CN114149870A - Complex iodine floor disinfection cleaning agent and preparation process thereof - Google Patents
Complex iodine floor disinfection cleaning agent and preparation process thereof Download PDFInfo
- Publication number
- CN114149870A CN114149870A CN202111546022.4A CN202111546022A CN114149870A CN 114149870 A CN114149870 A CN 114149870A CN 202111546022 A CN202111546022 A CN 202111546022A CN 114149870 A CN114149870 A CN 114149870A
- Authority
- CN
- China
- Prior art keywords
- iodine
- floor
- complex
- complex iodine
- defoaming agent
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- ZCYVEMRRCGMTRW-UHFFFAOYSA-N 7553-56-2 Chemical compound [I] ZCYVEMRRCGMTRW-UHFFFAOYSA-N 0.000 title claims abstract description 72
- 239000011630 iodine Substances 0.000 title claims abstract description 72
- 229910052740 iodine Inorganic materials 0.000 title claims abstract description 72
- 238000004659 sterilization and disinfection Methods 0.000 title claims abstract description 46
- 239000012459 cleaning agent Substances 0.000 title claims abstract description 18
- 238000002360 preparation method Methods 0.000 title claims abstract description 14
- 239000002518 antifoaming agent Substances 0.000 claims abstract description 40
- 239000003381 stabilizer Substances 0.000 claims abstract description 19
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 14
- 125000003118 aryl group Chemical group 0.000 claims abstract description 12
- PNDPGZBMCMUPRI-UHFFFAOYSA-N iodine Chemical compound II PNDPGZBMCMUPRI-UHFFFAOYSA-N 0.000 claims abstract description 7
- 229920001519 homopolymer Polymers 0.000 claims description 13
- 239000001267 polyvinylpyrrolidone Substances 0.000 claims description 12
- 235000013855 polyvinylpyrrolidone Nutrition 0.000 claims description 12
- 229920000036 polyvinylpyrrolidone Polymers 0.000 claims description 12
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 9
- NLKNQRATVPKPDG-UHFFFAOYSA-M potassium iodide Chemical compound [K+].[I-] NLKNQRATVPKPDG-UHFFFAOYSA-M 0.000 claims description 9
- FVAUCKIRQBBSSJ-UHFFFAOYSA-M sodium iodide Chemical compound [Na+].[I-] FVAUCKIRQBBSSJ-UHFFFAOYSA-M 0.000 claims description 9
- 238000003756 stirring Methods 0.000 claims description 9
- 239000004721 Polyphenylene oxide Substances 0.000 claims description 8
- 229920000570 polyether Polymers 0.000 claims description 8
- 238000011012 sanitization Methods 0.000 claims description 7
- 235000019501 Lemon oil Nutrition 0.000 claims description 5
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims description 5
- 239000010501 lemon oil Substances 0.000 claims description 5
- JLKDVMWYMMLWTI-UHFFFAOYSA-M potassium iodate Chemical compound [K+].[O-]I(=O)=O JLKDVMWYMMLWTI-UHFFFAOYSA-M 0.000 claims description 5
- 239000001230 potassium iodate Substances 0.000 claims description 5
- 235000006666 potassium iodate Nutrition 0.000 claims description 5
- 229940093930 potassium iodate Drugs 0.000 claims description 5
- 229910052710 silicon Inorganic materials 0.000 claims description 5
- 239000010703 silicon Substances 0.000 claims description 5
- 239000001509 sodium citrate Substances 0.000 claims description 5
- NLJMYIDDQXHKNR-UHFFFAOYSA-K sodium citrate Chemical compound O.O.[Na+].[Na+].[Na+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O NLJMYIDDQXHKNR-UHFFFAOYSA-K 0.000 claims description 5
- 238000010668 complexation reaction Methods 0.000 claims description 4
- 238000010438 heat treatment Methods 0.000 claims description 4
- 239000007790 solid phase Substances 0.000 claims description 4
- UNMYWSMUMWPJLR-UHFFFAOYSA-L Calcium iodide Chemical compound [Ca+2].[I-].[I-] UNMYWSMUMWPJLR-UHFFFAOYSA-L 0.000 claims description 3
- 235000005976 Citrus sinensis Nutrition 0.000 claims description 3
- 240000002319 Citrus sinensis Species 0.000 claims description 3
- UIIMBOGNXHQVGW-DEQYMQKBSA-M Sodium bicarbonate-14C Chemical compound [Na+].O[14C]([O-])=O UIIMBOGNXHQVGW-DEQYMQKBSA-M 0.000 claims description 3
- 229940046413 calcium iodide Drugs 0.000 claims description 3
- 229910001640 calcium iodide Inorganic materials 0.000 claims description 3
- 235000014113 dietary fatty acids Nutrition 0.000 claims description 3
- 239000000194 fatty acid Substances 0.000 claims description 3
- 229930195729 fatty acid Natural products 0.000 claims description 3
- 150000004665 fatty acids Chemical class 0.000 claims description 3
- 239000002480 mineral oil Substances 0.000 claims description 3
- 235000010446 mineral oil Nutrition 0.000 claims description 3
- 229910000403 monosodium phosphate Inorganic materials 0.000 claims description 3
- 235000019799 monosodium phosphate Nutrition 0.000 claims description 3
- NALMPLUMOWIVJC-UHFFFAOYSA-N n,n,4-trimethylbenzeneamine oxide Chemical compound CC1=CC=C([N+](C)(C)[O-])C=C1 NALMPLUMOWIVJC-UHFFFAOYSA-N 0.000 claims description 3
- 239000010502 orange oil Substances 0.000 claims description 3
- -1 polysiloxane Polymers 0.000 claims description 3
- 229920001296 polysiloxane Polymers 0.000 claims description 3
- 229960004839 potassium iodide Drugs 0.000 claims description 3
- 235000007715 potassium iodide Nutrition 0.000 claims description 3
- 235000011083 sodium citrates Nutrition 0.000 claims description 3
- AJPJDKMHJJGVTQ-UHFFFAOYSA-M sodium dihydrogen phosphate Chemical compound [Na+].OP(O)([O-])=O AJPJDKMHJJGVTQ-UHFFFAOYSA-M 0.000 claims description 3
- 235000011121 sodium hydroxide Nutrition 0.000 claims description 3
- 239000011697 sodium iodate Substances 0.000 claims description 3
- 235000015281 sodium iodate Nutrition 0.000 claims description 3
- 229940032753 sodium iodate Drugs 0.000 claims description 3
- 235000009518 sodium iodide Nutrition 0.000 claims description 3
- 229940083599 sodium iodide Drugs 0.000 claims description 3
- 238000004519 manufacturing process Methods 0.000 claims 2
- 230000000694 effects Effects 0.000 abstract description 20
- 238000000034 method Methods 0.000 abstract description 6
- 239000002023 wood Substances 0.000 abstract description 5
- 238000005202 decontamination Methods 0.000 abstract description 4
- 230000003588 decontaminative effect Effects 0.000 abstract description 4
- 230000008569 process Effects 0.000 abstract description 3
- 239000000919 ceramic Substances 0.000 abstract description 2
- 238000002791 soaking Methods 0.000 abstract 1
- 238000012360 testing method Methods 0.000 description 27
- 230000001954 sterilising effect Effects 0.000 description 11
- 239000000645 desinfectant Substances 0.000 description 10
- 230000002147 killing effect Effects 0.000 description 9
- 241000894006 Bacteria Species 0.000 description 8
- 241000233866 Fungi Species 0.000 description 8
- 239000003599 detergent Substances 0.000 description 8
- 238000004140 cleaning Methods 0.000 description 7
- 230000036541 health Effects 0.000 description 7
- 239000006260 foam Substances 0.000 description 6
- 241000222122 Candida albicans Species 0.000 description 5
- 241000588724 Escherichia coli Species 0.000 description 5
- 241000191967 Staphylococcus aureus Species 0.000 description 5
- 230000001580 bacterial effect Effects 0.000 description 5
- 229940095731 candida albicans Drugs 0.000 description 5
- 239000002736 nonionic surfactant Substances 0.000 description 4
- 238000011160 research Methods 0.000 description 4
- 238000010998 test method Methods 0.000 description 4
- 238000005034 decoration Methods 0.000 description 3
- 239000003814 drug Substances 0.000 description 3
- 238000007689 inspection Methods 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- 239000000203 mixture Substances 0.000 description 3
- 229920000642 polymer Polymers 0.000 description 3
- 239000008213 purified water Substances 0.000 description 3
- 241000700605 Viruses Species 0.000 description 2
- 230000000844 anti-bacterial effect Effects 0.000 description 2
- 230000002860 competitive effect Effects 0.000 description 2
- 238000001514 detection method Methods 0.000 description 2
- 238000011156 evaluation Methods 0.000 description 2
- 238000005187 foaming Methods 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 238000005070 sampling Methods 0.000 description 2
- 239000011550 stock solution Substances 0.000 description 2
- 239000000725 suspension Substances 0.000 description 2
- 102000004506 Blood Proteins Human genes 0.000 description 1
- 108010017384 Blood Proteins Proteins 0.000 description 1
- 229920000742 Cotton Polymers 0.000 description 1
- 239000003899 bactericide agent Substances 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 235000019864 coconut oil Nutrition 0.000 description 1
- 239000003240 coconut oil Substances 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 230000000249 desinfective effect Effects 0.000 description 1
- 238000010790 dilution Methods 0.000 description 1
- 239000012895 dilution Substances 0.000 description 1
- 230000036267 drug metabolism Effects 0.000 description 1
- 238000003255 drug test Methods 0.000 description 1
- 239000000428 dust Substances 0.000 description 1
- 230000003670 easy-to-clean Effects 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 235000013305 food Nutrition 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 230000002538 fungal effect Effects 0.000 description 1
- 239000010648 geranium oil Substances 0.000 description 1
- 235000019717 geranium oil Nutrition 0.000 description 1
- 239000008233 hard water Substances 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 238000013095 identification testing Methods 0.000 description 1
- 230000007794 irritation Effects 0.000 description 1
- 230000007246 mechanism Effects 0.000 description 1
- 239000001525 mentha piperita l. herb oil Substances 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 230000009972 noncorrosive effect Effects 0.000 description 1
- 231100000956 nontoxicity Toxicity 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 235000019198 oils Nutrition 0.000 description 1
- 230000036961 partial effect Effects 0.000 description 1
- 235000019477 peppermint oil Nutrition 0.000 description 1
- XKJCHHZQLQNZHY-UHFFFAOYSA-N phthalimide Chemical compound C1=CC=C2C(=O)NC(=O)C2=C1 XKJCHHZQLQNZHY-UHFFFAOYSA-N 0.000 description 1
- 230000003449 preventive effect Effects 0.000 description 1
- 150000003242 quaternary ammonium salts Chemical group 0.000 description 1
- 230000002829 reductive effect Effects 0.000 description 1
- 235000019719 rose oil Nutrition 0.000 description 1
- 239000010666 rose oil Substances 0.000 description 1
- 239000010671 sandalwood oil Substances 0.000 description 1
- 238000004088 simulation Methods 0.000 description 1
- 239000002689 soil Substances 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 238000013112 stability test Methods 0.000 description 1
- 238000012916 structural analysis Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 238000013268 sustained release Methods 0.000 description 1
- 239000012730 sustained-release form Substances 0.000 description 1
- 239000008399 tap water Substances 0.000 description 1
- 235000020679 tap water Nutrition 0.000 description 1
- 231100000167 toxic agent Toxicity 0.000 description 1
- 239000003440 toxic substance Substances 0.000 description 1
- 231100000027 toxicology Toxicity 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- 239000000080 wetting agent Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N59/00—Biocides, pest repellants or attractants, or plant growth regulators containing elements or inorganic compounds
- A01N59/12—Iodine, e.g. iodophors; Compounds thereof
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/04—Water-soluble compounds
- C11D3/044—Hydroxides or bases
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/04—Water-soluble compounds
- C11D3/046—Salts
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/04—Water-soluble compounds
- C11D3/06—Phosphates, including polyphosphates
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/04—Water-soluble compounds
- C11D3/10—Carbonates ; Bicarbonates
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2075—Carboxylic acids-salts thereof
- C11D3/2086—Hydroxy carboxylic acids-salts thereof
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/26—Organic compounds containing nitrogen
- C11D3/32—Amides; Substituted amides
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3703—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C11D3/3707—Polyethers, e.g. polyalkyleneoxides
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3703—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C11D3/373—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing silicones
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/38—Products with no well-defined composition, e.g. natural products
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/38—Products with no well-defined composition, e.g. natural products
- C11D3/382—Vegetable products, e.g. soya meal, wood flour, sawdust
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/48—Medical, disinfecting agents, disinfecting, antibacterial, germicidal or antimicrobial compositions
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02A—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
- Y02A50/00—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE in human health protection, e.g. against extreme weather
- Y02A50/30—Against vector-borne diseases, e.g. mosquito-borne, fly-borne, tick-borne or waterborne diseases whose impact is exacerbated by climate change
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Wood Science & Technology (AREA)
- Engineering & Computer Science (AREA)
- Organic Chemistry (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Inorganic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Dentistry (AREA)
- General Health & Medical Sciences (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Plant Pathology (AREA)
- Pest Control & Pesticides (AREA)
- Agronomy & Crop Science (AREA)
- Emergency Medicine (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
- Detergent Compositions (AREA)
Abstract
The invention provides a complex iodine floor disinfection cleaner and a preparation process thereof, wherein the complex iodine floor disinfection cleaner comprises the following components in percentage by weight: 0.1-3.0% of complex iodine, 0.01-1.0% of defoaming agent, 0.01-0.4% of stabilizing agent, 0.01-0.2% of aromatic, 0.01-0.5% of pH regulator and the balance of water; wherein the weight ratio of the complex iodine to the defoaming agent is 4:1, and the weight ratio of the complex iodine to the stabilizing agent is 12: 1. The complex iodine floor disinfection cleaning agent has the advantages of good disinfection effect, strong decontamination capability, no corrosiveness to wood floors, ceramic tiles and the like, high soaking speed in the use process and strong rinsing capability.
Description
Technical Field
The invention relates to the technical field of floor disinfectants, in particular to a complex iodine floor disinfection cleaning agent and a preparation process thereof.
Background
The complex iodine is the only iodine which passes through the FDA in the United states, is recognized and widely adopted, and is the only iodine which is listed as a national basic disinfection medicament by the Ministry of health in China. Complex iodine is a high molecular polymer physiologically similar to human plasma protein, and is the best one of nonionic surfactants. It has stable property, no toxicity, no odor, and good effects of film forming, adhesion, removing toxic substance, and sustained release. From the advent to the present, scientists in various countries prove that hydrogen bonds of high molecular polymers can be tightly complexed with iodine molecules through chemical preparation, formulation research, structural analysis, pharmacology, toxicology, drug metabolism, sterilization mechanism and kinetic research thereof, and the intermolecular complexation effectively reduces the corrosivity and irritation of iodine and ensures that products are safer.
Preventive disinfection and sanitation protection measures for families and public places are taken, and the method is important for the health and safety of the public. At present, wood floors are mostly adopted in home decoration, hotel decoration, exhibition hall decoration and the like, but after the wood floors are used for a period of time, bacteria are easy to breed, dirt is not easy to clean, so that the dirt removing capability is strong, and the sterilizing cleaning agent with a good sterilizing effect is an urgent need in the market.
Patent CN201710936360.6 describes a disinfectant special for floors, which is composed of surfactant, wetting agent, bactericide and purified water, wherein the bactericidal component is quaternary ammonium salt, and the cleaning component is nonionic surfactant. The sterilizing component in the patent is a low-efficiency disinfectant, and the added nonionic surfactant is easy to use to generate foam, so that the using effect is influenced. Patent CN201410233430.8 describes a wooden floor sterilization cleaning agent, the sterilization component of which is phthalimide, the sterilization effect on partial bacterial propagules, fungi and viruses is poor, and the product can be only used within the range of 10-35 ℃, and the application range is narrow.
Disclosure of Invention
In order to make up for the defects in the prior art, the invention provides the complex iodine floor disinfection cleaning agent which has the advantages of good disinfection effect, strong decontamination capability, no corrosiveness to wood floors, ceramic tiles and the like, high defoaming speed, strong rinsing capability and the like in the use process.
In order to achieve the purpose, the technical scheme adopted by the invention is as follows:
the complex iodine floor disinfection cleaner comprises the following components in percentage by weight: 0.1-3.0% of complex iodine, 0.01-1.0% of defoaming agent, 0.01-0.4% of stabilizing agent, 0.01-0.2% of aromatic, 0.01-0.5% of pH regulator and the balance of water; wherein the weight ratio of the complex iodine to the defoaming agent is 4:1, and the weight ratio of the complex iodine to the stabilizing agent is 12: 1.
In the scheme, the weight ratio of the defoaming agent to the stabilizer is particularly critical, and if the ratio of the defoaming agent is too small, the defoaming effect is weakened, and the brightness after cleaning is insufficient; if the proportion of the defoaming agent is too high and the proportion of the stabilizing agent is too small, the phenomenon of sudden drop of the sterilization effect can occur; only in the proportion, all the advantages can be considered, and the optimal technical effect is achieved.
Furthermore, the iodine complex is prepared by high-temperature solid-phase complexation of iodine and a polyvinylpyrrolidone homopolymer, wherein the average molecular weight of the polyvinylpyrrolidone homopolymer is 35000-50000, and the preferable average molecular weight is 42000.
Further, the defoaming agent is one of a fatty acid amide defoaming agent, a polysiloxane defoaming agent, a polyether defoaming agent, an organosilicon defoaming agent, a polyether modified organosilicon defoaming agent and a mineral oil defoaming agent, and preferably is a polyether modified organosilicon defoaming agent.
Further, the stabilizer is one or more of potassium iodate, sodium iodate, potassium iodide, sodium iodide and calcium iodide, and preferably potassium iodate.
Further, the aromatic is one of peppermint oil, sandalwood oil, lemon oil, sweet orange oil, rose oil, geranium oil and coconut oil, and lemon oil is preferred.
Further, the pH regulator is one or more of sodium citrate, sodium bicarbonate, sodium dihydrogen phosphate and sodium hydroxide, preferably sodium citrate.
As a preferable scheme, the complex iodine floor disinfection cleaning agent comprises the following components in percentage by weight: 1.0-2.0% of complex iodine, 0.25-0.50% of defoaming agent, 0.08-0.25% of stabilizer, 0.05-0.12% of aromatic, 0.1-0.3% of pH regulator and the balance of water. Wherein the weight ratio of the complex iodine to the defoaming agent is 4:1, and the weight ratio of the complex iodine to the stabilizing agent is 12: 1.
The invention also provides a preparation process of the complex iodine floor disinfection cleaning agent, which comprises the following steps:
s1, placing iodine and polyvinylpyrrolidone homopolymer in a reactor, heating and carrying out rotary mixing to obtain complex iodine;
s2, adding part of water into a preparation container, adding the prepared complex iodine, stirring, adjusting the pH to weak acidity by using a pH regulator, sequentially adding a stabilizer, a defoaming agent and an aromatic into the preparation container, stirring until the components are completely dissolved, adding water to the total amount, and stirring uniformly.
Further, in step S1, the weight ratio of iodine to polyvinylpyrrolidone homopolymer was 8: 1, the heating temperature was 75 ℃, and the rotational mixing time was 18 hours.
Compared with the prior art, the invention has the following beneficial technical effects:
1. the complex iodine floor disinfection cleaning agent can quickly kill bacteria, spores, viruses, fungi and the like attached to the floor, and has a good disinfection effect. Meanwhile, the polymer homopolymer of the product can change the wettability of objects, so that an extremely thin sterilization film is formed on the floor, effective iodine can be slowly released, and the sterilization effect is durable.
2. The polyvinylpyrrolidone homopolymer used in the invention is a high molecular nonionic surfactant, has good hydrophilicity and lipophilicity, is non-corrosive, can efficiently remove floor stains, and can quickly dry, comfortable, and permanently bright the floor after being used.
3. The complex iodine floor disinfection cleaning agent has the advantages of high defoaming speed and strong rinsing capacity in use, only needs to be mopped once, does not need to be mopped and washed by clean water again, and is convenient and quick to use and good in user experience.
Detailed Description
In the following description, numerous specific details are set forth in order to provide a thorough understanding of the present invention. This invention may, however, be embodied in many different forms and should not be construed as limited to the embodiments set forth herein.
TABLE 1 Complex iodine floor sanitizing cleaner compositions of examples 1-5 (weight percent)
| Example 1 | Example 2 | Example 3 | Example 4 | Example 5 | |
| Complex iodine | 0.1 | 1.0 | 1.5 | 2.0 | 3.0 |
| Defoaming agent | 0.01 | 0.25 | 0.38 | 050 | 0.75 |
| Stabilizer | 0.01 | 0.08 | 0.12 | 0.17 | 0.25 |
| Aromatic agent | 0.01 | 0.09 | 0.12 | 0.16 | 0.20 |
| pH regulator | 0.01 | 0.15 | 0.25 | 0.30 | 0.50 |
| Water (W) | 99.60 | 98.43 | 97.63 | 96.87 | 95.30 |
Wherein the weight ratio of the complex iodine to the defoaming agent is 4:1, and the weight ratio of the complex iodine to the stabilizing agent is 12: 1.
The complex iodine is formed by high-temperature solid-phase complexation of iodine and polyvinylpyrrolidone homopolymer, wherein the average molecular weight of the polyvinylpyrrolidone homopolymer is 35000-50000, and the preferable average molecular weight is 42000.
The defoaming agent is one of fatty acid amide defoaming agent, polysiloxane defoaming agent, polyether defoaming agent, organic silicon defoaming agent, polyether modified organic silicon defoaming agent and mineral oil defoaming agent, preferably polyether modified organic silicon defoaming agent.
The stabilizer is one or more of potassium iodate, sodium iodate, potassium iodide, sodium iodide and calcium iodide, and preferably potassium iodate.
The aromatic is one of oleum Menthae Dementholatum, oleum Santali albi, lemon oil, sweet orange oil, oleum Rosae Rugosae, oleum Neocinnamomi Delavayi, and oleum Cocois, preferably lemon oil.
One or more of pH regulator sodium citrate, sodium bicarbonate, sodium dihydrogen phosphate and sodium hydroxide, preferably sodium citrate.
The preparation process of the complex iodine floor disinfection cleaner of the above examples 1-5 is as follows:
s1, mixing iodine and polyvinylpyrrolidone homopolymer according to the ratio of 8: the mixture is put into a solid phase complex reaction kettle according to the proportion of 1, and the materials are fully rotated and mixed for 18 hours at the temperature of 75 ℃ to obtain the complex iodine.
S2, adding purified water accounting for 60% of the total preparation amount into the preparation tank, adding complex iodine accounting for the prescription amount, uniformly stirring for 40 minutes, and adjusting the pH value of the liquid medicine to 4.0-5.0 by using a pH regulator. Then adding the stabilizer, the defoaming agent and the aromatic into the preparation tank in sequence according to the proportion, and uniformly stirring for 20 minutes until the materials are completely dissolved. And finally, adding purified water to a specified amount, uniformly stirring for 25 minutes, and subpackaging the obtained liquid medicine to obtain a finished product.
Proof of Effect test
1. Stability of complex iodine floor disinfecting cleaner
The stability study of the 1.0% complex iodine floor disinfection cleaner of the invention is carried out on 3 batches of products (batch numbers: 210310AS1, 210310BS1 and 210310CS1) respectively subjected to accelerated stability tests at 37 ℃/3 months and 54 ℃/14 days according to the requirements of the disinfection technical Specification (2002 edition) of the Ministry of health, and specifically comprises the following steps:
37 ℃/3 months: placing the test sample at 37 + -2 deg.C, and sampling and detecting at month 1, month 2 and month 3;
54 ℃/14 days: placing the test sample at 54 + -2 deg.C, and sampling and detecting at 5 days, 10 days and 14 days;
detection indexes are as follows: properties, identification, pH value and content.
TABLE 21.0% Complex iodine floor sanitizer high temperature test (37 + -2 deg.C) test results
TABLE 31.0% Complex iodine floor disinfectant Cleaner high temperature test (54 ℃. + -. 2 ℃) test results table
The inspection results of three batches of 1.0 percent complex iodine floor disinfection cleaning agent products (batch numbers: 210310AS1, 210310BS1 and 210310CS1) at 37 +/-2 ℃/3 months and 54 +/-2 ℃/14 days are shown in tables 1 and 2, the detection results of the samples conform to the drawn-up product quality standard draft, the content of the effective components of the products is reduced by less than 10 percent under 2 inspection conditions, and the product stability inspection requirements in the disinfection technical specification are met, which shows that the 1.0 percent complex iodine floor disinfection cleaning agent product has good stability and the prescription process is reasonable and feasible.
2. Research on disinfection effect of complex iodine floor disinfection detergent
The 1.0% iodine complex floor sanitizer product of the present invention (lot No. 210310AS1) was subjected to a bacteria/fungi quantitative kill test and a floor sanitizer field test to confirm the sanitizing effect of the product of the present invention in the actual use of floors.
2.1 test reagents
1.0% complex iodine floor disinfectant cleaner (batch No. 210310AS1), Staphylococcus aureus (Staphylococcus aureus), Escherichia coli (Escherichia coli), Candida albicans (Candida albicans), from the Chinese food and drug testing institute; the natural bacterial strain is from the floor of family and public place.
2.2 test apparatus
A constant temperature and humidity chamber DHS06A-D5-ST4, a biochemical incubator LRH-150B, a sterilizing cabinet XG1.DTXD-0.36B, an ultra-clean bench VS-1300-U and a biological safety cabinet BSC-1300-A2.
2.3 test methods
A. Bacterial/fungal quantitative kill test: washing fresh cultured staphylococcus aureus, escherichia coli and candida albicans with PBS, preparing the staphylococcus aureus and the escherichia coli into bacterial suspension with the concentration of 1 x 107 cfu/ml-5 x 107cfu/ml, and preparing the candida albicans into bacterial suspension with the concentration of 1 x 106 cfu/ml-5 x 106 cfu/ml. Then, according to the test method of the fungus killing test of disinfection technical Specification (2002 edition) -2.1.1.9 of Ministry of health, after the test sample is diluted by 150 times, the test sample acts for 1 minute, and the test is repeated for 3 times.
B. Floor disinfection field test: according to the test method of the simulation on-site identification of disinfectant on other surfaces by disinfectant technical Specification (2002 edition) 2.1.2.9 of Ministry of health, after test samples are diluted by 150 times, the test samples are acted for 1 minute, and 30 samples are tested.
2.4 results of the study
The results of the bacteria/fungi quantitative killing test and the floor disinfection field test of the 1.0 percent complex iodine floor disinfection cleaning agent are shown in tables 3 and 4, the stock solution is diluted by 150 times and acts for 1 minute, the average killing logarithm values of the escherichia coli, staphylococcus aureus and candida albicans are respectively more than 6.37, more than 6.51 and more than 5.21, and the results are in accordance with the disinfection technical specification (2002 edition) of the Ministry of health and the evaluation regulations of the bacteria/fungi quantitative killing test (the bacteria killing logarithm value is more than or equal to 5.00, and the fungi killing logarithm value is more than or equal to 4.00). In addition, after the stock solution is diluted by 150 times and acts for 1 minute, the average killing logarithm value of natural bacteria of household and public floors is 1.77, the killing rate is 98.25 percent, and the disinfection solution meets the evaluation regulation (the killing logarithm value is more than or equal to 1.00) of disinfection technical specification (2002) of the Ministry of health, namely a disinfectant simulates the on-site identification test of disinfection on other surfaces, which shows that the 1.0 percent complex iodine floor disinfection cleaning agent has good disinfection effect in practical use.
TABLE 41.0% iodine complex floor sanitizer results of quantitative kill of bacteria/fungi
TABLE 51.0% complex iodine floor disinfectant cleaner to floor disinfectant on-site test result table
3. Cleaning effect test of complex iodine floor disinfection cleaner
The 1.0 percent complex iodine floor disinfection cleaner product (batch number: 210310AS1) and the products with better public praise (competitive products 1 and 2) in the market are subjected to comparative research on foaming performance, anti-skid performance and decontamination performance so AS to confirm the cleaning effect of the product in the actual use of the floor.
3.1 test methods
A. And (3) measuring the foam performance: the foaming volumes of the 3 detergents were measured at 0min and 5min after dilution in the application ratio, as tested by the Ross-Mile method of GB/T13173-2008.
B. And (3) measuring the foam performance: after 3 kinds of cleaning agents are diluted according to the using proportion, a sponge mop or a cotton cloth mop is used for mopping the ground on the glazed tile. The tester wears the flat shoes (rubber soles) and the slippers (EVA soles) respectively and steps on the wood floor with the right foot to move back and forth, and the slip degree of the soles is evaluated. The sole is divided into 5 points when slipping easily, 3 points when slipping slightly and 1 point when not slipping, and the slip degree when mopping the floor with pure tap water is evaluated as 0 point.
C. And (3) measuring the foam performance: according to the detergency determination method of QB/T4532-2013, the detergency of a test soil piece on 3 cleaning agents prepared by hard water and having a concentration of 0.5% is detected. Detergency is expressed as a percentage, with a higher value indicating greater detergency.
3.2 results of the study
The results of comparison of cleaning test effects of the 3 detergents are shown in Table 5, the 0min foam amount of the product is equivalent to that of the competitive products 1 and 2, and the 5min foam amount is 0, 22ml and 26ml respectively, which shows that the product has high defoaming speed and good rinsing performance; the slip scores of the soles made of 2 materials of the 3 detergents are all 1, which shows that the anti-slip effect of the 3 detergents is good. The detergency of the 3 detergents is 96.3%, 95.7% and 96.1%, respectively, and the detergents have better capabilities of removing oil stains, dust, fibers and the like. In summary, this shows that the 1.0% complex iodine floor disinfection cleaner of the present invention has a fast defoaming speed, and good anti-skid, decontamination and cleaning effects compared with the similar products on the market.
TABLE 63 comparison of cleaning test results for detergents
Although the present invention has been described in detail with reference to the embodiments, it will be apparent to those skilled in the art that modifications may be made to the embodiments or portions thereof without departing from the spirit and scope of the invention.
Claims (9)
1. The complex iodine floor disinfection cleaning agent is characterized by comprising the following components in percentage by weight: 0.1-3.0% of complex iodine, 0.01-1.0% of defoaming agent, 0.01-0.4% of stabilizing agent, 0.01-0.2% of aromatic, 0.01-0.5% of pH regulator and the balance of water; wherein the weight ratio of the complex iodine to the defoaming agent is 4:1, and the weight ratio of the complex iodine to the stabilizing agent is 12: 1.
2. The complex iodine floor sanitizing cleaner of claim 1 wherein: the iodine complex is formed by high-temperature solid-phase complexation of iodine and a polyvinylpyrrolidone homopolymer, and the average molecular weight of the polyvinylpyrrolidone homopolymer is 35000-50000.
3. The complex iodine floor sanitizing cleaner of claim 2 wherein: the defoaming agent is one of a fatty acid amide defoaming agent, a polysiloxane defoaming agent, a polyether defoaming agent, an organic silicon defoaming agent, a polyether modified organic silicon defoaming agent and a mineral oil defoaming agent.
4. The complex iodine floor sanitizing cleaner of claim 3 wherein: the stabilizer is one or more of potassium iodate, sodium iodate, potassium iodide, sodium iodide and calcium iodide.
5. The complex iodine floor sanitizing cleaner of claim 4 wherein: the aromatic is selected from oleum Menthae Dementholatum, oleum Santali albi, lemon oil, sweet orange oil, oleum Rosae Rugosae, oleum Pelargonii Graveolentis, and oleum Cocois.
6. The complex iodine floor sanitizing cleaner of claim 5 wherein: the pH regulator is one or more of sodium citrate, sodium bicarbonate, sodium dihydrogen phosphate and sodium hydroxide.
7. The complex iodine floor sanitizer according to any one of claims 1 to 6 comprising in weight percent: 1.0-2.0% of complex iodine, 0.25-0.50% of defoaming agent, 0.08-0.25% of stabilizer, 0.05-0.12% of aromatic, 0.1-0.3% of pH regulator and the balance of water.
8. The process for preparing a complex iodine floor sanitizer according to any one of claims 1 to 7 comprising the steps of:
s1, placing iodine and polyvinylpyrrolidone homopolymer in a reactor, heating and carrying out rotary mixing to obtain complex iodine;
s2, adding part of water into a preparation container, adding the prepared complex iodine, stirring, adjusting the pH to weak acidity by using a pH regulator, sequentially adding a stabilizer, a defoaming agent and an aromatic into the preparation container, stirring until the components are completely dissolved, adding water to the total amount, and stirring uniformly.
9. The process for preparing a complex iodine floor sanitizer according to claim 8 wherein: in step S1, the weight ratio of iodine to polyvinylpyrrolidone homopolymer is 8: 1, the heating temperature is 75 ℃, and the rotary mixing time is 18 hours.
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1788568A (en) * | 2005-12-23 | 2006-06-21 | 张慧贤 | Quick-effective iodine disinfectant and production method thereof |
| CN104147043A (en) * | 2014-08-13 | 2014-11-19 | 武汉新大地环保材料有限公司 | Povidone iodine and preparation method and application thereof |
| CN105311050A (en) * | 2015-11-25 | 2016-02-10 | 上海银京医用卫生材料有限公司 | Traceless povidone iodine disinfectant |
| CN109362797A (en) * | 2018-12-04 | 2019-02-22 | 怀化学院 | Iodine disinfectant and preparation method thereof |
| CN113318122A (en) * | 2021-03-24 | 2021-08-31 | 厦门大开生物科技有限公司 | Disinfectant composition containing povidone iodine and application thereof |
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Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1788568A (en) * | 2005-12-23 | 2006-06-21 | 张慧贤 | Quick-effective iodine disinfectant and production method thereof |
| CN104147043A (en) * | 2014-08-13 | 2014-11-19 | 武汉新大地环保材料有限公司 | Povidone iodine and preparation method and application thereof |
| CN105311050A (en) * | 2015-11-25 | 2016-02-10 | 上海银京医用卫生材料有限公司 | Traceless povidone iodine disinfectant |
| CN109362797A (en) * | 2018-12-04 | 2019-02-22 | 怀化学院 | Iodine disinfectant and preparation method thereof |
| CN113318122A (en) * | 2021-03-24 | 2021-08-31 | 厦门大开生物科技有限公司 | Disinfectant composition containing povidone iodine and application thereof |
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