Strong dual phase steel of cold rolling low cost superelevation and preparation method thereof
Technical field
The invention belongs to automobile high-strength steel technical fields, and in particular to the strong dual phase steel of cold rolling low cost superelevation and its preparation
Method.
Background technique
With the development of automotive light weight technology technology, automobile steel develops towards high-strength steel direction has become inexorable trend.It is double
Phase steel has the characteristics that low yield strength, high-tensile and excellent plasticity, becomes automobile first choice high-strength steel, and dosage is estimated
It will be more than 70% in the advanced high-strength steel of automobile.With the continuous release of internal vapor sweep production capacity, the competition in high-strength steel market
Also more and more fierce, the dual phase steel of low-cost and high-performance has become the target that each enterprise is pursued, and receives great attention.
Patent document CN 102021483A discloses a kind of tensile strength 1200MPa grades of cold-rolled biphase steels and preparation method,
Its preferred chemical component percentage are as follows: C:0.19~0.21%, Si:0.70~0.90%, Mn:1.90~2.10%, Cr:0.01
~0.02%, Nb:0.02~0.04%, surplus are Fe and inevitable impurity;By 820-860 DEG C of heat preservation, 710 DEG C of slow cooling,
45~55 DEG C/s rapid cooling, 240-320 DEG C of Wetted constructures have obtained the cold-rolled biphase steel that tensile strength is greater than 1200MPa.Although
There is excellent mechanical property by cold-rolled biphase steel prepared by above-mentioned chemical component and production method, but higher C content and
Si content causes welding performance poor, and adding micro Nb leads to high hot rolling load, and it is extensive on automobile to necessarily affect dual phase steel
Using.
Patent document CN 102021482A discloses a kind of cold-rolled galvanized duplex steel and its manufacturing method, chemistry at
Divide percentage are as follows: C:0.095~0.12%, Si:0.80~0.12%, Mn:1.90~2.50%, Cr:0.40~0.60%,
Nb:0.005~0.025%, Mo:0.04~0.30%, surplus are Fe and inevitable impurity;Pass through 760-840 DEG C of heat preservation, 1
~40 DEG C/s rapid cooling, 450-465 DEG C of hot galvanizing have obtained the hot dip galvanized dual phase steel that tensile strength is greater than 1180MPa.Although passing through
This method is prepared for the qualified strong dual phase steel of superelevation, however dual phase steel needs to add the expensive microalloy element such as Nb, Mo, not only makes
Production cost obviously increases, while in the hot rolling, the effects of Nb inhibits austenite recrystallization, so that hot rolling difficulty is obvious
It improves.
Summary of the invention
Present invention solves the technical problem that being that existing 1180MPa grades of cold-rolled biphase steel high production cost, production difficulty are big.
Technical proposal that the invention solves the above-mentioned problems is to provide the strong dual phase steel of cold rolling low cost superelevation, chemical component matter
Measure percentage are as follows: C:0.12~0.17%, Si:0.10~0.60%, Mn:2.00~2.50%, Al:0.01~0.06%, Cr:
0.30~0.80%, V:0.05~0.20%, P≤0.015%, S≤0.005%, N≤0.006%, surplus are Fe and can not keep away
Exempt from impurity.
Preferably, the present invention provides the strong dual phase steel of cold rolling low cost superelevation, chemical component mass percent are as follows: C:0.13
~0.16%, Si:0.30~0.60%, Mn:2.20~2.50%, Al:0.02~0.05%, Cr:0.50~0.80%, V:
0.05~0.10%, P≤0.015%, S≤0.010%, N≤0.005%, surplus are Fe and inevitable impurity.
Wherein, the microstructure of dual phase steel is mainly made of ferrite and martensite.
Wherein, dual phase steel yield strength is 850-950MPa, tensile strength 1200-1300MPa, elongation 5.0-
10.0%.
The present invention also provides the preparation method of the strong dual phase steel of cold rolling low cost superelevation, include the following steps: according to above-mentioned double
Phase steel chemical composition mass percent is smelted, and V content is controlled in converter, slab is cast as after smelting, then hot rolling,
Acid rolls, annealing process, obtains the strong dual phase steel of cold rolling low cost superelevation.
Wherein, hot rolling includes heating, roughing, finish rolling and batches.
Wherein, in course of hot rolling, heating temperature is 1200~1300 DEG C, and finish rolling start rolling temperature is 1000~1100 DEG C, essence
Rolling finishing temperature is 850~950 DEG C, and coiling temperature is 600~700 DEG C.
Wherein, acid rolls for cold rolling after pickling, and cold rolling reduction ratio is 40~60%.
Wherein, annealing temperature is 800~850 DEG C, slowly cools to 700~750 DEG C from annealing temperature, is quickly cooled down immediately
To 200~300 DEG C of overaging temperature, it is finally cooled to room temperature, smooth 0.20~0.50%.
Further, annealing temperature is 800~850 DEG C, is cooled to 700~750 DEG C from 800~850 DEG C with 2~5 DEG C/s,
200~300 DEG C of overaging temperature are cooled to 30~80 DEG C/s immediately, is finally cooled to room temperature, smooth 0.20~0.50%.
Beneficial effects of the present invention:
1, the strong dual phase steel yield strength of cold rolling low cost superelevation provided by the invention is 850-950MPa, and tensile strength is
1200-1300MPa, elongation 5.0-10.0%, microstructure are mainly made of ferrite and martensite, have good power
Learn performance, welding performance and forming property;
2, the strong two-phase of cold rolling low cost superelevation of the present invention is free of expensive Nb, Mo, and smelting process controls V in converter
Content, production cost reduce;
3, the present invention is not added with the microalloy element that Nb etc. improves hot rolling deformation drag, and production difficulty reduces.
Detailed description of the invention
Fig. 1 is the continuous annealing process schematic diagram of cold-rolled biphase steel of the present invention;
Fig. 2 is the microstructure morphology of cold-rolled biphase steel of the present invention.
Specific embodiment
The present invention provides the strong dual phase steel of cold rolling low cost superelevation, chemical component mass percent are as follows: and C:0.12~
0.17%, Si:0.10~0.60%, Mn:2.00~2.50%, Al:0.01~0.06%, Cr:0.30~0.80%, V:0.05
~0.20%, P≤0.015%, S≤0.005%, N≤0.006%, surplus are Fe and inevitable impurity.
Preferably, the present invention provides the strong dual phase steel of cold rolling low cost superelevation, chemical component mass percent are as follows: C:0.13
~0.16%, Si:0.30~0.60%, Mn:2.20~2.50%, Al:0.02~0.05%, Cr:0.50~0.80%, V:
0.05~0.10%, P≤0.015%, S≤0.010%, N≤0.005%, surplus are Fe and inevitable impurity.
C determines the intensity, plasticity and forming property of steel plate as one of most important component of dual phase steel.C is steel material
The most apparent element of solid solution strengthening effect in material, solid solution C content increases by 0.1% in steel, and about 450MPa can be improved in intensity.C contains
When measuring too low, the stability and martensite hardenability of austenite decline, and lead to low strength, are generally not less than in dual phase steel
0.02%;When C content is excessively high, the plasticity and welding performance of dual phase steel decline, and are generally not more than 0.20% in dual phase steel.Therefore,
C content of the present invention be C:0.12~0.17%, preferably 0.13~0.16%.
Si can be solid-solution in the intensity that steel is improved in ferrite and austenite, and effect is only second to C, P, compared with Mn, Cr, Ti and Ni
Equal elements are strong;Si can also inhibit the precipitation of carbide in ferrite, be enriched with solid solution C atom sufficiently into austenite, thus
Improve its stability.However, the scale on surface that Si is formed in heating furnace is difficult to remove when Si too high levels, increase
Dephosphorization difficulty.Therefore, Si content of the present invention is 0.10~0.60%%, preferably 0.30~0.60%.
Mn is common solution strengthening element in good deoxidier and desulfurizing agent and steel, general not low in dual phase steel
In 1.20%.Mn can both form a variety of carbide in conjunction with C and play the role of precipitation strength, and also dissolving in enhances solid solution in matrix
Strengthening effect.Mn easily forms high melting compound MnS in conjunction with S, so that the hot-short phenomenon due to caused by FeS is eliminated or weakens,
Improve the hot-working character of steel.Stabilization of austenite can be improved in Mn, moves to right C curve, to significantly reduce facing for martensite
Boundary's cooling rate.Therefore, Mn content is 2.00~2.50%, preferably 2.20~2.50% in the present invention.
Al is deoxidier common in steel, while can form AlN pinning crystal boundary, to play the role of refining crystal grain;
In addition, Al is similar to Si effect, Carbide Precipitation can be inhibited, to make the sufficiently rich carbon of austenite.Therefore, Al contains in the present invention
Amount is 0.01~0.06%, preferably 0.02~0.05%.
Cr can significantly postpone pearlite and bainite transformation, and austenite is made sufficiently to be changed into martensitic structure, to obtain
Obtain higher tensile strength.Since Cr has apparent cost advantage compared with Mo, so largely making an addition to cold rolling or hot galvanizing two-phase
In steel.Therefore, in the present invention, Cr content is 0.30~0.80%, preferably 0.50~0.80%.
V mainly exists in the form of VC in dual phase steel, has the function of that significant crystal grain refinement and intergranular precipitation are strengthened.In heat
In cooling procedure after rolling, VC provides a large amount of nucleation sites for ferrite crystal grain, so that ferrite crystal grain obviously refines.In cold rolling
During annealing heating, undissolved VC particle can be with pinning ferrite grain boundaries, to play the role of refining crystal grain;Annealing temperature
When increasing to two-phase section, VC solution temperature is lower, therefore is completely dissolved in matrix, while being dissolved C atom and being enriched with into austenite
To improve its stability;In annealing process, the VC in ferrite will be precipitated again, to produce apparent precipitation strength.Cause
This, in the present invention, V content is 0.05~0.20%, preferably 0.05~0.10%.
In the design of chemical component, the present invention uses higher C, Mn, Cr content to guarantee the stability of cold rolling austenite
And harden ability, to obtain the martensite of high-volume fractional;Using trace V come fining ferrite and martensitic crystal grains, while VC
Disperse educt plays the effect of precipitation strength, while resistant to hydrogen can be improved and cause delayed fracture property.
The present invention also provides the preparation method of the strong dual phase steel of cold rolling low cost superelevation, according to above-mentioned two-phase steel chemical composition into
Row smelt, V content is controlled in converter, slab is cast as after smelting, then hot rolling, acid roll, annealing process, it is low to obtain cold rolling
The strong dual phase steel of cost superelevation.
Specifically, it can carry out in accordance with the following steps:
(1) smelting procedure: being smelted according to above-mentioned designed chemical component, and is controlled V content in converter and (passed through
Control V content in original molten iron), then it is cast as slab;
(2) hot-rolled process: obtaining hot rolled coil after heating, dephosphorization, roughing, finish rolling and section cooling for slab, wherein
Heating temperature is 1200~1300 DEG C, and finish rolling start rolling temperature is 1000~1100 DEG C, and finish rolling finishing temperature is 850~950 DEG C, volume
Taking temperature is 600~700 DEG C;
(3) acid rolls process: by above-mentioned hot rolled coil, cold rolling becomes cold-rolled thin steel strip after overpickling, and wherein cold rolling reduction ratio is
40~60%;
(4) by above-mentioned cold-rolled thin steel strip after continuous annealing, required cold-rolled biphase steel steel continuous annealing process: is made
Plate;Wherein annealing temperature be 800~850 DEG C, from annealing temperature with 2~5 DEG C/s slowly cool to rapid cooling start temperature 700~
750 DEG C, it is quickly cooled to 200~300 DEG C of overaging temperature immediately, slow cooling rate CR1 is 2~5 DEG C/s, rapid cooling rate CR2
For 30~80 DEG C/s, it is finally cooled to room temperature, smooth 0.20~0.50%.
The present invention will be further explained by the following examples and explanation.
Embodiment 1 and embodiment 2 respectively according to the method for the present invention be prepared the strong dual phase steel DP1 of cold rolling low cost superelevation and
DP2, the specific steps are as follows:
(1) pass through smelting process, be prepared for the dual phase steel slab of chemical component percentage as shown in table 1 below;
1 two-phase steel chemical composition (wt.%) of table
Number |
C |
Si |
Mn |
P |
S |
Als |
Cr |
V |
N |
DP1 |
0.13 |
0.60 |
2.50 |
0.010 |
0.005 |
0.02 |
0.50 |
0.05 |
0.004 |
DP2 |
0.16 |
0.30 |
2.20 |
0.012 |
0.003 |
0.05 |
0.80 |
0.10 |
0.004 |
(2) slab is obtained into hot rolled coil after heating, dephosphorization, hot rolling and section cooling, wherein finish rolling start rolling temperature is
1000~1100 DEG C, finish rolling finishing temperature is 850~950 DEG C, and coiling temperature is 600~700 DEG C, and specific hot-rolled process parameter is such as
Shown in the following table 2;
2 dual phase steel hot rolling main technologic parameters of table
Number |
Heating temperature/DEG C |
Final rolling temperature/DEG C |
Finishing temperature/DEG C |
Coiling temperature/DEG C |
Hot rolled thickness/mm |
DP1 |
1250 |
1070 |
850~900 |
600~650 |
2.50 |
DP2 |
1250 |
1080 |
900~950 |
650~700 |
3.00 |
(3) by after hot rolled coil pickling, it is cold rolled to Thin Strip Steel, wherein the cold rolling reduction ratio of DP1 and DP2 is respectively 52.0% He
50.0%;
(4) required product is made in cold-rolled thin steel strip after continuous annealing process is handled, wherein annealing temperature be 800~
850 DEG C, 700~750 DEG C of rapid cooling start temperature are slowly cooled to from annealing temperature, is quickly cooled to overaging temperature 200 immediately
~300 DEG C, slow cooling rate CR1 is 2~5 DEG C/s, and rapid cooling rate CR2 is 30~80 DEG C/s, is finally cooled to room temperature, smooth
0.20~0.50%, annealing process schematic diagram is as shown in Figure 1, specific cold rolled annealed technological parameter is as shown in table 3.
The cold rolled annealed main technologic parameters of table 3
Number |
Annealing temperature/DEG C |
Slow cooling temperature/DEG C |
Overaging temperature/DEG C |
Rapid cooling rate/DEG C/s |
DP1 |
800 |
700 |
200 |
57 |
DP2 |
850 |
750 |
300 |
42 |
The cold-rolled biphase steel microstructure that is prepared through above-mentioned technique as shown in Fig. 2, its mechanical property and the prior art pair
Than as shown in table 4 below.
4 present invention of table is compared with existing cold-rolled biphase steel mechanical property
Number |
Yield strength/MPa |
Tensile strength/MPa |
Elongation A80/ % |
Yield tensile ratio |
DP1 |
862 |
1203 |
9.1 |
0.71 |
DP2 |
925 |
1287 |
6.7 |
0.72 |
CN 102021483A |
665 |
1219 |
9.5(A50) |
0.55 |
CN 102021482A |
691 |
1210 |
11.4(A50) |
0.57 |
The result shows that cold-rolled biphase steel microstructure prepared by the present invention is made of tiny ferrite and martensite,
Yield strength (850-950MPa) is lower, and tensile strength (1200-1300MPa) and elongation (5.0-10.0%) are higher.Cold rolling
The inexpensive strong dual phase steel of superelevation so cost advantage is obvious, while having excellent forming without the expensive microalloy element such as Mo, Nb
Performance.