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CN113528950B - Preparation method of hot-dip galvanized high-strength steel with good welding performance - Google Patents

Preparation method of hot-dip galvanized high-strength steel with good welding performance Download PDF

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CN113528950B
CN113528950B CN202110693552.5A CN202110693552A CN113528950B CN 113528950 B CN113528950 B CN 113528950B CN 202110693552 A CN202110693552 A CN 202110693552A CN 113528950 B CN113528950 B CN 113528950B
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hot
dip galvanized
strength steel
rolling
galvanized high
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CN113528950A (en
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刘华赛
王崇学
李维
林志峰
张永强
韩赟
白雪
邱木生
滕华湘
朱国森
李飞
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Shougang Group Co Ltd
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Abstract

本发明实施例公开了一种具有良好焊接性能的热镀锌高强钢及其制备方法,所述方法包括:采用所述的具有良好焊接性能的热镀锌高强钢的化学成分经冶炼和连铸,获得连铸板坯;将所述连铸板坯进行轧前加热或/和粗轧,后精轧、轧后冷却和卷取,获得热轧成品;将所述热轧成品酸洗、冷轧、退火、热镀锌、热处理和光整处理,获得所述具有良好焊接性能的热镀锌高强钢;其中,所述热处理的温度为70~400℃,所述热处理的时间10~60min,所述热处理在质量分数为1~3%氢气的氛围下进行。通过对成分进行调整配合工艺使得热镀锌高强钢中扩散性氢含量≤0.2ppm,从而使得焊接时扩散的氢气不会对材料造成裂纹,进而保证材料焊接性能。

Figure 202110693552

The embodiment of the present invention discloses a hot-dip galvanized high-strength steel with good welding performance and a preparation method thereof. The method includes: smelting and continuous casting using the chemical composition of the hot-dip galvanizing high-strength steel with good welding performance. , to obtain a continuous casting slab; heating the continuous casting slab before rolling or/and rough rolling, finishing rolling, cooling after rolling, and coiling to obtain a hot-rolled product; pickling and cooling the hot-rolled product Rolling, annealing, hot-dip galvanizing, heat treatment and skin-passing treatment to obtain the hot-dip galvanized high-strength steel with good welding performance; wherein, the temperature of the heat treatment is 70-400° C., and the time of the heat-treatment is 10-60 minutes, so that the The heat treatment is carried out in an atmosphere with a mass fraction of 1-3% hydrogen. The content of diffusible hydrogen in the hot-dip galvanized high-strength steel is less than or equal to 0.2ppm by adjusting the composition and the matching process, so that the hydrogen diffused during welding will not cause cracks to the material, thereby ensuring the welding performance of the material.

Figure 202110693552

Description

一种具有良好焊接性能的热镀锌高强钢的制备方法A kind of preparation method of hot-dip galvanized high-strength steel with good welding performance

技术领域technical field

本发明实施例涉及钢材制备技术领域,特别涉及一种具有良好焊接性能的热镀锌高强钢及其制备方法。The embodiments of the present invention relate to the technical field of steel preparation, in particular to a hot-dip galvanized high-strength steel with good welding performance and a preparation method thereof.

背景技术Background technique

近年来,随着汽车行业对碰撞安全性和轻量化要求的提高,高强钢在车身上的应用逐年增加。而随着高强钢不仅用在结构件上,也同时用在车身覆盖件等其他零件上,在具有较高的抗拉强度的基础上还需要具有更好的延展性。In recent years, the application of high-strength steel in the body has been increasing year by year with the increasing requirements for crash safety and lightweight in the automotive industry. As high-strength steel is used not only in structural parts, but also in other parts such as body panels, it needs to have better ductility on the basis of higher tensile strength.

对比文件1:申请号为“201610542806.2”的专利申请公开了一种1000MPa级低碳热镀锌双相钢及其制备方法,属于高强汽车用钢技术领域,重量百分比成分为:C:0.05~0.10%, Si:0.20~0.60%,Mn:1.40~1.90%,Cr:0.20~0.70%,Mo:0.20~0.50%,Al:0.02~ 0.06%,Ti:0.020~0.050%,Nb:0.010~0.040%,B:0.0010~0.0030%,P≤0.015%, S≤0.005%,N≤0.006%,余量为Fe及不可避免杂质。其屈服强度为630~700MPa,抗拉强度为1010~1050MPa,伸长率为11~14%。尽管上述高强度钢通过成分体系及制造工艺,使钢板强度达到1000MPa以上,但同时也带来了一些负面影响。由于在退火过程中,需要使用氢气作为还原性气氛,有一部分氢气会进入到钢铁组织之中,而由于后续镀锌工序,又使得氢气难以从钢板之中释放出来。在后续汽车零件的焊接过程中会由于氢气的释放而产生裂纹,进而影响材料使用性能。Reference document 1: The patent application with the application number "201610542806.2" discloses a 1000MPa grade low-carbon hot-dip galvanized dual-phase steel and a preparation method thereof, belonging to the technical field of high-strength automotive steel, and the weight percentage composition is: C: 0.05-0.10 %, Si: 0.20-0.60%, Mn: 1.40-1.90%, Cr: 0.20-0.70%, Mo: 0.20-0.50%, Al: 0.02-0.06%, Ti: 0.020-0.050%, Nb: 0.010-0.040% , B: 0.0010 ~ 0.0030%, P≤0.015%, S≤0.005%, N≤0.006%, the balance is Fe and inevitable impurities. The yield strength is 630-700MPa, the tensile strength is 1010-1050MPa, and the elongation is 11-14%. Although the above-mentioned high-strength steel can achieve a strength of more than 1000 MPa through the composition system and manufacturing process, it also brings some negative effects. Due to the need to use hydrogen as a reducing atmosphere during the annealing process, a part of the hydrogen will enter the steel structure, and due to the subsequent galvanizing process, it is difficult to release the hydrogen from the steel plate. In the subsequent welding process of automobile parts, cracks will occur due to the release of hydrogen, which will affect the performance of the material.

因此,如何解决现有技术中镀锌高强钢板由于氢气释放而导致的焊接性能劣化问题,成为亟待解决的技术问题。Therefore, how to solve the problem of the deterioration of the welding performance of the galvanized high-strength steel sheet due to the release of hydrogen in the prior art has become an urgent technical problem to be solved.

发明内容SUMMARY OF THE INVENTION

本发明实施例目的是提供一种具有良好焊接性能的热镀锌高强钢及其制备方法,制备得到的额热镀锌高强钢焊接后熔核无裂纹,具有良好的焊接性能。The purpose of the embodiments of the present invention is to provide a hot-dip galvanized high-strength steel with good welding performance and a preparation method thereof. The prepared hot-dip galvanized high-strength steel has no cracks in the nugget after welding and has good welding performance.

为了实现上述目的,本发明实施例提供一种具有良好焊接性能的热镀锌高强钢,所述钢的化学成分以质量分数计为:C:0.10~0.30%,Si:1~2.5%,Mn:1.8~2.3%,P:≤0.01%, S:≤0.01%,Al:0.01~0.5%,N:0.1~0.6%,其余为Fe及不可避免的杂质。In order to achieve the above purpose, the embodiment of the present invention provides a hot-dip galvanized high-strength steel with good welding performance, and the chemical composition of the steel is calculated as: C: 0.10-0.30%, Si: 1-2.5%, Mn in terms of mass fraction. : 1.8-2.3%, P: ≤ 0.01%, S: ≤ 0.01%, Al: 0.01-0.5%, N: 0.1-0.6%, and the rest are Fe and inevitable impurities.

进一步地,所述钢的化学成分以质量分数计为:C:0.10~0.30%,Si:1~2.5%,Mn: 1.8~2.3%,P:≤0.01%,S:≤0.01%,Al:0.01~0.5%,N:0.1~0.6%,合金元素0.005%~0.5%,所述合金元素包括Ti、Nb、V、Zr、Mo、Cr、Cu和Ni中的至少一种,其余为Fe及不可避免的杂质。Further, the chemical composition of the steel in terms of mass fraction is: C: 0.10-0.30%, Si: 1-2.5%, Mn: 1.8-2.3%, P: ≤ 0.01%, S: ≤ 0.01%, Al: 0.01-0.5%, N: 0.1-0.6%, alloying elements 0.005-0.5%, the alloying elements include at least one of Ti, Nb, V, Zr, Mo, Cr, Cu and Ni, and the rest are Fe and inevitable impurities.

进一步地,所述钢基体的金相组织以体积分数计为:10~30%的铁素体、40%~80%的马氏体、≤10%的贝氏体和4~20%的残余奥氏体。Further, the metallographic structure of the steel matrix is calculated by volume fraction: 10-30% ferrite, 40%-80% martensite, ≤10% bainite and 4-20% residual Austenite.

进一步地,所述铁素体的晶粒尺寸为3μm~6μm,所述马氏体的晶粒尺寸为1μm~4μm,所述贝氏体的晶粒尺寸为0.7μm~3.6μm,所述残余奥氏体的晶粒尺寸为0.6μm~ 1.8μm。Further, the grain size of the ferrite is 3 μm to 6 μm, the grain size of the martensite is 1 μm to 4 μm, the grain size of the bainite is 0.7 μm to 3.6 μm, and the residual The grain size of austenite is 0.6 μm to 1.8 μm.

本发明实施例还提供了所述具有良好焊接性能的热镀锌高强钢的制备方法,所述制备方法包括:The embodiment of the present invention also provides a preparation method of the hot-dip galvanized high-strength steel with good welding performance, the preparation method comprising:

采用所述的具有良好焊接性能的热镀锌高强钢的化学成分经冶炼和连铸,获得连铸板坯;Using the chemical composition of the hot-dip galvanized high-strength steel with good weldability, through smelting and continuous casting, continuous casting slabs are obtained;

将所述连铸板坯进行轧前加热或/和粗轧,后精轧、轧后冷却和卷取,获得热轧成品;The continuous casting slab is heated or/and rough rolled before rolling, followed by finish rolling, cooled after rolling and coiled to obtain a hot rolled product;

将所述热轧成品酸洗、冷轧、退火、热镀锌、热处理和光整处理,获得所述具有良好焊接性能的热镀锌高强钢;其中,所述热处理的温度为70~400℃,所述热处理的时间为 10~60min,所述热处理在质量分数为1~3%氢气的氛围下进行。The hot-rolled finished product is pickled, cold-rolled, annealed, hot-dip galvanized, heat-treated and smoothed to obtain the hot-dip galvanized high-strength steel with good welding performance; wherein, the heat treatment temperature is 70-400° C., The time of the heat treatment is 10-60 minutes, and the heat treatment is performed in an atmosphere with a mass fraction of 1-3% hydrogen.

进一步地,所述轧前加热的温度1100~1300℃,所述轧前加热的时间≥180min。Further, the temperature of the heating before rolling is 1100-1300° C., and the heating time before rolling is ≥180 min.

进一步地,所述精轧的出口温度为800~950℃。Further, the outlet temperature of the finishing rolling is 800-950°C.

进一步地,所述卷取的温度为450~700℃。Further, the temperature of the coiling is 450-700°C.

进一步地,所述冷轧压下率为20%~50%。Further, the cold rolling reduction ratio is 20% to 50%.

进一步地,所述退火依次包括加热段、冷却段和时效段,其中,所述加热段为在820~ 900℃下保温5~25s;所述冷却段为由820~900℃以4℃/s~10℃/s速率冷却至400~550℃;所述时效段为400~550℃下保温≥8s;所述退火在质量分数为2%~10%氢气的氛围下进行。Further, the annealing includes a heating section, a cooling section and an aging section in sequence, wherein, the heating section is kept at 820-900°C for 5-25s; Cool to 400-550°C at a rate of ~10°C/s; the aging section is kept at 400-550°C for ≥8s; the annealing is performed in an atmosphere with a mass fraction of 2%-10% hydrogen.

本发明实施例中的一个或多个技术方案,至少具有如下技术效果或优点:One or more technical solutions in the embodiments of the present invention have at least the following technical effects or advantages:

本发明实施例提供的一种具有良好焊接性能的热镀锌高强钢,所述钢的化学成分以质量分数计为:C:0.10~0.30%,Si:1~2.5%,Mn:1.8~2.3%,P:≤0.01%,S:≤0.01%, Al:0.01~0.5%,N:0.1~0.6%,其余为Fe及不可避免的杂质;本发明实施例通过对成分进行调整使得热镀锌高强钢中扩散性氢含量≤0.2ppm。在扩散氢含量≤0.2ppm的情况下,焊接时扩散的氢气不会对材料造成裂纹,进而保证材料焊接性能。The embodiment of the present invention provides a hot-dip galvanized high-strength steel with good welding performance. The chemical composition of the steel is calculated as: C: 0.10-0.30%, Si: 1-2.5%, Mn: 1.8-2.3 %, P: ≤ 0.01%, S: ≤ 0.01%, Al: 0.01-0.5%, N: 0.1-0.6%, and the rest are Fe and inevitable impurities; The diffusible hydrogen content in high strength steel is less than or equal to 0.2ppm. When the diffusible hydrogen content is less than or equal to 0.2ppm, the hydrogen diffused during welding will not cause cracks to the material, thereby ensuring the welding performance of the material.

附图说明Description of drawings

为了更清楚地说明本发明实施例中的技术方案,下面将对实施例描述中所需要使用的附图作一简单地介绍,显而易见地,下面描述中的附图是本发明实施例的一些实施例,对于本领域普通技术人员来讲,在不付出创造性劳动的前提下,还可以根据这些附图获得其它的附图。In order to illustrate the technical solutions in the embodiments of the present invention more clearly, the following briefly introduces the accompanying drawings that need to be used in the description of the embodiments. Obviously, the drawings in the following description are some implementations of the embodiments of the present invention. For example, for those of ordinary skill in the art, other drawings can also be obtained from these drawings without any creative effort.

图1为本发明实施例1制备得到的具有良好焊接性能的热镀锌高强钢的金相组织图;Fig. 1 is the metallographic structure diagram of the hot-dip galvanized high-strength steel with good weldability prepared in Example 1 of the present invention;

图2为本发明实施例1制备得到的具有良好焊接性能的热镀锌高强钢焊接后无裂纹的图片;2 is a picture of no cracks after welding of the hot-dip galvanized high-strength steel with good weldability prepared in Example 1 of the present invention;

图3为对比例1制备得到的热镀锌高强钢焊接后有裂纹的图片;Figure 3 is a picture of cracks after welding of the hot-dip galvanized high-strength steel prepared in Comparative Example 1;

图4为本发明实施例提供的一种具有良好焊接性能的热镀锌高强钢的制备方法的流程图。FIG. 4 is a flow chart of a method for preparing a hot-dip galvanized high-strength steel with good weldability provided by an embodiment of the present invention.

具体实施方式Detailed ways

下文将结合具体实施方式和实施例,具体阐述本发明实施例,本发明实施例的优点和各种效果将由此更加清楚地呈现。本领域技术人员应理解,这些具体实施方式和实施例是用于说明本发明实施例,而非限制本发明实施例。Hereinafter, the embodiments of the present invention will be described in detail with reference to specific implementation manners and examples, and the advantages and various effects of the embodiments of the present invention will be more clearly presented thereby. Those skilled in the art should understand that these specific implementation manners and examples are used to illustrate the embodiments of the present invention, but not to limit the embodiments of the present invention.

在整个说明书中,除非另有特别说明,本文使用的术语应理解为如本领域中通常所使用的含义。因此,除非另有定义,本文使用的所有技术和科学术语具有与本发明实施例所属领域技术人员的一般理解相同的含义。若存在矛盾,本说明书优先。Throughout the specification, unless specifically stated otherwise, terms used herein are to be understood as commonly used in the art. Therefore, unless otherwise defined, all technical and scientific terms used herein have the same meaning as commonly understood by one of ordinary skill in the art to which the embodiments of this invention belong. In case of conflict, the present specification takes precedence.

除非另有特别说明,本发明实施例中用到的各种原材料、试剂、仪器和设备等,均可通过市场购买获得或者可通过现有方法获得。Unless otherwise specified, various raw materials, reagents, instruments and equipment, etc. used in the embodiments of the present invention can be purchased from the market or can be obtained by existing methods.

本申请实施例的技术方案为解决上述技术问题,总体思路如下:The technical solutions of the embodiments of the present application are to solve the above-mentioned technical problems, and the general idea is as follows:

根据本发明实施例一种典型的实施方式,提供一种具有良好焊接性能的热镀锌高强钢,所述钢的化学成分以质量分数计为:C:0.10~0.30%,Si:1~2.5%,Mn:1.8~2.3%,P:≤0.01%,S:≤0.01%,Al:0.01~0.5%,N:0.1~0.6%,其余为Fe及不可避免的杂质。According to a typical embodiment of the embodiment of the present invention, a hot-dip galvanized high-strength steel with good welding performance is provided, and the chemical composition of the steel is calculated as: C: 0.10-0.30%, Si: 1-2.5 %, Mn: 1.8-2.3%, P: ≤ 0.01%, S: ≤ 0.01%, Al: 0.01-0.5%, N: 0.1-0.6%, and the rest are Fe and inevitable impurities.

本申请通过优化组成元素进而形成以上化学成分的具有良好焊接性能的热镀锌高强钢,是基于以下原理:The present application forms a hot-dip galvanized high-strength steel with good weldability of the above chemical composition by optimizing the composition elements, based on the following principles:

(1)在本发明实施例化学成分设计中控制原理如下:(1) the control principle is as follows in the chemical composition design of the embodiment of the present invention:

C元素是双相钢中最重要的固溶强化元素及奥氏体稳定化元素,通过调节C元素含量,使钢铁材料在冷却过程中获得足够的马氏体量以保证强度,并获得一定量的残余奥氏体量以提升成形性能。C element is the most important solid solution strengthening element and austenite stabilizing element in dual-phase steel. By adjusting the content of C element, the steel material can obtain sufficient martensite content during the cooling process to ensure the strength and obtain a certain amount of retained austenite to improve formability.

Si元素也是一种强化元素,有助于扩大两相区,溶解于铁素体起到强化效果,同时Si 可以有效抑制残余奥氏体分解及碳化物析出。但Si元素过多会对焊接性能及表面质量带来不利影响,因此本发明将Si含量控制在1-2.5%。Si element is also a strengthening element, which helps to expand the two-phase region and dissolves in ferrite for strengthening effect. At the same time, Si can effectively inhibit the decomposition of retained austenite and the precipitation of carbides. However, too much Si element will adversely affect the welding performance and surface quality, so the present invention controls the Si content to 1-2.5%.

Mn元素也是固溶强化、稳定奥氏体的重要元素,Mn元素能够阻止在冷却过程中奥氏体向珠光体的转变,进而提高材料的淬透性,保证参与奥氏体的问题性。而Mn元素过高的话则会对材料的加工性能产生负面影响,因此本发明Mn含量控制在1.8-2.3%。Mn element is also an important element for solid solution strengthening and stabilizing austenite. Mn element can prevent the transformation of austenite to pearlite during the cooling process, thereby improving the hardenability of the material and ensuring the problem of participating in austenite. However, if the Mn element is too high, it will have a negative impact on the processability of the material, so the Mn content in the present invention is controlled at 1.8-2.3%.

P元素为材料有害元素,在晶界偏聚将会导致晶界强度下降从而恶化材料机械性能,因此本发明P元素含量控制在0.01%以下。The P element is a harmful element of the material, and segregation at the grain boundary will cause the grain boundary strength to decrease and deteriorate the mechanical properties of the material. Therefore, the content of the P element in the present invention is controlled below 0.01%.

S元素同样作为有害元素,在材料中含量过高会导致与Mn结合产生MnS从而影响材料的扩孔及耐蚀性能。因此本发明S元素含量控制在0.01%以下。S element is also a harmful element, and if the content is too high in the material, it will combine with Mn to produce MnS, which will affect the hole expansion and corrosion resistance of the material. Therefore, the content of S element in the present invention is controlled below 0.01%.

Al元素可以促进铁素体的生成,同时有效抑制残余奥氏体分解及碳化物析出,但Al 元素含量过高在会导致生产过程中产生非金属夹杂物等问题,因此Al含量需要与作用类似的Si元素协同控制在一个合适的范围。本发明的Al含量需要控制在0.01-0.5%。Al element can promote the formation of ferrite, and at the same time effectively inhibit the decomposition of retained austenite and carbide precipitation, but too high content of Al element will cause problems such as non-metallic inclusions in the production process, so the content of Al needs to be similar to the effect The Si element is synergistically controlled within a suitable range. The Al content of the present invention needs to be controlled at 0.01-0.5%.

N元素可以与固溶铝相结合,形成AlN,并阻止材料在加热时奥氏体晶粒长大,从而获得本质细晶粒钢。考虑到N含量过多会导致时效现象,因此本发明将N含量控制在0.1-0.6%。N element can combine with solid solution aluminum to form AlN and prevent the growth of austenite grains when the material is heated, resulting in an intrinsically fine-grained steel. Considering that too much N content will lead to aging phenomenon, the present invention controls the N content to 0.1-0.6%.

作为一种可选的实施方式,所述钢还包括合金元素0.005%~0.5%,所述合金元素包括 Ti、Nb、V、Zr、Mo、Cr、Cu和Ni中的至少一种;As an optional embodiment, the steel further includes 0.005% to 0.5% of alloy elements, and the alloy elements include at least one of Ti, Nb, V, Zr, Mo, Cr, Cu and Ni;

Ti、Nb、V、Zr、Mo、Cr、Cu、Ni等合金元素可以提高奥氏体淬透性,从而获得足够量的马氏体保证强度,如Ti元素作为微合金元素,可以与C结合生成TiC纳米析出相,起到细化晶粒及析出强化的作用,对改善组织形态、提高屈服强度有着显著的作用。但同时合金元素含量过多,不利于残余奥氏体的生成,并且会导致成本明显上升,因此将合金元素含量控制在0.005%~0.5%。Ti, Nb, V, Zr, Mo, Cr, Cu, Ni and other alloying elements can improve the hardenability of austenite, so as to obtain a sufficient amount of martensite to ensure the strength. For example, as a microalloying element, Ti can be combined with C The formation of TiC nano-precipitation phase plays the role of grain refinement and precipitation strengthening, and has a significant effect on improving the structure and improving the yield strength. But at the same time, the content of alloying elements is too much, which is not conducive to the formation of retained austenite, and will lead to a significant increase in cost, so the content of alloying elements is controlled at 0.005% to 0.5%.

作为一种可选的实施方式,所述钢基体的金相组织以体积分数计为:10~30%的铁素体、 40%~80%的马氏体、≤10%的贝氏体和4~20%的残余奥氏体。所述铁素体的晶粒尺寸为3 μm~6μm,所述马氏体的晶粒尺寸为1μm~4μm,所述贝氏体的晶粒尺寸为0.7μm~ 3.6μm,所述残余奥氏体的晶粒尺寸为0.6μm~1.8μm。As an optional embodiment, the metallographic structure of the steel matrix, in terms of volume fraction, is: 10-30% ferrite, 40-80% martensite, ≤10% bainite and 4 to 20% retained austenite. The grain size of the ferrite is 3 μm to 6 μm, the grain size of the martensite is 1 μm to 4 μm, the grain size of the bainite is 0.7 μm to 3.6 μm, and the retained austenite has a grain size of 0.7 μm to 3.6 μm. The grain size of the bulk is 0.6 μm to 1.8 μm.

本发明实施例进一步通过显微组织的精准控制获得性能的进一步改良:马氏体为材料提供足够的强度,但是马氏体过高则会导致材料成形能力的明显下降,因此将马氏体含量设定为40~80%。铁素体是材料的软基体,在塑性变形过程中,通过得到适量的铁素体使其周围出现额外变形确保几何兼容性。残余奥氏体能够增强材料的成形能力,但残余奥氏体<4%时,由于变形时的相变诱导塑性效应导致无法明显提高延伸率,而如果含量过高则必须大幅增加合金含量,造成成本升高,并且造成成形能力的浪费。The embodiment of the present invention further improves the performance through precise control of the microstructure: martensite provides sufficient strength for the material, but if the martensite is too high, the forming ability of the material will be significantly reduced, so the martensite content Set to 40 to 80%. Ferrite is the soft matrix of the material, and during plastic deformation, geometric compatibility is ensured by getting the right amount of ferrite around it and having additional deformation around it. The retained austenite can enhance the forming ability of the material, but when the retained austenite is less than 4%, the elongation cannot be significantly improved due to the transformation-induced plasticity effect during deformation, and if the content is too high, the alloy content must be greatly increased, resulting in Costs rise and formability is wasted.

根据本发明实施例另一种典型的实施方式,提供了所述具有良好焊接性能的热镀锌高强钢的制备方法,如图4所示,所述制备方法包括:According to another typical embodiment of the embodiment of the present invention, a preparation method of the hot-dip galvanized high-strength steel with good welding performance is provided, as shown in FIG. 4 , the preparation method includes:

S1、采用所述的具有良好焊接性能的热镀锌高强钢的化学成分经冶炼和连铸,获得连铸板坯;S1, adopt the chemical composition of described hot-dip galvanized high-strength steel with good weldability to obtain continuous casting slab through smelting and continuous casting;

S2、将所述连铸板坯进行轧前加热或/和粗轧,后精轧、轧后冷却和卷取,获得热轧成品;S2, heating the continuous casting slab before rolling or/and rough rolling, finishing rolling, cooling and coiling after rolling, to obtain a hot-rolled product;

所述连铸板坯可以加热后进行粗轧,也可以是所示连铸板坯直接进行粗轧;The continuous casting slab can be subjected to rough rolling after heating, or the continuous casting slab can be directly subjected to rough rolling;

所述轧前加热的温度1100~1300℃,所述轧前加热的时间≥180min。选择所述的加热温度1100~1300℃主要是防止钢坯析出物的粗大,对后续组织生成产生不利影响。若所述加热温度过高或过低均容易对组织造成不利影响;The heating temperature before rolling is 1100-1300° C., and the heating time before rolling is ≥180 min. The above-mentioned heating temperature of 1100-1300° C. is selected mainly to prevent the thickening of the precipitation of the billet, which has an adverse effect on the subsequent structure formation. If the heating temperature is too high or too low, it will easily cause adverse effects on the tissue;

所述精轧的出口温度为800~950℃。选择所述的精轧温度能够使材料组织更加均匀,保证性能。若所述精轧的出口温度过高或过低均容易对组织均匀性造成不利影响;The outlet temperature of the finish rolling is 800-950°C. Selecting the finishing rolling temperature can make the material structure more uniform and ensure the performance. If the outlet temperature of the finishing rolling is too high or too low, it is easy to adversely affect the uniformity of the structure;

所述卷取的温度为450~700℃。选择所述卷取温度是为了保证组织均匀性,使最终性能符合要求。若所述卷取温度过高或过低均容易对组织均匀性造成不利影响;The temperature of the coiling is 450 to 700°C. The coiling temperature is chosen to ensure uniformity of the tissue and final properties to meet requirements. If the coiling temperature is too high or too low, it will easily cause adverse effects on the uniformity of the tissue;

S3、将所述热轧成品酸洗、冷轧、退火、热镀锌、热处理和光整处理,获得所述具有良好焊接性能的热镀锌高强钢;其中,所述热处理的温度为70~400℃,所述热处理的时间为10-60min,所述热处理在质量分数为1~3%氢气的氛围下进行。S3, subjecting the hot-rolled finished product to pickling, cold-rolling, annealing, hot-dip galvanizing, heat treatment and skin-passing to obtain the hot-dip galvanized high-strength steel with good welding performance; wherein, the temperature of the heat treatment is 70-400 °C ℃, the time of the heat treatment is 10-60 min, and the heat treatment is performed in an atmosphere with a mass fraction of 1-3% hydrogen.

所述冷轧压下率控制在20~50%。这一限定为保证得到均匀的钢铁组织,并保证表面结构的完好。所述冷轧压下率若低于20%或高于50%均容易对组织均匀性造成不利影响;The cold rolling reduction ratio is controlled at 20-50%. This limit is to ensure a uniform steel structure and to ensure the integrity of the surface structure. If the cold rolling reduction ratio is lower than 20% or higher than 50%, it will easily cause adverse effects on the uniformity of the structure;

所述冷轧之后的退火工序主要为加热段、冷却段、时效段。其中加热段温度为820~ 900℃,加热时间为5~25s,时效段为400~550℃,时效段时间≥8s。退火炉中的氢含量为 2%~10%。选择加热段温度为820~900℃,加热时间为5~25s可以使钢铁组织更加均匀,确保生成必要的马氏体、残余奥氏体、贝氏体。经过冷却段后,在时效段为400~550℃,时效段时间≥8s的条件下,生成贝氏体和残余奥氏体,同时去除部分钢中的氢。从制造成本的角度考虑,时效段时间不宜过长,但延长时效段时间不会对组织产生影响。退火炉中的氢气含量限定为2~10%。将氢气氛围设定在超过2%主要考虑所需的还原性气氛,而将氢气控制在10%以下可以防止过剩的氢进入钢铁材料中,保证后续过程中氢气的残留含量可以控制在一个较低的水平。The annealing process after the cold rolling mainly includes a heating section, a cooling section and an aging section. The temperature of the heating section is 820-900℃, the heating time is 5-25s, the aging section is 400-550℃, and the aging section time is ≥8s. The hydrogen content in the annealing furnace is 2% to 10%. Selecting the heating section temperature of 820-900°C and the heating time of 5-25s can make the steel structure more uniform and ensure the formation of necessary martensite, retained austenite and bainite. After the cooling section, bainite and retained austenite are formed under the condition that the aging section is 400-550 °C and the aging section time is ≥8s, and the hydrogen in part of the steel is removed at the same time. From the perspective of manufacturing cost, the aging period should not be too long, but extending the aging period will not affect the organization. The hydrogen content in the annealing furnace is limited to 2 to 10%. Setting the hydrogen atmosphere above 2% mainly considers the required reducing atmosphere, while controlling the hydrogen below 10% can prevent excess hydrogen from entering the steel material, and ensure that the residual hydrogen content in the subsequent process can be controlled at a lower level. s level.

所述热镀锌工序中,入锌锅前温度限定在400~550℃,选择低于550℃可以确保保留残余奥氏体,同时选择超过400℃可以避免入锌锅温度过低导致锌液提前凝固。若高于550℃难以保留残余奥氏体,若低于400℃容易导致锌液提前凝固。In the hot-dip galvanizing process, the temperature before entering the zinc pot is limited to 400-550°C, and the temperature below 550°C can ensure the retention of retained austenite, and at the same time, selecting more than 400°C can avoid the temperature of the zinc pot being too low and causing the zinc liquid to advance in advance. solidification. If it is higher than 550 ℃, it is difficult to retain retained austenite, and if it is lower than 400 ℃, it is easy to cause the zinc liquid to solidify in advance.

所述热处理的温度为70~400℃,时间为10~60min,热处理炉中氢气含量为1~3%。所述氢气含量在确保还原性气氛的条件下,能够抑制钢中氢的增加,并在所述的热处理温度下,使钢中在前工序进入的氢缓慢释放。若氢气含量低于1%,无法提供足够的还原性气氛,影响表明质量;若氢气含量高于3%,则由于外界氢含量过高,内部氢无法充分释放;The temperature of the heat treatment is 70-400 DEG C, the time is 10-60 min, and the hydrogen content in the heat-treatment furnace is 1-3%. The hydrogen content can suppress the increase of hydrogen in the steel under the condition that the reducing atmosphere is ensured, and at the heat treatment temperature, the hydrogen entered in the steel in the previous process can be slowly released. If the hydrogen content is less than 1%, a sufficient reducing atmosphere cannot be provided, which affects the quality of the indicator; if the hydrogen content is higher than 3%, the internal hydrogen cannot be fully released due to the high external hydrogen content;

所限定的热处理温度和时间可以保证氢的释放时间,并在最多1h左右的时间达到氢进入与渗出的平衡。若热处理的温度小于70℃,时间小于10min不利于氢气的扩散;若热处理的温度大于400℃,时间大于60min扩散的氢气容易对材料造成裂纹;The limited heat treatment temperature and time can ensure the release time of hydrogen, and the equilibrium of hydrogen entry and permeation can be reached in about 1h at most. If the heat treatment temperature is less than 70°C and the time is less than 10min, it is not conducive to the diffusion of hydrogen; if the heat treatment temperature is greater than 400°C, the hydrogen diffused for more than 60min will easily cause cracks to the material;

综上可知,本发明实施例制备得到的一种具有良好焊接性能的热镀锌高强钢,通过成分和工艺的调整,使热镀锌高强钢中扩散性氢含量≤0.2ppm。在扩散氢含量≤0.2ppm的情况下,焊接时扩散的氢气不会对材料造成裂纹,进而保证材料焊接性能;制备得到的具有良好焊接性能的热镀锌高强钢,力学性能参数指标为:抗拉强度大于980MPa,屈服强度大于700MPa,标距在80mm的延伸率≥12%。To sum up, the hot-dip galvanized high-strength steel with good welding performance prepared in the embodiment of the present invention is adjusted to make the diffusible hydrogen content in the hot-dip galvanized high-strength steel ≤ 0.2 ppm by adjusting the composition and process. When the diffusible hydrogen content is less than or equal to 0.2ppm, the hydrogen diffused during welding will not cause cracks to the material, thereby ensuring the welding performance of the material; the prepared hot-dip galvanized high-strength steel with good welding performance has mechanical performance parameters as follows: The tensile strength is greater than 980MPa, the yield strength is greater than 700MPa, and the elongation with a gauge length of 80mm is greater than or equal to 12%.

下面将结合实施例、对比例及实验数据对本申请的一种具有良好焊接性能的热镀锌高强钢及其制备方法进行详细说明。A hot-dip galvanized high-strength steel with good welding performance and a preparation method thereof of the present application will be described in detail below with reference to the embodiments, comparative examples and experimental data.

S1、将钢水经过转炉冶炼,采用连铸方式获得连铸板坯;实际化学成分如表1所示;S1. The molten steel is smelted in a converter, and the continuous casting slab is obtained by continuous casting; the actual chemical composition is shown in Table 1;

表1-各组别的热镀锌高强钢化学成分(wt%)Table 1 - Chemical composition of hot-dip galvanized high-strength steel for each group (wt%)

成分Element CC SiSi MnMn PP SS AlAl NN NbNb CrCr MoMo TiTi 实施例1Example 1 0.170.17 1.661.66 2.062.06 0.0050.005 0.0020.002 0.430.43 0.15 -- -- -- -- 实施例2Example 2 0.180.18 1.331.33 2.112.11 0.0050.005 0.0020.002 0.250.25 0.180.18 -- -- -- -- 实施例3Example 3 0.190.19 1.571.57 2.022.02 0.0070.007 0.0030.003 0.340.34 0.320.32 0.0310.031 -- -- -- 实施例4Example 4 0.210.21 1.611.61 2.142.14 0.0060.006 0.0030.003 0.270.27 0.15 -- 0.210.21 -- -- 实施例5Example 5 0.190.19 1.671.67 2.042.04 0.0050.005 0.0020.002 0.440.44 0.540.54 -- -- 0.110.11 -- 实施例6Example 6 0.220.22 2.232.23 1.871.87 0.0070.007 0.0020.002 0.340.34 0.130.13 -- -- -- 0.0310.031 实施例7Example 7 0.15 1.511.51 2.222.22 0.0090.009 0.0040.004 0.260.26 0.240.24 0.0310.031 0.270.27 0.15 0.0310.031 对比例1Comparative Example 1 0.170.17 1.661.66 2.062.06 0.0050.005 0.0020.002 0.430.43 0.15 -- -- -- -- 对比例2Comparative Example 2 0.170.17 1.661.66 2.062.06 0.0050.005 0.0020.002 0.430.43 0.15 -- -- -- -- 对比例3Comparative Example 3 0.080.08 0.20.2 2.32.3 0.0050.005 0.0050.005 0.60.6 -- -- 0.70.7 0.30.3 0.040.04 对比例4Comparative Example 4 0.0850.085 0.00.0 1.71.7 0.0120.012 0.0020.002 0.040.04 0.0040.004 0.020.02 0.420.42 0.350.35 0.03 0.03

S2、经过常规工艺得到铸坯后进行热轧,也可以采用铸坯直接热轧的方法,热轧加热温度限定为1100~1300℃,精轧温度限定为为800~950℃,卷取温度限定为450~700℃。热轧卷经过常规酸洗程序之后,进行冷轧,所述冷轧工序压下率控制在20~50%。冷轧之后的退火工序主要为加热段、冷却段、时效段。其中加热段温度为820~900℃,加热时间为5~25s,时效段为400~550℃,时效段时间≥8s。退火炉中的氢含量为2%-10%。退火后的钢板进入热镀锌工序,入锌锅前温度限定在400~550℃。镀锌冷却后进行后续热处理,所述热处理温度为70~400℃,时间为10分钟~1小时,热处理炉中氢气含量为1~3%。具体如表2所示。S2. After the casting billet is obtained by conventional technology, hot rolling is carried out. The method of direct hot rolling of the casting billet can also be used. It is 450~700 ℃. After the hot-rolled coil is subjected to a conventional pickling procedure, cold rolling is performed, and the reduction ratio of the cold rolling procedure is controlled at 20-50%. The annealing process after cold rolling is mainly a heating section, a cooling section, and an aging section. The heating section temperature is 820-900°C, the heating time is 5-25s, the aging section is 400-550°C, and the aging section time is ≥8s. The hydrogen content in the annealing furnace is 2%-10%. The annealed steel sheet enters the hot-dip galvanizing process, and the temperature before entering the zinc pot is limited to 400-550 °C. After the galvanizing is cooled, subsequent heat treatment is performed, the heat treatment temperature is 70-400° C., the time is 10 minutes-1 hour, and the hydrogen content in the heat treatment furnace is 1-3%. The details are shown in Table 2.

表2-工艺参数Table 2 - Process Parameters

Figure BDA0003127165300000071
Figure BDA0003127165300000071

对成品取样进行力学性能测试。对钢板样品经去除表面锌层后进行评价。其中表面氢含量通过在石英管中使用氩气进行置换,并通过气相色谱仪测定氢气释放量。焊接性能的评价方法为使用直流电阻点焊机对两片钢板进行连接,通过控制电流强度的方法使熔核直径达到4mm左右。焊接材料放置24小时之后,通过SEM观察熔核断面是否有裂纹。结果见表3。The finished product samples were tested for mechanical properties. The steel samples were evaluated after the surface zinc layer was removed. The surface hydrogen content was replaced by using argon gas in a quartz tube, and the amount of hydrogen released was determined by a gas chromatograph. The evaluation method of welding performance is to use a DC resistance spot welder to connect two steel plates, and control the current intensity to make the nugget diameter reach about 4 mm. After the welding material was placed for 24 hours, the nugget cross-section was observed for cracks by SEM. The results are shown in Table 3.

表3具有良好焊接性能的热镀锌高强钢力学及焊接性能Table 3 Mechanical and welding properties of hot-dip galvanized high-strength steel with good welding properties

Figure BDA0003127165300000072
Figure BDA0003127165300000072

Figure BDA0003127165300000081
Figure BDA0003127165300000081

由表3数据可知:It can be seen from the data in Table 3 that:

对比例1中,热处理段氢气含量为0,小于本发明实施例1~3%的范围,存在表面质量较差缺点;In Comparative Example 1, the hydrogen content in the heat treatment section is 0, which is less than the range of 1 to 3% in the embodiment of the present invention, and has the disadvantage of poor surface quality;

对比例2中,热处理的温度为50℃,小于本发明实施例70~400℃的范围,但由于温度较低,无法实现氢释放;In Comparative Example 2, the temperature of the heat treatment is 50°C, which is lower than the range of 70 to 400°C in the embodiment of the present invention, but due to the low temperature, hydrogen release cannot be achieved;

对比例3中,化学成分与实施例1不同,且不进行镀锌后热处理步骤,抗拉强度偏低,且焊接后熔核有裂纹;In Comparative Example 3, the chemical composition is different from that of Example 1, and the post-galvanizing heat treatment step is not performed, the tensile strength is low, and the nugget has cracks after welding;

对比例4中,化学成分与实施例1不同,且不进行镀锌后热处理步骤,抗拉强度偏低,且焊接后熔核有裂纹;In Comparative Example 4, the chemical composition is different from that of Example 1, and the post-galvanizing heat treatment step is not performed, the tensile strength is low, and the nugget has cracks after welding;

实施例1-6中热镀锌高强钢板,屈服强度达到700MPa以上,抗拉强度达到980MPa以上,延伸率超过12%。同时钢板扩散氢含量较低,焊接后熔核无裂纹,能够同时具有良好的机械性能和焊接性能。The hot-dip galvanized high-strength steel sheet in Examples 1-6 has a yield strength of over 700 MPa, a tensile strength of over 980 MPa, and an elongation of over 12%. At the same time, the diffusible hydrogen content of the steel plate is low, and the nugget has no cracks after welding, which can have good mechanical properties and welding performance at the same time.

附图1-3的详细说明:Detailed description of Figures 1-3:

图1中本发明实施例1制备得到的具有良好焊接性能的热镀锌高强钢的金相组织包含铁素体10-30%、马氏体40%-80%、贝氏体≤10%、残余奥氏体4-20%。In Fig. 1, the metallographic structure of the hot-dip galvanized high-strength steel with good weldability prepared in Example 1 of the present invention includes 10-30% ferrite, 40%-80% martensite, bainite≤10%, Retained austenite 4-20%.

图2中实施例1中热镀锌高强钢焊接后熔核断面无裂纹;There is no crack in the nugget section after welding of hot-dip galvanized high-strength steel in Example 1 in Fig. 2;

图3中对比例1中热镀锌高强钢焊接后熔核断面有裂纹;In Fig. 3, there are cracks in the nugget section of the hot-dip galvanized high-strength steel in Comparative Example 1 after welding;

最后,还需要说明的是,术语“包括”、“包含”或者其任何其他变体意在涵盖非排他性的包含,从而使得包括一系列要素的过程、方法、物品或者设备不仅包括那些要素,而且还包括没有明确列出的其他要素,或者是还包括为这种过程、方法、物品或者设备所固有的要素。Finally, it should also be noted that the terms "comprising", "comprising" or any other variation thereof are intended to encompass a non-exclusive inclusion such that a process, method, article or device comprising a series of elements includes not only those elements, but also Also included are other elements not expressly listed or inherent to such a process, method, article or apparatus.

尽管已描述了本发明实施例的优选实施例,但本领域内的技术人员一旦得知了基本创造性概念,则可对这些实施例作出另外的变更和修改。所以,所附权利要求意欲解释为包括优选实施例以及落入本发明实施例范围的所有变更和修改。While preferred embodiments of the embodiments of the present invention have been described, additional changes and modifications to these embodiments may occur to those skilled in the art once the basic inventive concepts are known. Therefore, the appended claims are intended to be construed to include the preferred embodiments as well as all changes and modifications that fall within the scope of the embodiments of the present invention.

显然,本领域的技术人员可以对本发明实施例进行各种改动和变型而不脱离本发明实施例的精神和范围。这样,倘若本发明实施例的这些修改和变型属于本发明实施例权利要求及其等同技术的范围之内,则本发明实施例也意图包含这些改动和变型在内。Obviously, those skilled in the art can make various changes and modifications to the embodiments of the present invention without departing from the spirit and scope of the embodiments of the present invention. Thus, if these modifications and variations of the embodiments of the present invention fall within the scope of the claims of the embodiments of the present invention and their equivalents, the embodiments of the present invention are also intended to include these modifications and variations.

Claims (4)

1.一种具有良好焊接性能的热镀锌高强钢的制备方法,其特征在于,所述制备方法包括:1. a preparation method of hot-dip galvanized high-strength steel with good weldability, is characterized in that, described preparation method comprises: 采用具有良好焊接性能的热镀锌高强钢的化学成分经冶炼和连铸,获得连铸板坯,所述化学成分以质量分数计为:C:0.10~0.30%,Si:1~2.5%,Mn:1.8~2.3%,P:≤0.01%,S:≤0.01%,Al:0.01~0.5%,N:0.1~0.6%,其余为Fe及不可避免的杂质;The chemical composition of hot-dip galvanized high-strength steel with good welding performance is used for smelting and continuous casting to obtain continuous casting slab. Mn: 1.8~2.3%, P: ≤0.01%, S: ≤0.01%, Al: 0.01~0.5%, N: 0.1~0.6%, the rest are Fe and inevitable impurities; 将所述连铸板坯进行轧前加热或/和粗轧,后精轧、轧后冷却和卷取,获得热轧成品;The continuous casting slab is heated or/and rough rolled before rolling, followed by finish rolling, cooled after rolling and coiled to obtain a hot rolled product; 将所述热轧成品酸洗、冷轧、退火、热镀锌、热处理和光整处理,获得所述具有良好焊接性能的热镀锌高强钢;其中,所述热处理的温度为70~400℃,所述热处理的时间为10~60min,所述热处理在质量分数为1~3%氢气的氛围下进行;The hot-rolled finished product is pickled, cold-rolled, annealed, hot-dip galvanized, heat-treated and smoothed to obtain the hot-dip galvanized high-strength steel with good welding performance; wherein, the heat treatment temperature is 70-400° C., The time of the heat treatment is 10 to 60 minutes, and the heat treatment is carried out in an atmosphere with a mass fraction of 1 to 3% hydrogen; 所述退火依次包括加热段、冷却段和时效段,其中,所述加热段为在820~900℃下保温5~25s;所述冷却段为由820~900℃以4℃/s~10℃/s速率冷却至400~550℃;所述时效段为400~550℃下保温≥8s;所述退火在质量分数为2%~10%氢气的氛围下进行;The annealing includes a heating section, a cooling section and an aging section in sequence, wherein, the heating section is kept at 820-900°C for 5-25s; Cooling to 400-550°C at a rate of /s; the aging section is kept at 400-550°C for ≥8s; the annealing is performed in an atmosphere with a mass fraction of 2%-10% hydrogen; 所述轧前加热的温度1100~1300℃,所述轧前加热的时间≥180min;所述精轧的出口温度为800~950℃,所述卷取的温度为450~700℃,所述冷轧压下率为20%~50%。The heating temperature before rolling is 1100-1300°C, the heating time before rolling is ≥180min; the exit temperature of the finishing rolling is 800-950°C, the coiling temperature is 450-700°C, and the cooling The rolling reduction rate is 20% to 50%. 2.根据权利要求1所述的一种具有良好焊接性能的热镀锌高强钢的制备方法,其特征在于,所述钢的化学成分以质量分数计为:C:0.10~0.30%,Si:1~2.5%,Mn:1.8~2.3%,P:≤0.01%,S:≤0.01%,Al:0.01~0.5%,N:0.1~0.6%,合金元素0.005%~0.5%,所述合金元素包括Ti、Nb、V、Zr、Mo、Cr、Cu和Ni中的至少一种,其余为Fe及不可避免的杂质。2 . The method for preparing a hot-dip galvanized high-strength steel with good weldability according to claim 1 , wherein the chemical composition of the steel in terms of mass fraction is: C: 0.10-0.30%, Si: 1~2.5%, Mn: 1.8~2.3%, P: ≤0.01%, S: ≤0.01%, Al: 0.01~0.5%, N: 0.1~0.6%, alloying elements 0.005%~0.5%, the alloying elements It includes at least one of Ti, Nb, V, Zr, Mo, Cr, Cu and Ni, and the rest are Fe and inevitable impurities. 3.根据权利要求1所述的一种具有良好焊接性能的热镀锌高强钢的制备方法,其特征在于,钢基体的金相组织以体积分数计为:10~30%的铁素体、40%~80%的马氏体、≤10%的贝氏体和4~20%的残余奥氏体。3. The method for preparing a hot-dip galvanized high-strength steel with good weldability according to claim 1, wherein the metallographic structure of the steel matrix is calculated as: 10-30% ferrite, 40%~80% martensite, ≤10% bainite and 4~20% retained austenite. 4.根据权利要求3所述的一种具有良好焊接性能的热镀锌高强钢的制备方法,其特征在于,所述铁素体的晶粒尺寸为3μm~6μm,所述马氏体的晶粒尺寸为1μm~4μm,所述贝氏体的晶粒尺寸为0.7μm~3.6μm,所述残余奥氏体的晶粒尺寸为0.6μm~1.8μm。4 . The method for preparing a hot-dip galvanized high-strength steel with good weldability according to claim 3 , wherein the ferrite has a grain size of 3 μm to 6 μm, and the martensite has a crystal grain size of 3 μm to 6 μm. 5 . The grain size is 1 μm˜4 μm, the grain size of the bainite is 0.7 μm˜3.6 μm, and the grain size of the retained austenite is 0.6 μm˜1.8 μm.
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