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CN115579391A - Multi-channel fin structure and its preparation method - Google Patents

Multi-channel fin structure and its preparation method Download PDF

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CN115579391A
CN115579391A CN202211229937.7A CN202211229937A CN115579391A CN 115579391 A CN115579391 A CN 115579391A CN 202211229937 A CN202211229937 A CN 202211229937A CN 115579391 A CN115579391 A CN 115579391A
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谢勇
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Dongke Semiconductor Anhui Co ltd
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    • HELECTRICITY
    • H10SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10DINORGANIC ELECTRIC SEMICONDUCTOR DEVICES
    • H10D30/00Field-effect transistors [FET]
    • H10D30/40FETs having zero-dimensional [0D], one-dimensional [1D] or two-dimensional [2D] charge carrier gas channels
    • H10D30/47FETs having zero-dimensional [0D], one-dimensional [1D] or two-dimensional [2D] charge carrier gas channels having 2D charge carrier gas channels, e.g. nanoribbon FETs or high electron mobility transistors [HEMT]
    • H10D30/471High electron mobility transistors [HEMT] or high hole mobility transistors [HHMT]
    • H10D30/475High electron mobility transistors [HEMT] or high hole mobility transistors [HHMT] having wider bandgap layer formed on top of lower bandgap active layer, e.g. undoped barrier HEMTs such as i-AlGaN/GaN HEMTs
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
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    • H01L23/00Details of semiconductor or other solid state devices
    • H01L23/34Arrangements for cooling, heating, ventilating or temperature compensation ; Temperature sensing arrangements
    • H01L23/36Selection of materials, or shaping, to facilitate cooling or heating, e.g. heatsinks
    • H01L23/367Cooling facilitated by shape of device
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L23/00Details of semiconductor or other solid state devices
    • H01L23/34Arrangements for cooling, heating, ventilating or temperature compensation ; Temperature sensing arrangements
    • H01L23/36Selection of materials, or shaping, to facilitate cooling or heating, e.g. heatsinks
    • H01L23/373Cooling facilitated by selection of materials for the device or materials for thermal expansion adaptation, e.g. carbon
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    • H10D30/01Manufacture or treatment
    • H10D30/021Manufacture or treatment of FETs having insulated gates [IGFET]
    • H10D30/024Manufacture or treatment of FETs having insulated gates [IGFET] of fin field-effect transistors [FinFET]
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    • H10DINORGANIC ELECTRIC SEMICONDUCTOR DEVICES
    • H10D30/00Field-effect transistors [FET]
    • H10D30/60Insulated-gate field-effect transistors [IGFET]
    • H10D30/62Fin field-effect transistors [FinFET]
    • HELECTRICITY
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    • H10DINORGANIC ELECTRIC SEMICONDUCTOR DEVICES
    • H10D62/00Semiconductor bodies, or regions thereof, of devices having potential barriers
    • H10D62/10Shapes, relative sizes or dispositions of the regions of the semiconductor bodies; Shapes of the semiconductor bodies
    • H10D62/17Semiconductor regions connected to electrodes not carrying current to be rectified, amplified or switched, e.g. channel regions
    • H10D62/213Channel regions of field-effect devices
    • H10D62/221Channel regions of field-effect devices of FETs
    • H10D62/235Channel regions of field-effect devices of FETs of IGFETs

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Abstract

本申请公开了一种集成金刚石的多沟道鳍式GaN器件结构及其制备方法,从器件结构和材料两方面对GaN器件热管理进行了改进。结构上采用多异质结沟道和FinFET器件设计,其中多沟道能够提供更大的电流密度和功率,FinFET结构设计能够在增强栅控的同时,提供更大的散热面积,可以通过氧化湿法腐蚀工艺制备。材料上引入高热导率的金刚石,通过键合工艺集成金刚石衬底,并在栅指之间生长高热导率的金刚石盖帽层,能够将器件热量从上下两个方向有效导出。在多沟道结构和金刚石盖帽层之间以及多沟道结构与栅极之间设计了介质层,保护多沟道结构表面,减少金刚石盖帽层生长过程带来的损伤,能够实现金刚石氧等离子体刻蚀自停止,同时减小栅极漏电。

Figure 202211229937

The present application discloses a diamond-integrated multi-channel fin-type GaN device structure and a preparation method thereof, which improves the thermal management of the GaN device from two aspects of the device structure and materials. The structure adopts multi-heterojunction channel and FinFET device design, among which the multi-channel can provide greater current density and power, and the FinFET structure design can provide a larger heat dissipation area while enhancing gate control, which can prepared by corrosion process. Diamond with high thermal conductivity is introduced into the material, the diamond substrate is integrated through the bonding process, and a diamond cap layer with high thermal conductivity is grown between the gate fingers, which can effectively conduct the heat of the device from the upper and lower directions. A dielectric layer is designed between the multi-channel structure and the diamond cap layer and between the multi-channel structure and the gate to protect the surface of the multi-channel structure, reduce the damage caused by the growth of the diamond cap layer, and realize diamond oxygen plasma Etch self-stop while reducing gate leakage.

Figure 202211229937

Description

多沟道鳍式结构及其制备方法Multi-channel fin structure and its preparation method

技术领域technical field

本申请涉及微电子器件技术领域,具体涉及一种双沟道的鳍式结构及其制备方法。The present application relates to the technical field of microelectronic devices, in particular to a double-channel fin structure and a preparation method thereof.

背景技术Background technique

GaN材料具有禁带宽度大、击穿场强高、迁移率高、电子饱和速度大等特点。由于GaN基材料自发极化和压电极化的特性,AlGaN/GaN异质中可以形成高浓度二维电子气沟道,由此可以制备GaN高电子迁移率晶体管(HEMT),适用于射频和电力电子领域。GaN HEMT器件常工作在高压、大电流条件下,器件的自热效应显著,特别是在栅下靠近漏侧,会在工作时产生局部热点,引起电学特性退化和可靠性问题。GaN materials have the characteristics of large band gap, high breakdown field strength, high mobility, and high electron saturation velocity. Due to the characteristics of spontaneous polarization and piezoelectric polarization of GaN-based materials, a high-concentration two-dimensional electron gas channel can be formed in the AlGaN/GaN heterostructure, and GaN high electron mobility transistors (HEMTs) can be prepared, which are suitable for radio frequency and field of power electronics. GaN HEMT devices often work under high voltage and high current conditions, and the self-heating effect of the device is significant, especially near the drain side under the gate, which will generate local hot spots during operation, causing electrical characteristic degradation and reliability problems.

发明内容Contents of the invention

本申请实施例提供一种多沟道鳍式结构及其制备方法,用于解决现有技术中的高电子迁移率晶体管自热效应明显的技术问题。Embodiments of the present application provide a multi-channel fin structure and a manufacturing method thereof, which are used to solve the technical problem of obvious self-heating effect of high electron mobility transistors in the prior art.

多沟道鳍式结构,包括:Multi-channel fin structures, including:

衬底;Substrate;

多沟道结构,位于所述衬底之上;a multi-channel structure on the substrate;

源/漏/栅极,位于所述多沟道结构中的底部的沟道层之上;a source/drain/gate located on the bottom channel layer in the multi-channel structure;

所述多沟道结构中位于所述栅极内以及所述栅极和漏极之间具有鳍式结构,所述鳍式结构包括多个鳍,所述每个鳍的深度贯穿所述多沟道结构的顶势垒层至底势垒层;In the multi-channel structure, there is a fin structure located in the gate and between the gate and the drain, the fin structure includes a plurality of fins, and the depth of each fin penetrates the multi-channel from the top barrier layer to the bottom barrier layer of the channel structure;

盖帽层,位于所述源极和栅极之间以及所述栅极和漏极之间的多沟道结构之上以及鳍间;a capping layer located between the source and the gate and on the multi-channel structure between the gate and the drain and between the fins;

所述衬底和所述盖帽层的导热率高于所述多沟道结构。The thermal conductivity of the substrate and the capping layer is higher than that of the multi-channel structure.

进一步的,所述盖帽层还位于所述多沟道结构中位于边缘的鳍的外侧。Further, the capping layer is also located outside the edge fins in the multi-channel structure.

进一步的,还包括:Further, it also includes:

一介质层,a medium layer,

位于所述多沟道结构与所述盖帽层之间,located between the multi-channel structure and the capping layer,

和/或,and / or,

位于所述多沟道结构与所述栅极之间。Located between the multi-channel structure and the gate.

进一步的,所述盖帽层的材质为金刚石。Further, the material of the capping layer is diamond.

进一步的,所述盖帽层的厚度为180nm~250nm。Further, the thickness of the capping layer is 180nm-250nm.

进一步的,所述介质层的材质为Al2O3Further, the material of the dielectric layer is Al 2 O 3 .

进一步的,所述介质层的厚度为4nm~6nm。Further, the thickness of the dielectric layer is 4nm-6nm.

进一步的,所述多沟道结构包括多层AlGaN/GaN异质结。Further, the multi-channel structure includes a multi-layer AlGaN/GaN heterojunction.

进一步的,所述衬底的材质为金刚石。Further, the material of the substrate is diamond.

本发明的第二个方面,提供一种多沟道鳍式结构的制备方法,包括:A second aspect of the present invention provides a method for preparing a multi-channel fin structure, including:

准备Si衬底;Prepare the Si substrate;

形成多沟道结构于所述Si衬底之上;forming a multi-channel structure on the Si substrate;

研磨和刻蚀所述Si衬底并在所述多沟道结构下方键合金刚石衬底;grinding and etching the Si substrate and bonding a diamond substrate below the multi-channel structure;

在所述多沟道结构上生长SiO2掩膜层并刻蚀形成凹槽,所述SiO2掩膜层位于栅极区域以及所栅极和漏极区域之间,且所述SiO2掩膜层成鳍式分布;A SiO 2 mask layer is grown on the multi-channel structure and etched to form a groove, the SiO 2 mask layer is located between the gate region and the gate and drain regions, and the SiO 2 mask layer Layered fin distribution;

沿所述SiO2掩膜层的每个鳍刻蚀其下方的多沟道结构直至底势垒层;Etching the multi-channel structure below it along each fin of the SiO2 mask layer until the bottom barrier layer;

高温氧化所述底势垒层,然后湿法腐蚀所述底势垒层并自停止于底部的沟道层表面,使得所述多沟道结构形成鳍式结构;Oxidizing the bottom barrier layer at a high temperature, then wet etching the bottom barrier layer and self-stopping on the surface of the channel layer at the bottom, so that the multi-channel structure forms a fin structure;

去除所述SiO2掩膜层;removing the SiO 2 mask layer;

形成完全覆盖在所有沟道结构表面的介质层,并刻蚀去除源漏区域的介质层;Form a dielectric layer completely covering the surface of all channel structures, and etch to remove the dielectric layer in the source and drain regions;

形成完全覆盖在所述介质层表面的盖帽层;forming a capping layer completely covering the surface of the dielectric layer;

在所述盖帽层上位于源漏区域之间的位置生长Al2O3掩膜层并腐蚀形成图案;growing an Al 2 O 3 mask layer at a position between the source and drain regions on the capping layer and etching to form a pattern;

刻蚀所述源漏区域位置处的盖帽层并自停止于所述介质层表面;etching the cap layer at the position of the source-drain region and self-stopping on the surface of the dielectric layer;

形成在源漏区域的源/漏极并实现欧姆接触;Form the source/drain in the source-drain region and realize the ohmic contact;

形成在栅区域的Al2O3掩膜层凹槽;forming grooves in the Al 2 O 3 mask layer in the gate region;

刻蚀所述Al2O3掩膜层凹槽正下方的盖帽层并自停止于所述介质层表面;Etching the cap layer directly below the groove of the Al 2 O 3 mask layer and self-stopping on the surface of the dielectric layer;

形成在栅区的介质层之上的栅极;a gate formed on the dielectric layer of the gate region;

腐蚀高于源/漏/栅极位置的Al2O3掩膜层。 Etch the Al2O3 mask layer above the source/drain/gate locations.

有益效果Beneficial effect

本发明提出的一种多沟道鳍式结构及其制备方法,该结构采用多异质结沟道和FinFET的结构设计,其中多沟道能够提供更大的电流密度和功率;FinFET结构设计能够在增强栅控的同时,提供更大的散热面积,可以通过氧化湿法腐蚀工艺制备;引入高热导率材料,优选金刚石材料,通过键合集成金刚石衬底,并在栅指之间生长金刚石盖帽层,能够从器件上方和下方将热量有效导出;在多沟道结构和盖帽层之间以及多沟道结构与栅极之间设计了介质层,保护多沟道结构表面,减少金刚石盖帽层生长过程带来的损伤,能够实现金刚石层氧等离子体刻蚀自停止,同时还能减小栅极漏电。The present invention proposes a multi-channel fin structure and its preparation method. The structure adopts the structure design of multiple heterojunction channels and FinFET, wherein the multi-channel can provide greater current density and power; the FinFET structure design can While enhancing grid control, it provides a larger heat dissipation area, which can be prepared by oxidation wet etching process; introduces high thermal conductivity materials, preferably diamond materials, integrates diamond substrates by bonding, and grows diamond caps between grid fingers layer, which can effectively conduct heat from the top and bottom of the device; a dielectric layer is designed between the multi-channel structure and the capping layer and between the multi-channel structure and the gate to protect the surface of the multi-channel structure and reduce the growth of the diamond capping layer The damage caused by the process can realize the self-stopping of the oxygen plasma etching of the diamond layer, and at the same time reduce the gate leakage.

附图说明Description of drawings

构成本申请的一部分的附图用来提供对本申请的进一步理解,本申请的示意性实施例及其说明用于解释本申请,并不构成对本申请的不当限定。在附图中:The drawings constituting a part of the application are used to provide further understanding of the application, and the schematic embodiments and descriptions of the application are used to explain the application, and do not constitute an improper limitation to the application. In the attached picture:

图1为本申请实施例的立体结构示意图;Fig. 1 is the three-dimensional structure schematic diagram of the embodiment of the present application;

图2为本申请申请实施例的在立体结构示意图上的垂直于沟道方向和沿沟道方向的竖直截面位置示意图;Fig. 2 is a schematic diagram of vertical cross-sectional positions perpendicular to the direction of the channel and along the direction of the channel on the schematic diagram of the three-dimensional structure of the embodiment of the application;

图3为本申请实施例中按照图2中垂直于沟道方向且在A-A1位置处的截面示意图;Fig. 3 is a schematic cross-sectional view at the position A-A1 perpendicular to the channel direction in Fig. 2 according to the embodiment of the present application;

图4为本申请实施例中按照图2中垂直于沟道方向且在B-B1位置处的截面示意图;Fig. 4 is a schematic cross-sectional view at the position B-B1 perpendicular to the channel direction in Fig. 2 according to the embodiment of the present application;

图5为本申请实施例中按照图2中垂直于沟道方向且在C-C1位置处的截面示意图;Fig. 5 is a schematic cross-sectional view at the position C-C1 perpendicular to the channel direction in Fig. 2 according to the embodiment of the present application;

图6为本申请实施例中按照图2中沿沟道方向且在D-D1位置处的截面示意图;Fig. 6 is a schematic cross-sectional view at the position D-D1 along the channel direction in Fig. 2 according to the embodiment of the present application;

图7为本申请实施例中按照图2中沿沟道方向且在E-E1位置处的截面示意图;Fig. 7 is a schematic cross-sectional view at the position E-E1 along the channel direction in Fig. 2 according to the embodiment of the present application;

图8为本申请实施例中硅衬底和多沟道结构示意图;FIG. 8 is a schematic diagram of a silicon substrate and a multi-channel structure in an embodiment of the present application;

图9为本申请实施例中去除硅衬底后的结构示意图;FIG. 9 is a schematic diagram of the structure after removing the silicon substrate in the embodiment of the present application;

图10为本申请实施例中金刚石衬底和多沟道结构示意图;10 is a schematic diagram of a diamond substrate and a multi-channel structure in an embodiment of the present application;

图11为本申请实施例中制作Fin结构时生长的SiO2掩膜层的示意图;Fig. 11 is the schematic diagram of the SiO2 mask layer grown when making the Fin structure in the embodiment of the present application;

图12为本申请实施例中制作Fin结构时Cl基ICP刻蚀的示意图;12 is a schematic diagram of Cl-based ICP etching when making a Fin structure in the embodiment of the present application;

图13为本申请实施例中制作Fin结构时湿法氧化腐蚀剩余AlGaN层的示意图;FIG. 13 is a schematic diagram of wet oxidation and etching of the remaining AlGaN layer when the Fin structure is fabricated in the embodiment of the present application;

图14为本申请实施例中制作Fin结构时去除SiO2掩膜层的示意图;14 is a schematic diagram of removing the SiO2 mask layer when making a Fin structure in the embodiment of the present application;

图15为本申请实施例中生长Al2O3介质层的示意图;Fig. 15 is a schematic diagram of growing an Al 2 O 3 dielectric layer in the embodiment of the present application;

图16为本申请实施例中生长金刚石帽层的示意图;Figure 16 is a schematic diagram of growing a diamond cap layer in the embodiment of the present application;

图17为本申请实施例中制作欧姆接触时生长Al2O3掩膜的示意图;17 is a schematic diagram of growing an Al 2 O 3 mask when making an ohmic contact in the embodiment of the present application;

图18为本申请实施例中制作欧姆接触时氧ICP刻蚀金刚石的示意图;Figure 18 is a schematic diagram of oxygen ICP etching diamond when making ohmic contacts in the embodiment of the present application;

图19为本申请实施例中制作欧姆接触时BOE腐蚀去除欧姆区域Al2O3的示意图;Figure 19 is a schematic diagram of BOE etching to remove Al2O3 in the ohmic region when making ohmic contacts in the embodiment of the present application;

图20为本申请实施例中制作欧姆接触时溅射生长源漏金属的示意图;FIG. 20 is a schematic diagram of sputtering and growing source and drain metals when making ohmic contacts in the embodiment of the present application;

图21为本申请实施例中制作栅金属时BOE腐蚀Al2O3,在栅位置形成掩膜版凹槽的示意图;Figure 21 is a schematic diagram of forming a mask groove at the gate position by BOE etching Al 2 O 3 when making the gate metal in the embodiment of the present application;

图22为本申请实施例中制作栅金属时积淀栅金属的示意图。FIG. 22 is a schematic diagram of depositing gate metal when fabricating the gate metal in the embodiment of the present application.

图中,各附图标记含义如下:In the figure, the meanings of each reference sign are as follows:

第一衬底0;衬底1;鳍2;多沟道结构3;第一沟道层3-1;底势垒层3-2;第二沟道层3-3;顶势垒层3-4;介质层4;源极5;漏极6;栅极7;盖帽层8;SiO2掩膜层9;Al2O3掩膜层10。First substrate 0; substrate 1; fin 2; multi-channel structure 3; first channel layer 3-1; bottom barrier layer 3-2; second channel layer 3-3; top barrier layer 3 -4; dielectric layer 4; source 5; drain 6; gate 7; cap layer 8; SiO 2 mask layer 9; Al 2 O 3 mask layer 10.

具体实施方式detailed description

需要说明的是,在不冲突的情况下,本申请中的实施例及实施例中的特征可以相互组合。下面将参考附图并结合实施例来详细说明本申请。It should be noted that, in the case of no conflict, the embodiments in the present application and the features in the embodiments can be combined with each other. The present application will be described in detail below with reference to the accompanying drawings and embodiments.

为了方便描述,此处可能使用诸如“之下”、“下方”、“低于”、“下面”、“上方”、“上”等的空间关系词语来描述附图中所示的一个元件或特征与其他元件或特征的关系。将理解到,这些空间关系词语意图包含使用中或操作中的器件的、除了附图中描绘的方向之外的其他方向。此外,当一层被称为在两层“之间”时,它可以是所述两层之间仅有的层,或者也可以存在一个或多个介于其间的层。For the convenience of description, spatial relation terms such as "below", "below", "below", "below", "above", "on" etc. may be used herein to describe an element or element shown in the drawings. The relationship of a feature to other components or features. It will be understood that these spatially relative terms are intended to encompass other orientations of the device in use or operation in addition to the orientation depicted in the figures. In addition, when a layer is referred to as being "between" two layers, it can be the only layer between the two layers, or one or more intervening layers may also be present.

在本申请的上下文中,所描述的第一特征在第二特征“之上”的结构可以包括第一和第二特征形成为直接接触的实施例,也可以包括另外的特征形成在第一和第二特征之间的实施例,这样第一和第二特征可能不是直接接触。In the context of this application, structures described as having a first feature "on top of" a second feature may include embodiments where the first and second features are formed in direct contact, as well as additional features formed between the first and second features. Embodiments between the second feature such that the first and second features may not be in direct contact.

针对传统GaN器件热管理问题,本发明的实施例提出了一种多沟道鳍式结构及其制备方法。本发明的实施例为了针对高压、大电流的要求,采用多沟道设计,为了提高散热,分别从提高散热效率和改善栅控出发,具体通过设置比多沟道结构具有更大导热率的散热表面将热量从器件内部传导出来、设置具有更大的散热表面从而加快散热以及设置鳍式结构实现。基于上述几种综合手段,如图1所示,为本申请实施例的一种多沟道鳍式结构,该结构包括:Aiming at the thermal management problem of traditional GaN devices, the embodiments of the present invention propose a multi-channel fin structure and a manufacturing method thereof. In order to meet the requirements of high voltage and high current, the embodiment of the present invention adopts a multi-channel design. In order to improve heat dissipation, starting from improving heat dissipation efficiency and improving gate control, specifically by setting a heat dissipation channel with a higher thermal conductivity than the multi-channel structure. The surface conducts heat from the inside of the device, a larger heat dissipation surface is provided to speed up heat dissipation, and a fin structure is provided for realization. Based on the above comprehensive means, as shown in Figure 1, it is a multi-channel fin structure according to the embodiment of the present application, which includes:

衬底;Substrate;

多沟道结构,位于所述衬底之上;a multi-channel structure on the substrate;

源/漏/栅极,位于所述多沟道结构中的底部的沟道层之上;a source/drain/gate located on the bottom channel layer in the multi-channel structure;

所述多沟道结构中位于所述栅极内以及所述栅极和漏极之间具有鳍式结构,所述鳍式结构包括多个鳍,所述每个鳍的深度贯穿所述多沟道结构的顶势垒层至底势垒层;In the multi-channel structure, there is a fin structure located in the gate and between the gate and the drain, the fin structure includes a plurality of fins, and the depth of each fin penetrates the multi-channel from the top barrier layer to the bottom barrier layer of the channel structure;

盖帽层,位于所述源极和栅极之间以及所述栅极和漏极之间的多沟道结构之上以及鳍间,所述盖帽层的导热率高于所述多沟道结构。The capping layer is located on the multi-channel structure between the source and the gate and between the gate and the drain and between the fins, and the thermal conductivity of the capping layer is higher than that of the multi-channel structure.

鳍式结构又称为FinFET结构,在传统晶体管结构中,控制电流通过的闸门,只能在闸门的一侧控制电路的接通与断开,属于平面的架构。在FinFET结构中,闸门成类似鱼鳍的叉状3D架构,可于电路的两侧控制电路的接通与断开。这种设计可以大幅改善电路控制并减少漏电流,也可以大幅缩短晶体管的栅长。The fin structure is also called FinFET structure. In the traditional transistor structure, the gate that controls the flow of current can only control the on and off of the circuit on one side of the gate, which belongs to the planar structure. In the FinFET structure, the gate is formed into a fork-shaped 3D structure similar to a fish fin, which can control the on and off of the circuit on both sides of the circuit. This design can greatly improve circuit control and reduce leakage current, and can also greatly shorten the gate length of the transistor.

本申请实施例利用上述结构的优点并将上述结构应用于高电子迁移率晶体管中。通过设置的上述鳍式结构能够提高对多沟道结构的栅控能力,同时带来更大的散热面积。上述鳍式结构的分布情况,实现了在栅区域采用鳍式结构改善栅控,在漏侧栅边缘采用鳍式结构提高散热,以及在栅源沟道和漏侧更远处沟道采用平面沟道设计降低沟道导通电阻。为进一步提高器件散热能力,集成了具有更高导热率的盖帽层,热量传递到盖帽层后因为导热率更高因此散热更快,同时盖帽层的散热面积较大,也能能够较快散热。The embodiment of the present application utilizes the advantages of the above structure and applies the above structure to a high electron mobility transistor. The provided fin structure can improve the gate control ability of the multi-channel structure, and at the same time bring a larger heat dissipation area. The distribution of the above-mentioned fin structure realizes the use of a fin structure in the gate area to improve gate control, the use of a fin structure at the gate edge of the drain side to improve heat dissipation, and the use of planar trenches in the gate-source channel and the channel farther away from the drain side. The channel design reduces the channel on-resistance. In order to further improve the heat dissipation capability of the device, a cap layer with higher thermal conductivity is integrated. After the heat is transferred to the cap layer, the heat dissipation is faster because of the higher thermal conductivity. At the same time, the cap layer has a larger heat dissipation area and can dissipate heat faster.

在某些实施例中,上述多沟道结构采用多层AlGaN/GaN异质结,具体在如图1所示的实施例中采用的是AlGaN/GaN/AlGaN/GaN双异质结沟道,该结构相比于单沟道器件,能够获得更大的导通电流、更宽的高跨导区从而改善器件线性度,下方沟道电流崩塌现象得到改善。其中,最下方的为第一沟道层,其由缓冲层和沟道层组成,材质为AlGaN,其中缓冲层在下、沟道层在上,且厚度分别为缓冲层4000nm、沟道层400nm。在其他一些实施例中,所述第一沟道层包括成核层、缓冲层和沟道层,其顺序分别从下至上布置,其中缓冲层和沟道层的尺寸与材质均与上述只包括缓冲层和沟道层的实施例相同,所述成核层的尺寸在90nm左右、材质为AlN,能够起到缓解晶格失配的作用。紧邻所述第一沟道层之上的为底势垒层,其材质为GaN,厚度为10nm。紧邻所述底势垒层之上的为第二沟道层,材质为AlGaN,厚度为10nm。紧邻所述第二沟道层之上的为顶势磊层,材质为GaN,厚度为20nm。In some embodiments, the above-mentioned multi-channel structure adopts a multi-layer AlGaN/GaN heterojunction, specifically, in the embodiment shown in FIG. 1, an AlGaN/GaN/AlGaN/GaN double heterojunction channel is used, Compared with a single-channel device, this structure can obtain a larger on-current, a wider high-transconductance region to improve the linearity of the device, and the lower channel current collapse phenomenon is improved. Among them, the bottom one is the first channel layer, which is composed of a buffer layer and a channel layer, and the material is AlGaN, wherein the buffer layer is on the bottom and the channel layer is on the top, and the thickness of the buffer layer is 4000nm, and the channel layer is 400nm. In some other embodiments, the first channel layer includes a nucleation layer, a buffer layer, and a channel layer, which are arranged in sequence from bottom to top, wherein the size and material of the buffer layer and the channel layer are the same as those mentioned above. The embodiment of the buffer layer and the channel layer are the same, the size of the nucleation layer is about 90nm, and the material is AlN, which can play a role in alleviating lattice mismatch. The bottom barrier layer immediately above the first channel layer is made of GaN and has a thickness of 10 nm. Immediately above the bottom barrier layer is a second channel layer made of AlGaN with a thickness of 10 nm. Immediately above the second channel layer is a top epitaxial layer made of GaN with a thickness of 20nm.

基于如图1所示的双异质结沟道一个沟道距离栅极较远,栅控能力较差。FinFET结构可以有效改善双沟道器件栅控能力,实现增强型操作,同时增加器件散热路径,改善器件热管理。Based on the double heterojunction channel shown in Figure 1, one channel is far from the gate, and the gate control capability is poor. The FinFET structure can effectively improve the gate control capability of the dual-channel device, realize enhanced operation, increase the heat dissipation path of the device, and improve the thermal management of the device.

所述鳍式结构的存在,使得所述多沟道结构中在高度方向上每层平面的尺寸不完全相同,如图6所示,其中以最下方的第一沟道层尺寸最大,其尺寸不受鳍式结构的影响。而所述第一沟道层上方依次存在的底势磊层、第二沟道层以及顶势垒层的平面尺寸则小于所述第一沟道层的尺寸,一部分是由于需要让开空间给两侧的源极和漏极,另一方面源极和漏极之间需要留出鳍间空间以形成鳍式结构。同样,所述多沟道结构在长度方向上各个不同截面处的尺寸也不完全相同,如图3~5所示,以及,所述多沟道结构在宽度方向上各个不同截面处的尺寸也不完全相同,如图6和图7所示。上述多种截面变化形成的鳍间空间具有多个侧壁从而增加了散热面积。上述鳍间空间以及鳍式结构之上至各个电极顶端之间的空间内均填充满盖帽层,将热量引导至盖帽层上,进而降低沟道温度,特别是漏侧栅边缘热点温度,并且盖帽层上表面较大,能够快速地将热量引导至器件之外。如图1所示的实施例中,整个器件的宽度为10μm,源极和栅极之间的间距为2μm,栅极和漏极之间的距离为13μm,所述鳍式结构具有3个鳍,每个鳍的宽度为2μm、在源极和栅极之间长度为2.5μm,两两鳍之间具有1个鳍间,合计形成2个鳍间,每个鳍间宽度为1μm、在源极和栅极之间长度为2.5μm。The existence of the fin structure makes the dimensions of each plane in the height direction in the multi-channel structure not completely the same, as shown in FIG. Not affected by the fin structure. The planar dimensions of the bottom epitaxial layer, the second channel layer, and the top barrier layer that exist sequentially above the first channel layer are smaller than the size of the first channel layer, partly due to the need to make room for The source and drain on both sides, on the other hand, need to leave a space between the fins between the source and the drain to form a fin structure. Similarly, the dimensions of the multi-channel structure at different sections in the length direction are not completely the same, as shown in Figures 3-5, and the dimensions of the multi-channel structure at different sections in the width direction are also Not exactly the same, as shown in Figure 6 and Figure 7. The space between the fins formed by the above-mentioned various cross-sectional changes has multiple sidewalls to increase the heat dissipation area. The space between the above-mentioned fins and the space between the top of the fin structure and the top of each electrode are filled with a capping layer, which guides heat to the capping layer, thereby reducing the channel temperature, especially the edge hot spot temperature of the drain side gate, and capping The upper surface of the layer is large to quickly conduct heat away from the device. In the embodiment shown in Figure 1, the width of the entire device is 10 μm, the distance between the source and the gate is 2 μm, and the distance between the gate and the drain is 13 μm, and the fin structure has 3 fins , the width of each fin is 2 μm, the length between the source and the gate is 2.5 μm, there is one inter-fin between two fins, and a total of two fins are formed, and the width between each fin is 1 μm. The length between the electrode and the gate is 2.5 μm.

上述盖帽层的导热率较高,优选金刚石材质。金刚石是自然界导热率最高的材料,一般为138.16W/(m·K)。The thermal conductivity of the above-mentioned capping layer is relatively high, and it is preferably made of diamond. Diamond is the material with the highest thermal conductivity in nature, generally 138.16W/(m·K).

金刚石按所含微量元素可分为Ⅰ型金刚石和Ⅱ型金刚石两个类型。其中,Ⅱ型金刚石具有更好的导热性和半导体性。金刚石材料热导率为2200~3300W/mK,远高于GaN、SiC和Si等材料。本实施例中具体通过GaN/金刚石晶圆或金刚石薄膜钝化层的方式,能够将器件峰值温度降低10%~20%,将器件热阻降低最多30%。Diamond can be divided into two types: type I diamond and type II diamond according to the trace elements contained in it. Among them, type II diamond has better thermal conductivity and semiconductor properties. The thermal conductivity of diamond material is 2200-3300W/mK, much higher than GaN, SiC and Si and other materials. In this embodiment, the peak temperature of the device can be reduced by 10% to 20%, and the thermal resistance of the device can be reduced by at most 30% by means of a GaN/diamond wafer or a diamond film passivation layer.

在某些实施例中,所述盖帽层还位于所述多沟道结构中位于边缘的鳍的外侧。位于边缘的两个鳍的外侧还有一部分空间,每部分空间的宽度为1μm,所述盖帽层将位于外部的空间也填充满,使得整个结构规整,使得多沟道结构在各个位置处均能与盖帽层接触,从而将热量引出。上述结构中各个不同位置处的盖帽层厚度不一,在本实施例中,所述盖帽层的厚度为180nm~250nm,其中在鳍上到器件顶部的厚度为180nm左右,在鳍间的底部以及鳍外侧的底部到器件顶部的厚度为250nm左右。In some embodiments, the capping layer is also located outside the edge-located fins in the multi-channel structure. There is a part of space on the outside of the two fins located at the edge, and the width of each part of the space is 1 μm. The capping layer also fills the space located outside, so that the entire structure is regular, so that the multi-channel structure can be placed at each position. In contact with the capping layer, the heat is drawn away. The thickness of the capping layer at different positions in the above structure is different. In this embodiment, the thickness of the capping layer is 180nm-250nm, wherein the thickness from the top of the fin to the top of the device is about 180nm, the bottom between the fins and The thickness from the bottom of the outside of the fin to the top of the device is around 250nm.

在某些实施例中,上述结构还包括:一介质层,位于所述多沟道结构与所述盖帽层之间,和/或,位于所述多沟道结构与所述栅极之间。在某些实施例中,所述介质层的材质为Al2O3,Al2O3介质层起到三方面的作用,一是在金刚石帽层生长的过程中作半导体材料表面保护层,减小生长过程带来的损伤;二是在金刚石氧等离子体刻蚀可以自停止在Al2O3层,避免过刻蚀损伤沟道;三是作为栅介质层减小栅极漏电。为兼顾栅控能力和表面保护作用,厚度设计为4nm~6nm。In some embodiments, the above structure further includes: a dielectric layer located between the multi-channel structure and the capping layer, and/or located between the multi-channel structure and the gate. In some embodiments, the material of the dielectric layer is Al 2 O 3 , and the Al 2 O 3 dielectric layer plays three roles. One is to serve as a surface protection layer of the semiconductor material during the growth of the diamond cap layer, reducing The damage caused by the small growth process; the second is that the diamond oxygen plasma etching can self-stop on the Al 2 O 3 layer to avoid over-etching damage to the channel; the third is to reduce the gate leakage as a gate dielectric layer. In order to take into account both gate control capability and surface protection, the thickness is designed to be 4nm to 6nm.

在上述实施例中,通过表面的高导热率和大导热面积使得器件内部的热量从上方容易散出,在某些实施例中,还能进一步从器件的下方散热,因此在这些实施例中,所述衬底的导热率高于所述多沟道结构,衬底材料也选择金刚石材质,从而上下配合散热获得更好的散热效果。In the above-mentioned embodiments, the heat inside the device is easily dissipated from above through the high thermal conductivity and large heat-conducting area of the surface. In some embodiments, heat can be further dissipated from the bottom of the device. Therefore, in these embodiments, The thermal conductivity of the substrate is higher than that of the multi-channel structure, and the substrate material is also made of diamond, so that the upper and lower sides cooperate with each other to obtain better heat dissipation effect.

进一步的,给出如图1所示的一种多沟道鳍式结构的制备方法,包括以下步骤:Further, a method for preparing a multi-channel fin structure as shown in Figure 1 is given, including the following steps:

步骤S101、准备第一衬底。Step S101, preparing a first substrate.

硅是常见的衬底材料,除了硅以外,还可以是氮化镓、碳化硅等材质,本实施例中第一衬底为硅衬底,且厚度为1000μm。Silicon is a common substrate material. In addition to silicon, it can also be made of gallium nitride, silicon carbide and other materials. In this embodiment, the first substrate is a silicon substrate with a thickness of 1000 μm.

步骤S102、形成多沟道结构于所述第一衬底之上。Step S102, forming a multi-channel structure on the first substrate.

如图8所示,在第一衬底之上依次生长4μm GaN缓冲层/400nm GaN沟道层/10nmAl0.15Ga0.84N底势垒层/10nm GaN沟道层/20nm Al0.3Ga0.7N势垒层形成双异质结沟道。As shown in Figure 8, 4μm GaN buffer layer/400nm GaN channel layer/10nmAl 0.15 Ga 0.84 N bottom barrier layer/10nm GaN channel layer/20nm Al 0.3 Ga 0.7 N barrier layer are grown sequentially on the first substrate layers form a double heterojunction channel.

步骤S103、研磨和刻蚀所述第一衬底,具体通过在晶圆正面贴片,然后研磨去除Si衬底,撕片。如图9所示,并在所述多沟道结构下方表面键合第二衬底,如图10所示。本实施例中所述第二衬底选择散热效果更好的金刚石材料。Step S103 , grinding and etching the first substrate, specifically by attaching a wafer on the front side of the wafer, then grinding to remove the Si substrate, and tearing the wafer. As shown in FIG. 9 , a second substrate is surface-bonded under the multi-channel structure, as shown in FIG. 10 . The diamond material with better heat dissipation effect is selected for the second substrate in this embodiment.

制备Fin结构,包括步骤S104~S107。Prepare the Fin structure, including steps S104-S107.

步骤S104、如图11所示,采用等离子体增强化学气相淀积的方式在所述多沟道结构上生长50~70nm厚度的SiO2掩膜层并采用反应离子刻蚀技术形成凹槽作为Fin之间凹槽,所述SiO2掩膜层位于栅极区域以及栅极和漏极区域之间,且所述SiO2掩膜层成鳍式分布。Step S104, as shown in FIG. 11, grow a SiO2 mask layer with a thickness of 50-70 nm on the multi-channel structure by means of plasma-enhanced chemical vapor deposition, and use reactive ion etching technology to form grooves as Fin The SiO 2 mask layer is located between the gate region and the gate and drain regions, and the SiO 2 mask layer is distributed in a fin shape.

步骤S105、如图12所示,采用Cl基等离子体干法刻蚀,将Fin之间凹槽区域刻蚀至最后一层AlGaN势垒层剩余,实际制备过程中,如图所示,刻蚀掉最后一层AlGaN势垒层的上部分一定厚度并保留该层下部分一定厚度,即沿所述SiO2掩膜层的每个鳍刻蚀其下方的多沟道结构直至底势垒层。Step S105, as shown in Figure 12, using Cl-based plasma dry etching to etch the groove area between the Fins until the last AlGaN barrier layer remains. In the actual preparation process, as shown in the figure, the etching Remove a certain thickness of the upper part of the last AlGaN barrier layer and retain a certain thickness of the lower part of the layer, that is, etch the multi-channel structure below it along each fin of the SiO2 mask layer until the bottom barrier layer.

步骤S106、如图13所示,将外延片放置于620~680℃的氧氛围中100~120分钟,高温氧化所述底势垒层,此条件下AlGaN层下方GaN层不会被氧化;然后湿法腐蚀所述底势垒层并自停止于底部的沟道层表面,使得所述多沟道结构形成鳍式结构;具体通过将氧化后的外延片放置于70~90℃的TMAH或KOH溶液中腐蚀100~120分钟,凹槽区域被腐蚀,自停止于下方GaN层;氧化湿法腐蚀工艺可以避免干法刻蚀对GaN沟道层的过刻蚀,减小对沟道损伤,至此完成Fin结构的制备。Step S106 , as shown in FIG. 13 , place the epitaxial wafer in an oxygen atmosphere at 620-680° C. for 100-120 minutes, and oxidize the bottom barrier layer at a high temperature. Under this condition, the GaN layer below the AlGaN layer will not be oxidized; then Wet etching the bottom barrier layer and self-stopping on the surface of the channel layer at the bottom, so that the multi-channel structure forms a fin structure; specifically, by placing the oxidized epitaxial wafer in TMAH or KOH at 70-90°C Etching in the solution for 100 to 120 minutes, the groove area is etched and stops at the lower GaN layer; the oxidation wet etching process can avoid over-etching of the GaN channel layer by dry etching and reduce damage to the channel. Complete the preparation of the Fin structure.

步骤S107、如图14所示,采用BOE腐蚀去除所述SiO2掩膜层。Step S107 , as shown in FIG. 14 , remove the SiO 2 mask layer by BOE etching.

步骤S108、如图15所示,形成完全覆盖在所有沟道结构表面的介质层,并刻蚀去除源漏区域的介质层。具体通过ALD淀积厚度约为5nm的Al2O3介质层。Al2O3介质层在AlGaN表面可以在后续的盖帽层材料金刚石生长过程中起到保护作用,在金刚石的刻蚀过程中起到自停止作用,栅下可以形成MIS结构减小栅极漏电。Step S108 , as shown in FIG. 15 , forming a dielectric layer completely covering the surface of all channel structures, and etching to remove the dielectric layer in the source and drain regions. Specifically, an Al 2 O 3 dielectric layer with a thickness of about 5 nm is deposited by ALD. The Al 2 O 3 dielectric layer on the surface of AlGaN can play a protective role in the subsequent growth of the cap layer material diamond, and play a self-stop role in the etching process of diamond, and a MIS structure can be formed under the gate to reduce gate leakage.

步骤S109、如图16所示,形成完全覆盖在所述介质层表面的盖帽层;具体采用微波等离子体化学气相沉积(MPCVD)生长约300nm厚度的多晶金刚石帽层。金刚石热导率远高于GaN层,在器件顶部提供了有效的散热通道,能够有效降低沟道温度。Step S109 , as shown in FIG. 16 , forming a capping layer completely covering the surface of the dielectric layer; specifically, a polycrystalline diamond capping layer with a thickness of about 300 nm is grown by microwave plasma chemical vapor deposition (MPCVD). The thermal conductivity of diamond is much higher than that of the GaN layer, providing an effective heat dissipation channel on the top of the device, which can effectively reduce the channel temperature.

步骤S110、如图17所示,在所述盖帽层上位于源漏区域之间的位置生长Al2O3掩膜层并采用BOE腐蚀形成图案。Step S110 , as shown in FIG. 17 , grow an Al 2 O 3 mask layer on the capping layer between the source and drain regions and form a pattern by BOE etching.

步骤S111、如图18所示,采用ICP氧等离子体刻蚀刻蚀所述源漏区域位置处的盖帽层并自停止于所述Al2O3介质层表面。Step S111 , as shown in FIG. 18 , using ICP oxygen plasma etching to etch the cap layer at the position of the source and drain regions and self-stop on the surface of the Al 2 O 3 dielectric layer.

采用ICP氧离子干法刻蚀金刚石,采用Al2O3作掩膜层,可以获得较高的刻蚀比。同时在AlGaN表面引入Al2O3介质保护层,该层同时起到三个作用:①在栅下区域作为栅介质,减小漏电;②在金刚石生长过程中起到表面保护作用;③在刻蚀金刚石过程中起到自停止作用,防止过刻蚀。Using ICP oxygen ion dry etching of diamond, using Al 2 O 3 as a mask layer, can obtain a higher etching ratio. At the same time, an Al 2 O 3 dielectric protection layer is introduced on the surface of AlGaN, which plays three functions at the same time: ① it acts as a gate dielectric in the area under the gate to reduce leakage; ② it plays a role of surface protection during the diamond growth process; It plays a self-stop function during the diamond etching process to prevent over-etching.

步骤S112、如图19所示,形成在源漏区域的源/漏极并实现欧姆接触,具体通过电子束蒸发生长Ti/Al/Ni/Au金属叠层,剥离后在欧姆接触的位置留下金属叠层,紧接着在快速退火形成欧姆接触。Step S112, as shown in Figure 19, form the source/drain electrodes in the source and drain regions and realize the ohmic contact, specifically grow the Ti/Al/Ni/Au metal stack by electron beam evaporation, and leave at the ohmic contact position after stripping The metal stack is followed by rapid annealing to form ohmic contacts.

制备栅极,包括步骤S113~S115。Preparing the grid includes steps S113-S115.

步骤S113、如图20所示,光刻,BOE腐蚀Al2O3,形成在栅区域的Al2O3掩膜层凹槽;Step S113, as shown in FIG. 20 , photolithography, BOE etching of Al2O3, forming grooves in the Al2O3 mask layer in the gate region;

步骤S114、如图21所示,ICP氧等离子体刻蚀所述Al2O3掩膜层凹槽正下方的盖帽层并自停止于所述介质层表面;Step S114, as shown in FIG. 21, ICP oxygen plasma etches the cap layer directly below the groove of the Al 2 O 3 mask layer and self-stops on the surface of the dielectric layer;

步骤S115、如图22所示,电子束蒸发淀积金属叠层Ni/Au,剥离后留下栅极金属,形成在栅区的介质层之上的栅极;Step S115, as shown in FIG. 22, electron beam evaporation deposits the metal stack Ni/Au, leaves the gate metal after stripping, and forms the gate on the dielectric layer of the gate region;

步骤S116、BOE腐蚀高于源/漏/栅极位置的Al2O3掩膜层。Step S116, BOE etching the Al 2 O 3 mask layer higher than the source/drain/gate position.

上述实施例的工艺,使得器件上下均为散热效果好的材料,并且采用湿法腐蚀工艺保证了沟道完整性。The process of the above embodiment makes the top and bottom of the device are materials with good heat dissipation effect, and the wet etching process is used to ensure the integrity of the channel.

以上仅为本申请的实施例而已,并不用于限制本申请。对于本领域技术人员来说,本申请可以有各种更改和变化。凡在本申请的精神和原理之内所作的任何修改、等同替换、改进等,均应包含在本申请的权利要求范围之内。The above are only examples of the present application, and are not intended to limit the present application. For those skilled in the art, various modifications and changes may occur in this application. Any modification, equivalent replacement, improvement, etc. made within the spirit and principle of the present application shall be included within the scope of the claims of the present application.

Claims (10)

1. A multi-channel fin structure, comprising:
a substrate;
a multi-channel structure located over the substrate;
a source/drain/gate located on the bottom channel layer in the multi-channel structure;
a fin structure in the multi-channel structure within the gate and between the gate and the drain, the fin structure comprising a plurality of fins each having a depth that penetrates a top barrier layer to a bottom barrier layer of the multi-channel structure;
the cap layer is positioned above the multi-channel structure between the source electrode and the grid electrode and between the grid electrode and the drain electrode and between the fins;
the substrate and the cap layer have higher thermal conductivity than the multi-channel structure.
2. The structure of claim 1 wherein the cap layer is further located outside the marginally located fin in the multi-channel structure.
3. The structure of claim 1 or 2, further comprising:
a dielectric layer, a first dielectric layer and a second dielectric layer,
between the multi-channel structure and the cap layer,
and/or the presence of a gas in the gas,
located between the multi-channel structure and the gate.
4. The structure of claim 3, wherein the cap layer is made of diamond.
5. The structure of claim 4 wherein the cap layer has a thickness of 180nm to 250nm.
6. The structure of claim 3, wherein the dielectric layer is made of Al 2 O 3
7. The structure of claim 6, wherein the dielectric layer has a thickness of 4nm to 6nm.
8. The structure of claim 3, wherein the multi-channel structure comprises a multilayer AlGaN/GaN heterojunction.
9. A structure according to any one of claims 4 to 6, wherein the substrate is diamond.
10. The preparation method of the multi-channel fin structure is characterized by comprising the following steps:
preparing a Si substrate;
forming a multi-channel structure on the Si substrate;
grinding and etching the Si substrate and bonding an alloy diamond substrate below the multi-channel structure;
growing SiO on the multi-channel structure 2 Masking film layer and etching to form a groove, wherein the SiO is 2 A mask layer arranged between the gate region and the gate and drain regions and made of SiO 2 The mask layer is distributed in a fin mode;
along the SiO 2 Etching a multi-channel structure below each fin of the mask layer until reaching the bottom barrier layer;
oxidizing the bottom barrier layer at high temperature, and then etching the bottom barrier layer by a wet method and stopping on the surface of the channel layer at the bottom, so that the multi-channel structure forms a fin structure;
removing the SiO 2 A mask layer;
forming a dielectric layer which completely covers the surfaces of all the channel structures, and etching to remove the dielectric layer in the source drain region;
forming a cap layer completely covering the surface of the dielectric layer;
growing Al on the cap layer at the position between the source and drain regions 2 O 3 The mask layer is etched to form a pattern;
etching the cap layer at the position of the source-drain region and stopping on the surface of the dielectric layer;
forming a source/drain electrode in the source/drain region and realizing ohmic contact;
al formed in gate region 2 O 3 A mask layer groove;
etching the Al 2 O 3 The cover cap layer is arranged right below the mask layer groove and stops on the surface of the medium layer;
a gate formed over the dielectric layer of the gate region;
etching Al higher than source/drain/gate 2 O 3 And (5) masking the layer.
CN202211229937.7A 2022-10-08 2022-10-08 Multi-channel fin structure and its preparation method Pending CN115579391A (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN118016689A (en) * 2024-01-15 2024-05-10 湖北九峰山实验室 GaN multi-channel structure without channel coupling effect and GaN HEMT device

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN118016689A (en) * 2024-01-15 2024-05-10 湖北九峰山实验室 GaN multi-channel structure without channel coupling effect and GaN HEMT device

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