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CN112206640B - System and method for detecting pH value and concentration of limestone slurry in flying manner, control system and desulfurization system - Google Patents

System and method for detecting pH value and concentration of limestone slurry in flying manner, control system and desulfurization system Download PDF

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CN112206640B
CN112206640B CN202010974621.5A CN202010974621A CN112206640B CN 112206640 B CN112206640 B CN 112206640B CN 202010974621 A CN202010974621 A CN 202010974621A CN 112206640 B CN112206640 B CN 112206640B
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金国强
吴建国
李�杰
徐明军
于信波
房高超
孙广庆
杨春
王少君
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Abstract

本发明公开了一种石灰石浆液pH值浓度飞升检测系统、方法、控制系统和脱硫系统,检测系统,包括第一一阶惯性模块、第二一阶惯性模块、测量偏差模块和高低报警模块;第一一阶惯性模块对pH值测量信号进行第一滤波得到第一滤波值;第二一阶惯性模块对pH值测量信号进行第二滤波得到第二滤波值;测量偏差模块将第一滤波值和第二滤波值进行偏差处理得到偏差值;高低报警模块由所述偏差值得到pH值的变化趋势和变化量,对变化量进行阈值判断,并输出飞升检测结果。本发明采用实时pH值信号本身判断出pH值信号处于飞升状态时,可以剔除当前的失真信号,脱硫控制系统可以使用飞升检测判断信号进行对实时pH值信号处理。

Figure 202010974621

The invention discloses a detection system, method, control system and desulfurization system for limestone slurry pH value concentration soaring. The detection system includes a first-order inertial module, a second-first-order inertial module, a measurement deviation module and a high-low alarm module; The first-order inertial module performs the first filtering on the pH value measurement signal to obtain the first filtered value; the second first-order inertial module performs the second filtering on the pH value measurement signal to obtain the second filtered value; the measurement deviation module combines the first filtered value and the The second filter value is subjected to deviation processing to obtain a deviation value; the high-low alarm module obtains the change trend and change amount of the pH value from the deviation value, performs a threshold value judgment on the change amount, and outputs the detection result of flying up. The present invention uses the real-time pH value signal itself to determine that the pH value signal is in the soaring state, the current distorted signal can be eliminated, and the desulfurization control system can use the soaring detection and judgment signal to process the real-time pH value signal.

Figure 202010974621

Description

石灰石浆液pH值浓度飞升检测系统、方法、控制系统和脱硫 系统Limestone slurry pH concentration detection system, method, control system and desulfurization system

技术领域technical field

本发明涉及燃煤发电厂的FGD脱硫自动控制领域,具体涉及一种石灰石浆液pH值浓度飞升检测系统、方法、控制系统和脱硫系统。The invention relates to the field of FGD desulfurization automatic control of coal-fired power plants, in particular to a limestone slurry pH value concentration soaring detection system, method, control system and desulfurization system.

背景技术Background technique

二氧化硫(SO2)主要来自于煤、石油、天然气的燃烧过程,是主要大气污染物之一。因此控制燃煤电厂SO2排放是减少大气中SO2含量的主要措施之一。Sulfur dioxide (SO 2 ) mainly comes from the combustion process of coal, oil and natural gas, and is one of the main air pollutants. Therefore, controlling SO 2 emissions from coal-fired power plants is one of the main measures to reduce SO 2 content in the atmosphere.

根据《火电厂大气污染物排放标准》(GB13223-2011),为削减燃煤电厂污染物排放总量,各燃煤电厂将燃煤电厂污染物排放标准向“燃气轮机排放标准”看齐,即:烟尘、二氧化硫、氮氧化物三项排放限值分别为5mg/Nm3、35mg/Nm3、50mg/Nm3,通常在业内将此限值定义为燃煤锅炉“超净排放”标准。According to the "Emission Standard of Air Pollutants for Thermal Power Plants" (GB13223-2011), in order to reduce the total amount of pollutants emitted by coal-fired power plants, each coal-fired power plant will align the pollutant emission standards of coal-fired power plants with the "gas turbine emission standards", namely: soot The three emission limits of , sulfur dioxide and nitrogen oxides are 5mg/Nm3, 35mg/Nm3 and 50mg/Nm3 respectively, which are usually defined as the "ultra-clean emission" standard of coal-fired boilers in the industry.

减少SO2排放方法有多种。目前普遍采用的SO2控制技术基本上分为三类:“燃烧前脱硫、燃烧中脱硫及燃烧后脱硫即烟气脱硫(FGD)。There are many ways to reduce SO 2 emissions. Currently commonly used SO2 control technologies are basically divided into three categories: "Desulfurization before combustion, Desulfurization during combustion and Desulfurization after combustion, namely Flue Gas Desulfurization (FGD).

燃烧前脱硫指通过物理或化学方法对原煤进行洗选,除去或减少原煤中的硫分、灰分等杂质。采用的方法包括选煤、气化、水煤浆和型煤加工等。但该方法只能脱除煤中部分硫(主要是无机硫),不能根本上解决SO2对大气的污染问题;燃烧中脱硫是指向炉膛内喷入石灰CaO/CaCO3吸收剂,以此固化S02/SO3来脱硫,采用的方法有炉内喷钙、流化床掺烧石灰石脱硫;燃烧后脱硫即烟气脱硫技术(FGD)指在锅炉尾部烟道加装脱硫设备,利用脱硫剂对烟气进行脱硫,包括湿法、干法(半干法)脱硫工艺。其中:石灰石-石膏湿法被认为是当前控制SO2排放最行之有效的途径。Pre-combustion desulfurization refers to the washing of raw coal by physical or chemical methods to remove or reduce impurities such as sulfur and ash in the raw coal. The methods used include coal preparation, gasification, coal-water slurry and briquette processing. However, this method can only remove part of the sulfur (mainly inorganic sulfur) in the coal, and cannot fundamentally solve the problem of SO 2 pollution to the atmosphere; the desulfurization during combustion is to inject lime CaO/CaCO 3 absorbent into the furnace to solidify S0 2 /SO 3 is used for desulfurization. The methods used include calcium injection in the furnace and limestone mixing in fluidized bed for desulfurization; post-combustion desulfurization, namely flue gas desulfurization (FGD), refers to the addition of desulfurization equipment to the flue at the tail of the boiler, and the use of desulfurization agents. Desulfurization of flue gas, including wet and dry (semi-dry) desulfurization processes. Among them: Limestone-gypsum wet method is considered to be the most effective way to control SO 2 emissions.

现有脱硫控制系统是以燃煤发电机组净烟气出口SO2浓度为控制目标,石灰石-石膏湿法脱硫控制中同时控制石灰石浆液pH值浓度,以达到控制对SO2的吸收程度,从而控制净烟气出口SO2浓度满足环保要求。The existing desulfurization control system takes the SO 2 concentration at the net flue gas outlet of the coal-fired generator set as the control target, and controls the pH value concentration of the limestone slurry in the limestone-gypsum wet desulfurization control, so as to control the degree of SO 2 absorption, thereby controlling the pH value of the limestone slurry. The SO 2 concentration at the net flue gas outlet meets the requirements of environmental protection.

现有脱硫控制系统中需要使用石灰石浆液pH值浓度,计算出需要的石灰石浆液阀门开度,从而实现对脱硫后净烟气出口SO2含量的控制。In the existing desulfurization control system, the pH concentration of limestone slurry needs to be used to calculate the required valve opening of the limestone slurry, so as to realize the control of SO 2 content in the net flue gas outlet after desulfurization.

从运行现状和控制逻辑方面的分析:FGD脱硫控制系统自动投入运行依赖于石灰石浆液pH值浓度的测定。From the analysis of operation status and control logic: FGD desulfurization control system automatically put into operation depends on the determination of pH concentration of limestone slurry.

由于石灰石浆液pH值浓度的测定装置定期清洗(每个小时清洗一次),石灰石浆液pH值浓度失去真实性,且控制系统不能正确获取清洗过程,测量值大幅上升,影响了石灰石浆液pH值浓度测量准确度,造成脱硫自动控制无法适应pH值变化而投入自动。Due to the regular cleaning of the limestone slurry pH concentration measuring device (cleaning once every hour), the pH value concentration of limestone slurry loses its authenticity, and the control system cannot correctly obtain the cleaning process, and the measured value rises greatly, which affects the measurement of limestone slurry pH concentration. Accuracy, resulting in automatic desulfurization control can not adapt to pH changes and put into automatic.

发明内容SUMMARY OF THE INVENTION

为解决因清洗pH值大幅飞升信号失真的问题,本发明提供一种石灰石浆液pH值浓度飞升检测系统、方法、控制系统和脱硫系统。本发明可以实时pH值信号剔除失真信号后能够保证脱硫控制系统PID的正常工作。In order to solve the problem of signal distortion caused by the sharp rise of pH value in cleaning, the present invention provides a detection system, method, control system and desulfurization system of limestone slurry pH value concentration fly-up. The invention can ensure the normal operation of the PID of the desulfurization control system after removing the distorted signal from the real-time pH value signal.

为达到上述目的,本发明采用以下技术方案予以实现:To achieve the above object, the present invention adopts the following technical solutions to realize:

一种石灰石浆液pH值浓度飞升检测系统,包括:第一一阶惯性模块、第二一阶惯性模块、测量偏差模块和高低报警模块;A limestone slurry pH value concentration soaring detection system, comprising: a first-order inertial module, a second-first-order inertial module, a measurement deviation module and a high-low alarm module;

所述第一一阶惯性模块,用于对pH值测量信号进行第一滤波得到第一滤波值;The first-order inertial module is used to perform a first filter on the pH value measurement signal to obtain a first filter value;

所述第二一阶惯性模块,用于对pH值测量信号进行第二滤波得到第二滤波值;The second first-order inertial module is used to perform a second filter on the pH value measurement signal to obtain a second filter value;

所述测量偏差模块,用于将第一滤波值和第二滤波值进行偏差处理得到偏差值;The measurement deviation module is used to perform deviation processing on the first filter value and the second filter value to obtain a deviation value;

所述高低报警模块,用于由所述偏差值得到pH值的变化趋势和变化量,对变化量进行阈值判断,并输出飞升检测结果。The high and low alarm module is used to obtain the change trend and change amount of the pH value from the deviation value, perform a threshold value judgment on the change amount, and output the detection result of the soaring rise.

作为本发明的进一步改进,所述第一一阶惯性模块的传递函数公式为:

Figure GDA0003677329880000031
As a further improvement of the present invention, the transfer function formula of the first-order inertial module is:
Figure GDA0003677329880000031

所述第二一阶惯性模块的传递函数公式为:

Figure GDA0003677329880000032
The transfer function formula of the second first-order inertial module is:
Figure GDA0003677329880000032

其中,G(s)表征零初始条件下线性系统响应输入与输出的拉普拉斯变换之比;T1,T2表征惯性环节的惯性时间常数。Among them, G(s) represents the ratio of the Laplace transform of the input to the output of the linear system response under the zero initial condition; T1, T2 represent the inertial time constant of the inertial link.

作为本发明的进一步改进,所述第一一阶惯性模块惯性时间T1为10s~20s;第一一阶惯性模块的惯性时间T2为60s~70s。As a further improvement of the present invention, the inertia time T1 of the first-order inertial module is 10s-20s; the inertial time T2 of the first-order inertial module is 60s-70s.

作为本发明的进一步改进,还包括飞升检测投入开关和飞升检测投入确认模块;As a further improvement of the present invention, it also includes a soaring detection input switch and a soaring detection and input confirmation module;

所述飞升检测投入开关,用于给出飞升检测系统的工作状态;The soaring detection input switch is used to give the working state of the soaring detection system;

所述飞升检测投入确认模块,用于根据所述飞升检测结果与飞升检测投入开关的工作状态判断飞升检测结果的有效性。The ascension detection and input confirmation module is used for judging the validity of the ascension detection result according to the ascension detection result and the working state of the ascension detection input switch.

一种石灰石浆液pH值浓度飞升检测系统的检测方法,包括以下步骤:A detection method for a limestone slurry pH value concentration soaring detection system, comprising the following steps:

对pH值测量信号进行第一滤波得到第一滤波值;performing a first filtering on the pH value measurement signal to obtain a first filtering value;

对pH值测量信号进行第二滤波得到第二滤波值;performing a second filter on the pH value measurement signal to obtain a second filter value;

对第一滤波值和第二滤波值进行偏差处理得到偏差值;Performing deviation processing on the first filter value and the second filter value to obtain a deviation value;

由所述偏差值得到pH值的变化趋势和变化量,对变化量进行阈值判断,并输出飞升检测结果。The change trend and change amount of pH value are obtained from the deviation value, the threshold value is judged for the change amount, and the detection result of the soaring rise is output.

作为本发明的进一步改进,还包括:As a further improvement of the present invention, it also includes:

根据给出飞升检测系统的工作状态和飞升检测结果判断飞升检测结果的有效性。According to the given working status of the ascension detection system and the ascension detection result, the validity of the ascension detection result is judged.

所述有效性是指当飞升检测投入开关处于投入状态,且高低报警模块输出飞升检测结果为真,则飞升检测控制系统的输出为真;否则,检测到pH值的信号处于飞升状态,信号失真。The validity means that when the Feisheng detection input switch is in the input state, and the high and low alarm module output Feisheng detection result is true, the output of Feisheng detection control system is true; otherwise, the signal that detects the pH value is in the Feisheng state, and the signal is distorted. .

一种FGD脱硫自动控制系统,包括pH值测量系统、脱硫控制系统和所述的石灰石浆液pH值浓度飞升检测系统;An FGD desulfurization automatic control system, comprising a pH value measurement system, a desulfurization control system and the limestone slurry pH value concentration soaring detection system;

所述pH值测量系统,和pH值测量装置连接,用于获得pH值测量信号;The pH value measurement system is connected to the pH value measurement device for obtaining a pH value measurement signal;

所述的石灰石浆液pH值浓度飞升检测系统,用于判断pH值测量装置得到的pH值测量信号是否处于飞升失真;The described limestone slurry pH value concentration soaring detection system is used for judging whether the pH value measurement signal obtained by the pH value measuring device is in soaring distortion;

所述脱硫控制系统,用于根据所述飞升失真结果对SO2吸收剂进行控制。The desulfurization control system is used to control the SO 2 absorbent according to the result of the fly-up distortion.

一种FGD脱硫系统,包括锅炉下降段换热器、脱硝喷氨格栅、脱硝反应器、空气预热器、电除尘器、脱硫吸收塔、烟囱、石灰石浆液循环泵、pH值测量装置、石灰石新浆液补充管道和所述的FGD脱硫自动控制系统;An FGD desulfurization system includes a boiler descending heat exchanger, a denitration ammonia injection grill, a denitration reactor, an air preheater, an electrostatic precipitator, a desulfurization absorption tower, a chimney, a limestone slurry circulating pump, a pH value measuring device, a limestone New slurry replenishment pipeline and described FGD desulfurization automatic control system;

锅炉燃烧的烟气流经所述锅炉下降段换热器到达脱硝喷氨格栅,再与喷射的氨-空气混合物进行混合,进入脱硝反应器进行化学反应脱硝,脱硝后的烟气进入空气预热器将热量回收后经电除尘器和脱硫吸收塔后经烟囱排入大气;The flue gas from the boiler combustion passes through the heat exchanger in the descending section of the boiler to reach the denitrification and ammonia injection grille, and then mixes with the injected ammonia-air mixture, and enters the denitration reactor for chemical reaction and denitrification. After the heat is recovered by the heater, it is discharged into the atmosphere through the chimney through the electrostatic precipitator and the desulfurization absorption tower;

所述石灰石浆液循环泵与石灰石浆液供脱硫吸收塔内的喷淋设备连接;所述pH值测量装置设置在脱硫吸收塔内的石灰石浆液中,所述pH值测量装置与FGD脱硫自动控制系统电连接;所述石灰石新浆液补充管道与脱硫吸收塔连通,所述FGD脱硫自动控制系统控制所述石灰石新浆液补充管道的通断。The limestone slurry circulating pump is connected to the spray equipment in the desulfurization absorption tower for limestone slurry supply; the pH value measuring device is arranged in the limestone slurry in the desulfurization absorption tower, and the pH value measuring device is electrically connected to the FGD desulfurization automatic control system. connection; the new limestone slurry supplement pipeline is communicated with the desulfurization absorption tower, and the FGD desulfurization automatic control system controls the on-off of the new limestone slurry supplement pipeline.

作为本发明的进一步改进,所述烟囱中还设置有净烟气SO2测量装置。As a further improvement of the present invention, the chimney is also provided with a net flue gas SO 2 measuring device.

与现有技术相比,本发明提供的PH值飞升检测系统具有自动辨识和剔除对脱硫控制系统无用甚至的干扰脱硫控制系统的PH值虚假失真信号,为脱硫控制系统能够实时在线全自动打下基础。Compared with the prior art, the pH value soaring detection system provided by the present invention can automatically identify and eliminate the false and distorted signals of the pH value that are useless to the desulfurization control system and even interfere with the desulfurization control system, laying a foundation for the desulfurization control system to be fully automatic in real time. .

本发明采用两个一阶惯性模块对pH值测量信号进行滤波处理,并进行偏差处理,对变化量进行阈值判断,并输出飞升检测结果,对实时pH值信号本身进行判断pH值信号是否失真,解决pH值测量装置清洗带来的pH值不可用的难题。因为pH值测量装置定期清洗,脱硫控制系统不能取得pH值测量装置的清洗信息,pH值测量信号在pH值测量装置清洗时会出现信号的飞升,信号失真,信号不能被脱硫控制系统使用,pH值测量值大幅变化,影响了测量准确度和相应时间,进而影响脱硫控制系统的投入,影响脱硫系统所控制的环保指标。本发明采用实时pH值信号本身判断出pH值信号处于飞升状态时,可以剔除当前的失真信号,脱硫控制系统可以使用飞升检测判断信号进行对实时pH值信号处理。实时pH值信号剔除失真信号后能够保证脱硫控制系统PID的正常工作。The invention adopts two first-order inertial modules to filter and process the pH value measurement signal, and performs deviation processing, performs threshold value judgment on the change amount, and outputs the detection result of flying liters, and judges whether the pH value signal is distorted by the real-time pH value signal itself. Solve the problem that the pH value is unavailable due to the cleaning of the pH value measuring device. Because the pH value measuring device is cleaned regularly, the desulfurization control system cannot obtain the cleaning information of the pH value measuring device, and the pH value measurement signal will rise when the pH value measuring device is cleaned, the signal will be distorted, and the signal cannot be used by the desulfurization control system. The measured value changes greatly, which affects the measurement accuracy and corresponding time, which in turn affects the input of the desulfurization control system and affects the environmental protection indicators controlled by the desulfurization system. The present invention uses the real-time pH value signal itself to judge that the pH value signal is in the state of soaring, the current distorted signal can be eliminated, and the desulfurization control system can use the soaring detection and judgment signal to process the real-time pH signal. The real-time pH value signal can ensure the normal operation of the PID of the desulfurization control system after eliminating the distorted signal.

附图说明Description of drawings

图1为pH值飞升检测系统框图;Fig. 1 is the block diagram of pH value soaring detection system;

图2为pH值测量飞升检测系统示意图;Fig. 2 is the schematic diagram of pH value measurement Femtoliter detection system;

图3为脱硫系统流程图;Fig. 3 is the flow chart of desulfurization system;

图中装置与模块代号说明表:Device and module code description table in the figure:

1、锅炉下降段换热器;1. Heat exchanger in the descending section of the boiler;

2、脱硝喷氨格栅;2. Denitrification and ammonia injection grill;

3、脱硝反应器;3. Denitrification reactor;

4、空气预热器;4. Air preheater;

5、电除尘器;5. Electrostatic precipitator;

6、脱硫吸收塔;6. Desulfurization absorption tower;

7、烟囱;7. Chimney;

8、净烟气SO2测量装置;8. Net flue gas SO 2 measuring device;

9、石灰石浆液循环泵;9. Limestone slurry circulating pump;

10、石灰石浆液pH值测量装置;10. Limestone slurry pH value measuring device;

11、石灰石新浆液补充管道;11. Limestone new slurry supplement pipeline;

12、LAG第一一阶惯性模块;12. LAG first-order inertial module;

13、LAG第二一阶惯性模块;13. LAG second-order inertial module;

ON/OFF、飞升检测投入开关模块;ON/OFF, Feisheng detection input switch module;

ALARM、高低报警模块;ALARM, high and low alarm module;

DEV、测量偏差模块;DEV, measurement deviation module;

AND、飞升检测投入确认模块。AND, Feisheng detection and input confirmation module.

具体实施方式Detailed ways

为了使本技术领域的人员更好地理解本发明方案,下面将结合本发明实施例中的附图,对本发明实施例中的技术方案进行清楚、完整地描述,显然,所描述的实施例仅仅是本发明一部分的实施例,不是全部的实施例,而并非要限制本发明公开的范围。此外,在以下说明中,省略了对公知结构和技术的描述,以避免不必要的混淆本发明公开的概念。基于本发明中的实施例,本领域普通技术人员在没有做出创造性劳动前提下所获得的所有其他实施例,都应当属于本发明保护的范围。In order to make those skilled in the art better understand the solutions of the present invention, the technical solutions in the embodiments of the present invention will be clearly and completely described below with reference to the accompanying drawings in the embodiments of the present invention. Obviously, the described embodiments are only The embodiments are part of the present invention, not all of the embodiments, and are not intended to limit the scope of the present disclosure. Furthermore, in the following description, descriptions of well-known structures and techniques are omitted to avoid unnecessarily obscuring the concepts disclosed in the present invention. Based on the embodiments of the present invention, all other embodiments obtained by persons of ordinary skill in the art without creative efforts shall fall within the protection scope of the present invention.

在附图中示出了根据本发明公开实施例的各种结构示意图。这些图并非是按比例绘制的,其中为了清楚表达的目的,放大了某些细节,并且可能省略了某些细节。图中所示出的各种区域、层的形状及它们之间的相对大小、位置关系仅是示例性的,实际中可能由于制造公差或技术限制而有所偏差,并且本领域技术人员根据实际所需可以另外设计具有不同形状、大小、相对位置的区域/层。Various structural schematic diagrams according to the disclosed embodiments of the present invention are shown in the accompanying drawings. The figures are not to scale, some details have been exaggerated for clarity, and some details may have been omitted. The shapes of various regions and layers shown in the figures and their relative sizes and positional relationships are only exemplary, and in practice, there may be deviations due to manufacturing tolerances or technical limitations, and those skilled in the art should Regions/layers with different shapes, sizes, relative positions can be additionally designed as desired.

本发明公开的上下文中,当将一层/元件称作位于另一层/元件“上”时,该层/元件可以直接位于该另一层/元件上,或者它们之间可以存在居中层/元件。另外,如果在一种朝向中一层/元件位于另一层/元件“上”,那么当调转朝向时,该层/元件可以位于该另一层/元件“下”。In the context of the present disclosure, when a layer/element is referred to as being "on" another layer/element, it can be directly on the other layer/element or intervening layers/elements may be present therebetween. element. In addition, if a layer/element is "on" another layer/element in one orientation, then when the orientation is reversed, the layer/element can be "under" the other layer/element.

需要说明的是,本发明的说明书和权利要求书及上述附图中的术语“第一”、“第二”等是用于区别类似的对象,而不必用于描述特定的顺序或先后次序。应该理解这样使用的数据在适当情况下可以互换,以便这里描述的本发明的实施例能够以除了在这里图示或描述的那些以外的顺序实施。此外,术语“包括”和“具有”以及他们的任何变形,意图在于覆盖不排他的包含,例如,包含了一系列步骤或单元的过程、方法、系统、产品或设备不必限于清楚地列出的那些步骤或单元,而是可包括没有清楚地列出的或对于这些过程、方法、产品或设备固有的其它步骤或单元。It should be noted that the terms "first", "second" and the like in the description and claims of the present invention and the above drawings are used to distinguish similar objects, and are not necessarily used to describe a specific sequence or sequence. It is to be understood that the data so used may be interchanged under appropriate circumstances such that the embodiments of the invention described herein can be practiced in sequences other than those illustrated or described herein. Furthermore, the terms "comprising" and "having" and any variations thereof, are intended to cover non-exclusive inclusion, for example, a process, method, system, product or device comprising a series of steps or units is not necessarily limited to those expressly listed Rather, those steps or units may include other steps or units not expressly listed or inherent to these processes, methods, products or devices.

鉴于以上问题,为解决FGD脱硫控制中由于石灰石浆液pH值测量装置因清洗pH值大幅飞升信号失真造成脱硫控制无法投入。In view of the above problems, in order to solve the problem of FGD desulfurization control, the desulfurization control cannot be put into operation due to the signal distortion of the limestone slurry pH value measuring device due to the sharp rise of the cleaning pH value.

本发明第一个目的是提供一种石灰石浆液pH值浓度飞升检测系统,包括:第一一阶惯性模块12、第二一阶惯性模块13、测量偏差模块DEV和高低报警模块ALARM;The first object of the present invention is to provide a limestone slurry pH concentration soaring detection system, including: a first-order inertial module 12, a second-first-order inertial module 13, a measurement deviation module DEV and a high-low alarm module ALARM;

所述第一一阶惯性模块12,用于对pH值测量信号进行第一滤波得到第一滤波值;The first-order inertial module 12 is used to perform a first filter on the pH value measurement signal to obtain a first filter value;

所述第二一阶惯性模块13,用于对pH值测量信号进行第二滤波得到第二滤波值;The second first-order inertial module 13 is used to perform a second filter on the pH value measurement signal to obtain a second filter value;

所述测量偏差模块DEV,用于将第一滤波值和第二滤波值进行偏差处理得到偏差值;The measurement deviation module DEV is configured to perform deviation processing on the first filter value and the second filter value to obtain a deviation value;

所述高低报警模块ALARM,用于由所述偏差值得到pH值的变化趋势和变化量,对变化量进行阈值判断,并输出飞升检测结果。The high and low alarm module ALARM is used to obtain the change trend and change amount of the pH value from the deviation value, perform threshold value judgment on the change amount, and output the detection result of soaring.

该石灰石浆液pH值浓度飞升检测系统处于DCS内,介于pH值测量系统与脱硫控制系统之间。见附图1和2。The limestone slurry pH value concentration fly-up detection system is located in the DCS, between the pH value measurement system and the desulfurization control system. See Figures 1 and 2.

pH值测量信号飞升检测系统包含两个环节:pH值偏差处理和pH值报警即第一一阶惯性模块12、第二一阶惯性模块13、测量偏差模块DEV、高低报警模块ALARM、飞升检测投入开关ON/OFF、飞升检测投入确认模块AND组成飞升检测控制系统。以上都是本发明所提出的飞升检测控制系统用于脱硫控制的关键部件。The pH value measurement signal soaring detection system includes two links: pH value deviation processing and pH value alarming, namely the first and first-order inertial module 12, the second and first-order inertial module 13, the measurement deviation module DEV, the high and low alarm module ALARM, and the soaring detection input The switch ON/OFF and the ascension detection input confirmation module AND constitute the ascension detection control system. The above are all the key components used in the desulfurization control of the fly-up detection and control system proposed by the present invention.

本发明提出的pH值飞升检测控制系统构成如附图1所示,脱硫吸收塔内的pH值测量经过测量装置取得pH值测量信号,经过测量环节处理后送入脱硫控制系统进行脱硫控制使用。The composition of the pH value soaring detection and control system proposed by the present invention is shown in Figure 1. The pH value measurement in the desulfurization absorption tower obtains the pH value measurement signal through the measuring device, and sends it to the desulfurization control system for desulfurization control after processing in the measurement process.

所述第一一阶惯性模块12的传递函数公式为:

Figure GDA0003677329880000081
The transfer function formula of the first-order inertial module 12 is:
Figure GDA0003677329880000081

所述第二一阶惯性模块13的传递函数公式为:

Figure GDA0003677329880000082
The transfer function formula of the second first-order inertial module 13 is:
Figure GDA0003677329880000082

其中,G(s)表征零初始条件下线性系统响应输入与输出的拉普拉斯变换之比;T1,T2表征惯性环节的惯性时间常数。Among them, G(s) represents the ratio of the Laplace transform of the input to the output of the linear system response under the zero initial condition; T1, T2 represent the inertial time constant of the inertial link.

pH值测量信号进入第一一阶惯性模块12、惯性模块惯性时间为10s~20s之间;pH值测量信号进入第二一阶惯性模块13,惯性模块惯性时间为60s~70s之间。The pH value measurement signal enters the first-order inertial module 12, and the inertial module inertia time is between 10s and 20s; the pH value measurement signal enters the second first-order inertial module 13, and the inertial module inertial time is between 60s and 70s.

第一一阶惯性模块12的输出和第二一阶惯性模块13的输出进入测量偏差模块DEV;测量偏差模块DEV的输出进入高低报警模块ALARM,高低报警模块ALARM检测当前pH值的变化趋势和变化量,一旦超出了预设阈值,高低报警模块ALARM输出飞升检测结果。这个飞升检测的结果与飞升检测投入开关ON/OFF的状态进入飞升检测投入确认模块AND。The output of the first-order inertial module 12 and the output of the second-order inertial module 13 enter the measurement deviation module DEV; the output of the measurement deviation module DEV enters the high-low alarm module ALARM, and the high-low alarm module ALARM detects the change trend and change of the current pH value Once it exceeds the preset threshold, the high and low alarm module ALARM outputs the soaring detection result. The result of the ascension detection and the ON/OFF state of the ascension detection input switch enter the ascension detection input confirmation module AND.

本发明第二个目的为提供一种石灰石浆液pH值浓度飞升检测系统的检测方法,包括以下步骤:The second object of the present invention is to provide a kind of detection method of limestone slurry pH value concentration soaring detection system, comprising the following steps:

对pH值测量信号进行第一滤波得到第一滤波值;performing a first filtering on the pH value measurement signal to obtain a first filtering value;

对pH值测量信号进行第二滤波得到第二滤波值;performing a second filter on the pH value measurement signal to obtain a second filter value;

对第一滤波值和第二滤波值进行偏差处理得到偏差值;Performing deviation processing on the first filter value and the second filter value to obtain a deviation value;

由所述偏差值得到pH值的变化趋势和变化量,对变化量进行阈值判断,并输出飞升检测结果。The change trend and change amount of pH value are obtained from the deviation value, the threshold value is judged for the change amount, and the detection result of the soaring rise is output.

当飞升检测投入开关ON/OFF处于投入状态,且高低报警模块ALARM输出飞升检测结果为真,则飞升检测控制系统的输出为真。否则,此时,检测到pH值的信号处于飞升状态,信号失真,不可用。When the soaring detection input switch ON/OFF is in the input state, and the high and low alarm module ALARM outputs the soaring detection result is true, the output of the soaring detection control system is true. Otherwise, at this time, the signal that detects the pH value is in a soaring state, and the signal is distorted and unavailable.

本发明第三个目的是提供一种FGD脱硫自动控制系统,包括pH值测量系统、脱硫控制系统和所述的石灰石浆液pH值浓度飞升检测系统;The third object of the present invention is to provide a FGD desulfurization automatic control system, including a pH value measurement system, a desulfurization control system and the limestone slurry pH value concentration soaring detection system;

所述pH值测量系统,和pH值测量装置连接,用于获得pH值测量信号;The pH value measurement system is connected to the pH value measurement device for obtaining a pH value measurement signal;

所述的石灰石浆液pH值浓度飞升检测系统,用于判断pH值测量装置得到的pH值测量信号是否处于飞升失真;The described limestone slurry pH value concentration soaring detection system is used for judging whether the pH value measurement signal obtained by the pH value measuring device is in soaring distortion;

所述脱硫控制系统,用于根据所述飞升失真结果对SO2吸收剂进行控制。The desulfurization control system is used to control the SO 2 absorbent according to the result of the fly-up distortion.

pH值飞升检测控制系统位于pH值测量系统与脱硫控制系统之间。pH值测量信号从测量系统送出后,进入脱硫控制之前,进入飞升检测控制系统。飞升检测控制系统实时在线检测pH值测量信号,一旦检测到pH值测量信号因测量仪器清洗出现飞升现象,信号失真,失真的pH值测量信号将不被送入脱硫控制系统。The pH value soaring detection control system is located between the pH value measurement system and the desulfurization control system. After the pH value measurement signal is sent from the measurement system, before entering the desulfurization control, it enters the Feisheng detection control system. The soaring detection and control system detects the pH value measurement signal online in real time. Once the pH value measurement signal is detected to be soaring due to the cleaning of the measuring instrument, the signal is distorted, and the distorted pH value measurement signal will not be sent to the desulfurization control system.

该石灰石浆液pH值浓度飞升检测系统在脱硫控制投入自动时起作用,pH值测量飞升检测系统产生pH值测量信号的飞升判断信号。当pH值测量飞升检测系统判断出测量信号处于飞升状态,进入到脱硫控制的pH值信号处于失真状态,失真的信号会被剔除。The limestone slurry pH value concentration Feather detection system works when desulfurization control is put into automatic operation, and the pH value measurement Feather detection system generates a Feather judgment signal of the pH value measurement signal. When the pH value measurement soaring detection system determines that the measurement signal is in the soaring state, the pH value signal entering the desulfurization control is in a distorted state, and the distorted signal will be eliminated.

该石灰石浆液pH值浓度飞升检测系统的作用是判断pH值测量装置因清洗产生失真的pH值测量,形成pH值测量信号是否处于飞升失真的判断。该系统包含两个环节:pH值偏差处理模块和pH值偏差报警模块。该系统产生合理的pH值信号失真判断信号供脱硫系统控制使用,保障合理的脱硫控制品质,防止脱硫控制系统大幅波动。The function of the limestone slurry pH concentration detection system is to judge whether the pH value measurement device is distorted due to cleaning, so as to judge whether the pH value measurement signal is in the fly-up distortion. The system consists of two links: pH value deviation processing module and pH value deviation alarm module. The system generates a reasonable pH value signal distortion judgment signal for the control of the desulfurization system to ensure a reasonable desulfurization control quality and prevent the desulfurization control system from fluctuating greatly.

本发明第四个目的为提供一种FGD脱硫系统,包括锅炉下降段换热器1、脱硝喷氨格栅2、脱硝反应器3、空气预热器4、电除尘器5、脱硫吸收塔6、烟囱7、石灰石浆液循环泵9、pH值测量装置10、石灰石新浆液补充管道11和所述的FGD脱硫自动控制系统;The fourth object of the present invention is to provide a FGD desulfurization system, which includes a boiler descending section heat exchanger 1, a denitration ammonia spray grid 2, a denitration reactor 3, an air preheater 4, an electric precipitator 5, and a desulfurization absorption tower 6 , chimney 7, limestone slurry circulating pump 9, pH value measuring device 10, new limestone slurry supplement pipeline 11 and described FGD desulfurization automatic control system;

典型的脱硫系统流程如附图3所示,锅炉燃烧的烟气流经锅炉下降段换热器1,到达脱硝喷氨格栅2,与喷射的氨-空气混合物进行混合,进入脱硝反应器3进行化学反应,脱硝后的烟气进入空气预热器4进一步将热量回收后经电除尘器5和脱硫吸收塔6后经烟囱7排入大气。A typical process of the desulfurization system is shown in Figure 3. The flue gas from the boiler combustion passes through the boiler descending section heat exchanger 1, reaches the denitration ammonia injection grid 2, is mixed with the injected ammonia-air mixture, and enters the denitration reactor 3. The chemical reaction is carried out, and the denitrified flue gas enters the air preheater 4 for further heat recovery, passes through the electrostatic precipitator 5 and the desulfurization absorption tower 6, and then is discharged into the atmosphere through the chimney 7.

在脱硫吸收塔6中,由石灰石浆液循环泵9提供石灰石浆液供吸收塔喷淋设备使用,石灰石浆液与原烟气中的SO2进行反应并被吸收,除去绝大多数的SO2。石灰石浆液的石灰石浓度通过pH值测量装置10检测,送DCS的脱硫控制系统使用。当石灰石浆液pH值偏高,说明石灰石浆液中吸收SO2的吸收剂不足,将通过石灰石新浆液补充管道11进行补充。In the desulfurization absorption tower 6, the limestone slurry is supplied by the limestone slurry circulation pump 9 for the spraying equipment of the absorption tower. The limestone slurry reacts with the SO 2 in the original flue gas and is absorbed to remove most of the SO 2 . The limestone concentration of the limestone slurry is detected by the pH value measuring device 10 and sent to the desulfurization control system of DCS for use. When the pH value of the limestone slurry is high, it means that the absorbent for absorbing SO 2 in the limestone slurry is insufficient, and it will be supplemented through the new limestone slurry supplement pipeline 11 .

所述石灰石浆液循环泵9与石灰石浆液供脱硫吸收塔6内的喷淋设备连接;所述pH值测量装置10设置在脱硫吸收塔6内的石灰石浆液中,所述pH值测量装置10与FGD脱硫自动控制系统电连接;所述石灰石新浆液补充管道11与脱硫吸收塔6连通,所述FGD脱硫自动控制系统控制所述石灰石新浆液补充管道11的通断。所述烟囱7中还设置有净烟气SO2测量装置8。The limestone slurry circulating pump 9 is connected with the limestone slurry for the spray equipment in the desulfurization absorption tower 6; the pH value measuring device 10 is arranged in the limestone slurry in the desulfurization absorption tower 6, and the pH value measuring device 10 is connected with the FGD. The desulfurization automatic control system is electrically connected; the new limestone slurry supplement pipeline 11 is connected with the desulfurization absorption tower 6 , and the FGD desulfurization automatic control system controls the on-off of the limestone new slurry supplement pipeline 11 . The chimney 7 is also provided with a clean flue gas SO 2 measuring device 8 .

pH值测量信号飞升检测系统的设计方法:pH值信号经过测量信号系统进入DCS内,在送入脱硫控制系统之前经过pH值信号飞升检测系统。飞升检测系统实时在线检测当前的pH值测量信号,当检测到飞升趋势并判断出当前的pH值处于飞升状态,当前的pH值信号不被采纳,利用飞升前的数值作为pH值的控制量,送入到脱硫控制系统。The design method of the pH value measurement signal soaring detection system: the pH value signal enters the DCS through the measuring signal system, and passes through the pH value signal soaring detection system before being sent to the desulfurization control system. The soaring detection system detects the current pH value measurement signal online in real time. When the soaring trend is detected and the current pH value is judged to be in the soaring state, the current pH value signal is not adopted, and the value before the soaring is used as the pH value control amount. sent to the desulfurization control system.

例如:pH值信号飞升检测系统的DEV模块实时检测第一一阶惯性模块12和第二一阶惯性模块13的偏差,高低报警检测模块ALARM根据预设的阈值(现场根据实测信号曲线给出判断阈值,根据现场经验高限报警判断值设置8~10之间;低限告警判断设置-8~~-10之间)输出信号飞升的诊断结果信息。For example: the DEV module of the pH value signal soaring detection system detects the deviation of the first-order inertial module 12 and the second-order inertial module 13 in real time; Threshold, according to field experience, the high alarm judgment value is set between 8 and 10; the low alarm judgment value is set between -8 and -10) The diagnostic result information of the output signal soaring.

该技术方案的特点主要有:The main features of this technical solution are:

1.采用实时pH值信号本身进行判断pH值信号是否失真,解决pH值测量装置清洗带来的pH值不可用的难题。因为pH值测量装置定期清洗,脱硫控制系统不能取得pH值测量装置的清洗信息,pH值测量信号在pH值测量装置清洗时会出现信号的飞升,信号失真,信号不能被脱硫控制系统使用,pH值测量值大幅变化,影响了测量准确度和相应时间,进而影响脱硫控制系统的投入,影响脱硫系统所控制的环保指标。1. Use the real-time pH signal itself to judge whether the pH signal is distorted, and solve the problem of unusable pH caused by the cleaning of the pH measuring device. Because the pH value measuring device is cleaned regularly, the desulfurization control system cannot obtain the cleaning information of the pH value measuring device, and the pH value measurement signal will rise when the pH value measuring device is cleaned, the signal will be distorted, and the signal cannot be used by the desulfurization control system. The measured value changes greatly, which affects the measurement accuracy and corresponding time, which in turn affects the input of the desulfurization control system and affects the environmental protection indicators controlled by the desulfurization system.

2.采用实时pH值信号本身判断出pH值信号处于飞升状态时,可以剔除当前的失真信号,脱硫控制系统可以使用飞升检测判断信号进行对实时pH值信号处理。实时pH值信号剔除失真信号后能够保证脱硫控制系统PID的正常工作。2. When the real-time pH signal itself is used to judge that the pH signal is in the soaring state, the current distorted signal can be eliminated, and the desulfurization control system can use the soaring detection and judgment signal to process the real-time pH signal. The real-time pH value signal can ensure the normal operation of the PID of the desulfurization control system after eliminating the distorted signal.

3.采用实时pH值信号本身判断出pH值信号处于飞升状态时,可以精确控制石灰石供浆阀门,防止阀门因pH值信号失真大开大合而退出自动运行状态,脱硫控制系统能够稳定的运行。3. When the real-time pH value signal is used to judge that the pH value signal is in the soaring state, the limestone slurry supply valve can be accurately controlled to prevent the valve from exiting the automatic operation state due to the distortion of the pH value signal, and the desulfurization control system can run stably .

以上内容仅为说明本发明的技术思想,不能以此限定本发明的保护范围,凡是按照本发明提出的技术思想,在技术方案基础上所做的任何改动,均落入本发明权利要求书的保护范围之内。The above content is only to illustrate the technical idea of the present invention, and cannot limit the protection scope of the present invention. Any modification made on the basis of the technical solution proposed in accordance with the technical idea of the present invention falls within the scope of the claims of the present invention. within the scope of protection.

Claims (5)

1. The utility model provides a lime stone thick liquid pH value concentration fly-lift detecting system which characterized in that includes: the system comprises a first-order inertia module (12), a second-order inertia module (13), a measurement deviation module (DEV) and an ALARM module (ALARM);
the first order inertia module (12) is used for carrying out first filtering on the pH value measurement signal to obtain a first filtering value;
the second first-order inertia module (13) is used for carrying out second filtering on the pH value measurement signal to obtain a second filtering value;
the deviation measuring module (DEV) is used for carrying out deviation processing on the first filtering value and the second filtering value to obtain a deviation value;
the high-low ALARM module (ALARM) is used for obtaining the change trend and the change quantity of the pH value according to the deviation value, carrying out threshold judgment on the change quantity and outputting a flight-rise detection result;
the first-order inertia module (12) and the second first-order inertia module (13) are arranged in parallel;
the transfer function formula of the first order inertia module (12) is as follows:
Figure 734382DEST_PATH_IMAGE001
the transfer function formula of the second first order inertia module (13) is as follows:
Figure 842016DEST_PATH_IMAGE002
wherein G(s) characterizes the ratio of the Laplace transform of the linear system response input and output at zero initial condition; t1 and T2 represent inertia time of the inertia link;
the inertia time T1 of the first-order inertia module (12) is 10 s-20 s; the inertia time T2 of the first-order inertia module (12) is 60 s-70 s;
the system also comprises a flying detection input switch (ON/OFF) AND a flying detection input confirmation module (AND);
the flying detection input switch (ON/OFF) is used for providing the working state of the flying detection system;
AND the flying detection input confirmation module (AND) is used for judging the validity of the flying detection result according to the flying detection result AND the working state of a flying detection input switch (ON/OFF).
2. A detection method of a limestone slurry pH value concentration fly-up detection system is based on the limestone slurry pH value concentration fly-up detection system of claim 1, and is characterized by comprising the following steps:
carrying out first filtering on the pH value measurement signal to obtain a first filtered value;
carrying out second filtering on the pH value measurement signal to obtain a second filtering value;
carrying out deviation processing on the first filtering value and the second filtering value to obtain a deviation value;
obtaining the change trend and the change quantity of the pH value according to the deviation value, carrying out threshold judgment on the change quantity, and outputting a fly-up detection result;
further comprising:
judging the validity of the fly-lift detection result according to the working state of the fly-lift detection system and the fly-lift detection result;
the validity means that when a flying lift detection switch (ON/OFF) is in a switching state and a high-low ALARM module (ALARM) outputs a flying lift detection result to be true, the output of a flying lift detection control system is true; otherwise, the signal for detecting the pH value is in a flying state, and the signal is distorted.
3. An automatic FGD desulfurization control system, which is characterized by comprising a pH value measuring system, a desulfurization control system and a limestone slurry pH value concentration fly-up detection system of claim 1;
the pH value measuring system is connected with the pH value measuring device and is used for obtaining a pH value measuring signal;
the limestone slurry pH value concentration fly-up detection system is used for judging whether a pH value measurement signal obtained by the pH value measurement device is in fly-up distortion or not;
the desulfurization control system is used for controlling SO according to the fly-up distortion result 2 The absorbent is controlled.
4. An FGD desulfurization system is characterized by comprising a boiler descending section heat exchanger (1), a denitration ammonia-spraying grid (2), a denitration reactor (3), an air preheater (4), an electric dust remover (5), a desulfurization absorption tower (6), a chimney (7), a limestone slurry circulating pump (9), a pH value measuring device (10), a limestone new slurry supplementing pipeline (11) and the FGD desulfurization automatic control system of claim 3;
flue gas combusted by the boiler flows through the boiler descending section heat exchanger (1) to reach the denitration ammonia injection grid (2), then is mixed with an injected ammonia-air mixture, enters the denitration reactor (3) for chemical reaction denitration, enters the air preheater (4) for recovering heat, passes through the electric dust collector (5) and the desulfurization absorption tower (6), and is discharged into the atmosphere through the chimney (7);
the limestone slurry circulating pump (9) is connected with spraying equipment in the limestone slurry supply desulfurization absorption tower (6); the pH value measuring device (10) is arranged in limestone slurry in the desulfurization absorption tower (6), and the pH value measuring device (10) is electrically connected with an FGD desulfurization automatic control system; the limestone new slurry supplementing pipeline (11) is communicated with the desulfurization absorption tower (6), and the FGD desulfurization automatic control system controls the on-off of the limestone new slurry supplementing pipeline (11).
5. A FGD desulfurization system according to claim 4, characterized in that the stack (7) is further provided with clean flue gas SO 2 A measuring device (8).
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