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CN111533517B - Rapid repair mortar for high-speed railway concrete track slab and preparation method thereof - Google Patents

Rapid repair mortar for high-speed railway concrete track slab and preparation method thereof Download PDF

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Publication number
CN111533517B
CN111533517B CN202010346732.1A CN202010346732A CN111533517B CN 111533517 B CN111533517 B CN 111533517B CN 202010346732 A CN202010346732 A CN 202010346732A CN 111533517 B CN111533517 B CN 111533517B
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parts
cement
repair mortar
mortar
agent
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CN111533517A (en
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吴韶亮
李海燕
贾恒琼
魏曌
张恒
王涛
杜玮
张琪
王炳岩
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China Academy of Railway Sciences Corp Ltd CARS
Railway Engineering Research Institute of CARS
Beijing Teletron Telecom Engineering Co Ltd
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China Academy of Railway Sciences Corp Ltd CARS
Railway Engineering Research Institute of CARS
Beijing Teletron Telecom Engineering Co Ltd
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    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B28/00Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
    • C04B28/02Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing hydraulic cements other than calcium sulfates
    • C04B28/06Aluminous cements
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2103/00Function or property of ingredients for mortars, concrete or artificial stone
    • C04B2103/0045Polymers chosen for their physico-chemical characteristics
    • C04B2103/0053Water-soluble polymers
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/72Repairing or restoring existing buildings or building materials
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2201/00Mortars, concrete or artificial stone characterised by specific physical values
    • C04B2201/50Mortars, concrete or artificial stone characterised by specific physical values for the mechanical strength
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02WCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W30/00Technologies for solid waste management
    • Y02W30/50Reuse, recycling or recovery technologies
    • Y02W30/91Use of waste materials as fillers for mortars or concrete

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Ceramic Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Structural Engineering (AREA)
  • Organic Chemistry (AREA)
  • Curing Cements, Concrete, And Artificial Stone (AREA)

Abstract

The invention provides a quick repair mortar for a high-speed railway concrete track slab, which comprises the following raw materials in percentage by mass: 100 parts of cement, 50-250 parts of fine aggregate, 5-25 parts of mineral admixture, 0-8 parts of soluble latex powder, 0-20 parts of polymer emulsion, 0.1-1.0 part of water reducing agent, 0.2-2.0 parts of expansion component, 0.1-1.5 parts of plastic agent, 0.1-1.2 parts of early strength agent, 0.2-1.5 parts of retarding component, 0.1-0.5 part of defoaming agent and 0-30 parts of water; wherein the mass parts of the soluble latex powder and the polymer emulsion are not 0 at the same time. The invention also provides a preparation method of the rapid modification mortar and application of the rapid modification mortar in repairing non-structural damage of a ballastless high-speed railway concrete track slab. The rapid repair mortar disclosed by the invention has the characteristics of good workability, high early strength and high strength, high volume stability, good durability and the like.

Description

一种高速铁路混凝土轨道板用快速修补砂浆及其制备方法Rapid repair mortar for high-speed railway concrete track slab and preparation method thereof

技术领域technical field

本发明属于混凝土和铁路建筑材料领域,具体涉及一种用于高速铁路混凝土轨道板快速修补的砂浆及其制备方法。The invention belongs to the field of concrete and railway building materials, and particularly relates to a mortar for rapid repair of concrete track slabs of high-speed railways and a preparation method thereof.

背景技术Background technique

板式无砟轨道是我国高速铁路的主要轨道结构形式之一,以预制轨道板为结构核心。预制轨道板主要可分为CRTSI型、CRTSII型和CRTSIII型。截止到2019年,我国高速铁路运营总里程超过3万公里,铁路线上混凝土轨道板服役数量近1000万块。随着运营时间的增加,出现损伤的轨道板也随之增多。当轨道板出现影响运营安全和耐久性能的局部碎裂、掉块、蜂窝麻面等非结构性损伤时,需要通过天窗时间段内(一般为4小时)对损伤部位进行修补,以达到终止伤损、完善性能、延长使用寿命的目的。常规的水泥砂浆材料存在强度结构形成慢、界面粘结性能和体积稳定性能差等缺点,因此无法满足维修后列车及时开通运营的要求,而且开通运营后维修部位短时间内又重新出现伤损。Slab ballastless track is one of the main track structures of my country's high-speed railways, with prefabricated track slabs as the structural core. Prefabricated track slabs can be mainly divided into CRTSI type, CRTSII type and CRTSIII type. As of 2019, the total operating mileage of high-speed railways in my country has exceeded 30,000 kilometers, and the number of concrete track slabs in service on the railway lines is nearly 10 million. As the operating hours increased, the number of track slabs showing damage also increased. When the track slab has non-structural damage such as local chipping, falling blocks, and honeycomb pitting that affect operational safety and durability, it is necessary to repair the damaged part within the time period of the skylight (usually 4 hours) to stop the damage. damage, improve performance and prolong service life. Conventional cement mortar materials have shortcomings such as slow strength structure formation, poor interfacial bonding performance and volume stability, so they cannot meet the requirements of timely opening and operation of trains after repairs, and the repaired parts are damaged again within a short period of time after opening and operation.

为此,现有技术中出现了专门用于无砟轨道预制轨道板快速修复的砂浆。如公开号CNl02924021A(公开日2013年2月13日)的中国发明专利申请公开了一种无砟轨道维修用复合水泥基快凝干料和砂浆及其制作方法。其中所述干料由质量比是25%~45%复合水泥、7.8%~15%复合矿物掺合料、0.05%~0.1%缓凝剂、0.05%~0.11%消泡剂、0%~0.01%保水剂、0.26%~1%增稠剂、0.1%~0.16%减水剂、0.05%~0.1%纤维和46%~62.5%石英砂组成,所述复合水泥由质量比是10%~20%硅酸盐水泥和80%~90%硫铝酸盐水泥组成,所述复合矿物掺合料由质量比是20%~60%硅灰和40%~80%矿粉组成,所述缓凝剂是硼酸或酒石酸,所述消泡剂是聚醚改性硅消泡剂或聚二甲基硅氧烷,所述保水剂是羟丙基甲基纤维素醚或甲基纤维素醚,所述增稠剂是可再分散乳胶粉,所述减水剂是聚羧酸盐高效减水剂,所述纤维是聚丙烯腈纤维或聚丙烯纤维。虽然该发明披露的砂浆具有快凝早强的性能,但该砂浆的流动性大、塑性差,仅适用于密闭空间填充式施工。而且该发明披露的砂浆28d抗压强度最大仅为45MPa(说明书实施例2),与轨道板C60的强度不匹配,无法满足使用要求。现有技术还出现了有机树脂修补材料。该材料成本较高,对施工环境要求苛刻,且工艺复杂。同时,树脂材料耐老化、耐久性能较差。而且无机-有机材料对温度的敏感性和应力-应变响应性等均存在较大差异,由此容易在修补界面形成应力差,从而导致修补材料与轨道板基体之间产生裂纹、甚至脱落等,难以实现维修的耐久性。中国发明专利CN101560077A中公布了一种应用于板式无砟轨道的环氧树脂砂浆组合物,该砂浆对水泥具有耐热老化、耐化学腐蚀、弹性和机械强度好等特点,但是原材料制备工艺较为复杂,搅拌时间较长,不能较好地满足高铁无砟轨道快速施工和修复要求,该专利中的环氧树脂砂浆组合物未涉及小时强度,而且其28d强度较低。For this reason, the mortar specially used for the rapid repair of the prefabricated track slab of the ballast track appears in the prior art. For example, the Chinese invention patent application with the publication number CN102924021A (published on February 13, 2013) discloses a composite cement-based quick-setting dry material and mortar for ballastless track maintenance and a manufacturing method thereof. The dry material is composed of 25%-45% composite cement, 7.8%-15% composite mineral admixture, 0.05%-0.1% retarder, 0.05%-0.11% defoamer, 0%-0.01% by mass. % water-retaining agent, 0.26%-1% thickener, 0.1%-0.16% water-reducing agent, 0.05%-0.1% fiber and 46%-62.5% quartz sand, the composite cement is composed of 10%-20% by mass. % Portland cement and 80%-90% sulfoaluminate cement, the composite mineral admixture is composed of 20%-60% silica fume and 40%-80% mineral powder in a mass ratio, and the retarder The agent is boric acid or tartaric acid, the defoamer is polyether modified silicon defoamer or polydimethylsiloxane, and the water retention agent is hydroxypropyl methyl cellulose ether or methyl cellulose ether. The thickening agent is redispersible latex powder, the water reducing agent is polycarboxylate superplasticizer, and the fiber is polyacrylonitrile fiber or polypropylene fiber. Although the mortar disclosed in the invention has the properties of fast setting and early strength, the mortar has high fluidity and poor plasticity, and is only suitable for filling construction in confined spaces. Moreover, the maximum compressive strength of the mortar 28d disclosed in this invention is only 45MPa (Example 2 of the specification), which does not match the strength of the track plate C60 and cannot meet the use requirements. There are also organic resin repair materials in the prior art. The cost of the material is high, the construction environment is demanding, and the process is complicated. At the same time, the resin material has poor aging resistance and durability. In addition, the sensitivity to temperature and stress-strain responsiveness of inorganic-organic materials are quite different, so it is easy to form a stress difference at the repair interface, which leads to cracks or even shedding between the repair material and the track plate substrate. It is difficult to achieve durability for maintenance. Chinese invention patent CN101560077A discloses an epoxy resin mortar composition applied to slab ballastless track. The mortar has the characteristics of heat aging resistance, chemical corrosion resistance, good elasticity and mechanical strength to cement, but the preparation process of raw materials is relatively complicated. , the stirring time is long, and it cannot well meet the requirements of rapid construction and repair of high-speed rail ballastless tracks. The epoxy resin mortar composition in this patent does not involve hourly strength, and its 28d strength is low.

发明内容SUMMARY OF THE INVENTION

本发明的主要目的是提供一种用于高速铁路混凝土轨道板用快速修补砂浆及其制备方法。该快速修补砂浆具有施工简便、界面粘结性和匹配性好、体积稳定性高、抗渗性能和耐久性能优良等优点。The main purpose of the present invention is to provide a quick repair mortar for high-speed railway concrete track slab and a preparation method thereof. The quick repair mortar has the advantages of simple construction, good interfacial adhesion and matching, high volume stability, excellent impermeability and durability.

为了实现上述技术效果,本发明所采用了如下的技术方案:In order to realize the above-mentioned technical effect, the present invention adopts the following technical scheme:

一种用于高速铁路混凝土轨道板的快速修补砂浆,原料按质量分数计包括:水泥100份,细骨料50份~250份,矿物掺合料5~25份,可溶性乳胶粉0份~8份,聚合物乳液0份~20份,减水剂0.1份~1.0份,膨胀组分0.2份~2.0份,塑性剂0.1份~1.5份,早强剂0.1份~1.2份,缓凝组分0.2份~1.5份,消泡剂0.1~0.5份,水0份~30份;其中所述可溶性乳胶粉和所述聚合物乳液的质量份数不同时为0。A kind of quick repair mortar for high-speed railway concrete track slab, raw materials by mass fraction include: cement 100 parts, fine aggregates 50-250 parts, mineral admixtures 5-25 parts, soluble latex powder 0-8 parts parts, polymer emulsion 0-20 parts, water reducing agent 0.1-1.0 parts, swelling component 0.2-2.0 parts, plasticizer 0.1-1.5 parts, early strength agent 0.1-1.2 parts, retarding component 0.2 to 1.5 parts, 0.1 to 0.5 parts of defoamer, and 0 to 30 parts of water; wherein the parts by mass of the soluble latex powder and the polymer emulsion are not 0 at the same time.

优选地,所述用于高速铁路混凝土轨道板的快速修补砂浆,原料按质量分数计包括:水泥100份,细骨料100份~180份,矿物掺合料10~25份,可溶性乳胶粉0份~5份,聚合物乳液0份~15份,减水剂0.1份~0.6份,膨胀组分0.2份~1.5份,塑性剂0.1份~1.0份,早强剂0.1份~1.0份,缓凝组分0.2份~1.0份,消泡剂0.1~0.3份,水3份~25份;其中所述可溶性乳胶粉和所述聚合物乳液的质量份数不同时为0。Preferably, for the rapid repair mortar for high-speed railway concrete track slab, the raw materials, in terms of mass fraction, include: 100 parts of cement, 100 to 180 parts of fine aggregate, 10 to 25 parts of mineral admixture, and 0 parts of soluble latex powder. parts to 5 parts, 0 parts to 15 parts of polymer emulsion, 0.1 part to 0.6 part of water reducing agent, 0.2 part to 1.5 part of swelling component, 0.1 part to 1.0 part of plasticizer, 0.1 part to 1.0 part of early strength agent, 0.2 to 1.0 parts of coagulation component, 0.1 to 0.3 parts of defoamer, and 3 to 25 parts of water; wherein the parts by mass of the soluble latex powder and the polymer emulsion are not 0 at the same time.

优选地,所述水泥选自硫铝酸盐水泥、硅酸盐水泥或超细水泥中的一种或任意比例的多种。Preferably, the cement is selected from one or any ratio of sulfoaluminate cement, Portland cement or ultrafine cement.

优选地,所述硅酸盐水泥选自52.5级硅酸盐水泥和62.5级硅酸盐水泥中的一种或任意比例的多种。Preferably, the Portland cement is selected from one or a plurality of any proportions of Portland cement of grade 52.5 and Portland cement of grade 62.5.

优选地,所述的硫铝酸盐水泥为42.5级硫铝酸盐水泥和52.5级硫铝酸盐水泥中的一种或任意比例的多种。Preferably, the sulfoaluminate cement is one or more than one of grade 42.5 sulfoaluminate cement and grade 52.5 sulfoaluminate cement.

优选地,所述的超细水泥的比表面积不小于500m2/kg。Preferably, the specific surface area of the ultrafine cement is not less than 500 m 2 /kg.

优选地,所述细骨料选自连续颗粒级配的40目~120目、含水率不大于0.5%(w/w)的石英砂、河砂和山砂中的一种或任意比例的多种。Preferably, the fine aggregate is selected from one or more of quartz sand, river sand and mountain sand with a continuous particle gradation of 40 mesh to 120 mesh and a moisture content of not more than 0.5% (w/w). kind.

优选地,所述矿物掺合料选自硅灰、磨细矿渣粉、I级粉煤灰和II级粉煤灰中的一种或任意比例的多种。Preferably, the mineral admixture is selected from one or more than one selected from the group consisting of silica fume, ground slag powder, Class I fly ash and Class II fly ash.

所述硅灰为满足标准GB/T27690《砂浆和混凝土用硅灰》要求的任一种或多种硅灰,包括普通硅灰和/或改性硅灰。The silica fume is any one or more kinds of silica fume that meet the requirements of the standard GB/T27690 "Silica Fume for Mortar and Concrete", including ordinary silica fume and/or modified silica fume.

优选地,所述可溶性乳胶粉选自醋酸乙烯酯与乙烯共聚胶粉、苯乙烯与丁二烯共聚胶粉和丙烯酸酯与苯乙烯共聚胶粉中的一种或任意比例的多种。Preferably, the soluble latex powder is selected from one or any ratio of vinyl acetate-ethylene copolymer rubber powder, styrene-butadiene copolymer rubber powder, and acrylate-styrene copolymer rubber powder.

优选地,所述聚合物乳液选自改性丙烯酸乳液、丁苯乳液、苯丙乳液、羧基丁苯乳液和醋酸乙烯胶乳中的一种或任意比例的多种。Preferably, the polymer emulsion is selected from modified acrylic emulsion, styrene-butadiene emulsion, styrene-acrylic emulsion, carboxylated styrene-butadiene emulsion and vinyl acetate latex, or a plurality of them in any proportion.

还优选地,所述聚合物乳液的固含量为30%~50%(w/w)。Also preferably, the solid content of the polymer emulsion is 30% to 50% (w/w).

优选地,所述减水剂选自氨基羧酸减水剂、聚羧酸减水剂和萘系减水剂中的一种或任意比例的多种。Preferably, the water-reducing agent is selected from one or a plurality of arbitrary proportions of aminocarboxylic acid water-reducing agent, polycarboxylic acid water-reducing agent and naphthalene-based water-reducing agent.

优选地,所述膨胀组分选自铝粉、塑性膨胀剂、UEA膨胀组分、CSA膨胀组分、氧化钙膨胀组分和氧化镁膨胀组分中的一种或任意比例的多种。Preferably, the expansion component is selected from one or a plurality of any ratios of aluminum powder, plastic expansion agent, UEA expansion component, CSA expansion component, calcium oxide expansion component and magnesium oxide expansion component.

还优选地,所述铝粉为细度大于200目的鳞片状铝粉或颗粒状铝粉。Also preferably, the aluminum powder is scaly aluminum powder or granular aluminum powder with a fineness greater than 200 meshes.

优选地,所述塑性剂选自膨润土、羟丙基甲基纤维素醚、卡波姆树脂和改性淀粉中的一种或任意比例的多种。Preferably, the plasticizer is selected from one or more of bentonite, hydroxypropyl methyl cellulose ether, carbomer resin and modified starch in any proportion.

优选地,所述早强剂选自甲酸钙、三乙醇胺、碳酸锂和氢氧化锂中的一种或任意比例的多种。Preferably, the early strength agent is selected from calcium formate, triethanolamine, lithium carbonate and lithium hydroxide, or a plurality of them in any proportion.

优选地,所述缓凝组分选自葡萄酸钠、硼砂、柠檬酸钠、硼酸和酒石酸中的一种或任意比例的多种。Preferably, the setting retarding component is selected from one or a plurality of any ratios of sodium gluconate, borax, sodium citrate, boric acid and tartaric acid.

优选地,所述消泡剂为有机硅消泡剂。Preferably, the defoamer is a silicone defoamer.

优选地,本发明所述用于高速铁路混凝土轨道板的快速修补砂浆还可以包括调色剂。Preferably, the quick repair mortar for high-speed railway concrete track slabs of the present invention may further include a toner.

优选地,所述调色剂的质量份数不多于0.5份。Preferably, the mass part of the toner is not more than 0.5 part.

优选地,所述调色剂选自油墨、石墨和炭黑中的一种或任意比例的多种。Preferably, the toner is selected from one or more of ink, graphite and carbon black in any proportion.

上述原料中,水泥、细骨料、矿物掺合料、可溶性乳胶粉、减水剂、膨胀组分、塑性剂、早强剂、缓凝组分和调色剂为固态的原料;聚合物乳液、消泡剂和水是非固态的原料。Among the above-mentioned raw materials, cement, fine aggregate, mineral admixture, soluble latex powder, water reducing agent, swelling component, plasticizer, early strength agent, retarding component and toner are solid raw materials; polymer emulsion , defoamer and water are non-solid raw materials.

本发明还有一个目的在于提供上述用于高速铁路混凝土轨道板的快速修补砂浆的制备方法,包括如下操作:Another object of the present invention is to provide the above-mentioned preparation method for the rapid repair mortar for high-speed railway concrete track slab, comprising the following operations:

I.按照配比准备各原料;1. Prepare each raw material according to the proportion;

II.将固态的原料(水泥、细骨料、矿物掺合料、可溶性乳胶粉、减水剂、膨胀组分、塑性剂、早强剂、缓凝组分和调色剂(如有)等)混合均匀;II. The solid raw materials (cement, fine aggregate, mineral admixture, soluble latex powder, water reducing agent, swelling component, plasticizer, early strength agent, retarding component and toner (if any), etc. )well mixed;

III.再加入非固态的原料(消泡剂、聚合物乳液(如有)和水),搅拌混合均匀。III. Add non-solid raw materials (defoamer, polymer emulsion (if any) and water), stir and mix evenly.

优选地,所述步骤II和步骤III在带有搅拌装置的设备中进行。Preferably, the steps II and III are carried out in equipment with stirring means.

进一步优选地,在带有搅拌装置地设备中,所述步骤II搅拌速度不小于60r/min,搅拌时间不小于30s,所述步骤III搅拌速度不小于120r/min,搅拌时间不小于60s。Further preferably, in the equipment with a stirring device, the stirring speed of the step II is not less than 60r/min, the stirring time is not less than 30s, the stirring speed of the step III is not less than 120r/min, and the stirring time is not less than 60s.

本发明还有第三个目的在于提供上述快速修补砂浆以及通过上述方法制备的快速修补砂浆在无砟高速铁路混凝土轨道板非结构性伤损修补中的应用。The third object of the present invention is to provide the above quick repair mortar and the application of the quick repair mortar prepared by the above method in non-structural damage repair of ballastless high-speed railway concrete track slabs.

所述高速铁路无砟轨道混凝土轨道板包括CTRSI型、CTRSII型和CTRIII型。The high-speed railway ballastless track concrete track slab includes CTRSI type, CTRSII type and CTRIIII type.

具体地,所述无砟高速铁路混凝土轨道板非结构性伤损修补包括如下步骤:Specifically, the non-structural damage repair of the ballastless high-speed railway concrete track slab includes the following steps:

第一步:待维修部位的清洁,除去待维修部位表面不牢固的结构和灰尘等杂物;Step 1: Clean the parts to be repaired, and remove the weak structure and dust and other debris on the surface of the parts to be repaired;

第二步:待维修部位预处理,涂刷界面剂,必要时可进行植筋以增强维修砂浆与混凝土基体的粘结性能和耐久性能;Step 2: Pre-treat the parts to be repaired, paint the interface agent, and plant reinforcement if necessary to enhance the bonding performance and durability of the repair mortar and the concrete matrix;

第三步:灌注所述快速修补砂浆;The third step: pouring the quick repair mortar;

第四步:根据实际情况进行维修部位的后续处理,如涂刷防护涂料等。Step 4: Carry out the follow-up treatment of the repaired parts according to the actual situation, such as painting protective paint, etc.

在本说明书中,如无特殊说明,技术术语具有其通常的含义。如,“和易性”是指新拌砂浆(或者混凝土)的一项综合技术指标,通常包括流动性、保水性、泌水性、黏聚性等性能指标。In this specification, unless otherwise specified, technical terms have their usual meanings. For example, "workability" refers to a comprehensive technical index of fresh mortar (or concrete), usually including performance indicators such as fluidity, water retention, bleeding, and cohesion.

在本说明书中,所述各组分的质量份数是指各组分的相对用量配比关系,而不是指各组分的具体质量。根据具体情况,1质量份可以是500g,1kg,10kg,或任意质量。In this specification, the mass fraction of each component refers to the relative dosage ratio relationship of each component, rather than the specific mass of each component. 1 mass part can be 500g, 1kg, 10kg, or any mass according to specific circumstances.

本发明的目的是针对高速铁路板式无砟轨道混凝土轨道板出现的蜂窝麻面、局部碎裂或掉块、承台损坏、预应力锚穴封锚砂浆损坏等非结构性损伤,提供一种快速修补砂浆。该快速修补砂浆是根据高速铁路天窗维修期短的特点(一般为4小时)和施工要求,通过优化细骨料的级配,以及通过膨胀组分、减水剂、可溶性胶粉、聚合物乳液、早强剂、缓凝组分等组分的复配技术,使得砂浆具有和易性好、早强和高强、体积稳定性高、耐久性好等特性。并且本发明提供的所述快速修补砂浆的界面粘结性和匹配性好,与混凝土轨道板基体具有良好的一致性。The purpose of the present invention is to provide a quick and easy solution for non-structural damages such as honeycomb pitted surface, local fragmentation or falling blocks, damage to the bearing platform, damage to the prestressed anchor hole sealing mortar of the high-speed railway slab-type ballastless track concrete track slab, etc. Repair mortar. The quick repair mortar is based on the characteristics of short maintenance period (usually 4 hours) and construction requirements of high-speed railway skylights, by optimizing the gradation of fine aggregates, and by expanding components, water reducing agents, soluble rubber powder, polymer emulsion The compound technology of components such as early strength agent and retarder component makes the mortar have the characteristics of good workability, early strength and high strength, high volume stability and good durability. In addition, the quick repair mortar provided by the present invention has good interfacial cohesion and matching, and has good consistency with the base of the concrete track slab.

具体而言,可溶性胶粉和/或聚合物乳液能够使砂浆浆体具有较高粘结性能,有助于提高修补砂浆与界面的粘结力,而且砂浆固化与聚合物成膜同步进行,显著提高了修补砂浆的密实性,进而改善了砂浆的抗渗性和抗冻性能等。不同膨胀组分的复配显著改善了修补砂浆硬化过程中各个阶段的体积稳定性。后续实施例示出,本发明提供的快速修补砂浆2h抗压强度就达到21MPa以上,1d抗压强度在42MPa以上,28天时抗压强度可达70MPa。砂浆的抗折强度在2h、1d和28d时分别可以达到4.3MPa以上、6.3MPa以上以及11.7MPa以上。此外,实施例还示出,28d的砂浆收缩率小于0.01%,修补砂浆与轨道板基体之间的界面应力得以降低,从而保证了修补效果的耐久性。塑性剂有效地改善砂浆的和易性的同时,增强了所述修补砂浆的保塑性,因此降低了施工难度,提高了工作效率。Specifically, the soluble rubber powder and/or polymer emulsion can make the mortar paste have high bonding performance, which helps to improve the adhesion between the repair mortar and the interface, and the mortar curing and polymer film formation are carried out simultaneously, which significantly The compactness of the repair mortar is improved, and the impermeability and frost resistance of the mortar are further improved. The compounding of different expansion components significantly improves the volume stability of the repair mortar at various stages during the hardening process. Subsequent examples show that the compressive strength of the quick repair mortar provided by the present invention reaches over 21 MPa in 2 hours, over 42 MPa in 1 d, and up to 70 MPa in 28 days. The flexural strength of mortar can reach above 4.3MPa, above 6.3MPa and above 11.7MPa at 2h, 1d and 28d, respectively. In addition, the examples also show that the mortar shrinkage rate of 28d is less than 0.01%, and the interface stress between the repair mortar and the track plate substrate is reduced, thereby ensuring the durability of the repair effect. The plasticizer effectively improves the workability of the mortar and at the same time enhances the plasticity retention of the repair mortar, thus reducing the difficulty of construction and improving the work efficiency.

具体实施方式Detailed ways

以下参照具体的实施例来说明本发明。本领域技术人员能够理解,这些实施例仅用于说明本发明,其不以任何方式限制本发明的范围。The present invention will be described below with reference to specific examples. Those skilled in the art can understand that these examples are only for illustrating the present invention, and they do not limit the scope of the present invention in any way.

下述实施例中的实验方法,如无特殊说明,均为常规方法。下述实施例中所用的原料、试剂材料等,如无特殊说明,均为市售购买产品。The experimental methods in the following examples are conventional methods unless otherwise specified. The raw materials, reagent materials, etc. used in the following examples are all commercially available products unless otherwise specified.

实施例1一种用于高速铁路混凝土轨道板的快速修补砂浆 Embodiment 1 A kind of quick repair mortar for high-speed railway concrete track slab

本实施例中的快速修补砂浆原材料及其质量份数如表1所示;其中,The rapid repair mortar raw materials and their mass fractions in this embodiment are shown in Table 1; wherein,

水泥为52.5级快硬硫铝酸盐水泥;矿物掺合料为I级粉煤灰;细骨料为40目~120目连续颗粒级配的机制砂;膨胀组分为质量比1∶10的塑性膨胀剂和UEA膨胀剂;塑性剂为羟丙基甲基纤维素醚;减水剂为聚羧酸减水剂;早强剂为碳酸锂;缓凝组分为质量比1∶1的酒石酸和硼酸;可溶性胶粉为丙烯酸酯与苯乙烯共聚胶粉(质量比1∶1);消泡剂为有机硅消泡剂;调色剂为炭黑;聚合物乳液为固含量48%的改性丙烯酸乳液。The cement is grade 52.5 fast-hardening sulfoaluminate cement; the mineral admixture is grade I fly ash; the fine aggregate is machine-made sand with continuous particle gradation of 40 mesh to 120 mesh; the swelling component is a mass ratio of 1:10 Plastic expansion agent and UEA expansion agent; plastic agent is hydroxypropyl methyl cellulose ether; water reducing agent is polycarboxylate water reducing agent; early strength agent is lithium carbonate; retarding component is tartaric acid with a mass ratio of 1:1 and boric acid; the soluble rubber powder is acrylate and styrene copolymer rubber powder (mass ratio 1:1); the defoamer is a silicone defoamer; the toner is carbon black; the polymer emulsion is modified with a solid content of 48%. acrylic emulsion.

所述快速修补砂浆通过如下方法制备:The quick repair mortar is prepared by the following method:

将所有固态的原料(水泥、细骨料、矿物掺合料、可溶性乳胶粉、减水剂、膨胀组分、塑性剂、早强剂、缓凝组分和调色剂)按比例计量完毕后等加入搅拌机中,以60r/min的速度搅拌45s,将其混合均匀;再按照比例加入消泡剂、聚合物乳液和水,以150r/min搅拌90s,即得。After all solid raw materials (cement, fine aggregate, mineral admixture, soluble latex powder, water reducer, swelling component, plasticizer, early strength agent, retarder component and toner) are measured in proportion After adding it into the mixer, stir at a speed of 60r/min for 45s, and mix it evenly; then add defoamer, polymer emulsion and water in proportion, and stir at 150r/min for 90s, that is, it is obtained.

实施例2一种用于高速铁路混凝土轨道板的快速修补砂浆 Embodiment 2 A kind of quick repair mortar for high-speed railway concrete track slab

本实施例中的快速修补砂浆原材料及其质量份数如表1所示,其中:The rapid repair mortar raw materials and their mass fractions in the present embodiment are shown in Table 1, wherein:

水泥为质量比4∶1的52.5级快硬硫铝酸盐水泥和超细硅酸盐水泥;矿物掺合料为质量比2∶3的硅灰和I级粉煤灰;细骨料为含水率0.1%的40目~120目的河砂;膨胀组分为质量比为1∶2∶12的200目的鳞片状铝粉、塑性膨胀剂和UEA膨胀组分;塑性剂为羟丙基甲基纤维素醚;减水剂为聚羧酸减水剂;早强剂为质量比1∶10的碳酸锂和甲酸钙;缓凝组分为质量比1∶1的酒石酸和柠檬酸;可溶性胶粉为丙烯酸酯与苯乙烯共聚胶粉(质量比为1∶2);消泡剂为有机硅消泡剂;调色剂为炭黑;聚合物乳液为固含量48%的改性丙烯酸乳液。The cement is grade 52.5 fast-hardening sulfoaluminate cement and ultrafine Portland cement with a mass ratio of 4:1; the mineral admixtures are silica fume and grade I fly ash with a mass ratio of 2:3; the fine aggregate is water-containing 40 mesh to 120 mesh river sand with a ratio of 0.1%; the expansion component is 200 mesh scaly aluminum powder with a mass ratio of 1:2:12, plastic expansion agent and UEA expansion component; the plasticizer is hydroxypropyl methyl fiber Plain ether; water reducing agent is polycarboxylate water reducing agent; early strength agent is lithium carbonate and calcium formate with mass ratio of 1:10; retarding component is tartaric acid and citric acid with mass ratio of 1:1; soluble rubber powder is Acrylate and styrene copolymerized rubber powder (mass ratio is 1:2); the defoamer is a silicone defoamer; the toner is carbon black; the polymer emulsion is a modified acrylic emulsion with a solid content of 48%.

所述快速修补砂浆通过如下方法制备:The quick repair mortar is prepared by the following method:

将固态的原料(水泥、细骨料、矿物掺合料、可溶性乳胶粉、减水剂、膨胀组分、塑性剂、早强剂、缓凝组分和调色剂)按比例计量完毕后等加入搅拌机中,以60r/min的速度搅拌45s,将其混合均匀;再按照比例加入消泡剂、聚合物乳液和水,以150r/min搅拌90s,即得。After the solid raw materials (cement, fine aggregate, mineral admixture, soluble latex powder, water reducer, swelling component, plasticizer, early strength agent, retarder component and toner) are measured in proportion, etc. Add it to the mixer, stir at a speed of 60r/min for 45s, and mix it evenly; then add defoamer, polymer emulsion and water according to the proportion, and stir at 150r/min for 90s, that is, it is obtained.

实施例3一种用于高速铁路混凝土轨道板的快速修补砂浆 Embodiment 3 A kind of quick repair mortar for high-speed railway concrete track slab

本实施例中的快速修补砂浆原材料及其质量份数如表1所示,其中:The rapid repair mortar raw materials and their mass fractions in the present embodiment are shown in Table 1, wherein:

水泥为42.5级快硬硫铝酸盐水泥;矿物掺合料为硅灰;细骨料为含水率0.1%的40目~120目河砂;膨胀组分为质量比1∶12的塑性膨胀剂和UEA膨胀组分;塑性剂为质量比1∶1的改性淀粉和羟丙基甲基纤维素醚;减水剂为聚羧酸减水剂;早强剂为氢氧化锂;缓凝组分为2∶1的硼砂和柠檬酸;消泡剂为有机硅消泡剂;调色剂为炭黑;聚合物乳液为固含量48%的改性丙烯酸乳液。The cement is grade 42.5 fast-hardening sulfoaluminate cement; the mineral admixture is silica fume; the fine aggregate is 40-120 mesh river sand with a moisture content of 0.1%; the expansion component is a plastic expansion agent with a mass ratio of 1:12 and UEA swelling component; plasticizer is modified starch and hydroxypropyl methylcellulose ether in mass ratio of 1:1; water reducing agent is polycarboxylate water reducing agent; early strength agent is lithium hydroxide; retarder group It is divided into 2:1 borax and citric acid; the defoamer is a silicone defoamer; the toner is carbon black; the polymer emulsion is a modified acrylic emulsion with a solid content of 48%.

所述快速修补砂浆通过如下方法制备:The quick repair mortar is prepared by the following method:

将固态的原料(水泥、细骨料、矿物掺合料、减水剂、膨胀组分、塑性剂、早强剂、缓凝组分和调色剂)按比例计量完毕后等加入搅拌机中,以60r/min的速度搅拌45s,将其混合均匀;再按照比例加入消泡剂、聚合物乳液和水,以150r/min搅拌90s,即得。Add the solid raw materials (cement, fine aggregate, mineral admixture, water reducing agent, swelling component, plasticizer, early strength agent, retarder component and toner) in proportion to the mixer, etc. Stir at a speed of 60r/min for 45s, and mix it evenly; then add defoamer, polymer emulsion and water in proportion, and stir at 150r/min for 90s, that is, it is obtained.

实施例4一种用于高速铁路混凝土轨道板的快速修补砂浆 Embodiment 4 A kind of quick repair mortar for high-speed railway concrete track slab

本实施例中的快速修补砂浆原材料及其质量份数如表1所示,其中:The rapid repair mortar raw materials and their mass fractions in the present embodiment are shown in Table 1, wherein:

水泥为质量比1∶1的52.5级快硬硫铝酸盐水泥和超细硅酸盐水泥;矿物掺合料为质量比2∶1的I级粉煤灰和硅灰;细骨料为含水率不大于0.1%的质量比1∶1的机制硅砂和烘干河砂;膨胀组分为质量比1∶1∶10的200目的颗粒状铝粉、塑性膨胀剂和UEA膨胀组分;塑性剂为质量比3∶1的膨润土和羟丙基甲基纤维素醚;减水剂为聚羧酸高性能减水剂;早强剂为质量比5∶1的甲酸钙和氢氧化锂;缓凝组分为质量比4∶1的葡萄糖酸钠和酒石酸;消泡剂为有机硅消泡剂;调色剂为炭黑;聚合物乳液为质量比1∶1的固含量48%的改性丙烯酸乳液和固含量50%的苯丙乳液。The cement is grade 52.5 fast-hardening sulfoaluminate cement and ultrafine Portland cement with a mass ratio of 1:1; the mineral admixtures are I-grade fly ash and silica fume with a mass ratio of 2:1; the fine aggregate is water-containing Machine-made silica sand and dried river sand with a mass ratio of 1:1 and a mass ratio of not more than 0.1%; the expansion components are 200 mesh granular aluminum powder with a mass ratio of 1:1:10, plastic expansion agent and UEA expansion component; plasticizer It is bentonite and hydroxypropyl methyl cellulose ether with a mass ratio of 3:1; the water reducing agent is a high-performance polycarboxylate superplasticizer; the early strength agent is calcium formate and lithium hydroxide with a mass ratio of 5:1; retarder The components are sodium gluconate and tartaric acid in a mass ratio of 4:1; the defoamer is a silicone defoamer; the toner is carbon black; the polymer emulsion is a modified acrylic acid with a solid content of 48% in a mass ratio of 1:1 Emulsion and 50% solids styrene-acrylic emulsion.

所述快速修补砂浆通过如下方法制备:The quick repair mortar is prepared by the following method:

将固态的原料(水泥、细骨料、矿物掺合料、减水剂、膨胀组分、塑性剂、早强剂、缓凝组分和调色剂)按比例计量完毕后等加入搅拌机中,以60r/min的速度搅拌45s,将其混合均匀;再按照比例加入消泡剂、聚合物乳液和水,以150r/min搅拌90s,即得。Add the solid raw materials (cement, fine aggregate, mineral admixture, water reducing agent, swelling component, plasticizer, early strength agent, retarder component and toner) in proportion to the mixer, etc. Stir at a speed of 60r/min for 45s, and mix it evenly; then add defoamer, polymer emulsion and water in proportion, and stir at 150r/min for 90s, that is, it is obtained.

实施例5一种用于高速铁路混凝土轨道板的快速修补砂浆 Embodiment 5 A kind of quick repair mortar for high-speed railway concrete track slab

本实施例中的快速修补砂浆原材料及其质量份数如表1所示,其中:The rapid repair mortar raw materials and their mass fractions in the present embodiment are shown in Table 1, wherein:

水泥为52.5级快硬硫铝酸盐水泥;矿物掺合料为质量比1∶1的I级粉煤灰和硅灰;细骨料为含水率不大于0.1%的质量比1∶2的机制硅砂和烘干河砂;膨胀组分为质量比1∶10的塑性膨胀剂和CSA膨胀组分;塑性剂为质量比10∶1的膨润土和羟丙基甲基纤维素醚;减水剂为聚羧酸高性能减水剂;早强剂为碳酸锂;缓凝组分为质量比3∶1的葡萄糖酸钠和硼酸;消泡剂为有机硅消泡剂;调色剂为炭黑;聚合物乳液为固含量50%的丁苯乳液。The cement is grade 52.5 fast-hardening sulfoaluminate cement; the mineral admixtures are grade I fly ash and silica fume with a mass ratio of 1:1; Silica sand and dried river sand; the swelling component is the plastic expansion agent and the CSA expansion component with a mass ratio of 1:10; the plasticizer is bentonite and hydroxypropyl methyl cellulose ether with a mass ratio of 10:1; the water reducing agent is Polycarboxylate high-performance water reducing agent; early strength agent is lithium carbonate; retarding component is sodium gluconate and boric acid with a mass ratio of 3:1; defoamer is silicone defoamer; toner is carbon black; The polymer emulsion is a styrene-butadiene emulsion with a solid content of 50%.

所述快速修补砂浆通过如下方法制备:The quick repair mortar is prepared by the following method:

将固态的原料(水泥、细骨料、矿物掺合料、减水剂、膨胀组分、塑性剂、早强剂、缓凝组分和调色剂)按比例计量完毕后等加入搅拌机中,以60r/min的速度搅拌45s,将其混合均匀;再按照比例加入消泡剂、聚合物乳液和水,以150r/min搅拌90s,即得。Add the solid raw materials (cement, fine aggregate, mineral admixture, water reducing agent, swelling component, plasticizer, early strength agent, retarder component and toner) in proportion to the mixer, etc. Stir at a speed of 60r/min for 45s, and mix it evenly; then add defoamer, polymer emulsion and water in proportion, and stir at 150r/min for 90s, that is, it is obtained.

实施例6一种用于高速铁路混凝土轨道板的快速修补砂浆 Embodiment 6 A kind of quick repair mortar for high-speed railway concrete track slab

本实施例的快速修补砂浆的组成与实施例5完全相同,通过如下方法制备:The composition of the quick repair mortar of this embodiment is exactly the same as that of embodiment 5, and is prepared by the following method:

将固态的原料(水泥、细骨料、矿物掺合料、减水剂、膨胀组分、塑性剂、早强剂、缓凝组分和调色剂)按比例计量完毕后放入高速混料机中,高速混合搅拌12min制得干粉料,封装,备用;在抢修施工现场,按照配合比将所述干粉料、消泡剂、聚合物乳液和水等加入搅拌机,以150r/min搅拌120s,即得。The solid raw materials (cement, fine aggregate, mineral admixture, water reducing agent, swelling component, plasticizer, early strength agent, retarder component and toner) are measured in proportion and put into high-speed mixing In the machine, high-speed mixing and stirring for 12 minutes to obtain dry powder, package, and standby; at the emergency repair construction site, add the dry powder, defoamer, polymer emulsion and water according to the mixing ratio into the mixer, and stir at 150r/min for 120s, That's it.

对比例1一种砂浆 Comparative Example 1 A mortar

本对比例中的砂浆原材料及其质量份数如表1所示,其中:The mortar raw materials and their mass fractions in this comparative example are shown in Table 1, wherein:

水泥为质量比1∶1的52.5级快硬硫铝酸盐水泥和超细硅酸盐水泥;矿物掺合料为质量比2∶1的I级粉煤灰和硅灰;细骨料为含水率不大于0.1%的质量比1∶1的机制硅砂和烘干河砂;膨胀组分为质量比1∶1∶10的200目的颗粒状铝粉、塑性膨胀剂和UEA膨胀组分;塑性剂为质量比3∶1的膨润土和羟丙基甲基纤维素醚;减水剂为聚羧酸高性能减水剂;早强剂为质量比5∶1的甲酸钙和氢氧化锂;缓凝组分为质量比4∶1的葡萄糖酸钠和酒石酸;消泡剂为有机硅消泡剂;调色剂为炭黑。The cement is grade 52.5 fast-hardening sulfoaluminate cement and ultrafine Portland cement with a mass ratio of 1:1; the mineral admixtures are I-grade fly ash and silica fume with a mass ratio of 2:1; the fine aggregate is water-containing Machine-made silica sand and dried river sand with a mass ratio of 1:1 and a mass ratio of not more than 0.1%; the expansion components are 200 mesh granular aluminum powder with a mass ratio of 1:1:10, plastic expansion agent and UEA expansion component; plasticizer It is bentonite and hydroxypropyl methyl cellulose ether with a mass ratio of 3:1; the water reducing agent is a high-performance polycarboxylate superplasticizer; the early strength agent is calcium formate and lithium hydroxide with a mass ratio of 5:1; retarder The components are sodium gluconate and tartaric acid in a mass ratio of 4:1; the defoaming agent is an organosilicon defoaming agent; and the toner is carbon black.

所述快速修补砂浆通过如下方法制备:The quick repair mortar is prepared by the following method:

将所有原料按比例计量完毕后等加入搅拌机中,以60r/min的速度搅拌45s,将其混合均匀;再按照比例加入水,以150r/min搅拌90s,即得。After all the raw materials are measured in proportion, add them to the mixer, stir at a speed of 60r/min for 45s, and mix them evenly; then add water according to the proportion, and stir at 150r/min for 90s.

对比例2一种砂浆 Comparative Example 2 A mortar

本对比例中的砂浆原材料及其质量份数如表1所示,其中:The mortar raw materials and their mass fractions in this comparative example are shown in Table 1, wherein:

水泥为42.5级快硬硫铝酸盐水泥;矿物掺合料为硅灰;细骨料为含水率0.1%的8目~40目河砂;膨胀组分为质量比1∶12的塑性膨胀剂和UEA膨胀组分;塑性剂为质量比1∶1的改性淀粉和羟丙基甲基纤维素醚;减水剂为聚羧酸减水剂;早强剂为氢氧化锂;缓凝组分为2∶1的硼砂和柠檬酸;消泡剂为有机硅消泡剂;调色剂为炭黑;聚合物乳液为固含量48%的改性丙烯酸乳液。The cement is grade 42.5 fast-hardening sulfoaluminate cement; the mineral admixture is silica fume; the fine aggregate is 8-40 mesh river sand with a moisture content of 0.1%; the expansion component is a plastic expansion agent with a mass ratio of 1:12 and UEA swelling component; plasticizer is modified starch and hydroxypropyl methylcellulose ether in mass ratio of 1:1; water reducing agent is polycarboxylate water reducing agent; early strength agent is lithium hydroxide; retarder group It is divided into 2:1 borax and citric acid; the defoamer is a silicone defoamer; the toner is carbon black; the polymer emulsion is a modified acrylic emulsion with a solid content of 48%.

所述快速修补砂浆通过如下方法制备:The quick repair mortar is prepared by the following method:

将固态的原料(水泥、细骨料、矿物掺合料、减水剂、膨胀组分、塑性剂、早强剂、缓凝组分和调色剂)按比例计量完毕后等加入搅拌机中,以60r/min的速度搅拌45s,将其混合均匀;再按照比例加入消泡剂、聚合物乳液和水,以150r/min搅拌90s,即得。Add the solid raw materials (cement, fine aggregate, mineral admixture, water reducing agent, swelling component, plasticizer, early strength agent, retarder component and toner) in proportion to the mixer, etc. Stir at a speed of 60r/min for 45s, and mix it evenly; then add defoamer, polymer emulsion and water in proportion, and stir at 150r/min for 90s, that is, it is obtained.

测试例1实施例1~6制备的用于高速铁路混凝土轨道板的快速修补砂浆及对比例1~2制备的砂浆的性能测定 Test Example 1 Performance determination of the quick repair mortar for high-speed railway concrete track slab prepared in Examples 1-6 and the mortar prepared in Comparative Examples 1-2

按照《水泥胶砂强度检验方法》GB/T 17671-1999、《聚合物改性水泥砂浆试验规程》DL/T5126-2001、《普通混凝土长期性能和耐久性能试验方法标准》GB/T50082-2009等标准规定对上述实施例1~6制备的快速修补砂浆和对比例1~2制备的砂浆分别进行性能测试。测试结果见表2所示。In accordance with "Test Method for Strength of Cement Mortar" GB/T 17671-1999, "Test Procedure for Polymer Modified Cement Mortar" DL/T5126-2001, "Standard for Long-term Performance and Durability Test of Ordinary Concrete" GB/T50082-2009, etc. The standard stipulates that the quick repair mortars prepared in the above examples 1-6 and the mortars prepared in the comparative examples 1-2 are respectively tested for performance. The test results are shown in Table 2.

表2的测试结果显示,本发明的快速修补砂浆2h抗压强度>21MPa,2h抗折强度≥4.3MPa,表明该快速修补砂浆具有早强早硬性,能够满足高速铁路维修窗口期短的要求。本发明的快速修补砂浆28d的抗压强度>67MPa,28d的抗折强度≥11.7MPa,与轨道板的强度匹配。另外,所述快速修补砂浆的抗渗性能均大于P20,28d收缩率不高于0.008%,抗冻等级达到P300,这些数据均说明本发明的快速修补砂浆具有体积稳定性高、抗渗性能和耐久性能优良的特点。The test results in Table 2 show that the 2h compressive strength of the rapid repair mortar of the present invention is greater than 21MPa, and the 2h flexural strength is greater than or equal to 4.3MPa, indicating that the rapid repair mortar has early strength and early hardness, and can meet the requirements of a short maintenance window for high-speed railways. The compressive strength of the quick repair mortar 28d of the present invention is greater than 67MPa, and the flexural strength of the 28d is greater than or equal to 11.7MPa, which is matched with the strength of the track plate. In addition, the impermeability of the quick repair mortar is greater than P20, the 28d shrinkage rate is not higher than 0.008%, and the frost resistance grade reaches P300. These data all show that the rapid repair mortar of the present invention has high volume stability, impermeability and Features of excellent durability.

相比实施例4,对比例1中除了省略聚合物乳液和增加了水的用量,其它原材料及其质量份数均与实施例4相同。对比例1中由于聚合物乳液的缺失导致砂浆的拌和外加水增加,制得砂浆的抗压强度虽略有增加,但是砂浆的抗折强度略有降低,28d收缩率>0.01%。由此表明由于聚合物乳液的缺失使得砂浆的弹韧性变差,进而导致砂浆的抗剪切、抗形变等抗疲劳性能变差。此外砂浆的抗氯离子渗透性能也略有下降。以上均对砂浆的耐久性能有不利影响。Compared with Example 4, in Comparative Example 1, except for omitting the polymer emulsion and increasing the amount of water, other raw materials and their mass fractions are the same as those in Example 4. In Comparative Example 1, due to the lack of polymer emulsion, the mixing of mortar and the addition of water increased. Although the compressive strength of the prepared mortar was slightly increased, the flexural strength of the mortar was slightly reduced, and the 28d shrinkage rate was >0.01%. This shows that the lack of polymer emulsion makes the elasticity and toughness of the mortar deteriorate, which in turn leads to the deterioration of the anti-shearing, anti-deformation and other fatigue resistance properties of the mortar. In addition, the resistance to chloride ion penetration of mortar also decreased slightly. All of the above have an adverse effect on the durability of the mortar.

相对实施例3,对比例2除了细骨料采用8目~40目的砂子外,原材料组成及其质量份数均与实施例3相同。通过结果对比可以看出细骨料级配的改变导致制得砂浆的抗压/抗折强度均有所降低,砂浆的抗氯离子渗透性能变差、收缩率变大,由此表明不按照本发明特定配比进行砂浆的制备,都会使砂浆性能变劣。Compared with Example 3, in Comparative Example 2, the composition of raw materials and their mass fractions are the same as those in Example 3, except that the fine aggregates are 8-40 mesh sand. Through the comparison of the results, it can be seen that the change of the fine aggregate gradation leads to a decrease in the compressive/flexural strength of the prepared mortar, and the resistance to chloride ion penetration and the shrinkage rate of the mortar become worse. Inventing a specific ratio for the preparation of mortar will make the mortar performance worse.

Figure BDA0002468880410000091
Figure BDA0002468880410000091

Claims (10)

1.一种用于高速铁路混凝土轨道板的快速修补砂浆,按质量分数计,原料的组成为:水泥100份,细骨料100份~180份,矿物掺合料10~25份,可溶性乳胶粉0份~5份,聚合物乳液0份~15份,减水剂0.1份~0.6份,膨胀组分0.2份~1.5份,塑性剂0.1份~1.0份,早强剂0.1份~1.0份,缓凝组分0.2份~1.0份,消泡剂0.1~0.3份,水3份~25份;其中所述可溶性乳胶粉和所述聚合物乳液的质量份数不同时为0;1. A rapid repair mortar for high-speed railway concrete track slabs, in terms of mass fraction, the composition of raw materials is: 100 parts of cement, 100 to 180 parts of fine aggregates, 10 to 25 parts of mineral admixtures, and soluble latex 0 to 5 parts of powder, 0 to 15 parts of polymer emulsion, 0.1 to 0.6 parts of water reducing agent, 0.2 to 1.5 parts of swelling components, 0.1 to 1.0 parts of plasticizer, 0.1 to 1.0 parts of early strength agent , 0.2 to 1.0 parts of retarding components, 0.1 to 0.3 parts of defoamer, and 3 to 25 parts of water; wherein the mass fractions of the soluble latex powder and the polymer emulsion are not 0 at the same time; 所述细骨料选自连续颗粒级配的40目~120目、含水率不大于0.5%(w/w)的石英砂或河砂;The fine aggregate is selected from quartz sand or river sand with a continuous particle gradation of 40 mesh to 120 mesh and a moisture content of not more than 0.5% (w/w); 所述矿物掺合料选自硅灰和I级粉煤灰中的一种或两种;The mineral admixture is selected from one or both of silica fume and Class I fly ash; 所述可溶性乳胶粉为丙烯酸酯与苯乙烯共聚胶粉;The soluble latex powder is acrylate and styrene copolymerized rubber powder; 所述聚合物乳液选自质量百分比固含量30%~50%的改性丙烯酸乳液、丁苯乳液和苯丙乳液中的一种或多种;The polymer emulsion is selected from one or more of modified acrylic emulsion, styrene-butadiene emulsion and styrene-acrylic emulsion with a solid content of 30% to 50% by mass percentage; 所述减水剂为聚羧酸减水剂;The water reducing agent is a polycarboxylate water reducing agent; 所述膨胀组分选自铝粉、塑性膨胀剂、UEA膨胀组分和CSA膨胀组分中的一种或多种;The expansion component is selected from one or more of aluminum powder, plastic expansion agent, UEA expansion component and CSA expansion component; 所述塑性剂选自膨润土、羟丙基甲基纤维素醚和改性淀粉中的一种或多种;The plasticizer is selected from one or more of bentonite, hydroxypropyl methylcellulose ether and modified starch; 所述早强剂选自碳酸锂、甲酸钙和氢氧化锂中的一种或多种;Described early strength agent is selected from one or more in lithium carbonate, calcium formate and lithium hydroxide; 所述缓凝组分选自葡萄酸钠、硼砂、柠檬酸钠、硼酸和酒石酸中的一种或多种;The retarding component is selected from one or more of sodium gluconate, borax, sodium citrate, boric acid and tartaric acid; 所述消泡剂为有机硅消泡剂。The defoamer is a silicone defoamer. 2.根据权利要求1所述的快速修补砂浆,其特征在于,所述水泥选自硫铝酸盐水泥、硅酸盐水泥或超细水泥中的一种或任意比例的多种;2. quick repair mortar according to claim 1, is characterized in that, described cement is selected from one or a plurality of arbitrary proportions in sulfoaluminate cement, Portland cement or ultrafine cement; 所述硅酸盐水泥选自52.5级硅酸盐水泥和62.5级硅酸盐水泥中的一种或任意比例的多种;The Portland cement is selected from one or any proportion of Portland cement of grade 52.5 and Portland cement of grade 62.5; 所述的硫铝酸盐水泥为42.5级硫铝酸盐水泥和52.5级硫铝酸盐水泥中的一种或任意比例的多种;Described sulfoaluminate cement is one or a variety of arbitrary proportions in 42.5-grade sulfoaluminate cement and 52.5-grade sulfoaluminate cement; 所述的超细水泥的比表面积不小于500m2/kg。The specific surface area of the ultrafine cement is not less than 500m 2 /kg. 3.根据权利要求1所述的快速修补砂浆,其特征在于,所述铝粉为细度大于200目的鳞片状铝粉或颗粒状铝粉。3 . The quick repair mortar according to claim 1 , wherein the aluminum powder is scaly aluminum powder or granular aluminum powder with a fineness greater than 200 meshes. 4 . 4.根据权利要求1至3任一项所述的快速修补砂浆,其特征在于,所述快速修补砂浆还可以包括调色剂。4. The quick repair mortar according to any one of claims 1 to 3, characterized in that, the quick repair mortar may further comprise a toner. 5.根据权利要求4所述的快速修补砂浆,其特征在于,所述调色剂的质量份数不多于0.5份。5. The quick repair mortar according to claim 4, characterized in that, the mass part of the toner is not more than 0.5 part. 6.根据权利要求4所述的快速修补砂浆,其特征在于,所述调色剂选自油墨、石墨和炭黑中的一种或任意比例的多种。6 . The quick repair mortar according to claim 4 , wherein the toner is selected from one or more of ink, graphite and carbon black in any proportion. 7 . 7.根据权利要求5所述的快速修补砂浆,其特征在于,所述调色剂选自油墨、石墨和炭黑中的一种或任意比例的多种。7 . The quick repair mortar according to claim 5 , wherein the toner is selected from one or more of ink, graphite and carbon black in any proportion. 8 . 8.权利要求1至7中任一项所述的快速修补砂浆的制备方法,包括如下操作:8. the preparation method of the quick repair mortar described in any one of claim 1 to 7, comprises the following operations: I. 按照配比准备各原料;I. Prepare each raw material according to the proportion; II. 将固态的原料混合均匀;II. Mix the solid raw materials evenly; III. 再加入非固态的原料,搅拌混合均匀。III. Add non-solid raw materials, stir and mix evenly. 9.根据权利要求8所述的制备方法,其特征在于,所述步骤II和步骤III在带有搅拌装置的设备中进行。9. The preparation method according to claim 8, wherein the step II and the step III are carried out in a device with a stirring device. 10.根据权利要求9所述的制备方法,其特征在于,在带有搅拌装置地设备中,所述步骤II搅拌速度不小于60r/min,搅拌时间不小于30s,所述步骤III搅拌速度不小于120r/min,搅拌时间不小于60s。10. preparation method according to claim 9 is characterized in that, in the equipment with stirring device, described step II stirring speed is not less than 60r/min, and stirring time is not less than 30s, and described step III stirring speed is not less than 30s. Less than 120r/min, stirring time not less than 60s.
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