CN1357580A - Production process of colar glaze guartz paint - Google Patents
Production process of colar glaze guartz paint Download PDFInfo
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- CN1357580A CN1357580A CN 01133748 CN01133748A CN1357580A CN 1357580 A CN1357580 A CN 1357580A CN 01133748 CN01133748 CN 01133748 CN 01133748 A CN01133748 A CN 01133748A CN 1357580 A CN1357580 A CN 1357580A
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Abstract
The production process of color glaze quartz paint includes preparation of color glaze quartzite, preparation of polymer slurry and compounding of color glaze quartz paint. It features that during preparation of color glaze quartzite, using only two kinds of material for producing the inorganic basic pigment material and inorganic basic glaze material capable of produce the color quartzite material through mixing, sieving and middle temperature baking; and that the polymer slurry is compounded with several polymer adhesives and additives. The present invention has the advantages of simple process, easy operation, no toxicity, no environmental pollution and low cost and can produce excellent color glaze quartz paint with different required performance.
Description
Technical field
The present invention relates to a kind of manufacture method of stone-like coating, definitely saying so relates to a kind of manufacture method of colar glaze guartz paint.
Background technology
Since 1999, China cities and towns almost completely adopt the situation of glazed wall tile decorative constructure exterior wall to be restricted, under national industrial policies instruct, the plasticity finishing material that with the paint is representative is favored day by day, particularly since 2000, much more more and more the newly-built buildings in big and medium-sized cities uses coating as building outer wall decorative material.But, Coating Industry in Our Country really can not adapt to the development of this situation far away, many building coatings or have the flavor poisonous, or fugitive color variable color, or poor adhesion, easy to crack, skull patch, come off, or water tolerance, weathering resistance are poor, and working life is short etc., thereby in China's " hi-tech development project guide " one of project is listed " developing water-based, nontoxic, high-performance coating ", particularly outer wall building coating in recent years by China.In the world, since the eighties, people praise highly gradually and return Piao and return very, and back to nature has been researched and developed stone-like coating.Stone-like coating one is the problem that has solved the variable color of common buildings coating fugitive color, the 2nd, solved the problem that the common buildings coating durability is poor, working life is short, and the 3rd, solved common buildings coatings decoration buildings and seemed that texture is flat, ornamental relatively poor problem.The buildings of decorating with stone-like coating seem nature, serious, luxurious, be imbued with texture, liked by the people of various countries, become one of popular coating variety in the world.The major ingredient of stone-like coating is band look aggregate and a polymer binder, and other contains a small amount of multiple additives, and different sources band look of different nature aggregate and as different types of macromolecular compound kind of tackiness agent is determining the salient features of stone-like coating.Band look aggregate in the stone-like coating claims color sand again, so stone-like coating is also referred to as sand texture coating.The used color sand of domestic and international at present production stone-like coating has two kinds, and a kind of is natural colour sand, and it is to get through pulverizing, sieving with band colored stone material.Claim on the stone-like coating commodity of producing by natural colour sand " true mineral varnish " or " stone coating " etc.Because the lithotome color variety is limited, the bright color kind is few, and color consistency is poor, hardness reduces behind dispersion and fining, and color and luster tarnishes, and color sensation is poor, factors such as decorative effect is undesirable, and band colored stone material source is also restricted, thereby the large-scale popularization application of " true mineral varnish " is affected.Another kind of color sand is to form by colourless quartz sand is painted, is called " artificial color sand ".Artificial color sand color and luster is various, abundant, bright in luster, solid colour, and epigranular hardness height, good endurance becomes the preferred material of producing modern stone-like coating gradually.The production technique of domestic and international artificial color sand has three kinds at present:
The one, with the pigment dyestuff quartz sand that dyes.This production method is simple, but the color sand of gained can fade.
The 2nd, make tackiness agent with macromolecule resin, mix inorganic color after, be coated on quartz sand surface, and allow resin crosslinks solidify and painted.
The 3rd, inorganic color is adhered to quartz sand surface, at 1200～1350 ℃ of high temperature sinterings and fixation, though the color grittiness energy of this gained is better than preceding two kinds, the cost height.
Another major ingredient of decision stone-like coating performance is a polymer binder.The used tackiness agent great majority of stone-like coating in the market are interpolymer latex of polystyrene and acrylic ester, the popular name benzene emulsion.Because only with a kind of tackiness agent of benzene emulsion, thereby the stone-like coating performance of producing is single, be difficult to satisfy the requirement that the market diversity changes, different requirements as decoration of exterior wall and inner wall decoration, to the different requirements of decorative paint length in work-ing life, cold district, the torrid zone, subtropical zone, coastal and interior ground, humid area and dry area are to the different requirements of decorative paint etc.
Therefore, with the stone-like coating that present technology is produced, have price height, performance single, can not satisfy shortcomings such as market diversity requirement, influenced its applying in construction industry.
Summary of the invention
The objective of the invention is to: overcome the shortcoming that present stone-like coating exists, for enterprise provides a kind of production cost low, performance is various, rich color, long service life, the manufacture method of the colar glaze guartz paint of nontoxic, water-based.
Basic thought of the present invention is: by the different colours requirement, but basic mineral compound and the basic mineral compound mixing that can become glaze with multiple quality, and be coated on quartz sand surface, through firing of 600～1000 ℃ of degree different times, color reaction by mineral compound with become the glaze reaction, make quartz sand surface form one deck will never fade colored glaze the same with porcelain.Then, adopt the tackiness agent of multiple different performance, as aqueous polyvinyl acetate emulsion, vinyl acetate-ethylene copolymerization emulsions (EVA emulsion), vinyl acetate-tertiary ethylene carbonate copolymer emulsion (popular name VA-VeoVa10 copolymer emulsion), vinyl acetate-acrylate copolymer emulsion (popular name vinegar-acrylic emulsion), general interpolymer latex of polystyrene and acrylic ester, hud typed interpolymer latex of polystyrene and acrylic ester (the hud typed benzene emulsion of popular name), the copolymer emulsion of acrylic acid derivative (popular name pure-acrylic emulsion), organosilicon-acrylate copolymer emulsion (popular name organosilicon crylic acid latex), the blend of poly organic silicon emulsion and acrylate copolymer emulsion, (gathering) organic silicon emulsions etc. cooperate with colar glaze guartz sand with the tackiness agent of multiple different performance, produce and can satisfy the will never fade colar glaze guartz paint that the market diversity changes the many kinds that require.Can produce the colar glaze guartz paint of the different class of tens of kinds of different colours (performance) by the present invention.
Technological process of the present invention is as follows: a kind of manufacture method of colar glaze guartz paint, and by colar glaze guartz sand preparation technology, polymer slurry preparation technology and colar glaze guartz paint modulation process are formed; Colar glaze guartz sand preparation technology wherein, in regular turn by the preparation colorant, coat that quartz, dry colored stone, middle temperature are fired, all operations of aftertreatment are formed; Described preparation colorant operation is meant according to decorating requirement, with the mineral compound basic material of the generated pigment of certain proportioning and the mineral compound basic material that can generate glaze through mixing, after the screening, becoming with thinking the colorant process for preparation that quartz sand is painted; The quartzy operation of described coating is meant earlier the quartz sand preheating to be joined tackiness agent in the preheating quartz sand again to stir, and then adds colorant again, evenly stirs, and makes the process of quartz sand particle surface parcel one deck colorant; Described dry colored stone operation, be meant that one deck colorant has been wrapped up on the quartz sand particle surface after, quartz sand is carried out the exsiccant process; Warm ablating work procedure in described, be meant that the quartz sand after will be enclosed with colorant drying operation handles sends in the electric furnace, the control furnace temperature is fired at 600 ℃～1000 ℃ degree under oxidizing atmosphere, through color reaction with becomes glaze to react, makes the process of quartz sand surface formation one deck colored glaze; Described postprocessing working procedures is meant that the quartz sand that will be fired into colored glaze cools off, crushes and sieves, and obtains the treating processes of the required colar glaze guartz sand of preparation colar glaze guartz paint.
Polymer slurry preparation technology in the method, operation by polymer binder and additive formula, mixed preparing polymer slurries is formed, definitely say so according to decorating requirement, adopt the polymer binder and the additive of multiple different performance and proportioning, make the modulation process process that is used to modulate colar glaze guartz sand, produces the polymer slurries of colar glaze guartz paint through mixing, grind, filtering.
Colar glaze guartz paint modulation process in present method, form by colar glaze guartz sand and polymer slurries hybrid modulation operation, be that colar glaze guartz sand is put into mixing tank, under stirring, add the polymer slurries, mix the production process that is modulated into the colar glaze guartz paint product.
Present method is characterised in that: the 1. preparation colorant operation in colar glaze guartz sand preparation technology, be not with a kind of inorganic color that can buy on the market as existing technology, but adopt two class raw materials of certain proportioning, the mineral compound basic material that can generate the mineral compound basic material of pigment and can generate glaze is through mixing, screening and be made as the colorant blending process of quartz sand colorant, 2. in this technology between dry colored stone operation and postprocessing working procedures, also be provided with the middle temperature ablating work procedure of colored stone under 600 ℃～1000 ℃ temperature, but not be 1200 ℃～1350 ℃ high-temperature firing; 3. in polymer slurry preparation technology, adopt the polymer binder of multiple different performance and proportioning and additive to modulate the polymer slurries, but not only adopt a kind of benzene emulsion modulation slurries.
The invention has the advantages that: whole processing method is simple, processing ease, nontoxic, do not produce industrial pollution, can produce low cost, high performance building coating.Because in the method, need not expensive ceramic pigment, and adopt the cheap generation pigment and the mineral compound basic raw material of glaze, adopt the low middle temperature sintering technology of energy consumption and without the high high-temperature firing technology of energy consumption, thereby greatly reduce the production cost of artificial smalt raw material; Because in this processing method, the artificial sandy plain material of producing is the same will never fade colar glaze guartz sand with porcelain, and is different from the artificial smalt that general high-temperature firing goes out, and it is various, colored bright-coloured, abundant to have a color and luster, the distinguishing feature of solid colour; Can make with polymer binder, the additive of this colar glaze guartz sand and multiple performance and to satisfy architectural design department and user to the Suresh Kumar design model with decorate having long service life, application and once can using nondiscoloration more than 15 years, fade of requiring, do not ftracture, peel off, water-based, nontoxic, high performance decorative paint free from environmental pollution in production and the use.Promote the use of this colar glaze guartz paint, will make urban architecture more apparent serious, magnificent, can bring up to a higher level to China's building decoration.
Description of drawings Fig. 1 is colar glaze guartz paint technological process of production figure of the present invention for colored glaze quartz sand preparation technology schema Fig. 2 among the present invention for polymer slurry preparation process flow sheet Fig. 3 among the present invention
Embodiment embodiment 1 golden yellow colar glaze guartz sand prescription: quartz sand (18～140 order) 60～95%
Colorant (＞325 order) 5～40% wherein colorant consists of: zinc oxide 5～12% saltpetre 5～1%
Antimonous oxide 7～11% red leads 50～71%
The raw material of producing glaze during boric acid 8～2% silicon-dioxide 25～3% colorants are formed is: red lead, boric acid, silicon-dioxide, all the other are for producing the raw material of pigment.First with the quartz sand preheating, the weighing in proportion of various compositions, grinding, mixing, screening in the colorant.Under even stirring situation, elder generation joins tackiness agent in the preheating quartz sand and stirs, and then adds colorant again, evenly stirs, and makes the quartz sand particle surface wrap up one deck colorant, drying.The quartz sand that will be enclosed with colorant is again sent in the electric furnace, under oxidizing atmosphere, fire in 600 ℃～1000 ℃ furnace temperature, and postcooling, crushing, screening promptly obtains golden yellow colar glaze guartz sand.Embodiment 2 sky blue colar glaze guartz sand prescriptions: quartz sand (18～140 order) 60～95%
Colorant (＞325 order) 5～40% wherein colorant consists of: zinc oxide 35～12% silicon-dioxide 8～2.8%
Boric acid 10～20% red leads 17～35%
The raw material of producing glaze during aluminum oxide 15～30% cobalt sesquioxides 15～0.2% colorants are formed is: red lead, boric acid, silicon-dioxide, all the other are for producing the raw material of pigment.By embodiment 1 described the operation, 1000 ℃ with interior calcining, can obtain evenly gorgeous sky blue colar glaze guartz sand of color and luster.The yellow colar glaze guartz sand prescription of embodiment 3 teeth: quartz sand (18～140 order) 55～95%
Colorant (＞325 order) 5～45% wherein colorant consists of: ferric oxide 1.5～12% zinc oxide 0.5～5%
Saltpetre 10～1% red leads 20～49%
Antimonous oxide 8～20% boric acid 35～10%
The raw material of producing glaze during silicon-dioxide 25～3% ferric sulfate 0～7% colorant is formed is: red lead, boric acid, silicon-dioxide, all the other are for producing the raw material of pigment.By embodiment 1 described the operation, fire below 900 ℃, can obtain the yellow colar glaze guartz sand of tooth after the cooling.Embodiment 4 orange colar glaze guartz sand prescription: quartz sand (18～140 order) 65～95%
Colorant (＞325 order) 5～35% wherein colorant consists of: lime carbonate 0.5～8% salt of wormwood 1～11%
Cadmium carbonate 5～25% boric acid 3～10%
Red lead 15～25% zinc oxide 0.1～5%
Silicon-dioxide 20～30% plumbous oxide 0.5～10%
Borax 3～10% selenium 0.1～2%
The raw material of producing glaze during sulphur 2～12% colorants are formed is: zinc oxide, red lead, boric acid, silicon-dioxide, borax, plumbous oxide, salt of wormwood, lime carbonate, all the other are for producing the raw material of pigment.By embodiment 1 described the operation, to fire below 800 ℃, cooling can obtain nacarat colar glaze guartz sand.With the technology of the present invention can produce tens of kinds bright in luster, the colar glaze guartz sand of different color and lusters.Embodiment 5 universal colar glaze guartz paint formulas: benzene emulsion 13～25% film coalescence aid 1～3%
Thickening material 0.05～0.25% mould inhibitor 0.1～0.3%
Titanium dioxide 0.05～1.5% talcum powder 0.05～5%
Anti-settling agent 0.05～0.1% defoamer is an amount of
Water 1～10% colar glaze guartz sand 5～35%
Quartz sand 40～60%
Elder generation dissolves thickening material, anti-settling agent, mould inhibitor, titanium dioxide, talcum powder or is dispersed in the water, and high-speed stirring is even, grinds, and filters.This mixed solution is mixed with macromolecule emulsion, and add the part defoamer, stir, obtain the polymer slurries.
Colar glaze guartz sand and quartz sand are put into the Hi-mixer mixing, add the polymer slurries under stirring, add remaining defoamer again, stirring and evenly mixing is colar glaze guartz paint.Embodiment 6 inner wall decorations colar glaze guartz paint formula: vinyl acetate-ethylene copolymerization emulsions (or using aqueous polyvinyl acetate emulsion) 15～30%
Film coalescence aid 1～5% thickening material 0.05～0.1%
Mould inhibitor 0.1～0.3% titanium dioxide 0.05～0.1%
Talcum powder 0.05～5% anti-settling agent 0.05～0.2%
Water 3～15% defoamers are an amount of
Colar glaze guartz sand 3～10% quartz sands 50～70%
By embodiment 5 described operations, can obtain to be used for the colar glaze guartz paint that inner wall decoration is used.Embodiment 7 decoration of exterior wall are with senior colar glaze guartz paint formula: nucleocapsid benzene emulsion (or using pure-acrylic emulsion) 13～50%
Film coalescence aid 1～4% thickening material 0.05～0.15%
Mould inhibitor 0.1～0.5% titanium dioxide 0.01～2.0%
Talcum powder 0～1% anti-settling agent 0.03～0.25%
Water 1～5% defoamer is an amount of
Colar glaze guartz sand 5～60% quartz sands 25～50%
By embodiment 5 described operations, can obtain the senior colar glaze guartz paint of decoration of exterior wall.Embodiment 8 decoration of exterior wall are with super colar glaze guartz paint formula: organosilicon crylic acid latex (or using the poly organic silicon emulsion) 15～25%
Film coalescence aid 1～5% thickening material 0.05～0.25%
Mould inhibitor 0.1～0.5% titanium dioxide 0.05～2.0%
Talcum powder 0～2% anti-settling agent 0.03～0.3%
Water 1～10% defoamer is an amount of
Colar glaze guartz sand 5～65% quartz sands 35～55%
By embodiment 5 described operations, can obtain super colar glaze guartz paint, its remarkable performance can guarantee that reach more than 20 years the work-ing life of super colar glaze guartz paint.Embodiment 9 inner wall decorations are with senior colar glaze guartz paint formula: vinegar-acrylic emulsion (or with vinyl acetate-tertiary ethylene carbonate copolymer emulsion) 15～30%
Film coalescence aid 1～5% thickening material 0.05～0.1%
Mould inhibitor 0.01～0.3% titanium dioxide 0.1～0.5%
Talcum powder 0.3～3% anti-settling agent 0.05～0.25%
Water 3～15% defoamers are an amount of
Colar glaze guartz sand 3～10% quartz sands 45～65%
By embodiment 5 described operations, can obtain the senior colar glaze guartz paint that inner wall decoration is used.Embodiment 10 decoration of exterior wall are with senior colar glaze guartz paint formula: benzene emulsion 8～20% commixed type organosilicon crylic acid latexs 3～10%
Film coalescence aid 1～4% thickening material 0.05～0.15%
Mould inhibitor 0.05～0.15% titanium dioxide 0.1～0.35%
Talcum powder 0～0.15% anti-settling agent 0.03～0.3%
Water 1～5% defoamer is an amount of
Colar glaze guartz sand 5～60% quartz sands 5～50%
By embodiment 5 described operations, can obtain the senior colar glaze guartz paint of decorating outer wall of building.
The technical performance index of the colar glaze guartz paint of producing with present method is far superior to the quality index of the decorating outer wall of building coating standard GB/T9755-1995 of China's nineteen ninety-five promulgation, is compared as follows:
| Colar glaze guartz paint | ????GB/T9755-1995 | |
| Water tolerance | 240 hours no changes | 96 hours no changes |
| Alkali resistance | 240 hours no changes | 48 hours no changes |
| Abrasion resistance | 1000 times | 500 times qualified |
| Artificial ageing resistance | 500 hours | 200 hours |
Comparison shows that more than the technical performance index of colar glaze guartz paint is better than the technical feature of exterior wall latex paint coating commonly used in the market greatly.
After detecting, specified authoritative feeler mechanism of country shows that the performance of the colar glaze guartz paint of producing with the present invention reaches the national standard of GB9153-88 fully.
The national standard of GB9153-88 and colar glaze guartz paint detected result
| Classification | Test item | Technical requirements | Colar glaze guartz paint | |
| The coating test | Condition in container | After stirring, be uniform state and do not have caking | Qualified | |
| Aggregate settleability % | ????＜10％ | Qualified | ||
| Package stability | Low tempertaure storage | 3 times the no lump in test back do not have cohesion and form variation | Qualified | |
| Heat-storage | Do not have lump, mouldy, cohesion after 1 month and form to change | Qualified | ||
| The dope layer test | Time of drying | Surface drying≤2 hour | Qualified | |
| Color and outward appearance | Relatively there is not significant difference with model | Qualified | ||
| Water tolerance | Soaked in 240 hours, the coating flawless, bubble, peel off, softening thing separates out, color, gloss have a little and change | Qualified | ||
| Alkali resistance | Soaked in 240 hours, the coating flawless, bubble, peel off, softening thing separates out, color, gloss allow to change a little | Qualified | ||
| Abrasion resistance | Scrub test back coating no change for 1000 times | 2000 times | ||
| Anti-contamination rate % | Behind 5 staining tests, contamination rate≤15% | Qualified | ||
| The anti-cyclicity of freezing | 10 circulation back coating flawlesses, bubble, peel off, color gloss allows to change a little | Qualified | ||
| Cohesive strength | ????＞0.69Mpa | Qualified | ||
| The artificial weathering resistance of quickening | Coating flawless after 500 hours, bubble, peel off, efflorescence, variable color＜2 grade | Qualified | ||
In addition, compare with emulsion paint commonly used, colar glaze guartz paint has better ornamental and decorative effect (texture is simple, serious, luxurious), and it is a kind of water-based, nontoxic, high-performance building decorative paint really.From economically, guaranteeing that the present invention has the low characteristics of production cost under the high-performance prerequisite, with the like product comparison of import,, still can make manufacturing enterprise obtain favorable economic benefit even price reduces about 1/3rd.
Claims (12)
1, a kind of manufacture method of colar glaze guartz paint, by colar glaze guartz sand preparation technology, polymer slurry preparation technology and colar glaze guartz paint modulation process are formed; Wherein colar glaze guartz sand preparation technology is made up of operations such as preparation colorant, coating quartz, dry colored stone, aftertreatments in regular turn; Polymer slurry preparation technology is made up of the operation of polymer binder and additive formula mixed preparing polymer slurries; The colar glaze guartz paint modulation process is made up of colar glaze guartz sand and polymer slurries hybrid modulation operation; It is characterized in that: the preparation colorant operation among the colar glaze guartz sand preparation technology, be the two class raw materials that require to adopt certain proportioning according to decorating, can generate the mineral compound basic material and the mineral compound basic material that can generate glaze of pigment, be made as the colorant process for preparation of quartz sand colorant through mixing, sieving, in this technology, between dry colored stone operation and postprocessing working procedures, also be provided with the middle temperature ablating work procedure of colored stone under 600 ℃～1000 ℃ temperature; Described polymer slurry preparation technology is according to decorating requirement, adopting the polymer binder and the additive of multiple different performance and proportioning, the process of mixed preparing polymer slurries.
2, according to the manufacture method of the described colar glaze guartz paint of claim 1, it is characterized in that: in the preparation technology of colar glaze guartz sand, described postprocessing working procedures, be the quartz sand that will be coated with colorant, temperature is fired the back taking-up in finishing in stove, obtains the treating processes of colar glaze guartz sand after cooling, crushing, screening.
3, according to the manufacture method of the described colar glaze guartz paint of claim 1, it is characterized in that: in colar glaze guartz sand preparation technology, the proportioning raw materials of employing is: prescription: quartz sand (18～140 order) 60～95%
Colorant (＞325 order) 5～40% wherein colorant consists of: zinc oxide 5～12% saltpetre 5～1%
Antimonous oxide 7～11% red leads 50～71%
Boric acid 8～2% silicon-dioxide 25～3%
4, according to the manufacture method of the described colar glaze guartz paint of claim 1, it is characterized in that: in colar glaze guartz sand preparation technology, the proportioning raw materials of employing is: prescription: quartz sand (18～140 order) 60～95%
Colorant (＞325 order) 5～40% wherein colorant consists of: zinc oxide 35～12% silicon-dioxide 8～2.8%
Boric acid 10～20% red leads 17～35%
Aluminum oxide 15～30% cobalt sesquioxides 15～0.2%
5, according to the manufacture method of the described colar glaze guartz paint of claim 1, it is characterized in that: in colar glaze guartz sand preparation technology, the proportioning raw materials of employing is: prescription: quartz sand (18～140 order) 55～95%
Colorant (＞325 order) 5～45% wherein colorant consists of: ferric oxide 1.5～12% zinc oxide 0.5～5%
Saltpetre 10～1% red leads 20～49%
Antimonous oxide 8～20% boric acid 35～10%
Silicon-dioxide 25～3% ferric sulfate 0～7%
6, according to the manufacture method of the described colar glaze guartz paint of claim 1, it is characterized in that: in colar glaze guartz sand preparation technology, the proportioning raw materials of employing is: prescription: quartz sand (18～140 order) 65～95%
Colorant (＞325 order) 5～35% wherein colorant consists of: lime carbonate 0.5～8% salt of wormwood 1～11%
Cadmium carbonate 5～25% boric acid 3～10%
Red lead 15～25% zinc oxide 0.1～5%
Silicon-dioxide 20～30% plumbous oxide 0.5～10%
Borax 3～10% selenium 0.1～2%
Sulphur 2～12%
7, according to the manufacture method of the described colar glaze guartz paint of claim 1, it is characterized in that: in colar glaze guartz paint preparation technology, the proportioning raw materials of employing is: prescription: benzene emulsion 13～25% film coalescence aid 1～3%
Thickening material 0.05～0.25% mould inhibitor 0.1～0.3%
Titanium dioxide 0.05～1.5% talcum powder 0.05～5%
Anti-settling agent 0.05～0.1% defoamer is an amount of
Water 1～10% colar glaze guartz sand 5～35%
Quartz sand 40～60%
8, according to the manufacture method of the described colar glaze guartz paint of claim 1, it is characterized in that: in colar glaze guartz paint preparation technology, the proportioning raw materials of employing is: prescription: vinyl acetate-ethylene copolymerization emulsions (or using aqueous polyvinyl acetate emulsion) 15～30%
Film coalescence aid 1～5% thickening material 0.05～0.1%
Mould inhibitor 0.1～0.3% titanium dioxide 0.05～0.1%
Talcum powder 0.05～5% anti-settling agent 0.05～0.2%
Water 3～15% defoamers are an amount of
Colar glaze guartz sand 3～10% quartz sands 50～70%
9, according to the manufacture method of the described colar glaze guartz paint of claim 1, it is characterized in that: in colar glaze guartz paint preparation technology, the proportioning raw materials of employing is: prescription: nucleocapsid benzene emulsion (or using pure-acrylic emulsion) 13～50%
Film coalescence aid 1～4% thickening material 0.05～0.15%
Mould inhibitor 0.1～0.5% titanium dioxide 0.01～2.0%
Talcum powder 0～1% anti-settling agent 0.03～0.25%
Water 1～5% defoamer is an amount of
Colar glaze guartz sand 5～60% quartz sands 25～50%
10, according to the manufacture method of the described colar glaze guartz paint of claim 1, it is characterized in that: in colar glaze guartz paint preparation technology, the proportioning raw materials of employing is: prescription: organosilicon crylic acid latex (or using the poly organic silicon emulsion) 15～25%
Film coalescence aid 1～5% thickening material 0.05～0.25%
Mould inhibitor 0.1～0.5% titanium dioxide 0.05～2.0%
Talcum powder 0～2% anti-settling agent 0.03～0.3%
Water 1～10% defoamer is an amount of
Colar glaze guartz sand 5～65% quartz sands 35～55%
11, according to the manufacture method of the described colar glaze guartz paint of claim 1, it is characterized in that: in colar glaze guartz paint preparation technology, the proportioning raw materials of employing is: prescription: vinegar-acrylic emulsion (or with vinyl acetate-tertiary ethylene carbonate copolymer emulsion) 15～30%
Film coalescence aid 1～5% thickening material 0.05～0.1%
Mould inhibitor 0.01～0.3% titanium dioxide 0.1～0.5%
Talcum powder 0.3～3% anti-settling agent 0.05～0.25%
Water 3～15% defoamers are an amount of
Colar glaze guartz sand 3～10% quartz sands 45～65%
12, according to the manufacture method of the described colar glaze guartz paint of claim 1, it is characterized in that: in colar glaze guartz paint preparation technology, the proportioning raw materials of employing is: prescription: benzene emulsion 8～20% commixed type organosilicon crylic acid latexs 3～10%
Film coalescence aid 1～4% thickening material 0.05～0.15%
Mould inhibitor 0.05～0.15% titanium dioxide 0.1～0.35%
Talcum powder 0.～0.15% anti-settling agent 0.03～0.3%
Water 1～5% defoamer is an amount of
Colar glaze guartz sand 5～60% quartz sands 25～50%
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB011337486A CN1169892C (en) | 2001-12-27 | 2001-12-27 | Production process of colar glaze guartz paint |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB011337486A CN1169892C (en) | 2001-12-27 | 2001-12-27 | Production process of colar glaze guartz paint |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1357580A true CN1357580A (en) | 2002-07-10 |
| CN1169892C CN1169892C (en) | 2004-10-06 |
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| CNB011337486A Expired - Fee Related CN1169892C (en) | 2001-12-27 | 2001-12-27 | Production process of colar glaze guartz paint |
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|---|---|---|---|---|
| CN100513342C (en) * | 2006-12-04 | 2009-07-15 | 武汉共达材料科技有限公司 | Pavement colored sand and its preparation |
| CN102180620A (en) * | 2011-01-28 | 2011-09-14 | 牛智勇 | A kind of preparation technology of vitrified stone paint |
| CN102304310A (en) * | 2011-06-10 | 2012-01-04 | 卢晓谊 | Particles showing yellow and having golden gloss |
| CN101704266B (en) * | 2009-11-17 | 2012-01-11 | 哈尔滨工业大学 | Method for preparing organic silicon colored sand |
| RU2466970C1 (en) * | 2011-07-06 | 2012-11-20 | Юлия Алексеевна Щепочкина | Glaze charge |
| RU2473525C1 (en) * | 2011-09-30 | 2013-01-27 | Юлия Алексеевна Щепочкина | Tile glaze |
| CN102953535A (en) * | 2012-10-26 | 2013-03-06 | 浙江未来家木业有限公司 | Glazed floor board processing technology |
| CN102976646A (en) * | 2012-11-26 | 2013-03-20 | 孙志勤 | Method for preparing agate red colored stands |
| CN103274618A (en) * | 2013-06-08 | 2013-09-04 | 合肥万博制漆有限公司 | Real mineral varnish sintered sand manufacturing method |
| CN103571288A (en) * | 2013-10-25 | 2014-02-12 | 安徽工贸职业技术学院 | Color powder coating |
| CN103571286A (en) * | 2013-10-25 | 2014-02-12 | 安徽工贸职业技术学院 | Preparation method of color powder coating |
| CN103910502A (en) * | 2013-01-05 | 2014-07-09 | 潍坊龙成建材有限公司 | Colored sand capable of coloring by reaction and its preparation method |
| CN104176977A (en) * | 2013-05-21 | 2014-12-03 | 辽宁明上建材工业有限公司 | Stone like coating prepared by using waste ceramic, and its preparation method |
| CN104356810A (en) * | 2014-11-21 | 2015-02-18 | 苏州大乘环保建材有限公司 | Reflective thermal insulation real stone paint |
| CN105859137A (en) * | 2016-03-30 | 2016-08-17 | 安徽青花坊瓷业股份有限公司 | Cover glaze for preparing high temperature in-glaze color |
| CN109734317A (en) * | 2019-03-21 | 2019-05-10 | 北京工业大学 | A kind of colored sand for construction, preparation method and application |
| CN110642972A (en) * | 2019-09-26 | 2020-01-03 | 青岛天地彩涂料工程应用有限公司 | Weather-resistant exterior wall coating with 10-year gradient colors and manufacturing method thereof |
| CN114347244A (en) * | 2022-01-20 | 2022-04-15 | 河北久申防水建筑材料有限公司 | Calcined mellow color sand |
| CN110644732B (en) * | 2019-09-30 | 2023-12-05 | 江苏久诺新材科技股份有限公司 | Spraying process of waterproof white stone paint |
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2001
- 2001-12-27 CN CNB011337486A patent/CN1169892C/en not_active Expired - Fee Related
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|---|---|---|---|---|
| CN100513342C (en) * | 2006-12-04 | 2009-07-15 | 武汉共达材料科技有限公司 | Pavement colored sand and its preparation |
| CN101704266B (en) * | 2009-11-17 | 2012-01-11 | 哈尔滨工业大学 | Method for preparing organic silicon colored sand |
| CN102180620A (en) * | 2011-01-28 | 2011-09-14 | 牛智勇 | A kind of preparation technology of vitrified stone paint |
| CN102180620B (en) * | 2011-01-28 | 2012-10-10 | 牛智勇 | Preparation process of vitrified stone paint |
| CN102304310A (en) * | 2011-06-10 | 2012-01-04 | 卢晓谊 | Particles showing yellow and having golden gloss |
| RU2466970C1 (en) * | 2011-07-06 | 2012-11-20 | Юлия Алексеевна Щепочкина | Glaze charge |
| RU2473525C1 (en) * | 2011-09-30 | 2013-01-27 | Юлия Алексеевна Щепочкина | Tile glaze |
| CN102953535B (en) * | 2012-10-26 | 2015-06-03 | 浙江未来家木业有限公司 | Glazed floor board processing technology |
| CN102953535A (en) * | 2012-10-26 | 2013-03-06 | 浙江未来家木业有限公司 | Glazed floor board processing technology |
| CN102976646A (en) * | 2012-11-26 | 2013-03-20 | 孙志勤 | Method for preparing agate red colored stands |
| CN103910502A (en) * | 2013-01-05 | 2014-07-09 | 潍坊龙成建材有限公司 | Colored sand capable of coloring by reaction and its preparation method |
| CN104176977A (en) * | 2013-05-21 | 2014-12-03 | 辽宁明上建材工业有限公司 | Stone like coating prepared by using waste ceramic, and its preparation method |
| CN103274618A (en) * | 2013-06-08 | 2013-09-04 | 合肥万博制漆有限公司 | Real mineral varnish sintered sand manufacturing method |
| CN103571288A (en) * | 2013-10-25 | 2014-02-12 | 安徽工贸职业技术学院 | Color powder coating |
| CN103571286A (en) * | 2013-10-25 | 2014-02-12 | 安徽工贸职业技术学院 | Preparation method of color powder coating |
| CN104356810A (en) * | 2014-11-21 | 2015-02-18 | 苏州大乘环保建材有限公司 | Reflective thermal insulation real stone paint |
| CN104356810B (en) * | 2014-11-21 | 2016-09-21 | 苏州大乘环保建材有限公司 | A kind of true mineral varnish of reflection heat-insulating type |
| CN105859137A (en) * | 2016-03-30 | 2016-08-17 | 安徽青花坊瓷业股份有限公司 | Cover glaze for preparing high temperature in-glaze color |
| CN109734317A (en) * | 2019-03-21 | 2019-05-10 | 北京工业大学 | A kind of colored sand for construction, preparation method and application |
| CN110642972A (en) * | 2019-09-26 | 2020-01-03 | 青岛天地彩涂料工程应用有限公司 | Weather-resistant exterior wall coating with 10-year gradient colors and manufacturing method thereof |
| CN110644732B (en) * | 2019-09-30 | 2023-12-05 | 江苏久诺新材科技股份有限公司 | Spraying process of waterproof white stone paint |
| CN114347244A (en) * | 2022-01-20 | 2022-04-15 | 河北久申防水建筑材料有限公司 | Calcined mellow color sand |
| CN114347244B (en) * | 2022-01-20 | 2024-09-17 | 河北久申防水建筑材料有限公司 | Calcined round color sand and manufacturing process thereof |
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