CN116217191B - Cold region desert sand composite alkali-activated anti-freezing mortar and preparation and construction methods thereof - Google Patents
Cold region desert sand composite alkali-activated anti-freezing mortar and preparation and construction methods thereof Download PDFInfo
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- CN116217191B CN116217191B CN202310287067.7A CN202310287067A CN116217191B CN 116217191 B CN116217191 B CN 116217191B CN 202310287067 A CN202310287067 A CN 202310287067A CN 116217191 B CN116217191 B CN 116217191B
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- 239000003513 alkali Substances 0.000 title claims abstract description 98
- 239000004570 mortar (masonry) Substances 0.000 title claims abstract description 91
- 239000004576 sand Substances 0.000 title claims abstract description 64
- 239000002131 composite material Substances 0.000 title claims abstract description 62
- 238000010276 construction Methods 0.000 title claims abstract description 25
- 238000002360 preparation method Methods 0.000 title claims abstract description 6
- 238000007710 freezing Methods 0.000 title claims abstract 12
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 106
- ODINCKMPIJJUCX-UHFFFAOYSA-N Calcium oxide Chemical compound [Ca]=O ODINCKMPIJJUCX-UHFFFAOYSA-N 0.000 claims abstract description 71
- 239000010881 fly ash Substances 0.000 claims abstract description 61
- 239000000292 calcium oxide Substances 0.000 claims abstract description 38
- 235000012255 calcium oxide Nutrition 0.000 claims abstract description 37
- 239000003638 chemical reducing agent Substances 0.000 claims abstract description 36
- 238000003756 stirring Methods 0.000 claims abstract description 28
- 239000000203 mixture Substances 0.000 claims abstract description 19
- 238000011049 filling Methods 0.000 claims abstract description 17
- 238000002156 mixing Methods 0.000 claims abstract description 13
- 239000002985 plastic film Substances 0.000 claims abstract description 7
- 229920006255 plastic film Polymers 0.000 claims abstract description 7
- 239000002002 slurry Substances 0.000 claims abstract description 5
- 239000003795 chemical substances by application Substances 0.000 claims abstract 7
- 238000005303 weighing Methods 0.000 claims abstract 3
- 238000004140 cleaning Methods 0.000 claims abstract 2
- 239000012190 activator Substances 0.000 claims description 49
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 45
- 238000000034 method Methods 0.000 claims description 16
- 239000011435 rock Substances 0.000 claims description 10
- 230000008569 process Effects 0.000 claims description 8
- 238000005204 segregation Methods 0.000 claims description 7
- 239000004035 construction material Substances 0.000 claims description 6
- 230000005611 electricity Effects 0.000 claims description 6
- 235000008733 Citrus aurantifolia Nutrition 0.000 claims description 3
- 229910004298 SiO 2 Inorganic materials 0.000 claims description 3
- 235000011941 Tilia x europaea Nutrition 0.000 claims description 3
- 239000004571 lime Substances 0.000 claims description 3
- 238000012423 maintenance Methods 0.000 claims description 2
- 150000001875 compounds Chemical class 0.000 claims 2
- 239000000463 material Substances 0.000 abstract description 19
- 238000000465 moulding Methods 0.000 abstract 1
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 58
- 230000002528 anti-freeze Effects 0.000 description 29
- 230000004913 activation Effects 0.000 description 13
- 230000000694 effects Effects 0.000 description 11
- 239000000843 powder Substances 0.000 description 11
- 230000001965 increasing effect Effects 0.000 description 8
- 239000002245 particle Substances 0.000 description 8
- UXVMQQNJUSDDNG-UHFFFAOYSA-L Calcium chloride Chemical compound [Cl-].[Cl-].[Ca+2] UXVMQQNJUSDDNG-UHFFFAOYSA-L 0.000 description 7
- 239000001110 calcium chloride Substances 0.000 description 7
- 235000011148 calcium chloride Nutrition 0.000 description 7
- 229910001628 calcium chloride Inorganic materials 0.000 description 7
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 5
- 229910052593 corundum Inorganic materials 0.000 description 5
- 239000002994 raw material Substances 0.000 description 5
- 230000009467 reduction Effects 0.000 description 5
- 239000002893 slag Substances 0.000 description 5
- 229910001845 yogo sapphire Inorganic materials 0.000 description 5
- 230000008901 benefit Effects 0.000 description 4
- BRPQOXSCLDDYGP-UHFFFAOYSA-N calcium oxide Chemical compound [O-2].[Ca+2] BRPQOXSCLDDYGP-UHFFFAOYSA-N 0.000 description 4
- 229910052681 coesite Inorganic materials 0.000 description 4
- 229920001577 copolymer Polymers 0.000 description 4
- 238000005336 cracking Methods 0.000 description 4
- 229910052906 cristobalite Inorganic materials 0.000 description 4
- 238000001035 drying Methods 0.000 description 4
- 230000006872 improvement Effects 0.000 description 4
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 4
- 239000000377 silicon dioxide Substances 0.000 description 4
- 235000012239 silicon dioxide Nutrition 0.000 description 4
- 239000002910 solid waste Substances 0.000 description 4
- 229910052682 stishovite Inorganic materials 0.000 description 4
- 229910052905 tridymite Inorganic materials 0.000 description 4
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 3
- 239000011575 calcium Substances 0.000 description 3
- 238000005516 engineering process Methods 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 3
- 229920002554 vinyl polymer Polymers 0.000 description 3
- 229910018072 Al 2 O 3 Inorganic materials 0.000 description 2
- 229920000642 polymer Polymers 0.000 description 2
- 229910018516 Al—O Inorganic materials 0.000 description 1
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
- KKCBUQHMOMHUOY-UHFFFAOYSA-N Na2O Inorganic materials [O-2].[Na+].[Na+] KKCBUQHMOMHUOY-UHFFFAOYSA-N 0.000 description 1
- 239000011398 Portland cement Substances 0.000 description 1
- 229910018557 Si O Inorganic materials 0.000 description 1
- 229910002800 Si–O–Al Inorganic materials 0.000 description 1
- 229910002808 Si–O–Si Inorganic materials 0.000 description 1
- 239000004115 Sodium Silicate Substances 0.000 description 1
- GRWPEXLRROVDML-UHFFFAOYSA-N [Ca].ClOCl Chemical compound [Ca].ClOCl GRWPEXLRROVDML-UHFFFAOYSA-N 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- 230000003213 activating effect Effects 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000000740 bleeding effect Effects 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- OSMSIOKMMFKNIL-UHFFFAOYSA-N calcium;silicon Chemical compound [Ca]=[Si] OSMSIOKMMFKNIL-UHFFFAOYSA-N 0.000 description 1
- 239000004568 cement Substances 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 230000002950 deficient Effects 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 230000029087 digestion Effects 0.000 description 1
- 230000002708 enhancing effect Effects 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 239000005038 ethylene vinyl acetate Substances 0.000 description 1
- 230000005284 excitation Effects 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 230000036571 hydration Effects 0.000 description 1
- 238000006703 hydration reaction Methods 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000003204 osmotic effect Effects 0.000 description 1
- 229920001200 poly(ethylene-vinyl acetate) Polymers 0.000 description 1
- NOTVAPJNGZMVSD-UHFFFAOYSA-N potassium monoxide Inorganic materials [K]O[K] NOTVAPJNGZMVSD-UHFFFAOYSA-N 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- LIVNPJMFVYWSIS-UHFFFAOYSA-N silicon monoxide Inorganic materials [Si-]#[O+] LIVNPJMFVYWSIS-UHFFFAOYSA-N 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 description 1
- 229910052911 sodium silicate Inorganic materials 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000007790 solid phase Substances 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- 239000013589 supplement Substances 0.000 description 1
- 230000001502 supplementing effect Effects 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- 229920001567 vinyl ester resin Polymers 0.000 description 1
Classifications
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B28/00—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
- C04B28/02—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing hydraulic cements other than calcium sulfates
- C04B28/10—Lime cements or magnesium oxide cements
- C04B28/12—Hydraulic lime
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B14/00—Use of inorganic materials as fillers, e.g. pigments, for mortars, concrete or artificial stone; Treatment of inorganic materials specially adapted to enhance their filling properties in mortars, concrete or artificial stone
- C04B14/02—Granular materials, e.g. microballoons
- C04B14/04—Silica-rich materials; Silicates
- C04B14/06—Quartz; Sand
- C04B14/068—Specific natural sands, e.g. sea -, beach -, dune - or desert sand
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B7/00—Hydraulic cements
- C04B7/24—Cements from oil shales, residues or waste other than slag
- C04B7/243—Mixtures thereof with activators or composition-correcting additives, e.g. mixtures of fly ash and alkali activators
-
- E—FIXED CONSTRUCTIONS
- E02—HYDRAULIC ENGINEERING; FOUNDATIONS; SOIL SHIFTING
- E02D—FOUNDATIONS; EXCAVATIONS; EMBANKMENTS; UNDERGROUND OR UNDERWATER STRUCTURES
- E02D3/00—Improving or preserving soil or rock, e.g. preserving permafrost soil
- E02D3/12—Consolidating by placing solidifying or pore-filling substances in the soil
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
- C04B2111/00017—Aspects relating to the protection of the environment
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
- C04B2111/00474—Uses not provided for elsewhere in C04B2111/00
- C04B2111/00663—Uses not provided for elsewhere in C04B2111/00 as filling material for cavities or the like
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
- C04B2111/20—Resistance against chemical, physical or biological attack
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
- C04B2111/70—Grouts, e.g. injection mixtures for cables for prestressed concrete
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
- C04B2111/76—Use at unusual temperatures, e.g. sub-zero
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2201/00—Mortars, concrete or artificial stone characterised by specific physical values
- C04B2201/50—Mortars, concrete or artificial stone characterised by specific physical values for the mechanical strength
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
- Y02W30/00—Technologies for solid waste management
- Y02W30/50—Reuse, recycling or recovery technologies
- Y02W30/91—Use of waste materials as fillers for mortars or concrete
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Ceramic Engineering (AREA)
- Structural Engineering (AREA)
- Organic Chemistry (AREA)
- Materials Engineering (AREA)
- Civil Engineering (AREA)
- Life Sciences & Earth Sciences (AREA)
- Inorganic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Agronomy & Crop Science (AREA)
- Environmental & Geological Engineering (AREA)
- Soil Sciences (AREA)
- General Life Sciences & Earth Sciences (AREA)
- Mining & Mineral Resources (AREA)
- Paleontology (AREA)
- General Engineering & Computer Science (AREA)
- Curing Cements, Concrete, And Artificial Stone (AREA)
Abstract
Description
技术领域Technical Field
本发明涉及寒区建筑工程抗冻技术领域,尤其涉及一种寒区沙漠沙复合碱激发抗冻砂浆及其制备、施工方法。The invention relates to the technical field of antifreeze of cold region construction projects, and in particular to a cold region desert sand composite alkali-activated antifreeze mortar and a preparation and construction method thereof.
背景技术Background Art
随着寒区经济的发展,工程建设用砂浆需求日益增大。寒区建筑物如公路路面、桥墩、高压铁塔桩基础等易受冻融破坏产生裂隙;热棒基坑在回填过程中需要流动性高、均匀、快速回填基坑缝隙的等问题。此外,寒区广泛分布有沙漠沙,目前,针对寒区工程开发的碱激发砂浆技术中还未见到相关报道。With the development of cold region economy, the demand for mortar for engineering construction is increasing. Cold region buildings such as highway pavement, bridge piers, high-voltage iron tower pile foundations, etc. are susceptible to freeze-thaw damage and cracks; hot rod foundation pits need high fluidity, uniformity, and rapid backfilling of foundation pit gaps during backfilling. In addition, desert sand is widely distributed in cold regions. At present, there are no related reports on alkali-activated mortar technology developed for cold region projects.
专利申请CN202011347104.1中公开了一种矿渣基碱激发胶凝材料及其制备方法和应用,该碱激发胶凝材料组分为:矿渣70-99质量份、硅钙渣1-30质量份、碱激发剂1%-5%,碱激发液体是模数为2.2-3.4的硅酸钠。专利申请CN201510810774.5中公开了一种改性碱激发胶凝材料,按质量份数计,原料包含:粉煤灰和矿渣100份、碱激发剂25-50份、缓凝剂0.5-2份、聚合物胶粉2-15份,其中碱激发剂的固含量为30%-40%,聚合物胶粉选自丁二烯-苯乙烯共聚物胶粉、苯乙烯-丙烯酸共聚物胶粉、丙烯酸酯共聚物胶粉、乙烯醋酸乙烯酯共聚物胶粉、醋酸乙烯酯-叔碳酸乙烯酯共聚物胶粉或醋酸乙烯酯-叔碳酸乙烯酯-丙烯酸酯共聚物胶粉中的一种或多种。Patent application CN202011347104.1 discloses a slag-based alkali-activated cementitious material, a preparation method and an application thereof. The components of the alkali-activated cementitious material are: 70-99 parts by mass of slag, 1-30 parts by mass of calcium-silicon slag, 1%-5% of alkali activator, and the alkali-activated liquid is sodium silicate with a modulus of 2.2-3.4. Patent application CN201510810774.5 discloses a modified alkali-activated cementitious material. The raw materials include, by mass, 100 parts of fly ash and slag, 25-50 parts of alkali activator, 0.5-2 parts of retarder, and 2-15 parts of polymer rubber powder, wherein the solid content of the alkali activator is 30%-40%, and the polymer rubber powder is selected from one or more of butadiene-styrene copolymer rubber powder, styrene-acrylic acid copolymer rubber powder, acrylate copolymer rubber powder, ethylene vinyl acetate copolymer rubber powder, vinyl acetate-versatate vinyl ester copolymer rubber powder, or vinyl acetate-versatate vinyl ester-acrylate copolymer rubber powder.
上述现有的碱激发胶凝材料存在以下缺陷:(1)大部分碱激发材料砂浆都从材料学的角度去设计,没有工程针对性,尤其是没有适用于寒区工程的碱激发砂浆;(2)碱激发多采用NaOH和Na2SiO4的复合碱激发组合,激发效果还有很大提升空间;(3)粉体采用粉煤灰和矿渣,没有达到对粉煤灰的高效碱激发,生成的砂浆强度较低;(4)较少考虑砂浆的流动性,然而寒区充填工程中,流动性直接决定了充填密实度和后期耐久性。The above-mentioned existing alkali-activated cementitious materials have the following defects: (1) Most alkali-activated mortars are designed from the perspective of materials science and have no engineering specificity, especially there is no alkali-activated mortar suitable for cold-region projects; (2) Alkali activation mostly adopts a composite alkali activation combination of NaOH and Na2SiO4 , and the activation effect still has a lot of room for improvement; (3) The powder uses fly ash and slag , which does not achieve efficient alkali activation of fly ash, and the strength of the generated mortar is relatively low; (4) The fluidity of the mortar is rarely considered. However, in cold-region filling projects, the fluidity directly determines the filling density and later durability.
发明内容Summary of the invention
为了克服现有技术的不足,本发明的目的在于提供一种寒区沙漠沙复合碱激发抗冻砂浆及其制备、施工方法,以寒区常见沙漠沙和粉煤灰为原料,采用复合碱激发技术和耐久性提高措施,制备了适用于寒区工程建筑的砂浆,能够解决目前寒区工程技术难题,具有就地取材、施工方便、早强快硬、抗冻性能好、充填性能佳的优势,而且充分利用了当地资源,降低了工程造价。In order to overcome the shortcomings of the prior art, the purpose of the present invention is to provide a cold-region desert sand composite alkali-activated antifreeze mortar and a preparation and construction method thereof. Common desert sand and fly ash in cold regions are used as raw materials, and composite alkali activation technology and durability improvement measures are adopted to prepare mortar suitable for cold-region engineering construction. The mortar can solve the current technical problems in cold-region engineering, has the advantages of local materials, convenient construction, early strength and fast hardening, good antifreeze performance, and good filling performance, and makes full use of local resources to reduce engineering costs.
为了实现上述目的,本发明所采用的技术方案是:In order to achieve the above object, the technical solution adopted by the present invention is:
一种寒区沙漠沙复合碱激发抗冻砂浆,按重量份数计包含以下组分:粉煤灰100份、生石灰20-30份、碱激发剂10-15份、沙漠沙500-800份、复合减水剂4-8份,水35-50份。A cold region desert sand composite alkali-activated antifreeze mortar comprises the following components by weight: 100 parts of fly ash, 20-30 parts of quicklime, 10-15 parts of alkali activator, 500-800 parts of desert sand, 4-8 parts of composite water reducing agent, and 35-50 parts of water.
所述粉煤灰包括占粉煤灰质量50%-70%的任意比例的活性SiO2、活性Al2O3和f-CaO,占粉煤灰质量5%-10%的Fe2O3,粉煤灰细度小于100um。The fly ash comprises active SiO 2 , active Al 2 O 3 and f-CaO in any proportion accounting for 50%-70% of the fly ash mass, and Fe 2 O 3 accounting for 5%-10% of the fly ash mass. The fly ash fineness is less than 100um.
所述生石灰为常见磨细生石灰,CaO占生石灰质量大于70%,中速灰。The quicklime is common ground quicklime, in which CaO accounts for more than 70% of the quicklime mass, and the quicklime is medium-speed lime.
所述碱激发剂为复合激发剂,包括均匀混合的占碱激发剂质量1%-2%的NaOH和2%-3%的CaCl2。The alkaline activator is a composite activator, comprising uniformly mixed NaOH accounting for 1%-2% of the mass of the alkaline activator and CaCl 2 accounting for 2%-3% of the mass of the alkaline activator.
所述沙漠沙粒径25um-400um,细度模数0.2-0.3。The desert sand has a particle size of 25um-400um and a fineness modulus of 0.2-0.3.
所述复合减水剂为引气型减水剂,减水率大于25%,引气量6%-15%。The composite water reducing agent is an air entraining type water reducing agent, with a water reduction rate greater than 25% and an air entraining amount of 6%-15%.
所述水的温度在60℃-80℃间。The temperature of the water is between 60°C and 80°C.
一种寒区沙漠沙复合碱激发抗冻砂浆的制备方法,包括以下步骤:A method for preparing cold region desert sand composite alkali activated antifreeze mortar comprises the following steps:
(1)按权利要求1所述抗冻砂浆配合比取60℃-80℃的水和碱激发剂充分搅拌混合,待充分溶解后置于60℃-80℃养护箱中备用;(1) Take water at 60°C to 80°C and an alkali activator according to the antifreeze mortar mix ratio of claim 1, stir and mix thoroughly, and place in a 60°C to 80°C curing box for standby after being fully dissolved;
(2)根据权利要求1所述抗冻砂浆配合比称量粉煤灰、生石灰和沙漠沙,混合搅拌均匀,再将步骤(1)配置好的碱激发剂溶液缓慢加入;(2) According to the antifreeze mortar mix ratio of claim 1, fly ash, quicklime and desert sand are weighed, mixed and stirred evenly, and then the alkaline activator solution prepared in step (1) is slowly added;
(3)将步骤(2)得到的砂浆,以100-150r/min的速度搅拌5-8min,搅拌的过程中缓慢加入复合减水剂和水。(3) The mortar obtained in step (2) is stirred at a speed of 100-150 r/min for 5-8 min, and the composite water reducing agent and water are slowly added during the stirring process.
步骤(3)中用水量=总用水量-碱激发中的用水量。The amount of water used in step (3) = the total amount of water used - the amount of water used in the alkali excitation.
一种寒区沙漠沙复合碱激发抗冻砂浆的施工方法,具体包括以下步骤:A construction method of cold region desert sand composite alkali activated antifreeze mortar, specifically comprising the following steps:
步骤一、准备好水、电及管道等施工材料,将岩石裂缝、孔洞的地面整平,再将流水注入裂缝、孔洞将其内部冲刷干净;Step 1: Prepare water, electricity, pipes and other construction materials, level the ground of the rock cracks and holes, and then inject running water into the cracks and holes to flush them clean;
步骤二、将沙漠沙碱激发抗冻砂浆制备步骤(3)中拌合好的砂浆进行灌注施工,施工为连续施工,避免出现离析、漏浆,并保证在砂浆初凝前完成灌注;Step 2: pouring the mortar mixed in the step (3) of preparing the desert sand-alkali activated antifreeze mortar, the construction is continuous to avoid segregation and leakage, and ensure that the pouring is completed before the mortar begins to set;
步骤三、在对缝隙、孔洞充填完成后,对灌注表面进行抹平与清理,并覆盖塑料膜养护。Step 3: After filling the gaps and holes, smooth and clean the poured surface and cover it with plastic film for maintenance.
本发明的有益效果是:The beneficial effects of the present invention are:
(1)采用北方广泛分布的沙漠沙为主要原料,具有取材方便,价格低廉,绿色环保,工程应用性好,在经济环保上具有显著优势。沙漠沙粒度组成如表1所示,沙漠沙的平均粒径在0.04mm-0.08mm,由于粒径细小,用其配置得到砂浆流动性具有流动性好的先天优势;沙漠沙颗粒特征如表2及图1所示,其表面较为粗糙,配置砂浆时黏结力与标准砂接近;沙漠沙化学成分如表3所示,其CaO、K2O和Na2O等碱性成分含量高于普通沙,尤其是CaO含量接近17%。沙漠沙中CaO为主的碱性成分可以补充碱激发材料中碱性原料的不足,增大碱激发的胶凝作用,有利于碱激发强度的生成。(1) Desert sand, which is widely distributed in the north, is used as the main raw material. It is easy to obtain, low-priced, green and environmentally friendly, and has good engineering applicability. It has significant advantages in terms of economy and environmental protection. The particle size composition of desert sand is shown in Table 1. The average particle size of desert sand is 0.04mm-0.08mm. Due to its small particle size, the mortar prepared with it has an inherent advantage of good fluidity; the characteristics of desert sand particles are shown in Table 2 and Figure 1. Its surface is relatively rough, and its bonding strength when preparing mortar is close to that of standard sand; the chemical composition of desert sand is shown in Table 3. Its alkaline components such as CaO, K2O and Na2O are higher than those of ordinary sand, especially the CaO content is close to 17%. The alkaline components mainly composed of CaO in desert sand can supplement the deficiency of alkaline raw materials in alkali-activated materials, increase the gelling effect of alkali activation, and are conducive to the generation of alkali-activated strength.
表1青藏高原沙漠沙粒度组成(W%)Table 1 Grain size composition of desert sand on the Qinghai-Tibet Plateau (W%)
表2沙漠沙特征Table 2 Characteristics of desert sand
表3沙漠沙化学成分表Table 3 Chemical composition of desert sand
(2)采用粉煤灰和生石灰的优化配比。粉煤灰属于Cao-SiO2-Al2O3系统,其成分如表4所示。与普通硅酸盐水泥熟料相比,粉煤灰CaO含量较低属于“先天缺钙”,因此,补充CaO含量,增大Ca(OH)2生成量,更有利于粉煤灰就能水化硬化形成强度。生石灰中CaO的含量70%-76%,且成本低廉,非常适合作为粉煤灰的辅料添加。通过大量实验得出,粉煤灰和石灰的比例为75:25时,能够获得最佳的力学性能。生石灰在消解产生热量(可达80℃-90℃)和消耗水可以促进粉煤灰活性的激发和降低硬化体系的孔隙率,系统暂时性的高浓度OH-1对粉煤灰颗粒表面进行侵蚀,破坏其≡Si-O-Si≡和Si-O-Al≡的网格结构,因而取得较好的激发效果。(2) Use the optimal ratio of fly ash and quicklime. Fly ash belongs to the Cao-SiO 2 -Al 2 O 3 system, and its composition is shown in Table 4. Compared with ordinary Portland cement clinker, fly ash has a lower CaO content and is "congenitally calcium deficient". Therefore, supplementing the CaO content and increasing the amount of Ca(OH) 2 generated are more conducive to the hydration and hardening of fly ash to form strength. The CaO content in quicklime is 70%-76%, and the cost is low, making it very suitable as an auxiliary material for fly ash. Through a large number of experiments, it was found that the best mechanical properties can be obtained when the ratio of fly ash to lime is 75:25. The heat generated by quicklime during digestion (up to 80℃-90℃) and the consumption of water can promote the activation of fly ash activity and reduce the porosity of the hardening system. The temporary high concentration of OH -1 in the system corrodes the surface of fly ash particles, destroying its ≡Si-O-Si≡ and Si-O-Al≡ grid structure, thereby achieving a better activation effect.
表4粉煤灰化学成分表Table 4 Chemical composition of fly ash
(3)采用NaOH和CaCl2的复合碱激发剂,强度激发效果好。粉煤灰的组成物是酸性氧化物,所以具有一定的弱酸性,NaOH中的OH-,能够使粉煤灰中的Si-O键、Al-O键折断开裂,从而增强粉煤灰活性;同时,NaOH中Na+可以改变粉煤灰玻璃体网络结构,使网络结构解体,提高粉煤灰活性。CaCl2中Ca2+和CL-能很好地扩散到粉煤灰颗粒内部,与粉煤灰活性Al2O3发生化学反应,生成C-A-H,增大内外渗透压,破坏粉煤灰包裹体;CaCl2还可以与体系中Ca(OH)2发生化学反应,生成氧氯化钙复盐,不溶于水,是体系中固相成分增加,从而使体系强度增大(图2)。(3) The composite alkali activator of NaOH and CaCl2 is used, which has a good strength activating effect. The components of fly ash are acidic oxides, so it has a certain weak acidity. The OH- in NaOH can break and cleave the Si-O bonds and Al-O bonds in the fly ash, thereby enhancing the activity of the fly ash; at the same time, the Na + in NaOH can change the fly ash glass network structure, disintegrate the network structure, and improve the activity of the fly ash. The Ca2 + and Cl- in CaCl2 can diffuse well into the fly ash particles, react chemically with the active Al2O3 in the fly ash, generate CAH, increase the internal and external osmotic pressure, and destroy the fly ash inclusions; CaCl2 can also react chemically with Ca(OH) 2 in the system to generate calcium oxychloride complex salt, which is insoluble in water, and increases the solid phase component in the system, thereby increasing the strength of the system (Figure 2).
(4)采用复合减水剂,增大强度的同时提高耐久性。复合减水剂为高效引气型减水剂,对粉体颗粒具有分散作用,能改善其工作性,减少单位用水量,改善流动性,节约粉体材料。添加量为粉土的总质量的1.5%-2.5%,在保持塌落度不变的情况下,减少拌合用水量10%-20%;或者在水胶比不变的情况下,增大砂浆的流动性25%-35%。同时,该复合减水剂能够在在拌合的过程中引入大量微小、封闭且均匀分布的气泡,以减少拌合物的泌水、离析,改善和易性,显著提高砂浆抗冻性、耐久性。该复合减水剂可以使砂浆在获得高强度同时具有高耐久性,经检测,基本性能如表5所示。(4) Use composite water reducer to increase strength and durability. Composite water reducer is a high-efficiency air-entraining water reducer that has a dispersing effect on powder particles, can improve its workability, reduce unit water consumption, improve fluidity, and save powder materials. The addition amount is 1.5%-2.5% of the total mass of the silt. While keeping the slump unchanged, the mixing water consumption is reduced by 10%-20%; or while keeping the water-cement ratio unchanged, the fluidity of the mortar is increased by 25%-35%. At the same time, the composite water reducer can introduce a large number of tiny, closed and evenly distributed bubbles during the mixing process to reduce the bleeding and segregation of the mixture, improve workability, and significantly improve the frost resistance and durability of the mortar. The composite water reducer can make the mortar have high strength and high durability at the same time. After testing, the basic properties are shown in Table 5.
表5砂浆耐久性基本参数Table 5 Basic parameters of mortar durability
综上所述,本发明以寒区常见沙漠沙和粉煤灰为原料,采用碱激发技术和耐久性提高措施,制备了适用于寒区工程建筑的砂浆,能够解决目前寒区工程技术难题;技术方案简单、资源丰富、绿色环保、成本低廉;灌注浆液流动性高,充填性好,浆液成型早强快硬,且具有硬化材料耐久的优势,可广泛应用于北方寒区孔洞、基坑、裂缝充填施工。In summary, the present invention uses common desert sand and fly ash in cold regions as raw materials, adopts alkali activation technology and durability improvement measures to prepare mortar suitable for cold region engineering construction, which can solve the current technical problems of cold region engineering; the technical solution is simple, resource-rich, green and environmentally friendly, and low-cost; the pouring slurry has high fluidity and good filling properties, the slurry is formed early and hardens quickly, and has the advantage of durable hardened materials, and can be widely used in the filling construction of holes, foundation pits, and cracks in northern cold regions.
附图说明BRIEF DESCRIPTION OF THE DRAWINGS
图1为电镜放大1000倍不同种类砂特征图,其中(a)为标准砂,(b)为青藏高原沙漠沙,(c)为毛乌素沙漠沙。Figure 1 is a characteristic diagram of different types of sand under an electron microscope magnified 1000 times, where (a) is standard sand, (b) is Qinghai-Tibet Plateau desert sand, and (c) is Maowusu Desert sand.
图2为本发明复合激发剂强度结果图。FIG. 2 is a graph showing the composite stimulator strength results of the present invention.
具体实施方式DETAILED DESCRIPTION
为了使本技术领域的人员更好地理解本发明方案,下面将对发明实施例中的技术方案进行清楚、完整的描述,显然,所描述的实施例仅是发明的一部分实施例,而不是全部的实施例。基于本发明中的实施例,本领域普通技术人员在没有做出创造性劳动前提下所获得的所有其他实施例,都应当属于本发明保护的范围。In order to enable those skilled in the art to better understand the solutions of the present invention, the technical solutions in the embodiments of the present invention are described clearly and completely below. Obviously, the described embodiments are only part of the embodiments of the present invention, not all of them. Based on the embodiments of the present invention, all other embodiments obtained by ordinary technicians in this field without creative work should fall within the scope of protection of the present invention.
实施例1Example 1
一种寒区沙漠沙复合碱激发抗冻砂浆,主要应用于北方寒区工程建设中,包括以下组分:A cold region desert sand composite alkali activated antifreeze mortar, mainly used in northern cold region engineering construction, including the following components:
粉煤灰100份、生石灰20份、碱激发剂10份、沙漠沙500份、复合减水剂4份,水35份;粉煤灰为工业粉煤灰,如燃煤电厂排除的固体废弃物,任意比的活性SiO2、活性Al2O3和f-CaO(游离氧化钙)占粉煤灰质量50%,Fe2O3占粉煤灰质量5%;碱激发剂为复合激发剂,含均匀混合的占碱激发剂质量1%的NaOH和占碱激发剂质量2%的CaCl2;复合减水剂为引气型减水剂,减水率25%,引气量6%;水的温度为60℃。100 parts of fly ash, 20 parts of quicklime, 10 parts of alkali activator, 500 parts of desert sand, 4 parts of composite water reducer, and 35 parts of water; the fly ash is industrial fly ash, such as solid waste discharged from coal-fired power plants, and any proportion of active SiO2 , active Al2O3 and f-CaO (free calcium oxide) accounts for 50% of the fly ash mass, and Fe2O3 accounts for 5% of the fly ash mass; the alkali activator is a composite activator, containing evenly mixed NaOH accounting for 1% of the mass of the alkali activator and CaCl2 accounting for 2% of the mass of the alkali activator; the composite water reducer is an air-entraining type water reducer with a water reduction rate of 25% and an air entrainment amount of 6%; the water temperature is 60°C.
一种寒区沙漠沙复合碱激发抗冻砂浆的制备方法,包括以下步骤:A method for preparing cold region desert sand composite alkali activated antifreeze mortar comprises the following steps:
(1)准备复合碱激发剂:取10份均匀混合的占碱激发剂质量1%的NaOH和占碱激发剂质量2%的CaCl2,后用60℃水充分拌合溶解,待充分溶解后置于60℃养护箱中备用;(1) Prepare the composite alkali activator: Take 10 parts of NaOH accounting for 1% of the mass of the alkali activator and CaCl 2 accounting for 2% of the mass of the alkali activator, mix them thoroughly with 60°C water to dissolve, and place them in a 60°C curing box for use after they are fully dissolved;
(2)取粉煤灰100份、生石灰20份和沙漠沙500份,反复搅拌,待均匀混合后备用;(2) Take 100 parts of fly ash, 20 parts of quicklime and 500 parts of desert sand, stir repeatedly until evenly mixed and set aside;
(3)将步骤(1)配置好的复合激发剂溶液缓慢加入步骤(2)得到的砂浆中,在搅拌器中以120r/min的速度搅拌,搅拌的过程中缓慢加入4份引气型减水剂和水,其中用水量=总用水量-碱激发中的用水量;(3) slowly adding the composite activator solution prepared in step (1) into the mortar obtained in step (2), stirring in a stirrer at a speed of 120 r/min, and slowly adding 4 parts of air-entraining water-reducing agent and water during stirring, wherein the amount of water used = the total amount of water used - the amount of water used in alkali activation;
由于减水剂的作用,砂浆会变得粘稠,因此整个加水搅拌时间为8min,得到沙漠沙碱激发抗冻砂浆材料密封保存备用,砂浆工程参数见表6所示。Due to the effect of the water reducer, the mortar will become viscous, so the entire water adding and stirring time is 8 minutes. The desert sand alkali activated antifreeze mortar material is sealed and stored for later use. The mortar engineering parameters are shown in Table 6.
一种寒区沙漠沙复合碱激发抗冻砂浆的施工方法,包括以下步骤:A construction method of cold region desert sand composite alkali activated antifreeze mortar, comprising the following steps:
步骤一、准备好水、电及管道等施工材料,将岩石裂缝的地面整平,再将流水注入裂缝将其内部冲刷干净,增大岩石与胶凝材料的黏结力;Step 1: Prepare water, electricity, pipelines and other construction materials, level the ground of the rock crack, and then inject running water into the crack to clean it, thereby increasing the bonding force between the rock and the cementitious material;
步骤二、将拌合好制备的沙漠沙碱激发抗冻砂浆进行灌注施工,应注意需进行连续施工,避免出现离析、漏浆,并保证在砂浆初凝前完成灌注;Step 2: Pour the prepared desert sand-alkali activated antifreeze mortar into the mortar. It should be noted that continuous construction is required to avoid segregation and leakage, and the pouring is completed before the mortar begins to set;
步骤三、在充填完成后,对灌注表面进行抹平与清理,并覆盖塑料膜,避免养护过程中水分流失、表面干燥开裂,从而提高砂浆强度。Step 3. After the filling is completed, the poured surface is smoothed and cleaned, and covered with plastic film to prevent moisture loss and surface drying and cracking during the curing process, thereby improving the mortar strength.
表6砂浆工程参数Table 6 Mortar engineering parameters
实施例2Example 2
一种寒区沙漠沙复合碱激发抗冻砂浆,主要应用于北方寒区工程建设中,包括以下组分:A cold region desert sand composite alkali activated antifreeze mortar, mainly used in northern cold region engineering construction, including the following components:
粉煤灰100份、生石灰25份、碱激发剂13份、沙漠沙600份、复合减水剂6份,水40份;粉煤灰为工业粉煤灰,如燃煤电厂排除的固体废弃物,任意比的活性SiO2、活性Al2O3和f-CaO(游离氧化钙)占粉煤灰质量51.3%,Fe2O3占粉煤灰质量5.1%;碱激发剂为复合激发剂,含均匀混合的占碱激发剂质量1.5%的NaOH和占碱激发剂质量2.3%的CaCl2;复合减水剂为引气型减水剂,减水率22.4%,引气量6.5%;水的温度为70℃。100 parts of fly ash, 25 parts of quicklime, 13 parts of alkali activator, 600 parts of desert sand, 6 parts of composite water reducer, and 40 parts of water; the fly ash is industrial fly ash, such as solid waste discharged from coal-fired power plants, and any proportion of active SiO2 , active Al2O3 and f-CaO (free calcium oxide) accounts for 51.3% of the fly ash mass, and Fe2O3 accounts for 5.1% of the fly ash mass; the alkali activator is a composite activator , containing evenly mixed NaOH accounting for 1.5% of the mass of the alkali activator and CaCl2 accounting for 2.3% of the mass of the alkali activator; the composite water reducer is an air-entraining type water reducer with a water reduction rate of 22.4% and an air entrainment amount of 6.5%; the temperature of the water is 70°C.
一种寒区沙漠沙复合碱激发抗冻砂浆的制备方法,包括以下步骤:A method for preparing cold region desert sand composite alkali activated antifreeze mortar comprises the following steps:
(1)准备复合碱激发剂:取13份均匀混合的占碱激发剂质量1.5%的NaOH和占碱激发剂质量2.3%的CaCl2,后用60℃水充分拌合溶解,待充分溶解后置于70℃养护箱中备用;(1) Prepare a composite alkali activator: Take 13 parts of NaOH accounting for 1.5% of the mass of the alkali activator and CaCl 2 accounting for 2.3% of the mass of the alkali activator, mix them thoroughly with 60°C water to dissolve, and place them in a 70°C curing box for use after they are fully dissolved;
(2)取粉煤灰100份、生石灰25份和沙漠沙600份,反复搅拌,待均匀混合后备用;(2) Take 100 parts of fly ash, 25 parts of quicklime and 600 parts of desert sand, stir repeatedly until evenly mixed and set aside;
(3)将步骤(1)配置好的复合激发剂溶液缓慢加入步骤(2)得到的砂浆中,在搅拌器中以120r/min的速度搅拌,搅拌的过程中缓慢加入6份引气型减水剂和水,其中用水量=总用水量-碱激发中的用水量;(3) slowly adding the composite activator solution prepared in step (1) into the mortar obtained in step (2), stirring in a stirrer at a speed of 120 r/min, and slowly adding 6 parts of air-entraining water-reducing agent and water during stirring, wherein the amount of water used = the total amount of water used - the amount of water used in alkali activation;
由于减水剂的作用,砂浆会变得粘稠,因此整个加水搅拌时间为8min,得到沙漠沙碱激发抗冻砂浆材料密封保存备用,砂浆工程参数见表7所示。Due to the effect of the water reducer, the mortar will become viscous, so the entire water adding and stirring time is 8 minutes. The desert sand alkali activated antifreeze mortar material is sealed and stored for later use. The mortar engineering parameters are shown in Table 7.
一种寒区沙漠沙复合碱激发抗冻砂浆的施工方法,包括以下步骤:A construction method of cold region desert sand composite alkali activated antifreeze mortar, comprising the following steps:
步骤一、准备好水、电及管道等施工材料,将岩石裂缝的地面整平,再将流水注入裂缝将其内部冲刷干净,增大岩石与胶凝材料的黏结力;Step 1: Prepare water, electricity, pipelines and other construction materials, level the ground of the rock crack, and then inject running water into the crack to clean it, thereby increasing the bonding force between the rock and the cementitious material;
步骤二、将拌合好制备的沙漠沙碱激发抗冻砂浆进行灌注施工,应注意需进行连续施工,避免出现离析、漏浆,并保证在砂浆初凝前完成灌注;Step 2: Pour the prepared desert sand-alkali activated antifreeze mortar into the mortar. It should be noted that continuous construction is required to avoid segregation and leakage, and the pouring is completed before the mortar begins to set;
步骤三、在充填完成后,对灌注表面进行抹平与清理,并覆盖塑料膜,避免养护过程中水分流失、表面干燥开裂,从而提高砂浆强度。Step 3. After the filling is completed, the poured surface is smoothed and cleaned, and covered with plastic film to prevent moisture loss and surface drying and cracking during the curing process, thereby improving the mortar strength.
表7砂浆工程参数Table 7 Mortar engineering parameters
实施例3Example 3
一种寒区沙漠沙复合碱激发抗冻砂浆,包括以下组分:A cold region desert sand composite alkali activated antifreeze mortar, comprising the following components:
粉煤灰100份、生石灰23份、碱激发剂14份、沙漠沙620份、复合减水剂6份,水42份;粉煤灰为工业粉煤灰,如燃煤电厂排除的固体废弃物,任意比的活性SiO2、活性Al2O3和f-CaO(游离氧化钙)占粉煤灰质量57%,Fe2O3占粉煤灰质量5.7%;碱激发剂为复合激发剂,含均匀混合的占碱激发剂质量1.4%的NaOH和占碱激发剂质量2.3%的CaCl2;复合减水剂为引气型减水剂,减水率22.4%,引气量6.5%;水的温度为70℃。100 parts of fly ash, 23 parts of quicklime, 14 parts of alkali activator, 620 parts of desert sand, 6 parts of composite water reducer, and 42 parts of water; the fly ash is industrial fly ash, such as solid waste discharged from coal-fired power plants, and any proportion of active SiO2 , active Al2O3 and f-CaO (free calcium oxide) accounts for 57% of the fly ash mass, and Fe2O3 accounts for 5.7% of the fly ash mass; the alkali activator is a composite activator, containing uniformly mixed NaOH accounting for 1.4% of the mass of the alkali activator and CaCl2 accounting for 2.3% of the mass of the alkali activator; the composite water reducer is an air-entraining type water reducer with a water reduction rate of 22.4% and an air entrainment amount of 6.5%; the temperature of the water is 70°C.
一种寒区沙漠沙复合碱激发抗冻砂浆的制备方法,包括以下步骤:A method for preparing cold region desert sand composite alkali activated antifreeze mortar comprises the following steps:
(1)准备复合碱激发剂:取14份均匀混合的占碱激发剂质量1.4%的NaOH和占碱激发剂质量2.3%的CaCl2,后用70℃水充分拌合溶解,待充分溶解后置于70℃养护箱中备用;(1) Prepare a composite alkali activator: Take 14 parts of NaOH accounting for 1.4% of the mass of the alkali activator and CaCl 2 accounting for 2.3% of the mass of the alkali activator, mix them thoroughly with 70°C water to dissolve, and place them in a 70°C curing box for use after they are fully dissolved;
(2)取粉煤灰100份、生石灰23份和沙漠沙620份,反复搅拌,待均匀混合后备用;(2) Take 100 parts of fly ash, 23 parts of quicklime and 620 parts of desert sand, stir repeatedly until they are evenly mixed and set aside;
(3)将步骤(1)配置好的复合激发剂溶液缓慢加入步骤(2)得到的砂浆中,在搅拌器中以120r/min的速度搅拌,搅拌的过程中缓慢加入6份引气型减水剂和水,其中用水量=总用水量-碱激发中的用水量;(3) slowly adding the composite activator solution prepared in step (1) into the mortar obtained in step (2), stirring in a stirrer at a speed of 120 r/min, and slowly adding 6 parts of air-entraining water-reducing agent and water during stirring, wherein the amount of water used = the total amount of water used - the amount of water used in alkali activation;
由于减水剂的作用,砂浆会变得粘稠,因此整个加水搅拌时间为8min,得到沙漠沙碱激发抗冻砂浆材料密封保存备用,砂浆工程参数见表8所示。Due to the effect of the water reducer, the mortar will become viscous, so the entire water adding and stirring time is 8 minutes. The desert sand alkali activated antifreeze mortar material is sealed and stored for later use. The mortar engineering parameters are shown in Table 8.
一种寒区沙漠沙复合碱激发抗冻砂浆的施工方法,包括以下步骤:A construction method of cold region desert sand composite alkali activated antifreeze mortar, comprising the following steps:
步骤一、准备好水、电及管道等施工材料,将岩石裂缝的地面整平,再将流水注入裂缝将其内部冲刷干净,增大岩石与胶凝材料的黏结力;Step 1: Prepare water, electricity, pipelines and other construction materials, level the ground of the rock crack, and then inject running water into the crack to clean it, thereby increasing the bonding force between the rock and the cementitious material;
步骤二、将拌合好制备的沙漠沙碱激发抗冻砂浆进行灌注施工,应注意需进行连续施工,避免出现离析、漏浆,并保证在砂浆初凝前完成灌注;Step 2: Pour the prepared desert sand-alkali activated antifreeze mortar into the mortar. It should be noted that continuous construction is required to avoid segregation and leakage, and the pouring is completed before the mortar begins to set;
步骤三、在充填完成后,对灌注表面进行抹平与清理,并覆盖塑料膜,避免养护过程中水分流失、表面干燥开裂,从而提高砂浆强度。Step 3. After the filling is completed, the poured surface is smoothed and cleaned, and covered with plastic film to prevent moisture loss and surface drying and cracking during the curing process, thereby improving the mortar strength.
表8砂浆工程参数Table 8 Mortar engineering parameters
实施例4Example 4
一种寒区沙漠沙复合碱激发抗冻砂浆,包括以下组分:A cold region desert sand composite alkali activated antifreeze mortar, comprising the following components:
粉煤灰100份、生石灰28份、碱激发剂13份、沙漠沙700份、复合减水剂7份,水47份;粉煤灰为工业粉煤灰,如燃煤电厂排除的固体废弃物,任意比的活性SiO2、活性Al2O3和f-CaO(游离氧化钙)占粉煤灰质量50%,Fe2O3占粉煤灰质量5%;碱激发剂为复合激发剂,含均匀混合的占碱激发剂质量1.3%的NaOH和占碱激发剂质量2.6%的CaCl2;复合减水剂为引气型减水剂,减水率25%,引气量6%;水温度为60℃。100 parts of fly ash, 28 parts of quicklime, 13 parts of alkali activator, 700 parts of desert sand, 7 parts of composite water reducer, and 47 parts of water; the fly ash is industrial fly ash, such as solid waste discharged from coal-fired power plants, and any proportion of active SiO2 , active Al2O3 and f-CaO (free calcium oxide) accounts for 50% of the fly ash mass, and Fe2O3 accounts for 5% of the fly ash mass; the alkali activator is a composite activator, containing evenly mixed NaOH accounting for 1.3% of the mass of the alkali activator and CaCl2 accounting for 2.6% of the mass of the alkali activator; the composite water reducer is an air-entraining type water reducer with a water reduction rate of 25% and an air entrainment amount of 6%; the water temperature is 60°C.
一种寒区沙漠沙复合碱激发抗冻砂浆的制备方法,包括以下步骤:A method for preparing cold region desert sand composite alkali activated antifreeze mortar comprises the following steps:
(1)准备复合碱激发剂:取13份均匀混合的占碱激发剂质量1.3%的NaOH和占碱激发剂质量2.6%的CaCl2,后用60℃水充分拌合溶解,待充分溶解后置于60℃养护箱中备用;(1) Prepare a composite alkali activator: Take 13 parts of NaOH accounting for 1.3% of the mass of the alkali activator and CaCl 2 accounting for 2.6% of the mass of the alkali activator, mix them thoroughly with 60°C water to dissolve, and place them in a 60°C curing box for use after they are fully dissolved;
(2)取粉煤灰100份、生石灰28份和沙漠沙700份,反复搅拌,待均匀混合后备用;(2) Take 100 parts of fly ash, 28 parts of quicklime and 700 parts of desert sand, stir repeatedly until evenly mixed and set aside;
(3)将步骤(1)配置好的复合激发剂溶液缓慢加入步骤(2)得到的砂浆中,在搅拌器中以120r/min的速度搅拌,搅拌的过程中缓慢加入7份引气型减水剂和水,其中用水量=总用水量-碱激发中的用水量;(3) slowly adding the composite activator solution prepared in step (1) into the mortar obtained in step (2), stirring in a stirrer at a speed of 120 r/min, and slowly adding 7 parts of air-entraining water-reducing agent and water during stirring, wherein the amount of water used = the total amount of water used - the amount of water used in alkali activation;
由于减水剂的作用,砂浆会变得粘稠,因此整个加水搅拌时间为8min,得到沙漠沙碱激发抗冻砂浆材料密封保存备用,砂浆工程参数见表8所示。Due to the effect of the water reducer, the mortar will become viscous, so the entire water adding and stirring time is 8 minutes. The desert sand alkali activated antifreeze mortar material is sealed and stored for later use. The mortar engineering parameters are shown in Table 8.
一种寒区沙漠沙复合碱激发抗冻砂浆的施工方法,包括以下步骤:A construction method of cold region desert sand composite alkali activated antifreeze mortar, comprising the following steps:
步骤一、准备好水、电及管道等施工材料,将岩石裂缝的地面整平,再将流水注入裂缝将其内部冲刷干净,增大岩石与胶凝材料的黏结力;Step 1: Prepare water, electricity, pipelines and other construction materials, level the ground of the rock crack, and then inject running water into the crack to clean it, thereby increasing the bonding force between the rock and the cementitious material;
步骤二、将拌合制备好的砂浆进行灌注施工,应注意需进行连续施工,避免出现离析、漏浆,并保证在砂浆初凝前完成灌注;Step 2: Pour the prepared mortar into the mortar. It should be noted that continuous construction is required to avoid segregation and leakage, and the pouring should be completed before the mortar begins to set;
步骤三、在充填完成后,对灌注表面进行抹平与清理,并覆盖塑料膜,避免养护过程中水分流失、表面干燥开裂,从而提高砂浆强度。Step 3. After the filling is completed, the poured surface is smoothed and cleaned, and covered with plastic film to prevent moisture loss and surface drying and cracking during the curing process, thereby improving the mortar strength.
表9砂浆工程参数Table 9 Mortar engineering parameters
上述具体实施方式用来解释说明本发明,而不是对本发明进行限制,在本发明的精神和权利要求保护范围内,对本发明做出的任何修改、等同替换和改进等,均应包含在本发明的保护范围之内。The above-mentioned specific implementation modes are used to explain the present invention rather than to limit the present invention. Any modification, equivalent substitution and improvement of the present invention within the spirit of the present invention and the protection scope of the claims shall be included in the protection scope of the present invention.
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