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CN114383761A - Pressure sensor with single-direction conductive function, preparation method and application thereof - Google Patents

Pressure sensor with single-direction conductive function, preparation method and application thereof Download PDF

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CN114383761A
CN114383761A CN202111424219.0A CN202111424219A CN114383761A CN 114383761 A CN114383761 A CN 114383761A CN 202111424219 A CN202111424219 A CN 202111424219A CN 114383761 A CN114383761 A CN 114383761A
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electrode
pressure sensor
magnetic
nickel
fibers
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CN114383761B (en
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姜阳
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Beijing Institute of Nanoenergy and Nanosystems
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Beijing Institute of Nanoenergy and Nanosystems
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    • GPHYSICS
    • G01MEASURING; TESTING
    • G01LMEASURING FORCE, STRESS, TORQUE, WORK, MECHANICAL POWER, MECHANICAL EFFICIENCY, OR FLUID PRESSURE
    • G01L1/00Measuring force or stress, in general
    • G01L1/12Measuring force or stress, in general by measuring variations in the magnetic properties of materials resulting from the application of stress
    • GPHYSICS
    • G01MEASURING; TESTING
    • G01LMEASURING FORCE, STRESS, TORQUE, WORK, MECHANICAL POWER, MECHANICAL EFFICIENCY, OR FLUID PRESSURE
    • G01L9/00Measuring steady of quasi-steady pressure of fluid or fluent solid material by electric or magnetic pressure-sensitive elements; Transmitting or indicating the displacement of mechanical pressure-sensitive elements, used to measure the steady or quasi-steady pressure of a fluid or fluent solid material, by electric or magnetic means
    • G01L9/16Measuring steady of quasi-steady pressure of fluid or fluent solid material by electric or magnetic pressure-sensitive elements; Transmitting or indicating the displacement of mechanical pressure-sensitive elements, used to measure the steady or quasi-steady pressure of a fluid or fluent solid material, by electric or magnetic means by making use of variations in the magnetic properties of material resulting from the application of stress

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  • General Physics & Mathematics (AREA)
  • Measuring Magnetic Variables (AREA)
  • Measuring Fluid Pressure (AREA)

Abstract

The invention relates to the technical field of sensors, and particularly discloses a pressure sensor with a single-direction conducting function, and a preparation method and application thereof. The pressure sensor includes: the flexible electrode structure comprises two layers of flexible electrodes and a dielectric layer positioned between the two layers of flexible electrodes; the dielectric layer comprises a base material and magnetic conductive fibers distributed in the base material, and the magnetic conductive fibers are arranged in a direction perpendicular to the flexible electrodes. The pressure sensor provided by the invention has the advantages of flexibility, high sensitivity and wide monitoring range.

Description

具有单一方向导电功能的压力传感器及其制备方法和应用Pressure sensor with single-direction conductive function, preparation method and application thereof

技术领域technical field

本发明涉及传感器技术领域,具体涉及一种具有单一方向导电功能的压力传感器及其制备方法和应用。The invention relates to the technical field of sensors, in particular to a pressure sensor with a single-direction conduction function, a preparation method and application thereof.

背景技术Background technique

实时精确利用电子传感器测量人体重要信息对于健康监测、医疗保健具有重要作用,人体皮肤能够自然地区分压力以及各种机械刺激或机械变形并进行独立传感,因此可穿戴电子传感器件也应具备对各种机械应力的能力高灵敏的感知。但是,目前的传感器大多依靠接触电阻的改变实现压力传感,其形变范围较小,无法实现高灵敏度和宽的监测范围。The accurate use of electronic sensors to measure important human information in real time plays an important role in health monitoring and medical care. Human skin can naturally distinguish pressure and various mechanical stimuli or mechanical deformation and conduct independent sensing. Therefore, wearable electronic sensor devices should also have the ability to Capable of highly sensitive perception of various mechanical stresses. However, most of the current sensors rely on the change of contact resistance to realize pressure sensing, and their deformation range is small, which cannot achieve high sensitivity and wide monitoring range.

因此,制备高灵敏度和宽的监测范围的压力传感器仍然是传感器领域追求的热点。Therefore, the preparation of pressure sensors with high sensitivity and wide monitoring range is still a hot spot in the sensor field.

发明内容SUMMARY OF THE INVENTION

本发明的目的是为了克服现有技术存在的技术问题,提供一种具有单一方向导电功能的压力传感器及其制备方法和应用。The purpose of the present invention is to overcome the technical problems existing in the prior art, and to provide a pressure sensor with a single-direction conduction function and a preparation method and application thereof.

为了实现上述目的,本发明第一方面提供一种具有单一方向导电功能的压力传感器,该压力传感器包括:两层柔性电极和位于两层柔性电极之间的介电层;所述介电层包括基体材料和分布于该基体材料中的磁性导电纤维,且所述磁性导电纤维垂直于柔性电极定向排列。In order to achieve the above object, a first aspect of the present invention provides a pressure sensor with a single-direction conductive function, the pressure sensor includes: two layers of flexible electrodes and a dielectric layer between the two layers of flexible electrodes; the dielectric layer includes A matrix material and magnetic conductive fibers distributed in the matrix material, and the magnetic conductive fibers are oriented and arranged perpendicular to the flexible electrodes.

本发明第二方面提供一种制备具有单一方向导电功能的压力传感器的方法,该方法包括以下步骤:A second aspect of the present invention provides a method for preparing a pressure sensor with a single-directional conductive function, the method comprising the following steps:

使磁性导电纤维定向分布于基体材料中,并组装柔性电极;The magnetic conductive fibers are oriented and distributed in the matrix material, and the flexible electrodes are assembled;

其中,所述磁性导电纤维垂直于柔性电极定向排列。Wherein, the magnetic conductive fibers are oriented and arranged perpendicular to the flexible electrodes.

本发明第三方面提供一种前述方法制备得到的压力传感器。A third aspect of the present invention provides a pressure sensor prepared by the aforementioned method.

本发明第四方面提供一种前述压力传感器在可穿戴设备和/或人机交互领域中的应用。A fourth aspect of the present invention provides an application of the aforementioned pressure sensor in the field of wearable devices and/or human-computer interaction.

本发明第五方面提供一种可穿戴设备,所述可穿戴设备包括前述压力传感器。A fifth aspect of the present invention provides a wearable device comprising the aforementioned pressure sensor.

本发明提供的压力传感器具有柔性、灵敏度高和监测范围宽的优势。The pressure sensor provided by the present invention has the advantages of flexibility, high sensitivity and wide monitoring range.

附图说明Description of drawings

图1是本发明一种具体实施方式的定向排列后的磁性导电纤维的示意图;Fig. 1 is the schematic diagram of the magnetic conductive fiber after orientation arrangement of a specific embodiment of the present invention;

图2是本发明一种具体实施方式的传感器随压力变化的示意图;FIG. 2 is a schematic diagram of a sensor according to a specific embodiment of the present invention changing with pressure;

图3中,(a)分别是本发明实施例1,实施例4和对比例1制备的传感器在不同压力下,实时电流与初始电流的比值随压力变化而变化的曲线图;(b)分别是本发明实施例1,实施例2和实施例3制备的传感器在不同压力下,实时电流与初始电流的比值随压力变化而变化的曲线图;(c)是无压力状态下,实施例1制备的传感器在不同电压下的电流与电压关系(伏安曲线);(d)是本发明一种具体实施方式的传感器(实施例1)在不同压力下,实时电流压力变化而变化的曲线图;(e)是本发明一种具体实施方式的压力传感器在相同大小压力不同频率电流图;(f)是本发明一种具体实施方式的传感器(实施例1)在压力下刺激下,实时电流的变化曲线;(g)是本发明一种具体实施方式的传感器(实施例1)在3000次同一压力下刺激下,实时电流的变化曲线。In Fig. 3, (a) is a graph showing the change of the ratio of real-time current to initial current with pressure changes for the sensors prepared in Example 1, Example 4 and Comparative Example 1 under different pressures; (b) respectively It is the graph of the change of the ratio of real-time current and initial current with pressure changes under different pressures of the sensors prepared in Example 1, Example 2 and Example 3 of the present invention; (c) is the pressure-free state, Example 1 The relationship between the current and the voltage of the prepared sensor at different voltages (volt-ampere curve); (d) is a curve diagram of the real-time current and pressure changes of the sensor (Example 1) of a specific embodiment of the present invention under different pressures (e) is a current diagram of the pressure sensor of a specific embodiment of the present invention at the same size and pressure and different frequencies; (f) is a sensor of a specific embodiment of the present invention (Example 1) under pressure stimulation, real-time current The change curve of ; (g) is the change curve of the real-time current of the sensor of a specific embodiment of the present invention (Example 1) under the same pressure stimulation for 3000 times.

具体实施方式Detailed ways

在本文中所披露的范围的端点和任何值都不限于该精确的范围或值,这些范围或值应当理解为包含接近这些范围或值的值。对于数值范围来说,各个范围的端点值之间、各个范围的端点值和单独的点值之间,以及单独的点值之间可以彼此组合而得到一个或多个新的数值范围,这些数值范围应被视为在本文中具体公开。The endpoints of ranges and any values disclosed herein are not limited to the precise ranges or values, which are to be understood to encompass values proximate to those ranges or values. For ranges of values, the endpoints of each range, the endpoints of each range and the individual point values, and the individual point values can be combined with each other to yield one or more new ranges of values that Ranges should be considered as specifically disclosed herein.

本发明第一方面提供一种具有单一方向导电功能的压力传感器,该压力传感器包括:两层柔性电极和位于两层柔性电极之间的介电层;所述介电层包括基体材料和分布于该基体材料中的磁性导电纤维,且所述磁性导电纤维垂直于柔性电极定向排列。A first aspect of the present invention provides a pressure sensor with a single-direction conductive function, the pressure sensor includes: two layers of flexible electrodes and a dielectric layer between the two layers of flexible electrodes; the dielectric layer includes a base material and distributed in Magnetic conductive fibers in the matrix material, and the magnetic conductive fibers are oriented perpendicular to the flexible electrodes.

根据本发明的一些实施方式,所述基底材料与磁性导电纤维的重量比可以为(3-25):1(如3:1、4:1、5:1、10:1、15:1、20:1、25:1或以上数值之间的任意值)。According to some embodiments of the present invention, the weight ratio of the base material to the magnetic conductive fibers may be (3-25):1 (eg 3:1, 4:1, 5:1, 10:1, 15:1, 20:1, 25:1, or any value in between).

根据本发明的一些实施方式,所述磁性导电纤维可以为圆柱状。According to some embodiments of the present invention, the magnetic conductive fibers may be cylindrical.

优选地,所述磁性导电纤维的长度为0.5-3mm,直径为0.1-0.3mm。Preferably, the length of the magnetic conductive fiber is 0.5-3mm, and the diameter is 0.1-0.3mm.

根据本发明的一些实施方式,所述磁性导电纤维的导电系数可以为(1.5-2)×10-3Ω·cm;磁导率可以为(8-9)×103H/m。According to some embodiments of the present invention, the electrical conductivity of the magnetic conductive fiber may be (1.5-2)×10 −3 Ω·cm; the magnetic permeability may be (8-9)×10 3 H/m.

根据本发明的一些实施方式,所述磁性导电纤维可以选自镀镍碳纤维、镀镍金属纤维、镀镍不锈钢、镀铁碳纤维和镀钴碳纤维中的至少一种,优选为镀镍碳纤维和/或镀钴碳纤维。According to some embodiments of the present invention, the magnetic conductive fibers may be selected from at least one of nickel-plated carbon fibers, nickel-plated metal fibers, nickel-plated stainless steel, iron-plated carbon fibers and cobalt-plated carbon fibers, preferably nickel-plated carbon fibers and/or Cobalt-coated carbon fiber.

本发明对所述介电层的厚度没有特别的限制,只要能够满足奔本发明的需求即可,例如,所述介电层的厚度可以为2mm-5mm。The thickness of the dielectric layer is not particularly limited in the present invention, as long as it can meet the requirements of the present invention. For example, the thickness of the dielectric layer may be 2 mm-5 mm.

根据本发明的一些实施方式,所述基底材料可以选自热固化材料和/或光固化材料。According to some embodiments of the present invention, the base material may be selected from thermally curable materials and/or photocurable materials.

本发明中,所述基底材料的导热系数可以为0.134-0.159W/M*K,透光率可以为95-100%,具有生理惰性、良好的化学稳定性。其中,所述基底材料的电绝缘性和耐候性,抗剪切能力,能够在-50℃-200℃下长期使用。In the present invention, the thermal conductivity of the base material can be 0.134-0.159W/M*K, the light transmittance can be 95-100%, and it has physiological inertness and good chemical stability. Wherein, the electrical insulation, weather resistance and shear resistance of the base material can be used for a long time at -50°C to 200°C.

根据本发明的一些实施方式,所述热固化材料可以选自聚二甲基硅氧烷和/或硅胶。According to some embodiments of the present invention, the thermally curable material may be selected from polydimethylsiloxane and/or silica gel.

根据本发明的一些实施方式,所述光固化材料可以为光敏聚氨酯。According to some embodiments of the present invention, the photocurable material may be photosensitive polyurethane.

根据本发明的一些实施方式,所述两层柔性电极的厚度可以各自独立地为20μm-70μm。According to some embodiments of the present invention, the thicknesses of the two layers of flexible electrodes may each independently be 20 μm-70 μm.

根据本发明的一些实施方式,所述柔性电极可以选自叉指电极和/或导电金属电极。According to some embodiments of the present invention, the flexible electrodes may be selected from interdigitated electrodes and/or conductive metal electrodes.

根据本发明的一些实施方式,所述压力传感器的上电极为导电金属电极,下电极为叉指电极。According to some embodiments of the present invention, the upper electrode of the pressure sensor is a conductive metal electrode, and the lower electrode is an interdigital electrode.

根据本发明的一些实施方式,所述叉指电极的对数为8-20对。According to some embodiments of the present invention, the number of pairs of the interdigital electrodes is 8-20 pairs.

根据本发明的一些实施方式,所述叉指电极的叉指线宽和线距各自独立地为100-200μm。According to some embodiments of the present invention, the interdigital line width and line spacing of the interdigital electrodes are each independently 100-200 μm.

根据本发明优选的实施方式,所述叉指电极通过磁控溅射制备,其中,磁控溅射的时间为20-40min。According to a preferred embodiment of the present invention, the interdigital electrodes are prepared by magnetron sputtering, wherein the time of magnetron sputtering is 20-40 min.

根据本发明优选的实施方式,所述磁控溅射使得叉指电极上沉积的金属厚度为70-100nm。优选地,所述沉积的金属选自铜和/或金,优选为铜。According to a preferred embodiment of the present invention, the magnetron sputtering enables the thickness of the metal deposited on the interdigital electrodes to be 70-100 nm. Preferably, the deposited metal is selected from copper and/or gold, preferably copper.

根据本发明的一些实施方式,所述导电金属电极为网状电极;所述导电金属电极选自铜电极、镍布和银布中的至少一种。According to some embodiments of the present invention, the conductive metal electrodes are mesh electrodes; and the conductive metal electrodes are selected from at least one of copper electrodes, nickel cloth and silver cloth.

根据本发明的一些实施方式,压力传感器的灵敏度可以为10000-40000kPa-1According to some embodiments of the present invention, the sensitivity of the pressure sensor may be 10000-40000 kPa −1 .

本发明第二方面提供一种制备具有单一方向导电功能的压力传感器的方法,该方法包括以下步骤:A second aspect of the present invention provides a method for preparing a pressure sensor with a single-directional conductive function, the method comprising the following steps:

使磁性导电纤维定向分布于基体材料中,并组装柔性电极;The magnetic conductive fibers are oriented and distributed in the matrix material, and the flexible electrodes are assembled;

其中,所述磁性导电纤维垂直于柔性电极定向排列。Wherein, the magnetic conductive fibers are oriented and arranged perpendicular to the flexible electrodes.

根据本发明的一些实施方式,组装柔性电极的方式包括:将柔性电极和分布有磁性导电纤维的基体材料一起固化;According to some embodiments of the present invention, the manner of assembling the flexible electrode includes: curing the flexible electrode and the matrix material distributed with the magnetic conductive fibers together;

或者,在分布有磁性导电纤维的基体材料进行固化之后,再粘覆柔性电极。Alternatively, after the matrix material in which the magnetic conductive fibers are distributed is cured, the flexible electrodes are adhered.

其中,将柔性电极和分布有磁性导电纤维的基体材料一起固化,可以表示一个或多个柔性电极和分布有磁性导电纤维的基体材料一起固化。Wherein, curing the flexible electrodes together with the matrix material distributed with the magnetic conductive fibers may mean that one or more flexible electrodes are cured together with the matrix material distributed with the magnetic conductive fibers.

根据本发明的一些实施方式,所述磁性导电纤维定向分布于所述基体材料的方式可以为:According to some embodiments of the present invention, the manner in which the magnetic conductive fibers are oriented and distributed in the matrix material may be:

将所述磁性导电纤维与所述基体材料混合置于模具中,所述导电纤维在垂直于模具的磁场诱导下以平行于磁场的方向定向分布于所述基体材料中。The magnetic conductive fibers are mixed with the matrix material and placed in a mold, and the conductive fibers are oriented and distributed in the matrix material in a direction parallel to the magnetic field under the induction of a magnetic field perpendicular to the mold.

本发明中,采用先覆盖上表面柔性电极再固化的方式,能够减少接触电阻,利于稳定器件,同时简化制备流程。In the present invention, the method of first covering the upper surface of the flexible electrode and then curing can reduce the contact resistance, facilitate the stabilization of the device, and at the same time simplify the preparation process.

根据本发明的一些实施方式,所述基底材料与所述磁性导电纤维的重量比为(5-20):1。According to some embodiments of the present invention, the weight ratio of the base material to the magnetic conductive fiber is (5-20):1.

本发明第二方面所述的磁性导电纤维、所述基底材料以及所述柔性电极与前述第一方面具有相同的含义。此处不再赘述。The magnetic conductive fiber, the base material and the flexible electrode according to the second aspect of the present invention have the same meanings as those of the aforementioned first aspect. It will not be repeated here.

根据本发明的一些实施方式,所述模具可以为平板模具。为了获得更好的效果,所述模具的底部的材质为砂纸。其中,砂纸表面是蝶骨嵴结构可以有效提高传感灵敏度。According to some embodiments of the present invention, the mold may be a flat mold. In order to obtain a better effect, the material of the bottom of the mold is sandpaper. Among them, the surface of the sandpaper is a sphenoid ridge structure, which can effectively improve the sensing sensitivity.

根据本发明的一些实施方式,所述混合在搅拌下进行。所述搅拌的转速可以为1500-3000rpm,时间可以为20-30min;According to some embodiments of the present invention, the mixing is performed with stirring. The rotating speed of the stirring can be 1500-3000rpm, and the time can be 20-30min;

根据本发明的一些实施方式,所述磁场诱导的条件可以包括:磁场强度为0.1-0.3T;所述磁场诱导在均匀磁场下进行。According to some embodiments of the present invention, the conditions for the magnetic field induction may include: the magnetic field strength is 0.1-0.3 T; and the magnetic field induction is performed under a uniform magnetic field.

根据本发明的一些实施方式,所述固化为光固化或热固化。According to some embodiments of the present invention, the curing is photocuring or thermal curing.

优选地,所述光固化的条件包括:紫外光的波长为360-380nm,强度为20-50W,时间为20-30s。Preferably, the photo-curing conditions include: the wavelength of the ultraviolet light is 360-380 nm, the intensity is 20-50 W, and the time is 20-30 s.

优选地,所述热固化的条件包括:70-80℃,时间为60-90min。Preferably, the thermal curing conditions include: 70-80° C. for 60-90 min.

本发明中,对柔性电极的组装方式没有特别的限制,只要能够满足本发明的需求即可。例如所述组装的方式可以为层压和/或粘贴。In the present invention, there is no particular limitation on the assembling method of the flexible electrode, as long as it can meet the requirements of the present invention. For example, the manner of assembly may be lamination and/or gluing.

本发明第三方面提供一种前述方法制备得到的压力传感器。A third aspect of the present invention provides a pressure sensor prepared by the aforementioned method.

本发明第四方面提供一种前述压力传感器在可穿戴设备和/或人机交互领域中的应用。A fourth aspect of the present invention provides an application of the aforementioned pressure sensor in the field of wearable devices and/or human-computer interaction.

本发明的方法还可以应用于3D打印中,可以取向打印具有特定图案的样材料。The method of the present invention can also be applied in 3D printing, where a sample material with a specific pattern can be oriented to print.

本发明第五方面提供一种可穿戴设备,所述可穿戴设备包括前述压力传感器。A fifth aspect of the present invention provides a wearable device comprising the aforementioned pressure sensor.

以下将通过实施例对本发明进行详细描述。The present invention will be described in detail below by means of examples.

实施例1Example 1

(1)将4g镀镍碳纤维(直径为0.2mm、长度为2mm、导电系数为1.5×10-3Ω·cm、磁导率为8×103H/m)加入16g基体材料(聚二甲基硅氧烷(PDMS))中,在2000rpm下搅拌20min,混合均匀后倒入平板模具(材质:亚克力(聚甲基丙烯酸甲酯;4cm(长)×4cm(宽)×2mm(高)),模具底部为表面粗糙的砂纸)中,并将混合后的镀镍碳纤维和基体材料的表面刮涂(用薄刀片在基底材料上进行均匀刮膜)平整,之后将装有镀镍碳纤维和基体材料的模具放置于垂直方向的磁场中,在0.2T的磁场(均匀磁场)诱导下使其中的镀镍碳纤维沿磁场方向进行定向扭转,得到介电层前体;之后在得到的介电层前体的上表面覆盖一层厚度为50μm的导电薄膜(铜网,4cm(长)×4cm(宽)),室温下静置,10min自流平,得到上表面覆盖有导电薄膜的介电层前体;(1) Add 4g nickel-plated carbon fiber (diameter 0.2mm, length 2mm, conductivity 1.5×10-3Ω·cm, magnetic permeability 8×103H/m) into 16g base material (polydimethylsiloxane alkane (PDMS)), stir at 2000rpm for 20min, mix well and pour into a flat mold (material: acrylic (polymethyl methacrylate; 4cm (length) × 4cm (width) × 2mm (height)), the bottom of the mold The surface of the mixed nickel-plated carbon fiber and the base material is scraped (a thin blade is used to make a uniform film on the base material), and then the mold with the nickel-plated carbon fiber and the base material is installed. Placed in a vertical magnetic field, under the induction of a 0.2T magnetic field (uniform magnetic field), the nickel-plated carbon fibers in it are oriented and twisted along the direction of the magnetic field to obtain a dielectric layer precursor; then, on the obtained dielectric layer precursor The surface is covered with a conductive film (copper mesh, 4 cm (length) × 4 cm (width)) with a thickness of 50 μm, left standing at room temperature, and self-leveling for 10 min to obtain a dielectric layer precursor covered with a conductive film on the upper surface;

将得到的介电层前体在70℃下进行热固化60min,得到上表面覆盖有导电薄膜的介电层,其中,介电层的厚度为2mm;The obtained dielectric layer precursor is thermally cured at 70° C. for 60 minutes to obtain a dielectric layer with a conductive film covering the upper surface, wherein the thickness of the dielectric layer is 2 mm;

(2)采用磁控溅射(时间为30min)制备叉指电极,叉指电极上沉积铜的厚度为100nm,叉指电极的厚度为72μm,叉指电极的叉指线宽和线距各自为150μm;将其作为下电极粘覆至上述上表面覆盖有导电薄膜的介电层的下表面。(2) The interdigital electrodes were prepared by magnetron sputtering (the time was 30 min), the thickness of the copper deposited on the interdigital electrodes was 100 nm, the thickness of the interdigital electrodes was 72 μm, and the interdigital line width and line spacing of the interdigital electrodes were respectively 150 μm; stick it as a lower electrode to the lower surface of the dielectric layer whose upper surface is covered with a conductive film.

实施例2Example 2

(1)将4.4g镀镍碳纤维(直径为0.2mm、长度为2mm、导电系数为1.5×10-3Ω·cm、磁导率为8×103H/m)加入15.6g基体材料(聚二甲基硅氧烷(PDMS))中,在2000rpm下搅拌20min,混合均匀后倒入平板模具(材质:亚克力(聚甲基丙烯酸甲酯;4cm(长)×4cm(宽)×2mm(高)),模具底部为表面粗糙的砂纸)中,并将混合后的镀镍碳纤维和基体材料的表面刮涂(用薄刀片在基底材料上进行均匀刮膜)平整,之后将装有镀镍碳纤维和基体材料的模具放置于垂直方向的磁场中,在0.2T的磁场(均匀磁场)诱导下使其中的镀镍碳纤维沿磁场方向进行定向扭转,得到介电层前体;之后在得到的介电层的上表面覆盖一层厚度为50μm的导电薄膜(铜网,4cm(长)×4cm(宽)),室温下静置,10min自流平,得到上表面覆盖有导电薄膜的介电层前体;(1) Add 4.4g of nickel-plated carbon fiber (0.2mm in diameter, 2mm in length, 1.5×10-3Ω·cm, and 8×103H/m in conductivity) into 15.6g of matrix material (polydimethyl Siloxane (PDMS)), stir at 2000rpm for 20min, mix well and pour into a flat mold (material: acrylic (polymethyl methacrylate; 4cm (length) × 4cm (width) × 2mm (height)), The bottom of the mold is sandpaper with rough surface), and the surface of the mixed nickel-plated carbon fiber and the base material is scraped (a thin blade is used to uniformly scrape the base material), and then the nickel-plated carbon fiber and the base material will be installed. The mold is placed in a vertical magnetic field, and under the induction of a 0.2T magnetic field (uniform magnetic field), the nickel-plated carbon fibers in it are oriented and twisted along the direction of the magnetic field to obtain a dielectric layer precursor; The surface is covered with a conductive film (copper mesh, 4 cm (length) × 4 cm (width)) with a thickness of 50 μm, left standing at room temperature, and self-leveling for 10 min to obtain a dielectric layer precursor covered with a conductive film on the upper surface;

将得到的介电层前体在70℃下进行热固化60min,得到上表面覆盖有导电薄膜的介电层,其中,介电层的厚度为2mm;The obtained dielectric layer precursor is thermally cured at 70° C. for 60 minutes to obtain a dielectric layer with a conductive film covering the upper surface, wherein the thickness of the dielectric layer is 2 mm;

(2)采用磁控溅射(时间为30min)制备叉指电极,叉指电极上沉积铜的厚度为100nm,叉指电极的厚度为72μm,叉指电极的叉指线宽和线距各自为150μm;将其作为下电极粘覆至上述上表面覆盖有导电薄膜的介电层的下表面。(2) The interdigital electrodes were prepared by magnetron sputtering (the time was 30 min), the thickness of the copper deposited on the interdigital electrodes was 100 nm, the thickness of the interdigital electrodes was 72 μm, and the interdigital line width and line spacing of the interdigital electrodes were respectively 150 μm; stick it as a lower electrode to the lower surface of the dielectric layer whose upper surface is covered with a conductive film.

实施例3Example 3

(1)将3.6g镀镍碳纤维(直径为0.2mm、长度为2mm、导电系数为1.5×10-3Ω·cm、磁导率为8×103H/m)加入16.4g基体材料(聚二甲基硅氧烷(PDMS))中,在2000rpm下搅拌20min,混合均匀后倒入平板模具(材质:亚克力(聚甲基丙烯酸甲酯;4cm(长)×4cm(宽)×2mm(高)),模具底部为表面粗糙的砂纸)中,并将混合后的镀镍碳纤维和基体材料的表面刮涂(用薄刀片在基底材料上进行均匀刮膜)平整,之后将装有镀镍碳纤维和基体材料的模具放置于垂直方向的磁场中,在0.2T的磁场(均匀磁场)诱导下使其中的镀镍碳纤维沿磁场方向进行定向扭转,得到介电层前体;之后在得到的介电层的上表面覆盖一层厚度为50μm的导电薄膜(铜网,4cm(长)×4cm(宽)),室温下静置,10min自流平,得到上表面覆盖有导电薄膜的介电层前体;(1) Add 3.6g of nickel-plated carbon fiber (0.2mm in diameter, 2mm in length, 1.5×10-3Ω·cm, and 8×103H/m in conductivity) into 16.4g of matrix material (polydimethyl Siloxane (PDMS)), stir at 2000rpm for 20min, mix well and pour into a flat mold (material: acrylic (polymethyl methacrylate; 4cm (length) × 4cm (width) × 2mm (height)), The bottom of the mold is sandpaper with rough surface), and the surface of the mixed nickel-plated carbon fiber and the base material is scraped (a thin blade is used to uniformly scrape the base material), and then the nickel-plated carbon fiber and the base material will be installed. The mold is placed in a vertical magnetic field, and under the induction of a 0.2T magnetic field (uniform magnetic field), the nickel-plated carbon fibers in it are oriented and twisted along the direction of the magnetic field to obtain a dielectric layer precursor; The surface is covered with a conductive film (copper mesh, 4 cm (length) × 4 cm (width)) with a thickness of 50 μm, left standing at room temperature, and self-leveling for 10 min to obtain a dielectric layer precursor covered with a conductive film on the upper surface;

将得到的介电层前体在70℃下进行热固化60min,得到上表面覆盖有导电薄膜的介电层,其中,介电层的厚度为2mm;The obtained dielectric layer precursor is thermally cured at 70° C. for 60 minutes to obtain a dielectric layer with a conductive film covering the upper surface, wherein the thickness of the dielectric layer is 2 mm;

(2)采用磁控溅射(时间为30min)制备叉指电极,叉指电极上沉积铜的厚度为100nm,叉指电极的厚度为72μm,叉指电极的叉指线宽和线距各自为150μm;将其作为下电极粘覆至上述上表面覆盖有导电薄膜的介电层的下表面。(2) The interdigital electrodes were prepared by magnetron sputtering (the time was 30 min), the thickness of the copper deposited on the interdigital electrodes was 100 nm, the thickness of the interdigital electrodes was 72 μm, and the interdigital line width and line spacing of the interdigital electrodes were respectively 150 μm; stick it as a lower electrode to the lower surface of the dielectric layer whose upper surface is covered with a conductive film.

实施例4Example 4

(1)将4g镀镍碳纤维(直径为0.2mm、长度为2mm、导电系数为1.5×10-3Ω·cm、磁导率为8×103H/m)加入16g基体材料(聚二甲基硅氧烷(PDMS))中,在2000rpm下搅拌20min,混合均匀后倒入平板模具(材质:亚克力(聚甲基丙烯酸甲酯;4cm(长)×4cm(宽)×2mm(高)),模具底部为表面为光滑亚克力材料)中,并将混合后的镀镍碳纤维和基体材料的表面刮涂(用薄刀片在基底材料上进行均匀刮膜)平整,之后将装有镀镍碳纤维和基体材料的模具放置于垂直方向的磁场中,在0.2T的磁场(均匀磁场)诱导下使其中的镀镍碳纤维沿磁场方向进行定向扭转,得到介电层前体;之后在得到的介电层的上表面覆盖一层厚度为50μm的导电薄膜(铜网,4cm(长)×4cm(宽)),室温下静置,10min自流平,得到上表面覆盖有导电薄膜的介电层前体;(1) Add 4g nickel-plated carbon fiber (diameter 0.2mm, length 2mm, conductivity 1.5×10-3Ω·cm, magnetic permeability 8×103H/m) into 16g base material (polydimethylsiloxane alkane (PDMS)), stir at 2000rpm for 20min, mix well and pour into a flat mold (material: acrylic (polymethyl methacrylate; 4cm (length) × 4cm (width) × 2mm (height)), the bottom of the mold The surface is smooth acrylic material), and the surface of the mixed nickel-plated carbon fiber and the base material is scraped (using a thin blade to uniformly scrape the base material), and then the nickel-plated carbon fiber and the base material The mold is placed in a vertical magnetic field, and under the induction of a 0.2T magnetic field (uniform magnetic field), the nickel-plated carbon fibers in it are oriented and twisted along the direction of the magnetic field to obtain a dielectric layer precursor; then, on the upper surface of the obtained dielectric layer Cover a layer of conductive film (copper mesh, 4cm (length) × 4cm (width)) with a thickness of 50 μm, stand at room temperature, and self-leveling for 10 minutes to obtain a dielectric layer precursor covered with a conductive film on the upper surface;

将得到的介电层前体在70℃下进行热固化60min,得到上表面覆盖有导电薄膜的介电层,其中,介电层的厚度为2mm;The obtained dielectric layer precursor is thermally cured at 70° C. for 60 minutes to obtain a dielectric layer with a conductive film covering the upper surface, wherein the thickness of the dielectric layer is 2 mm;

(2)采用磁控溅射(时间为30min)制备叉指电极,叉指电极上沉积铜的厚度为100nm,叉指电极的厚度为72μm,叉指电极的叉指线宽和线距各自为150μm;将其作为下电极粘覆至上述上表面覆盖有导电薄膜的介电层的下表面。(2) The interdigital electrodes were prepared by magnetron sputtering (the time was 30 min), the thickness of the copper deposited on the interdigital electrodes was 100 nm, the thickness of the interdigital electrodes was 72 μm, and the interdigital line width and line spacing of the interdigital electrodes were respectively 150 μm; stick it as a lower electrode to the lower surface of the dielectric layer whose upper surface is covered with a conductive film.

对比例1Comparative Example 1

按照实施例1的方式进行,不同的是,不用磁场对镀镍碳纤维进行定向诱导。The method of Example 1 was carried out, except that the orientation induction of the nickel-plated carbon fibers was not performed with a magnetic field.

对上述得到的压力传感器进行效果测试:Test the effect of the pressure sensor obtained above:

图3中(a)是利用线性马达对实施例1,实施例4,和对比例1制备的压力传感器施加可变的压力,其中,采用数字源表吉时利-2400(来施加恒定的电压,采用数字源表吉时利-6517来进行电流的测试。由测试结果可知,实时电流与初始电流的比值随施加压力的增大而增大。(a) in Figure 3 is the use of linear motor to apply variable pressure to the pressure sensors prepared in Example 1, Example 4, and Comparative Example 1, wherein a digital source meter Keithley-2400 ( is used to apply a constant voltage , using the digital source meter Keithley-6517 to test the current. According to the test results, the ratio of the real-time current to the initial current increases with the increase of the applied pressure.

图3中(a)的测试结果表明实施例1,实施例4和对比例1制备的压力传感对压力有较好的响应度。The test results of (a) in FIG. 3 show that the pressure sensors prepared in Example 1, Example 4 and Comparative Example 1 have good response to pressure.

对于图3中(a)的不同的曲线、不同的斜率分别说明实施例1制备的压力传感器对压力的响应度要远远地高于实施例4和对比例1。The different curves and different slopes of (a) in FIG. 3 respectively show that the response of the pressure sensor prepared in Example 1 to pressure is much higher than that in Example 4 and Comparative Example 1.

图3中(b)与图3中(a)中的测试条件相同,分别代表的是实施例1,实施例2和实施例3对不同压力的响应电流。The test conditions in (b) in FIG. 3 are the same as those in (a) in FIG. 3 , respectively representing the response currents of Example 1, Example 2 and Example 3 to different pressures.

对于图3中(a)的不同的曲线、不同的斜率分别说明实施例1制备的压力传感器对压力的响应度要远远地高于实施例2和实施例3。The different curves and different slopes of (a) in FIG. 3 respectively indicate that the response of the pressure sensor prepared in Example 1 to pressure is much higher than that in Examples 2 and 3.

图3中(c)是对实施例1制备的压力传感器测试的电压与电流成线性关系图。测试方法为电化学工作站,施加可变电压,测试其电流。结果表明实施1制备的压力传感器为纯电阻器件。(c) in FIG. 3 is a graph showing a linear relationship between the voltage and the current tested on the pressure sensor prepared in Example 1. The test method is an electrochemical workstation, applying a variable voltage and testing its current. The results show that the pressure sensor prepared in Example 1 is a pure resistance device.

图3中(d)-(g)测试方法与(a)和(b)相同。The test methods of (d)-(g) in Figure 3 are the same as those of (a) and (b).

图3中(d)表示在具体施加的压力(1-100kPa下,如1kPa、15kPa、38kPa、48kPa和58kPa)下,实施例1制备的压力传感器对应的电流;结果表明输出的电流信号在同一压力刺激下稳定且随压力增长而增大。(d) in Figure 3 represents the current corresponding to the pressure sensor prepared in Example 1 under a specific applied pressure (1-100kPa, such as 1kPa, 15kPa, 38kPa, 48kPa, and 58kPa); the results show that the output current signal is in the same Stable under stressful stimulation and increased with increasing stress.

图3中(e)表示,实施例1制备的压力传感器输出电流随频率的加快而加快,且不会随着施加力频率的增大而增大。(e) in FIG. 3 shows that the output current of the pressure sensor prepared in Example 1 increases with the increase of the frequency, and does not increase with the increase of the applied force frequency.

图3中(f)表示对实施例1制备的压力传感器施加力,电流的响应时间为30ms,施加力的即刻产生电流信号。表明器件信号对压力响应快。(f) in FIG. 3 shows that a force is applied to the pressure sensor prepared in Example 1, the response time of the current is 30ms, and a current signal is generated immediately when the force is applied. It indicates that the device signal responds quickly to pressure.

图3中(g)表示实施例1制备的压力传感器的电流信号在3000次循环下,依然保持较好的稳定性。(g) in FIG. 3 shows that the current signal of the pressure sensor prepared in Example 1 still maintains good stability under 3000 cycles.

以上详细描述了本发明的优选实施方式,但是,本发明并不限于此。在本发明的技术构思范围内,可以对本发明的技术方案进行多种简单变型,包括各个技术特征以任何其它的合适方式进行组合,这些简单变型和组合同样应当视为本发明所公开的内容,均属于本发明的保护范围。The preferred embodiments of the present invention have been described above in detail, however, the present invention is not limited thereto. Within the scope of the technical concept of the present invention, a variety of simple modifications can be made to the technical solutions of the present invention, including combining various technical features in any other suitable manner. These simple modifications and combinations should also be regarded as the content disclosed in the present invention. All belong to the protection scope of the present invention.

Claims (14)

1. A pressure sensor having a unidirectional electrical conduction function, the pressure sensor comprising: the flexible electrode structure comprises two layers of flexible electrodes and a dielectric layer positioned between the two layers of flexible electrodes; the dielectric layer comprises a base material and magnetic conductive fibers distributed in the base material, and the magnetic conductive fibers are arranged in a direction perpendicular to the flexible electrodes.
2. The pressure sensor of claim 1, wherein the weight ratio of the base material to the magnetic conductive fibers is (3-25): 1;
and/or the magnetic conductive fiber is cylindrical; preferably, the length of the magnetic conductive fiber is 0.5-3mm, and the diameter is 0.1-0.3 mm;
and/or the conductivity coefficient of the magnetic conductive fiber is (1.5-2) multiplied by 10-3Omega cm; magnetic permeability of (8-9) × 103H/m。
3. Pressure sensor according to claim 1 or 2, wherein the magnetic conductive fibers are selected from at least one of nickel-plated carbon fibers, nickel-plated metal fibers, nickel-plated stainless steel, iron-plated carbon fibers and cobalt-plated carbon fibers, preferably nickel-plated carbon fibers and/or cobalt-plated carbon fibers.
4. The pressure sensor of claim 1 or 2, wherein the dielectric layer has a thickness of 2mm-5 mm;
and/or, the substrate material is selected from a thermosetting material and/or a photo-curing material;
preferably, the thermosetting material is selected from polydimethylsiloxane and/or silica gel;
preferably, the light-curable material is a light-sensitive polyurethane.
5. The pressure sensor of claim 1 or 2, wherein the two layers of flexible electrodes each independently have a thickness of 20-70 μ ι η;
and/or the flexible electrode is selected from an interdigital electrode and/or a conductive metal electrode;
preferably, the upper electrode of the pressure sensor is a conductive metal electrode, and the lower electrode is an interdigital electrode;
preferably, the number of pairs of the interdigital electrodes is 8-20 pairs;
preferably, the line width and the line distance of the interdigital electrode are respectively and independently 100-200 μm;
preferably, the conductive metal electrode is a mesh electrode; the conductive metal electrode is selected from at least one of a copper electrode, a nickel cloth and a silver cloth.
6. The pressure sensor according to any of claims 1-5, wherein the sensitivity of the pressure sensor is 10000-40000kPa-1
7. A method of making a pressure sensor having a single-direction conductive function, the method comprising: the magnetic conductive fibers are directionally distributed in the base material, and the flexible electrode is assembled;
wherein the magnetic conductive fibers are aligned perpendicular to the flexible electrodes.
8. The method of claim 7, wherein assembling the flexible electrode comprises: curing the flexible electrode and the matrix material distributed with the magnetic conductive fibers together;
or after the matrix material distributed with the magnetic conductive fibers is solidified, the flexible electrode is adhered and covered.
9. The method of claim 7 or 8, wherein the magnetically conductive fibers are directionally distributed in the matrix material by:
and mixing the magnetic conductive fibers with the matrix material, and placing the mixture into a mold, wherein the conductive fibers are directionally distributed in the matrix material in a direction parallel to a magnetic field under the induction of the magnetic field perpendicular to the mold.
10. The method of claim 9, wherein the weight ratio of the base material to the magnetic, electrically conductive fibers is (5-20): 1;
and/or the magnetic conductive fiber is cylindrical; preferably, the length of the magnetic conductive fiber is 0.5-3mm, and the diameter is 0.1-0.3 mm;
and/or the conductivity coefficient of the magnetic conductive fiber is (1.5-2) multiplied by 10-3Omega cm; magnetic permeability of (8-9) × 103H/m;
And/or the magnetic conductive fiber is selected from at least one of nickel-plated carbon fiber, nickel-plated metal fiber, nickel-plated stainless steel, iron-plated carbon fiber and cobalt-plated carbon fiber, preferably nickel-plated carbon fiber and/or cobalt-plated carbon fiber;
and/or, the substrate material is selected from a thermosetting material and/or a photo-curing material;
preferably, the thermosetting material is selected from polydimethylsiloxane and/or silica gel;
preferably, the light-curable material is a photosensitive polyurethane;
and/or, the mould is a flat mould; the bottom of the mold is made of abrasive paper;
and/or, the mixing is carried out under stirring; the stirring speed is 1500-3000rpm, and the time is 20-30 min;
and/or, the magnetic field-induced conditions comprise: the magnetic field intensity is 0.1-0.3T; the magnetic field induction is carried out under a uniform magnetic field;
and/or, the curing is photo-curing or thermal curing;
preferably, the conditions of photocuring include: the wavelength of the ultraviolet light is 360-380nm, the intensity is 20-50W, and the time is 20-30 s;
preferably, the conditions for the thermal curing include: at 70-80 deg.C for 60-90 min.
11. The method of any one of claims 7-10, wherein the flexible electrode has a thickness of 20 μ ι η to 70 μ ι η;
and/or the flexible electrode is selected from an interdigital electrode and/or a conductive metal electrode;
preferably, the upper electrode of the pressure sensor is a conductive metal electrode, and the lower electrode is an interdigital electrode;
preferably, the conductive metal electrode is a mesh electrode; the conductive metal electrode is selected from at least one of a copper electrode, a nickel cloth and a silver cloth;
preferably, the number of pairs of the interdigital electrodes is 8-20 pairs;
preferably, the line width and the line distance of the interdigital electrode are respectively and independently 100-200 μm;
preferably, the conductive metal electrode is a mesh electrode; the conductive metal electrode is selected from at least one of a copper electrode, a nickel cloth and a silver cloth;
preferably, the interdigital electrode is prepared by magnetron sputtering, wherein the magnetron sputtering time is 20-40min,
and/or the magnetron sputtering ensures that the thickness of the metal deposited on the interdigital electrode is 70-100 nm;
preferably, the deposited metal is selected from copper and/or gold, preferably copper.
12. A pressure sensor prepared by the method of any one of claims 7-11.
13. Use of a pressure sensor according to any of claims 1-6 and 12 in the field of wearable devices and/or human-computer interaction.
14. A wearable device, characterized in that it comprises a pressure sensor according to any of claims 1-6 and 12.
CN202111424219.0A 2021-11-26 2021-11-26 Pressure sensor with unidirectional conductive function and preparation method and application thereof Active CN114383761B (en)

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