CN1162485C - Anti-pollution emulsoid paint for internal wall and its preparing process - Google Patents
Anti-pollution emulsoid paint for internal wall and its preparing process Download PDFInfo
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- CN1162485C CN1162485C CNB011148845A CN01114884A CN1162485C CN 1162485 C CN1162485 C CN 1162485C CN B011148845 A CNB011148845 A CN B011148845A CN 01114884 A CN01114884 A CN 01114884A CN 1162485 C CN1162485 C CN 1162485C
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Abstract
The present invention discloses dirt resistant internal wall latex paint and a preparing method thereof. The latex paint is mainly composed of styrene-acrylate emulsion, PVA water solution, sodium hexametaphosphate, titanium white powder, lithopone, wollastonite powder, ground limestone, bentonite, a contamination resistant agent, HEC sterilization preservative, an anionic dispersing agent, Texanol ester alcohol, an SN612 leveling agent, waterproof powder, an NXZ defoaming agent, an ASE-6 thickener and water which are proportionally dissolved, polymerized, stirred and ground. After the latex paint of the present invention is brushed, sprayed, rolled, etc. to be attached on a wall, common stains and even red ink and blue ink which are stuck on the surface of the wall can be easily smeared and washed, and the wall is like a new one. Therefore, the dirt resistant internal wall latex paint of the present invention is a novel product which has the advantages of water resistance, washing and brushing resistance and strong dirt resistance.
Description
Technical field
The present invention relates to a kind of building coating, relate in particular to a kind of water tolerance, abrasion resistance, the building coating of pollution resistance and compound method thereof.
Background technology
Along with the continuous development of building coating in recent years, the quality of product constantly improves.At present, the interiro wall latex paint of domestic application, part has had good water tolerance and abrasion resistance.For example: Vinyl Acetate Copolymer class emulsion paint, acrylic acid or the like zero diopter.But; find that through market survey and retrieval " Chinese patent database " generally all there is the weakness of pollution resistance difference in interiro wall latex paint in the market, in a single day the metope behind the decoration has stain or is stained with ink; though accomplishing to smear, metope can't is washed off powder, the stain of the metope of can not erasing.
Summary of the invention
The objective of the invention is to overcome the deficiencies in the prior art part and provide a kind of water tolerance, abrasion resistance, the inner wall of building emulsion paint and the compound method thereof of pollution resistance.
In order to reach the purpose of foregoing invention, anti-pollution emulsoid paint for internal wall of the present invention is mainly formed through polymerization, stirring, grinding according to a certain weight ratio by benzene emulsion, the PVA aqueous solution, Sodium hexametaphosphate 99, titanium dioxide, zinc sulfide white, wollastonite powder, water-ground limestone, wilkinite, anti-stain resistant agent, HEC, fungicidal preservative, anionic dispersing agent, Texanol ester alcohol, SN612 flow agent, water-proofing powder, NXZ defoamer, ASE-60 thickening material and water; The PVA aqueous solution is heated, stirs, is stirred evenly and form by proportioning by polyvinyl alcohol, ultramarine, VBL whitening agent and water.
Described anti-pollution emulsoid paint for internal wall composition weight proportioning (%) is: benzene emulsion 28～33, the PVA aqueous solution 4～6, Sodium hexametaphosphate 99 0.1～0.2, titanium dioxide 3～4, zinc sulfide white 5～6, wollastonite powder 3～3.5, water-ground limestone 20～24, wilkinite 2～2.5, anti-stain resistant agent 0.4～0.6, HEC0.15～0.25, fungicidal preservative 0.04～0.06, anionic dispersing agent 0.6～0.7, Texanol ester alcohol 0.3～0.6, SN612 flow agent 0.15～0.2, water-proofing powder 5～7, NXZ defoamer 0.4～0.5, ASE～60 thickening materials 0.6～0.8 and water 12～27.
Described water-proofing powder adopts the OK powder, and described fungicidal preservative adopts derosal and the compound use of m-tetrachlorophthalodinitrile, and described HEC adopts the viscosity of 15000CPS.
Anti-pollution emulsoid paint for internal wall compound method of the present invention is as follows:
A. with an amount of hot water stirred pot is dropped in Sodium hexametaphosphate 99 dissolving back, drop into anionic dispersing agent, NXZ defoamer (part) and anti-stain resistant agent again and also fully stir evenly, drop into the quantitative PVA aqueous solution again, water-ground limestone stirs.
B. drop into 10 kg of water to stirred pot, slowly drop into HEC along with stirring then, make HEC be dissolved into uniform glue, drop into quantitative SN612 flow agent, water-proofing powder, titanium dioxide, zinc sulfide white, wollastonite powder again and stir evenly together through pretreated wilkinite.
C. a and b are mixed after be ground to 30 microns of fineness in the sand mill, obtain levigate slurry.
D. adding benzene emulsion, Texanol ester alcohol and fungicidal preservative to stirred pot stirs evenly with slurry.
E. after with an amount of water the ASE-60 thickening material being diluted, drop into stirred pot, make it adjust emulsion paint, and continue to be stirred to evenly, promptly get a kind of anti-pollution emulsoid paint for internal wall behind the froth breaking to desirable viscosity.
The process for preparation of the described PVA aqueous solution is as follows: 50 kg of water are added in the reactor heat, slowly add 3 kilograms of polyvinyl alcohol again, and start stirrer simultaneously, when treating that temperature is raised to 95 ℃, insulated and stirred, and, add 1.5 kilograms of the VBL whitening agent aqueous solution of 0.1 kilogram of ultramarine and 1% weight ratio gradually cooling the time along with polyvinyl alcohol all after the dissolving, behind cold filtration, become the PVA aqueous solution.
Anti-pollution emulsoid paint for internal wall of the present invention, raw material sources are extensive, and production technique is simple, and cost is low, and nontoxic no abnormal smell does not contain hazardous substance.With this emulsion paint through the wall of message after the duration such as brush, spray, rollers; not only has the present high-performance that has of generic latex lacquer; and its general stain or red, blue ink that sticks in metope also can be smeared and wash as newly, has more superior performance than in the market emulsion paint.
Embodiment
The present invention is further described with embodiment below.
According to benzene emulsion: the PVA aqueous solution: Sodium hexametaphosphate 99: titanium dioxide: zinc sulfide white: wollastonite powder: water-ground limestone: wilkinite: anti-stain resistant agent: HEC: fungicidal preservative: anionic dispersing agent: Texanol ester alcohol: SN612 flow agent: water-proofing powder: NXZ defoamer: ASE-60 thickening material: water=32: 5: 0.15: 4: 5: 3: 23: 2: 0.5: 0.2: 0.05: 0.6: 0.5: 0.2: 6: 0.4: 0.7: 17 ratio, with an amount of hot water stirred pot is dropped in Sodium hexametaphosphate 99 dissolving back, drop into anionic dispersing agents again, NXZ defoamer (1/2) stirs evenly, drop into the quantitative PVA aqueous solution again, water-ground limestone fully disperses; In another stirred pot, add 10 kg of water and HEC, make HEC be dissolved into uniform glue, drop into quantitative SN612 flow agent, water-proofing powder, titanium dioxide, zinc sulfide white, wollastonite powder then successively and stir evenly together through pretreated wilkinite; At this moment, with the mixing of materials in two stirred pots of above respectively dispersed with stirring, and be ground to 30 microns of fineness, obtain levigate slurry through sand mill; Dropping into benzene emulsion, Texanol ester alcohol and fungicidal preservative again in stirred pot stirs evenly with slurry, at last, with 2 kilograms water with after the ASE-60 thickening material dilution, drop into stirred pot, make it adjust emulsion paint, and drop into defoamer (1/2), continue to stir to desirable viscosity, promptly obtain being rich in anti-pollution emulsoid paint for internal wall plentiful, fine and smooth texture, at last by standard capacity packing warehouse-in.
Constructional method: adopt the skill and technique of brush, spray, roller, scumbling is two times on smooth, solid, exsiccant basal plane, can form the decorative coveringn of anti-pollution emulsoid paint for internal wall.
Anti-pollution emulsoid paint for internal wall of the present invention is the concentrated type product, can be during construction according to weather, and the levelling property of temperature and construction requirement, opacifying power adds the dilution of 30-50% water, stirs evenly, and does not influence the technical feature and the feature of anti-pollution emulsoid paint for internal wall.
Anti-pollution emulsoid paint for internal wall of the present invention does not precipitate caking in container, be fine and smooth plentiful state, it opens jar effect can compete U.S. with external best brand of product fully, and 1 year product shelf-time never degenerated, coating after constructions such as brush, spray, roller, color and luster is even, smooth soft.The sodium hydroxide saturated solution soak 24 hours no abnormal, the not shedding in 48 hours of water logging bubble, water-fast scrubbing more than 500 times, and used water is smeared and is washed the stain that sticks on the coating, tea steeps red blue ink, and the nontoxic no abnormal smell of product, meets the requirement of present home decoration about health environment-friendly, with low cost, easy construction.
Compare with present similar technology, anti-pollution emulsoid paint for internal wall of the present invention has not only kept the technical characterictic of traditional emulsion paint, but also has improved the performance of anti-soil greatly.
Claims (7)
1, a kind of anti-pollution emulsoid paint for internal wall is characterized in that: this emulsion paint is mainly formulated by benzene emulsion, the PVA aqueous solution, Sodium hexametaphosphate 99, titanium dioxide, zinc sulfide white, wollastonite powder, water-ground limestone, wilkinite, anti-stain resistant agent, HEC, fungicidal preservative, anionic dispersing agent, Texanol ester alcohol, SN612 flow agent, water-proofing powder, NXZ defoamer, ASE-60 thickening material and water;
The described PVA aqueous solution is heated, is stirred by proportioning by polyvinyl alcohol, ultramarine, VBL whitening agent and water, stirs evenly to form.
2, anti-pollution emulsoid paint for internal wall according to claim 1 is characterized in that: the weight proportion of this emulsion paint component (%) is: benzene emulsion 28～33, the PVA aqueous solution 4～6, Sodium hexametaphosphate 99 0.1～0.2, titanium dioxide 3～4, zinc sulfide white 5～6, wollastonite powder 3～3.5, water-ground limestone 20～24, wilkinite 2～2.5, anti-stain resistant agent 0.4～0.6, HEC0.15～0.25, fungicidal preservative 0.04～0.06, anionic dispersing agent 0.6～0.7, Texanol ester alcohol 0.3～0.6, SN612 flow agent 0.15～0.2, water-proofing powder 5～7, NXZ defoamer 0.4～0.5, ASE～60 thickening materials 0.6～0.8 and water 12～27.
3, anti-pollution emulsoid paint for internal wall according to claim 1 is characterized in that: described water-proofing powder OK powder.
4, anti-pollution emulsoid paint for internal wall according to claim 1 is characterized in that: described fungicidal preservative is the mixture of derosal and m-tetrachlorophthalodinitrile.
5, anti-pollution emulsoid paint for internal wall according to claim 1 is characterized in that: described HEC adopts the viscosity of 15000CPS.
6, a kind of compound method of anti-pollution emulsoid paint for internal wall as claimed in claim 1 is characterized in that: this making method comprises the steps:
A. with an amount of hot water stirred pot is dropped in Sodium hexametaphosphate 99 dissolving back, drop into anionic dispersing agent, part NXZ defoamer and anti-stain resistant agent again and also fully stir evenly, add the PVA aqueous solution then, water-ground limestone fully disperses;
B. drop into 10 kg of water and HEC to stirred pot, make HEC be dissolved into uniform glue, drop into SN612 flow agent, water-proofing powder, titanium dioxide, zinc sulfide white, wollastonite powder again and stir evenly together through pretreated wilkinite;
C. a and b are mixed after be ground to 30 microns of fineness in the sand mill, obtain levigate slurry;
D. adding benzene emulsion, Texanol ester alcohol and fungicidal preservative to stirred pot stirs evenly with slurry;
E. after with an amount of water the ASE-60 thickening material being diluted, drop into stirred pot, make it adjust emulsion paint, and continue to be stirred to evenly, promptly get a kind of anti-pollution emulsoid paint for internal wall behind the froth breaking to desirable viscosity.
7, the compound method of anti-pollution emulsoid paint for internal wall according to claim 6, it is characterized in that: the blending process of the described PVA aqueous solution, to heat in the 50 kg of water adding reactor, add 3 kilograms of polyvinyl alcohol more lentamente, and start stirrer simultaneously, when treating that temperature is raised to 95 ℃, insulated and stirred, and along with after the whole dissolvings of polyvinyl alcohol, in cooling time, add 1.5 kilograms of the VBL whitening agent aqueous solution of 0.1 kilogram of ultramarine and 1% weight ratio gradually, becomes the PVA aqueous solution behind cold filtration.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB011148845A CN1162485C (en) | 2001-06-29 | 2001-06-29 | Anti-pollution emulsoid paint for internal wall and its preparing process |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB011148845A CN1162485C (en) | 2001-06-29 | 2001-06-29 | Anti-pollution emulsoid paint for internal wall and its preparing process |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1330119A CN1330119A (en) | 2002-01-09 |
| CN1162485C true CN1162485C (en) | 2004-08-18 |
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| Application Number | Title | Priority Date | Filing Date |
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| CNB011148845A Expired - Fee Related CN1162485C (en) | 2001-06-29 | 2001-06-29 | Anti-pollution emulsoid paint for internal wall and its preparing process |
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Families Citing this family (11)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN1331966C (en) * | 2004-04-23 | 2007-08-15 | 谢健文 | Water shedding facade wall paint and its preparing process |
| CN101348636B (en) * | 2007-07-16 | 2011-03-30 | 韩康城 | Environment-friendly type aqueous paint for marine shrimp pond |
| CN103160153A (en) * | 2013-04-14 | 2013-06-19 | 河北青竹美术颜料有限公司 | Formaldehyde-free art paint and preparation method thereof |
| CN103193418A (en) * | 2013-04-26 | 2013-07-10 | 许从玉 | Sound-absorbing coating for interior wall and production method thereof |
| CN103382333A (en) * | 2013-07-08 | 2013-11-06 | 吴江市物华五金制品有限公司 | Stain resistant environment-friendly latex paint for inner walls and preparation method thereof |
| CN103602165B (en) * | 2013-11-19 | 2016-03-23 | 青岛祥嘉知识产权服务有限公司 | A kind of full-bodied waterproof paint |
| CN104530842A (en) * | 2014-12-25 | 2015-04-22 | 三棵树涂料股份有限公司 | Elastic high-stain-resistance water-based paint composition and preparation method thereof |
| CN104530849A (en) * | 2015-01-26 | 2015-04-22 | 欧美龙（南通）重防腐涂料有限公司 | Formula of compound ceramic simulating coating |
| CN104559575A (en) * | 2015-01-28 | 2015-04-29 | 桑达化工（南通）有限公司 | Anti-fouling interior wall latex paint |
| CN107383971A (en) * | 2017-08-31 | 2017-11-24 | 白建宏 | A kind of new indoor emulsion paint |
| CN108659634A (en) * | 2018-06-12 | 2018-10-16 | 安徽喜宝高分子材料有限公司 | A kind of corrosion-resistant emulsion paint of anti-crack |
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2001
- 2001-06-29 CN CNB011148845A patent/CN1162485C/en not_active Expired - Fee Related
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| Publication number | Publication date |
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| CN1330119A (en) | 2002-01-09 |
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