CN114602878A - Online cleaning system of evaporative crystallization device - Google Patents
Online cleaning system of evaporative crystallization device Download PDFInfo
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- CN114602878A CN114602878A CN202210342976.1A CN202210342976A CN114602878A CN 114602878 A CN114602878 A CN 114602878A CN 202210342976 A CN202210342976 A CN 202210342976A CN 114602878 A CN114602878 A CN 114602878A
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- evaporative crystallization
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- 238000004140 cleaning Methods 0.000 title claims abstract description 204
- 238000002425 crystallisation Methods 0.000 title claims abstract description 99
- 230000008025 crystallization Effects 0.000 title claims abstract description 99
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 135
- 239000007788 liquid Substances 0.000 claims abstract description 61
- 238000001704 evaporation Methods 0.000 claims abstract description 35
- 230000008020 evaporation Effects 0.000 claims abstract description 34
- 230000009471 action Effects 0.000 claims abstract description 6
- 239000012459 cleaning agent Substances 0.000 claims description 34
- 238000001514 detection method Methods 0.000 claims description 25
- 239000006096 absorbing agent Substances 0.000 claims description 12
- 238000009833 condensation Methods 0.000 claims description 12
- 230000005494 condensation Effects 0.000 claims description 12
- 239000002253 acid Substances 0.000 claims description 7
- 239000000428 dust Substances 0.000 claims description 6
- 239000003595 mist Substances 0.000 claims description 6
- 238000004321 preservation Methods 0.000 claims description 6
- 238000001914 filtration Methods 0.000 claims description 3
- 238000000034 method Methods 0.000 description 19
- 230000008569 process Effects 0.000 description 17
- OSGAYBCDTDRGGQ-UHFFFAOYSA-L calcium sulfate Chemical compound [Ca+2].[O-]S([O-])(=O)=O OSGAYBCDTDRGGQ-UHFFFAOYSA-L 0.000 description 9
- 238000013461 design Methods 0.000 description 8
- 239000000463 material Substances 0.000 description 8
- 238000005406 washing Methods 0.000 description 8
- 238000010438 heat treatment Methods 0.000 description 7
- 238000012546 transfer Methods 0.000 description 7
- 238000004519 manufacturing process Methods 0.000 description 6
- 230000000694 effects Effects 0.000 description 5
- 238000009434 installation Methods 0.000 description 5
- 238000011084 recovery Methods 0.000 description 5
- 150000003839 salts Chemical class 0.000 description 5
- XAEFZNCEHLXOMS-UHFFFAOYSA-M potassium benzoate Chemical compound [K+].[O-]C(=O)C1=CC=CC=C1 XAEFZNCEHLXOMS-UHFFFAOYSA-M 0.000 description 4
- 238000002360 preparation method Methods 0.000 description 4
- 238000004064 recycling Methods 0.000 description 4
- 159000000000 sodium salts Chemical class 0.000 description 4
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- 230000002378 acidificating effect Effects 0.000 description 3
- ZFXVRMSLJDYJCH-UHFFFAOYSA-N calcium magnesium Chemical compound [Mg].[Ca] ZFXVRMSLJDYJCH-UHFFFAOYSA-N 0.000 description 3
- 229910052500 inorganic mineral Inorganic materials 0.000 description 3
- 239000011707 mineral Substances 0.000 description 3
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 2
- KCXVZYZYPLLWCC-UHFFFAOYSA-N EDTA Chemical compound OC(=O)CN(CC(O)=O)CCN(CC(O)=O)CC(O)=O KCXVZYZYPLLWCC-UHFFFAOYSA-N 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 2
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 2
- 239000011575 calcium Substances 0.000 description 2
- 230000008859 change Effects 0.000 description 2
- 239000008367 deionised water Substances 0.000 description 2
- 229910021641 deionized water Inorganic materials 0.000 description 2
- 230000002349 favourable effect Effects 0.000 description 2
- 238000011086 high cleaning Methods 0.000 description 2
- 238000009413 insulation Methods 0.000 description 2
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- 238000012986 modification Methods 0.000 description 2
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- 239000007787 solid Substances 0.000 description 2
- 230000003068 static effect Effects 0.000 description 2
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
- 229910000975 Carbon steel Inorganic materials 0.000 description 1
- 239000004696 Poly ether ether ketone Substances 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- 239000004734 Polyphenylene sulfide Substances 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 238000013459 approach Methods 0.000 description 1
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- 230000009286 beneficial effect Effects 0.000 description 1
- JUPQTSLXMOCDHR-UHFFFAOYSA-N benzene-1,4-diol;bis(4-fluorophenyl)methanone Chemical compound OC1=CC=C(O)C=C1.C1=CC(F)=CC=C1C(=O)C1=CC=C(F)C=C1 JUPQTSLXMOCDHR-UHFFFAOYSA-N 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- 229910000019 calcium carbonate Inorganic materials 0.000 description 1
- 238000009924 canning Methods 0.000 description 1
- 239000010962 carbon steel Substances 0.000 description 1
- 239000000919 ceramic Substances 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 238000007599 discharging Methods 0.000 description 1
- 239000003814 drug Substances 0.000 description 1
- 229960001484 edetic acid Drugs 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
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- JEGUKCSWCFPDGT-UHFFFAOYSA-N h2o hydrate Chemical compound O.O JEGUKCSWCFPDGT-UHFFFAOYSA-N 0.000 description 1
- 229920001903 high density polyethylene Polymers 0.000 description 1
- 239000004700 high-density polyethylene Substances 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 238000011068 loading method Methods 0.000 description 1
- 239000012528 membrane Substances 0.000 description 1
- 238000005374 membrane filtration Methods 0.000 description 1
- 239000007769 metal material Substances 0.000 description 1
- 229910052755 nonmetal Inorganic materials 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 238000005554 pickling Methods 0.000 description 1
- 229920002530 polyetherether ketone Polymers 0.000 description 1
- 229920000069 polyphenylene sulfide Polymers 0.000 description 1
- 239000004810 polytetrafluoroethylene Substances 0.000 description 1
- 229920001343 polytetrafluoroethylene Polymers 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 238000004092 self-diagnosis Methods 0.000 description 1
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- 229910000029 sodium carbonate Inorganic materials 0.000 description 1
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- 229910001220 stainless steel Inorganic materials 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000002918 waste heat Substances 0.000 description 1
Images
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B08—CLEANING
- B08B—CLEANING IN GENERAL; PREVENTION OF FOULING IN GENERAL
- B08B3/00—Cleaning by methods involving the use or presence of liquid or steam
- B08B3/04—Cleaning involving contact with liquid
- B08B3/08—Cleaning involving contact with liquid the liquid having chemical or dissolving effect
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D1/00—Evaporating
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D9/00—Crystallisation
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B08—CLEANING
- B08B—CLEANING IN GENERAL; PREVENTION OF FOULING IN GENERAL
- B08B1/00—Cleaning by methods involving the use of tools
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B08—CLEANING
- B08B—CLEANING IN GENERAL; PREVENTION OF FOULING IN GENERAL
- B08B1/00—Cleaning by methods involving the use of tools
- B08B1/10—Cleaning by methods involving the use of tools characterised by the type of cleaning tool
- B08B1/12—Brushes
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B08—CLEANING
- B08B—CLEANING IN GENERAL; PREVENTION OF FOULING IN GENERAL
- B08B3/00—Cleaning by methods involving the use or presence of liquid or steam
- B08B3/04—Cleaning involving contact with liquid
- B08B3/10—Cleaning involving contact with liquid with additional treatment of the liquid or of the object being cleaned, e.g. by heat, by electricity or by vibration
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B08—CLEANING
- B08B—CLEANING IN GENERAL; PREVENTION OF FOULING IN GENERAL
- B08B9/00—Cleaning hollow articles by methods or apparatus specially adapted thereto
- B08B9/02—Cleaning pipes or tubes or systems of pipes or tubes
- B08B9/027—Cleaning the internal surfaces; Removal of blockages
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B08—CLEANING
- B08B—CLEANING IN GENERAL; PREVENTION OF FOULING IN GENERAL
- B08B9/00—Cleaning hollow articles by methods or apparatus specially adapted thereto
- B08B9/08—Cleaning containers, e.g. tanks
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B08—CLEANING
- B08B—CLEANING IN GENERAL; PREVENTION OF FOULING IN GENERAL
- B08B9/00—Cleaning hollow articles by methods or apparatus specially adapted thereto
- B08B9/08—Cleaning containers, e.g. tanks
- B08B9/087—Cleaning containers, e.g. tanks by methods involving the use of tools, e.g. brushes, scrapers
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B08—CLEANING
- B08B—CLEANING IN GENERAL; PREVENTION OF FOULING IN GENERAL
- B08B2209/00—Details of machines or methods for cleaning hollow articles
- B08B2209/02—Details of apparatuses or methods for cleaning pipes or tubes
- B08B2209/027—Details of apparatuses or methods for cleaning pipes or tubes for cleaning the internal surfaces
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Crystallography & Structural Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Cleaning By Liquid Or Steam (AREA)
- Cleaning In General (AREA)
Abstract
The application discloses evaporation crystallization device online cleaning system includes: the device comprises an evaporation crystallization unit, at least one cleaning unit, a heat exchange unit and a hot water unit; the heat exchange unit is used for preheating liquid entering the hot water unit; the hot water unit comprises a hot water tank and a hot water pump, and the hot water pump is used for conveying liquid in the hot water tank to the evaporative crystallization unit and/or the cleaning unit; the cleaning unit comprises a cleaning tank and a circulating pump, the circulating pump is used for conveying liquid in the cleaning tank to the evaporative crystallization unit and/or the heat exchange unit, the liquid conveyed to the evaporative crystallization unit is suitable for being conveyed back to the cleaning tank after being cleaned, and the liquid conveyed to the heat exchange unit is suitable for entering the hot water tank and being conveyed back to the cleaning tank under the action of the hot water pump.
Description
Technical Field
The application relates to the technical field of evaporative crystallization, in particular to an online cleaning system of an evaporative crystallization device.
Background
The evaporative crystallization device is widely applied to the industries of chemical industry, food, light industry, pharmacy, environmental protection, energy, new materials and the like at present. Calcium-magnesium scale and salt scale are frequently formed in the operation process of the evaporation crystallization device, the evaporation crystallization device needs to be shut down periodically and the evaporation device needs to be cleaned manually, and a series of cleaning problems such as high cleaning frequency, high cleaning difficulty, incomplete cleaning and the like always troubles the whole evaporation industry. The main reasons for the generation of calcium-magnesium scale and salt scale in the evaporative crystallization device are as follows:
firstly, the water contains Ca due to the different conditions of the materials in the water2+、Mg2+Isocation and SO4 2-、CO3 2-And calcium carbonate, calcium sulfate salt and the like which are composed of the ions can be supersaturated due to the change of concentration and temperature to be crystallized and separated out, and generate scale solids on the half piece of the plate heat exchanger, in the circulating pipeline, in the heating pipe of the heat exchanger and on the inner wall of the crystallizer or the separator, so that the heat exchange efficiency is influenced slightly, the plate fins and the heat exchange pipe are blocked seriously, and the normal operation of the evaporative crystallization device is seriously influenced. Wherein the solubility of calcium sulfate is not large, and the solubility is specially increased and then decreased, for example, the solubility is 0.1928g/(100g H) at 10 DEG C2O), the solubility is reduced to 0.1619g/(100g H) at 100 DEG C2O) when the temperature is more than or equal to 40 ℃, the temperature is changed along with the temperatureThe solubility of the calcium sulfate is increased to show a descending trend, and the change of the solubility ensures that the concentration of the calcium sulfate is easy to approach saturation when the material water in the heat exchange tube of the heater is heated in the circulating evaporation process, and the calcium sulfate is easy to crystallize and separate out at the wall surface to generate calcium scale.
Secondly, when the operation control is improper or the instrument is in fault during the evaporation process during production, the phenomena of false liquid level and low liquid level appear in the crystallizer or the separator, when heating steam (raw steam or MVR secondary steam) is still conveyed according to the steam supply amount during normal evaporation, the static liquid level pressure at the outlet of the heating pipe is very easy to cause, the material subjected to heat exchange by the heat exchange pipe is originally boiled above the liquid level of the outlet of the heating pipe, and the material is boiled in the heating pipe due to the insufficient static liquid level pressure, so that salt is inevitably crystallized and separated out, and salt scale and calcium magnesium scale are formed by the attachment of the heating inner wall.
Conventional equipment washs and all need adopt special belt cleaning device to carry out certain part or device and wash alone in present trade, and need equipment to park the cooling when wasing, and the parking time is longer, and corresponding pipeline need be connected to cleaning equipment or device, prepares to wash the medicament, and the recovery work after preparing and wasing finishing before whole washing is more loaded down with trivial details and time-consuming, can not arrange alone after the washing liquid that the cleaning process used has been washed, need carry out independent processing or discharge to corresponding sewage treatment plant. In the industry, some online cleaning equipment mainly adopts a cleaning ball or cleaning brush structure, the structural design of the equipment is complex, a single ball chamber or cleaning brush chamber needs to be arranged, the design, manufacture, installation and debugging difficulty is increased, and in the whole cleaning process, the cleaning ball and the cleaning brush are likely to be damaged and enter the subsequent pipelines, valves and equipment, so that the blockage of partial valves, pipelines and equipment is caused, and the safety of the material carrying operation of the device is influenced.
Disclosure of Invention
An object of the present application is to provide an online cleaning system for an evaporative crystallization device, which can perform online cleaning on the evaporative crystallization device without shutdown.
Another object of the present invention is to provide an online cleaning system for an evaporative crystallization apparatus, which can perform online cleaning on each of a plurality of working units of the evaporative crystallization apparatus.
Another aim at of this application provides an evaporation crystallization device online cleaning system, can reuse the cleaner wash different work units, is favorable to using water wisely.
Another object of this application is to provide an evaporation crystallization device online cleaning system, the cleaning process is simple, and the cleaning efficiency is high.
In order to achieve the above object, the present application provides an online cleaning system for an evaporative crystallization apparatus, comprising: the device comprises an evaporation crystallization unit, at least one cleaning unit, a heat exchange unit and a hot water unit; the heat exchange unit is used for preheating liquid entering the hot water unit; the hot water unit comprises a hot water tank and a hot water pump, and the hot water pump is used for conveying liquid in the hot water tank to the evaporative crystallization unit and/or the cleaning unit; the cleaning unit comprises a cleaning tank and a circulating pump, the circulating pump is used for conveying liquid in the cleaning tank to the evaporative crystallization unit and/or the heat exchange unit, the liquid conveyed to the evaporative crystallization unit is suitable for being conveyed back to the cleaning tank after being cleaned, and the liquid conveyed to the heat exchange unit is suitable for entering the hot water tank and being conveyed back to the cleaning tank under the action of the hot water pump.
Furthermore, the online cleaning system for the evaporative crystallization device comprises two sets of cleaning units, and the two cleaning units are used for circulating different cleaning agents.
Further, the cleaning unit is provided with a quick interface for inputting cleaning agents, and the quick interface is suitable for being connected with a conveying pipe of a cleaning agent canning vehicle or other cleaning agent discharging tanks.
Further, at least one cleaning unit also comprises a first absorber which is arranged on the cleaning tank and used for absorbing acid mist or dust.
Further, online cleaning system of evaporation crystallization device still includes the buffer memory unit, the buffer memory unit includes the buffer memory jar, thereby the buffer memory jar be suitable for with the accessible of washing jar intercommunication the circulating pump will wash the liquid in the jar and carry to the buffer memory jar, the buffer memory jar still be suitable for with evaporation crystallization unit intercommunication, thereby wash the completion the cleaner of evaporation crystallization unit can flow back to the buffer memory jar.
Further, the buffer unit further comprises a second absorber arranged on the buffer tank, and the second absorber is used for absorbing acid mist or dust in the buffer tank.
Further, the heat exchange unit comprises a heat exchanger and a filter, the filter is used for filtering liquid preheated by the heat exchanger, and the heat exchanger is connected with the hot water tank, so that the liquid preheated by the heat exchanger is suitable for entering the hot water tank.
Further, the heat exchange unit further comprises a condensing tank and a condensing pump, the condensing tank is used for collecting condensed water, and the condensing pump is used for conveying the condensed water in the condensing tank to the hot water tank.
Furthermore, a shell of the hot water tank is provided with a heat preservation coil pipe, the heat preservation coil pipe is provided with a steam inlet and a condensate outlet, and the condensate outlet is communicated with the condensing tank.
Furthermore, a first temperature detection device is arranged at a liquid outlet of the heat exchanger, so that the amount of steam entering the heat exchanger is adjusted according to the detection result of the first temperature detection device, and a first pressure detection device and a second pressure detection device are respectively arranged at a water inlet end and a water outlet end of the heat exchanger, so that whether the heat exchanger needs to be cleaned is judged according to the detection results of the first pressure detection device and the second pressure detection device.
Compared with the prior art, the beneficial effect of this application lies in:
(1) most cleaning devices in the prior art can only perform partial cleaning on single parts or units, and the online cleaning system of the evaporative crystallization device can perform online cleaning on a complete set of evaporative crystallization devices;
(2) in the prior art, most of cleaning devices cannot clean water again after cleaning once, and other parts or units can be cleaned only by replacing the original cleaning liquid again after the original cleaning liquid is discharged outside;
(3) most cleaning devices in the prior art can be cleaned only after equipment or parts are stopped, so that production discontinuity is caused, and production efficiency and the whole process are greatly influenced;
(4) most of cleaning devices in the prior art need more cleaning preparation work before cleaning, need to be equipped with certain machines, need to carry on work such as recovery installation and leak detection after cleaning too, the process is tedious, last for a long time, and the evaporation crystallization device online cleaning system of this application is before cleaning and after the relevant preparation and recovery work is less, save the manpower, reduce and wash preparation and recovery time;
(5) most of cleaning devices in the prior art need to be provided with unique cleaning equipment and corresponding exclusive cleaning devices aiming at different parts and parts, and the universality is not high, and the online cleaning system of the evaporative crystallization device has simple flow equipment and high universality;
(6) in the prior art, a part of cleaning devices need unique cleaning small parts such as cleaning balls and cleaning brushes, and need to design an independent ball chamber or brush chamber, so that corresponding design, manufacturing, installation and operation costs are increased.
Drawings
FIG. 1 is a schematic view of one embodiment of an in-line cleaning system for an evaporative crystallization apparatus of the present application;
FIG. 2 is a schematic view of one embodiment of an evaporative crystallization unit of the present application;
FIG. 3 is a schematic view of an embodiment of a first cleaning unit of the present application;
FIG. 4 is a schematic view of an embodiment of a second cleaning unit of the present application;
FIG. 5 is a schematic view of an embodiment of a heat exchange unit of the present application;
FIG. 6 is a schematic view of an embodiment of a hot water unit of the present application;
FIG. 7 is a diagram illustrating an embodiment of a cache unit of the present application;
in the figure:
100. an evaporative crystallization unit; 101. evaporating sodium salt for 1 effect; 102. sodium salt is evaporated for 2 effects; 103. potassium salt is evaporated for 1 effect; 104. potassium salt is evaporated for 2 effects;
200(A/B), a cleaning unit; 201(A/B), a cleaning tank; 202(A/B), circulation pump; 203. a first absorber;
300. a heat exchange unit; 301. a heat exchanger; 302. a filter; 303. a condensing tank; 304. a condensate pump;
400. a hot water unit; 401. a hot water tank; 402. a hot water pump; 403. a heat preservation coil pipe;
500. a cache unit; 501. a buffer tank; 502. a cache pump; 503. and a second absorber.
Detailed Description
The present application is further described below with reference to specific embodiments, and it should be noted that, without conflict, any combination between the embodiments or technical features described below may form a new embodiment.
It is noted that the terms first, second and the like in the description and in the claims of the present application are used for distinguishing between similar elements and not necessarily for describing a particular sequential or chronological order.
The terms "comprises," "comprising," and "having," and any variations thereof, in the description and claims of this application, are intended to cover a non-exclusive inclusion, such that a process, method, system, article, or apparatus that comprises a list of steps or elements is not necessarily limited to those steps or elements expressly listed, but may include other steps or elements not expressly listed or inherent to such process, method, article, or apparatus.
As shown in fig. 1 to 7, the present application provides an online cleaning system for an evaporative crystallization device, which comprises an evaporative crystallization unit 100, at least one cleaning unit 200, a heat exchange unit 300, and a hot water unit 400.
The heat exchange unit 300 is used for preheating the liquid entering the hot water unit 400; the hot water unit 400 comprises a hot water tank 401 and a hot water pump 402, wherein the hot water pump 402 is used for conveying liquid in the hot water tank 401 to the evaporative crystallization unit 100 and/or the cleaning unit 200; the cleaning unit 200 comprises a cleaning tank 201 and a circulating pump 202, wherein the circulating pump 202 is used for conveying the liquid in the cleaning tank 201 to the evaporative crystallization unit 100 and/or the heat exchange unit 300, the liquid conveyed to the evaporative crystallization unit 100 is suitable for being conveyed back to the cleaning tank 201 after being cleaned, and the liquid conveyed to the heat exchange unit 300 is suitable for entering a hot water tank 401 and being conveyed back to the cleaning tank 201 under the action of a hot water pump 402.
The cleaning unit 200 of this application can wash evaporative crystallization unit 100 alone, and at this moment, will wash the cleaner in the jar 201 through circulating pump 202 and carry to evaporative crystallization unit 100, and the cleaner flows back to in the cleaning tank 201 after wasing evaporative crystallization unit 100, utilizes circulating pump 202 can make the cleaner constantly circulate between evaporative crystallization unit 100 and cleaning tank 201. The cleaning agent can be circularly cleaned for many times in the whole cleaning process, and the using amount of the cleaning agent is saved.
The cleaning unit 200 of this application can also wash heat transfer unit 300 and hot water unit 400 alone, at this moment, carry to heat transfer unit 300 through the cleaner that circulating pump 202 will wash in the jar 201, the cleaner enters hot-water tank 401 after wasing heat transfer unit 300, then utilize the cleaner of hot-water pump 402 in with hot-water tank 401 to carry back washing jar 201, utilize circulating pump 202 and hot-water pump 402 to make the cleaner constantly at heat transfer unit 300, hot-water tank 401 and wash jar 201 between the circulation, when reducing the cleaner quantity, the cleaning performance has been improved.
The cleaning unit 200 of this application can also wash evaporation crystallization unit 100, heat transfer unit 300 and hot water unit 400 simultaneously, at this moment, utilize circulating pump 202 to carry the cleaner to evaporation crystallization unit 100 and heat transfer unit 300 simultaneously, the cleaner that has washd evaporation crystallization unit 100 flows back to cleaning tank 201, and after the cleaner that carries to heat transfer unit 300 got into hot-water tank 401, defeated again through hot-water pump 402 and wash tank 201.
The cleaning unit 200 of the present application may also clean the evaporative crystallization unit 100, the heat exchange unit 300, and the hot water unit 400 in a suitable order. For example, the cleaning agent in the cleaning tank 201 may be first conveyed to the heat exchange unit 300, then the cleaning agent enters the hot water tank 401, then the hot water pump 401 is used to convey the cleaning agent to the evaporative crystallization unit 100, and the cleaning agent flows back to the cleaning tank 201 after the evaporative crystallization unit 100 is cleaned.
The application can also utilize the hot water unit 400 to wash the evaporative crystallization unit 100, that is, input water to the heat exchange unit 300, the water is heated by the hot water unit 400 and then is conveyed to the evaporative crystallization unit 100 by the hot water pump, and the cleaning solution after washing can be conveyed to the cleaning tank 201 and then discharged, and can also be conveyed to other tank bodies (such as a buffer tank) and then discharged.
It should be noted that when the cleaning is not needed, the circulation pump 202 of the cleaning unit 200 is turned off, and the evaporation crystallization unit 100, the heat exchange unit 300, and the hot water unit 400 can perform the evaporation crystallization normally.
The online cleaning system for the evaporative crystallization device can clean the evaporative crystallization unit 100 without stopping, and can save the system startup and shutdown time.
The on-line cleaning system of the evaporative crystallization device can automatically control the opening and closing of various pumps and valves in the cleaning system by adopting software, so that the whole-course automatic cleaning can be realized, the cleaning process can be monitored on line and the on-line fault self-diagnosis function is realized, the operation is simple, and professional cleaning personnel do not need to be equipped.
In a preferred embodiment, the online cleaning system of the evaporative crystallization device comprises two sets of cleaning units 200, wherein the two sets of cleaning units 200 are used for circulating different cleaning agents, for example, one set of cleaning unit 200 is used for circulating an acidic cleaning agent, and the other set of cleaning unit 200 is used for circulating an alkaline cleaning agent.
The cleaning liquid can be properly selected according to operation systems of different materials. The cleaning fluid may be, but is not limited to: 1 to 3 percent of hydrochloric acid, 2 to 5 percent of sodium hydroxide, 3 to 5 percent of sodium carbonate and ethylene diamine tetraacetic acid (4 to 6 percent of EDTA).
Specifically, as shown in fig. 3, the first cleaning unit 200A includes a first cleaning tank 201A and a first circulation pump 202A, the first cleaning agent enters the first cleaning tank 201A through an inlet G14 or is directly conveyed to the G7 channel of the evaporative crystallization unit 100 by the first circulation pump 202A, the first cleaning agent flows back to the first cleaning tank 201A through the G9 channel after cleaning the evaporative crystallization unit 100, and the first cleaning agent in the first cleaning tank 201A is continuously conveyed to the G7 channel of the evaporative crystallization unit 100 under the action of the first circulation pump 202A. The first cleaning agent in the first cleaning tank 201A may also be delivered to the heat exchange unit 300 through the G4 channel by the first circulation pump 202A, so as to clean the heat exchange unit 300 and the hot water unit 400, and the cleaned first cleaning agent may be delivered back to the first cleaning tank 201A by the hot water pump 402.
As shown in FIG. 4, the second cleaning unit 200B includes a second cleaning tank 201B and a second circulation pump 202B, the second cleaning agent enters the second cleaning tank 201B through the G15 inlet or is directly conveyed to the G8 channel of the evaporative crystallization unit 100 by the second circulation pump 202B, the second cleaning agent flows back to the second cleaning tank 201B through the G10 channel after cleaning the evaporative crystallization unit 100, and the second cleaning agent in the second cleaning tank 201B is continuously conveyed to the G8 channel of the evaporative crystallization unit 100 under the action of the second circulation pump 202B. The second cleaning agent in the second cleaning tank 201B can also be delivered to the heat exchange unit 300 through the G4 by the second circulation pump 202B to clean the heat exchange unit 300 and the hot water unit 400, and the cleaned second cleaning solution can be delivered back to the second cleaning tank 201B by the hot water pump 402.
In some embodiments, the first cleaning unit 200A is used for storing and circulating an acidic cleaning solution, the first cleaning unit 200A further comprises a first absorber 203 disposed on the first cleaning tank 201A, the first absorber 203 is adapted to absorb a portion of acid mist or dust in the first cleaning tank 201A when the first circulation pump 202A is operated, as shown in fig. 3.
In some embodiments, the G14 and/or G15 inlets are quick connectors, and the quick connectors can be respectively connected with the mobile cleaning agent tank loading conveying pipe or the dosing cleaning discharge tank of the dosing device area in the urban mineral resource recycling treatment system, so that the universality is improved.
In some embodiments, the online cleaning system of the evaporative crystallization apparatus comprises a buffer unit 500, as shown in fig. 7, the buffer unit 500 comprises a buffer tank 501 and a buffer pump 502; the buffer tank 501 is suitable for being communicated with the cleaning tank 201, so that the liquid in the cleaning tank 201 is conveyed to the buffer tank 501 through the circulating pump 202; the buffer tank 501 is also suitable for being communicated with the evaporative crystallization unit 100, so that the cleaning agent directly flows back to the buffer tank 501 after the evaporative crystallization unit 100 is cleaned; the buffer pump 502 is suitable for conveying the liquid in the buffer tank 501 to a water washing device of the urban mineral resource utilization processing system for recycling water resources; after the pH value of the liquid in the buffer tank 501 is adjusted according to the water quality condition in the buffer tank 501, the buffer pump 502 is used for conveying the liquid to the evaporative crystallization unit for treatment, so that the utilization of water resources is improved, and the discharge is reduced.
In one embodiment, as shown in fig. 1 and 7, the buffer tank 501 is communicated with the first wash tank 201A through the G11 channel, and the liquid in the first wash tank 201A is adapted to enter the buffer tank 501 through the G11 channel by the first circulation pump 202A. The buffer tank 501 is communicated with the second cleaning tank 201B through a G12 channel, and the liquid in the second cleaning tank 201B is suitable for passing through the second circulating pump 202B into the buffer tank 501 through a G12. The buffer tank 501 is also selectively communicated with the G9 channel and the G10 channel, so that the liquid in the evaporative crystallization unit 100 can be conveyed to the buffer tank 501 through the G9 channel or the G10 channel.
In addition, the liquid in the hot water tank 401 can also be delivered to the buffer tank 501 through the hot water pump 402. Specifically, the liquid in the hot water tank 401 can be delivered to the G6 channel through the hot water pump 402, and the liquid in the G6 channel can be delivered to the evaporative crystallization unit 100 and also to the buffer tank 501 through adjusting the corresponding valves.
In some embodiments, the buffer unit 500 further comprises a second absorber 503 disposed on the buffer tank 501, and the second absorber 503 is used for absorbing part of acid mist or dust in the buffer tank 501.
In some embodiments, automatic drain valves may be disposed at the bottoms of the hot water tank 401, the cleaning tank 201, and the buffer tank 501, so that the liquid in the tanks may be drained to a water washing device of the urban mineral resource recycling system for recycling water resources.
In one embodiment, the liquid in the hot water tank 401 can be directly discharged through the G16 channel, the liquid in the first wash tank 201A can be directly discharged through the G18 channel, the liquid in the second wash tank 201B can be directly discharged through the G19 channel, and the liquid in the buffer tank 501 can be directly discharged through the G20 channel.
In some embodiments, heat exchange unit 300 comprises a heat exchanger 301 and a filter 302, wherein filter 302 is used for filtering liquid entering heat exchanger 301 to remove solid impurity particles in the liquid. The water outlet of the heat exchanger 301 is communicated with the hot water tank 401, so that the liquid preheated by the heat exchanger 301 enters the hot water tank 401 for heating.
It is worth mentioning that the heat exchanger 301 may be, but not limited to, a plate heat exchanger, a shell-and-tube heat exchanger, a hot air heat exchanger, a waste heat recovery device, a heat pump, etc. The filter 302 may be, but is not limited to, a vertical filter, a tube filter, a ceramic membrane filter, a membrane filtration device, a pure water producing device, or the like.
In some embodiments, the heat exchanging unit 300 further includes a condensing tank 303 and a condensing pump 304, wherein the steam for heat exchanging is condensed by the heat exchanger 301, the condensing tank 303 is used for collecting condensed water, and the condensing pump 304 is used for delivering the condensed water to the hot water tank 401. Therefore, the steam utilization rate is improved, and the water consumption is saved. Of course, the condensation tank 303 and the condensation pump 304 may be directly replaced by pipes through which the condensed water is directly fed into the hot water tank 401.
In one embodiment, as shown in fig. 5, on one hand, the liquid (which may be water, deionized water or cleaning agent) enters the filter 302 through the G4 channel, then enters the heat exchanger 301, and enters the hot water tank 401 through the G5 channel after the heat exchange of the heat exchanger 301; on the other hand, the raw steam enters the heat exchanger 301 through the G2 channel, enters the G3 channel after heat exchange, condensed water is collected in the condensation tank 303, and the condensation pump 304 can convey liquid in the condensation tank 303 to the hot water tank 401.
Further, the liquid in the filter 302 can be directly discharged through the G22 channel, and the liquid in the condensation tank 303 can be directly discharged through the G21 channel.
Further, the water temperature of G5 can be detected by a first temperature detection device (TT-02), and the valve of the G2 channel can be adjusted according to the data of the first temperature detection device to adjust the steam quantity passing through the heat exchanger 301, so that the water temperature of the G5 channel can be controlled. The steam admission amount of G2 can be counted by FT-02.
Furthermore, a first pressure detection device (PT-02) and a second pressure detection device (PT-03) are respectively arranged at the water inlet end and the water outlet end of the heat exchanger 301, the heat exchange unit 300 is further provided with a cleaning alarm device, the cleaning alarm device is electrically connected with the first pressure detection device and the second pressure detection device, whether the interior of the heat exchanger 301 is seriously blocked or not can be judged by comparing the pressure data of the first pressure detection device and the pressure data of the second pressure detection device, and the cleaning alarm device automatically alarms when the interior of the heat exchanger 301 is required to be cleaned.
In some embodiments, the hot water unit 400 further comprises a thermal insulating coil 403 disposed outside the hot water tank 401, the thermal insulating coil 403 being used to ensure that the liquid inside the hot water tank 401 is stably maintained at the desired process temperature. The heat preservation coil 403 is provided with a steam inlet and a condensed water outlet, and the condensed water outlet is communicated with the condensing tank 303, so that the steam utilization rate is improved, and the water consumption is saved.
In one embodiment, as shown in FIG. 6, the raw steam is adapted to pass through the G1 channel into the thermal insulation coil 403, and the condensed water in the thermal insulation coil 403 is adapted to be transported to the condensation tank 303 through the G17 channel.
The hot water tank 401 of the present application can be made of a tank body with a built-in coil or a jacket type.
In some embodiments, as shown in fig. 2, evaporative crystallization unit 100 comprises sodium salt evaporation 1-effect 101, sodium salt evaporation 2-effect 102, potassium salt evaporation 1-effect 103, potassium salt evaporation 2-effect 104. The operation principle of each effect of the evaporative crystallization unit 100 is the prior art, and is not described in detail in this application.
It is worth mentioning that the opening of each equipment in the application can be automatically controlled through the program, and during cleaning, the whole cleaning work can be completed through the program only by setting the cleaning time.
In this application, the cleaning tank 201 and the buffer tank 501 can be made of different materials, for example, carbon steel or stainless steel (such as 304 or 316L) is used as the outer shell, and the inner lining is made of non-metal material (such as PE, PTFE, glass fiber reinforced plastic, resin, PEEK, HDPE, PPS)
It is worth mentioning that the general cleaning process includes alkali cleaning, acid cleaning, and hot water cleaning for 1-2 times, wherein the hot water temperature is 80-95 degrees. During actual cleaning, an alkaline cleaning agent is arranged in the second cleaning tank 201B, the second circulating pump 202B of the second cleaning unit 200B is controlled to start working first, alkaline cleaning is performed on a target, the target can be cleaned circularly for multiple times according to actual needs, and the cleaning agent can flow back to the cleaning tank 201B or the cache tank 501 after the alkaline cleaning is completed; an acidic cleaning agent is arranged in the first cleaning tank 201A, a first circulating pump 202A of the first cleaning unit 200A is controlled to start working, a target is pickled, the target can be cleaned circularly for multiple times according to actual needs, and the cleaning agent can flow back to the cleaning tank 201A or the buffer tank 501 after the pickling is finished; after the cleaning is completed, water or deionized water is introduced into the heat exchange unit 300, the hot water unit 400 is controlled to start working, water is heated by the hot water unit 400 and then is input into the evaporative crystallization unit 100 for hot water cleaning, and the cleaning solution can be conveyed to the buffer tank 501. The whole cleaning process can be controlled through a program, the person is not required to watch, and the operation is simple.
In the prior art, the online cleaning equipment mainly adopts a structure of a cleaning ball or a cleaning brush, the structural design of the equipment is complex, and an independent ball chamber or a cleaning chamber needs to be arranged, so that the design, manufacturing, installation and debugging difficulty is increased. And the evaporation crystallization device online cleaning system's of this application equipment mainly is equipment such as jar class, pump class, heat exchanger, its installation and maintenance homogeneous phase are relatively simple to be favorable to reducing maintenance cost and working costs, in addition, this application does not have widget such as corresponding ball or brush, and the corresponding solution of preparation also mostly is dilute solution, can not be to the jam of equipment such as evaporation crystallization device pipeline, filter, valve, heat exchanger, also can not cause the damage to pump impeller, has improved the stability after the evaporation plant starts.
The utility model provides an evaporation crystallization device on-line cleaning system can realize whole self-cleaning, can rinse dirt and salt dirt comparatively thoroughly, and the cleaning performance can reach more than 95%, can effectively improve evaporation crystallization device's operation security and stability after the washing.
The application discloses evaporation crystallization device on-line cleaning system can dispose the hot water of different temperatures and carry out the local washing for different positions or part, and the cleaning process is controllable, washs the wide of coverage.
The online cleaning system for the evaporative crystallization device can be used for online cleaning by accessing different types of cleaning liquids from the G4 port according to the actual running state and the field device arrangement condition, and is flexible to operate.
The online cleaning system for the evaporative crystallization device can be systematically designed according to actual conditions, the skid-mounted structural design can be carried out on small cleaning amount, the design is relatively compact, and subsequent process equipment can be flexibly arranged and connected.
The utility model provides an evaporation crystallization device on-line cleaning system can dispose corresponding water consumption according to the actual capacity of evaporation crystallization unit, and whole water resource can recycle, has improved the utilization ratio of water resource.
The foregoing has described the general principles, essential features, and advantages of the application. It will be understood by those skilled in the art that the present application is not limited to the embodiments described above, which are merely illustrative of the principles of the application, but that various changes and modifications may be made without departing from the spirit and scope of the application, and these changes and modifications are intended to be within the scope of the application as claimed. The scope of protection claimed by this application is defined by the following claims and their equivalents.
Claims (10)
1. An online cleaning system for an evaporative crystallization device, comprising: the device comprises an evaporation crystallization unit, at least one cleaning unit, a heat exchange unit and a hot water unit;
the heat exchange unit is used for preheating liquid entering the hot water unit;
the hot water unit comprises a hot water tank and a hot water pump, and the hot water pump is used for conveying liquid in the hot water tank to the evaporative crystallization unit and/or the cleaning unit;
the cleaning unit comprises a cleaning tank and a circulating pump, the circulating pump is used for conveying liquid in the cleaning tank to the evaporative crystallization unit and/or the heat exchange unit, the liquid conveyed to the evaporative crystallization unit is suitable for being conveyed back to the cleaning tank after being cleaned, and the liquid conveyed to the heat exchange unit is suitable for entering the hot water tank and being conveyed back to the cleaning tank under the action of the hot water pump.
2. The online cleaning system for the evaporative crystallization device as claimed in claim 1, comprising two sets of the cleaning units, wherein the two sets of the cleaning units are used for circulating different cleaning agents.
3. The evaporative crystallization device on-line cleaning system as claimed in claim 2, wherein the cleaning unit is provided with a quick interface for inputting cleaning agent, and the quick interface is suitable for being connected with a cleaning agent tank truck delivery pipe or other cleaning agent discharge tank.
4. The evaporative crystallization device on-line cleaning system as claimed in claim 1, wherein at least one of the cleaning units further comprises a first absorber disposed on the cleaning tank for absorbing acid mist or dust.
5. The online cleaning system for the evaporative crystallization device as claimed in claim 1, further comprising a buffer unit, wherein the buffer unit comprises a buffer tank, the buffer tank is adapted to be communicated with the cleaning tank so that the liquid in the cleaning tank can be conveyed to the buffer tank through the circulating pump, and the buffer tank is further adapted to be communicated with the evaporative crystallization unit so that the cleaning agent used for cleaning the evaporative crystallization unit can flow back to the buffer tank.
6. The evaporative crystallization device in-line cleaning system as claimed in claim 5, wherein the buffer unit further comprises a second absorber disposed on the buffer tank, the second absorber is used for absorbing acid mist or dust in the buffer tank.
7. The on-line cleaning system for the evaporative crystallization device as claimed in any one of claims 1 to 6, wherein the heat exchange unit comprises a heat exchanger and a filter, the filter is used for filtering the liquid preheated by entering the heat exchanger, the heat exchanger is connected with the hot water tank, so that the liquid preheated by the heat exchanger is suitable for entering the hot water tank.
8. The online cleaning system for the evaporative crystallization device as claimed in claim 7, wherein the heat exchange unit further comprises a condensation tank and a condensation pump, the condensation tank is used for collecting condensed water, and the condensation pump is used for conveying the condensed water in the condensation tank to the hot water tank.
9. The on-line cleaning system for the evaporative crystallization device as claimed in claim 8, wherein the housing of the hot water tank is provided with a heat preservation coil pipe, the heat preservation coil pipe is provided with a steam inlet and a condensed water outlet, and the condensed water outlet is communicated with the condensing tank.
10. The online cleaning system for the evaporative crystallization device as claimed in claim 7, wherein a first temperature detection device is arranged at a liquid outlet of the heat exchanger, so as to adjust the amount of steam entering the heat exchanger according to the detection result of the first temperature detection device, and a first pressure detection device and a second pressure detection device are respectively arranged at a water inlet end and a water outlet end of the heat exchanger, so as to determine whether the heat exchanger needs to be cleaned according to the detection results of the first pressure detection device and the second pressure detection device.
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