CN113651640A - Matt double-layer reaction glaze glazing decoration and preparation method - Google Patents
Matt double-layer reaction glaze glazing decoration and preparation method Download PDFInfo
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- CN113651640A CN113651640A CN202110959227.9A CN202110959227A CN113651640A CN 113651640 A CN113651640 A CN 113651640A CN 202110959227 A CN202110959227 A CN 202110959227A CN 113651640 A CN113651640 A CN 113651640A
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- 238000005034 decoration Methods 0.000 title claims abstract description 57
- 238000002360 preparation method Methods 0.000 title claims abstract description 23
- 239000002994 raw material Substances 0.000 claims abstract description 57
- 238000000498 ball milling Methods 0.000 claims abstract description 43
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 22
- 230000001680 brushing effect Effects 0.000 claims abstract description 21
- 238000012216 screening Methods 0.000 claims abstract description 21
- 229910000831 Steel Inorganic materials 0.000 claims abstract description 17
- 239000010959 steel Substances 0.000 claims abstract description 17
- 238000010304 firing Methods 0.000 claims abstract description 16
- 238000005303 weighing Methods 0.000 claims abstract description 16
- QMGYPNKICQJHLN-UHFFFAOYSA-M Carboxymethylcellulose cellulose carboxymethyl ether Chemical compound [Na+].CC([O-])=O.OCC(O)C(O)C(O)C(O)C=O QMGYPNKICQJHLN-UHFFFAOYSA-M 0.000 claims abstract description 14
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 claims description 44
- 239000010459 dolomite Substances 0.000 claims description 33
- 229910000514 dolomite Inorganic materials 0.000 claims description 33
- 229910021532 Calcite Inorganic materials 0.000 claims description 22
- AYJRCSIUFZENHW-UHFFFAOYSA-L barium carbonate Chemical compound [Ba+2].[O-]C([O-])=O AYJRCSIUFZENHW-UHFFFAOYSA-L 0.000 claims description 22
- GNTDGMZSJNCJKK-UHFFFAOYSA-N divanadium pentaoxide Chemical compound O=[V](=O)O[V](=O)=O GNTDGMZSJNCJKK-UHFFFAOYSA-N 0.000 claims description 22
- 239000010433 feldspar Substances 0.000 claims description 22
- 239000010453 quartz Substances 0.000 claims description 22
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicon dioxide Inorganic materials O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 22
- 239000000454 talc Substances 0.000 claims description 22
- 229910052623 talc Inorganic materials 0.000 claims description 22
- 235000012222 talc Nutrition 0.000 claims description 22
- 239000011787 zinc oxide Substances 0.000 claims description 22
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 claims description 18
- 238000000034 method Methods 0.000 claims description 15
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 11
- 229910052656 albite Inorganic materials 0.000 claims description 11
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 11
- CNLWCVNCHLKFHK-UHFFFAOYSA-N aluminum;lithium;dioxido(oxo)silane Chemical compound [Li+].[Al+3].[O-][Si]([O-])=O.[O-][Si]([O-])=O CNLWCVNCHLKFHK-UHFFFAOYSA-N 0.000 claims description 11
- DLHONNLASJQAHX-UHFFFAOYSA-N aluminum;potassium;oxygen(2-);silicon(4+) Chemical compound [O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[Al+3].[Si+4].[Si+4].[Si+4].[K+] DLHONNLASJQAHX-UHFFFAOYSA-N 0.000 claims description 11
- 238000001035 drying Methods 0.000 claims description 11
- XGZVUEUWXADBQD-UHFFFAOYSA-L lithium carbonate Chemical compound [Li+].[Li+].[O-]C([O-])=O XGZVUEUWXADBQD-UHFFFAOYSA-L 0.000 claims description 11
- 229910052808 lithium carbonate Inorganic materials 0.000 claims description 11
- 239000000463 material Substances 0.000 claims description 11
- 239000000843 powder Substances 0.000 claims description 11
- 239000002689 soil Substances 0.000 claims description 11
- 229910052642 spodumene Inorganic materials 0.000 claims description 11
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 claims description 11
- 238000004321 preservation Methods 0.000 claims description 5
- 238000007873 sieving Methods 0.000 claims description 5
- NDLPOXTZKUMGOV-UHFFFAOYSA-N oxo(oxoferriooxy)iron hydrate Chemical compound O.O=[Fe]O[Fe]=O NDLPOXTZKUMGOV-UHFFFAOYSA-N 0.000 claims description 4
- 239000000919 ceramic Substances 0.000 abstract description 7
- 239000000203 mixture Substances 0.000 abstract 1
- 230000000694 effects Effects 0.000 description 4
- 239000004927 clay Substances 0.000 description 3
- 238000002955 isolation Methods 0.000 description 3
- 229910052573 porcelain Inorganic materials 0.000 description 3
- 238000007650 screen-printing Methods 0.000 description 3
- 230000007547 defect Effects 0.000 description 2
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 2
- 238000005299 abrasion Methods 0.000 description 1
- 230000003796 beauty Effects 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 238000004851 dishwashing Methods 0.000 description 1
- 238000005562 fading Methods 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 238000000465 moulding Methods 0.000 description 1
- 230000037452 priming Effects 0.000 description 1
- 230000035939 shock Effects 0.000 description 1
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/45—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
- C04B41/52—Multiple coating or impregnating multiple coating or impregnating with the same composition or with compositions only differing in the concentration of the constituents, is classified as single coating or impregnation
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C8/00—Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/80—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone of only ceramics
- C04B41/81—Coating or impregnation
- C04B41/85—Coating or impregnation with inorganic materials
- C04B41/86—Glazes; Cold glazes
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/80—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone of only ceramics
- C04B41/81—Coating or impregnation
- C04B41/89—Coating or impregnation for obtaining at least two superposed coatings having different compositions
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Ceramic Engineering (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Structural Engineering (AREA)
- Inorganic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
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- General Chemical & Material Sciences (AREA)
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Abstract
The invention discloses a matt double-layer reaction glaze brushing decoration and a preparation method thereof, which comprises the steps of weighing raw materials, screening, glaze preparation, glaze brushing and firing, wherein a matt double-layer reaction glaze ground glaze is placed by separating a surface glaze, and then ball milling steel balls and water are added into the ground glaze and the surface glaze, so that the ground glaze and the surface glaze are as follows: ball milling steel balls: water 1: 1.6: 0.65, then adding five thousandths of CMC powder into the mixture, putting the raw materials into a ball mill after adding the CMC powder, and carrying out wet ball milling. The invention relates to the technical field of ceramic decoration, in particular to a matt double-layer reaction glaze brushed decoration and a preparation method thereof.
Description
Technical Field
The invention relates to the technical field of ceramics, in particular to a matt double-layer reaction glaze glazing decoration and a preparation method thereof.
Background
Ceramics, which is a general name of pottery and porcelain, is a ware made of two kinds of clay with different properties, namely pottery clay and porcelain clay, through the process flows of material preparation, molding, drying, roasting and the like. Pottery ware fired with pottery clay is called pottery, and porcelain ware fired with porcelain clay is called porcelain, and decoration work is usually performed on the surface of the pottery in order to enhance the beauty of the pottery.
At present, however, the decoration effect of ceramics at home and abroad is mainly achieved by relief stained paper or screen printing isolation, the relief stained paper is characterized by bright color but poor abrasion resistance, which is a common problem of daily ceramics such as stained paper, and the screen printing isolation has weak three-dimensional effect and rigid reaction.
Disclosure of Invention
Aiming at the defects of the prior art, the invention provides a matt double-layer reaction glaze glazing decoration and a preparation method thereof, and solves the problems of poor wear resistance, common problem of stained paper type daily ceramics, screen printing isolation, weak stereoscopic effect and dull reaction of the existing ceramic decoration.
In order to achieve the purpose, the invention is realized by the following technical scheme: the matte double-layer reaction glaze brushed decoration comprises a base glaze and a surface glaze, wherein the base glaze is prepared from the following components: 30-45 parts of feldspar; 10-13 parts of dolomite; 8-13 parts of calcite; 20-25 parts of quartz and 6-10 parts of talc; 5-8 parts of Guizhou soil; 5-8 parts of iron oxide, wherein the overglaze is prepared from the following components: 25-30 parts of potassium feldspar; 10-15 parts of calcite; 10-15 parts of zinc oxide; 10-14 parts of dolomite; 10-15 parts of spodumene; 10-15 parts of quartz; 3-5 parts of lithium carbonate; 6-8 parts of aluminum powder; 10-15 parts of titanium oxide, wherein the glaze is prepared from the following components: 35-40 parts of feldspar; 10-15 parts of albite; 12-15 parts of zinc oxide; 10-12 parts of dolomite; 3-5 parts of barium carbonate; 5-8 parts of talc; 2 parts of vanadium pentoxide.
Preferably, the ground glaze of the matt double-layer reaction glaze is prepared from the following components: 30 parts of feldspar; 10 parts of dolomite; 8 parts of calcite; 20 parts of quartz and 6 parts of talcum; 5 parts of Guizhou soil; 5 parts of ferric oxide, wherein the overglaze of the matt double-layer reaction glaze is prepared from the following components: 25 parts of potassium feldspar; 10 parts of calcite; 10 parts of zinc oxide; 10 parts of dolomite; 10 parts of spodumene; 10 parts of quartz; 3 parts of lithium carbonate; 6 parts of aluminum powder; 10 parts of titanium oxide, wherein the glaze is prepared from the following components: 35 parts of feldspar; 10 parts of albite; 12 parts of zinc oxide; 10 of dolomite; 3 parts of barium carbonate; 5 parts of talc; 2 parts of vanadium pentoxide.
Preferably, the ground glaze of the matt double-layer reaction glaze is prepared from the following components: 45 parts of feldspar; 13 parts of dolomite; 13 parts of calcite; 25 parts of quartz and 10 parts of talcum; 8 parts of Guizhou soil; 8 parts of iron oxide, wherein the overglaze of the matt double-layer reaction glaze is prepared from the following components: 30 parts of potassium feldspar; 15 parts of calcite; 15 parts of zinc oxide; 14 parts of dolomite; 15 parts of spodumene; 15 parts of quartz; 5 parts of lithium carbonate; 8 parts of aluminum powder; 15 parts of titanium oxide, wherein the glaze is prepared from the following components: 40 parts of feldspar; 15 parts of albite; 15 parts of zinc oxide; 12 of dolomite; 5 parts of barium carbonate; 8 parts of talc; 2 parts of vanadium pentoxide.
Preferably, the ground glaze of the matt double-layer reaction glaze is prepared from the following components: 37 parts of feldspar; 12 parts of dolomite; 10 parts of calcite; 23 parts of quartz and 8 parts of talcum; 7 parts of Guizhou soil; 7 parts of iron oxide, wherein the overglaze of the matt double-layer reaction glaze is prepared from the following components: 27 parts of potassium feldspar; 13 parts of calcite; 13 parts of zinc oxide; 12 parts of dolomite; 13 parts of spodumene; 13 parts of quartz; 4 parts of lithium carbonate; 7 parts of aluminum powder; 13 parts of titanium oxide, wherein the glaze is prepared from the following components: 37 parts of feldspar; 13 parts of albite; 13 parts of zinc oxide; dolomite 11; 4 parts of barium carbonate; 7 parts of talc; 2 parts of vanadium pentoxide.
Preferably, the preparation method of the matte double-layer reaction glaze brushed decoration comprises the following steps:
s1, weighing the following raw materials: weighing each component and raw materials of each component by mass, and separately placing the raw materials of each component after weighing;
s2, screening: after the raw materials are screened, screening a base glaze raw material of the matt double-layer reaction glaze by using a 150-200-mesh sieve, screening a surface glaze raw material of the matt double-layer reaction glaze by using a 160-200-mesh sieve, and screening a glazed raw material by using a 200-250-mesh sieve;
s3, glaze preparation: placing the matt double-layer reaction glaze ground glaze separately from the surface glaze, and then adding ball milling steel balls and water to the ground glaze and the surface glaze to ensure that the ground glaze and the surface glaze are as follows: ball milling steel balls: water = 1: 1.6: 0.65, then adding five thousandths of CMC powder into the powder, putting the raw materials into a ball mill after adding, and carrying out wet ball milling operation, so that the ground glaze after wet ball milling is controlled below 200 meshes, the overglaze is controlled below 200 meshes, the ground glaze is adjusted to be baume concentration of 48-50 degrees, and the overglaze is adjusted to be baume concentration of 52-53 degrees;
adding ball milling steel balls and water into the matt double-layer reaction glaze material to ensure that the matt double-layer reaction glaze material: ball: water 1: 1.6: 0.65, adding five thousandths of CMC powder into the glaze, then putting the CMC powder into a ball mill, and carrying out wet ball milling operation to control the glazing fineness to be below 250 meshes and the concentration to be 54-56 degrees in Baume;
s4, glazing: taking a clean green body, firstly loading the green body by using a matt double-layer reaction glaze ground coat, drying the green body after loading, then loading the green body by using a matt double-layer reaction glaze surface coat, and brushing a required pattern surface on the green body with the surface coat by using a brushing glaze after finishing the surface coat;
s5, firing: and putting the glazed decoration with the matt double-layer reaction glaze into a roller kiln for firing to finally prepare the glazed decoration with the matt double-layer reaction glaze.
Preferably, in the step S2, when each group of raw materials is sieved, each group of raw materials is sieved 3 to 4 times, so as to ensure the fineness required by the raw material sieving.
Preferably, in step S3, the wet ball milling of the ground glaze and the cover glaze is 17 hours, and the wet ball milling of the brushing glaze is 21 hours.
Preferably, in the step S4, when the green body is dried, the drying temperature is 100 to 200 ℃, and the heat preservation time is 10 to 20 min.
Preferably, in the step S5, the firing temperature of the roller kiln is 1180 ℃ and the time is 1-2 hours.
Preferably, in the step S5, after the matte double-layer reaction glaze decoration is fired, the glaze is taken out and naturally cooled.
Advantageous effects
The invention provides a matt double-layer reaction glaze glazing decoration and a preparation method thereof, compared with the prior art, the matt double-layer reaction glaze glazing decoration and the preparation method thereof have the following beneficial effects:
1. according to the matt double-layer reaction glaze brushed decoration and the preparation method, a plurality of advantages are integrated through the matt double-layer reaction glaze brushed decoration, other defects are eliminated, so that the matt double-layer reaction glaze brushed decoration has strong competitiveness in products of the type, meanwhile, the matt double-layer reaction glaze brushed decoration can pass through a microwave oven test, a dish washing machine test, a thermal shock resistance test and the like, and meanwhile, the matt double-layer reaction glaze brushed decoration is attractive, natural and good in stereoscopic impression, and meets development and production requirements.
2. According to the matt double-layer reaction glaze brushed glaze decoration and the preparation method, the matt double-layer reaction glaze brushed glaze decoration is processed, so that the wear resistance of the matt double-layer reaction glaze brushed glaze decoration is strong, the conditions of fading, decoloring and the like are not easy to occur, and the quality of the matt double-layer reaction glaze brushed glaze decoration is further ensured.
Drawings
FIG. 1 is a flow chart of the preparation of the present invention.
Detailed Description
The technical solutions in the embodiments of the present invention will be clearly and completely described below with reference to the drawings in the embodiments of the present invention, and it is obvious that the described embodiments are only a part of the embodiments of the present invention, and not all of the embodiments. All other embodiments, which can be derived by a person skilled in the art from the embodiments given herein without making any creative effort, shall fall within the protection scope of the present invention.
Referring to fig. 1, the present invention provides three technical solutions:
example one
The matte double-layer reaction glaze brushed decoration comprises a base glaze and a surface glaze, wherein the base glaze is prepared from the following components: 30 parts of feldspar; 10 parts of dolomite; 8 parts of calcite; 20 parts of quartz and 6 parts of talcum; 5 parts of Guizhou soil; 5 parts of ferric oxide, and the overglaze is prepared from the following components: 25 parts of potassium feldspar; 10 parts of calcite; 10 parts of zinc oxide; 10 parts of dolomite; 10 parts of spodumene; 10 parts of quartz; 3 parts of lithium carbonate; 6 parts of aluminum powder; 10 parts of titanium oxide, and the glaze is prepared from the following components: 35 parts of feldspar; 10 parts of albite; 12 parts of zinc oxide; 10 of dolomite; 3 parts of barium carbonate; 5 parts of talc; 2 parts of vanadium pentoxide.
In the embodiment of the invention, the preparation method of the matt double-layer reaction glaze decoration comprises the following steps:
s1, weighing the following raw materials: weighing each component and raw materials of each component by mass, and separately placing the raw materials of each component after weighing;
s2, screening: after the raw materials are screened, screening a base glaze raw material of the matt double-layer reaction glaze by using a 150-mesh sieve, screening a cover glaze raw material of the matt double-layer reaction glaze by using a 160-mesh sieve, and screening a glazed raw material by using a 200-mesh sieve;
s3, glaze preparation: placing the matt double-layer reaction glaze ground glaze separately from the surface glaze, and then adding ball milling steel balls and water to the ground glaze and the surface glaze to ensure that the ground glaze and the surface glaze are as follows: ball milling steel balls: water = 1: 1.6: 0.65, then adding five thousandths of CMC powder into the powder, putting the raw materials into a ball mill after adding, and carrying out wet ball milling operation, so that the ground glaze after wet ball milling is controlled below 200 meshes, the overglaze is controlled below 200 meshes, the ground glaze is adjusted to be at baume concentration of 48 degrees, and the overglaze is adjusted to be at baume concentration of 52 degrees;
adding ball milling steel balls and water into the matt double-layer reaction glaze material to ensure that the matt double-layer reaction glaze material: ball: water 1: 1.6: 0.65, then adding five thousandths of CMC powder into the powder, then putting the powder into a ball mill, and carrying out wet ball milling operation to control the glazing fineness to be below 250 meshes and the concentration to be 54 degrees in Baume;
s4, glazing: taking a clean green body, firstly loading the green body by using a matt double-layer reaction glaze ground coat, drying the green body after loading, then loading the green body by using a matt double-layer reaction glaze surface coat, and brushing a required pattern surface on the green body with the surface coat by using a brushing glaze after finishing the surface coat;
s5, firing: and putting the glazed decoration with the matt double-layer reaction glaze into a roller kiln for firing to finally prepare the glazed decoration with the matt double-layer reaction glaze.
In the embodiment of the invention, in step S2, when each group of raw materials is sieved, each group of raw materials is sieved 3 times, so as to ensure the fineness required by sieving the raw materials.
In the embodiment of the invention, in the step S3, the wet ball milling of the ground glaze and the overglaze is 17 hours, and the wet ball milling of the brushing glaze is 21 hours.
In the embodiment of the invention, in the step S4, when the green body is dried, the drying temperature is 100 ℃, and the heat preservation time is 10 min.
In the embodiment of the invention, in the step S5, the firing temperature of the roller kiln is 1180 ℃ and the time is 1 h.
In the embodiment of the invention, in the step S5, after the matte double-layer reaction glaze brushing decoration is fired, the decoration is taken out and naturally cooled.
Example two
The matte double-layer reaction glaze brushed decoration comprises a base glaze and a surface glaze, wherein the base glaze is prepared from the following components: 45 parts of feldspar; 13 parts of dolomite; 13 parts of calcite; 25 parts of quartz and 10 parts of talcum; 8 parts of Guizhou soil; 8 parts of ferric oxide, and the overglaze is prepared from the following components: 30 parts of potassium feldspar; 15 parts of calcite; 15 parts of zinc oxide; 14 parts of dolomite; 15 parts of spodumene; 15 parts of quartz; 5 parts of lithium carbonate; 8 parts of aluminum powder; 15 parts of titanium oxide, and the glaze is prepared from the following components: 40 parts of feldspar; 15 parts of albite; 15 parts of zinc oxide; 12 of dolomite; 5 parts of barium carbonate; 8 parts of talc; 2 parts of vanadium pentoxide.
In the embodiment of the invention, the preparation method of the matt double-layer reaction glaze decoration comprises the following steps:
s1, weighing the following raw materials: weighing each component and raw materials of each component by mass, and separately placing the raw materials of each component after weighing;
s2, screening: after the raw materials are screened, screening a priming glaze raw material of the matt double-layer reaction glaze by using a 200-mesh sieve, screening a surface glaze raw material of the matt double-layer reaction glaze by using a 200-mesh sieve, and screening a glazed raw material by using a 250-mesh sieve;
s3, glaze preparation: placing the matt double-layer reaction glaze ground glaze separately from the surface glaze, and then adding ball milling steel balls and water to the ground glaze and the surface glaze to ensure that the ground glaze and the surface glaze are as follows: ball milling steel balls: water = 1: 1.6: 0.65, then adding five thousandths of CMC powder into the powder, putting the raw materials into a ball mill after adding, and carrying out wet ball milling operation, so that the ground glaze after wet ball milling is controlled below 200 meshes, the overglaze is controlled below 200 meshes, the ground glaze is adjusted to be at baume concentration of 50 degrees, and the overglaze is adjusted to be at baume concentration of 53 degrees;
adding ball milling steel balls and water into the matt double-layer reaction glaze material to ensure that the matt double-layer reaction glaze material: ball: water 1: 1.6: 0.65, then adding five thousandths of CMC powder into the powder, then putting the powder into a ball mill, and carrying out wet ball milling operation to control the glazing fineness to be below 250 meshes and the concentration to be 56 degrees in Baume;
s4, glazing: taking a clean green body, firstly loading the green body by using a matt double-layer reaction glaze ground coat, drying the green body after loading, then loading the green body by using a matt double-layer reaction glaze surface coat, and brushing a required pattern surface on the green body with the surface coat by using a brushing glaze after finishing the surface coat;
s5, firing: and putting the glazed decoration with the matt double-layer reaction glaze into a roller kiln for firing to finally prepare the glazed decoration with the matt double-layer reaction glaze.
In the embodiment of the invention, in step S2, when each group of raw materials is sieved, each group of raw materials is sieved for 4 times, so as to ensure the fineness required by sieving the raw materials.
In the embodiment of the invention, in the step S3, the wet ball milling of the ground glaze and the overglaze is 17 hours, and the wet ball milling of the brushing glaze is 21 hours.
In the embodiment of the invention, in the step S4, when the green body is dried, the drying temperature is 200 ℃, and the heat preservation time is 20 min.
In the embodiment of the invention, in the step S5, the firing temperature of the roller kiln is 1180 ℃ and the time is 2 hours.
In the embodiment of the invention, in the step S5, after the matte double-layer reaction glaze brushing decoration is fired, the decoration is taken out and naturally cooled.
EXAMPLE III
The matte double-layer reaction glaze brushed decoration comprises a base glaze and a surface glaze, wherein the base glaze is prepared from the following components: 37 parts of feldspar; 12 parts of dolomite; 10 parts of calcite; 23 parts of quartz and 8 parts of talcum; 7 parts of Guizhou soil; 7 parts of iron oxide, wherein the overglaze is prepared from the following components: 27 parts of potassium feldspar; 13 parts of calcite; 13 parts of zinc oxide; 12 parts of dolomite; 13 parts of spodumene; 13 parts of quartz; 4 parts of lithium carbonate; 7 parts of aluminum powder; 13 parts of titanium oxide, and the glaze is prepared from the following components: 37 parts of feldspar; 13 parts of albite; 13 parts of zinc oxide; dolomite 11; 4 parts of barium carbonate; 7 parts of talc; 2 parts of vanadium pentoxide.
In the embodiment of the invention, the preparation method of the matt double-layer reaction glaze decoration comprises the following steps:
s1, weighing the following raw materials: weighing each component and raw materials of each component by mass, and separately placing the raw materials of each component after weighing;
s2, screening: after the raw materials are screened, screening a ground glaze raw material of the matt double-layer reaction glaze by using a 170-mesh screen, screening a surface glaze raw material of the matt double-layer reaction glaze by using a 180-mesh screen, and screening a glazed raw material by using a 230-mesh screen;
s3, glaze preparation: placing the matt double-layer reaction glaze ground glaze separately from the surface glaze, and then adding ball milling steel balls and water to the ground glaze and the surface glaze to ensure that the ground glaze and the surface glaze are as follows: ball milling steel balls: water = 1: 1.6: 0.65, then adding five thousandths of CMC powder into the powder, putting the raw materials into a ball mill after adding, and carrying out wet ball milling operation, so that the ground glaze after wet ball milling is controlled below 200 meshes, the overglaze is controlled below 200 meshes, the ground glaze is adjusted to the baume concentration of 49 degrees, and the overglaze is adjusted to the baume concentration of 52.5 degrees;
adding ball milling steel balls and water into the matt double-layer reaction glaze material to ensure that the matt double-layer reaction glaze material: ball: water 1: 1.6: 0.65, then adding five thousandths of CMC powder into the powder, then putting the powder into a ball mill, and carrying out wet ball milling operation to control the glazing fineness to be below 250 meshes and the concentration to be 55 degrees in Baume;
s4, glazing: taking a clean green body, firstly loading the green body by using a matt double-layer reaction glaze ground coat, drying the green body after loading, then loading the green body by using a matt double-layer reaction glaze surface coat, and brushing a required pattern surface on the green body with the surface coat by using a brushing glaze after finishing the surface coat;
s5, firing: and putting the glazed decoration with the matt double-layer reaction glaze into a roller kiln for firing to finally prepare the glazed decoration with the matt double-layer reaction glaze.
In the embodiment of the invention, in step S2, when each group of raw materials is sieved, each group of raw materials is sieved for 4 times, so as to ensure the fineness required by sieving the raw materials.
In the embodiment of the invention, in the step S3, the wet ball milling of the ground glaze and the overglaze is 17 hours, and the wet ball milling of the brushing glaze is 21 hours.
In the embodiment of the invention, in the step S4, when the green body is dried, the drying temperature is 150 ℃, and the heat preservation time is 15 min.
In the embodiment of the invention, in the step S5, the firing temperature of the roller kiln is 1180 ℃ and the time is 1.5 hours.
In the embodiment of the invention, in the step S5, after the matte double-layer reaction glaze brushing decoration is fired, the decoration is taken out and naturally cooled.
And those not described in detail in this specification are well within the skill of those in the art.
It is noted that, herein, relational terms such as first and second, and the like may be used solely to distinguish one entity or action from another entity or action without necessarily requiring or implying any actual such relationship or order between such entities or actions. Also, the terms "comprises," "comprising," or any other variation thereof, are intended to cover a non-exclusive inclusion, such that a process, method, article, or apparatus that comprises a list of elements does not include only those elements but may include other elements not expressly listed or inherent to such process, method, article, or apparatus.
Claims (10)
1. A dull double-layer reactive glaze glazing decoration is characterized in that: the matt double-layer reaction glaze consists of a ground glaze and a surface glaze, wherein the ground glaze is prepared from the following components: 30-45 parts of feldspar; 10-13 parts of dolomite; 8-13 parts of calcite; 20-25 parts of quartz and 6-10 parts of talc; 5-8 parts of Guizhou soil; 5-8 parts of iron oxide, wherein the overglaze is prepared from the following components: 25-30 parts of potassium feldspar; 10-15 parts of calcite; 10-15 parts of zinc oxide; 10-14 parts of dolomite; 10-15 parts of spodumene; 10-15 parts of quartz; 3-5 parts of lithium carbonate; 6-8 parts of aluminum powder; 10-15 parts of titanium oxide, wherein the glaze is prepared from the following components: 35-40 parts of feldspar; 10-15 parts of albite; 12-15 parts of zinc oxide; 10-12 parts of dolomite; 3-5 parts of barium carbonate; 5-8 parts of talc; 2 parts of vanadium pentoxide.
2. A matt double reaction glaze glazing decoration according to claim 1 wherein: the ground glaze of the matt double-layer reaction glaze is prepared from the following components: 30 parts of feldspar; 10 parts of dolomite; 8 parts of calcite; 20 parts of quartz and 6 parts of talcum; 5 parts of Guizhou soil; 5 parts of ferric oxide, wherein the overglaze of the matt double-layer reaction glaze is prepared from the following components: 25 parts of potassium feldspar; 10 parts of calcite; 10 parts of zinc oxide; 10 parts of dolomite; 10 parts of spodumene; 10 parts of quartz; 3 parts of lithium carbonate; 6 parts of aluminum powder; 10 parts of titanium oxide, wherein the glaze is prepared from the following components: 35 parts of feldspar; 10 parts of albite; 12 parts of zinc oxide; 10 of dolomite; 3 parts of barium carbonate; 5 parts of talc; 2 parts of vanadium pentoxide.
3. A matt double reaction glaze glazing decoration according to claim 1 wherein: the ground glaze of the matt double-layer reaction glaze is prepared from the following components: 45 parts of feldspar; 13 parts of dolomite; 13 parts of calcite; 25 parts of quartz and 10 parts of talcum; 8 parts of Guizhou soil; 8 parts of iron oxide, wherein the overglaze of the matt double-layer reaction glaze is prepared from the following components: 30 parts of potassium feldspar; 15 parts of calcite; 15 parts of zinc oxide; 14 parts of dolomite; 15 parts of spodumene; 15 parts of quartz; 5 parts of lithium carbonate; 8 parts of aluminum powder; 15 parts of titanium oxide, wherein the glaze is prepared from the following components: 40 parts of feldspar; 15 parts of albite; 15 parts of zinc oxide; 12 of dolomite; 5 parts of barium carbonate; 8 parts of talc; 2 parts of vanadium pentoxide.
4. A matt double reaction glaze glazing decoration according to claim 1 wherein: the ground glaze of the matt double-layer reaction glaze is prepared from the following components: 37 parts of feldspar; 12 parts of dolomite; 10 parts of calcite; 23 parts of quartz and 8 parts of talcum; 7 parts of Guizhou soil; 7 parts of iron oxide, wherein the overglaze of the matt double-layer reaction glaze is prepared from the following components: 27 parts of potassium feldspar; 13 parts of calcite; 13 parts of zinc oxide; 12 parts of dolomite; 13 parts of spodumene; 13 parts of quartz; 4 parts of lithium carbonate; 7 parts of aluminum powder; 13 parts of titanium oxide, wherein the glaze is prepared from the following components: 37 parts of feldspar; 13 parts of albite; 13 parts of zinc oxide; dolomite 11; 4 parts of barium carbonate; 7 parts of talc; 2 parts of vanadium pentoxide.
5. A matt double reaction glaze cover glaze decoration according to any one of claims 1 to 4, wherein the preparation method comprises the steps of:
s1, weighing the following raw materials: weighing each component and raw materials of each component by mass, and separately placing the raw materials of each component after weighing;
s2, screening: after the raw materials are screened, screening a base glaze raw material of the matt double-layer reaction glaze by using a 150-200-mesh sieve, screening a surface glaze raw material of the matt double-layer reaction glaze by using a 160-200-mesh sieve, and screening a glazed raw material by using a 200-250-mesh sieve;
s3, glaze preparation: placing the matt double-layer reaction glaze ground glaze separately from the surface glaze, and then adding ball milling steel balls and water to the ground glaze and the surface glaze to ensure that the ground glaze and the surface glaze are as follows: ball milling steel balls: water = 1: 1.6: 0.65, then adding five thousandths of CMC powder into the powder, putting the raw materials into a ball mill after adding, and carrying out wet ball milling operation, so that the ground glaze after wet ball milling is controlled below 200 meshes, the overglaze is controlled below 200 meshes, the ground glaze is adjusted to be baume concentration of 48-50 degrees, and the overglaze is adjusted to be baume concentration of 52-53 degrees;
adding ball milling steel balls and water into the matt double-layer reaction glaze material to ensure that the matt double-layer reaction glaze material: ball: water 1: 1.6: 0.65, adding five thousandths of CMC powder into the glaze, then putting the CMC powder into a ball mill, and carrying out wet ball milling operation to control the glazing fineness to be below 250 meshes and the concentration to be 54-56 degrees in Baume;
s4, glazing: taking a clean green body, firstly loading the green body by using a matt double-layer reaction glaze ground coat, drying the green body after loading, then loading the green body by using a matt double-layer reaction glaze surface coat, and brushing a required pattern surface on the green body with the surface coat by using a brushing glaze after finishing the surface coat;
s5, firing: and putting the glazed decoration with the matt double-layer reaction glaze into a roller kiln for firing to finally prepare the glazed decoration with the matt double-layer reaction glaze.
6. The method for preparing a matt double-layer reactive glaze glazing decoration according to claim 5, wherein the method comprises the following steps: in the step S2, when each group of raw materials is sieved, each group of raw materials is sieved 3-4 times, so that the fineness required by the raw material sieving is ensured.
7. The method for preparing a matt double-layer reactive glaze glazing decoration according to claim 5, wherein the method comprises the following steps: in the step S3, the wet ball milling of the ground glaze and the cover glaze is 17 hours, and the wet ball milling of the brushing glaze is 21 hours.
8. The method for preparing a matt double-layer reactive glaze glazing decoration according to claim 5, wherein the method comprises the following steps: in the step S4, when the blank body is dried, the drying temperature is 100-200 ℃, and the heat preservation time is 10-20 min.
9. The method for preparing a matt double-layer reactive glaze glazing decoration according to claim 5, wherein the method comprises the following steps: in the step S5, the firing temperature of the roller kiln is 1180 ℃ and the time is 1-2 hours.
10. The method for preparing a matt double-layer reactive glaze glazing decoration according to claim 5, wherein the method comprises the following steps: in the step S5, after the matte double-layer reaction glaze brushing decoration is finished, the glaze is taken out and naturally cooled.
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