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CN207203835U - A kind of exhaust treatment system in glass furnace production - Google Patents

A kind of exhaust treatment system in glass furnace production Download PDF

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Publication number
CN207203835U
CN207203835U CN201721036956.2U CN201721036956U CN207203835U CN 207203835 U CN207203835 U CN 207203835U CN 201721036956 U CN201721036956 U CN 201721036956U CN 207203835 U CN207203835 U CN 207203835U
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China
Prior art keywords
tower
defluorinate tower
defluorinate
tail gas
spray gun
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CN201721036956.2U
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Inventor
罗秋生
张谦
杨宏美
韩向阳
张睿
黄中义
刘刚
秦平刚
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Sichuan Chenguang Engineering Design Institute Co Ltd
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Sichuan Chenguang Engineering Design Institute Co Ltd
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Abstract

The exhaust treatment system in a kind of glass furnace production is the utility model is related to, belongs to tail gas disposal technique field in glass manufacture.System of the present utility model includes tail gas admission line, preheater, defluorinate tower, milk of lime underground tank and chimney;Washer is provided with the tower wall of the defluorinate tower;The washer is L-type, is made up of vertical cylindrical part and horizontal tubular elements.The utility model can avoid direct spraying cooling cooling pretreatment from producing a large amount of steam, both influence the absorbing and removing of waste gas containing fluoride, while the fluoride grit in tail gas carries the outer situation generation arranged, cause the discharge beyond standards of fluoride secretly by a large amount of steam.

Description

A kind of exhaust treatment system in glass furnace production
Technical field
A kind of exhaust treatment system is the utility model is related to, more specifically, the utility model is related to a kind of glass furnace Exhaust treatment system in production, belong to tail gas disposal technique field in glass manufacture.
Background technology
When glass furnace is run, a certain amount of SO is produced2, NOx and HF, if being arranged without processing is directly outer, periphery can be polluted Environment.To reach state environmental emissioning standard and requirement, and according to national environmental protection policy, minimum discharge, realize dedusting, desulfurization, Denitration, while reach the technical requirements of enterprise, meet the requirement of Environmental protection, its boiler exhaust gas need to be administered.
The raw material added in industrial glass kiln production process contain fluoride composition, cause to deposit in discharged waste gas In a certain amount of waste gas containing fluoride, according to respective country standard, its corresponding concentration of emission is 6mg/m3.The main composition of fluoride is Hydrogen fluoride and a small amount of fluoride grit not soluble in water, the main purpose of defluorinate are to remove the fluorine ion in flue gas.
Because hydrogen fluoride possesses stronger solubility property, therefore typically uses calcium hydroxide wet method defluorinate.Its general principle is Hydrogen fluoride and calcium hydroxide reaction in flue gas, generation are insoluble in the calcirm-fluoride deposit of water, fluorine ion in flue gas are realized with this Removing.
State Intellectual Property Office discloses a Publication No. CN201079729Y, entitled " glass in 2008.07.02 The utility model of kiln gas defluorinate tower ", the utility model are related to a kind of glass of defluorinate in opal glass article manufacturing process Glass kiln gas defluorinate tower.Include that top is provided with exhanst gas outlet (3), bottom is provided with gas approach (2), bottom is provided with out The main cylinder (1) of liquid mouth (4), the nozzle (7) of the interior sprinkling defluorinate liquid being provided with no less than two layers of main cylinder (1), gas approach (2) connected with main cylinder (1) in tangent line, the Venturi tube (5) equipped with water distributor (6) is set at gas approach (2) place, in main cylinder The spiral board (8) no less than one layer can be set in body (1);Described defluorinate liquid species is a lot, can be pH value > 8 Ca (OH) 2 solution.With the HF toxic gases that can effectively eliminate in glass kiln gas, prevent from polluting environment;And it is simple in construction, cost is low The features such as.
Because fluoride can be just fully absorbed in low temperature condition, so without by cooling in advance in above-mentioned technical proposal , the problem of Absorption of Fluoride is insufficient be present in processing.
State Intellectual Property Office discloses a Publication No. CN104841263A, entitled " setting snail in 2015.8.19 The invention of the glass fibre stove flue gas desulphurization unit and technique of wheel supercharging turbulator ", the invention set turbocharging turbulator Glass fibre stove flue gas desulphurization unit and technique be environmental technology field.Device is furnace flue gas pipe and benefit air-valve, air-cooled Tower is fixed with cooling down tower, cooling down tower and desulfurizing tower by pipeline, furnace flue gas pipe and air cooling tower, cooling down tower and mist Change nozzle sets to fix, cooling down tower is with inserting the pipeline of circulating slot, groove is fixed with inserting the pipeline of circulating slot, in desulfurizing tower Wall is fixed with (operating) water nozzle group, desulfurization nozzle group, turbocharging turbulator, groove successively, sets agitator in circulating slot, circulating slot with Desulfurization pump and fixed with atomizer pump, desulfurization pump and desulfurization nozzle group, atomizer pump and atomizer group by pipeline, desulfurizing tower and secondary tower Flue, secondary tower flue and air-introduced machine, air-introduced machine and chimney, circulating slot and blowoff valve are fixed by pipeline;Technique is the air-cooled drop of flue gas Warm desulfurization defluorinate demisting discharge and liquid backflow organic whole are automatic continuous, in good time blowdown.For fume desulfurizing, defluorinating.Device is skilful Technique letter effect is steady.
Problems be present in above-mentioned prior art:Tail gas cooling causes tail gas amount to increase using cold air mode is directly added into Greatly, subsequent processing device pressure is caused to become big;Defluorinate tower bottom discharge opeing is immediately discharged to circulating slot, and circulating slot is provided with agitator, The solid particles such as calcirm-fluoride can not be settled effectively, and system can be returned after agitated on the contrary, cause circulation fluid solid content to increase.
Utility model content
The utility model aims to solve the problem that direct spraying cooling cooling pretreatment can produce existing for defluorination process in the prior art Raw a large amount of steam, the absorbing and removing of waste gas containing fluoride was both influenceed, while the fluoride grit in tail gas carries outer row secretly by a large amount of steam, The problem of causing the discharge beyond standards of fluoride, there is provided the exhaust treatment system in a kind of glass furnace production, can avoid directly Spraying cooling cooling pretreatment can produce a large amount of steam, both influence the absorbing and removing of waste gas containing fluoride, while the fluoride in tail gas Grit carries the outer situation generation arranged, cause the discharge beyond standards of fluoride secretly by a large amount of steam.
In order to realize above-mentioned purpose of utility model, its specific technical scheme is as follows:
A kind of exhaust treatment system in glass furnace production, it is characterised in that:Including tail gas admission line, preheater, Defluorinate tower, milk of lime underground tank and chimney;Washer is provided with the tower wall of the defluorinate tower;The washer is L-type, by hanging down Straight-tube shape part and horizontal tubular elements composition, the top of the vertical cylindrical part connect with the tail gas admission line, described vertical The bottom of tubular elements connects with one end of the horizontal tubular elements, and the other end of the horizontal tubular elements is in the defluorinate tower Inside on the outer wall of bottom with the defluorinate tower connects;At least two washers are provided with from top to bottom in the vertical cylindrical part Spray gun, the middle and upper part in the defluorinate tower are provided with least two defluorinate tower spray guns, the washer spray gun and institute from top to bottom The connection of milk of lime underground tank is stated, the defluorinate tower spray gun is by circulating pump with being connected in the defluorinate tower;The top of the defluorinate tower Portion is connected by pipeline with the chimney.
The utility model is preferable, and the horizontal tubular elements take off along the tangent line of circle where the defluorinate tower cross section with described Fluorine tower connects.
The utility model is preferable, and the preheater is arranged on the tail gas admission line, and the preheater is included simultaneously The tail gas that row is set cools chamber and air heat-exchange chamber in advance;The tail gas admission line cools chamber in advance by the tail gas, the sky Gas heat exchanging chamber is passed through by air duct;The trend of the tail gas admission line and the air duct is on the contrary, the air duct Glass furnace is gone to after the air heat-exchange chamber.
The utility model is preferable, and the washer spray gun and/or the defluorinate tower spray gun are all the cloth that interlocks from top to bottom Put.
The utility model is preferable, and wash tub pipe, the wash tub pipe and institute are provided with above the defluorinate tower spray gun State and be provided with demister between defluorinate tower spray gun.
The utility model is preferable, and the bottom inside the defluorinate tower is provided with aerator, the liquid inside the defluorinate tower It is provided with the first liquid outlet on the outer wall of face position, the second liquid is provided with the defluorinate tower outer wall above the aerator Body is exported, and the 3rd liquid outlet is provided with the defluorinate tower outer wall below the aerator;First liquid outlet and Second liquid outlet passes through pipeline communication thick slurry by milk of lime underground tank described in pipeline communication, the 3rd liquid outlet respectively Subsider, the thick slurry subsider connect with the milk of lime underground tank again.
The utility model is preferable, and serum outlet is provided with the shell of the defluorinate tower bottom, and the serum outlet leads to Circulating pump connection shell-and-tube heat exchanger is crossed, the shell-and-tube heat exchanger connects further through pipeline with the defluorinate tower spray gun.
The utility model is preferable, and multiple baffle demister is provided with the chimney, passes through pipeline at the top of the defluorinate tower Connected with the multiple baffle demister of the chimney.
The advantageous effects that the utility model is brought:
1st, the utility model aims to solve the problem that direct spraying cooling cooling pretreatment meeting existing for defluorination process in the prior art A large amount of steam are produced, have both influenceed the absorbing and removing of waste gas containing fluoride, while the fluoride grit in tail gas is outer by the entrainment of a large amount of steam Row, the problem of causing the discharge beyond standards of fluoride, there is provided the exhaust treatment system in a kind of glass furnace production, can avoid straight A large amount of steam can be produced by connecing spraying cooling cooling pretreatment, both influence the absorbing and removing of waste gas containing fluoride, while the fluorination in tail gas Thing grit carries the outer situation generation arranged, cause the discharge beyond standards of fluoride secretly by a large amount of steam.
2nd, the utility model sets two-stage to cool before tail gas enters defluorinate tower:One-level cooling uses preheater, through with it is cold Follow-up system is sent into after air heat-exchange cooling;Two level cools in washing section, and cleaning solution is contacted into cooling with tail gas by spray gun.Two Level cooling avoids direct spraying cooling cooling pretreatment from producing a large amount of steam, has both influenceed the absorbing and removing of waste gas containing fluoride, simultaneously Fluoride grit in tail gas by a large amount of steam carry secretly it is outer arrange, the problem of causing the discharge beyond standards of fluoride.
3rd, in the utility model, after the preheated device of tail gas, temperature is also in higher state, because defluorinate tower is rubber-lining equipment, It is directly entered in tower, tower line with rubber will necessarily be caused to damage as exhaust temperature is too high, therefore reducing temperature twice must be carried out to tail gas.Tail After the preheated device of gas, L-type washer is initially entered, in L-type washer vertical cylindrical part, the de- of at least two layers different height is set Fluorine tower spray gun.Supernatant in milk of lime underground tank is delivered to defluorinate tower spray gun by washer circulating pump, after the atomization of defluorinate tower spray gun Washer is sent into, tail gas is contacted in washer with atomized liquid, and exhaust temperature is reduced into suitable inlet temperature of stabilizer, while right Tail gas carries out pre-absorption.In the horizontal tubular section of L-type washer, temperature detection can be set, monitor tail gas inlet temperature of stabilizer in real time, together When to enter defluorinate tower tail gas carry out water conservancy diversion.
4th, the utility model is preferable, the horizontal tubular elements along the tangent line of circle where the defluorinate tower cross section with it is described Defluorinate tower connects.The said equipment connected mode is selected, process gas flow can be made to form cyclonic separation state in defluorinate tower, to increase Fluoride Separation effect in aerating stream.
5th, in the utility model, using preheater, avoid cold air being directly added into tail gas is cooled, and then increase Vent gas treatment amount, cause follow-up defluorinate systematic lectotype to increase, increase first cost of investment.Preheater is set up, by being incited somebody to action after heat exchange Exhaust temperature control is produced in certain temperature, so as to avoid tail gas from being passed directly into defluorinate system, direct spraying cooling cooling processing Raw a large amount of steam, influence the absorbing and removing of waste gas containing fluoride, while it is outer to avoid the fluoride grit in tail gas from being carried secretly by a large amount of steam Row, the problem of causing the discharge beyond standards of fluoride.
6th, in the utility model, at least two layers of different height, and washer spray gun staggeredly is set in washer, will be circulated Clear liquid is by being pumped into washer spray gun;The cleaning solution that washer spray gun is sprayed, which can accumulate washer inner section, all to be covered Lid, so as to carry out reducing temperature twice and pre-absorption to flue gas.Set from top to bottom in defluorinate tower at least two layers, and defluorinate tower staggeredly Spray gun, defluorinate tower spray gun is sent into after slurries in tower are pumped out by circulation, has and selects the spies such as area coverage is wide, atomizing effect is good Point, fully hydrogen fluoride in flue gas can be absorbed, ensure higher removal efficiency.
7th, in the utility model, wash tub pipe is set, and its object is to prevent demister fouling to block up above defluorinate tower spray gun Plug.After defluorinate tower runs a period of time, wash tub pipe valve can be opened, 5-10 minutes are rinsed to demister, is easy to take off Fluorine tower normal table is run.
8th, in the utility model, tower bottom can be deposited in, it is necessary to set stirring to fill by reacting the bulky grains such as the calcirm-fluoride of generation Put, avoid particulate matter from being accumulated in bottom of towe.Because the tower diameter of most defluorinate tower is too small, agitator is such as set, agitator will be unable to install. Therefore aerator is set in bottom of towe, liquid is remained certain mixed flow state by being sent into compressed air, pass through the liquid of bottom of towe the 3rd Thick slurry subsider is sent into body outlet, and by three-level natural subsidence, solids particles precipitate, supernatant returns to milk of lime underground tank.For It is too high to avoid holding liquid liquid level in tower, sets second liquid to export above aerator, i.e. overfall, by superelevation liquid level liquid flooding To milk of lime underground tank.
9th, in the utility model, bottom of towe loop slurry contacts through circulating pump, defluorinate tower spray gun with tail gas, will be fluorinated in tail gas Thing absorbing and removing, loop slurry temperature increase., need to be by loop slurry temperature to ensure that fluoride has higher removal efficiency Reduce.System sets shell-and-tube heat exchanger, and defluorinate tower slurries out first pass around shell-and-tube heat exchanger out of tower through circulating pump, lead to Cross and exchanged heat with cooling circulating water, cool the temperature to certain temperature, be re-fed into defluorinate tower top defluorinate tower spray gun and enter in tower, Ensure that loop slurry is in higher absorption efficiency all the time.
10th, in the utility model, multiple baffle demister is provided with chimney, the moisture in final discharge flue gas can be removed, So as to reduce discharge capacity.
Brief description of the drawings
Fig. 1 is the connection and device structure schematic diagram of Tthe utility model system;
Fig. 2 is the cross-sectional structure schematic diagram of defluorinate tower in Tthe utility model system.
Reference:1 be tail gas admission line, 2 be preheater, 3 be defluorinate tower, 4 be milk of lime underground tank, 5 be chimney, 6 it is washer, 7 be vertical cylindrical part, 8 be horizontal tubular elements, 9 be washer spray gun, 10 be defluorinate tower spray gun, 11 is that tail gas is pre- Cooling chamber, 12 be air heat-exchange chamber, 13 be air duct, 14 be wash tub pipe, 15 be demister, 16 be aerator, 17 be the One liquid outlet, 18 be second liquid outlet, 19 be the 3rd liquid outlet, 20 be thick slurry subsider, 21 be serum outlet, 22 be Shell-and-tube heat exchanger, 23 are multiple baffle demister.
Embodiment
Embodiment 1
A kind of exhaust treatment system in glass furnace production, including tail gas admission line 1, preheater 2, defluorinate tower 3, stone The newborn underground tank 4 of ash and chimney 5;Washer 6 is provided with the tower wall of the defluorinate tower 3;The washer 6 is L-type, by vertical cylinder Shape part 7 and horizontal tubular elements 8 form, and the top of the vertical cylindrical part 7 connects with the tail gas admission line 1, described vertical The bottom of tubular elements 7 connects with one end of the horizontal tubular elements 8, and the other end of the horizontal tubular elements 8 is in the defluorinate tower 3 Middle and lower part outer wall on connected with the inside of the defluorinate tower 3;At least two are provided with from top to bottom in the vertical cylindrical part 7 Washer spray gun 9, the middle and upper part in the defluorinate tower 3 are provided with least two defluorinate tower spray guns 10, the washing from top to bottom Device spray gun 9 connects with the milk of lime underground tank 4, and the defluorinate tower spray gun 10 is by circulating pump with being connected in the defluorinate tower 3; The top of the defluorinate tower 3 is connected by pipeline with the chimney 5.
Embodiment 2
A kind of exhaust treatment system in glass furnace production, including tail gas admission line 1, preheater 2, defluorinate tower 3, stone The newborn underground tank 4 of ash and chimney 5;Washer 6 is provided with the tower wall of the defluorinate tower 3;The washer 6 is L-type, by vertical cylinder Shape part 7 and horizontal tubular elements 8 form, and the top of the vertical cylindrical part 7 connects with the tail gas admission line 1, described vertical The bottom of tubular elements 7 connects with one end of the horizontal tubular elements 8, and the other end of the horizontal tubular elements 8 is in the defluorinate tower 3 Middle and lower part outer wall on connected with the inside of the defluorinate tower 3;At least two are provided with from top to bottom in the vertical cylindrical part 7 Washer spray gun 9, the middle and upper part in the defluorinate tower 3 are provided with least two defluorinate tower spray guns 10, the washing from top to bottom Device spray gun 9 connects with the milk of lime underground tank 4, and the defluorinate tower spray gun 10 is by circulating pump with being connected in the defluorinate tower 3; The top of the defluorinate tower 3 is connected by pipeline with the chimney 5.
Preferably, tangent line of the horizontal tubular elements 8 along circle where the cross section of defluorinate tower 3 connects with the defluorinate tower 3 It is logical.
Embodiment 3
A kind of exhaust treatment system in glass furnace production, including tail gas admission line 1, preheater 2, defluorinate tower 3, stone The newborn underground tank 4 of ash and chimney 5;Washer 6 is provided with the tower wall of the defluorinate tower 3;The washer 6 is L-type, by vertical cylinder Shape part 7 and horizontal tubular elements 8 form, and the top of the vertical cylindrical part 7 connects with the tail gas admission line 1, described vertical The bottom of tubular elements 7 connects with one end of the horizontal tubular elements 8, and the other end of the horizontal tubular elements 8 is in the defluorinate tower 3 Middle and lower part outer wall on connected with the inside of the defluorinate tower 3;At least two are provided with from top to bottom in the vertical cylindrical part 7 Washer spray gun 9, the middle and upper part in the defluorinate tower 3 are provided with least two defluorinate tower spray guns 10, the washing from top to bottom Device spray gun 9 connects with the milk of lime underground tank 4, and the defluorinate tower spray gun 10 is by circulating pump with being connected in the defluorinate tower 3; The top of the defluorinate tower 3 is connected by pipeline with the chimney 5.
Preferably, the preheater 2 is arranged on the tail gas admission line 1, and the preheater 2 includes what is be arranged side by side Tail gas cools chamber 11 and air heat-exchange chamber 12 in advance;The tail gas admission line 1 cools chamber 11 in advance by the tail gas, the air Heat exchanging chamber 12 is passed through by air duct 13;The trend of the tail gas admission line 1 and the air duct 13 is on the contrary, the air Pipeline 13 goes to glass furnace after the air heat-exchange chamber 12.
Specifically:Preheater 2 is set before washer 6, defluorinate tower 3 is entered, sent after exhaust temperature is down into certain temperature Enter washer 6.Preheater 2 uses heat-pipe heat exchanger, is in tilted layout, hot side(That is tail gas cools chamber 11 in advance)Entrance end is low End, cold side(That is air heat-exchange chamber 12)Entrance end is high-end.Tail gas heats heat exchanger tube by the heat exchanger tube of the hot side of preheater 2 Interior heating agent, heating agent are risen to high-end cold side by heat exchanger tube by after thermal evaporation;Cold side uses air, is sent into by air blower Preheater 2, cold air exchange heat after heat exchanger tube with heating agent, heating agent condensing reflux to low side hot side, air temperature rise Afterwards, it is combustion-supporting to be sent into glass furnace.
Embodiment 4
A kind of exhaust treatment system in glass furnace production, including tail gas admission line 1, preheater 2, defluorinate tower 3, stone The newborn underground tank 4 of ash and chimney 5;Washer 6 is provided with the tower wall of the defluorinate tower 3;The washer 6 is L-type, by vertical cylinder Shape part 7 and horizontal tubular elements 8 form, and the top of the vertical cylindrical part 7 connects with the tail gas admission line 1, described vertical The bottom of tubular elements 7 connects with one end of the horizontal tubular elements 8, and the other end of the horizontal tubular elements 8 is in the defluorinate tower 3 Middle and lower part outer wall on connected with the inside of the defluorinate tower 3;At least two are provided with from top to bottom in the vertical cylindrical part 7 Washer spray gun 9, the middle and upper part in the defluorinate tower 3 are provided with least two defluorinate tower spray guns 10, the washing from top to bottom Device spray gun 9 connects with the milk of lime underground tank 4, and the defluorinate tower spray gun 10 is by circulating pump with being connected in the defluorinate tower 3; The top of the defluorinate tower 3 is connected by pipeline with the chimney 5.
Preferably, the washer spray gun 9 and/or the defluorinate tower spray gun 10 are all interlaced arrangement from top to bottom.
Embodiment 5
A kind of exhaust treatment system in glass furnace production, including tail gas admission line 1, preheater 2, defluorinate tower 3, stone The newborn underground tank 4 of ash and chimney 5;Washer 6 is provided with the tower wall of the defluorinate tower 3;The washer 6 is L-type, by vertical cylinder Shape part 7 and horizontal tubular elements 8 form, and the top of the vertical cylindrical part 7 connects with the tail gas admission line 1, described vertical The bottom of tubular elements 7 connects with one end of the horizontal tubular elements 8, and the other end of the horizontal tubular elements 8 is in the defluorinate tower 3 Middle and lower part outer wall on connected with the inside of the defluorinate tower 3;At least two are provided with from top to bottom in the vertical cylindrical part 7 Washer spray gun 9, the middle and upper part in the defluorinate tower 3 are provided with least two defluorinate tower spray guns 10, the washing from top to bottom Device spray gun 9 connects with the milk of lime underground tank 4, and the defluorinate tower spray gun 10 is by circulating pump with being connected in the defluorinate tower 3; The top of the defluorinate tower 3 is connected by pipeline with the chimney 5.
Preferably, the top of the defluorinate tower spray gun 10 is provided with wash tub pipe 14, and the wash tub pipe 14 takes off with described Demister 15 is provided between fluorine tower spray gun 10.
Embodiment 6
A kind of exhaust treatment system in glass furnace production, including tail gas admission line 1, preheater 2, defluorinate tower 3, stone The newborn underground tank 4 of ash and chimney 5;Washer 6 is provided with the tower wall of the defluorinate tower 3;The washer 6 is L-type, by vertical cylinder Shape part 7 and horizontal tubular elements 8 form, and the top of the vertical cylindrical part 7 connects with the tail gas admission line 1, described vertical The bottom of tubular elements 7 connects with one end of the horizontal tubular elements 8, and the other end of the horizontal tubular elements 8 is in the defluorinate tower 3 Middle and lower part outer wall on connected with the inside of the defluorinate tower 3;At least two are provided with from top to bottom in the vertical cylindrical part 7 Washer spray gun 9, the middle and upper part in the defluorinate tower 3 are provided with least two defluorinate tower spray guns 10, the washing from top to bottom Device spray gun 9 connects with the milk of lime underground tank 4, and the defluorinate tower spray gun 10 is by circulating pump with being connected in the defluorinate tower 3; The top of the defluorinate tower 3 is connected by pipeline with the chimney 5.
Preferably, the bottom inside the defluorinate tower 3 is provided with aerator 16, in the internal liquid level position of defluorinate tower 3 Outer wall on be provided with the first liquid outlet 17, be provided with the second liquid on the outer wall of defluorinate tower 3 of the top of aerator 16 Body exports 18, and the 3rd liquid outlet 19 is provided with the outer wall of defluorinate tower 3 of the lower section of aerator 16;First liquid Outlet 17 and second liquid outlet 18 are logical by milk of lime underground tank 4 described in pipeline communication, the 3rd liquid outlet 19 respectively Piping connection thick slurry subsider 20, the thick slurry subsider 20 connects with the milk of lime underground tank 4 again.
Embodiment 7
A kind of exhaust treatment system in glass furnace production, including tail gas admission line 1, preheater 2, defluorinate tower 3, stone The newborn underground tank 4 of ash and chimney 5;Washer 6 is provided with the tower wall of the defluorinate tower 3;The washer 6 is L-type, by vertical cylinder Shape part 7 and horizontal tubular elements 8 form, and the top of the vertical cylindrical part 7 connects with the tail gas admission line 1, described vertical The bottom of tubular elements 7 connects with one end of the horizontal tubular elements 8, and the other end of the horizontal tubular elements 8 is in the defluorinate tower 3 Middle and lower part outer wall on connected with the inside of the defluorinate tower 3;At least two are provided with from top to bottom in the vertical cylindrical part 7 Washer spray gun 9, the middle and upper part in the defluorinate tower 3 are provided with least two defluorinate tower spray guns 10, the washing from top to bottom Device spray gun 9 connects with the milk of lime underground tank 4, and the defluorinate tower spray gun 10 is by circulating pump with being connected in the defluorinate tower 3; The top of the defluorinate tower 3 is connected by pipeline with the chimney 5.
Preferably, serum outlet 21 is provided with the shell of the bottom of defluorinate tower 3, the serum outlet 21 passes through circulation Pump connects shell-and-tube heat exchanger 22, and the shell-and-tube heat exchanger 22 connects further through pipeline with the defluorinate tower spray gun 10.
Embodiment 8
A kind of exhaust treatment system in glass furnace production, including tail gas admission line 1, preheater 2, defluorinate tower 3, stone The newborn underground tank 4 of ash and chimney 5;Washer 6 is provided with the tower wall of the defluorinate tower 3;The washer 6 is L-type, by vertical cylinder Shape part 7 and horizontal tubular elements 8 form, and the top of the vertical cylindrical part 7 connects with the tail gas admission line 1, described vertical The bottom of tubular elements 7 connects with one end of the horizontal tubular elements 8, and the other end of the horizontal tubular elements 8 is in the defluorinate tower 3 Middle and lower part outer wall on connected with the inside of the defluorinate tower 3;At least two are provided with from top to bottom in the vertical cylindrical part 7 Washer spray gun 9, the middle and upper part in the defluorinate tower 3 are provided with least two defluorinate tower spray guns 10, the washing from top to bottom Device spray gun 9 connects with the milk of lime underground tank 4, and the defluorinate tower spray gun 10 is by circulating pump with being connected in the defluorinate tower 3; The top of the defluorinate tower 3 is connected by pipeline with the chimney 5.
Preferably, be provided with multiple baffle demister 23 in the chimney 5, the top of the defluorinate tower 3 by pipeline with it is described The multiple baffle demister 23 of chimney 5 connects.

Claims (8)

  1. A kind of 1. exhaust treatment system in glass furnace production, it is characterised in that:Including tail gas admission line(1), preheater (2), defluorinate tower(3), milk of lime underground tank(4)And chimney(5);The defluorinate tower(3)Tower wall on be provided with washer(6); The washer(6)For L-type, by vertical cylindrical part(7)With horizontal tubular elements(8)Composition, the vertical cylindrical part(7)Top With the tail gas admission line(1)Connection, the vertical cylindrical part(7)Bottom and the horizontal tubular elements(8)One end connect It is logical, the horizontal tubular elements(8)The other end in the defluorinate tower(3)Middle and lower part outer wall on the defluorinate tower(3)It is interior Portion connects;The vertical cylindrical part(7)In be provided with least two washer spray guns from top to bottom(9), the defluorinate tower(3)It is interior Middle and upper part be provided with least two defluorinate tower spray guns from top to bottom(10), the washer spray gun(9)With the milk of lime Lower groove(4)Connection, the defluorinate tower spray gun(10)Pass through circulating pump and the defluorinate tower(3)Interior connection;The defluorinate tower(3)'s Top passes through pipeline and the chimney(5)Connection.
  2. 2. the exhaust treatment system in a kind of glass furnace production according to claim 1, it is characterised in that:The level Tubular elements(8)Along the defluorinate tower(3)The tangent line of circle where cross section and the defluorinate tower(3)Connection.
  3. 3. the exhaust treatment system in a kind of glass furnace production according to claim 1, it is characterised in that:The preheating Device(2)It is arranged on the tail gas admission line(1)On, the preheater(2)Tail gas including being arranged side by side cools chamber in advance(11) With air heat-exchange chamber(12);The tail gas admission line(1)Cool in advance chamber by the tail gas(11), the air heat-exchange chamber (12)By air duct(13)Pass through;The tail gas admission line(1)With the air duct(13)Trend on the contrary, the sky Feed channel(13)By the air heat-exchange chamber(12)After go to glass furnace.
  4. 4. the exhaust treatment system in a kind of glass furnace production according to claim 1, it is characterised in that:The washing Device spray gun(9)And/or the defluorinate tower spray gun(10)All it is interlaced arrangement from top to bottom.
  5. 5. the exhaust treatment system in a kind of glass furnace production according to claim 1, it is characterised in that:The defluorinate Tower spray gun(10)Top be provided with wash tub pipe(14), the wash tub pipe(14)With the defluorinate tower spray gun(10)Between set It is equipped with demister(15).
  6. 6. the exhaust treatment system in a kind of glass furnace production according to claim 1, it is characterised in that:The defluorinate Tower(3)Internal bottom is provided with aerator(16), in the defluorinate tower(3)First is provided with the outer wall of internal liquid level position Liquid outlet(17), the aerator(16)The defluorinate tower of top(3)Second liquid outlet is provided with outer wall(18), institute State aerator(16)The defluorinate tower of lower section(3)The 3rd liquid outlet is provided with outer wall(19);First liquid outlet (17)Exported with second liquid(18)Pass through milk of lime underground tank described in pipeline communication respectively(4), the 3rd liquid outlet (19)Pass through pipeline communication thick slurry subsider(20), the thick slurry subsider(20)And with the milk of lime underground tank(4)Connection.
  7. 7. the exhaust treatment system in a kind of glass furnace production according to claim 1, it is characterised in that:The defluorinate Tower(3)Serum outlet is provided with the shell of bottom(21), the serum outlet(21)Pipe shell type heat exchange is connected by circulating pump Device(22), the shell-and-tube heat exchanger(22)Further through pipeline and the defluorinate tower spray gun(10)Connection.
  8. 8. the exhaust treatment system in a kind of glass furnace production according to claim 1, it is characterised in that:The chimney (5)In be provided with multiple baffle demister(23), the defluorinate tower(3)Top pass through pipeline and the chimney(5)The multiple gear Demister(23)Connection.
CN201721036956.2U 2017-08-18 2017-08-18 A kind of exhaust treatment system in glass furnace production Active CN207203835U (en)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111054205A (en) * 2020-02-28 2020-04-24 瓮福紫金化工股份有限公司 High-efficient fluorine recovery unit of wet process phosphoric acid
CN113587663A (en) * 2021-07-08 2021-11-02 河南安彩高科股份有限公司 Device is administered in well borosilicate medicinal glass kiln waste gas environmental protection

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111054205A (en) * 2020-02-28 2020-04-24 瓮福紫金化工股份有限公司 High-efficient fluorine recovery unit of wet process phosphoric acid
CN113587663A (en) * 2021-07-08 2021-11-02 河南安彩高科股份有限公司 Device is administered in well borosilicate medicinal glass kiln waste gas environmental protection

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