CN113213758A - Mihuang glaze and method for preparing mihuang glaze ceramic product by using same - Google Patents
Mihuang glaze and method for preparing mihuang glaze ceramic product by using same Download PDFInfo
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- CN113213758A CN113213758A CN202110541123.6A CN202110541123A CN113213758A CN 113213758 A CN113213758 A CN 113213758A CN 202110541123 A CN202110541123 A CN 202110541123A CN 113213758 A CN113213758 A CN 113213758A
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- beige
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- 239000000919 ceramic Substances 0.000 title claims abstract description 40
- 238000000034 method Methods 0.000 title abstract description 10
- AMWRITDGCCNYAT-UHFFFAOYSA-L hydroxy(oxo)manganese;manganese Chemical compound [Mn].O[Mn]=O.O[Mn]=O AMWRITDGCCNYAT-UHFFFAOYSA-L 0.000 claims abstract description 16
- 239000002270 dispersing agent Substances 0.000 claims abstract description 15
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 claims abstract description 14
- 239000010433 feldspar Substances 0.000 claims abstract description 9
- APVVRLGIFCYZHJ-UHFFFAOYSA-N trioctyl 2-hydroxypropane-1,2,3-tricarboxylate Chemical compound CCCCCCCCOC(=O)CC(O)(C(=O)OCCCCCCCC)CC(=O)OCCCCCCCC APVVRLGIFCYZHJ-UHFFFAOYSA-N 0.000 claims abstract description 9
- 239000005995 Aluminium silicate Substances 0.000 claims abstract description 8
- 235000012211 aluminium silicate Nutrition 0.000 claims abstract description 8
- 229960000892 attapulgite Drugs 0.000 claims abstract description 8
- AYJRCSIUFZENHW-DEQYMQKBSA-L barium(2+);oxomethanediolate Chemical compound [Ba+2].[O-][14C]([O-])=O AYJRCSIUFZENHW-DEQYMQKBSA-L 0.000 claims abstract description 8
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 claims abstract description 8
- 229910052625 palygorskite Inorganic materials 0.000 claims abstract description 8
- 240000007594 Oryza sativa Species 0.000 claims abstract 2
- 235000007164 Oryza sativa Nutrition 0.000 claims abstract 2
- 235000009566 rice Nutrition 0.000 claims abstract 2
- 238000010304 firing Methods 0.000 claims description 36
- IAZDPXIOMUYVGZ-UHFFFAOYSA-N Dimethylsulphoxide Chemical compound CS(C)=O IAZDPXIOMUYVGZ-UHFFFAOYSA-N 0.000 claims description 14
- 238000001816 cooling Methods 0.000 claims description 12
- 239000000126 substance Substances 0.000 claims description 12
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 12
- 239000011347 resin Substances 0.000 claims description 7
- 229920005989 resin Polymers 0.000 claims description 7
- 150000003505 terpenes Chemical class 0.000 claims description 7
- 235000007586 terpenes Nutrition 0.000 claims description 7
- ZORQXIQZAOLNGE-UHFFFAOYSA-N 1,1-difluorocyclohexane Chemical compound FC1(F)CCCCC1 ZORQXIQZAOLNGE-UHFFFAOYSA-N 0.000 claims description 6
- 235000013162 Cocos nucifera Nutrition 0.000 claims description 6
- 244000060011 Cocos nucifera Species 0.000 claims description 6
- 235000014113 dietary fatty acids Nutrition 0.000 claims description 6
- 239000000194 fatty acid Substances 0.000 claims description 6
- 229930195729 fatty acid Natural products 0.000 claims description 6
- 150000004665 fatty acids Chemical class 0.000 claims description 6
- 229920001522 polyglycol ester Polymers 0.000 claims description 6
- 239000001593 sorbitan monooleate Substances 0.000 claims description 6
- 229940035049 sorbitan monooleate Drugs 0.000 claims description 6
- 235000011069 sorbitan monooleate Nutrition 0.000 claims description 6
- NDLPOXTZKUMGOV-UHFFFAOYSA-N oxo(oxoferriooxy)iron hydrate Chemical compound O.O=[Fe]O[Fe]=O NDLPOXTZKUMGOV-UHFFFAOYSA-N 0.000 claims description 2
- 238000004519 manufacturing process Methods 0.000 claims 3
- 230000000007 visual effect Effects 0.000 abstract description 5
- 239000002585 base Substances 0.000 description 5
- 230000000694 effects Effects 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 208000003464 asthenopia Diseases 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 229910052793 cadmium Inorganic materials 0.000 description 1
- BDOSMKKIYDKNTQ-UHFFFAOYSA-N cadmium atom Chemical compound [Cd] BDOSMKKIYDKNTQ-UHFFFAOYSA-N 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 238000001514 detection method Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- LGZXYFMMLRYXLK-UHFFFAOYSA-N mercury(2+);sulfide Chemical compound [S-2].[Hg+2] LGZXYFMMLRYXLK-UHFFFAOYSA-N 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 239000012744 reinforcing agent Substances 0.000 description 1
- 235000014692 zinc oxide Nutrition 0.000 description 1
- 239000011787 zinc oxide Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C8/00—Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/45—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
- C04B41/52—Multiple coating or impregnating multiple coating or impregnating with the same composition or with compositions only differing in the concentration of the constituents, is classified as single coating or impregnation
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/80—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone of only ceramics
- C04B41/81—Coating or impregnation
- C04B41/89—Coating or impregnation for obtaining at least two superposed coatings having different compositions
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Ceramic Engineering (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Structural Engineering (AREA)
- Life Sciences & Earth Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Geochemistry & Mineralogy (AREA)
- Compositions Of Oxide Ceramics (AREA)
Abstract
The invention discloses a beige glaze and a method for preparing a beige glaze ceramic product by using the same, belonging to the technical field of ceramics. The yellow rice glaze is characterized by consisting of a surface glaze and a ground glaze, wherein the surface glaze and the ground glaze are as follows by mass: 1: 1-2. The overglaze comprises the following components: kaolin, feldspar, barium carbonate, sawdust, attapulgite, a dispersing agent and trioctyl citrate, wherein the ground glaze comprises the following components: iron oxide and manganese oxide. The prepared beige glaze ceramic product has high strength and beige antique visual effect.
Description
Technical Field
The invention belongs to the technical field of ceramics, and particularly relates to a beige glaze and a method for preparing a beige glaze ceramic product by using the same.
Background
The ceramic products in China are many in every year, the types of the ceramic products are even many, and the ceramic products have certain significance such as Chinese red ceramics, Chinese white ceramics and the like with Chinese characteristics. However, various bright and beautiful ceramic products on the market already give visual fatigue, and beige gives vintage visual effect, and vintage ceramic products on the market are rare, so that a beige glaze ceramic product needs to be developed to fill the blank of the market.
Disclosure of Invention
The invention aims to overcome the defects of the prior art and provides a beige glaze and a method for preparing a beige glaze ceramic product by using the beige glaze.
The invention adopts the following technical scheme:
the yellow glaze comprises a surface glaze and a bottom glaze, wherein the surface glaze and the bottom glaze are prepared from the following components in percentage by mass: 1: 1-2.
Further, the overglaze comprises the following components in parts by weight: 70-85 parts of kaolin, 10-15 parts of feldspar, 5-7 parts of barium carbonate, 10-15 parts of sawdust, 17-20 parts of attapulgite, 4-6 parts of a dispersing agent and 10-13 parts of trioctyl citrate.
Further, the ground coat comprises the following components in parts by weight: 70-75 parts of ferric oxide and 25-30 parts of manganese oxide.
Further, the dispersing agent comprises the following components in parts by weight: 3-5 parts of fatty acid polyglycol ester, 6-7 parts of sorbitan monooleate and 10-11 parts of coconut diethanolamide.
Further, the overglaze also comprises the following components in parts by mass: 4-6 parts of dimethyl sulfoxide and 11-15 parts of terpene resin.
The method for preparing the beige glaze ceramic product by using the beige glaze comprises the following steps:
step one, applying base coat and firing for one time:
applying the ground glaze on the surface of the ceramic blank, airing, absorbing water on the surface of the ground glaze by using a water-absorbing substance, then carrying out primary firing, and naturally cooling to obtain a primary fired product;
step two, applying surface glaze and secondary firing:
and (3) applying the overglaze to the primary fired product obtained in the step one, airing, absorbing water on the surface of the overglaze by using a water-absorbing substance, then carrying out secondary firing, and naturally cooling to obtain the beige glaze ceramic product.
Further, in the step one, the primary firing temperature is 500-600 ℃, and the primary firing time is 50-60 min.
Further, in the second step, the secondary firing temperature is 1250-1270 ℃, and the secondary firing time is 2-3 hours.
Compared with the prior art, the invention has the following beneficial effects:
firstly, in order to achieve the beige visual effect, firstly, iron oxide and manganese oxide are adopted as ground glaze and are combined with a ceramic blank to form a primary beige visual effect, and then a layer of overglaze is applied on the ground glaze, so that the ground glaze is effectively protected from being damaged;
secondly, the overglaze adopts kaolin as a main framework, feldspar, barium carbonate, attapulgite, a dispersing agent and trioctyl citrate are used as auxiliary materials, so that the transparency and the glossiness of the overglaze are improved, the beige visual effect of the overglaze is improved, a small amount of sawdust is added, the overglaze can generate more bubbles than common ceramic glaze during firing, pits appear on the glaze surface, and the flaw feeling is formed;
thirdly, in order to improve the strength of the overglaze, trioctyl citrate is adopted as a reinforcing agent and is matched with a dispersing agent to effectively improve the strength of the overglaze;
fourthly, when the overglaze also contains dimethyl sulfoxide and terpene resin, the strength of the overglaze is further improved.
Detailed Description
The raw materials adopted by the invention are all commercial products.
Example 1
The yellow glaze consists of a surface glaze and a ground glaze, wherein the surface glaze and the ground glaze are prepared from the following components in percentage by mass: 1:1.
The overglaze comprises the following components in parts by mass: 70 parts of kaolin, 10 parts of feldspar, 5 parts of barium carbonate, 10 parts of sawdust, 17 parts of attapulgite, 4 parts of a dispersing agent and 10 parts of trioctyl citrate.
The ground glaze comprises the following components in parts by weight: 70 parts of iron oxide and 30 parts of manganese oxide.
The dispersing agent comprises the following components in parts by weight: 3 parts of fatty acid polyglycol ester, 6 parts of sorbitan monooleate and 6 parts of coconut diethanolamide.
The method for preparing the beige glaze ceramic product by using the beige glaze comprises the following steps:
step one, applying base coat and firing for one time:
applying the ground glaze on the surface of the ceramic blank, airing, absorbing water on the surface of the ground glaze by using a water-absorbing substance, then carrying out primary firing at the temperature of 500 ℃ for 50min, and naturally cooling to obtain a primary fired product;
step two, applying surface glaze and secondary firing:
and (3) applying the overglaze to the primary fired product obtained in the step one, airing, absorbing water on the surface of the overglaze by using a water-absorbing substance, then performing secondary firing at 1250 ℃, wherein the secondary firing time is 2 hours, and naturally cooling to obtain the beige glaze ceramic product.
Example 2
The yellow glaze consists of a surface glaze and a ground glaze, wherein the surface glaze and the ground glaze are prepared from the following components in percentage by mass: 1:1.
The overglaze comprises the following components in parts by mass: 75 parts of kaolin, 12 parts of feldspar, 6 parts of barium carbonate, 12 parts of sawdust, 18 parts of attapulgite, 5 parts of a dispersing agent and 11 parts of trioctyl citrate.
The ground glaze comprises the following components in parts by weight: 72 parts of iron oxide and 26 parts of manganese oxide.
The dispersing agent comprises the following components in parts by weight: 4 parts of fatty acid polyglycol ester, 6 parts of sorbitan monooleate and 11 parts of coconut diethanolamide.
The method for preparing the beige glaze ceramic product by using the beige glaze comprises the following steps:
step one, applying base coat and firing for one time:
applying the ground glaze on the surface of the ceramic blank, airing, absorbing water on the surface of the ground glaze by using a water-absorbing substance, then carrying out primary firing at the temperature of 530 ℃ for 55min, and naturally cooling to obtain a primary fired product;
step two, applying surface glaze and secondary firing:
and (3) applying the overglaze to the primary fired product obtained in the step one, airing, absorbing water on the surface of the overglaze by using a water-absorbing substance, then performing secondary firing at the temperature of 1260 ℃, wherein the secondary firing time is 2.5h, and naturally cooling to obtain the beige glaze ceramic product.
Example 3
The yellow glaze consists of a surface glaze and a ground glaze, wherein the surface glaze and the ground glaze are prepared from the following components in percentage by mass: 1:2.
The overglaze comprises the following components in parts by mass: 80 parts of kaolin, 13 parts of feldspar, 6 parts of barium carbonate, 14 parts of sawdust, 19 parts of attapulgite, 5 parts of a dispersing agent and 13 parts of trioctyl citrate.
The ground glaze comprises the following components in parts by weight: 73 parts of iron oxide and 28 parts of manganese oxide.
The dispersing agent comprises the following components in parts by weight: 4 parts of fatty acid polyglycol ester, 7 parts of sorbitan monooleate and 11 parts of coconut diethanolamide.
The method for preparing the beige glaze ceramic product by using the beige glaze comprises the following steps:
step one, applying base coat and firing for one time:
applying the ground glaze on the surface of a ceramic blank, airing, absorbing water on the surface of the ground glaze by using a water-absorbing substance, then carrying out primary firing at the temperature of 500-600 ℃ for 50-60 min, and naturally cooling to obtain a primary fired product;
step two, applying surface glaze and secondary firing:
and (3) applying the overglaze to the primary fired product obtained in the step one, airing, absorbing water on the surface of the overglaze by using a water-absorbing substance, then performing secondary firing at the temperature of 1260 ℃, wherein the secondary firing time is 3 hours, and naturally cooling to obtain the beige glaze ceramic product.
Example 4
The yellow glaze consists of a surface glaze and a ground glaze, wherein the surface glaze and the ground glaze are prepared from the following components in percentage by mass: 1:2.
The overglaze comprises the following components in parts by mass: 85 parts of kaolin, 15 parts of feldspar, 7 parts of barium carbonate, 15 parts of sawdust, 20 parts of attapulgite, 6 parts of a dispersing agent, 13 parts of trioctyl citrate, 27 parts of feldspar, 6 parts of dimethyl sulfoxide and 15 parts of terpene resin.
The ground glaze comprises the following components in parts by weight: 75 parts of iron oxide and 30 parts of manganese oxide.
The dispersing agent comprises the following components in parts by weight: 5 parts of fatty acid polyglycol ester, 7 parts of sorbitan monooleate and 11 parts of coconut diethanolamide.
The method for preparing the beige glaze ceramic product by using the beige glaze comprises the following steps:
step one, applying base coat and firing for one time:
applying the ground glaze on the surface of the ceramic blank, airing, absorbing water on the surface of the ground glaze by using a water-absorbing substance, then carrying out primary firing at the temperature of 600 ℃ for 60min, and naturally cooling to obtain a primary fired product;
step two, applying surface glaze and secondary firing:
and (3) applying the overglaze to the primary fired product obtained in the step one, airing, absorbing water on the surface of the overglaze by using a water-absorbing substance, then performing secondary firing at 1270 ℃ for 3h, and naturally cooling to obtain the beige glaze ceramic product.
Example 5
Compared with example 4, the difference is that: the overglaze also comprises the following components in parts by mass: 4 parts of dimethyl sulfoxide and 11 parts of terpene resin.
Example 6
Compared with example 4, the difference is that: the overglaze also comprises the following components in parts by mass: 5 parts of dimethyl sulfoxide and 14 parts of terpene resin.
EXAMPLE seven
Compared with example 4, the difference is that: the overglaze also comprises the following components in parts by mass: 6 parts of dimethyl sulfoxide and 15 parts of terpene resin.
The products prepared in the above examples 1 to 6 were tested, and the test results are shown in the following table 1:
1. carrying out low-concentration acid and alkali resistance detection according to GB/T4100-2006;
2. GB/T3534-2002 is used for detecting the content of the soluble lead and the content of the soluble cadmium;
3. GB/T15614-;
table 1 shows the results of testing the beige-glazed ceramic products obtained in examples 1 to 3 and comparative examples 1 to 2:
TABLE 1
As can be seen from table 1, the products obtained in examples 4 to 6 have higher glossiness than those obtained in examples 1 to 3, but do not affect the antique old feeling effect, and are the product effect required by the ceramic product prepared by the technology of the present invention, and the glaze has a slightly rough feeling, and has marks generated by bubbles rushing out of the glaze, thereby forming pits, giving a crushing feeling to people, and having a chronological feeling.
While the foregoing is directed to the preferred embodiment of the present invention, it will be understood by those skilled in the art that various changes and modifications may be made without departing from the spirit and scope of the invention.
Claims (8)
1. The yellow rice glaze is characterized by consisting of a surface glaze and a ground glaze, wherein the surface glaze and the ground glaze are prepared from the following components in percentage by mass: 1: 1-2.
2. The beige glaze according to claim 1, wherein the overglaze comprises the following components in parts by mass: 70-85 parts of kaolin, 10-15 parts of feldspar, 5-7 parts of barium carbonate, 10-15 parts of sawdust, 17-20 parts of attapulgite, 4-6 parts of a dispersing agent and 10-13 parts of trioctyl citrate.
3. The beige glaze according to claim 1, wherein the ground glaze comprises the following components in parts by mass: 70-75 parts of ferric oxide and 25-30 parts of manganese oxide.
4. The beige glaze according to claim 2, wherein the dispersant comprises the following components in parts by mass: 3-5 parts of fatty acid polyglycol ester, 6-7 parts of sorbitan monooleate and 10-11 parts of coconut diethanolamide.
5. The beige glaze according to claim 2, wherein the overglaze further comprises the following components in parts by mass: 4-6 parts of dimethyl sulfoxide and 11-15 parts of terpene resin.
6. A method of making a beige glazed ceramic article from the beige glaze of claim 1, comprising the steps of:
step one, applying base coat and firing for one time:
applying the ground glaze on the surface of the ceramic blank, airing, absorbing water on the surface of the ground glaze by using a water-absorbing substance, then carrying out primary firing, and naturally cooling to obtain a primary fired product;
step two, applying surface glaze and secondary firing:
and (3) applying the overglaze to the primary fired product obtained in the step one, airing, absorbing water on the surface of the overglaze by using a water-absorbing substance, then carrying out secondary firing, and naturally cooling to obtain the beige glaze ceramic product.
7. The method for producing a beige glazed ceramic product according to claim 6, wherein the first firing temperature in the step one is 500 to 600 ℃, and the first firing time is 50 to 60 min.
8. The method for producing a beige glazed ceramic product according to claim 6, wherein in the second step, the secondary firing temperature is 1250 to 1270 ℃ and the secondary firing time is 2 to 3 hours.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202110541123.6A CN113213758A (en) | 2021-05-18 | 2021-05-18 | Mihuang glaze and method for preparing mihuang glaze ceramic product by using same |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202110541123.6A CN113213758A (en) | 2021-05-18 | 2021-05-18 | Mihuang glaze and method for preparing mihuang glaze ceramic product by using same |
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| Publication Number | Publication Date |
|---|---|
| CN113213758A true CN113213758A (en) | 2021-08-06 |
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| CN202110541123.6A Pending CN113213758A (en) | 2021-05-18 | 2021-05-18 | Mihuang glaze and method for preparing mihuang glaze ceramic product by using same |
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Citations (5)
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|---|---|---|---|---|
| CN104478483A (en) * | 2014-11-18 | 2015-04-01 | 福建省德化协发光洋陶器有限公司 | Double-layer transmutation glaze and preparation method thereof |
| CN105272363A (en) * | 2015-10-16 | 2016-01-27 | 德化县如瓷生活文化有限公司 | She inkstone imitated porcelain with golden star and golden halo effects and firing method |
| CN107500722A (en) * | 2017-09-29 | 2017-12-22 | 禹州市大龙山钧瓷文化有限公司 | A kind of lightweight sky blue glaze pottery |
| CN109179993A (en) * | 2018-11-12 | 2019-01-11 | 福建省德化县华泰陶瓷有限公司 | Dark fund glaze, the preparation method of dark fund glaze and dark fund glaze method for preparing ceramic is prepared with it |
| CN111978091A (en) * | 2020-09-04 | 2020-11-24 | 福建省春秋陶瓷实业有限公司 | Ceramic product with coffee ground glaze and green overglaze and preparation method thereof |
-
2021
- 2021-05-18 CN CN202110541123.6A patent/CN113213758A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104478483A (en) * | 2014-11-18 | 2015-04-01 | 福建省德化协发光洋陶器有限公司 | Double-layer transmutation glaze and preparation method thereof |
| CN105272363A (en) * | 2015-10-16 | 2016-01-27 | 德化县如瓷生活文化有限公司 | She inkstone imitated porcelain with golden star and golden halo effects and firing method |
| CN107500722A (en) * | 2017-09-29 | 2017-12-22 | 禹州市大龙山钧瓷文化有限公司 | A kind of lightweight sky blue glaze pottery |
| CN109179993A (en) * | 2018-11-12 | 2019-01-11 | 福建省德化县华泰陶瓷有限公司 | Dark fund glaze, the preparation method of dark fund glaze and dark fund glaze method for preparing ceramic is prepared with it |
| CN111978091A (en) * | 2020-09-04 | 2020-11-24 | 福建省春秋陶瓷实业有限公司 | Ceramic product with coffee ground glaze and green overglaze and preparation method thereof |
Non-Patent Citations (1)
| Title |
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| 夏征农 陈至立主编: "《大辞海》", 31 December 2015, 上海辞书出版社 * |
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Application publication date: 20210806 |