Disclosure of Invention
The invention aims to provide a formula of a hyaluronic acid collagen facial mask and a preparation method thereof, and aims to solve the problems in the background technology.
In order to achieve the above object, in one aspect, the present invention provides a formula of a hyaluronic acid collagen facial mask, comprising the following raw materials: skin conditioner, humectant, antiseptic and aromatic, and the balance of deionized water;
the skin conditioner comprises 0.03-0.6% of seaweed extract, 0.3-0.7% of milk extract and 0.5-2.5% of snail extract, the milk protein extract is helpful for maintaining the moisture balance of the skin, softly purifying the skin and simultaneously nourishing the skin, the snail extract has good whitening and moisturizing effects on the skin of people, can improve the relaxation and wrinkles of the skin after long-term use and effectively repair scars, has good repairing and healing effects on the damaged skin, accelerates the growth of cells and reduces scars;
the humectant comprises 0.001-0.02% of chondroitin sodium sulfate, 0.5-2.5% of hydrolyzed collagen and 0.01-0.2% of sodium hyaluronate, the chondroitin sodium sulfate is added into cosmetics, because of the polysaccharide structure, the collagen gel has good moisturizing property, can inhibit various bacteria, has anti-inflammatory effect, can promote the growth of cells, plays a role in resisting aging, has rich amino acid in hydrolyzed collagen, can improve the moisture supply of skin, supplement cell nutrition, relieve skin, tighten skin elasticity, promote metabolism and inhibit the generation of wrinkles, has strong viscoelasticity and lubricity, is coated on the surface of the skin, can form a layer of moisturizing breathable film to keep skin moist and bright, and the micromolecular hyaluronic acid can permeate into the dermis layer to promote blood microcirculation, be beneficial to the absorption of skin on nutrient substances and play a role in beautifying and anti-wrinkle health care.
As a further improvement of the technical scheme, the preservative is phenoxyethanol, the dosage of the phenoxyethanol is 0.05-0.25%, and the phenoxyethanol has the main function of being added into the application to play an antibacterial and antiseptic role and possibly has a certain emulsification effect to influence the viscosity of the skin care product.
As a further improvement of the technical scheme, the aromatic is essence, the using amount of the essence is 0.001-0.005%, and the essence can provide pleasant smell in cosmetics, cover the smell of a product matrix, help the product to establish a brand-new image and enhance the attraction of the product to customers.
As a further improvement of the technical scheme, the seaweed extract comprises a giant kelp extract, an austenitic seaweed extract and a bonadt spirulina extract, and the dosage ratio of the giant kelp extract to the austenitic seaweed extract to the bonadt spirulina extract is 1: 1: the seaweed extract is a pure natural marine organism product, all the characteristics come from the special seaweed, the seaweed contains alginic acid, crude protein, various vitamins, enzymes and trace elements, the nutrition can reduce surface blood fat and improve the surface skin hematopoiesis function after being absorbed by the skin, and the seaweed extract has a large amount of anions and can stimulate fiber cells to generate collagen and elastin so as to promote the metabolism of the skin, resist wrinkles and resist aging.
As a further improvement of the technical scheme, the extraction step of the seaweed extract comprises the following operations:
s1.1, repeatedly cleaning the seaweed, removing surface impurities, naturally drying and crushing to obtain crushed materials;
s1.2, adding the crushed material into an extraction kettle, and heating at the temperature of 110-;
and S1.3, repeatedly filtering the separation liquid to obtain a seaweed extract.
As a further improvement of the technical scheme, the extraction step of the milk extract comprises the following operations:
s2.1, placing milk in an extraction furnace, adding the milk under stirring, preheating to 40 ℃, adding an acetic acid-sodium acetate buffer solution, adjusting the pH to 4.7, observing that flocculent precipitates appear in the milk and forming a suspension, and keeping the temperature until the precipitates are completely precipitated;
s2.2, cooling the suspension to room temperature, and centrifugally separating at the rotation speed of 2000-;
s2.3, repeatedly washing the precipitate with distilled water, centrifugally separating for 5-10min at the rotating speed of 3000-12000r/min, and discarding the supernatant;
s2.4, adding ethanol into the precipitate, stirring, filtering the whole suspension, washing the precipitate with an ethanol-ether mixed solution, finally washing the precipitate with ether, draining, spreading the precipitate on a watch glass, and air-drying to obtain the milk extract.
In another aspect, the present invention provides a method for preparing a formulation of a hyaluronic acid collagen mask, comprising the formulation of a hyaluronic acid collagen mask according to any one of claims 1 to 6, comprising the following steps:
s3.1, preparing a seaweed extract, a milk extract and a snail extract for later use;
s3.2, adding the giant kelp extract, the austenitic seaweed extract, the bonadt spirulina extract, the milk extract and the snail extract into deionized water, and stirring and mixing to prepare an initial solution;
s3.3, adding chondroitin sodium sulfate, hydrolyzed collagen and sodium hyaluronate into the initial solution, heating, stirring and mixing;
s3.4, adding an aromatic and a preservative into the initial solution, heating, stirring and mixing, and cooling to obtain a mask solution;
and S3.5, adding the facial mask paper into the facial mask liquid, and soaking for 1-2 hours at normal temperature to obtain the hyaluronic acid collagen facial mask.
Preferably, in S3.2, the processing temperature is 30-50 ℃, and the rotation speed is 900-1200r/min, and the stirring time is 50-80 min.
Preferably, in S3.3, firstly, the hydrolyzed collagen is put in, sodium chondroitin sulfate and sodium hyaluronate are slowly added during stirring to ensure that each humectant can be fully mixed with the initial solution, wherein the temperature is raised to 50-70 ℃, and the stirring is carried out for 1-1.5 hours under the condition that the rotating speed is 600-900 r/min.
Preferably, in S3.4, the temperature is raised to 80-100 ℃, and the stirring is carried out for 30-60min under the condition that the rotating speed is 700-900 r/min.
Compared with the prior art, the invention has the beneficial effects that:
1. in the formula and the preparation method of the hyaluronic acid collagen facial mask, the added seaweed extract is a pure natural marine organism product, and contains alginic acid, crude protein, multiple vitamins, enzymes and trace elements, and after the nutrition is absorbed by skin, the hyaluronic acid collagen facial mask can reduce surface blood fat and enhance the hemopoiesis function of the surface skin, has a large amount of anions, and can stimulate fiber cells to generate collagen and elastin so as to promote the metabolism of the skin, resist wrinkles and resist aging.
2. In the formula and the preparation method of the hyaluronic acid collagen facial mask, the added milk protein extract is helpful for maintaining the moisture balance of skin, softly purifying the skin and nourishing the skin, the added snail extract has good whitening and moisturizing effects on the skin of a human, can improve the relaxation and wrinkles of the skin after long-term use, can effectively repair scars, has good repairing and healing effects on the damaged skin, accelerates the growth of cells and reduces scars.
Detailed Description
The technical solutions in the embodiments of the present invention will be clearly and completely described below with reference to the drawings in the embodiments of the present invention, and it is obvious that the described embodiments are only a part of the embodiments of the present invention, and not all of the embodiments. All other embodiments, which can be derived by a person skilled in the art from the embodiments given herein without making any creative effort, shall fall within the protection scope of the present invention.
Embodiment 1 a formula of a hyaluronic acid collagen facial mask and a preparation method thereof, comprising:
preparation method of seaweed extract
Repeatedly cleaning giant black seaweed, austenitic seaweed and Bonatt spirulina to remove surface impurities, naturally drying, and pulverizing to obtain three pulverized materials; adding the three crushed materials into different extraction kettles respectively, and heating at the temperature of 110-; filtering the three separated solutions repeatedly to obtain black giant seaweed extract, Austenitic seaweed extract and Bonatt Spirulina extract.
Second, preparation of milk extract
Placing milk in an extraction furnace, adding the milk under stirring, preheating to 40 ℃, adding an acetic acid-sodium acetate buffer solution, adjusting the pH value to 4.7, observing that the milk begins to have flocculent precipitates, keeping the temperature until the precipitates are completely precipitated, cooling the suspension to room temperature, carrying out centrifugal separation at the rotation speed of 2000-8000r/min for 8-15min to obtain a crude casein product, repeatedly washing the precipitates with distilled water, carrying out centrifugal separation at the rotation speed of 3000-12000r/min for 5-10min, and discarding the supernatant. Adding ethanol into the precipitate, stirring, filtering the suspension, washing the precipitate with ethanol-diethyl ether mixture, washing the precipitate with diethyl ether, draining, spreading the precipitate on a watch glass, and air drying to obtain milk extract.
Third, preparation of facial mask liquid
Adding 0.01% of Megasphaera anomala extract, 0.01% of Austenitic seaweed extract, 0.01% of Bonatt spirulina extract, 0.3% of milk extract and 0.5% of snail extract into deionized water, stirring for 50-80min under the conditions that the temperature is 30-50 ℃ and the rotating speed is 900-1200r/min, and stirring and mixing to obtain an initial solution; adding 0.5% of hydrolyzed collagen into the initial solution, slowly adding 0.001% of chondroitin sodium sulfate and 0.01% of sodium hyaluronate during stirring to ensure that each humectant can be fully mixed with the initial solution, wherein stirring for 1-1.5h under the conditions that the temperature is raised to 50-70 ℃ and the rotating speed is 600-; adding 0.001% of aromatic and 0.05% of preservative into the initial solution, heating to 80-100 ℃, stirring for 30-60min under the condition that the rotating speed is 700-.
Embodiment 2 a formula of a hyaluronic acid collagen facial mask and a preparation method thereof, comprising:
preparation method of seaweed extract
Repeatedly cleaning giant black seaweed, austenitic seaweed and Bonatt spirulina to remove surface impurities, naturally drying, and pulverizing to obtain three pulverized materials; adding the three crushed materials into different extraction kettles respectively, and heating at the temperature of 110-; filtering the three separated solutions repeatedly to obtain black giant seaweed extract, Austenitic seaweed extract and Bonatt Spirulina extract.
Second, preparation of milk extract
Placing milk in an extraction furnace, adding the milk under stirring, preheating to 40 ℃, adding an acetic acid-sodium acetate buffer solution, adjusting the pH value to 4.7, observing that the milk begins to have flocculent precipitates, keeping the temperature until the precipitates are completely precipitated, cooling the suspension to room temperature, carrying out centrifugal separation at the rotation speed of 2000-8000r/min for 8-15min to obtain a crude casein product, repeatedly washing the precipitates with distilled water, carrying out centrifugal separation at the rotation speed of 3000-12000r/min for 5-10min, and discarding the supernatant. Adding ethanol into the precipitate, stirring, filtering the suspension, washing the precipitate with ethanol-diethyl ether mixture, washing the precipitate with diethyl ether, draining, spreading the precipitate on a watch glass, and air drying to obtain milk extract.
Third, preparation of facial mask liquid
Adding 0.2% of Megasphaera anomala extract, 0.2% of Austenitic seaweed extract, 0.2% of Bonatt spirulina extract, 0.7% of milk extract and 2.5% of snail extract into deionized water, stirring for 50-80min under the conditions that the temperature is 30-50 ℃ and the rotating speed is 900-1200r/min, and stirring and mixing to obtain an initial solution; putting 2.5% of hydrolyzed collagen into the initial solution, slowly adding 0.02% of chondroitin sodium sulfate and 0.2% of sodium hyaluronate during stirring to ensure that each humectant can be fully mixed with the initial solution, wherein stirring for 1-1.5h under the conditions that the temperature is raised to 50-70 ℃ and the rotating speed is 600-; adding 0.005% of aromatic and 0.25% of preservative into the initial solution, heating to 80-100 ℃, stirring for 30-60min under the condition that the rotating speed is 700-.
Embodiment 3 a formula of a hyaluronic acid collagen facial mask and a preparation method thereof, comprising:
preparation method of seaweed extract
Repeatedly cleaning giant black seaweed, austenitic seaweed and Bonatt spirulina to remove surface impurities, naturally drying, and pulverizing to obtain three pulverized materials; adding the three crushed materials into different extraction kettles respectively, and heating at the temperature of 110-; filtering the three separated solutions repeatedly to obtain black giant seaweed extract, Austenitic seaweed extract and Bonatt Spirulina extract.
Second, preparation of milk extract
Placing milk in an extraction furnace, adding the milk under stirring, preheating to 40 ℃, adding an acetic acid-sodium acetate buffer solution, adjusting the pH value to 4.7, observing that the milk begins to have flocculent precipitates, keeping the temperature until the precipitates are completely precipitated, cooling the suspension to room temperature, carrying out centrifugal separation at the rotation speed of 2000-8000r/min for 8-15min to obtain a crude casein product, repeatedly washing the precipitates with distilled water, carrying out centrifugal separation at the rotation speed of 3000-12000r/min for 5-10min, and discarding the supernatant. Adding ethanol into the precipitate, stirring, filtering the suspension, washing the precipitate with ethanol-diethyl ether mixture, washing the precipitate with diethyl ether, draining, spreading the precipitate on a watch glass, and air drying to obtain milk extract.
Third, preparation of facial mask liquid
Adding 0.1% of Megasphaera anomala extract, 0.1% of Austenitic seaweed extract, 0.1% of Bonatt spirulina extract, 0.5% of milk extract and 1.5% of snail extract into deionized water, stirring for 50-80min under the conditions that the temperature is 30-50 ℃ and the rotating speed is 900-1200r/min, stirring and mixing to obtain an initial solution; putting 1.5% of hydrolyzed collagen into the initial solution, slowly adding 0.01% of chondroitin sodium sulfate and 0.1% of sodium hyaluronate during stirring to ensure that each humectant can be fully mixed with the initial solution, wherein stirring for 1-1.5h under the conditions that the temperature is raised to 50-70 ℃ and the rotating speed is 600-; adding 0.003% of aromatic and 0.15% of preservative into the initial solution, heating to 80-100 ℃, stirring for 30-60min under the condition that the rotation speed is 700-900r/min, cooling to obtain facial mask solution, adding facial mask paper into the facial mask solution, and soaking for 1-2h at normal temperature to obtain the hyaluronic acid collagen facial mask.
In the above examples 1-3, the seaweed extract is a pure natural marine product, all the characteristics are derived from the special seaweed itself, which contains alginic acid, crude protein, vitamins, enzymes and trace elements, and after being absorbed by skin, the nutrition can reduce surface blood fat and enhance surface skin hematopoiesis, has a large amount of anions, and can stimulate fiber cells to generate collagen and elastin, promote skin metabolism, resist wrinkles and resist aging;
the milk protein extract is helpful for maintaining the moisture balance of the skin, softly purifying the skin and simultaneously nourishing the skin, the snail extract has good whitening and moisturizing effects on the skin of a human, can improve the looseness and wrinkles of the skin after long-term use, can effectively repair scars, has good repairing and healing effects on the damaged skin, accelerates the growth of cells and reduces scars;
in cosmetics, the chondroitin sodium sulfate has a polysaccharide structure, has a good moisturizing type, can inhibit various bacteria, has an anti-inflammatory effect, can promote the growth of cells and plays a role in resisting aging, hydrolyzed collagen has rich amino acids, can improve the water supply of skin, supplement cell nutrition, relieve the skin, tighten the elasticity of the skin, promote metabolism and inhibit the generation of wrinkles, and a sodium hyaluronate aqueous solution has strong viscoelasticity and lubricity and can form a moisturizing and breathable film when being coated on the surface of the skin to keep the skin moist and bright, so that small-molecule hyaluronic acid can permeate into a dermis layer to promote blood microcirculation, thereby being beneficial to the absorption of nutrients by the skin and playing a role in beautifying, anti-wrinkle and health care;
the preservative is phenoxyethanol, the dosage of the phenoxyethanol is 0.05-0.25%, the phenoxyethanol has the main function of playing the role of antibiosis and antisepsis when being added into the application, and simultaneously has a certain emulsification effect, thus influencing the viscosity of the skin care product;
the aromatic is essence, the dosage of the essence is 0.001-0.005%, the essence can provide pleasant smell in cosmetics, cover the smell of the product matrix, help the product to establish brand-new image, and enhance the attraction of the product to customers.
Comparative example 1
The comparative example provides a facial mask formula, comprising, by percent: 0.1% of austenitic seaweed extract, 0.1% of bonadt spirulina extract, 0.5% of milk extract, 1.5% of snail extract, 1.5% of hydrolyzed collagen, 0.01% of chondroitin sodium sulfate, 0.1% of sodium hyaluronate, 0.003% of aromatic, 0.15% of preservative and the balance of deionized water.
In contrast to example 3, the Megasphaera blankoensis extract was absent.
Comparative example 2
The comparative example provides a facial mask formula, comprising, by percent: 0.1% of Megasphaera anomala extract, 0.1% of Austenitic seaweed extract, 0.5% of milk extract, 1.5% of snail extract, 1.5% of hydrolyzed collagen, 0.01% of sodium chondroitin sulfate, 0.1% of sodium hyaluronate, 0.003% of aromatic, 0.15% of preservative and the balance of deionized water.
In contrast to example 3, there was a lack of B.borna extract.
Comparative example 3
The comparative example provides a facial mask formula, comprising, by percent: 0.5% of milk extract, 1.5% of snail extract, 1.5% of hydrolyzed collagen, 0.01% of chondroitin sodium sulfate, 0.1% of sodium hyaluronate, 0.003% of aromatic, 0.15% of preservative and the balance of deionized water.
In comparison to example 3, there was a lack of borna spirulina extract, borna spirulina extract and seaweeds extract.
Comparative example 4
The comparative example provides a facial mask formula, comprising, by percent: 0.1% of Megasphaera nigroca extract, 0.1% of Austenitic seaweed extract, 0.1% of Bonatt spirulina extract, 1.5% of snail extract, 1.5% of hydrolyzed collagen, 0.01% of chondroitin sodium sulfate, 0.1% of sodium hyaluronate, 0.003% of aromatic, 0.15% of preservative and the balance of deionized water.
In contrast to example 3, milk extract was absent.
Comparative example 5
The comparative example provides a facial mask formula, comprising, by percent: 0.1% of Megasphaera nigroca extract, 0.1% of Austenitic seaweed extract, 0.1% of Bonatt spirulina extract, 0.5% of milk extract, 1.5% of hydrolyzed collagen, 0.01% of sodium chondroitin sulfate, 0.1% of sodium hyaluronate, 0.003% of aromatic, 0.15% of preservative and the balance of deionized water.
In contrast to example 3, snail extract was absent.
Comparative example 6
The comparative example provides a facial mask formula, comprising, by percent: 0.1% of Megasphaera nigroca extract, 0.1% of Austenitic seaweed extract, 0.1% of Bonatt spirulina extract, 1.5% of hydrolyzed collagen, 0.01% of sodium chondroitin sulfate, 0.1% of sodium hyaluronate, 0.003% of aromatic, 0.15% of preservative and the balance of deionized water.
Milk extract and snail extract were absent compared to example 3.
Comparative examples 1-6 provide facial mask formulations prepared in the same manner as example 3, wherein the missing materials were not added directly, and other steps were not changed, and thus are not described herein again.
Test example 1
The mask prepared from the mask formulations provided in examples 1-3 and comparative examples 1-6 above was tested by randomly inviting 45 women between ages 22-25 and divided into 9 groups. 5 persons were randomly assigned to each group, and the corresponding masks prepared according to the formulations in examples and comparative examples were tried, and the skin condition of the user was observed after 14 days of trial, and the test results are shown in table 1:
TABLE 1
As can be seen from table 1, compared with comparative examples 1 to 6, the improved facial mask formulations in examples 1 to 3 of the present invention have more significant color difference, which indicates that the skin whitening effect is better, the moisture content of the skin after application is higher, and the moisturizing effect is better, which indicates that the formula components and the mixture ratio of the hyaluronic acid collagen facial mask provided by the present invention are more reasonable, and the prepared facial mask has a better effect.
The foregoing shows and describes the general principles, essential features, and advantages of the invention. It will be understood by those skilled in the art that the present invention is not limited to the embodiments described above, and the preferred embodiments of the present invention are described in the above embodiments and the description, and are not intended to limit the present invention. The scope of the invention is defined by the appended claims and equivalents thereof.