Active burnt clean system of large-scale thermal power generating unit flue gas
Technical Field
The utility model belongs to the technical field of thermal power unit flue gas pollutant desorption, a active burnt clean system of large-scale thermal power unit flue gas is related to.
Background
In the field of flue gas emission control of large-scale thermal power generating units, China currently executes the strictest ultra-low emission policy in the world and requires that the emission concentration of nitrogen oxide is less than 50mg/m3(Standard, dry, 6% O)2) The emission concentration of sulfur dioxide is less than 35mg/m3(Standard, dry, 6% O)2). At present, large-scale thermal power generating units at home and abroad generally adopt an SCR (selective catalytic reduction) or SNCR + SCR denitration process and a limestone-gypsum wet desulphurization process.
However, because of the limited natural environment of China, the amount of industry is huge, the work of preventing and controlling air pollution is still far in the way, and the research on the treatment technology of flue gas pollution is endless.
The SCR mainstream process scheme adopted by the existing denitration is that a denitration device is arranged behind an economizer and in front of an air preheater, so that the operation cost is high, and a large amount of ammonia or urea is consumed; the problems that the waste generated after the service life of the catalyst generates secondary pollution to the environment and the like are urgently needed to be solved; the denitration efficiency is difficult to break through the level of 94 percent, the full-load denitration requirement cannot be met, and the like, and the new requirement of people for improving the environment cannot be met technically.
The wet desulphurization process scheme adopted by the existing desulphurization needs to consume a very large amount of limestone; the utilization rate of the byproduct gypsum is lower and lower; the treatment difficulty and the cost of the desulfurization wastewater are very high; and the sulfur dioxide can not be completely removed.
In addition, the existing denitration and desulfurization processes are completely and independently designed, the synergistic removal efficiency is very low, and the removal efficiency of harmful substances such as sulfur trioxide and mercury in the flue gas is not high.
SUMMERY OF THE UTILITY MODEL
An object of the utility model is to overcome above-mentioned prior art's shortcoming, provide a large-scale thermal power generating unit flue gas active coke clean system, can carry out the desorption to all harmful substance in the flue gas, the desorption efficiency is high.
In order to achieve the above purpose, the utility model adopts the following technical scheme:
a flue gas active coke purification system of a large thermal power generating unit comprises a distributed low-temperature economizer, a chamber-divided low-temperature dust collector, a waste heat recoverer, a spray cooling tower, a multi-chamber fluidized bed desulfurization and dehumidification tower, a multi-chamber ultralow-temperature fluidized bed denitration tower, an economizer and a preheater;
the economizer is connected with an inlet of the preheater, an outlet of the preheater is communicated with an inlet of the distributed low-temperature economizer, an outlet of the distributed low-temperature economizer is respectively communicated with an inlet of the chamber-divided low-temperature dust remover, an outlet of the chamber-divided low-temperature dust remover is communicated with an inlet of the waste heat recoverer, an outlet of the waste heat recoverer is communicated with an inlet of the spray cooling tower, an outlet of the spray cooling tower is communicated with an inlet of the multi-chamber fluidized bed desulfurization and dehumidification tower through a direct flue, an outlet of the multi-chamber fluidized bed desulfurization and dehumidification tower is communicated with an inlet of the evaporative cooler, and an outlet of the evaporative cooler is communicated with an inlet of the multi-chamber ultralow-temperature fluidized bed denitration tower.
The utility model discloses further improvement lies in, the export of pre-heater collects the flue through high temperature and is linked together with the entry of distributing type low temperature economizer.
The utility model discloses further improvement lies in, and the export of locellus low temperature dust remover is linked together with waste heat recoverer's entry after gathering the flue.
The utility model discloses further improvement lies in, waste heat recoverer's export is linked together through the entry that communicates flue and spray cooling tower.
The utility model discloses further improvement lies in, still includes cold volume recoverer, draught fan and dry chimney, and the export of many minutes storehouse ultra-low temperature fluidized bed denitration towers is linked together through the entry of ultra-clean ultra-low temperature flue with cold volume recoverer, and the play and the draught fan entry of cold volume recoverer are linked together, and the draught fan export is through the entry intercommunication of ultra-clean flue with dry chimney.
The utility model discloses further improvement lies in, and the export of dividing storehouse fluidized bed desulfurization dehumidification tower more is linked together through the entry of clean flue and evaporative cooler, and evaporative cooler's export is linked together through the entry of clean flue of ultra-low temperature and dividing storehouse ultra-low temperature fluidized bed denitration tower more.
The utility model discloses further improvement lies in, divide storehouse fluidized bed desulfurization dehumidification tower more still be connected with first active burnt warehouse, divide storehouse ultra-low temperature fluidized bed denitration tower more still to be connected with the active burnt warehouse of second.
The utility model discloses a further improvement lies in, and the spray cooling tower is connected with the spray cooling circulating pump.
The utility model discloses further improvement lies in, evaporative cooler is connected with compressor and cold water machine.
Compared with the prior art, the utility model discloses following beneficial effect has:
the utility model discloses a denitration adsorption tower arrange high temperature, high dust region before air heater unlike traditional SCR denitrification facility, but arrange behind many minutes storehouse fluidized bed desulfurization dehumidification towers, do not have special requirement to the high temperature of flue gas temperature, thoroughly solved full load denitration difficult problem.
Further, the utility model discloses a two-stage divides storehouse fluidized bed desulfurization dehumidification tower more and divides storehouse ultra-low temperature fluidized bed denitration tower to deviate from the pollutant in grades, and it is high to deviate from efficiency, divides moreWhen the bin adsorption tower works in practice, one or more sub-bins of the bin adsorption tower are in an operation mode, the other sub-bins of the adsorption tower are in an analysis mode, and the adsorption tower and a matched sulfur-containing active coke analysis tower and a matched nitrate-containing active coke analysis tower work together to realize continuous desorption and analysis treatment of flue gas and realize SO2、SO3、NOxAnd resolving and recycling harmful substances such as Hg and dioxin generated in the mixed combustion of sludge, so as to realize resource utilization.
Active burnt clean system of large-scale thermal power generating unit flue gas when concrete operation, high temperature flue gas need not through SCR denitration reactor after the economizer in proper order, and directly get into the pre-heater, all environmental protection facility equipartitions are put after the pre-heater, need not to increase any equipment or carry out any transformation at the former economizer of unit to the flue of pre-heater department. The flue gas gets into locular low temperature dust remover behind low temperature economizer and removes dust, it further reduces the flue gas temperature to above zero below the ambient temperature to go into spray cooling tower after waste heat recoverer cooling again, sulfur dioxide in the flue gas simultaneously, sulfur trioxide carries out desorption in advance, later get into many minutes storehouse fluidized bed desulfurization dehumidification tower and adsorb the desulfurization, later get into in the evaporative cooler and cool down to below zero, it adsorbs the denitration to get into many minutes storehouse ultra-low temperature fluidized bed denitration tower again, simultaneously to remaining sulfur dioxide in the flue gas, sulfur trioxide, harmful substance such as mercury adsorbs the desorption. Because the flue gas temperature drops, the flue gas volume reduces by a wide margin for pollutant desorption equipment size reduces by a wide margin, and simultaneously, the flue gas temperature reduces to below the dew point of flue gas pollutant, and the pollutant is deviate from efficiency and is improved by a wide margin, can realize the target of harmful substance zero release such as nitrogen oxide, sulfur dioxide, sulfur trioxide and mercury in the flue gas, and the desorption is efficient, and area and investment cost are low more reasonable relatively. The utility model discloses a denitration adsorption tower arrange high temperature, high dust region before air heater unlike traditional SCR denitrification facility, but arrange behind many minutes storehouse fluidized bed desulfurization dehumidification towers, do not have special requirement to the high temperature of flue gas temperature, thoroughly solved full load denitration difficult problem.
Drawings
Fig. 1 is a schematic plan view of the present invention.
Fig. 2 is a side view development flow chart of the present invention.
The system comprises a distributed low-temperature coal economizer 1, a chambered low-temperature dust remover 2, a waste heat recoverer 3, a spray cooling tower 4, a multi-bin fluidized bed desulfurization and dehumidification tower 5, an evaporative cooler 6, a multi-bin ultralow-temperature fluidized bed denitration tower 7, a cold energy recoverer 8, an induced draft fan 9, a dry chimney 10, a high-temperature collecting flue 11, a collecting flue 12, a communicating flue 13, a through flue 14, a clean flue 15, a low-temperature clean flue 16, an ultra-clean ultralow-temperature flue 18, an ultra-clean flue 21, a coal economizer 22, a preheater 23, a first active coke storage bin 24, a second active coke storage bin 24, a sulfur-containing active coke analysis tower 25, a nitrate-containing active coke analysis tower 26, a spray cooling circulating pump 27, a refrigeration compressor 28 and a water chiller 29.
Detailed Description
The present invention will be described in further detail with reference to the accompanying drawings:
referring to fig. 1 and 2, the flue gas active coke purification system of the large thermal power generating unit of the present invention includes a distributed low-temperature economizer 1, a chambered low-temperature dust remover 2, a waste heat recoverer 3, and a spray cooling tower 4; the device comprises a multi-bin fluidized bed desulfurization and dehumidification tower 5, an evaporative cooler 6, a multi-bin ultralow-temperature fluidized bed denitration tower 7, a cold energy recoverer 8, an induced draft fan 9, a dry chimney 10, a high-temperature collection chimney 11, a collection chimney 12, a communication chimney 13, a straight-through chimney 14, a clean chimney 15, a low-temperature clean chimney 16, a super-clean ultralow-temperature chimney 17, a super-clean chimney 18, an economizer 21, a preheater 22, a first active coke storage bin 23, a second active coke storage bin 24, a sulfur-containing active coke desorption tower 25, a nitrate-containing active coke desorption tower 26, a spray cooling circulating pump 27, a refrigeration compressor 28 and a water chiller 29.
Wherein, the economizer 21 is connected with the inlet of the preheater 22, the outlet of the preheater 22 is communicated with the inlet of the distributed low-temperature economizer 1 through the high-temperature collecting flue 11, the outlet of the distributed low-temperature economizer 1 is respectively communicated with the inlet of the chamber-divided low-temperature dust remover 2, the outlet of the chamber-divided low-temperature dust remover 2 is communicated with the inlet of the waste heat recoverer 3 through the collecting flue 12, the outlet of the waste heat recoverer 3 is communicated with the inlet of the spray cooling tower 4 through the communicating flue 13, the outlet of the spray cooling tower 4 is communicated with the inlet of the multi-chamber fluidized bed desulfurization and dehumidification tower 5 through the direct flue 14, the outlet of the multi-chamber fluidized bed desulfurization and dehumidification tower 5 is communicated with the inlet of the evaporative cooler 6 through the clean flue 15, the outlet of the evaporative cooler 6 is communicated with the inlet of the multi-chamber ultra-low-temperature denitration tower 7 through the ultra-clean flue 16, the outlet of the multi-chamber ultra-low-temperature fluidized bed denitration tower, the outlet of the cold energy recoverer 8 is communicated with the inlet of an induced draft fan 9, and the outlet of the induced draft fan 9 is communicated with the inlet of a dry chimney 10 through an ultra-clean flue 18.
The first active coke storage bin 23, the second active coke storage bin 24, the sulfur-containing active coke desorption tower 25 and the nitrate-containing active coke desorption tower 26 which are matched with the multi-bin fluidized bed desulfurization and dehumidification tower 5 and the multi-bin ultralow-temperature fluidized bed denitration tower 7, a spray cooling circulating pump 27 matched with the spray cooling tower 4, a refrigeration compressor 28 and a water chiller 29 matched with the evaporative cooler 6. Namely, the multi-bin fluidized bed desulfurization and dehumidification tower 5 is connected with a first active coke storage bin 23, and the multi-bin ultralow temperature fluidized bed denitration tower 7 is connected with a second active coke storage bin 24; the spray cooling tower 4 is connected with a spray cooling circulation pump 27, and the evaporative cooler 6 is connected with a refrigeration compressor 28 and a water chiller 29.
The utility model discloses in the high temperature flue gas that comes out by the boiler passes through distributed low temperature economizer 1 back in proper order, need not through SCR denitration reactor and directly gets into air heater, all environmental protection facility equipartitions are put after pre-heater 22, need not to increase any equipment or carry out any transformation at the flue of former economizer 21 to pre-heater 22 department, and all environmental protection facility equipartitions are put after the pre-heater.
The multi-bin ultra-low temperature fluidized bed denitration tower 7 is arranged behind an air preheater of a thermal power generating unit and at the position of an ultra-low temperature clean flue 16.
The induced draft fan 9 is arranged behind the desulfurization facility and the denitration facility and in front of the chimney.
The flue gas of the thermal power generating unit is the ultra-clean emission of dry flue gas, and the anticorrosion modification treatment of a dry chimney is not needed.
The purification method of the utility model is as follows: flue gas of a large thermal power generating unit sequentially passes through an economizer 21 and a preheater 22 and then passes through a high-temperature collecting flue 11 to an inlet of a distributed low-temperature economizer 1, an outlet of the distributed low-temperature economizer 1 is respectively communicated with an inlet of a chamber low-temperature dust collector 2, the flue gas is dedusted in the chamber low-temperature dust collector 2, an outlet of the chamber low-temperature dust collector 2 is communicated with an inlet of a waste heat recoverer 3 through a collecting flue 12 and is cooled in the waste heat recoverer 3, an outlet of the waste heat recoverer 3 is communicated with an inlet of a spray cooling tower 4 through a communicating flue 13, the temperature is reduced to be below zero in the spray cooling tower 4, sulfur dioxide and sulfur trioxide in the flue gas are pre-removed, an outlet of the spray cooling tower 4 is communicated with an inlet of a multi-chamber fluidized bed desulfurization and dehumidification tower 5 through a flue through a direct connection 14, and desulfurization is absorbed in the multi-chamber fluidized bed desulfurization and dehumidification, the export of many minute storehouse fluidized bed desulfurization dehumidification towers 5 communicates through the entry of clean flue 15 with evaporative cooler 6, and the flue gas continues to cool down to below zero in evaporative cooler 6, and evaporative cooler 6's export is linked together through the entry of the clean flue 16 of ultra-low temperature and the many minute storehouse ultra-low temperature fluidized bed denitration tower 7 of ultra-low temperature, adsorbs the denitration in many minute storehouse ultra-low temperature fluidized bed denitration tower 7, adsorbs the desorption to remaining sulfur dioxide, sulfur trioxide, mercury in the flue gas simultaneously. The outlet of the multi-bin ultra-low temperature fluidized bed denitration tower 7 is communicated with the inlet of the cold energy recoverer 8 through the ultra-clean ultra-low temperature flue 17, the outlet of the cold energy recoverer 8 is communicated with the inlet of the induced draft fan 9, and the outlet of the induced draft fan 9 is communicated with the inlet of the dry chimney 10 through the ultra-clean flue 18.
The utility model discloses an active burnt clean system of large-scale thermal power unit flue gas need not to increase any equipment or carry out any transformation at the flue of former economizer 21 to air heater 22 department, and all environmental protection facilities equipartition are put after air heater 22.
The ultra-low temperature fluidized bed denitration tower 7 with multiple divided bins is arranged behind an air preheater of a thermal power generating unit, and the position of an ultra-low temperature clean flue 16 thoroughly solves the problems that the SCR denitration is easy to block ash, the denitration efficiency is low, and full-load denitration cannot be solved. The induced draft fan is arranged behind the desulfurization device and the denitrification device. The flue gas of the utility model is the ultra-clean emission of dry flue gas, and the corrosion prevention treatment of a dry chimney is not needed.
The utility model provides a brand-new flue gas pollutant treatment system of large-scale thermal power generating unit, area and investment are very reasonable, not only can desorption NO in the flue gas completelyxAnd SO2And can also completely remove SO3And HgAnd harmful substances such as dioxin and the like generated when the sludge is doped and burned, the removal efficiency is extremely high, and the complete removal of pollutants can be realized theoretically. The method is suitable for the design of an environmental protection island of a newly-built large thermal power generating unit and the upgrading and reconstruction of flue gas treatment, and has good scientific and technological value and economic and environmental benefits when being popularized in a large thermal power plant.
The utility model provides a brand-new flue gas pollutant treatment system of large-scale thermal power generating unit, area and investment are very reasonable, not only can desorption NO in the flue gas completelyxAnd SO2And can also completely remove SO3And HgAnd the removal efficiency is extremely high.
Above only for explaining the technical thought of the utility model, can not prescribe a limit to with this the utility model discloses a protection scope, the fan is according to the utility model provides a technical thought, any change of doing on technical scheme basis all fall into within the protection scope of the utility model.