CN113025883B - 1000MPa cold-rolled dual-phase steel with excellent local forming performance and preparation method thereof - Google Patents
1000MPa cold-rolled dual-phase steel with excellent local forming performance and preparation method thereof Download PDFInfo
- Publication number
- CN113025883B CN113025883B CN202110155733.2A CN202110155733A CN113025883B CN 113025883 B CN113025883 B CN 113025883B CN 202110155733 A CN202110155733 A CN 202110155733A CN 113025883 B CN113025883 B CN 113025883B
- Authority
- CN
- China
- Prior art keywords
- cold
- steel
- 1000mpa
- excellent local
- phase steel
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- 229910000885 Dual-phase steel Inorganic materials 0.000 title claims abstract description 39
- 238000002360 preparation method Methods 0.000 title claims abstract description 10
- 229910000831 Steel Inorganic materials 0.000 claims abstract description 33
- 239000010959 steel Substances 0.000 claims abstract description 33
- 229910000859 α-Fe Inorganic materials 0.000 claims abstract description 21
- 239000000126 substance Substances 0.000 claims abstract description 12
- 229910052804 chromium Inorganic materials 0.000 claims abstract description 11
- 229910052748 manganese Inorganic materials 0.000 claims abstract description 11
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims abstract description 8
- 229910052796 boron Inorganic materials 0.000 claims abstract description 7
- 229910052782 aluminium Inorganic materials 0.000 claims abstract description 5
- 239000012535 impurity Substances 0.000 claims abstract description 5
- 229910052750 molybdenum Inorganic materials 0.000 claims abstract description 5
- 229910052742 iron Inorganic materials 0.000 claims abstract description 4
- 229910000734 martensite Inorganic materials 0.000 claims description 34
- 238000005096 rolling process Methods 0.000 claims description 32
- 238000000034 method Methods 0.000 claims description 28
- 238000002791 soaking Methods 0.000 claims description 25
- 238000010438 heat treatment Methods 0.000 claims description 22
- 238000000137 annealing Methods 0.000 claims description 16
- 230000008569 process Effects 0.000 claims description 15
- 239000000203 mixture Substances 0.000 claims description 13
- 238000010583 slow cooling Methods 0.000 claims description 10
- 238000005336 cracking Methods 0.000 claims description 8
- 238000005097 cold rolling Methods 0.000 claims description 7
- 238000001816 cooling Methods 0.000 claims description 7
- 238000005452 bending Methods 0.000 claims description 5
- 238000003723 Smelting Methods 0.000 claims description 3
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 3
- 238000005242 forging Methods 0.000 claims description 3
- 239000007789 gas Substances 0.000 claims description 3
- 229910052760 oxygen Inorganic materials 0.000 claims description 3
- 239000001301 oxygen Substances 0.000 claims description 3
- 230000009467 reduction Effects 0.000 claims description 3
- 229910052717 sulfur Inorganic materials 0.000 claims description 3
- 238000005204 segregation Methods 0.000 abstract description 7
- 238000005728 strengthening Methods 0.000 abstract description 6
- 239000013078 crystal Substances 0.000 abstract 1
- 238000007670 refining Methods 0.000 abstract 1
- 229910001566 austenite Inorganic materials 0.000 description 7
- 230000000052 comparative effect Effects 0.000 description 7
- 230000000694 effects Effects 0.000 description 6
- 230000015572 biosynthetic process Effects 0.000 description 5
- 230000004048 modification Effects 0.000 description 5
- 238000012986 modification Methods 0.000 description 5
- 238000004458 analytical method Methods 0.000 description 4
- 230000009286 beneficial effect Effects 0.000 description 4
- 238000009749 continuous casting Methods 0.000 description 4
- 239000012467 final product Substances 0.000 description 4
- 239000000463 material Substances 0.000 description 4
- 229910052799 carbon Inorganic materials 0.000 description 3
- 238000004453 electron probe microanalysis Methods 0.000 description 3
- 230000006872 improvement Effects 0.000 description 3
- 239000002244 precipitate Substances 0.000 description 3
- 239000000047 product Substances 0.000 description 3
- 239000006104 solid solution Substances 0.000 description 3
- 239000000243 solution Substances 0.000 description 3
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
- 230000002411 adverse Effects 0.000 description 2
- 238000005275 alloying Methods 0.000 description 2
- 229910001563 bainite Inorganic materials 0.000 description 2
- 239000011248 coating agent Substances 0.000 description 2
- 238000000576 coating method Methods 0.000 description 2
- 230000007547 defect Effects 0.000 description 2
- 238000005098 hot rolling Methods 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 150000001247 metal acetylides Chemical class 0.000 description 2
- 238000001556 precipitation Methods 0.000 description 2
- 230000032683 aging Effects 0.000 description 1
- 229910045601 alloy Inorganic materials 0.000 description 1
- 239000000956 alloy Substances 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 230000037396 body weight Effects 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- 230000002542 deteriorative effect Effects 0.000 description 1
- 230000018109 developmental process Effects 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 239000011159 matrix material Substances 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- PXHVJJICTQNCMI-UHFFFAOYSA-N nickel Substances [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 1
- 230000006911 nucleation Effects 0.000 description 1
- 238000010899 nucleation Methods 0.000 description 1
- 230000008520 organization Effects 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 230000005501 phase interface Effects 0.000 description 1
- 238000007747 plating Methods 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 230000000087 stabilizing effect Effects 0.000 description 1
- 238000009628 steelmaking Methods 0.000 description 1
- 230000035882 stress Effects 0.000 description 1
- 230000009466 transformation Effects 0.000 description 1
- 238000003466 welding Methods 0.000 description 1
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/02—Ferrous alloys, e.g. steel alloys containing silicon
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D1/00—General methods or devices for heat treatment, e.g. annealing, hardening, quenching or tempering
- C21D1/26—Methods of annealing
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D6/00—Heat treatment of ferrous alloys
- C21D6/002—Heat treatment of ferrous alloys containing Cr
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D6/00—Heat treatment of ferrous alloys
- C21D6/005—Heat treatment of ferrous alloys containing Mn
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D6/00—Heat treatment of ferrous alloys
- C21D6/008—Heat treatment of ferrous alloys containing Si
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D8/00—Modifying the physical properties by deformation combined with, or followed by, heat treatment
- C21D8/02—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips
- C21D8/0221—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips characterised by the working steps
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D9/00—Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor
- C21D9/0081—Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor for slabs; for billets
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/002—Ferrous alloys, e.g. steel alloys containing In, Mg, or other elements not provided for in one single group C22C38/001 - C22C38/60
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/06—Ferrous alloys, e.g. steel alloys containing aluminium
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
- C22C38/22—Ferrous alloys, e.g. steel alloys containing chromium with molybdenum or tungsten
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
- C22C38/28—Ferrous alloys, e.g. steel alloys containing chromium with titanium or zirconium
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
- C22C38/32—Ferrous alloys, e.g. steel alloys containing chromium with boron
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
- C22C38/38—Ferrous alloys, e.g. steel alloys containing chromium with more than 1.5% by weight of manganese
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D2211/00—Microstructure comprising significant phases
- C21D2211/005—Ferrite
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D2211/00—Microstructure comprising significant phases
- C21D2211/008—Martensite
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Physics & Mathematics (AREA)
- Thermal Sciences (AREA)
- Crystallography & Structural Chemistry (AREA)
- Heat Treatment Of Sheet Steel (AREA)
Abstract
Description
技术领域technical field
本发明涉及钢材制备技术领域,特别涉及一种具有优异局部成形性能的1000MPa冷轧双相钢及其制备方法。The invention relates to the technical field of steel preparation, in particular to a 1000 MPa cold-rolled dual-phase steel with excellent local formability and a preparation method thereof.
背景技术Background technique
随着汽车工业对于轻量化、安全性、低排放等的要求日益严苛,汽车新车型中高强钢使用比例持续增加。其中的典型代表,在“超轻钢车体—先进车概念”项目所设计的车身结构中,以抗拉强度为1000MPa的高强钢所占的比例最大,占汽车车身重量的29%~30%左右。With the increasingly stringent requirements of the automotive industry for lightweight, safety, and low emissions, the proportion of high-strength steel used in new car models continues to increase. A typical representative among them is the high-strength steel with a tensile strength of 1000 MPa, which accounts for the largest proportion in the body structure designed by the "Ultra Light Steel Body - Advanced Vehicle Concept" project, accounting for 29% to 30% of the car body weight. about.
传统的双相钢组织主要由较软的铁素体基体和强度较高的马氏体组成,这种组织性能特点为较低的屈强比,同时具有优良的延伸率,适合冲压成形的零件生产。但不可否认,双相钢在对于扩孔及翻边要求的零件成形上开裂率较高,而现有技术复相钢显示出扩孔性能的改进对于边缘延展性的改良起到积极作用,然而现有技术中普遍存在由于合金元素的添加导致退火过程中选择性氧化,最终造成磷化不良等表面缺陷;因此,在传统双相钢的基础上,对其局部成形性能进一步优化,实现具有优良扩孔性能的双相钢的开发可以进一步满足不同用户的使用要求。The traditional dual-phase steel structure is mainly composed of a softer ferrite matrix and a high-strength martensite. This structure and properties are characterized by a lower yield ratio and excellent elongation, which are suitable for stamping and forming parts. Production. However, it is undeniable that dual-phase steel has a higher cracking rate in the forming of parts required for hole expansion and flanging, while the prior art multi-phase steel shows that the improvement of hole expansion performance plays a positive role in the improvement of edge ductility. However, In the prior art, it is common in the prior art that the addition of alloying elements leads to selective oxidation during the annealing process, which eventually results in surface defects such as poor phosphating; The development of dual-phase steel with hole expansion performance can further meet the requirements of different users.
因此,如何制备一种具有优异局部成形性能的1000MPa冷轧双相钢,成为亟待解决的技术问题。Therefore, how to prepare a 1000MPa cold-rolled dual-phase steel with excellent local formability has become an urgent technical problem to be solved.
发明内容SUMMARY OF THE INVENTION
本发明目的是提供一种具有优异局部成形性能的1000MPa冷轧双相钢及其制备方法,涂覆性能好、局部成形性能佳。The purpose of the present invention is to provide a 1000MPa cold-rolled dual-phase steel with excellent local formability and a preparation method thereof, which have good coating performance and good local formability.
为了实现上述目的,本发明提供一种具有优异局部成形性能的1000MPa冷轧双相钢,所述钢的化学成分以质量分数计为:C:0.06~0.11%,Si:0.1~0.3%,Mn:1.5~2.4%,Cr:0.2~0.6%,Mo:0.2~0.6%,P:≤0.010%,S:≤0.006%,Ti:0.01~0.04%,Al:0.1~0.3%,B:0.0001~0.005%,其余为铁和不可避免的杂质,其中,Mn、Cr和B元素的质量分数满足:Mn+Cr+B>2.1%。In order to achieve the above object, the present invention provides a 1000MPa cold-rolled dual-phase steel with excellent local formability, and the chemical composition of the steel in terms of mass fraction is: C: 0.06-0.11%, Si: 0.1-0.3%, Mn : 1.5~2.4%, Cr: 0.2~0.6%, Mo: 0.2~0.6%, P: ≤0.010%, S: ≤0.006%, Ti: 0.01~0.04%, Al: 0.1~0.3%, B: 0.0001~ 0.005%, the rest are iron and inevitable impurities, wherein the mass fraction of Mn, Cr and B elements satisfies: Mn+Cr+B>2.1%.
进一步地,所述Mn:1.5~1.8%。Further, the Mn: 1.5-1.8%.
进一步地,所述钢的内部组织为双相组织,所述双相组织以体积百分比计包含60~90%马氏体,余量为铁素体;所述马氏体中包含尺寸为2~4μm马氏体岛,且所述2~4μm马氏体岛的体积占所述马氏体总体积的80%以上。Further, the internal structure of the steel is a dual-phase structure, and the dual-phase structure contains 60-90% martensite in volume percentage, and the balance is ferrite; the martensite contains 2-90% martensite in size. 4 μm martensite islands, and the volume of the 2-4 μm martensite islands accounts for more than 80% of the total volume of the martensite.
本发明还提供了所述具有优异局部成形性能的1000MPa冷轧双相钢的制备方法,所述方法包括:The present invention also provides a method for preparing the 1000MPa cold-rolled dual-phase steel with excellent local formability, the method comprising:
采用所述的优异局部成形性能的1000MPa冷轧双相钢的化学成分进行熔炼、锻造,获得钢坯;Use the chemical composition of the 1000MPa cold-rolled dual-phase steel with excellent local formability to carry out smelting and forging to obtain a steel billet;
将所述钢坯进行轧前加热、粗轧、精轧和卷取,获得热轧板;subjecting the steel billet to pre-rolling heating, rough rolling, finishing rolling and coiling to obtain a hot-rolled sheet;
将所述热轧板进行冷轧,获得冷硬带钢;cold-rolling the hot-rolled sheet to obtain chilled strip;
将所述冷硬带钢进行退火,获得退火钢板;所述退火包括加热段、均热段、缓冷段和快冷段,所述加热段为由室温以0.9℃/s~21℃/s的速率加热至780℃~835℃;所述均热段的气氛采用N2-H2混合气体,所述H2含量为5%~15%,均热温度为780℃~835℃,均热时间为28s~210s,露点为-45℃~-41℃,氧气含量2ppm~5ppm;所述缓冷段为由所述均热温度缓冷至600℃~700℃;所述快冷段为由600℃~700℃以≥30℃/s的速率冷却至250℃~330℃;The chilled steel strip is annealed to obtain an annealed steel sheet; the annealing includes a heating section, a soaking section, a slow cooling section and a fast cooling section, and the heating section is a temperature of 0.9°C/s to 21°C/s from room temperature The heating rate is heated to 780℃~835℃; the atmosphere of the soaking section adopts N2 - H2 mixed gas, the H2 content is 5%~15%, the soaking temperature is 780℃~835℃, and the soaking temperature is 780℃~835℃. The time is 28s~210s, the dew point is -45℃~-41℃, and the oxygen content is 2ppm~5ppm; the slow cooling section is from the soaking temperature to 600℃~700℃; 600℃~700℃ cooled to 250℃~330℃ at a rate of ≥30℃/s;
将所述退火钢板进行平整处理,获得所述的优异局部成形性能的1000MPa冷轧双相钢。The annealed steel sheet is subjected to a levelling treatment to obtain the 1000 MPa cold-rolled dual-phase steel with excellent local formability.
进一步地,所述轧前加热中,控制轧前加热的温度为1150℃~1300℃,均热的时间为130min~250min,均热后出炉,控制所述出炉的温度为1120℃~1230℃。Further, in the heating before rolling, the temperature of the heating before rolling is controlled to be 1150°C to 1300°C, the soaking time is 130min to 250min, and the furnace is released after soaking, and the temperature of the furnace is controlled to be 1120°C to 1230°C.
进一步地,所述粗轧出口温度为910℃~1030℃,所述粗轧道次为6道~10道。Further, the outlet temperature of the rough rolling is 910°C to 1030°C, and the rough rolling passes are 6 to 10 passes.
进一步地,所述精轧的终轧温度为880℃~940℃;所述卷取温度为540℃~660℃。Further, the finishing rolling temperature of the finishing rolling is 880°C to 940°C; the coiling temperature is 540°C to 660°C.
进一步地,所述冷轧压下率为45%~60%。Further, the cold rolling reduction ratio is 45% to 60%.
进一步地,所述退火过程中带钢通过所述加热段、均热段、缓冷段、快冷段的速度均控制在120m/min~170m/min。Further, in the annealing process, the speed of the strip passing through the heating section, the soaking section, the slow cooling section, and the fast cooling section is all controlled at 120 m/min to 170 m/min.
进一步地,所述平整处理时,平整延伸率为0.1%~0.2%。Further, during the flattening treatment, the flattening elongation is 0.1%-0.2%.
本发明实施例中的一个或多个技术方案,至少具有如下技术效果或优点:One or more technical solutions in the embodiments of the present invention have at least the following technical effects or advantages:
本发明提供的一种具有优异局部成形性能的1000MPa冷轧双相钢及其制备方法,通过合理设计化学成分,限制易偏析元素Mn的加入量,控制Mn+Cr+B>2.1%;从炼钢源头抑制了最终产品带状组织形成,同时配合添加一定的微合金元素Ti而不添加昂贵的Nb,一方面节约成本,另一方面进一步细化晶粒的效果,并在铁素体中形成纳米析出相,强化铁素体组织,获得强度、延伸率及扩孔性能的平衡,同时配合本发明中特殊的连续退火工艺对马氏体组织回火处理,达到减小马氏体和铁素体两相硬度差的目的;最终产品屈服强度≥600MPa,抗拉强度≥1000MPa,延伸率≥12%,扩孔率≥60%,沿轧制方向180°折弯半径0.5T不开裂,表现出优异的局部成形性能。The invention provides a 1000MPa cold-rolled dual-phase steel with excellent local formability and a preparation method thereof. By rationally designing the chemical composition, the addition amount of Mn, a segregation-prone element, is limited, and Mn+Cr+B>2.1% is controlled; The steel source inhibits the formation of the band-like structure of the final product, and at the same time, it is matched to add a certain microalloying element Ti without adding expensive Nb, which saves costs on the one hand, and further refines the grains on the other hand. Nano-precipitate phase strengthens the ferrite structure and obtains the balance of strength, elongation and hole expansion performance. At the same time, the special continuous annealing process in the present invention is used to temper the martensite structure to reduce the amount of martensite and ferrite. The purpose of the hardness difference between the two phases of the body; the final product yield strength ≥ 600MPa, tensile strength ≥ 1000MPa, elongation ≥ 12%, hole expansion rate ≥ 60%, 180° bending radius along the rolling direction 0.5T without cracking, showing Excellent local formability.
附图说明Description of drawings
为了更清楚地说明本发明实施例中的技术方案,下面将对实施例描述中所需要使用的附图作一简单地介绍,显而易见地,下面描述中的附图是本发明的一些实施例,对于本领域普通技术人员来讲,在不付出创造性劳动的前提下,还可以根据这些附图获得其它的附图。In order to illustrate the technical solutions in the embodiments of the present invention more clearly, the following briefly introduces the accompanying drawings used in the description of the embodiments. Obviously, the drawings in the following description are some embodiments of the present invention. For those of ordinary skill in the art, other drawings can also be obtained from these drawings without any creative effort.
图1为本发明实施例1制备得到的具有优异局部成形性能的1000MPa冷轧双相钢的金相组织图;1 is a metallographic structure diagram of a 1000MPa cold-rolled dual-phase steel with excellent local formability prepared in Example 1 of the present invention;
图2为本发明实施例1制备得到的具有优异局部成形性能的1000MPa冷轧双相钢的产品Cr和Mn EPMA分析结果;其中(A)为Cr的EPMA分析结果;(B)为Mn的EPMA分析结果Fig. 2 is the EPMA analysis result of Cr and Mn of the 1000MPa cold-rolled dual-phase steel with excellent local formability prepared in Example 1 of the present invention; wherein (A) is the EPMA analysis result of Cr; (B) is the EPMA analysis result of Mn Analysis results
具体实施方式Detailed ways
下文将结合具体实施方式和实施例,具体阐述本发明,本发明的优点和各种效果将由此更加清楚地呈现。本领域技术人员应理解,这些具体实施方式和实施例是用于说明本发明,而非限制本发明。The present invention will be described in detail below with reference to specific embodiments and examples, and the advantages and various effects of the present invention will be more clearly presented therefrom. It should be understood by those skilled in the art that these specific embodiments and examples are used to illustrate the present invention, but not to limit the present invention.
在整个说明书中,除非另有特别说明,本文使用的术语应理解为如本领域中通常所使用的含义。因此,除非另有定义,本文使用的所有技术和科学术语具有与本发明所属领域技术人员的一般理解相同的含义。若存在矛盾,本说明书优先。Throughout the specification, unless specifically stated otherwise, terms used herein are to be understood as commonly used in the art. Therefore, unless otherwise defined, all technical and scientific terms used herein have the same meaning as commonly understood by one of ordinary skill in the art to which this invention belongs. In case of conflict, the present specification takes precedence.
除非另有特别说明,本发明中用到的各种原材料、试剂、仪器和设备等,均可通过市场购买获得或者可通过现有方法获得。Unless otherwise specified, all kinds of raw materials, reagents, instruments and equipment used in the present invention can be purchased from the market or can be obtained by existing methods.
本申请实施例的技术方案为解决上述技术问题,总体思路如下:The technical solutions of the embodiments of the present application are to solve the above-mentioned technical problems, and the general idea is as follows:
根据本发明实施例一种典型的实施方式,提供一种具有优异局部成形性能的1000MPa冷轧双相钢,所述钢的化学成分以质量分数计为:C:0.06~0.11%,Si:0.1~0.3%,Mn:1.5~2.4%,Cr:0.2~0.6%,Mo:0.2~0.6%,P:≤0.010%,S:≤0.006%,Ti:0.01~0.04%,Al:0.1~0.3%,B:0.0001~0.005%,其余为铁和不可避免的杂质,其中,Mn、Cr和B元素的质量分数满足:Mn+Cr+B>2.1%。According to a typical embodiment of the embodiment of the present invention, a 1000MPa cold-rolled dual-phase steel with excellent local formability is provided, and the chemical composition of the steel in terms of mass fraction is: C: 0.06-0.11%, Si: 0.1 ~0.3%, Mn: 1.5~2.4%, Cr: 0.2~0.6%, Mo: 0.2~0.6%, P: ≤0.010%, S: ≤0.006%, Ti: 0.01~0.04%, Al: 0.1~0.3% , B: 0.0001-0.005%, and the rest are iron and inevitable impurities, wherein the mass fractions of Mn, Cr and B elements satisfy: Mn+Cr+B>2.1%.
本申请通过优化组成元素、引入中间层-镀镍层进而形成以上化学成分的具有优异局部成形性能的1000MPa冷轧双相钢,是基于以下原理:The present application forms a 1000MPa cold-rolled dual-phase steel with excellent local formability of the above chemical composition by optimizing the composition elements, introducing an intermediate layer-nickel plating layer, and is based on the following principles:
C:0.06~0.11%,C元素是冷轧双相钢中最重要的固溶强化元素及提高奥氏体淬透性元素,为了在冷却过程中获得足够的马氏体量以保证强度,同时避免C含量过高恶化焊接性能,C含量需控制0.06-0.11%。C: 0.06~0.11%, C element is the most important solid solution strengthening element and element to improve austenite hardenability in cold-rolled dual-phase steel. To avoid excessive C content from deteriorating welding performance, the C content should be controlled at 0.06-0.11%.
Si:0.1~0.3%,Si元素也是重要的固溶强化元素,同时Si可以有效促进C元素向奥氏体富集,提高奥氏体淬透性同时,净化铁素体相,改善延伸率,但Si的缺点在于其过高的含量(>0.3%)会对连退过程中的发生表面富集,影响后续涂装,因此Si含量需控制在0.1-0.3%。Si: 0.1-0.3%, Si element is also an important solid solution strengthening element. At the same time, Si can effectively promote the enrichment of C element to austenite, improve the hardenability of austenite, and purify the ferrite phase and improve the elongation. However, the disadvantage of Si is that its too high content (>0.3%) will enrich the surface during the continuous retreat process and affect the subsequent coating, so the Si content needs to be controlled at 0.1-0.3%.
Mn:1.5~2.4%,Mn元素也是固溶强化、稳定奥氏体的重要元素,对强化具有重要作用,但Mn含量过高容易引起组织偏析,易导致成形开裂,恶化钢的综合性能,同时还会在退火过程中向表面富集,因此Mn含量不宜过高,需控制在1.5-2.4%。为了避免组织偏析,组织偏析导致应力集中引发偏析处早期开裂,进而恶化扩孔及折弯性能,优选的Mn≤1.8%。Mn: 1.5-2.4%, Mn element is also an important element for solid solution strengthening and stabilizing austenite, and plays an important role in strengthening, but too high Mn content can easily cause microstructure segregation, easily lead to forming cracking, and deteriorate the overall performance of the steel. It will also be enriched to the surface during the annealing process, so the Mn content should not be too high and should be controlled at 1.5-2.4%. In order to avoid the segregation of the structure, the stress concentration caused by the segregation of the structure causes the early cracking of the segregation, which further deteriorates the hole expansion and bending performance, and the preferred Mn is less than or equal to 1.8%.
P:≤0.010%,P元素可抑制碳化物的形成,因此认为含极少量的P元素是有利的,但在晶界偏聚将会导致晶界强度下降从而恶化材料机械性能,且为碳当量贡献的显著影响元素,本发明P元素含量控制在0.010%以下。P: ≤ 0.010%, P element can inhibit the formation of carbides, so it is considered beneficial to contain a very small amount of P element, but segregation at the grain boundary will lead to a decrease in grain boundary strength and deteriorate the mechanical properties of the material, and it is equivalent to carbon. Contributing significant elements, the content of P element in the present invention is controlled below 0.010%.
S:≤0.006%,S元素作为有害元素,主要防止与Mn结合产生MnS从而恶化材料性能,且为碳当量贡献显著影响元素,本发明S元素含量控制在0.006%以下。S: ≤0.006%, as a harmful element, S element mainly prevents the combination with Mn to generate MnS to deteriorate the material properties, and contributes significantly to the carbon equivalent. The content of S element in the present invention is controlled below 0.006%.
Cr:0.2~0.6%,Cr元素可以提高奥氏体淬透性,从而获得足够量的马氏体保证强度,添加一定含量的Cr来获得强度保证了合金制造成本足够低;但同时Cr元素为铁素体区扩大元素,Cr元素过多会导致两相区缩小,还会阻碍贝氏体转变,因此限制Cr的添加以保证一定量贝氏体的获得,因此Cr含量需控制0.2-0.6%。Cr: 0.2-0.6%, Cr element can improve the hardenability of austenite, so as to obtain a sufficient amount of martensite to ensure the strength, and adding a certain content of Cr to obtain the strength ensures that the manufacturing cost of the alloy is low enough; but at the same time, the Cr element is The ferrite area expands the element. Too much Cr element will lead to the shrinking of the two-phase area and hinder the bainite transformation. Therefore, the addition of Cr is limited to ensure the acquisition of a certain amount of bainite. Therefore, the Cr content needs to be controlled at 0.2-0.6% .
Mo:0.2~0.6%,Mo元素也可以提高奥氏体淬透性,从而获得足够量的马氏体保证强度,但过多的Mo元素易在铁素体当中偏聚,恶化延性,同时Mo元素成本较高,因此Mo含量需控制在一个合适范围。因此Mo含量需控制0.2~0.6%。Mo: 0.2-0.6%, Mo element can also improve the hardenability of austenite, so as to obtain a sufficient amount of martensite to ensure the strength, but too much Mo element is easy to segregate in the ferrite and deteriorate the ductility. The element cost is high, so the Mo content needs to be controlled within an appropriate range. Therefore, the Mo content needs to be controlled at 0.2 to 0.6%.
Ti:0.01~0.04%,Ti元素作为微合金元素,可以与C结合生成纳米析出相,起到细化晶粒及析出强化的作用,对改善组织形态、提高屈服强度有着显著的作用,但含量过高又会对延伸率造成不利影响,添加一定量的Ti可获得强度、延伸率及扩孔性能的平衡。同时添加Ti微合金也可抑制MnS有害杂质的形成,有利于减少局部成形时微裂纹形核点,因此其含量需控制在0.01-0.04%。Ti: 0.01-0.04%, as a micro-alloying element, Ti element can combine with C to form nano-precipitation phase, which plays the role of grain refinement and precipitation strengthening, and has a significant effect on improving the microstructure and yield strength, but the content If it is too high, it will adversely affect the elongation. Adding a certain amount of Ti can obtain the balance of strength, elongation and hole expansion performance. At the same time, adding Ti microalloy can also inhibit the formation of MnS harmful impurities, which is beneficial to reduce the nucleation point of microcracks during local forming, so its content should be controlled at 0.01-0.04%.
B:0.0001~0.005%,加入微量的B能显著提高钢的淬透性,在提高材料强度的同时对其他性能无明显影响,但B含量过高会引起脆性,因此其含量需控制在0.0001-0.0005%。B: 0.0001-0.005%, adding a small amount of B can significantly improve the hardenability of steel, and has no obvious effect on other properties while improving the strength of the material, but too high content of B will cause brittleness, so its content should be controlled within 0.0001- 0.0005%.
Al:0.1~0.3%,Al作为炼钢主要的脱氧剂,其热力学作用与Si类似,可以抑制碳化物形成,间接稳定奥氏体,本发明的铝含量需控制在Al:0.1-0.3%。Al: 0.1-0.3%. As the main deoxidizer in steelmaking, Al has a thermodynamic effect similar to that of Si, which can inhibit the formation of carbides and indirectly stabilize austenite. The aluminum content of the present invention needs to be controlled at Al: 0.1-0.3%.
为确保连退之后仍可获得足够的马氏体保障抗拉强度,Mn、Cr、B等淬透性提高元素含量需要进一步限定,本发明规定Mn+Cr+B>2.1%。In order to ensure that sufficient martensite can still be obtained to guarantee the tensile strength after continuous withdrawal, the content of hardenability-improving elements such as Mn, Cr, and B needs to be further limited. The present invention stipulates that Mn+Cr+B>2.1%.
作为一种优选选的实施方式,所述Mn:1.5~1.8%。进一步获得足够的马氏体保障抗拉强度。As a preferred embodiment, the Mn: 1.5-1.8%. Further obtain sufficient martensite to guarantee tensile strength.
作为一种优选选的实施方式,所述钢的内部组织为双相组织,所述双相组织以体积百分比计包含60~90%马氏体,余量为铁素体;所述马氏体中包含尺寸为2~4μm马氏体岛,且所述2~4μm马氏体岛的体积占所述马氏体总体积的80%以上。As a preferred embodiment, the internal structure of the steel is a dual-phase structure, and the dual-phase structure contains 60-90% martensite by volume percentage, and the balance is ferrite; the martensite It contains martensite islands with a size of 2-4 μm, and the volume of the 2-4 μm martensite islands accounts for more than 80% of the total volume of the martensite.
在铁素体中形成有纳米析出相可以强化铁素体组织,获得强度、延伸率及扩孔性能的平衡;同时配合连续退火过程时效段对马氏体组织回火处理,使得2~4μm马氏体岛的体积占所述马氏体总体积的80%以上,达到减小马氏体和铁素体两相硬度差的目的。所述铁素体中形成有纳米析出相,所述纳米析出相的体积占铁素体中的体积分数小于1%;若2~4μm马氏体岛的体积分数过低,大尺寸马氏体的存在将诱发沿相界面开裂风险,对局部成形性能提升具有不利影响;The formation of nano-precipitated phases in the ferrite can strengthen the ferrite structure and obtain the balance of strength, elongation and hole expansion performance; at the same time, the martensitic structure is tempered in the aging section of the continuous annealing process, so that the 2-4 μm martensite structure is tempered. The volume of the ingot island accounts for more than 80% of the total volume of the martensite, so as to achieve the purpose of reducing the hardness difference between the two phases of martensite and ferrite. A nano-precipitate phase is formed in the ferrite, and the volume of the nano-precipitate phase accounts for less than 1% of the volume fraction in the ferrite; The existence of shale will induce the risk of cracking along the phase interface, which will have an adverse effect on the improvement of local formability;
根据本发明另一种典型的实施方式,提供了所述具有优异局部成形性能的1000MPa冷轧双相钢的制备方法,所述制备方法包括:According to another typical embodiment of the present invention, a preparation method of the 1000MPa cold-rolled dual-phase steel with excellent local formability is provided, and the preparation method includes:
采用所述的优异局部成形性能的1000MPa冷轧双相钢的化学成分进行熔炼、锻造,获得钢坯;Use the chemical composition of the 1000MPa cold-rolled dual-phase steel with excellent local formability to carry out smelting and forging to obtain a steel billet;
将所述钢坯进行轧前加热、粗轧、精轧和卷取,获得热轧板;subjecting the steel billet to pre-rolling heating, rough rolling, finishing rolling and coiling to obtain a hot-rolled sheet;
将所述热轧板进行冷轧,获得冷硬带钢;cold-rolling the hot-rolled sheet to obtain chilled strip;
将所述冷硬带钢进行退火,获得退火钢板;所述退火包括加热段、均热段、缓冷段和快冷段,所述加热段为由室温以0.9℃/s~21℃/s的速率加热至780℃~835℃;所述均热段的气氛采用N2-H2混合气体,所述H2含量为5%~15%,均热温度为780℃~835℃,均热时间为28s~210s,露点为-45℃~-41℃,氧气含量2ppm~5ppm;所述缓冷段为由所述均热温度缓冷至600℃~700℃;所述快冷段为由600℃~700℃以≥30℃/s的速率冷却至250℃~330℃;The chilled steel strip is annealed to obtain an annealed steel sheet; the annealing includes a heating section, a soaking section, a slow cooling section and a fast cooling section, and the heating section is a temperature of 0.9°C/s to 21°C/s from room temperature The heating rate is heated to 780℃~835℃; the atmosphere of the soaking section adopts N2 - H2 mixed gas, the H2 content is 5%~15%, the soaking temperature is 780℃~835℃, and the soaking temperature is 780℃~835℃. The time is 28s~210s, the dew point is -45℃~-41℃, and the oxygen content is 2ppm~5ppm; the slow cooling section is from the soaking temperature to 600℃~700℃; 600℃~700℃ cooled to 250℃~330℃ at a rate of ≥30℃/s;
将所述退火钢板进行平整处理,获得所述的优异局部成形性能的1000MPa冷轧双相钢。The annealed steel sheet is subjected to a levelling treatment to obtain the 1000 MPa cold-rolled dual-phase steel with excellent local formability.
本发明中特殊的连续退火工艺(退火包括加热段、均热段、缓冷段和快冷段)对马氏体组织回火处理,达到减小马氏体和铁素体两相硬度差的目的;最终产品屈服强度≥600MPa,抗拉强度≥1000MPa,延伸率≥12%,扩孔率≥60%,沿轧制方向180°折弯半径0.5T不开裂,表现出优异的局部成形性能。The special continuous annealing process in the present invention (annealing includes heating section, soaking section, slow cooling section and rapid cooling section) tempers the martensite structure, so as to reduce the hardness difference between the two phases of martensite and ferrite. Purpose: The final product yield strength ≥ 600MPa, tensile strength ≥ 1000MPa, elongation ≥ 12%, hole expansion rate ≥ 60%, 180° bending radius 0.5T along the rolling direction without cracking, showing excellent local formability.
作为一种可选的实施方式,所述轧前加热中,控制轧前加热的温度为1150℃~1300℃,均热的时间为130min~250min,均热后出炉,控制所述出炉的温度为1120℃~1230℃。As an optional embodiment, in the pre-rolling heating, the temperature of the pre-rolling heating is controlled to be 1150°C to 1300°C, the soaking time is 130min to 250min, and the furnace is released after soaking, and the temperature of the furnace is controlled to be 1120℃~1230℃.
作为一种可选的实施方式,所述粗轧出口温度为910℃~1030℃,所述粗轧道次为6道~10道。As an optional embodiment, the outlet temperature of the rough rolling is 910°C to 1030°C, and the rough rolling passes are 6 to 10 passes.
作为一种可选的实施方式,所述精轧的终轧温度为880℃~940℃;所述卷取温度为540℃~660℃。As an optional embodiment, the finishing rolling temperature of the finishing rolling is 880°C to 940°C; the coiling temperature is 540°C to 660°C.
作为一种可选的实施方式,所述冷轧压下率为45%~60%。As an optional embodiment, the cold rolling reduction ratio is 45% to 60%.
作为一种可选的实施方式,所述退火过程中带钢通过所述加热段、均热段、缓冷段、快冷段的速度均控制在120m/min~170m/min。控制在所述速度内有利于将带钢在炉区各段时间控制在一定范围,对调控组织有重要影响。As an optional embodiment, in the annealing process, the speed of the strip passing through the heating section, soaking section, slow cooling section, and rapid cooling section is controlled at 120 m/min to 170 m/min. Controlling the speed within the stated speed is beneficial to control the time of the strip steel in the furnace zone within a certain range, which has an important influence on the regulation and control organization.
作为一种可选的实施方式,所述平整处理时,平整延伸率为0.1%~0.2%。有利于获得较好的表面质量,同时进一步调整屈服强度。As an optional embodiment, during the flattening treatment, the flattening elongation is 0.1% to 0.2%. It is beneficial to obtain better surface quality and further adjust the yield strength.
下面将结合实施例、对比例及实验数据对本申请的一种具有优异局部成形性能的1000MPa冷轧双相钢及其制备方法进行详细说明。A 1000MPa cold-rolled dual-phase steel with excellent local formability and a preparation method thereof of the present application will be described in detail below with reference to the examples, comparative examples and experimental data.
(1)将钢水经过转炉冶炼,采用连铸方式获得连铸坯;实际化学成分如表1所示。(1) The molten steel is smelted in a converter, and the continuous casting billet is obtained by continuous casting; the actual chemical composition is shown in Table 1.
表1-1000MPa冷轧双相钢化学成分(wt%)Table 1-Chemical composition of 1000MPa cold-rolled dual-phase steel (wt%)
(2)将上述连铸坯经过热轧获得热轧板,连铸坯加热至1150~1300℃,保温,终轧温度880-940℃,卷取温度540~660℃,热轧板进一步经冷轧得到冷硬带钢,冷轧变形量45-60%,具体如表2所示。(2) The above-mentioned continuous casting billet is subjected to hot rolling to obtain a hot-rolled sheet, the continuous casting billet is heated to 1150-1300 ℃, and the temperature is kept warm, the final rolling temperature is 880-940 ℃, and the coiling temperature is 540-660 ℃. The cold hard strip is obtained by rolling, and the cold rolling deformation amount is 45-60%, as shown in Table 2.
表2-1000MPa冷轧双相钢热轧工艺及产品厚度Table 2-1000MPa cold-rolled dual-phase steel hot rolling process and product thickness
(3)将上述冷硬带钢进行连续退火工艺处理得到成品。连退退火工艺见表3。(3) The above-mentioned chilled strip steel is subjected to a continuous annealing process to obtain a finished product. The continuous annealing process is shown in Table 3.
表3 1000MPa冷轧双相钢连续退火工艺Table 3 Continuous annealing process of 1000MPa cold-rolled dual-phase steel
对成品取样进行力学性能测试,结果见表4。The mechanical properties of the finished product samples were tested, and the results are shown in Table 4.
表4-1000MPa冷轧双相钢力学性能Table 4-Mechanical properties of 1000MPa cold-rolled dual-phase steel
由表4数据可知:It can be seen from the data in Table 4 that:
扩孔率是用来测量钢板在冲压期间的翻孔能力,扩孔率越高表明材料抗局部变形能力越好;The hole expansion rate is used to measure the hole turning ability of the steel plate during stamping. The higher the hole expansion rate, the better the local deformation resistance of the material;
对比例1中,Mn+Cr+B<2.1%,其余步骤均同实施例1,强度偏低;In Comparative Example 1, Mn+Cr+B<2.1%, the rest of the steps are the same as in Example 1, and the strength is low;
对比例2中,未采用本发明的退火工艺,其余步骤均同实施例1,强度偏高,塑性较差,同时扩孔性能偏低;In Comparative Example 2, the annealing process of the present invention was not adopted, and the remaining steps were the same as those in Example 1, with high strength, poor plasticity, and low hole expansion performance;
实施例1-5中的最终产品屈服强度≥600MPa,抗拉强度≥1000MPa,延伸率≥12%,扩孔率≥60%,沿轧制方向180°折弯半径0.5T不开裂;The final product in Examples 1-5 has a yield strength of ≥600MPa, a tensile strength of ≥1000MPa, an elongation rate of ≥12%, a hole expansion rate of ≥60%, and no cracking along the rolling direction with a 180° bending radius of 0.5T;
附图1的详细说明:Detailed description of accompanying drawing 1:
附图1所示为实施例1冷轧双相钢试样典型的微观组织照片。由图1可知,组织包含铁素体和马氏体,所述铁素体中形成有纳米析出相;所述马氏体中包含尺寸为2~4μm马氏体岛,且所述2~4μm马氏体岛的体积占所述马氏体总体积的80%以上。Figure 1 shows a typical microstructure photo of the cold-rolled dual-phase steel sample of Example 1. It can be seen from FIG. 1 that the structure includes ferrite and martensite, and nano-precipitated phases are formed in the ferrite; the martensite includes martensite islands with a size of 2-4 μm, and the size of the 2-4 μm is The volume of martensite islands accounts for more than 80% of the total volume of the martensite.
由附图2可知,Cr及Mn元素分布非常均匀,这也进一步说明成分在带钢内部的均一性,消除了成分偏析导致的带状缺陷,由此进一步提升局部成形时应变在各相内部的均匀性。It can be seen from Figure 2 that the distribution of Cr and Mn elements is very uniform, which further illustrates the homogeneity of the composition within the strip, eliminates the band-like defects caused by the segregation of the composition, and further improves the localized forming of the strain inside each phase. uniformity.
最后,还需要说明的是,术语“包括”、“包含”或者其任何其他变体意在涵盖非排他性的包含,从而使得包括一系列要素的过程、方法、物品或者设备不仅包括那些要素,而且还包括没有明确列出的其他要素,或者是还包括为这种过程、方法、物品或者设备所固有的要素。Finally, it should also be noted that the terms "comprising", "comprising" or any other variation thereof are intended to encompass a non-exclusive inclusion such that a process, method, article or device comprising a series of elements includes not only those elements, but also Also included are other elements not expressly listed or inherent to such a process, method, article or apparatus.
尽管已描述了本发明的优选实施例,但本领域内的技术人员一旦得知了基本创造性概念,则可对这些实施例作出另外的变更和修改。所以,所附权利要求意欲解释为包括优选实施例以及落入本发明范围的所有变更和修改。Although preferred embodiments of the present invention have been described, additional changes and modifications to these embodiments may occur to those skilled in the art once the basic inventive concepts are known. Therefore, the appended claims are intended to be construed to include the preferred embodiment and all changes and modifications that fall within the scope of the present invention.
显然,本领域的技术人员可以对本发明进行各种改动和变型而不脱离本发明的精神和范围。这样,倘若本发明的这些修改和变型属于本发明权利要求及其等同技术的范围之内,则本发明也意图包含这些改动和变型在内。It will be apparent to those skilled in the art that various modifications and variations can be made in the present invention without departing from the spirit and scope of the invention. Thus, provided that these modifications and variations of the present invention fall within the scope of the claims of the present invention and their equivalents, the present invention is also intended to include these modifications and variations.
Claims (9)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN202110155733.2A CN113025883B (en) | 2021-02-04 | 2021-02-04 | 1000MPa cold-rolled dual-phase steel with excellent local forming performance and preparation method thereof |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN202110155733.2A CN113025883B (en) | 2021-02-04 | 2021-02-04 | 1000MPa cold-rolled dual-phase steel with excellent local forming performance and preparation method thereof |
Publications (2)
Publication Number | Publication Date |
---|---|
CN113025883A CN113025883A (en) | 2021-06-25 |
CN113025883B true CN113025883B (en) | 2022-04-19 |
Family
ID=76459992
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN202110155733.2A Active CN113025883B (en) | 2021-02-04 | 2021-02-04 | 1000MPa cold-rolled dual-phase steel with excellent local forming performance and preparation method thereof |
Country Status (1)
Country | Link |
---|---|
CN (1) | CN113025883B (en) |
Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2014201765A (en) * | 2013-04-02 | 2014-10-27 | 新日鐵住金株式会社 | Cold rolled steel sheet and method of producing cold rolled steel sheet |
CN106119702A (en) * | 2016-06-21 | 2016-11-16 | 宝山钢铁股份有限公司 | A kind of 980MPa level hot-rolled high-strength height reaming steel and manufacture method thereof |
Family Cites Families (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN111910123B (en) * | 2020-07-13 | 2022-03-22 | 首钢集团有限公司 | A kind of cold-rolled and continuously degraded ultra-high-strength steel with excellent phosphating performance and preparation method thereof |
-
2021
- 2021-02-04 CN CN202110155733.2A patent/CN113025883B/en active Active
Patent Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2014201765A (en) * | 2013-04-02 | 2014-10-27 | 新日鐵住金株式会社 | Cold rolled steel sheet and method of producing cold rolled steel sheet |
CN106119702A (en) * | 2016-06-21 | 2016-11-16 | 宝山钢铁股份有限公司 | A kind of 980MPa level hot-rolled high-strength height reaming steel and manufacture method thereof |
Also Published As
Publication number | Publication date |
---|---|
CN113025883A (en) | 2021-06-25 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
CN113403549B (en) | 1.2 GPa-grade fatigue-resistant high-formability ultrahigh-strength automobile steel and preparation method thereof | |
CN108504958B (en) | 690 MPa-grade hot-rolled thick-specification low-yield-ratio automobile spoke steel and preparation method thereof | |
CN102586688B (en) | A kind of dual phase sheet steel and manufacture method thereof | |
CN111893377A (en) | A kind of 1900MPa grade high-strength toughness aluminum-silicon coated steel sheet for hot stamping and preparation method thereof | |
CN110129668A (en) | A kind of 1000MPa level alloyed hot-dip galvanized composite phase steel and its preparation method | |
CN101928875A (en) | High-strength cold-rolled steel sheet with good formability and preparation method thereof | |
CN111172466B (en) | Plasticity-enhanced cold-rolled dual-phase steel with tensile strength of 590MPa and production method thereof | |
CN112442632B (en) | High-bending-resistance hot-rolled hot-forming steel and preparation method thereof | |
CN111926247A (en) | 800 MPa-grade cold-rolled hot-galvanized complex-phase steel and preparation method thereof | |
CN111910123A (en) | A kind of cold-rolled and continuously degraded ultra-high-strength steel with excellent phosphating performance and preparation method thereof | |
CN111893378A (en) | A kind of low-cost high-plasticity cold-rolled galvanized steel sheet and preparation method thereof | |
CN112251668A (en) | A kind of forming reinforced composite phase steel and preparation method thereof | |
CN111647801A (en) | 690 MPa-grade ferrite-martensite dual-phase steel, and preparation method and application thereof | |
CN111893379A (en) | A 780MPa grade enhanced formability hot-dip galvanized dual-phase steel and its manufacturing method | |
CN115584440A (en) | A kind of 1180MPa grade continuous annealing dual-phase steel with different yield strength ratio and its preparation method | |
CN111926246B (en) | Hot-dip galvanized dual-phase steel with good baking hardening performance and preparation method thereof | |
CN115216708B (en) | A low-cost high yield ratio 1200MPa grade cold-rolled dual-phase steel and its preparation method | |
CN109518080A (en) | Strong dual phase steel of cold rolling low cost superelevation and preparation method thereof | |
CN113215484B (en) | Phase-change induced plasticity steel and preparation method and application thereof | |
CN113025882B (en) | Hot-base galvanized ferrite bainite high-strength steel plate and preparation method thereof | |
CN111647732A (en) | 1300 MPa-grade complex phase steel, preparation method and application thereof | |
CN115505847B (en) | Cold-rolled ultra-high-strength steel plate with excellent impact performance and preparation method thereof | |
CN113025883B (en) | 1000MPa cold-rolled dual-phase steel with excellent local forming performance and preparation method thereof | |
CN113528950B (en) | Preparation method of hot-dip galvanized high-strength steel with good welding performance | |
CN115198174A (en) | A kind of martensitic steel, preparation method and application |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
PB01 | Publication | ||
PB01 | Publication | ||
SE01 | Entry into force of request for substantive examination | ||
SE01 | Entry into force of request for substantive examination | ||
GR01 | Patent grant | ||
GR01 | Patent grant |