CN106243966A - A kind of composite multifunction double-component aqueous woodenware white finish paint and preparation method thereof - Google Patents
A kind of composite multifunction double-component aqueous woodenware white finish paint and preparation method thereof Download PDFInfo
- Publication number
- CN106243966A CN106243966A CN201610749993.1A CN201610749993A CN106243966A CN 106243966 A CN106243966 A CN 106243966A CN 201610749993 A CN201610749993 A CN 201610749993A CN 106243966 A CN106243966 A CN 106243966A
- Authority
- CN
- China
- Prior art keywords
- component
- water
- aqueous
- model
- finish paint
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D175/00—Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
- C09D175/04—Polyurethanes
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/14—Paints containing biocides, e.g. fungicides, insecticides or pesticides
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/16—Antifouling paints; Underwater paints
- C09D5/1656—Antifouling paints; Underwater paints characterised by the film-forming substance
- C09D5/1662—Synthetic film-forming substance
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/16—Antifouling paints; Underwater paints
- C09D5/1687—Use of special additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/014—Additives containing two or more different additives of the same subgroup in C08K
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Plant Pathology (AREA)
- Paints Or Removers (AREA)
- Chemical And Physical Treatments For Wood And The Like (AREA)
Abstract
The invention discloses a kind of composite multifunction double-component aqueous woodenware white finish paint, including first component, component B and water, the proportion by weight of described first component, component B and water is 100:20～25:10～20, and wherein first component is made up of the raw material of following weight/mass percentage composition: water based acrylic resin, composite modified self-crosslinking acrylic polymer, aqueous titanium dioxide slurry, aqueous delustering agent, defoamer, wetting agent, thickening agent, dispersant, levelling agent, antimildew disinfectant, surplus are water；Component B is made up of the raw material of following weight/mass percentage composition: hydrophilic aliphatic polyisocyanate and propylene glycol methyl ether acetate, this composite multifunction double-component aqueous woodenware white finish paint antibacterial except aldehyde spot-resistant effective, environmental protection, hardness is good, and richness is high, moderate cost.
Description
Technical field
The invention belongs to double-component aqueous woodwork coating technical field, be specifically related to a kind of composite multifunction double-component aqueous
Woodenware white finish paint and preparation method thereof.
Background technology
Woodwork coating is as a kind of ornament materials, and its ornamental requirement and environmental-protecting performance are more and more higher, fills as woodenware
Exterior material, traditional double-component solvent-borne type PU woodwork coating, formula for a product and technique are the most ripe, and properties of product are also to meet
Higher demand, is mainly manifested in richness good, and hardness is higher, can reach 2H-3H, high temperature resistant good with alcohol resistance, is difficult to loss of gloss
Pool, but owing to it contains a large amount of volatile organic matter (VOC), the health of atmospheric pollution and workmen is all brought certain danger
Evil, the environmental protection policy relevant by country is limited more and more obvious.And single-component water-based woodwork coating sharpest edges are environmental protection, permissible
Directly dilute with water is constructed, but its paint film property has brighter with traditional double-component solvent-borne type PU woodwork coating than still at present
Aobvious gap, is mainly manifested in construction admittedly containing relatively low, and richness and hardness are the most poor, and hardness is typically between F-HB scope, same
Time high temperature resistant and alcohol resistance the most poor, easy loss of gloss.To this end, people are seeking energy a kind of with research substitutes traditional double groups always
The double-component aqueous woodwork coating of part solvent-borne type PU woodwork coating, because it meets under environmental-protecting performance premise, more can be at woodenware table
Face obtains to be had or close to the same painting effect of traditional solvent-borne PU woodwork coating.Prior art also has many patents or
Document discloses some double-component aqueous woodwork coating and production methods thereof, but the painting effect in these patents, it is mostly
Meeting some Fundamental Physical Properties indexs of environmental-protecting performance and paint film, other special additional functions are the most less desirable, and cost
Height, additionally, these coating the most simultaneously spot-resistant and additional complex function such as antifungal, except features such as formaldehyde, the most not
Performance can be taken into account and antibacterial except the performance such as formaldehyde, spot-resistant.
Summary of the invention
It is an object of the invention to provide a kind of composite multifunction double-component aqueous woodenware white finish paint, this double-component aqueous wood
Device white finish paint forms high richness, the good white effect coating of hardness on woodenware base material, additional complex function such as antifungal, except first
The feature such as aldehyde, spot-resistant, the double-component aqueous woodenware white finish paint in the present invention does not contains the organic exhaust gas such as formaldehyde, healthy ring simultaneously
Protect.
The present invention also aims to provide the above-mentioned preparation side with composite multifunction double-component aqueous woodenware white finish paint
Method, the method technique is simple, and cost is reasonable, and the expense of per kilogram can reduce by 2～3 yuan by relatively like product.
First purpose of the present invention is achieved by the following technical solution: a kind of composite multifunction is double-component aqueous
Woodenware white finish paint, including first component, component B and water, the proportion by weight of described first component, component B and water be 100:20～
25:10～20, wherein first component is made up of the raw material of following weight/mass percentage composition:
Water based acrylic resin 30～40%
Composite modified self-crosslinking acrylic polymer 20～30%
Aqueous titanium dioxide slurry 25～30%
Aqueous delustering agent 1～3%
Defoamer 0.3～0.6%
Wetting agent 0.3～0.5%
Thickening agent 0.3～1.0%
Dispersant 0.3～0.6%
Levelling agent 0.2～0.4%
Antimildew disinfectant 2～3%
Surplus is water；
Component B is made up of the raw material of following weight/mass percentage composition:
Hydrophilic aliphatic polyisocyanate 70～75%,
Propylene glycol methyl ether acetate PMA 25～30%.
Wherein the composite modified self-crosslinking acrylic polymer described in first component is by the raw material of following weight/mass percentage composition
Make:
Self-crosslinking acrylic polymer 65～70%
Dipropylene glycol methyl ether DPM 5～10%
Dipropylene DPNB 1～3%
Propylene glycol 0.5～1%
Wetting agent 0.5～1%
Dispersant 0.5～1%
Defoamer 0.5～1%
Water-borne wax emulsion 1～3%
Eliminate the function additive SAMASO FA16 2～3% of formaldehyde
Antimildew disinfectant 1～2%
Surplus is water.
Aqueous titanium dioxide slurry described in first component is made up of the raw material of following weight/mass percentage composition:
Dispersant 3～4%
Rutile titanium white lead 70～75%
Aerosil 0.3～0.5%
Preservative 0.3～0.5%
Ultramarine 0.1～0.3%
Surplus is water.
Self-crosslinking acrylic polymer of the present invention preferably produces purchased from U.S.'s ROHM AND HAAS (Chinese) chemical company
Aqueous acrylamide acid polymer, model is elastene 3030, and its solid content is 48～49%, and minimum film formation temperature is 0 DEG C,
Without APEO and ammonia.
Water-borne wax emulsion of the present invention is preferably the polytetrafluoro that model is WW-1077 that Arkema of France produces
The model that ethylene waxes dispersion, Bi Ke chemical company of Germany produce is the one or several in BYK-539 wax emulsion and modified paraffin
Kind.
The function additive SAMASO FA16 of elimination formaldehyde of the present invention is the elimination first that Sa Masuo company of Germany produces
The specific function auxiliary agent of aldehyde, decomposes the first of absorption in dope layer by the way of its particular molecule is designed to by chemical reaction
Aldehyde, thus the effect of the quality that reaches to purify the air of a room.
Composite membrane-forming auxiliary agent dipropylene glycol methyl ether DPM and dipropylene DPNB of the present invention is preferably purchased from the U.S.
The coalescents that Dow Chemical produces.
Water based acrylic resin of the present invention produces purchased from Opel enlightening resin (Shenzhen) company limited of Germany
Water-based hydroxyl acrylate copolymer, this product type is AC 27401.Its hydroxy radical content is 4.7%, its solid content be 37～
39%, minimum film formation temperature is 15 DEG C, has outstanding chemical resistance and a mechanical performance, easy cleaning coating and heat-resist.
Composite modified self-crosslinking acrylic polymer of the present invention, for independent research intermediate, central aqueous acrylamide
The aqueous acrylamide acid polymer that acid polymer produces purchased from U.S.'s ROHM AND HAAS (Chinese) chemical company, this product type is
Elastene 3030, its solid content is 48～49%, and minimum film formation temperature is 0 DEG C, without APEO and ammonia.
The synthetic resin emulsion being currently used for producing double-component aqueous wood paint is mainly water-based hydroxyl acrylate copolymer.
There are some researches show water-based hydroxyl acrylate copolymer, found that different manufacturers produces the kind of this type of emulsion and different consumptions
All antibacterial influential effects except aldehyde and spot-resistant to film are distinguished little.
But in daily life, indoor antibacterial and mycete, under conditions of air humidity is relatively big, easily grow at furniture
Surface on, affect the health of people；And the material plate of wood furniture processes on surface and is likely to have the residual of formaldehyde, the most difficult
Exempt from some beverages such as tea, coffee to be sprinkled upon on white furniture surface；Again or child exists with ball pen, pen, free ink pen etc.
Coating and drawing at random in white Furniture Factory, causes white furniture surface pole unsightly, is difficult to again by some simple methods these are dirty
Stain is disposed.In order to let us is in the face of these spots when, only just these greasiness removals need to can be made white with wet rag
Furniture surface returns to former state, does not the most discharge noxious pollutant simultaneously, and present invention applicant finds through substantial amounts of experiment sieving,
The aqueous acrylamide acid polymer that U.S.'s ROHM AND HAAS (Chinese) chemical company produces, this product type is elastene 3030, tool
There is special molecular structure, the formaldehyde that can effectively reduce by irreversible chemical reaction and decompose in air, various base materials are had
Having good putting forth effort, outstanding scrub resistance and outstanding room temperature elastic, it also has the resistance to hydrophilic stains of excellence simultaneously
With resistance to hydrophobic stains performance, and a small amount of coalescents can be only needed i.e. to can reach the filming performance of excellence in basic components,
It is AP-Free product, without formaldehyde, meets health environment-friendly requirement.
So, it is based primarily upon the excellence of this aqueous pure acrylic acid polymer and refers to except aldehyde and spot-resistant performance and environmental-protecting performance
Mark, this aqueous pure acrylic acid polymer, present invention applicant finally selects to use ROHM AND HAAS (Chinese) chemical company of the U.S. raw
The aqueous pure acrylic acid polymer elastene 3030 produced, as main intermediate raw material, designs exclusively for improving Waterborne wood
Device white finish paint spot-resistant performance and the composite modified self-crosslinking acrylic polymer that designs, because by great many of experiments, find
If elastene 3030 aqueous acrylamide acid polymer and water-based hydroxyl acrylate copolymer directly blending, find that both are compatible
Property poor, particularly when joining paint add with introduce hydrophilic aliphatic polyisocyanate be Bayer A.G produce model
For Bayhydur XP 2655, the compatibility becomes worse, directly influences the final effect of bin stability and paint film, so must
Must elastene 3030 be carried out composite modified.
The present invention is directed to as its special structure of elastene 3030, intermediate based on elastene 3030,
Introduce hydrophilic auxiliary coalescents DPM (dipropylene glycol methyl ether) and oil loving coalescents DPNB (dipropylene glycol fourth
Ether), and add appropriate hydrophilic propylene glycol with improve elastene 3030 in aqueous double-component woodcare paint with aqueous hydroxyl
Base acrylate copolymer, this product type is AC 27401 compatible stability, simultaneously actual join paint during send out through overtesting
Now it is that Bayhydur XP 2655 can have more with the model that hydrophilic aliphatic polyisocyanate is Bayer A.G's production
The good compatibility, does not interferes with the chemical reaction of the esterification of AC27401 Yu Bayhydur XP 2655, thus is formed finer and close
Paint film.
The polyethers that model is BYK-346 that wetting agent of the present invention preferably produces purchased from Bi Ke chemical company of Germany changes
Property polysiloxane solution and/or win wound industrial group produce the polyether siloxane copolymer that model is TEGO-270.
Polycarboxylate sodium's type that model is SN-5040 that dispersant of the present invention preferably produces purchased from Japan Nuo Puke
The organically-modified polyacrylic acid containing pigment affinity groups that model is TEGO-735W that dispersant, win wound industrial group produce
One or more in ester solution and high-performance polymer type wetting dispersing agent that model is TEGO-750W.
Defoamer of the present invention is preferably purchased from winning the polyethers silica that model is TEGO-902W that wound industrial group produces
One or two in the defoamer based on mineral oil that model is BYK-094 that alkyl copolymer and Bi Ke company of Germany produce
Kind.
The model that antimildew disinfectant of the present invention preferably produces purchased from Rhom and Hass of the U.S. is ROCIMA 342
Antimildew disinfectant, its chemical composition is mainly the mixture of alkyl benzene sulphonate, octylisothiazolinone and Copper hydrate；Add
The new formula of the specific function auxiliary agent of the antimildew disinfectant that model is ROCIMA 342 that Rhom and Hass of the U.S. produces, makes
Obtaining coating and possessed anti-microbial property, antibacterial purifying effect persistency is good.
The model that aqueous delustering agent of the present invention preferably produces purchased from glaze chemical company of the U.S. is CP4-8991
Aqueous delustering agent.
The model that thickening agent of the present invention preferably produces purchased from LG-DOW chemical company is R-8W and/or RM2020
The most solvent-laden non-ionic polyurethane association thickener.
The polyethers that model is BYK-333 that levelling agent of the present invention preferably produces purchased from Bi Ke chemical company of Germany changes
Property polydimethylsiloxane solution and/or win wound industrial group produce the polyether siloxane copolymer that model is TEGO-410.
Pigment in aqueous titanium dioxide slurry of the present invention includes rutile titanium white lead and ultramarine.
Hydrophilic aliphatic polyisocyanate of the present invention is preferably the model of Bayer A.G's production
The chemical composition of Bayhydur XP 2655 is mainly hydrophilic aliphatic based on hexamethylene diisocyanate (HDI) and gathers different
Cyanate.
Propylene glycol methyl ether acetate of the present invention is preferably the propylene glycol first that Jiangsu Hua Lun Chemical Co., Ltd. produces
Ether acetate PMA environmentally friendly solvent.
In view of cost and antibacterial effect of formaldehyde, it is ROCIMA that the present invention adds the model of Rhom and Hass of U.S. production
The specific function auxiliary agent eliminating formaldehyde that the antimildew disinfectant of 342 and Sa Masuo company of Germany produce, model is SAMASO
FA16, so that the design of this formula takes into account antibacterium and antifungal, except formaldehyde and purifying air, the composite multifunction of spot-resistant.Increase
The addition of thick dose makes the coating preparing out be thick shape slurry, it is simple to trowelling application；Defoamer, wetting agent, dispersant and kill
Bacterium preservative etc. is also indispensable in the design of high-performance waterborne wood coating formula.
Second goal of the invention of the present invention is achieved through the following technical solutions: above-mentioned composite multifunction double-component
The preparation method of aqueous wooden ware white finish paint, containing following steps:
(1) prepare composite modified self-crosslinking acrylic polymer: by quantitative relation, choose the composite modified self-crosslinking third of preparation
Each raw material of olefin(e) acid polymer, first takes from crosslinked acrylic acid polymer, defoamer, wetting agent, dispersant and antimildew disinfectant, adds
Enter part water, stir 5～10 minutes with the stir speed (S.S.)s of 800～1000 revs/min, be subsequently adding dipropylene glycol methyl ether, dipropyl two
Alcohol butyl ether and propylene glycol, stir 10～15 minutes with the stir speed (S.S.)s of 400～600 revs/min, adds water-borne wax emulsion, eliminates first
The function additive SAMASO FA16 of aldehyde and remaining water, stir 5～10 minutes with the stir speed (S.S.)s of 200～400 revs/min, prepares
Composite modified self-crosslinking acrylic polymer；
(2) the composite modified self-crosslinking acrylic polymer of preparation in step (1) is joined water-based hydroxyl acrylic acid tree
In fat, under the stir speed (S.S.) of 400～600 revs/min, then press quantitative relation add defoamer, wetting agent, thickening agent and dispersion
Agent, adds part water, stirs 5～10 minutes with the stir speed (S.S.)s of 400～600 revs/min, is subsequently adding aqueous delustering agent, with
The stir speed (S.S.) of 1000～1200 revs/min stirs 15～20 minutes, be distributed to fineness qualified after, add levelling agent, antimycotic antiseptic
Agent and remaining water, stir 5～10 minutes with the stir speed (S.S.)s of 300～500 revs/min, make uniform sizing material；
(3) preparation aqueous titanium dioxide slurry: choose each raw material of preparation aqueous titanium dioxide slurry by quantitative relation, first take dispersant, gold
Red stone titanium dioxide, aerosil, preservative and ultramarine, add part water, stir with the stir speed (S.S.) of 1200～1500 revs/min
Mix 20～25 minutes, be dispersed to fineness qualified after, add in remaining water, make aqueous titanium dioxide slurry；
(4) the aqueous titanium dioxide slurry that step (3) is made is joined in the slurry that step (2) is made, with 400～500 revs/min
Stir speed (S.S.) stir 20～25 minutes, prepare first component；
(5) by fast with the stirring of 400～500 revs/min to hydrophilic aliphatic polyisocyanate and propylene glycol methyl ether acetate
Rate stirs 10～15 minutes, prepares component B；
(6) choose first component, component B and water by quantitative relation, first add water to first component stirs evenly, add second group
Part stirs evenly, and i.e. prepares the double-component aqueous woodenware white finish paint of composite multifunction after standing.
Further, particularly as follows: press following construction proportioning in step (6), first component: component B: water is 100:20～25:
10～20, first appropriate water is added first component and first stir, after being subsequently adding component B, then stir, stand
Spray after 10～15 minutes or brush.
In above-mentioned steps:
In step (1) and step (2), the addition of part water accounts for this step water gross mass 70～80%；In step (3)
The addition of part water accounts for the 60～70% of this step water gross mass.
Present invention have the advantage that
(1) the double-component aqueous woodenware white finish paint of the composite multifunction in the present invention, gives paint film excellent antibacterial except aldehyde merit
Can, do not contain the organic exhaust gas such as formaldehyde, health environment-friendly, spot-resistant；
(2) the double-component aqueous woodenware white finish paint materials of composite multifunction of the present invention rationally, moderate cost, every physical property
Can show outstanding, apply performance good；
(3) due to the fact that have employed exclusively for improve water-borne wood coating spot-resistant and design except aldehyde performance compound
Modified self-crosslinking acrylate copolymer, for improving the compatibility and the stability of product；
(4) in view of cost and antibacterial effect of formaldehyde, the present invention adds the model of Rhom and Hass of U.S. production and is
The specific function auxiliary agent eliminating formaldehyde that the biocide mildewcide of ROCIMA 342 and Sa Masuo company of Germany produce, model is
SAMASO FA16, cost advantage is obvious, adjusts through formulation cost, and resistant product similar with market compares discoverys, and cost is flat
All declining 2～3 yuan of per kilograms, the most high-grade, cost declines the most；The reason that its cost declines, is to add some spies
Different organic silicon emulsion or hydrophobic auxiliary agent realize, and both market prices rear are high, and dosage is the most more, scrubbing resistance and spot-resistant
Effect is not the most lasting, and basic components cost increases substantially, and these common like products the most do not possess antibacterial except aldehyde function, city simultaneously
Field synthesized competitiveness is general.
Accompanying drawing explanation
Fig. 1 is that the composite multifunction double-component aqueous woodenware white finish paint that embodiment of the present invention 1-3 is made is firm with conventional coating
Spot design sketch in brushing, the spot-resistant double-component aqueous woodenware white finish paint coating that wherein A figure is common on market, B figure is this
The double-component aqueous woodenware white finish paint of invention composite multifunction；
Fig. 2 is the composite multifunction double-component aqueous woodenware white finish paint and conventional coating that embodiment of the present invention 1-3 is made
After spot is cleaned, result of the test compares schematic diagram, the spot-resistant double-component aqueous woodenware white finish paint that wherein C figure is common on market
Coating, D figure is the double-component aqueous woodenware white finish paint of composite multifunction of the present invention.
Detailed description of the invention
Raw material employed in following example, if no special instructions, is commercially available prod.
Composite multifunction double-component aqueous woodenware white finish paint prepared by the Part I present invention
Embodiment 1
The composite multifunction double-component aqueous woodenware white finish paint that the present embodiment provides, including first component, component B and water, first
The proportion by weight of component, component B and water is 100:20:20, and concrete formula can be formulated as follows (weight/mass percentage composition):
A first component:
Water based acrylic resin 30%
Composite modified self-crosslinking acrylic polymer 30%
Aqueous titanium dioxide slurry 25%
Aqueous delustering agent 3%
Defoamer 0.5%
Wetting agent 0.3%
Thickening agent 0.5%
Dispersant 0.5%
Levelling agent 0.2%
Antimildew disinfectant 3%
Water 7%,
In first component, the weight/mass percentage composition sum of each raw material is 100%；
B component B
Hydrophilic aliphatic polyisocyanate 75%,
Propylene glycol methyl ether acetate (PMA) 25%
Each raw materials quality percentage composition sum is 100%；
Wherein in first component, composite modified self-crosslinking acrylic polymer is made up of the component of following weight/mass percentage composition: water
10%, self-crosslinking acrylic polymer 70%, dipropylene glycol methyl ether DPM 6.5%, dipropylene DPNB 3%, propylene glycol
1%, wetting agent 0.5%, dispersant 0.5%, defoamer 0.5%, water-borne wax emulsion 3%, eliminates the specific function auxiliary agent of formaldehyde
SAMASO FA16 3%, antimildew disinfectant 2%.
Wherein aqueous titanium dioxide slurry is made up of the component of following weight/mass percentage composition: water 20%, dispersant 3.8%, rutile
Titanium dioxide 75%, aerosil 0.5%, preservative 0.5%, ultramarine 0.2%.
The water-based hydroxyl propylene that water based acrylic resin produces purchased from Opel enlightening resin (Shenzhen) company limited of Germany
Acid polymer, this product type is AC 27401 (hydroxy radical content of 4.7%).
The water soluble acrylic acid polymerization that self-crosslinking acrylic polymer produces purchased from U.S.'s ROHM AND HAAS (Chinese) chemical company
Thing, model is elastene 3030.
The coalescents that dipropylene glycol methyl ether DPM and dipropylene DPNB produces purchased from Dow Chemical company.
Water-borne wax emulsion is the politef wax dispenser that model is WW-1077 that Arkema of France produces.
The specific function auxiliary agent SAMASO FA16 of elimination formaldehyde is the special of the elimination formaldehyde of Sa Masuo company of Germany production
Function additive.
Wetting agent is the Siloxane-Oxyalkylene Copolymers solution that model is BYK-346 that Bi Ke chemical company of Germany produces.
Dispersant is to win organically-modified containing pigment affinity groups that model is TEGO-735W that wound industrial group produces
Polyacrylate solution.
Defoamer is the defoamer based on mineral oil that model is BYK-094 that Bi Ke company of Germany produces, and it is main
Acting on is froth breaking, it is ensured that the paint film flatness of construction.
Antimildew disinfectant is the antimildew disinfectant that model is ROCIMA 342 that Rhom and Hass of the U.S. produces, its chemistry
Composition is mainly the mixture of alkyl benzene sulphonate, octylisothiazolinone and Copper hydrate；With the addition of Rhom and Hass of the U.S.
The new formula of the specific function auxiliary agent of the antimildew disinfectant that model is ROCIMA 342 produced so that coating has possessed antibiotic property
Can, antibacterial purifying effect persistency is good.
The aqueous delustering agent that model is CP4-8991 that aqueous delustering agent produces purchased from glaze chemical company of the U.S..
Thickening agent is that the most solvent-laden non-ionic polyurethane that model is R-8W that LG-DOW chemical company produces associates
Type thickening agent.
Levelling agent is that the polyether-modified polydimethylsiloxane that model is BYK-333 that Bi Ke chemical company of Germany produces is molten
Liquid.
Pigment in aqueous titanium dioxide slurry includes rutile titanium white lead and ultramarine.
Wherein titanium dioxide is import Rutile type titanium dioxide, and model is R-706, and ultramarine is mainly used in adjusting the color of coating
Phase, adds a small amount of, can make coating appearance slightly blue phase, it appears whiteness is higher.Can be selected for arbitrary producer, do not make particularly
Requirement.
Hydrophilic aliphatic polyisocyanate is the change that model is Bayhydur XP 2655 that Bayer A.G produces
Study point predominantly hydrophilic aliphatic polyisocyanate based on hexamethylene diisocyanate (HDI).
Propylene glycol methyl ether acetate is that the propylene glycol methyl ether acetate PMA environmental protection that Jiangsu Hua Lun Chemical Co., Ltd. produces is molten
Agent.
The preparation method of this composite multifunction double-component aqueous woodenware white finish paint is as follows:
(1) composite modified self-crosslinking acrylic polymer is prepared: by above-mentioned magnitude relation, be polymerized by self-crosslinking acrylic
Thing, defoamer, wetting agent, dispersant and antimildew disinfectant, add account for this step water gross mass 70～80% water in, with
Stirring at low speed 5～10 minutes in the stir speed (S.S.) of 800～1000 revs/min, be subsequently adding DPM (dipropylene glycol methyl ether), DPNB (two
Propandiol butyl ether) and propylene glycol, with stirring at low speed in the stir speed (S.S.)s of 400～600 revs/min 10～15 minutes, add water-borne wax
Emulsion, eliminates specific function auxiliary agent SAMASO FA16 and antimildew disinfectant, the remaining water of formaldehyde, with 200～400 revs/min
Stirring at low speed 5～10 minutes in stir speed (S.S.), prepare composite modified self-crosslinking acrylic polymer；
(2) by above-mentioned consumption, slurry (the composite modified self-crosslinking acrylic that step (1) is made in another container
Polymer) join in water based acrylic resin, then with stirring at low speed condition in the stir speed (S.S.) of 400～600 revs/min
Lower addition defoamer, wetting agent, thickening agent and dispersant, add account for this step water gross mass 70～80% water in, with 400
～stirring at low speed 5～10 minutes in the stir speed (S.S.) of 600 revs/min, it is subsequently adding aqueous delustering agent, with 1000～1200 revs/min
Stir speed (S.S.) high speed stir 15～20 minutes, be distributed to fineness qualified after, add levelling agent, antimildew disinfectant and remaining
Water, with stirring at low speed in the stir speed (S.S.)s of 300～500 revs/min 5～10 minutes, makes uniform sizing material；
(3) preparation aqueous titanium dioxide slurry: by above-mentioned magnitude relation in new container, by the dispersion in aqueous titanium dioxide slurry material
Agent, rutile titanium white lead, aerosil, preservative and ultramarine, add and account for this step water gross mass 60～the water of 70%
In, with the stir speed (S.S.) high-speed stirred 20 of 1200～1500 revs/min～25 minutes, be dispersed to fineness qualified after, add remaining
In water, make aqueous titanium dioxide slurry；
(4) the aqueous titanium dioxide slurry that step (3) is made is joined in the slurry that step (2) is made, with 400～500 revs/min
Stir speed (S.S.) stirring at low speed 20～25 minutes, prepare composite multifunction double-component aqueous woodenware white finish paint first component；
(5) by above-mentioned magnitude relation in another container, by hydrophilic aliphatic polyisocyanate and propylene glycol monomethyl ether
Acetate (PMA) joins in hermetic container, with the stir speed (S.S.) stirring at low speed 10 of 400～500 revs/min～15 minutes,
Prepare the double-component aqueous woodenware white finish paint component B of composite multifunction；
(6) construction method of the present invention, by following construction proportioning, first component: component B: water=100:20:20 (mass parts
Proportioning), first appropriate water is added first component and first stir, after being subsequently adding component B, then stir, stand 10
～the double-component aqueous woodenware white finish paint of prepared composite multifunction after 15 minutes, spray or brush.
Embodiment 2
The composite multifunction double-component aqueous woodenware white finish paint that the present embodiment provides, including first component, component B and water, first
The proportion by weight of component, component B and water is 100:22:15, and concrete formula can be formulated as follows (weight/mass percentage composition):
A first component:
Water based acrylic resin 35%
Composite modified self-crosslinking acrylic polymer 25%
Aqueous titanium dioxide slurry 28%
Aqueous delustering agent 2.5%
Defoamer 0.4%
Wetting agent 0.4%
Thickening agent 0.7%
Dispersant 0.5%
Levelling agent 0.3%
Antimildew disinfectant 2.5%
Water 4.7%,
In first component, the weight/mass percentage composition sum of each raw material is 100%；
B component B
Hydrophilic aliphatic polyisocyanate 73%,
Propylene glycol methyl ether acetate (PMA) 27%
In component B, the weight/mass percentage composition sum of each raw material is 100%；
The most composite modified self-crosslinking acrylic polymer is made up of the component of following weight/mass percentage composition: water 16.9%,
Self-crosslinking acrylic polymer 67%, DPM (dipropylene glycol methyl ether) 6%, DPNB (dipropylene) 2%, propylene glycol
0.7%, wetting agent 0.6%, dispersant 0.7%, defoamer 0.6%, water-borne wax emulsion 2%, the specific function eliminating formaldehyde helps
Agent SAMASO FA16 2%, antimildew disinfectant 1.5%.
Wherein aqueous titanium dioxide slurry is made up of the component of following weight/mass percentage composition: water 23.6%, dispersant 3.5%, golden red
Stone titanium dioxide 72%, aerosil 0.4%, preservative 0.4%, ultramarine 0.1%.
As different from Example 1:
The model that water-borne wax emulsion produces purchased from Bi Ke chemical company of Germany is BYK-539 wax emulsion.
Wetting agent is purchased from winning the polyether siloxane copolymer that model is TEGO-270 that wound industrial group produces.
Dispersant is purchased from winning the high-performance polymer type wetting and dispersing that model is TEGO-750W that wound industrial group produces
Agent.
Defoamer is purchased from winning the polyether siloxane copolymer that model is TEGO-902W that wound industrial group produces.
The most solvent-laden non-ionic polyurethane that model is RM2020 that thickening agent produces purchased from LG-DOW chemical company
Association thickener.
Levelling agent is purchased from winning the polyether siloxane copolymer that model is TEGO-410 that wound industrial group produces.
The preparation method of this composite multifunction double-component aqueous woodenware white finish paint is with embodiment 1.
Embodiment 3
The composite multifunction double-component aqueous woodenware white finish paint that the present embodiment provides, including first component, component B and water, first
The proportion by weight of component, component B and water is 100:25:10, and concrete formula can be formulated as follows (weight/mass percentage composition):
A first component:
Water based acrylic resin 40%
Composite modified self-crosslinking acrylic polymer 20%
Aqueous titanium dioxide slurry 25%
Aqueous delustering agent 2%
Defoamer 0.3%
Wetting agent 0.3%
Thickening agent 0.5%
Dispersant 0.5%
Levelling agent 0.2%
Antimildew disinfectant 2%
Water 9.2%,
In first component, the weight/mass percentage composition sum of each raw material is 100%；
B component B；
Hydrophilic aliphatic polyisocyanate 70%,
Propylene glycol methyl ether acetate (PMA) 30%
In component B, the weight/mass percentage composition sum of each raw material is 100%；
The most composite modified self-crosslinking acrylic polymer is made up of the component of following weight/mass percentage composition: water 20%, from
Crosslinked acrylic acid polymer elastene 3,030 65%, DPM (dipropylene glycol methyl ether) 5%, DPNB (dipropylene)
3%, propylene glycol 1%, wetting agent 0.5%, dispersant 0.5%, defoamer 0.5%, water-borne wax emulsion 1%, eliminates the spy of formaldehyde
Different function additive SAMASO FA16 2%, antimildew disinfectant 1.5%.
Wherein aqueous titanium dioxide slurry is made up of the component of following weight/mass percentage composition: water 25%, dispersant 3.9%, rutile
Titanium dioxide 70%, aerosil 0.3%, preservative 0.5%, ultramarine 0.3%.
As different from Example 1:
Water-borne wax emulsion is modified paraffin.
In aqueous titanium dioxide slurry, dispersant is polycarboxylate sodium's type that model is SN-5040 dispersion that Japan Nuo Puke produces
Agent and in composite modified self-crosslinking acrylic polymer in first component dispersant purchased from winning the model that wound industrial group produces be
The organically-modified polyacrylate solution containing pigment affinity groups of TEGO-735W.
The preparation method of this composite multifunction double-component aqueous woodenware white finish paint is with embodiment 1.
The performance test of Part II composite multifunction of the present invention double-component aqueous woodenware white finish paint
Use the composite multifunction double-component aqueous woodenware white finish paint made in the above embodiment of the present invention 1～3, use this
The detection method of field routine detects the conventional physico-chemical properties of this composite multifunction double-component aqueous woodenware white finish paint, specific performance
Index is as shown in table 1 below.
The double-component aqueous woodenware white finish paint of table 1 embodiment of the present invention 1～3 preparation and the traditional performance of film
From table 1 it follows that the properties of composite multifunction double-component aqueous woodenware white finish paint prepared by the present invention
Index all reaches or is better than standard GB/T/T 23999-2009.
The composite multifunction double-component aqueous woodenware white finish paint in above-described embodiment 1-3 is used to carry out spot-resistant performance examination
Testing, process of the test and result are as follows:
Coating application test (one): with hairbrush at 0.6m3The whole outer surface of experiment plank is coated with above-described embodiment 1～3
In composite multifunction double-component aqueous woodenware white finish paint 2 road made, per pass repainting time is 6～8 hours, coating dry film 1～
2mm, after room temperature maintenance 5 days, drips various spot sources on the paint film of vertical hanging, the most as shown in fig. 1, spot source from a left side to
The right side includes successively: dark soy sauce, vinegar, coffee, black tea, blue ink, edible oil, water solublity white carbon black, alcohol-soluble white carbon black, lipstick, ball pen,
Wax crayon (5 kinds of colors).Normally clean at coating surface after getting wet with wet towel, the double group of composite multifunction in embodiment 1～3
The spot-resistant of part aqueous wooden ware white finish paint is cleaned test result and is seen shown in Fig. 2.
Test comparison result from Fig. 2 is it can be seen that under the conditions of the same spot of same ground, in embodiment 1～3
The composite multifunction double-component aqueous woodenware white finish paint the made double-component aqueous woodenware white finish paint common with on market (refers generally to
Conventional products adds some special organic silicon emulsions or hydrophobic auxiliary agent realizes, but its DeGrain and the most lasting) phase
Ratio, only need to wet rag just can by these greasiness removals, make woodenware surface recovery to former state, and common double-component aqueous woodenware
White finish paint does not then reach this easy scrub effect, leaves obvious vestige or paint film because cleaning and occurring damaging in various degree.
Additionally, due to the fact that and have employed exclusively for improving aqueous wooden ware white finish paint spot-resistant performance and compound changing of designing
Property self-crosslinking acrylic polymer because by great many of experiments, elastene 3030 self-crosslinking acrylic polymer is carried out multiple
Close modification.For for its special structure of elastene 3030, intermediate based on elastene 3030, introduce hydrophilic
Property coalescents DPM (dipropylene glycol methyl ether) and oil loving coalescents DPNB (dipropylene), and add suitable
Amount hydrophilic propylene glycol, can improve elastene 3030 in aqueous double-component woodcare paint with AC 27401 aqueous hydroxyl
Base acrylate copolymer, simultaneously actual join during paint with hydrophilic aliphatic polyisocyanate Bayhydur XP 2655 energy
There is the more preferable compatibility, do not interfere with the chemical reaction of the esterification of AC27401 Yu Bayhydur XP 2655, thus formed more
Fine and close paint film.Elastene 3030 itself has the resistance to hydrophilic stains performance of excellence and resistance to hydrophobic stains performance simultaneously,
Minimum film formation temperature can only need a small amount of coalescents i.e. to can reach excellent with self-crosslinking under zero degree, room temperature in basic components
Different filming performance, thus cost advantage is obvious, adjusts through formulation cost, resistant product similar with market compares discovery,
Cost averagely declines 1～2 yuan of per kilogram, the most high-grade, and cost declines the most；The reason that its cost declines, is to add
Some special organic silicon emulsions or hydrophobic auxiliary agent realize, and both market prices rear are high, and dosage is the most more, scrubbing resistance and resistance to
The effect of spot is not the most lasting, and basic components cost increases substantially, and these other manufacturers of going together the most at present are using
Method.
Coating application test (two): by white according to the double-component aqueous woodenware of composite multifunction made in examples detailed above 1～3
Finish paint, through relevant detection, the sample anti-microbial property assay checked meets national sector standard HG/T3950-2007
The requirement of regulation in " antibiotic paint " (I grade), concrete testing result see table 3.
The double-component aqueous woodenware white finish paint anti-microbial property made in table 3 embodiment 1～3
Remarks: I class: there is the coating material of decoration functions
From table 3 test comparison result it can be concluded that go together in the double-component sold with embodiment 1-3 and market
Aqueous wooden ware finish paint sample is compared, because the model that with the addition of appropriate Rhom and Hass of U.S. production is ROCIMA's 342
The new formula of the specific function auxiliary agent of biocide mildewcide so that coating has possessed anti-microbial property, and antibacterial purifying effect persistency is good,
And common double-component aqueous woodenware white finish paint sample is not owing to having interpolation the most can not possess this with antiseptic raw material
Anti-microbial property.
Coating application test (three): by white according to the double-component aqueous woodenware of composite multifunction made in examples detailed above 1～3
Finish paint, through relevant detection, the sample purifying formaldehyde performance checked, purifying formaldehyde effect persistency assay meets country
The requirement that in building material industry standard JC/T 1074-2008 " function of purifying indoor air coating material purifying property ", I class specifies,
Concrete testing result see table 4.
The double-component aqueous woodenware white finish paint purifying formaldehyde performance made in table 4 embodiment 1～3
Remarks: I class: there is the coating material of decoration functions
From table 4 test comparison result it can be concluded that go together double groups sold with embodiment 1～3 and market
Part aqueous wooden ware finish paint sample is compared, because with the addition of composite modified self-crosslinking acrylic polymer and eliminating the special merit of formaldehyde
Can auxiliary agent double effects except the new formula of aldehyde, first pass through the composite modified irreversible chemistry of self-crosslinking acrylic polymer anti-
Formaldehyde and the timber that should effectively reduce and decompose in air are carrying out the formaldehyde that corrosion resistant surfaces pretreatment may remain, and pass through
Adding the appropriate specific function auxiliary agent SAMASO FA16 eliminating formaldehyde, its particular molecule is designed to by chemical reaction
Mode decomposes in dope layer the formaldehyde of absorption, thus the effect of the quality that reaches to purify the air of a room, thus it is excellent to give paint film
Absorbing formaldehyde function so that coating has possessed purifying formaldehyde performance, and purifying formaldehyde effect persistency is good, and common double-component aqueous
Lacquer as woodenware finish sample can the most not possess this purifying formaldehyde performance with purifying formaldehyde functional raw materials owing to not having interpolation.
Above-described embodiment is the present invention preferably embodiment, but embodiments of the present invention are not by above-described embodiment
Limit, the change made under other any spirit without departing from the present invention and principle, modify, substitute, combine, simplify,
All should be the substitute mode of equivalence, be included in protection scope of the present invention.
Claims (10)
1. a composite multifunction double-component aqueous woodenware white finish paint, is characterized in that: include first component, component B and water, described
The proportion by weight of first component, component B and water is 100:20～25:10～20, and wherein first component is by following weight/mass percentage composition
Raw material make:
Water based acrylic resin 30～40%
Composite modified self-crosslinking acrylic polymer 20～30%
Aqueous titanium dioxide slurry 25～30%
Aqueous delustering agent 1～3%
Defoamer 0.3～0.6%
Wetting agent 0.3～0.5%
Thickening agent 0.3～1.0%
Dispersant 0.3～0.6%
Levelling agent 0.2～0.4%
Antimildew disinfectant 2～3%
Surplus is water；
Component B is made up of the raw material of following weight/mass percentage composition:
Hydrophilic aliphatic polyisocyanate 70～75%
Propylene glycol methyl ether acetate 25～30%.
Composite multifunction the most according to claim 1 double-component aqueous woodenware white finish paint, is characterized in that described in first component
Composite modified self-crosslinking acrylic polymer be made up of the raw material of following weight/mass percentage composition:
Self-crosslinking acrylic polymer 65～70%
Dipropylene glycol methyl ether 5～10%
Dipropylene 1～3%
Propylene glycol 0.5～1%
Wetting agent 0.5～1%
Dispersant 0.5～1%
Defoamer 0.5～1%
Water-borne wax emulsion 1～3%
Eliminate the function additive SAMASO FA16 2～3% of formaldehyde
Antimildew disinfectant 1～2%
Surplus is water.
Composite multifunction the most according to claim 1 and 2 double-component aqueous woodenware white finish paint, is characterized in that institute in first component
The aqueous titanium dioxide slurry stated is made up of the raw material of following weight/mass percentage composition:
Dispersant 3～4%
Rutile titanium white lead 70～75%
Aerosil 0.3～0.5%
Preservative 0.3～0.5%
Ultramarine 0.1～0.3%
Surplus is water.
Composite multifunction the most according to claim 3 double-component aqueous woodenware white finish paint, is characterized in that: described self-crosslinking
The aqueous acrylamide acid polymer that acrylate copolymer produces purchased from U.S.'s ROHM AND HAAS (Chinese) chemical company, model is
elastene 3030；The polytetrafluoroethyl-ne that model is WW-1077 that described water-borne wax emulsion produces purchased from Arkema of France
The model that alkene wax dispenser, Bi Ke chemical company of Germany produce is one or more in BYK-539 wax emulsion and modified paraffin.
Composite multifunction the most according to claim 3 double-component aqueous woodenware white finish paint, is characterized in that: described aqueous hydroxyl
The water-based hydroxyl acrylate copolymer that base acrylic resin produces purchased from Opel enlightening resin (Shenzhen) company limited of Germany, this product
Model be AC 27401.
Composite multifunction the most according to claim 3 double-component aqueous woodenware white finish paint, is characterized in that: described wetting agent
The Siloxane-Oxyalkylene Copolymers solution that model is BYK-346 produced purchased from Bi Ke chemical company of Germany and/or win wound industry collection
The polyether siloxane copolymer that model is TEGO-270 that group produces；The model that described dispersant produces purchased from Japan Nuo Puke
Polycarboxylate sodium's type dispersant, the model of win wound industrial group production for SN-5040 are the affine containing pigment of TEGO-735W
In the organically-modified polyacrylate solution of group and high-performance polymer type wetting dispersing agent that model is TEGO-750W one
Plant or several；Described defoamer purchased from win wound industrial group produce model be TEGO-902W polyether siloxane copolymer and
Germany Bi Ke company produce the defoamer based on mineral oil that model is BYK-094 in one or both；Described
The antimildew disinfectant that model is ROCIMA 342 that antimildew disinfectant produces purchased from Rhom and Hass of the U.S., its chemical composition master
The mixture of alkyl benzene sulphonate to be, octylisothiazolinone and Copper hydrate.
Composite multifunction the most according to claim 3 double-component aqueous woodenware white finish paint, is characterized in that: described aqueous disappears
The aqueous delustering agent that model is CP4-8991 that photo etching produces purchased from glaze chemical company of the U.S.；Described thickening agent is purchased from U.S.
The most solvent-laden non-ionic polyurethane association type thickening that model is R-8W and/or RM2020 that Tao Shi chemical company of state produces
Agent；The polyether-modified polydimethylsiloxanes that model is BYK-333 that described levelling agent produces purchased from Bi Ke chemical company of Germany
The polyether siloxane copolymer that model is TEGO-410 that alkane solution and/or win wound industrial group produce.
Composite multifunction the most according to claim 3 double-component aqueous woodenware white finish paint, is characterized in that: described hydrophilic
The chemical composition that model is Bayhydur XP 2655 that aliphatic polymeric isocyanate produces purchased from Bayer A.G is mainly
Hydrophilic aliphatic polyisocyanate based on hexamethylene diisocyanate；Described propylene glycol methyl ether acetate is Jiangsu China
The propylene glycol methyl ether acetate PMA environmentally friendly solvent that logical sequence Chemical Co., Ltd. produces.
The preparation method of composite multifunction the most according to claim 1 double-component aqueous woodenware white finish paint, is characterized in that containing
Following steps:
(1) prepare composite modified self-crosslinking acrylic polymer: by quantitative relation, choose the composite modified self-crosslinking acrylic of preparation
Each raw material of polymer, first takes from crosslinked acrylic acid polymer, defoamer, wetting agent, dispersant and antimildew disinfectant, addition portion
Divide water, stir 5～10 minutes with the stir speed (S.S.)s of 800～1000 revs/min, be subsequently adding dipropylene glycol methyl ether, dipropylene glycol fourth
Ether and propylene glycol, stir 10～15 minutes with the stir speed (S.S.)s of 400～600 revs/min, adds water-borne wax emulsion, eliminates formaldehyde
Function additive SAMASO FA16 and remaining water, stir 5～10 minutes with the stir speed (S.S.)s of 200～400 revs/min, prepares compound
Modified self-crosslinking acrylate copolymer；
(2) the composite modified self-crosslinking acrylic polymer of preparation in step (1) is joined in water based acrylic resin,
Then under the stir speed (S.S.) of 400～600 revs/min, press quantitative relation add defoamer, wetting agent, thickening agent and dispersant, add
Enter part water, stir 5～10 minutes with the stir speed (S.S.)s of 400～600 revs/min, be subsequently adding aqueous delustering agent, with 1000～
The stir speed (S.S.) of 1200 revs/min stirs 15～20 minutes, be distributed to fineness qualified after, add levelling agent, antimildew disinfectant and surplus
Remaining water, stirs 5～10 minutes with the stir speed (S.S.)s of 300～500 revs/min, makes uniform sizing material；
(3) preparation aqueous titanium dioxide slurry: choose each raw material of preparation aqueous titanium dioxide slurry by quantitative relation, first take dispersant, rutile
Titanium dioxide, aerosil, preservative and ultramarine, add part water, stirs 20 with the stir speed (S.S.)s of 1200～1500 revs/min
～25 minutes, be dispersed to fineness qualified after, add in remaining water, make aqueous titanium dioxide slurry；
(4) the aqueous titanium dioxide slurry that step (3) is made is joined in the slurry that step (2) is made, with 400～500 revs/min stir
Mix speed to stir 20～25 minutes, prepare first component；
(5) hydrophilic aliphatic polyisocyanate and propylene glycol methyl ether acetate are stirred with the stir speed (S.S.) of 400～500 revs/min
Mix 10～15 minutes, prepare component B；
(6) choose first component, component B and water by quantitative relation, first add water to first component stirs evenly, add component B and stir
Even, i.e. prepare the double-component aqueous woodenware white finish paint of composite multifunction after standing.
The preparation method of composite multifunction the most according to claim 9 double-component aqueous woodenware white finish paint, is characterized in that:
In step (1) and step (2), the addition of part water accounts for this step water gross mass 70～80%；Part water in step (3)
Addition accounts for the 60～70% of this step water gross mass.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610749993.1A CN106243966B (en) | 2016-08-29 | 2016-08-29 | A kind of double-component aqueous woodenware white finish paint of composite multifunction and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610749993.1A CN106243966B (en) | 2016-08-29 | 2016-08-29 | A kind of double-component aqueous woodenware white finish paint of composite multifunction and preparation method thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN106243966A true CN106243966A (en) | 2016-12-21 |
| CN106243966B CN106243966B (en) | 2018-07-06 |
Family
ID=57597134
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610749993.1A Active CN106243966B (en) | 2016-08-29 | 2016-08-29 | A kind of double-component aqueous woodenware white finish paint of composite multifunction and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN106243966B (en) |
Cited By (15)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107163743A (en) * | 2017-07-14 | 2017-09-15 | 广东伊思曼新材料科技股份有限公司 | A kind of container roller coat aqueous wooden ware floor paint and preparation method thereof |
| CN108003744A (en) * | 2017-11-30 | 2018-05-08 | 青岛圣世恒业化工有限公司 | A kind of water-based interior finishing coat applied to steel and preparation method thereof |
| CN109401588A (en) * | 2018-10-31 | 2019-03-01 | 聂阳含 | A kind of aqueous light top coat top coat of two-component high rigidity and preparation method thereof |
| CN109468044A (en) * | 2018-10-31 | 2019-03-15 | 聂阳含 | A kind of two-component high definition is aqueous to repair coloured gold oil and preparation method thereof |
| CN109535881A (en) * | 2018-12-20 | 2019-03-29 | 惠州市银海涂料有限公司 | A kind of self-drying aqueous matte varnish |
| CN109535963A (en) * | 2018-10-31 | 2019-03-29 | 聂阳含 | A kind of special priming paint and preparation method thereof clearly of two-component high hardness |
| CN110698963A (en) * | 2019-10-23 | 2020-01-17 | 郑州一安水性高分子材料有限公司 | High-wear-resistance water-based acrylic acid-polyurethane two-component finish paint |
| CN111777933A (en) * | 2020-06-10 | 2020-10-16 | 惠州市奥亚皇冠涂料有限公司 | Aqueous two-component white elastic wood finish and preparation method thereof |
| CN114085577A (en) * | 2021-12-23 | 2022-02-25 | 东莞市涂芭新材料有限公司 | Water-based antiviral negative oxygen ion woodenware coating and preparation method thereof |
| CN114249999A (en) * | 2021-11-29 | 2022-03-29 | 广东家实多集团有限公司 | Sound-absorbing and sound-insulating coating and preparation method and application thereof |
| CN114369410A (en) * | 2021-12-30 | 2022-04-19 | 广州千顺工业材料有限公司 | Black water-based graphene electromagnetic wave shielding coating and preparation method thereof |
| CN114517035A (en) * | 2021-12-29 | 2022-05-20 | 广东大自然家居科技研究有限公司 | Water-based plant-based varnish, preparation method thereof and woodware |
| CN115948087A (en) * | 2022-09-21 | 2023-04-11 | 上海君子兰新材料股份有限公司 | Method for improving color stability of solid-color finish paint and application thereof |
| WO2023149934A1 (en) * | 2022-02-01 | 2023-08-10 | Hrl Laboratories, Llc | Formulas and methods for making shelf-stable antimicrobial biphasic polymers |
| BE1031227B1 (en) * | 2022-12-30 | 2024-07-30 | Duthoo Nv | METHOD FOR PRODUCING AN IMPROVED HYDROPHOBIC AGENT FOR THE TREATMENT OF OUTDOOR WOOD |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US11859098B2 (en) | 2017-08-10 | 2024-01-02 | Hrl Laboratories, Llc | Formulas and methods for making shelf-stable antimicrobial biphasic polymers |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102002292A (en) * | 2010-11-03 | 2011-04-06 | 广东巴德士化工有限公司 | Bi-component water woodware matte whitening paint |
| CN103881500A (en) * | 2014-03-27 | 2014-06-25 | 中华制漆（深圳）有限公司 | High-weather-resistance high-stain-resistance white paint for outdoor woodware and preparation method of paint |
| CN105505167A (en) * | 2015-12-25 | 2016-04-20 | 北京展辰新材料有限公司 | Waterborne bi-component bright white finish and application thereof |
-
2016
- 2016-08-29 CN CN201610749993.1A patent/CN106243966B/en active Active
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102002292A (en) * | 2010-11-03 | 2011-04-06 | 广东巴德士化工有限公司 | Bi-component water woodware matte whitening paint |
| CN103881500A (en) * | 2014-03-27 | 2014-06-25 | 中华制漆（深圳）有限公司 | High-weather-resistance high-stain-resistance white paint for outdoor woodware and preparation method of paint |
| CN105505167A (en) * | 2015-12-25 | 2016-04-20 | 北京展辰新材料有限公司 | Waterborne bi-component bright white finish and application thereof |
Cited By (16)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107163743A (en) * | 2017-07-14 | 2017-09-15 | 广东伊思曼新材料科技股份有限公司 | A kind of container roller coat aqueous wooden ware floor paint and preparation method thereof |
| CN107163743B (en) * | 2017-07-14 | 2019-06-25 | 广东伊思曼新材料科技股份有限公司 | A kind of container roller coating aqueous wooden ware floor paint and preparation method thereof |
| CN108003744A (en) * | 2017-11-30 | 2018-05-08 | 青岛圣世恒业化工有限公司 | A kind of water-based interior finishing coat applied to steel and preparation method thereof |
| CN109401588A (en) * | 2018-10-31 | 2019-03-01 | 聂阳含 | A kind of aqueous light top coat top coat of two-component high rigidity and preparation method thereof |
| CN109468044A (en) * | 2018-10-31 | 2019-03-15 | 聂阳含 | A kind of two-component high definition is aqueous to repair coloured gold oil and preparation method thereof |
| CN109535963A (en) * | 2018-10-31 | 2019-03-29 | 聂阳含 | A kind of special priming paint and preparation method thereof clearly of two-component high hardness |
| CN109535881A (en) * | 2018-12-20 | 2019-03-29 | 惠州市银海涂料有限公司 | A kind of self-drying aqueous matte varnish |
| CN110698963A (en) * | 2019-10-23 | 2020-01-17 | 郑州一安水性高分子材料有限公司 | High-wear-resistance water-based acrylic acid-polyurethane two-component finish paint |
| CN111777933A (en) * | 2020-06-10 | 2020-10-16 | 惠州市奥亚皇冠涂料有限公司 | Aqueous two-component white elastic wood finish and preparation method thereof |
| CN114249999A (en) * | 2021-11-29 | 2022-03-29 | 广东家实多集团有限公司 | Sound-absorbing and sound-insulating coating and preparation method and application thereof |
| CN114085577A (en) * | 2021-12-23 | 2022-02-25 | 东莞市涂芭新材料有限公司 | Water-based antiviral negative oxygen ion woodenware coating and preparation method thereof |
| CN114517035A (en) * | 2021-12-29 | 2022-05-20 | 广东大自然家居科技研究有限公司 | Water-based plant-based varnish, preparation method thereof and woodware |
| CN114369410A (en) * | 2021-12-30 | 2022-04-19 | 广州千顺工业材料有限公司 | Black water-based graphene electromagnetic wave shielding coating and preparation method thereof |
| WO2023149934A1 (en) * | 2022-02-01 | 2023-08-10 | Hrl Laboratories, Llc | Formulas and methods for making shelf-stable antimicrobial biphasic polymers |
| CN115948087A (en) * | 2022-09-21 | 2023-04-11 | 上海君子兰新材料股份有限公司 | Method for improving color stability of solid-color finish paint and application thereof |
| BE1031227B1 (en) * | 2022-12-30 | 2024-07-30 | Duthoo Nv | METHOD FOR PRODUCING AN IMPROVED HYDROPHOBIC AGENT FOR THE TREATMENT OF OUTDOOR WOOD |
Also Published As
| Publication number | Publication date |
|---|---|
| CN106243966B (en) | 2018-07-06 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN106243966B (en) | A kind of double-component aqueous woodenware white finish paint of composite multifunction and preparation method thereof | |
| CN101698770B (en) | Water-based anti-doodling paint and preparation method thereof | |
| CN101760090B (en) | Alcohol acid and polyurethane resin modified nitrocellulose matt varnish | |
| CN107163743B (en) | A kind of container roller coating aqueous wooden ware floor paint and preparation method thereof | |
| CN105199515B (en) | A kind of imitation porcelain coating and its spraying method | |
| CN105176220B (en) | Synthetic emulsion diatom interiro wall latex paint and preparation method thereof | |
| CN105462403B (en) | A kind of composite aqueous woodenware one-component semi-gloss varnish and preparation method thereof | |
| CN102002298A (en) | Aqueous antifouling adhesive preventing coating and production method thereof | |
| CN103131321A (en) | High transparency scratch-resisting matt clear paint | |
| CN105331271B (en) | A kind of water-based two-in-one woodcare paint and preparation method thereof | |
| CN105315882A (en) | Water-based scratch-resistant transparent finishing coat as well as preparation method and application thereof | |
| CN105219247B (en) | A kind of anti-scribble two-component clear varnish and preparation method thereof | |
| CN111073515B (en) | Plant-based water-based art paint and preparation method thereof | |
| CN101586002A (en) | Colorful terrace lacquer with beautiful color and tactile impression and construction technique thereof | |
| CN106957571A (en) | Low multi-functional sealing waxes of VOC and preparation method thereof | |
| CN106634544A (en) | Low-VOC (Volatile Organic Compound) sound-insulation PU (Polyurethane) matte white finish paint | |
| CN102757698B (en) | Low-VOC (Volatile Organic Compounds) nitrolacquer | |
| CN102093795A (en) | Water-based wooden toy paint | |
| CN109913083A (en) | Aqueous crackle coating of removing and preparation method thereof may be selected | |
| CN102220058B (en) | Bi-component aqueous epoxy latex paint capable of substituting for ceramic tile | |
| CN109486407A (en) | A kind of dedicated polyurethane paint of Recombinant Wood and preparation method thereof | |
| CN108342139A (en) | A kind of woodenware multifunctional coating | |
| CN106752540A (en) | A kind of high rigidity, wear-resistant aqueous woodware paint and preparation method thereof | |
| CN108707400A (en) | A kind of fishing gear water paint and preparation method thereof | |
| CN103627280B (en) | A kind of mono-component aqueous outdoor top-coat varnish |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| CB02 | Change of applicant information | ||
| CB02 | Change of applicant information |
Address after: 528303 16, Chun Road, Ma Gang Industrial Zone, Ronggui street, Shunde District, Foshan, Guangdong. Applicant after: Guangdong Yisiman new materials Polytron Technologies Inc Address before: 528303 16, Chun Road, Ma Gang Industrial Zone, Ronggui street, Shunde District, Foshan, Guangdong. Applicant before: Foshan Yisiman Chemical Co., Ltd. |
|
| GR01 | Patent grant | ||
| GR01 | Patent grant |