than 2/3 of mother metal ballistic work.So steel plate welding quality height, crack sensitivity is low, and low-temperature flexibility is good, and the tensile strength height can reduce welding procedure intensity effectively, improves and makes efficient, reduces manufacturing cost, economizes on resources and the energy.
Therefore, the marine steel plate of manufacturing can be widely used in large scale structure, equipment, facilities etc. such as ocean platform, boats and ships warship, especially is fit to various welding such as union-melt weld, gas guarantor weldering, electro-gas welding, electroslag welding.
Embodiment
Below in conjunction with embodiment, the present invention is further described:
Embodiment 1
A kind of soldering steel plate in high intensity in use for ocean by large line energy and manufacture method thereof.The chemical ingredients and the content thereof of this slab are: C be 0.04~0.08wt%, Si be 0.2~0.4wt%, Mn be 1.2~1.8wt%, Ni be 0.2~0.4wt%, Cu be 0.4~0.8wt%, Als be 0.03~0.05wt%, Nb be 0.03~0.07wt%, Ti be 0.01~0.05wt%, N be 0.006~0.010wt%, B be 0.0010~0.0020wt%, P for<0.009wt%, S be<0.005wt%, all the other are Fe and unavoidable impurities.
Its manufacturing process is: with converter molten iron is carried out refining after steel-making, refinery practice is first with the oxygen level in the quick Determining oxygen probe mensuration steel, and the oxygen level in the maintenance molten steel is carried out deoxidation at 500ppm with the Fe-Ti alloy, carries out final deoxidation with the Al line again; According to the chemical ingredients and the content thereof of strand, add B after the final deoxidation, carry out continuous casting, hot rolling then.Slab thickness is 210mm.
Its hot rolling technology is: earlier strand is heated to 1150~1250 ℃, hot rolling is carried out in soaking after 2~3 hours again, and rolling is the thick steel plate of 40mm.Roll back control relaxation 5~10s, get final product with the online cooling of the speed of cooling of 8~15 ℃/s then.
Present embodiment manufactured steel plates tensile strength is 550MPa, can weld under the heat input of 400~600kJ/cm, need not heat-treat after the welding, and the ballistic work of welded H AZ is not less than 2/3 of mother metal ballistic work.
Embodiment 2
A kind of soldering steel plate in high intensity in use for ocean by large line energy and manufacture method thereof.The chemical ingredients and the content thereof of this slab are: C be 0.03~0.07wt%, Si be 0.2~0.4wt%, Mn be 1.0~1.4wt%, Ni be 0.3~0.5wt%, Cu be 0.1~1.5wt%, Als be 0.04~0.06wt%, Nb be 0.02~0.06wt%, Ti be 0.01~0.05wt%, N be 0.002~0.010wt%, B be 0.001~0.003wt%, P for<0.010wt%, S be<0.005wt%, all the other are Fe and unavoidable impurities.
Its manufacturing process is: adopt converter that molten iron and steel scrap are carried out refining after steel-making, refinery practice is earlier with the oxygen level in the quick Determining oxygen probe mensuration steel, oxygen level in the maintenance molten steel is carried out deoxidation at 300ppm with the Fe-Ti alloy, carries out final deoxidation with the Al line again.According to the chemical ingredients and the content thereof of slab, add B after the final deoxidation, carry out continuous casting, hot rolling then.The strand thickness of slab is 230mm.
Hot rolling technology is: earlier strand is heated to 1200~1300 ℃, hot rolling is carried out in soaking after 2.5~3.5 hours again, and rolling is the thick steel plate of 50mm.Roll back control relaxation 10~20s, get final product with the online cooling of the speed of cooling of 10~15 ℃/s then.
The tensile strength of present embodiment manufactured steel plates is 520MPa, can weld under the heat input of 400~600kJ/cm, can not heat-treat after the welding.The ballistic work of welded H AZ is not less than 2/3 of mother metal ballistic work.
Embodiment 3
A kind of soldering steel plate in high intensity in use for ocean by large line energy and manufacture method thereof.The chemical ingredients and the content thereof of this slab are: C be 0.03~0.05wt%, Si be 0.1~0.3wt%, Mn be 1.3~1.5wt%, Ni be 0.4~0.5wt%, Cu be 0.4~0.8t%, Als be 0.01~0.05wt%, Nb be 0.02~0.06wt%, Ti be 0.02~0.04wt%, N be 0.006~0.010wt%, B be 0.0010~0.0025wt%, P for<0.009wt%, S be<0.004wt%, all the other are Fe and unavoidable impurities.
Its manufacturing process is: adopt converter that steel scrap is carried out refining after steel-making, refinery practice is to measure oxygen level in the steel with quick Determining oxygen probe earlier, and the oxygen level in the maintenance molten steel is carried out deoxidation at 400ppm with metal Ti, carries out final deoxidation with the Al line again.According to the chemical ingredients and the content thereof of slab, add B after the final deoxidation, carry out continuous casting, hot rolling then.The strand thickness of slab is 250mm.
Hot rolling technology is: earlier strand is heated to 1220~1280 ℃, hot rolling is carried out in soaking after 2~3 hours again, and rolling is the thick steel plate of 60mm.Roll back control relaxation 15~30s, get final product with online cooling of the speed of cooling of 10~20 ℃/s then.
The tensile strength of present embodiment manufactured steel plates is 550MPa, can weld under the heat input of 400~600kJ/cm, can not heat-treat after the welding.The ballistic work of welded H AZ is not less than 2/3 of mother metal ballistic work.
This embodiment have chemical ingredients and technology simple, be easy to control, characteristics that production cost is low.Manufactured steel plates can be widely used in large scale structure, equipment, facilities etc. such as ocean platform, boats and ships warship, be fit to the various welding of 400~600kJ/cm large-line energies inputs such as union-melt weld, gas guarantor weldering, electro-gas welding, electroslag welding, so the welding quality height, crack sensitivity is low, low-temperature flexibility good, tensile strength is high, can reduce welding procedure intensity effectively, improve and make efficient, reduce manufacturing cost, economize on resources and the energy.

Claims (3)

1, a kind of manufacture method of soldering steel plate in high intensity in use for ocean by large line energy, the chemical ingredients and the content thereof that it is characterized in that this slab are: C be 0.01~0.25wt%, Si be 0.05~0.5wt%, Mn be 0.5~1.8wt%, Ni be 0.1~1.5wt%, Cu be 0.1~1.5wt%, Als be 0.001~0.06wt%, Nb be 0.01~0.08wt%, Ti be 0.01~0.08wt%, N be 0.002~0.012wt%, B be 0.0001~0.003wt%, P for<0.010wt%, S be<0.005wt%, all the other are Fe and unavoidable impurities;
Its manufacturing process is: adopt converter or electric arc furnace that molten iron or steel scrap or molten iron are carried out refining with steel scrap after making steel, refinery practice is the oxygen level of measuring earlier in the molten steel, oxygen level in the maintenance molten steel is at 10~600ppm, carry out deoxidation with Fe-Ti alloy or metal Ti, carry out final deoxidation with the Al line again, according to the chemical ingredients and the content thereof of slab, add B after the final deoxidation, carry out continuous casting, hot rolling then.
2, the manufacture method of soldering steel plate in high intensity in use for ocean by large line energy according to claim 1, it is characterized in that described hot rolling technology is: earlier strand is heated to 1100~1320 ℃, hot rolling is carried out in soaking after 2~4 hours again, rolling is 20~100mm Plate Steel, roll back control relaxation 5~300s, cool off so that the speed of cooling of 1~30 ℃/s is online then.
3, according to the soldering steel plate in high intensity in use for ocean by large line energy of the manufacture method manufacturing of claim 1 or 2 described soldering steel plate in high intensity in use for ocean by large line energy.
CNB2007100521352A 2007-05-10 2007-05-10 Soldering steel plate in high intensity in use for ocean by large line energy, and manufacturing method Expired - Fee Related CN100523255C (en)

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Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101985719A (en) * 2010-11-01 2011-03-16 武汉科技大学 Composite additive for smelting high heat input welding low-alloy steel and using method thereof
CN102031441A (en) * 2010-11-01 2011-04-27 武汉科技大学 Complex additive for spheroidizing and dispersing sulfides in steel and use method thereof
CN102363238A (en) * 2011-08-15 2012-02-29 南京钢铁股份有限公司 A Submerged Arc Welding Process for Thick Plates Used in Low Temperature Offshore Engineering
CN103114241A (en) * 2013-02-25 2013-05-22 江苏省沙钢钢铁研究院有限公司 Hot-rolled steel plate with yield strength of 460MPa and capable of being welded by large heat input
CN106086650A (en) * 2016-07-25 2016-11-09 江阴兴澄特种钢铁有限公司 A kind of can the polar region ship plate and preparation method thereof of Large Heat Input Welding
CN106191659A (en) * 2016-08-19 2016-12-07 山东钢铁股份有限公司 A kind of can the steel plate for ocean engineering of Large Heat Input Welding and manufacture method thereof
CN107217216A (en) * 2017-06-05 2017-09-29 苏州双金实业有限公司 A kind of environmental protection easily welding alloy steel
CN117802413A (en) * 2024-03-01 2024-04-02 日钢营口中板有限公司 A 400MPa grade TMCP steel plate with excellent welding performance and its production method

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EP1337678B1 (en) * 2000-12-01 2007-10-03 Posco Steel plate to be precipitating tin+mns for welded structures, method for manufacturing the same and welding fabric using the same
CN1302144C (en) * 2004-03-29 2007-02-28 宝山钢铁股份有限公司 Superhigh strength thick steel plate capable of large-line energy welding and its manufacturing method

Cited By (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101985719A (en) * 2010-11-01 2011-03-16 武汉科技大学 Composite additive for smelting high heat input welding low-alloy steel and using method thereof
CN102031441A (en) * 2010-11-01 2011-04-27 武汉科技大学 Complex additive for spheroidizing and dispersing sulfides in steel and use method thereof
CN102031441B (en) * 2010-11-01 2012-11-28 武汉科技大学 Complex additive for spheroidizing and dispersing sulfides in steel and use method thereof
CN102363238A (en) * 2011-08-15 2012-02-29 南京钢铁股份有限公司 A Submerged Arc Welding Process for Thick Plates Used in Low Temperature Offshore Engineering
CN103114241A (en) * 2013-02-25 2013-05-22 江苏省沙钢钢铁研究院有限公司 Hot-rolled steel plate with yield strength of 460MPa and capable of being welded by large heat input
CN106086650A (en) * 2016-07-25 2016-11-09 江阴兴澄特种钢铁有限公司 A kind of can the polar region ship plate and preparation method thereof of Large Heat Input Welding
CN106191659A (en) * 2016-08-19 2016-12-07 山东钢铁股份有限公司 A kind of can the steel plate for ocean engineering of Large Heat Input Welding and manufacture method thereof
CN106191659B (en) * 2016-08-19 2018-07-24 山东钢铁股份有限公司 It is a kind of can Large Heat Input Welding steel plate for ocean engineering and its manufacturing method
CN107217216A (en) * 2017-06-05 2017-09-29 苏州双金实业有限公司 A kind of environmental protection easily welding alloy steel
CN117802413A (en) * 2024-03-01 2024-04-02 日钢营口中板有限公司 A 400MPa grade TMCP steel plate with excellent welding performance and its production method
CN117802413B (en) * 2024-03-01 2024-05-03 日钢营口中板有限公司 400 MPa-level TMCP steel plate with excellent welding performance and production method thereof

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