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CN111457414A - Flue gas reheating system and method with on-line desalination function - Google Patents

Flue gas reheating system and method with on-line desalination function Download PDF

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CN111457414A
CN111457414A CN202010275578.3A CN202010275578A CN111457414A CN 111457414 A CN111457414 A CN 111457414A CN 202010275578 A CN202010275578 A CN 202010275578A CN 111457414 A CN111457414 A CN 111457414A
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flue gas
tower
reheat
reheating
valve
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王建鑫
崔希岗
徐敏
林野
余卫东
王贵
朱少红
刘凯
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NORENDAR INTERNATIONAL Ltd
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    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23JREMOVAL OR TREATMENT OF COMBUSTION PRODUCTS OR COMBUSTION RESIDUES; FLUES 
    • F23J15/00Arrangements of devices for treating smoke or fumes
    • F23J15/08Arrangements of devices for treating smoke or fumes of heaters
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/002Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by condensation
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/001Processes for the treatment of water whereby the filtration technique is of importance
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/66Treatment of water, waste water, or sewage by neutralisation; pH adjustment
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23JREMOVAL OR TREATMENT OF COMBUSTION PRODUCTS OR COMBUSTION RESIDUES; FLUES 
    • F23J15/00Arrangements of devices for treating smoke or fumes
    • F23J15/06Arrangements of devices for treating smoke or fumes of coolers
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2258/00Sources of waste gases
    • B01D2258/02Other waste gases
    • B01D2258/0283Flue gases
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2103/00Nature of the water, waste water, sewage or sludge to be treated
    • C02F2103/18Nature of the water, waste water, sewage or sludge to be treated from the purification of gaseous effluents

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  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Mechanical Engineering (AREA)
  • General Engineering & Computer Science (AREA)
  • Water Supply & Treatment (AREA)
  • Environmental & Geological Engineering (AREA)
  • Hydrology & Water Resources (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • General Chemical & Material Sciences (AREA)
  • Analytical Chemistry (AREA)
  • Vaporization, Distillation, Condensation, Sublimation, And Cold Traps (AREA)
  • Treating Waste Gases (AREA)
  • Heat Treatment Of Water, Waste Water Or Sewage (AREA)

Abstract

The invention relates to a flue gas reheating system with an online desalting function and a method thereof, wherein the system comprises a circulating washing water tank, a wet washing tower arranged above the circulating washing water tank, a first reheating evaporation tower and a second reheating evaporation tower, the lower ends of which are communicated with the wet washing tower, a purified flue gas adjusting tower communicated with the upper ends of the first reheating evaporation tower and the second reheating evaporation tower, and a direct exhaust flue arranged above the purified flue gas adjusting tower, wherein one side of the lower part of the wet washing tower is provided with an incineration flue gas inlet; the invention creatively realizes that the salt concentration of the high-salinity wastewater is reduced, the online desalting is realized, the emission of flue gas is ensured to reach the standard, white smoke plume is eliminated, and the environmental perception is improved in one set of system.

Description

具有在线除盐功能的烟气再热系统及方法Flue gas reheating system and method with on-line desalination function

技术领域technical field

本发明涉及一种具有在线除盐功能的烟气再热系统及方法。The invention relates to a flue gas reheating system and method with on-line desalination function.

背景技术Background technique

目前国内外主流的危险废物焚烧工艺中,焚烧烟气的治理一般都包含有湿法洗涤除酸工艺。该工艺在焚烧烟气治理工艺流程中处在袋式除尘器后,烟气再热器之前。湿法洗涤工艺的主要作用是进一步去除焚烧烟气中含有的酸性气体、盐份或盐份物质、粉尘等。在采用湿法洗涤工艺进行除酸和颗粒物时,在洗涤塔下方设置循环水池,洗涤水与高温烟气换热并脱除烟气中酸性气体和颗粒物后,烟气温度降低,经过除雾后进入下一道治理工序;同时,洗涤水温度升高,通过换热器冷却后进入循环水池,循环水池中的水通过循环泵再喷入洗涤塔中洗涤烟气,以此循环使用。In the current mainstream hazardous waste incineration processes at home and abroad, the treatment of incineration flue gas generally includes a wet scrubbing and acid removal process. This process is located after the bag filter and before the flue gas reheater in the incineration flue gas treatment process. The main function of the wet scrubbing process is to further remove the acid gas, salt or salt material, dust, etc. contained in the incineration flue gas. When the wet scrubbing process is used to remove acid and particulate matter, a circulating water pool is set below the scrubbing tower. The washing water exchanges heat with the high-temperature flue gas and removes the acid gas and particulate matter in the flue gas. Enter the next treatment process; at the same time, the temperature of the washing water rises, and after being cooled by the heat exchanger, it enters the circulating water pool, and the water in the circulating water pool is sprayed into the washing tower through the circulating pump to wash the flue gas, so as to be recycled.

随着洗涤水循环洗涤烟气的次数增加,循环水池中的盐类物质(一般为氯化钠,氯化钙,硫酸钙等)含量逐渐增加,达到饱和后这些盐类物质便会结晶析出。在此情况下继续使用高盐洗涤水通过循环泵喷入洗涤塔洗涤烟气,会造成管道、喷头、塔体内壁等部位盐类物质结晶析出,堵塞管道、喷头,减小塔内体积从而增加烟气阻力等。As the number of times the flue gas is washed by the washing water cycle increases, the content of salts (usually sodium chloride, calcium chloride, calcium sulfate, etc.) in the circulating pool gradually increases, and these salts will crystallize out after reaching saturation. In this case, continue to use high-salt washing water to spray the flue gas into the washing tower through the circulating pump, which will cause the crystallization of salt substances in the pipeline, nozzle, inner wall of the tower, etc., blocking the pipeline and nozzle, reducing the volume of the tower and increasing the Smoke resistance, etc.

依据现行相关法规,此类废水及废盐属性仍为危险废物,而近些年有不法企业主为谋取非法利益、铤而走险,对该类废水进行厂内偷排。执法部门已制裁多家违法犯罪单位和人员。According to the current relevant laws and regulations, such waste water and waste salt are still hazardous waste, and in recent years, some unscrupulous business owners have secretly discharged this type of waste water in the factory in order to seek illegal benefits and take risks. Law enforcement agencies have sanctioned a number of illegal and criminal units and personnel.

目前所使用的方案有如下两种:There are two schemes currently in use:

方案一:国内部分工艺将此类高盐废水喷入前道工序的急冷塔,这种方式会造成急冷塔腐蚀、烟气管道腐蚀,烟气管道堵塞等情况,长期运行将导致产线停产甚至设备报废。Option 1: Some domestic processes spray such high-salt wastewater into the quenching tower of the previous process. This method will cause corrosion of the quenching tower, corrosion of flue gas pipes, blockage of flue gas pipes, etc. Long-term operation will cause the production line to stop production or even Equipment scrapped.

方案二:另有工艺,针对循环水池内高盐废水配置独立的高盐废水处理系统,目前有多效蒸发、膜浓缩、电化学、离子交换等技术,而实现规模化处理,被危废处置单位采用的主要是膜浓缩+多效蒸发相结合技术。通过配置沉淀池、超滤装置、蝶式反渗透膜组、多效蒸发结晶器、干燥器、管式换热器及配套泵组、泵站,通过对超滤和反渗透膜组的浓缩产水进行多效蒸发,最终制得干燥盐渣委外处理。该方案采用膜浓缩+多效蒸发相结合技术,暂时解决了高盐废水问题。但因该系统需要设计、采购、安装沉淀池、超滤装置、蝶式反渗透膜组、多效蒸发结晶器、干燥器、管式换热器及配套泵组、泵站等设备、管线,存在以下缺点:Option 2: Another process is to configure an independent high-salt wastewater treatment system for the high-salt wastewater in the circulating pool. At present, multi-effect evaporation, membrane concentration, electrochemistry, ion exchange and other technologies are used to achieve large-scale treatment and hazardous waste disposal. The unit mainly adopts the combined technology of membrane concentration + multi-effect evaporation. By configuring sedimentation tank, ultrafiltration device, butterfly reverse osmosis membrane group, multi-effect evaporation crystallizer, dryer, tubular heat exchanger and supporting pump group and pump station, through the concentrated production of ultrafiltration and reverse osmosis membrane group Water is subjected to multi-effect evaporation, and finally a dry salt residue is obtained for outsourcing treatment. The scheme adopts the combined technology of membrane concentration and multi-effect evaporation, which temporarily solves the problem of high-salt wastewater. However, because the system needs to design, purchase, and install sedimentation tanks, ultrafiltration devices, butterfly reverse osmosis membrane units, multi-effect evaporation crystallizers, dryers, tubular heat exchangers, and supporting pump sets, pump stations and other equipment and pipelines, The following disadvantages exist:

1、按洗涤水设计处理规模50t/d计算,装置投资成本约500万元,系统投资成本高;1. Calculated according to the design treatment scale of washing water of 50t/d, the investment cost of the device is about 5 million yuan, and the system investment cost is high;

2、占地空间约15m*12m*5m, 系统装置占地面积大;2. The floor space is about 15m*12m*5m, and the system device occupies a large area;

3、平均年用电量90*104 kW•h,年运行费用约50万元,运行能耗高;3. The average annual electricity consumption is 90*104 kW·h, the annual operating cost is about 500,000 yuan, and the operating energy consumption is high;

4、膜浓缩效率为70%,浓缩蒸发制盐效率低;4. The membrane concentration efficiency is 70%, and the concentration and evaporation salt production efficiency is low;

5、2-3个月需要进行系统清洗,系统清洗复杂,运维成本高。5. System cleaning is required for 2-3 months. The system cleaning is complicated and the operation and maintenance cost is high.

发明内容SUMMARY OF THE INVENTION

本发明所要解决的技术问题是提供一种具有在线除盐功能的烟气再热系统及方法,可以解决使用洗涤循环水喷入洗涤塔洗涤烟气,循环水池中的盐类物质逐渐增加形成高盐废水,达到饱和后便会结晶析出的问题。The technical problem to be solved by the present invention is to provide a flue gas reheating system and method with on-line desalination function, which can solve the problem of using washing circulating water to spray into the washing tower to wash the flue gas, and the salt substances in the circulating water pool gradually increase to form high The salt water will crystallize after reaching saturation.

本发明所采用的技术方案是:The technical scheme adopted in the present invention is:

一种具有在线除盐功能的烟气再热系统,其包括循环洗涤水池、设置在循环洗涤水池上方的湿法洗涤塔、下端与湿法洗涤塔连通的第一再热蒸发塔和第二再热蒸发塔、与第一再热蒸发塔和第二再热蒸发塔上端连通的净化烟气调节塔以及设置在净化烟气调节塔上方的直排烟道,在湿法洗涤塔的下部一侧设置有焚烧烟气进口。A flue gas reheating system with on-line desalination function, which comprises a circulating washing pool, a wet scrubbing tower arranged above the circulating washing pool, a first reheating evaporation tower and a second reheating tower whose lower end communicates with the wet scrubbing tower. The thermal evaporation tower, the purification flue gas conditioning tower connected with the upper ends of the first reheat evaporation tower and the second reheat evaporation tower, and the straight exhaust flue set above the purification flue gas conditioning tower, are on the lower side of the wet scrubbing tower A combustion flue gas inlet is provided.

进一步的,在所述循环洗涤水池上通过管路连接有过滤装置。Further, a filter device is connected to the circulating washing pool through a pipeline.

进一步的,所述第一再热蒸发塔包括沿烟气流动方向依次设置的第一电动烟气切断阀C、第一除盐部装、第一加热装置、第一压差探测器、第一温度探测器、第一清盐风机以及第一电动烟气切断阀B,在所述第一清盐风机的进风管路上设置有第一电动烟气切断阀A。Further, the first reheat evaporation tower includes a first electric flue gas cut-off valve C, a first desalination unit, a first heating device, a first differential pressure detector, a first The temperature detector, the first salt-cleaning fan and the first electric flue gas cut-off valve B are provided with a first electric flue gas cut-off valve A on the air inlet pipeline of the first salt-cleaning fan.

进一步的,所述第二再热蒸发塔包括沿烟气流动方向依次设置的第二电动烟气切断阀C、第二除盐部装、第二加热装置、第二压差探测器、第二温度探测器、第二清盐风机以及第二电动烟气切断阀B,在所述第二清盐风机的进风管路上设置有第二电动烟气切断阀A。Further, the second reheat evaporation tower includes a second electric flue gas cut-off valve C, a second desalination unit, a second heating device, a second differential pressure detector, a second The temperature detector, the second salt cleaning fan and the second electric flue gas cut-off valve B are provided with a second electric flue gas cut-off valve A on the air inlet pipeline of the second salt cleaning fan.

进一步的,在所述湿法洗涤塔的上部设有第三温度探测器。Further, a third temperature detector is arranged on the upper part of the wet scrubbing tower.

进一步的,所述第一加热装置包括沿烟气流动方向依次设置的第一初效再热蒸发器和第一二效再热蒸发器。Further, the first heating device includes a first primary effect reheat evaporator and a first second effect reheat evaporator arranged in sequence along the flue gas flow direction.

进一步的,所述第二加热装置包括沿烟气流动方向依次设置的第二初效再热蒸发器和第二二效再热蒸发器。Further, the second heating device includes a second primary effect reheat evaporator and a second second effect reheat evaporator arranged in sequence along the flue gas flow direction.

进一步的,所述净化烟气调节塔包括冷凝回用水收集装置、降温装置以及第四温度探测器,所述冷凝回用水收集装置位于降温装置的下方并且与循环洗涤水池连通,第四温度探测器位于降温装置的上方。Further, the purifying flue gas conditioning tower includes a condensing and recycling water collection device, a cooling device and a fourth temperature detector, the condensation and recycling water collection device is located below the cooling device and communicated with the circulating washing pool, and the fourth temperature detector above the cooling device.

进一步的,所述过滤装置为活性炭过滤罐,在活性炭过滤罐的进罐管路上设有加压水泵。Further, the filtering device is an activated carbon filter tank, and a pressurized water pump is provided on the tank inlet pipeline of the activated carbon filter tank.

一种具有在线除盐功能的烟气再热方法,其包括如下步骤:A flue gas reheating method with on-line desalination function, comprising the steps of:

步骤一、关闭第二电动烟气切断阀C、第二电动烟气切断阀B、第一电动烟气切断阀A以及第一清盐风机,打开第一电动烟气切断阀C、第一电动烟气切断阀B,使第一再热蒸发塔处于工作状态,循环洗涤水池内的循环水喷淋至湿法洗涤塔内,完成湿法洗涤焚烧烟气;Step 1. Close the second electric flue gas shut-off valve C, the second electric flue gas shut-off valve B, the first electric flue gas shut-off valve A and the first salt-cleaning fan, and open the first electric flue gas shut-off valve C, the first electric flue gas shut-off valve The flue gas cut-off valve B makes the first reheat evaporation tower in working state, and the circulating water in the circulating washing pool is sprayed into the wet washing tower to complete the wet washing and incineration of flue gas;

步骤二、循环洗涤水落入循环洗涤水池,通过加注碱液调节pH至弱碱性,同时池中的循环水通过水泵抽至过滤装置过滤,过滤颗粒物及杂质,制得循环洗涤水池内的高盐废水;Step 2: The circulating washing water falls into the circulating washing pool, and the pH is adjusted to weakly alkaline by adding lye. At the same time, the circulating water in the pool is pumped by the water pump to the filter device for filtration, and the particulate matter and impurities are filtered to obtain the circulating washing pool. High-salt wastewater;

步骤三、洗涤烟气进入第一再热蒸发塔,经第一初效再热蒸发器和第一二效再热蒸发器完成烟气加热蒸发及废盐结晶,进入净化烟气调节塔;Step 3, the washed flue gas enters the first reheating evaporation tower, completes the heating and evaporation of flue gas and the crystallization of waste salt through the first primary effect reheating evaporator and the first second effect reheating evaporator, and enters the purification flue gas conditioning tower;

步骤四、加热后的烟气经净化烟气调节塔内的降温装置,完成烟气降温冷凝,经直排烟道达标排放;Step 4. The heated flue gas is passed through the cooling device in the purification flue gas adjustment tower to complete the cooling and condensation of the flue gas, and is discharged up to the standard through the straight exhaust flue;

步骤五、步骤四降温产生的冷凝水落入设在净化烟气调节塔底部的冷凝回用水收集装置,经管路流至循环洗涤水池内回用;当第一再热蒸发塔内压差探测器探测显示压差大于Pa时,确定达到除盐要求;The condensed water produced in step 5 and step 4 falls into the condensed and reused water collection device located at the bottom of the purification flue gas conditioning tower, and flows to the circulating washing pool for reuse through the pipeline; when the pressure difference detector in the first reheating evaporation tower When the detection shows that the pressure difference is greater than Pa, it is determined that the desalination requirements are met;

步骤六:第一再热蒸发塔进入除盐状态,取出第二除盐插板关闭第二除盐部装,第二初效再热蒸发器和第二二效再热蒸发器内通入相应蒸汽,打开第二电动烟气切断阀C、第二电动烟气切断阀B、第一电动烟气切断阀A,关闭第一电动烟气切断阀C、第一电动烟气切断阀B、第二电动烟气切断阀A,完成湿法洗涤的焚烧烟气进入第二再热蒸发塔,在第二再热蒸发塔内重现步骤一至五;Step 6: The first reheating evaporation tower enters the demineralization state, take out the second demineralization insert and close the second demineralization unit, and the second primary effect reheating evaporator and the second second effect reheating evaporator Steam, open the second electric flue gas shut-off valve C, the second electric flue gas shut-off valve B, the first electric flue gas shut-off valve A, close the first electric flue gas shut-off valve C, the first electric flue gas shut-off valve B, the 2. Electric flue gas cut-off valve A, the incineration flue gas after wet scrubbing enters the second reheat evaporation tower, and steps 1 to 5 are repeated in the second reheat evaporation tower;

步骤七:第一温度探测器显示降温后,打开第一除盐部装,放入第一除盐插板,第一初效再热蒸发器和第一二效再热蒸发器内通入蒸汽,启动第一除盐风机通入干燥热风,对第一再热蒸发塔内进行除盐,当第一再热蒸发塔内第一压差探测器探测显示压差小于Pa时,确定除盐完成;Step 7: After the first temperature detector shows that the temperature is lowered, open the first demineralization unit, put in the first demineralization insert, and pass steam into the first primary effect reheat evaporator and the first second effect reheat evaporator , start the first demineralizing fan to pass in hot dry air, and demineralize the first reheating evaporation tower. When the first pressure difference detector in the first reheating evaporation tower detects that the pressure difference is less than Pa, it is determined that the demineralization is completed. ;

步骤八:关闭第一除盐风机、第一电动烟气切断阀A,切断第一初效再热蒸发器和第一二效再热蒸发器内的蒸汽;Step 8: Turn off the first desalination fan and the first electric flue gas cut-off valve A, and cut off the steam in the first primary effect reheat evaporator and the first second effect reheat evaporator;

步骤九:经冷却,第一温度探测器显示降温后,打开第一除盐部装取出除盐插板随后立即关闭除盐部装,收集废盐并处理,此时完成第一再热蒸发塔除盐工作,进入准工作状态;Step 9: After cooling, after the first temperature detector shows that the temperature has dropped, open the first demineralizing unit and take out the demineralizing insert, then immediately close the demineralizing unit, collect the waste salt and process it, at this time, the first reheating evaporation tower is completed. Desalination work, enter the quasi-working state;

步骤十:当第二再热蒸发塔显示达到除盐状态时,针对第二再热蒸发塔按照相同原理重复步骤六-步骤九,第一再热蒸发塔和第二再热蒸发塔如此循环更替作业,实现在线除盐的烟气再热。Step 10: When the second reheating evaporation tower shows that it has reached the desalting state, repeat steps six to nine according to the same principle for the second reheating evaporation tower, and the first reheating evaporation tower and the second reheating evaporation tower are replaced in this way operation to realize flue gas reheating for on-line desalination.

本发明的积极效果为:The positive effects of the present invention are:

一、本发明创造性的实现了在一套系统内既降低高盐废水的含盐浓度,实现在线除盐,同时保证烟气排放达标,消除白色烟羽,提升环境感观。1. The present invention creatively realizes that in one system, the salt concentration of high-salt wastewater can be reduced, the on-line desalination can be realized, and the flue gas emission can be guaranteed to meet the standard, the white smoke plume can be eliminated, and the environmental perception can be improved.

二、巧妙利用两级再热蒸发进行加热烟气、蒸发水蒸气、析出废盐,再通过降温装置降低烟气温度、凝结蒸汽回用,节省了目前主流需单独配置的膜浓缩+多效蒸发技术相结合的高盐废水处理系统的高昂采购及后期运维费用,最大限度降低能源消耗,有效回用水资源,节省了大量投资和运行成本。2. Ingeniously use two-stage reheat evaporation to heat flue gas, evaporate water vapor, and precipitate waste salt, and then reduce the temperature of flue gas and condense steam through a cooling device, saving the current mainstream need to be configured separately. Membrane concentration + multi-effect evaporation The high procurement and later operation and maintenance costs of the high-salt wastewater treatment system combined with the technology minimize energy consumption, effectively reuse water resources, and save a lot of investment and operating costs.

三、通过创新性的结构设计,利用两台再热蒸发塔并联,实现不停产的在线除盐,避免膜浓缩+多效蒸发相结合技术的2-3个月进行系统清理以及回喷技术中因除盐产线停产及设备报废的隐患。3. Through innovative structural design, two reheating evaporation towers are used in parallel to achieve non-stop online desalination, avoiding the 2-3 months of system cleaning and back-spraying technology of the combined technology of membrane concentration and multi-effect evaporation. Due to the hidden danger of demineralization production line shutdown and equipment scrapping.

四、通过系统配置的探测器及自动控制系统,系统仅在线除盐时需要人工参与,仅对除盐部装进行简单操作,提高了系统的安全性、稳定性,降低了操作人员的维护难度和劳动强度。4. Through the detector and automatic control system configured in the system, the system only needs manual participation during online desalination, and only simple operations are performed on the desalination unit, which improves the safety and stability of the system and reduces the maintenance difficulty for operators. and labor intensity.

附图说明Description of drawings

图1为本发明系统流程图;Fig. 1 is the system flow chart of the present invention;

图2为本发明第一再热蒸发塔处于工作状态时的结构示意图;Fig. 2 is the structural representation when the first reheat evaporation tower of the present invention is in the working state;

图3为本发明第一再热蒸发塔处于除盐状态时的结构示意图。3 is a schematic structural diagram of the first reheat evaporation tower of the present invention when it is in a demineralized state.

具体实施方式Detailed ways

如附图1-3所示,本发明的系统包括循环洗涤水池100、过滤装置200、湿法洗涤塔300、第一再热蒸发塔400、第二再热蒸发塔500、净化烟气调节塔600以及直排烟道700。As shown in Figures 1-3, the system of the present invention includes a circulating washing pool 100, a filtering device 200, a wet scrubbing tower 300, a first reheat evaporation tower 400, a second reheat evaporation tower 500, and a purification flue gas conditioning tower 600 and straight flue 700.

循环洗涤水池100通过管路连接过滤装置200,第一再热蒸发塔400和第二再热蒸发塔500并联设置,其下端分别与湿法洗涤塔300上部出口连通,其上端出口分别与净化烟气调节塔600的下部进口连接,净化烟气调节塔600的上部出口与直排烟道700相连。在湿法洗涤塔300的下部一侧设置有焚烧烟气进口,在其上部设有第三温度探测器310。The circulating washing pool 100 is connected to the filtering device 200 through pipelines, the first reheat evaporation tower 400 and the second reheat evaporation tower 500 are arranged in parallel, the lower ends thereof are respectively connected with the upper outlet of the wet scrubbing tower 300, and the upper end outlets are respectively connected with the purified smoke The lower inlet of the gas conditioning tower 600 is connected, and the upper outlet of the purification flue gas conditioning tower 600 is connected with the straight exhaust flue 700 . A combustion flue gas inlet is arranged on the lower side of the wet scrubbing tower 300, and a third temperature detector 310 is arranged on the upper portion thereof.

循环洗涤水池100中的循环水通过水泵加压抽至过滤装置200过滤,去除颗粒杂质的活性炭过滤水通过出罐管路返回循环洗涤水池100。在本实施例中,过滤装置200采用活性炭过滤罐,也可以是其他的初效或高效过滤装置,如超滤、砂滤、膜过滤等技术。The circulating water in the circulating washing pool 100 is pumped to the filter device 200 by the water pump for filtration, and the activated carbon filtered water with the particulate impurities removed is returned to the circulating washing pool 100 through the tank outlet pipeline. In this embodiment, the filter device 200 adopts an activated carbon filter tank, and may also be other primary or high-efficiency filter devices, such as ultrafiltration, sand filtration, membrane filtration and other technologies.

循环洗涤水池100设置于危险废物焚烧烟气湿法洗涤塔300下方,循环洗涤水池100中设有在线pH分析仪和液位计,具有pH调节系统和液位控制系统;循环洗涤水池100与过滤装置200通过管路连接形成循环管路,过滤装置的进液管路设有加压水泵。The circulating washing pool 100 is arranged below the hazardous waste incineration flue gas wet scrubbing tower 300. The circulating washing pool 100 is provided with an online pH analyzer and a liquid level gauge, and has a pH adjustment system and a liquid level control system; The device 200 is connected by pipelines to form a circulation pipeline, and the liquid inlet pipeline of the filtering device is provided with a pressurized water pump.

在湿法洗涤塔300的上部有两个出口,分别通过法兰与第一再热蒸发塔400和第二再热蒸发塔500连接。There are two outlets in the upper part of the wet scrubbing tower 300, which are respectively connected to the first reheat evaporation tower 400 and the second reheat evaporation tower 500 through flanges.

第一再热蒸发塔400包括沿烟气流动方向依次设置的第一电动烟气切断阀C410、第一第一除盐部装420、第一加热装置、第一第一压差探测器450、第一第一温度探测器460、第一第一清盐风机480以及第一电动烟气切断阀B490,第一第一清盐风机480通过管路与第一再热蒸发塔400的塔身连通,在该管路上设置有第一电动烟气切断阀A470,在第一第一除盐部装420处可安装第一除盐插板421。The first reheating evaporation tower 400 includes a first electric flue gas cut-off valve C410, a first first desalination unit 420, a first heating device, a first first differential pressure detector 450, The first first temperature detector 460, the first first salt cleaning fan 480 and the first electric flue gas cut-off valve B490, the first first salt cleaning fan 480 is communicated with the tower body of the first reheat evaporation tower 400 through pipelines , a first electric flue gas cut-off valve A470 is arranged on the pipeline, and a first demineralization insert plate 421 can be installed at the first demineralization part 420.

第二再热蒸发塔500包括沿烟气流动方向依次设置的第二电动烟气切断阀C510、第二除盐部装520、第二加热装置、第二第二压差探测器550、第二温度探测器560、第二清盐风机580以及第二电动烟气切断阀B590,所述第二清盐风机580通过管路与第二再热蒸发塔500的塔身连通,在该管路上设置有第二电动烟气切断阀A570,在第二除盐部装520位置处安装有第二除盐插板521。The second reheating evaporation tower 500 includes a second electric flue gas cut-off valve C510, a second desalination unit 520, a second heating device, a second second pressure difference detector 550, a second second pressure difference detector 550, a second The temperature detector 560, the second salt cleaning fan 580 and the second electric flue gas cut-off valve B590, the second salt cleaning fan 580 is communicated with the tower body of the second reheat evaporation tower 500 through a pipeline, and the pipeline is provided with There is a second electric flue gas cut-off valve A570, and a second demineralization insert plate 521 is installed at the position of the second demineralization part 520.

第一加热装置包括沿烟气流动方向依次设置的第一第一初效再热蒸发器430和第一第一二效再热蒸发器440,第二加热装置包括沿烟气流动方向依次设置的第二初效再热蒸发器530和第二二效再热蒸发器540。The first heating device includes a first first primary effect reheating evaporator 430 and a first first second effect reheating evaporator 440 arranged in sequence along the flue gas flow direction, and the second heating device includes sequentially arranged along the flue gas flow direction. The second primary effect reheat evaporator 530 and the second second effect reheat evaporator 540 .

第一再热蒸发塔400和第二再热蒸发塔500的上部出口通过法兰与净化烟气调节塔600的下部入口连接,所述净化烟气调节塔600包括冷凝回用水收集装置610、降温装置620以及第四第四温度探测器630,所述冷凝回用水收集装置610位于降温装置620的下方并且与循环洗涤水池100连通,第四第四温度探测器630位于降温装置620的上方。具体来讲,冷凝回用水收集装置610的位置应略低于第一再热蒸发塔400、第二再热蒸发塔500与净化烟气调节塔600的连接位置,以便于收集。The upper outlets of the first reheat evaporation tower 400 and the second reheat evaporation tower 500 are connected to the lower inlet of the purification flue gas conditioning tower 600 through flanges. The device 620 and the fourth and fourth temperature detectors 630 , the condensation and reuse water collection device 610 is located below the cooling device 620 and communicated with the circulating washing pool 100 , and the fourth and fourth temperature detectors 630 are located above the cooling device 620 . Specifically, the position of the condensed and recycled water collection device 610 should be slightly lower than the connection position of the first reheat evaporation tower 400, the second reheat evaporation tower 500 and the purification flue gas conditioning tower 600 to facilitate collection.

本发明的关键在于循环洗涤水池100设置于危险废物焚烧烟气湿法洗涤塔300下方,池中的水主要用来循环洗涤危险废物焚烧烟气,去除烟气中的酸性气体和颗粒物。The key of the present invention is that the circulating washing pool 100 is arranged below the hazardous waste incineration flue gas wet scrubbing tower 300, and the water in the pool is mainly used to circulate and wash the hazardous waste incineration flue gas to remove acid gas and particulate matter in the flue gas.

焚烧烟气经湿法洗涤塔300下部的焚烧烟气进口进入塔内上升,循环洗涤水池100中的循环洗涤水经过管路向塔内喷射循环洗涤水中和烟气酸性物质,湿法洗涤塔300上部设有温度探测器310,通过探测塔内烟气温度调整洗涤水用量,降低并控制烟气温度在100℃-110℃之间,形成洗涤烟气,其中颗粒物等杂质落入循环洗涤水池100,洗涤烟气裹挟含盐水蒸汽继续上升进入第一再热蒸发塔400或第二再热蒸发塔500;湿法洗涤塔300采用高温玻璃钢制作,具有耐火、耐高温性能;第一再热蒸发塔400或第二再热蒸发塔500本体及第一、第二初效再热蒸发器以及第一、第二二效再热蒸发器均采用导热性好、耐腐性强的不锈钢制作,塔体外侧做保温处理。The incineration flue gas enters the tower through the incineration flue gas inlet at the lower part of the wet scrubbing tower 300 and rises, and the circulating scrubbing water in the circulating scrubbing pool 100 sprays the circulating scrubbing water and flue gas acid substances into the tower through the pipeline, and the upper part of the wet scrubbing tower 300 A temperature detector 310 is provided, the amount of washing water is adjusted by detecting the temperature of the flue gas in the tower, and the temperature of the flue gas is reduced and controlled between 100°C and 110°C to form washing flue gas, in which impurities such as particulate matter fall into the circulating washing pool 100, The scrubbing flue gas continues to rise into the first reheating evaporation tower 400 or the second reheating evaporation tower 500 entrained by the brine steam; the wet scrubbing tower 300 is made of high-temperature glass fiber reinforced plastic, which has fire resistance and high temperature resistance; the first reheating evaporation tower 400 Or the body of the second reheating evaporation tower 500, the first and second primary effect reheating evaporators and the first and second second effect reheating evaporators are all made of stainless steel with good thermal conductivity and strong corrosion resistance. Do insulation treatment.

本系统在使用时,两个再热蒸发塔不同时工作,本实施例中,以烟气进入第一再热蒸发塔400,而第二再热蒸发塔处于非工作状态为例进行说明。When the system is in use, the two reheat evaporation towers do not work at the same time. In this embodiment, the flue gas enters the first reheat evaporation tower 400 and the second reheat evaporation tower is in a non-working state as an example for description.

如附图2所示,第一再热蒸发塔400处于工作状态,第二再热蒸发塔500作为非工作状态(除盐或关闭状态);第一电动烟气切断阀C410处于打开状态,第一除盐部装420处于关闭状态,洗涤烟气进入第一再热蒸发塔400到达第一初效再热蒸发器430和第一二效再热蒸发器440,第一初效再热蒸发器430和第一二效再热蒸发器440内由进气管路通入高温蒸汽,经与换热管束加热洗涤烟气,换热管束内高温蒸汽降温形成冷凝蒸汽经出气管路排出,洗涤烟气经再热其裹挟的水蒸气蒸发,溶解在水蒸气内的废盐被析出结晶附着在换热管束外壁;第一电动烟气切断阀A470和第一清盐风机480均处于关闭状态、第一电动烟气切断阀B490处于打开状态,洗涤烟气经再热蒸发工艺形成加热烟气继续上升,处于第一二效再热蒸发器440上部的第一压差探测器450具有对塔内再热蒸发前后的烟气压差进行探测的功能,便于对塔内烟气流速调节控制和判断第一再热蒸发塔400是否应进行除盐工作,根据实践经验大于1000Pa需要进行除盐;处于第一压差探测器450上部的第一温度探测器460具有对塔内烟气温度进行探测的功能,用于对塔内烟气温度的控制并保证塔内烟气所裹挟的水蒸气内溶解的废盐析出结晶,根据实践经验调整在140℃-160℃。随后加热烟气在塔内沿管道通过法兰接口进入净化烟气调节塔600,净化烟气调节塔600内设有降温装置620,当加热烟气经过降温装置620,其进口管路通有冷凝水的降温装置620换热管束在管道内与加热烟气进行热交换,换热管束内的冷凝水经加热排出降温装置620换热管束,加热烟气沿管道继续上升,降温装置620上方设有第四温度探测器630,用于对塔内烟气温度和降温装置620内冷凝水循环水量的控制,根据实践经验调整在60℃-80℃,加热烟气在上升过程通过热交换,凝结的冷凝水落入设在净化烟气调节塔600底部的冷凝回用水收集装置610,收集的冷凝回用水经管路回流至循环洗涤水池100继续用于烟气洗涤;而上升的加热烟气进行降温后达标排放,既能降低能源消耗,有效利用循环洗涤水,同时保证烟气排放温度,消除白色烟羽,提升环境感观。As shown in FIG. 2, the first reheat evaporation tower 400 is in the working state, the second reheat evaporation tower 500 is in the non-working state (desalting or closed state); the first electric flue gas cut-off valve C410 is in the open state, and the The first demineralization unit 420 is in a closed state, and the scrubbing flue gas enters the first reheat evaporation tower 400 to reach the first primary effect reheat evaporator 430 and the first second effect reheat evaporator 440, and the first primary effect reheat evaporator 440. 430 and the first two-effect reheat evaporator 440 are introduced into high-temperature steam through the air inlet pipe, and the flue gas is heated and washed with the heat exchange tube bundle. After reheating, the water vapor entrained in it evaporates, and the waste salt dissolved in the water vapor is precipitated and crystallized and attached to the outer wall of the heat exchange tube bundle; The electric flue gas cut-off valve B490 is in the open state, and the scrubbing flue gas is formed by the reheat evaporation process to form heated flue gas and continues to rise. The function of detecting the difference in flue gas pressure before and after evaporation is convenient for adjusting and controlling the flow rate of flue gas in the tower and judging whether the first reheating evaporation tower 400 should be demineralized. The first temperature detector 460 on the upper part of the differential pressure detector 450 has the function of detecting the temperature of the flue gas in the tower, which is used to control the temperature of the flue gas in the tower and ensure the dissolved waste gas in the water vapor entrained by the flue gas in the tower. The salt precipitates and crystallizes, and it is adjusted at 140℃-160℃ according to practical experience. Subsequently, the heated flue gas enters the purified flue gas conditioning tower 600 through the flange interface along the pipeline in the tower. The purified flue gas conditioning tower 600 is provided with a cooling device 620. When the heated flue gas passes through the cooling device 620, the inlet pipeline is connected to a condenser. The heat exchange tube bundle of the water cooling device 620 conducts heat exchange with the heating flue gas in the pipeline, the condensed water in the heat exchange tube bundle is heated and discharged from the heat exchange tube bundle of the cooling device 620, and the heated flue gas continues to rise along the pipeline. The fourth temperature detector 630 is used to control the temperature of the flue gas in the tower and the circulating water volume of the condensed water in the cooling device 620. According to practical experience, it is adjusted at 60°C-80°C. The heating flue gas passes heat exchange during the rising process, and the condensation of condensation The water falls into the condensed and recycled water collection device 610 located at the bottom of the purification flue gas conditioning tower 600, and the collected condensed and recycled water is returned to the circulating washing pool 100 through the pipeline to continue to be used for flue gas washing; and the rising heating flue gas reaches the standard after cooling. It can not only reduce energy consumption, effectively use circulating washing water, but also ensure the temperature of flue gas discharge, eliminate white smoke plumes, and improve environmental perception.

第二再热蒸发塔500结构形式及配置同于第一再热蒸发塔400,此时其处于除盐状态或关闭状态,第二电动烟气切断阀C510、第二电动烟气切断阀B590和第二电动烟气切断阀A570均处于关闭状态,除盐时第二除盐部装520盲板打开放入第二除盐插板521,第二初效再热蒸发器530和第二二效再热蒸发器540内通有高温蒸汽,经高温加热便于附着在换热管束外壁的废盐融化脱落,设置在第二二效再热蒸发器540上方的第二压差探测器550和第二温度探测器560用于探测塔内压差和温度。第二电动烟气切断阀A570处于打开位置,将清盐风机580打开通入干燥风进行吹扫清盐,当第二压差探测器550显示两探测位置压差小于100Pa时确定清盐完成,关闭第二电动烟气切断阀A570和第二清盐风机580,将第二除盐插板521取出收集废盐并委外处理;将第二除盐部装520恢复至工作状态,至此第二再热蒸发塔500完成清盐工作进入准工作状态,随时打开第二电动烟气切断阀C510和第二电动烟气切断阀B590即可进入工作状态。第一再热蒸发塔400和第二再热蒸发塔500如此循环更替形成在线除盐的烟气再热系统。The structure and configuration of the second reheat evaporation tower 500 are the same as those of the first reheat evaporation tower 400. At this time, it is in a desalination state or a closed state. The second electric flue gas cut-off valve C510, the second electric flue gas cut-off valve B590 and the The second electric flue gas cut-off valve A570 is in the closed state. When desalting, the blind plate 520 of the second desalting part is opened and put into the second desalting insert plate 521. The second primary effect reheat evaporator 530 and the second secondary effect The reheat evaporator 540 is filled with high-temperature steam, and the waste salt attached to the outer wall of the heat exchange tube bundle is easy to melt and fall off after being heated at a high temperature. Temperature detector 560 is used to detect differential pressure and temperature in the tower. The second electric flue gas cut-off valve A570 is in the open position, and the salt cleaning fan 580 is turned on to let in the drying air to clean the salt. When the second differential pressure detector 550 shows that the pressure difference between the two detection positions is less than 100Pa, it is determined that the salt cleaning is completed. Close the second electric flue gas cut-off valve A570 and the second salt cleaning fan 580, take out the second demineralization insert 521 to collect waste salt and outsource the treatment; restore the second demineralization unit 520 to the working state, so far the second The reheat evaporation tower 500 completes the salt cleaning work and enters the quasi-working state, and the second electric flue gas cut-off valve C510 and the second electric flue gas cut-off valve B590 can be opened at any time to enter the working state. The first reheat evaporating tower 400 and the second reheat evaporating tower 500 are cyclically replaced in this way to form a flue gas reheating system for on-line desalination.

利用本发明的系统进行工作的方法具体包括如下步骤:The method that utilizes the system of the present invention to work specifically comprises the following steps:

S01、如附图2所示,关闭第二电动烟气切断阀C510、第二电动烟气切断阀B590、第一电动烟气切断阀A470以及第一清盐风机480,打开第一电动烟气切断阀C410、第一电动烟气切断阀B490,使第一再热蒸发塔400处于工作状态,循环洗涤水池100内的循环水喷淋至湿法洗涤塔300内,完成湿法洗涤焚烧烟气,洗涤烟气温度控制在100℃-110℃之间;S01, as shown in FIG. 2, close the second electric flue gas shut-off valve C510, the second electric flue gas shut-off valve B590, the first electric flue gas shut-off valve A470 and the first salt cleaning fan 480, and open the first electric flue gas The cut-off valve C410 and the first electric flue gas cut-off valve B490 make the first reheat evaporation tower 400 in the working state, and the circulating water in the circulating washing pool 100 is sprayed into the wet washing tower 300 to complete the wet washing of the incineration flue gas , the temperature of the scrubbing flue gas is controlled between 100°C and 110°C;

S02、循环洗涤水落入循环洗涤水池100,通过加注碱液调节pH至弱碱性,同时池中的循环水通过水泵抽至过滤装置200过滤,过滤颗粒物及杂质,制得循环洗涤水池内的高盐废水;S02, the circulating washing water falls into the circulating washing pool 100, and the pH is adjusted to weakly alkaline by adding lye. At the same time, the circulating water in the pool is pumped to the filter device 200 by the water pump for filtering, and the particulate matter and impurities are filtered, and the circulating washing pool is obtained. of high-salt wastewater;

S03、洗涤烟气进入第一再热蒸发塔400,经第一初效再热蒸发器430和第一二效再热蒸发器440完成烟气加热蒸发及废盐结晶,进入净化烟气调节塔600, 加热烟气温度控制在140℃-160℃之间;S03, the washed flue gas enters the first reheating evaporation tower 400, completes the heating and evaporation of flue gas and the crystallization of waste salt through the first primary effect reheating evaporator 430 and the first second effect reheating evaporator 440, and enters the purification flue gas conditioning tower 600, the temperature of the heating flue gas is controlled between 140℃-160℃;

S04、加热后的烟气经净化烟气调节塔600内的降温装置620,完成烟气降温冷凝,降温烟气温度控制在60℃-80℃之间,经直排烟道700达标排放;S04, the heated flue gas is passed through the cooling device 620 in the purification flue gas conditioning tower 600 to complete the cooling and condensation of the flue gas, and the temperature of the cooled flue gas is controlled between 60°C and 80°C, and is discharged up to the standard through the straight exhaust flue 700;

S05、S04降温产生的冷凝水落入设在净化烟气调节塔600底部的冷凝回用水收集装置610,经管路流至循环洗涤水池100内回用;当第一再热蒸发塔400内压差探测器450探测显示压差大于1000Pa时,确定达到除盐要求;The condensed water produced by cooling in S05 and S04 falls into the condensed and recycled water collection device 610 located at the bottom of the purification flue gas conditioning tower 600, and flows to the circulating washing pool 100 for reuse through the pipeline; when the pressure difference in the first reheating evaporation tower 400 When the detector 450 detects and shows that the pressure difference is greater than 1000Pa, it is determined that the desalination requirement is met;

S06:如附图3所示,第一再热蒸发塔400进入除盐状态,取出第二除盐插板521关闭第二除盐部装520,第二初效再热蒸发器530和第二二效再热蒸发器540内通入相应蒸汽,打开第二电动烟气切断阀C510、第二电动烟气切断阀B590、第一电动烟气切断阀A470,关闭第一电动烟气切断阀C410、第一电动烟气切断阀B490、第二电动烟气切断阀A570,完成湿法洗涤的焚烧烟气进入第二再热蒸发塔500,在第二再热蒸发塔500内重现S01-S05;S06: As shown in FIG. 3, the first reheat evaporation tower 400 enters the demineralization state, and the second demineralization insert 521 is taken out to close the second demineralization unit 520, the second primary effect reheat evaporator 530 and the second Corresponding steam is introduced into the second-effect reheat evaporator 540, the second electric flue gas shut-off valve C510, the second electric flue gas shut-off valve B590, the first electric flue gas shut-off valve A470 are opened, and the first electric flue gas shut-off valve C410 is closed. , the first electric flue gas cut-off valve B490, the second electric flue gas cut-off valve A570, the incineration flue gas that has completed the wet washing enters the second reheat evaporation tower 500, and reproduces S01-S05 in the second reheat evaporation tower 500 ;

S07:经自然冷却,第一温度探测器460显示降温后,打开第一除盐部装420,放入第一除盐插板421,第一初效再热蒸发器430和第一二效再热蒸发器440内通入蒸汽,启动第一除盐风机480通入干燥热风,对第一再热蒸发塔400内进行除盐,当第一再热蒸发塔400内第一压差探测器450探测显示压差小于100Pa时,确定除盐完成;S07: After natural cooling, after the first temperature detector 460 shows that the temperature is lowered, open the first demineralization unit 420, put in the first demineralization insert 421, the first primary reheating evaporator 430 and the first secondary effect reheating Steam is introduced into the thermal evaporator 440, and the first demineralization fan 480 is activated to introduce hot dry air to demineralize the first reheat evaporation tower 400. When the first pressure difference detector 450 in the first reheat evaporation tower 400 When the detection shows that the pressure difference is less than 100Pa, it is determined that the desalination is completed;

S08:关闭第一除盐风机480、第一电动烟气切断阀A470,切断第一初效再热蒸发器430和第一二效再热蒸发器440内的蒸汽;S08: Turn off the first desalination fan 480 and the first electric flue gas cut-off valve A470, and cut off the steam in the first primary-effect reheat evaporator 430 and the first second-effect reheat evaporator 440;

S09:经自然冷却,第一温度探测器460显示降温后,打开第一除盐部装420取出除盐插板421随后立即关闭除盐部装420,收集废盐并处理,此时完成第一再热蒸发塔400除盐工作,进入准工作状态;S09: After natural cooling, after the first temperature detector 460 shows that the temperature has dropped, open the first demineralization unit 420, take out the demineralization insert 421, and immediately close the demineralization unit 420, collect and process the waste salt, and the first demineralization unit 420 is completed. Reheat evaporation tower 400 desalination work, enter the quasi-working state;

S10:当第二再热蒸发塔500显示达到除盐状态时,针对第二再热蒸发500按照相同原理重复S06-S09,第一再热蒸发塔400和第二再热蒸发塔500如此循环更替作业,实现在线除盐的烟气再热。S10: When the second reheat evaporation tower 500 shows that it has reached the desalting state, repeat S06-S09 according to the same principle for the second reheat evaporation tower 500, and the first reheat evaporation tower 400 and the second reheat evaporation tower 500 are cyclically replaced in this way operation to realize flue gas reheating for on-line desalination.

本系统涉及的压差和温度范围仅是针对20000m3/h的危废焚烧系统的实践数据。The pressure difference and temperature range involved in this system are only practical data for a 20000m 3 /h hazardous waste incineration system.

这里本发明的描述和应用是说明性的,并非想将本发明的范围限制在上述实施例中。这里所披露的实施例的变形和改变是可能的,对于那些本领域的普通技人员来说实施例的替换和等效的各种部件是公知的。本领域技术人员应该清楚的是,在不脱离本发明的精神或本质特征的情况下,本发明可以以其它形式、结构、布置、比例,以及用其它组件、材料和部件来实现。在不脱离本发明范围和精神的情况下,可以对这里所披的实施例进行其它变形和改变。The description and application of the present invention herein is illustrative, and is not intended to limit the scope of the present invention to the above-described embodiments. Variations and modifications to the embodiments disclosed herein are possible, and alternative and equivalent various components of the embodiments are known to those of ordinary skill in the art. It should be apparent to those skilled in the art that the present invention may be implemented in other forms, structures, arrangements, proportions, and with other components, materials and components without departing from the spirit or essential characteristics of the invention. Other modifications and changes of the embodiments disclosed herein may be made without departing from the scope and spirit of the invention.

Claims (10)

1.一种具有在线除盐功能的烟气再热系统,其特征在于其包括循环洗涤水池(100)、设置在循环洗涤水池(100)上方的湿法洗涤塔(300)、下端与湿法洗涤塔(300)连通的第一再热蒸发塔(400)和第二再热蒸发塔(500)、与第一再热蒸发塔(400)和第二再热蒸发塔(500)上端连通的净化烟气调节塔(600)以及设置在净化烟气调节塔(600)上方的直排烟道(700),在湿法洗涤塔(300)的下部一侧设置有焚烧烟气进口。1. A flue gas reheating system with on-line desalination function, characterized in that it comprises a circulating washing pool (100), a wet scrubbing tower (300) arranged above the circulating washing pool (100), a lower end and a wet scrubbing tower (300). The first reheat evaporation tower (400) and the second reheat evaporation tower (500) communicated with the washing tower (300), and the first reheat evaporation tower (400) and the upper end of the second reheat evaporation tower (500) are connected The purification flue gas conditioning tower (600) and the straight exhaust flue (700) arranged above the purification flue gas conditioning tower (600) are provided with a combustion flue gas inlet on the lower side of the wet scrubbing tower (300). 2.根据权利要求1所述的一种具有在线除盐功能的烟气再热系统,其特征在于在所述循环洗涤水池(100)上通过管路连接有过滤装置(200)。2 . The flue gas reheating system with on-line desalination function according to claim 1 , wherein a filter device ( 200 ) is connected to the circulating washing pool ( 100 ) through a pipeline. 3 . 3.根据权利要求1所述的一种具有在线除盐功能的烟气再热系统,其特征在于所述第一再热蒸发塔(400)包括沿烟气流动方向依次设置的第一电动烟气切断阀C(410)、第一除盐部装(420)、第一加热装置、第一压差探测器(450)、第一温度探测器(460)、第一清盐风机(480)以及第一电动烟气切断阀B(490),在所述第一清盐风机(480)的进风管路上设置有第一电动烟气切断阀A(470)。3. A flue gas reheating system with on-line desalination function according to claim 1, characterized in that the first reheating evaporation tower (400) comprises first electric cigarettes arranged in sequence along the flue gas flow direction Gas shut-off valve C (410), first demineralizing unit (420), first heating device, first differential pressure detector (450), first temperature detector (460), first salt cleaning fan (480) and a first electric flue gas cut-off valve B (490), a first electric flue gas cut-off valve A (470) is provided on the air inlet pipeline of the first salt cleaning fan (480). 4.根据权利要求1或3所述的一种具有在线除盐功能的烟气再热系统,其特征在于所述第二再热蒸发塔(500)包括沿烟气流动方向依次设置的第二电动烟气切断阀C(510)、第二除盐部装(520)、第二加热装置、第二压差探测器(550)、第二温度探测器(560)、第二清盐风机(580)以及第二电动烟气切断阀B(590),在所述第二清盐风机(580)的进风管路上设置有第二电动烟气切断阀A(570)。4. A flue gas reheating system with on-line desalination function according to claim 1 or 3, characterized in that the second reheating evaporation tower (500) comprises a second reheating tower (500) arranged in sequence along the flue gas flow direction Electric flue gas cut-off valve C (510), second demineralization unit (520), second heating device, second differential pressure detector (550), second temperature detector (560), second salt cleaning fan ( 580) and a second electric flue gas shut-off valve B (590), a second electric flue gas shut-off valve A (570) is provided on the air inlet pipeline of the second salt cleaning fan (580). 5.根据权利要求1所述的一种具有在线除盐功能的烟气再热系统,其特征在于在所述湿法洗涤塔(300)的上部设有第三温度探测器(310)。5 . The flue gas reheating system with on-line desalination function according to claim 1 , wherein a third temperature detector ( 310 ) is provided on the upper part of the wet scrubber ( 300 ). 6 . 6.根据权利要求3所述的一种具有在线除盐功能的烟气再热系统,其特征在于所述第一加热装置包括沿烟气流动方向依次设置的第一初效再热蒸发器(430)和第一二效再热蒸发器(440)。6. A flue gas reheating system with on-line desalination function according to claim 3, characterized in that the first heating device comprises a first primary effect reheating evaporator ( 430) and a first second effect reheat evaporator (440). 7.根据权利要求4所述的一种具有在线除盐功能的烟气再热系统,其特征在于所述第二加热装置包括沿烟气流动方向依次设置的第二初效再热蒸发器(530)和第二二效再热蒸发器(540)。7. A flue gas reheating system with on-line desalination function according to claim 4, characterized in that the second heating device comprises a second primary effect reheating evaporator ( 530) and a second second effect reheat evaporator (540). 8.根据权利要求1所述的一种具有在线除盐功能的烟气再热系统,其特征在于所述净化烟气调节塔(600)包括冷凝回用水收集装置(610)、降温装置(620)以及第四温度探测器(630),所述冷凝回用水收集装置(610)位于降温装置(620)的下方并且与循环洗涤水池(100)连通,第四温度探测器(630)位于降温装置(620)的上方。8. A flue gas reheating system with on-line desalination function according to claim 1, characterized in that the purification flue gas conditioning tower (600) comprises a condensing and recycling water collection device (610), a cooling device (620) ) and a fourth temperature detector (630), the condensation recycling water collection device (610) is located below the cooling device (620) and communicated with the circulating washing pool (100), and the fourth temperature detector (630) is located in the cooling device (620) above. 9.根据权利要求2所述的一种具有在线除盐功能的烟气再热系统,其特征在于所述过滤装置(200)为活性炭过滤罐,在活性炭过滤罐的进罐管路上设有加压水泵。9. A flue gas reheating system with on-line desalination function according to claim 2, characterized in that the filter device (200) is an activated carbon filter tank, and a tank inlet pipeline of the activated carbon filter tank is provided with a filter. pressure pump. 10.一种具有在线除盐功能的烟气再热方法,其特征在于其包括如下步骤:10. A flue gas reheating method with on-line desalination function, characterized in that it comprises the steps: 步骤一、关闭第二电动烟气切断阀C(510)、第二电动烟气切断阀B(590)、第一电动烟气切断阀A(470)以及第一清盐风机(480),打开第一电动烟气切断阀C(410)、第一电动烟气切断阀B(490),使第一再热蒸发塔(400)处于工作状态,循环洗涤水池(100)内的循环水喷淋至湿法洗涤塔(300)内,完成湿法洗涤焚烧烟气;Step 1. Close the second electric flue gas shut-off valve C (510), the second electric flue gas shut-off valve B (590), the first electric flue gas shut-off valve A (470) and the first salt cleaning fan (480), and turn on the The first electric flue gas cut-off valve C (410) and the first electric flue gas cut-off valve B (490) make the first reheat evaporation tower (400) in the working state, and the circulating water in the circulating washing pool (100) is sprayed into the wet scrubbing tower (300) to complete the wet scrubbing of the incineration flue gas; 步骤二、循环洗涤水落入循环洗涤水池(100),通过加注碱液调节pH至弱碱性,同时池中的循环水通过水泵抽至过滤装置(200)过滤,过滤颗粒物及杂质,制得循环洗涤水池内的高盐废水;Step 2: The circulating washing water falls into the circulating washing pool (100), and the pH is adjusted to weakly alkaline by adding lye. At the same time, the circulating water in the pool is pumped to the filter device (200) by the water pump for filtration, and the particulate matter and impurities are filtered. It is necessary to circulate the high-salt wastewater in the washing pool; 步骤三、洗涤烟气进入第一再热蒸发塔(400),经第一初效再热蒸发器(430)和第一二效再热蒸发器(440)完成烟气加热蒸发及废盐结晶,进入净化烟气调节塔(600);Step 3. The washed flue gas enters the first reheat evaporation tower (400), and the first primary effect reheat evaporator (430) and the first second effect reheat evaporator (440) complete the heating and evaporation of flue gas and the crystallization of waste salt , enter the purification flue gas adjustment tower (600); 步骤四、加热后的烟气经净化烟气调节塔(600)内的降温装置(620),完成烟气降温冷凝,经直排烟道(700)达标排放;Step 4. The heated flue gas is passed through the cooling device (620) in the purification flue gas conditioning tower (600) to complete the cooling and condensation of the flue gas, and is discharged up to the standard through the straight exhaust flue (700); 步骤五、步骤四降温产生的冷凝水落入设在净化烟气调节塔(600)底部的冷凝回用水收集装置(610),经管路流至循环洗涤水池(100)内回用;当第一再热蒸发塔(400)内压差探测器(450)探测显示压差大于1000Pa时,确定达到除盐要求;The condensed water generated in step 5 and step 4 falls into the condensed and reused water collection device (610) disposed at the bottom of the purification flue gas conditioning tower (600), and flows to the circulating washing pool (100) for reuse through the pipeline; When the pressure difference detector (450) in the reheat evaporation tower (400) detects and shows that the pressure difference is greater than 1000Pa, it is determined that the desalination requirement is met; 步骤六:第一再热蒸发塔(400)进入除盐状态,取出第二除盐插板(521)关闭第二除盐部装(520),第二初效再热蒸发器(530)和第二二效再热蒸发器(540)内通入相应蒸汽,打开第二电动烟气切断阀C(510)、第二电动烟气切断阀B(590)、第一电动烟气切断阀A(470),关闭第一电动烟气切断阀C(410)、第一电动烟气切断阀B(490)、第二电动烟气切断阀A(570),完成湿法洗涤的焚烧烟气进入第二再热蒸发塔(500),在第二再热蒸发塔(500)内重现步骤一至五;Step 6: The first reheating evaporation tower (400) enters the demineralization state, and the second demineralization insert (521) is taken out to close the second demineralization unit (520), and the second primary reheating evaporator (530) and Corresponding steam is introduced into the second second-effect reheat evaporator (540), and the second electric flue gas shut-off valve C (510), the second electric flue gas shut-off valve B (590), and the first electric flue gas shut-off valve A are opened. (470), close the first electric flue gas shut-off valve C (410), the first electric flue gas shut-off valve B (490), and the second electric flue gas shut-off valve A (570), and the incineration flue gas after the wet scrubbing is completed enters The second reheat evaporation tower (500), repeat steps 1 to 5 in the second reheat evaporation tower (500); 步骤七:第一温度探测器(460)显示降温后,打开第一除盐部装(420),放入第一除盐插板(421),第一初效再热蒸发器(430)和第一二效再热蒸发器(440)内通入蒸汽,启动第一除盐风机(480)通入干燥热风,对第一再热蒸发塔(400)内进行除盐,当第一再热蒸发塔(400)内第一压差探测器(450)探测显示压差小于100Pa时,确定除盐完成;Step 7: After the first temperature detector (460) shows that the temperature is lowered, open the first demineralization unit (420), put in the first demineralization insert (421), and the first primary reheat evaporator (430) and Steam is introduced into the first and second-effect reheating evaporator (440), and the first demineralizing fan (480) is activated to introduce hot drying air to demineralize the first reheating evaporation tower (400). When the first pressure difference detector (450) in the evaporation tower (400) detects and shows that the pressure difference is less than 100Pa, it is determined that the desalination is completed; 步骤八:关闭第一除盐风机(480)、第一电动烟气切断阀A(470),切断第一初效再热蒸发器(430)和第一二效再热蒸发器(440)内的蒸汽;Step 8: Turn off the first desalination fan (480), the first electric flue gas cut-off valve A (470), and cut off the inside of the first primary effect reheat evaporator (430) and the first second effect reheat evaporator (440). of steam; 步骤九:经冷却,第一温度探测器(460)显示降温后,打开第一除盐部装(420)取出除盐插板(421)随后立即关闭除盐部装(420),收集废盐并处理,此时完成第一再热蒸发塔(400)除盐工作,进入准工作状态;Step 9: After cooling, after the first temperature detector (460) shows that the temperature has dropped, open the first demineralization unit (420), take out the demineralization insert (421), and immediately close the demineralization unit (420) to collect waste salt At this time, the first reheat evaporation tower (400) desalination work is completed, and the quasi-working state is entered; 步骤十:当第二再热蒸发塔(500)显示达到除盐状态时,针对第二再热蒸发塔(500)按照相同原理重复步骤六-步骤九,第一再热蒸发塔(400)和第二再热蒸发塔(500)如此循环更替作业,实现在线除盐的烟气再热。Step 10: When the second reheat evaporation tower (500) shows that it has reached the desalination state, repeat steps six to nine according to the same principle for the second reheat evaporation tower (500), the first reheat evaporation tower (400) and the The second reheating evaporation tower (500) operates in such a cyclic and replacement manner to realize the reheating of the flue gas for on-line desalination.
CN202010275578.3A 2020-04-09 2020-04-09 Flue gas reheating system and method with on-line desalination function Pending CN111457414A (en)

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