CN111692524A - LNG regasification experimental system and experimental method - Google Patents
LNG regasification experimental system and experimental method Download PDFInfo
- Publication number
- CN111692524A CN111692524A CN202010562756.0A CN202010562756A CN111692524A CN 111692524 A CN111692524 A CN 111692524A CN 202010562756 A CN202010562756 A CN 202010562756A CN 111692524 A CN111692524 A CN 111692524A
- Authority
- CN
- China
- Prior art keywords
- lng
- propane
- liquid
- vaporizer
- vaporization
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Images
Classifications
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F17—STORING OR DISTRIBUTING GASES OR LIQUIDS
- F17C—VESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
- F17C9/00—Methods or apparatus for discharging liquefied or solidified gases from vessels not under pressure
- F17C9/02—Methods or apparatus for discharging liquefied or solidified gases from vessels not under pressure with change of state, e.g. vaporisation
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F17—STORING OR DISTRIBUTING GASES OR LIQUIDS
- F17C—VESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
- F17C13/00—Details of vessels or of the filling or discharging of vessels
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F17—STORING OR DISTRIBUTING GASES OR LIQUIDS
- F17C—VESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
- F17C13/00—Details of vessels or of the filling or discharging of vessels
- F17C13/04—Arrangement or mounting of valves
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F17—STORING OR DISTRIBUTING GASES OR LIQUIDS
- F17C—VESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
- F17C2205/00—Vessel construction, in particular mounting arrangements, attachments or identifications means
- F17C2205/03—Fluid connections, filters, valves, closure means or other attachments
- F17C2205/0302—Fittings, valves, filters, or components in connection with the gas storage device
- F17C2205/0323—Valves
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F17—STORING OR DISTRIBUTING GASES OR LIQUIDS
- F17C—VESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
- F17C2221/00—Handled fluid, in particular type of fluid
- F17C2221/03—Mixtures
- F17C2221/032—Hydrocarbons
- F17C2221/033—Methane, e.g. natural gas, CNG, LNG, GNL, GNC, PLNG
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F17—STORING OR DISTRIBUTING GASES OR LIQUIDS
- F17C—VESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
- F17C2223/00—Handled fluid before transfer, i.e. state of fluid when stored in the vessel or before transfer from the vessel
- F17C2223/01—Handled fluid before transfer, i.e. state of fluid when stored in the vessel or before transfer from the vessel characterised by the phase
- F17C2223/0146—Two-phase
- F17C2223/0153—Liquefied gas, e.g. LPG, GPL
- F17C2223/0161—Liquefied gas, e.g. LPG, GPL cryogenic, e.g. LNG, GNL, PLNG
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F17—STORING OR DISTRIBUTING GASES OR LIQUIDS
- F17C—VESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
- F17C2227/00—Transfer of fluids, i.e. method or means for transferring the fluid; Heat exchange with the fluid
- F17C2227/03—Heat exchange with the fluid
- F17C2227/0302—Heat exchange with the fluid by heating
- F17C2227/0304—Heat exchange with the fluid by heating using an electric heater
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F17—STORING OR DISTRIBUTING GASES OR LIQUIDS
- F17C—VESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
- F17C2227/00—Transfer of fluids, i.e. method or means for transferring the fluid; Heat exchange with the fluid
- F17C2227/03—Heat exchange with the fluid
- F17C2227/0302—Heat exchange with the fluid by heating
- F17C2227/0309—Heat exchange with the fluid by heating using another fluid
Landscapes
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- General Engineering & Computer Science (AREA)
- Filling Or Discharging Of Gas Storage Vessels (AREA)
Abstract
本发明涉及一种LNG再汽化实验系统,包括一LNG流通单元,所述LNG流通单元包括LNG液体罐、出液阀、柱塞式增压泵、稳压罐、微通道汽化器、背压阀、空温式再热器、排空管、三通阀Ⅰ、减压阀、储液罐;一丙烷循环单元,所述丙烷循环单元包括丙烷储液罐、丙烷循环泵、三通阀Ⅱ、浮动盘管式换热器、电加热器、进液阀、泄放阀;还涉及基于上述试验系统的试验方法,包括下述步骤:系统搭建、丙烷降温、LNG汽化、流量控制、LNG再热。本发明的优点在于:通过增加丙烷循环单元,避免了丙烷与LNG流体的直接换热,同时利用丙烷的相变换热释放大量潜热,有效降低微通道汽化器换热过程中结冰现象的发生,保证微通道汽化器高效运行。
The invention relates to an LNG re-vaporization experiment system, comprising an LNG circulation unit, wherein the LNG circulation unit comprises an LNG liquid tank, a liquid outlet valve, a plunger type booster pump, a pressure stabilization tank, a microchannel vaporizer, a back pressure valve, Air-temperature reheater, exhaust pipe, three-way valve I, pressure reducing valve, liquid storage tank; a propane circulation unit, the propane circulation unit includes a propane liquid storage tank, a propane circulation pump, three-way valve II, float A coil type heat exchanger, an electric heater, a liquid inlet valve, and a discharge valve; and a test method based on the above-mentioned test system, including the following steps: system construction, propane cooling, LNG vaporization, flow control, and LNG reheating. The advantages of the invention are: by adding a propane circulation unit, the direct heat exchange between propane and LNG fluid is avoided, and at the same time, a large amount of latent heat is released by using the phase change heat of propane, which effectively reduces the occurrence of icing during the heat exchange process of the microchannel vaporizer, Ensure efficient operation of microchannel vaporizers.
Description
技术领域technical field
本发明涉及一种LNG再汽化实验系统,还涉及上述实验系统的实验方法。The invention relates to an LNG re-vaporization experiment system, and also relates to an experiment method of the above-mentioned experiment system.
背景技术Background technique
深冷流体通常是指温度范围在-40 .15℃至-196 .15℃的流体。通常如LNG、液氧、液氢、液氮、液态二氧化碳等工业气体需要以液态形式储运,然后在终端进行再汽化使用。针对LNG再汽化,由于LNG体积仅为天然气(NG)体积的1/600 ,因此为满足储存和远距离运输要求NG通常需要先液化然后再汽化使用。但是LNG临界温度为-163℃,在汽化过程中易造成换热介质结冰或者汽化不完全的现象产生。Cryogenic fluids generally refer to fluids with a temperature range of -40.15°C to -196.15°C. Usually, industrial gases such as LNG, liquid oxygen, liquid hydrogen, liquid nitrogen, and liquid carbon dioxide need to be stored and transported in liquid form, and then re-vaporized at the terminal for use. For LNG re-vaporization, since the volume of LNG is only 1/600 of the volume of natural gas (NG), NG usually needs to be liquefied and then vaporized to meet the requirements of storage and long-distance transportation. However, the critical temperature of LNG is -163°C, which is easy to cause the phenomenon that the heat exchange medium freezes or the vaporization is incomplete during the vaporization process.
而采用中温介质回路的LNG流体再汽化系统避免了热源与LNG的直接换热,通过中温介质间接的将热源的热量传递给LNG,可以完全满足其再汽化的要求,易于根据工况的不同来控制汽化量的大小。The LNG fluid re-vaporization system using the medium-temperature medium circuit avoids the direct heat exchange between the heat source and the LNG. The heat of the heat source is indirectly transferred to the LNG through the medium-temperature medium, which can fully meet the requirements of its re-vaporization and is easy to use according to different working conditions. Controls the amount of vaporization.
申请号为201280010015 .5,名称为“ 液化汽体的再汽化装置及再汽化汽体制造方法”的发明专利,公开了一种将低温液化汽体再汽化的系统和方法。该系统中液化汽体首先流过预热用热交换器,与第一热交换器交换热量后再作为热源流入预热用热交换器与来流低温液化汽体换热,然后在进入第二热交换器再汽化使用。然而使用第一次升温后的液化汽体预热来流低温液化汽体并不能很明显的升高液化汽体的温度,由于管道中液化汽体的流量相同,升温后的液化汽体与低温液化汽体的换热仅通过温差传热,因此在一定程度上浪费了能源。此外在第一热交换器中低温液化汽体直接与水或海水换热避免不了结冰的问题,影响换热效果,从而整体上降低了系统的运行效率。The application number is 201280010015.5 and the invention patent titled "Liquid gas re-vaporization device and re-vaporization gas manufacturing method" discloses a system and method for re-vaporization of low-temperature liquefied gas. In this system, the liquefied gas first flows through the preheating heat exchanger, exchanges heat with the first heat exchanger, and then flows into the preheating heat exchanger as a heat source to exchange heat with the incoming low-temperature liquefied gas, and then enters the second heat exchanger. The heat exchanger is used for re-vaporization. However, using the preheated liquefied gas after the first heating to flow the low-temperature liquefied gas cannot significantly increase the temperature of the liquefied gas. The heat transfer of liquefied gas is only through temperature difference, so energy is wasted to a certain extent. In addition, in the first heat exchanger, the low-temperature liquefied gas directly exchanges heat with water or seawater to avoid the problem of freezing, which affects the heat exchange effect, thereby reducing the operating efficiency of the system as a whole.
申请号为201710014179 .X,名称为“ LNG再汽化系统”的发明专利,公开了一种LNG再汽化系统,该系统以海水作为热源,通过中间介质三次与海水换热,再将热量传递给LNG同时带动膨胀机发电,以达到发电和再汽化LNG的目的。然而该系统通过多次换热实现LNG再汽化,导致系统结构复杂,所需海水流量巨大,水泵能耗较高,此外海水温度四季发生变化,影响系统稳定运行。另外该系统的NG出口温度并不能达到使用要求,需要再次升温以满足使用需求。The application number is 201710014179.X, and the invention patent named "LNG re-vaporization system" discloses a LNG re-vaporization system, which uses seawater as a heat source, exchanges heat with seawater three times through an intermediate medium, and then transfers the heat to LNG At the same time, the expander is driven to generate electricity to achieve the purpose of generating electricity and re-vaporizing LNG. However, the system achieves LNG re-vaporization through multiple heat exchanges, resulting in a complex system structure, huge seawater flow required, and high water pump energy consumption. In addition, the NG outlet temperature of the system cannot meet the usage requirements, and it needs to be heated up again to meet the usage requirements.
申请号为201811354132.9,名称为“ 一种深冷超临界流体再气化实验系统及工作方法”的发明专利,公开了一种适合多种深冷超临界流体的再汽化系统,该系统以热水作为热源,通过中温介质与深冷超临界流体进行换热。结构上虽有所简化,但用热水流经浮动盘管式换热器时,易造成盘管内形成水垢进而影响换热效率,且盘管内的水垢较难清理,为后期工作带来很大困扰。The application number is 201811354132.9, and the invention patent titled "A cryogenic supercritical fluid regasification experimental system and working method" discloses a regasification system suitable for a variety of cryogenic supercritical fluids. The system uses hot water As a heat source, heat is exchanged with cryogenic supercritical fluid through a medium temperature medium. Although the structure is simplified, when hot water flows through the floating coil type heat exchanger, it is easy to cause scale to form in the coil and thus affect the heat exchange efficiency, and the scale in the coil is difficult to clean, which brings a lot to the later work. troubled.
发明内容SUMMARY OF THE INVENTION
本发明要解决的技术问题是提供一种结构简单、能够高效运行的LNG再汽化实验系统,以及基于上述LNG再汽化实验系统的试验方法。The technical problem to be solved by the present invention is to provide an LNG re-vaporization experimental system with a simple structure and efficient operation, and a test method based on the above-mentioned LNG re-vaporization experimental system.
为解决上述技术问题,本发明的技术方案为:一种LNG再汽化实验系统,其创新点在于:包括In order to solve the above-mentioned technical problems, the technical scheme of the present invention is as follows: an experimental system for LNG re-vaporization, the innovation of which is: comprising:
一LNG流通单元,所述LNG流通单元包括LNG液体罐、出液阀、柱塞式增压泵、稳压罐、微通道汽化器、背压阀、空温式再热器、排空管、三通阀Ⅰ、减压阀、储液罐,其中,LNG液体罐、出液阀、柱塞式增压泵、稳压罐、微通道汽化器、背压阀、空温式再热器、三通阀Ⅰ、减压阀、储液罐通过管道依次连接而成,三通阀Ⅰ的剩余一个出口与排空管相连;An LNG circulation unit, the LNG circulation unit includes an LNG liquid tank, a liquid outlet valve, a plunger booster pump, a pressure stabilization tank, a microchannel vaporizer, a back pressure valve, an air temperature reheater, an emptying pipe, three Through valve I, pressure reducing valve, liquid storage tank, among which, LNG liquid tank, liquid outlet valve, plunger type booster pump, pressure stabilizer tank, micro-channel vaporizer, back pressure valve, air temperature reheater, three-way The valve I, the pressure reducing valve and the liquid storage tank are connected in sequence through pipelines, and the remaining outlet of the three-way valve I is connected with the emptying pipe;
一丙烷循环单元,所述丙烷循环单元包括丙烷储液罐、丙烷循环泵、三通阀Ⅱ、浮动盘管式换热器、电加热器、进液阀、泄放阀,其中,丙烷储液罐、丙烷循环泵、三通阀Ⅱ、浮动盘管式换热器依次通过管道连接而成,且丙烷储液罐的进口与微通道汽化器的出口相连,浮动盘管式换热器的出口与微通道汽化器的进口相连,三通阀Ⅱ的剩余一个出口通过管道连接在丙烷储液罐与微通道汽化器连接的管道上,进液阀、电加热器、泄放阀均安装在浮动盘管式换热器上。A propane circulation unit, the propane circulation unit includes a propane liquid storage tank, a propane circulation pump, a three-way valve II, a floating coil type heat exchanger, an electric heater, a liquid inlet valve, and a discharge valve, wherein the propane liquid storage tank The tank, the propane circulating pump, the three-way valve II, and the floating coil type heat exchanger are connected by pipelines in sequence, and the inlet of the propane liquid storage tank is connected with the outlet of the microchannel vaporizer, and the outlet of the floating coil type heat exchanger is connected to the outlet of the microchannel vaporizer. The inlet of the micro-channel vaporizer is connected, and the remaining outlet of the three-way valve II is connected to the pipeline connecting the propane liquid storage tank and the micro-channel vaporizer through a pipeline. on the heat exchanger.
进一步的,所述微通道汽化器包括一汽化器芯体,该汽化器芯体为一空心长方体结构,在汽化器芯体的内腔中安装有LNG流道组与丙烷流道组,所述LNG流道组与丙烷流道组均有若干组,自上而下分布在汽化器芯体内,且LNG流道组与丙烷流道组依次间隔排布,所述LNG流道组由若干沿着汽化器芯体幅宽方向水平排布的LNG流道组成,且LNG流道沿着汽化器芯体的长轴方向延伸,所述丙烷流道组由若干沿着汽化器芯体长轴方向水平排布的丙烷流道组成,且丙烷流道沿着汽化器芯体的幅宽方向延伸,在汽化器芯体长轴方向的两侧分别具有与各个LNG流道的同一侧端连接的一LNG进液腔、一LNG出液腔,在汽化器芯体幅宽方向的两侧分别具有与各个丙烷流道的同一侧端连通的一丙烷进液腔、一丙烷出液腔,在丙烷进液腔中还设置有导流板。Further, the micro-channel vaporizer includes a vaporizer core body, the vaporizer core body is a hollow cuboid structure, and an LNG flow channel group and a propane flow channel group are installed in the inner cavity of the vaporizer core body, and the LNG flow channel group is installed. The propane flow channel group and the propane flow channel group have several groups, which are distributed in the vaporizer core from top to bottom, and the LNG flow channel group and the propane flow channel group are arranged at intervals in turn. The LNG flow channels are arranged horizontally in the direction, and the LNG flow channels extend along the long axis direction of the vaporizer core. The propane flow channel group is composed of several propane flow channels horizontally arranged along the long axis direction of the vaporizer core. And the propane flow channel extends along the width direction of the vaporizer core body, and there are an LNG liquid inlet cavity and an LNG liquid liquid outlet cavity connected to the same side end of each LNG flow channel on both sides of the long axis direction of the vaporizer core body, respectively. There are a propane liquid inlet cavity and a propane liquid outlet cavity connected to the same side end of each propane flow channel on both sides in the width direction of the core body of the vaporizer, and a flow guide plate is also arranged in the propane liquid inlet cavity.
进一步的,所述微通道汽化器为基于3D打印技术制造的紧凑高效微通道汽化器。Further, the microchannel vaporizer is a compact and efficient microchannel vaporizer manufactured based on 3D printing technology.
进一步的,所述LNG储液罐的高度高于柱塞式增压泵的高度。Further, the height of the LNG liquid storage tank is higher than that of the plunger type booster pump.
进一步的,所述泄放阀设置在浮动盘管式换热器的最低点处。Further, the relief valve is arranged at the lowest point of the floating coil heat exchanger.
一种LNG再汽化的试验方法,其创新点在于:包括下述步骤A test method for LNG re-vaporization, the innovation of which is: comprising the following steps
S1 系统搭建:通过管路将构成LNG流通单元的各个组件以及构成丙烷循环单元的各个组件连接在一起,并将LNG流通单元与丙烷循环单元连接在一起,形成LNG再汽化实验系统;S1 system construction: connect the components that constitute the LNG circulation unit and the components that constitute the propane circulation unit through pipelines, and connect the LNG circulation unit and the propane circulation unit together to form an LNG re-vaporization experimental system;
S2 丙烷降温:首先,向浮动盘管式换热器内注入冷水,再利用电加热器对浮动盘管式换热器内的冷水进行加热,然后,丙烷储液罐内的液态丙烷经过丙烷循环泵升高压力,使得压力达到0.36MPa,再经过三通阀Ⅱ送入浮动盘管式换热器中,与浮动盘管式换热器中的热水进行换热汽化,使得流入微通道汽化器中的气态丙烷达到0℃,送入微通道汽化器内以备用;S2 propane cooling: First, inject cold water into the floating coil heat exchanger, and then use the electric heater to heat the cold water in the floating coil heat exchanger, and then, the liquid propane in the propane storage tank is circulated through the propane The pump increases the pressure so that the pressure reaches 0.36MPa, and then it is sent to the floating coil type heat exchanger through the three-way valve II, and the hot water in the floating coil type heat exchanger is heated and vaporized, so that it flows into the microchannel vaporizer. The gaseous propane in the gas reaches 0 °C and is sent to the microchannel vaporizer for standby;
S3 LNG汽化:开启LNG出液阀,LNG储液罐中的低温低压的LNG液体经过柱塞式增压泵加压至13MPa,再经过稳压罐进行稳压,稳定压力后,液态的LNG流入微通道汽化器内,液态的LNG进入微通道汽化器的温度为-157℃,液态的LNG与0℃的气态丙烷进行换热,使得液态的LNG升温汽化后,从微通道汽化器内流出,流出的气态的LNG的温度为-10℃,换热后的丙烷的温度降至-5℃,再将降温后的丙烷送至丙烷储液罐中进行循环使用;S3 LNG vaporization: open the LNG outlet valve, the low-temperature and low-pressure LNG liquid in the LNG storage tank is pressurized to 13MPa by the plunger type booster pump, and then stabilized by the pressure-stabilizing tank. After the pressure is stabilized, the liquid LNG flows into In the microchannel vaporizer, the temperature of liquid LNG entering the microchannel vaporizer is -157°C, and the liquid LNG exchanges heat with gaseous propane at 0°C, so that after the liquid LNG is heated and vaporized, it flows out from the microchannel vaporizer, and the outflowing gaseous The temperature of the LNG is -10 °C, the temperature of the propane after heat exchange is reduced to -5 °C, and then the cooled propane is sent to the propane liquid storage tank for recycling;
S4 流量控制:在进行LNG汽化的过程中,通过调节三通阀Ⅱ的开度来控制与液态LNG换热的丙烷的量来匹配LNG不同汽化量的要求,用0和1表示三通阀Ⅱ的开度状态,当三通阀Ⅱ的开度为0时,表示三通阀Ⅱ与微通道汽化器相连的管道处于关闭状态,与丙烷储液罐相连的管道处于全开状态,当三通阀Ⅱ的开度为1时,表示三通阀Ⅱ与微通道汽化器相连的管道处于全开状态,与丙烷储液罐相连的管道处于关闭状态,当三通阀Ⅱ的开度为0时,LNG的汽化量为0kg/s,当三通阀Ⅱ的开度为1时,此时LNG的汽化量为0.3kg/s,S4 Flow control: In the process of LNG vaporization, the amount of propane exchanged with liquid LNG is controlled by adjusting the opening of the three-way valve II to match the requirements of different vaporization amounts of LNG, and 0 and 1 are used to represent the three-way valve II. When the opening of the three-way valve II is 0, it means that the pipeline connecting the three-way valve II and the micro-channel vaporizer is in a closed state, and the pipeline connected to the propane liquid storage tank is in a fully open state. When the opening degree of II is 1, it means that the pipeline connecting the three-way valve II and the micro-channel vaporizer is in a fully open state, and the pipeline connected to the propane liquid storage tank is in a closed state. When the opening degree of the three-way valve II is 0, the LNG The vaporization rate of LNG is 0kg/s. When the opening of the three-way valve II is 1, the vaporization rate of LNG is 0.3kg/s.
当LNG汽化量较小时,调节三通阀Ⅱ,使流入浮动盘管式换热器的丙烷流量减小,增大流入丙烷储液器的丙烷流量;当LNG汽化量较大时,调节方法相反,使流入浮动盘管式换热器的丙烷流量增大,流入丙烷储液器的丙烷流量减小,从而满足不同的LNG汽化量的需要;When the amount of LNG vaporization is small, adjust the three-way valve II to reduce the flow of propane flowing into the floating coil heat exchanger and increase the flow of propane flowing into the propane accumulator; when the amount of vaporization of LNG is large, the adjustment method is opposite , so that the flow of propane flowing into the floating coil heat exchanger is increased, and the flow of propane flowing into the propane accumulator is reduced, so as to meet the needs of different LNG vaporization volumes;
S5 LNG再热:汽化后的LNG送入空温式再热器中进行再次升温至5℃,升温后的气态LNG再送入储液罐中,完成LNG的再汽化。S5 LNG reheating: The vaporized LNG is sent to the air-temperature reheater for reheating to 5°C, and the heated gaseous LNG is sent to the liquid storage tank to complete the re-vaporization of LNG.
进一步的,所述S5中,在气态LNG送入空温式再热器的过程中,利用背压阀自带的内置弹簧来进行压力调整,当微通道汽化器与空温式再热器之间的管道内的压力比设定压力小时,背压阀的膜片在弹簧弹力的作用下,堵塞管路,形成憋压,使空温式再热器的进口压力达到设定压力;当管道内的压力比设定压力大时,膜片压缩弹簧,管路接通,以此稳定微通道汽化器的出口压力。Further, in the S5, in the process of feeding the gaseous LNG into the air-temperature reheater, the pressure is adjusted by using the built-in spring that comes with the back pressure valve. When the pressure in the pipeline is smaller than the set pressure, the diaphragm of the back pressure valve blocks the pipeline under the action of the spring force, forming a pressure hold, so that the inlet pressure of the air temperature reheater reaches the set pressure; When the pressure is greater than the set pressure, the diaphragm compresses the spring and the pipeline is connected to stabilize the outlet pressure of the microchannel vaporizer.
进一步的,所述S5中,当气态LNG的汽化量较大时,空温式再热器中的气态LNG直接通过排空管进入排空系统进行排空。Further, in the S5, when the vaporized amount of the gaseous LNG is large, the gaseous LNG in the air-temperature reheater directly enters the evacuation system through the evacuation pipe for evacuation.
本发明的优点在于:在本发明中,通过增加丙烷循环单元,避免了丙烷与LNG流体的直接换热,同时利用丙烷的相变换热释放大量潜热,有效降低微通道汽化器换热过程中结冰现象的发生,保证微通道汽化器高效运行。The advantages of the present invention are: in the present invention, by adding a propane circulation unit, the direct heat exchange between propane and LNG fluid is avoided, and at the same time, a large amount of latent heat is released by using the phase change heat of propane, which effectively reduces the junction in the heat exchange process of the microchannel vaporizer. The occurrence of ice phenomenon ensures the efficient operation of the microchannel vaporizer.
鉴于丙烷循环系统易于调节丙烷的流量,因此便于根据LNG实际汽化要求进行快速匹配,来达到所需工况下的最佳换热效果。In view of the fact that the propane circulation system is easy to adjust the flow of propane, it is convenient to quickly match according to the actual vaporization requirements of LNG to achieve the best heat exchange effect under the required working conditions.
通过采用基于3D打印技术制造的微通道汽化器,与传统汽化器相比,大大提高再汽化效率的同时,有效减小了汽化器的体积尺寸,较大程度上缩减了再汽化系统的整体占地面积,以满足有限空间的再汽化需求,此外,采用基于3D打印技术制造的微通道汽化器易于系统模块化组装。By using the micro-channel vaporizer manufactured based on 3D printing technology, compared with the traditional vaporizer, the re-vaporization efficiency is greatly improved, while the volume size of the vaporizer is effectively reduced, and the overall footprint of the re-vaporization system is greatly reduced. In order to meet the re-vaporization needs of limited space, in addition, the micro-channel vaporizer manufactured based on 3D printing technology is easy to system modular assembly.
通过控制电加热器和丙烷循环系统中三通阀换向口的开度,可以快速调整并匹配汽化量的需求。By controlling the opening of the reversing port of the three-way valve in the electric heater and propane circulation system, it can quickly adjust and match the demand of the vaporization amount.
由于本系统所有设备通过焊接或者法兰连接的形式,使用不锈钢管连接,因此可以满足系统内部高压的要求,同时可根据现场情况灵活安装。Since all the equipments in this system are connected by welding or flanges and are connected by stainless steel pipes, it can meet the requirements of high pressure inside the system, and can be installed flexibly according to the site conditions.
由于丙烷循环系统中采用浮动盘管式换热器,并使热水在盘管外与管内的丙烷进行换热,有效减小了管内水垢的形成,提高了换热效率并便于后期系统的维护。Because the floating coil type heat exchanger is used in the propane circulation system, the hot water is exchanged with the propane in the pipe outside the coil, which effectively reduces the formation of scale in the pipe, improves the heat exchange efficiency and facilitates the maintenance of the system in the later stage. .
由于本发明解决了LNG再汽化系统的技术问题,所以本发明具有实际的工程意义,可供相关工程人员参考。Since the present invention solves the technical problem of the LNG re-vaporization system, the present invention has practical engineering significance and can be referenced by relevant engineering personnel.
附图说明Description of drawings
下面结合附图和具体实施方式对本发明作进一步详细的说明。The present invention will be described in further detail below with reference to the accompanying drawings and specific embodiments.
图1为本发明的LNG再汽化实验系统的示意图。FIG. 1 is a schematic diagram of the LNG regasification experimental system of the present invention.
图2为本发明中微通道汽化器的正视图。Figure 2 is a front view of the microchannel vaporizer in the present invention.
图3为本发明中微通道汽化器的侧视图。Figure 3 is a side view of the microchannel vaporizer of the present invention.
具体实施方式Detailed ways
下面的实施例可以使本专业的技术人员更全面地理解本发明,但并不因此将本发明限制在所述的实施例范围之中。The following embodiments can make those skilled in the art understand the present invention more comprehensively, but do not limit the present invention to the scope of the described embodiments.
如图1-图3所示的一种LNG再汽化实验系统,包括An LNG regasification experimental system as shown in Figures 1-3, including
一LNG流通单元,LNG流通单元包括LNG液体罐1、出液阀2、柱塞式增压泵3、稳压罐4、微通道汽化器5、背压阀6、空温式再热器14、排空管16、三通阀Ⅰ15、减压阀17、储液罐18,其中,LNG液体罐1、出液阀2、柱塞式增压泵3、稳压罐4、微通道汽化器5、背压阀6、空温式再热器14、三通阀Ⅰ15、减压阀17、储液罐18通过管道依次连接而成,三通阀Ⅰ15的剩余一个出口与排空管16相连。An LNG circulation unit, the LNG circulation unit includes an LNG liquid tank 1, a liquid outlet valve 2, a plunger booster pump 3, a pressure stabilization tank 4, a microchannel vaporizer 5, a back pressure valve 6, an
LNG储液罐1的高度高于柱塞式增压泵3的高度。LNG储液罐1放置在高位,保证进入柱塞式增压泵3的LNG一直处于液态且不出现气泡,使LNG增压到所需压力。The height of the LNG storage tank 1 is higher than that of the plunger type booster pump 3 . The LNG storage tank 1 is placed at a high position to ensure that the LNG entering the plunger booster pump 3 is always in a liquid state without bubbles, so that the LNG is pressurized to the required pressure.
微通道汽化器5为基于3D打印技术制造的紧凑高效微通道汽化器。通过采用基于3D打印技术制造的微通道汽化器5,与传统汽化器相比,大大提高再汽化效率的同时,有效减小了汽化器的体积尺寸,较大程度上缩减了再汽化系统的整体占地面积,以满足有限空间的再汽化需求,此外,采用基于3D打印技术制造的微通道汽化器易于系统模块化组装。Microchannel vaporizer 5 is a compact and efficient microchannel vaporizer manufactured based on 3D printing technology. By using the micro-channel vaporizer 5 manufactured based on 3D printing technology, compared with the traditional vaporizer, the re-vaporization efficiency is greatly improved, while the volume size of the vaporizer is effectively reduced, and the overall footprint of the re-vaporization system is greatly reduced. , to meet the re-vaporization needs of limited space, in addition, the micro-channel vaporizer manufactured based on 3D printing technology is easy to system modular assembly.
如图2、图3所示的示意图可知,微通道汽化器5包括一汽化器芯体51,该汽化器芯体51为一空心长方体结构,在汽化器芯体51的内腔中安装有LNG流道组与丙烷流道组,LNG流道组与丙烷流道组均有若干组,自上而下分布在汽化器芯体51内,且LNG流道组与丙烷流道组呈交错流的形式依次间隔排布,LNG流道组由若干沿着汽化器芯体51幅宽方向水平排布的LNG流道52组成,且LNG流道52沿着汽化器芯体51的长轴方向延伸,丙烷流道组由若干沿着汽化器芯体长轴方向水平排布的丙烷流道53组成,且丙烷流道53沿着汽化器芯体51的幅宽方向延伸,在汽化器芯体51长轴方向的两侧分别具有与各个LNG流道52的同一侧端连接的一LNG进液腔54、一LNG出液腔,在汽化器芯体51幅宽方向的两侧分别具有与各个丙烷流道53的同一侧端连通的一丙烷进液腔、一丙烷出液腔,在丙烷进液腔中还设置有导流板,从而使得丙烷均匀流入丙烷流道中。As can be seen from the schematic diagrams shown in FIGS. 2 and 3 , the microchannel vaporizer 5 includes a
一丙烷循环单元,丙烷循环单元包括丙烷储液罐7、丙烷循环泵8、三通阀Ⅱ9、浮动盘管式换热器10、电加热器11、进液阀12、泄放阀13,其中,丙烷储液罐7、丙烷循环泵8、三通阀Ⅱ9、浮动盘管式换热器10依次通过管道连接而成,且丙烷储液罐7的进口与微通道汽化器5的出口相连,浮动盘管式换热器10的出口与微通道汽化器5的进口相连,三通阀Ⅱ9的剩余一个出口通过管道连接在丙烷储液罐7与微通道汽化器5连接的管道上,进液阀12、电加热器11、泄放阀13均安装在浮动盘管式换热器10上。A propane circulation unit, the propane circulation unit includes a propane liquid storage tank 7, a propane circulation pump 8, a three-way valve II 9, a floating coil heat exchanger 10, an
泄放阀13设置在浮动盘管式换热器10的最低点处。泄放阀13设在浮动盘管式换热器10的最低点处,以防水中杂质的堆积,影响系统的稳定运行。The relief valve 13 is provided at the lowest point of the floating coil heat exchanger 10 . The relief valve 13 is arranged at the lowest point of the floating coil type heat exchanger 10 to prevent the accumulation of impurities in the water and affect the stable operation of the system.
基于上述的LNG再汽化试验系统的LNG再汽化的试验方法,通过下述步骤得以实现:The test method for LNG re-vaporization based on the above-mentioned LNG re-vaporization test system is achieved through the following steps:
S1 系统搭建:通过管路将构成LNG流通单元的各个组件以及构成丙烷循环单元的各个组件连接在一起,并将LNG流通单元与丙烷循环单元连接在一起,形成LNG再汽化实验系统。S1 System construction: Connect the components that constitute the LNG circulation unit and the components that constitute the propane circulation unit through pipelines, and connect the LNG circulation unit to the propane circulation unit to form an LNG re-vaporization experimental system.
S2 丙烷降温:首先,向浮动盘管式换热器内注入冷水,再利用电加热器对浮动盘管式换热器内的冷水进行加热,然后,丙烷储液罐内的液态丙烷经过丙烷循环泵升高压力至0.36MPa,再经过三通阀Ⅱ送入浮动盘管式换热器中,与浮动盘管式换热器中的热水进行换热汽化,使得流入微通道汽化器中的气态丙烷达到0℃,送入微通道汽化器内以备用。S2 propane cooling: First, inject cold water into the floating coil heat exchanger, and then use the electric heater to heat the cold water in the floating coil heat exchanger, and then, the liquid propane in the propane storage tank is circulated through the propane The pump increases the pressure to 0.36MPa, and then sends it into the floating coil heat exchanger through the three-way valve II, and conducts heat exchange and vaporization with the hot water in the floating coil heat exchanger, so that the gaseous gas flowing into the microchannel vaporizer The propane reaches 0°C and is sent to the microchannel vaporizer for use.
S3 LNG汽化:开启LNG出液阀,LNG储液罐中的低温低压的LNG液体经过柱塞式增压泵加压至13MPa左右,再经过稳压罐进行稳压,稳定压力后,液态的LNG流入微通道汽化器内,液态的LNG进入微通道汽化器的温度为-157℃,液态的LNG与0℃的气态丙烷进行换热,使得液态的LNG升温汽化后,从微通道汽化器内流出,流出的气态的LNG的温度为-10℃,换热后的丙烷的温度降至-5℃,再将降温后的丙烷送至丙烷储液罐中进行循环使用;S3 LNG vaporization: Open the LNG outlet valve, the low-temperature and low-pressure LNG liquid in the LNG storage tank is pressurized to about 13MPa by the plunger type booster pump, and then stabilized by the pressure-stabilizing tank. After the pressure is stabilized, the liquid LNG Flowing into the microchannel vaporizer, the temperature of liquid LNG entering the microchannel vaporizer is -157°C, and the liquid LNG exchanges heat with gaseous propane at 0°C, so that the liquid LNG heats up and vaporizes, and flows out from the microchannel vaporizer. The temperature of the gaseous LNG is -10°C, the temperature of the propane after heat exchange is reduced to -5°C, and then the cooled propane is sent to the propane liquid storage tank for recycling;
S4 流量控制:在进行LNG汽化的过程中,通过调节三通阀Ⅱ的开度来控制与液态LNG换热的丙烷的量来匹配LNG不同汽化量的要求,用0和1表示三通阀Ⅱ的开度状态,当三通阀Ⅱ的开度为0时,表示三通阀Ⅱ与微通道汽化器相连的管道处于关闭状态,与丙烷储液罐相连的管道处于全开状态,当三通阀Ⅱ的开度为1时,表示三通阀Ⅱ与微通道汽化器相连的管道处于全开状态,与丙烷储液罐相连的管道处于关闭状态,当三通阀Ⅱ的开度为0时,LNG的汽化量为0kg/s,当三通阀Ⅱ的开度为1时,此时LNG的汽化量为0.3kg/s。S4 Flow control: In the process of LNG vaporization, the amount of propane exchanged with liquid LNG is controlled by adjusting the opening of the three-way valve II to match the requirements of different vaporization amounts of LNG, and 0 and 1 are used to represent the three-way valve II. When the opening of the three-way valve II is 0, it means that the pipeline connecting the three-way valve II and the micro-channel vaporizer is in a closed state, and the pipeline connected to the propane liquid storage tank is in a fully open state. When the opening degree of II is 1, it means that the pipeline connecting the three-way valve II and the micro-channel vaporizer is in a fully open state, and the pipeline connected to the propane liquid storage tank is in a closed state. When the opening degree of the three-way valve II is 0, the LNG The vaporization rate of LNG is 0kg/s. When the opening of the three-way valve II is 1, the vaporization rate of LNG is 0.3kg/s.
当LNG汽化量较小时,调节三通阀Ⅱ,使流入浮动盘管式换热器的丙烷流量减小,增大流入丙烷储液器的丙烷流量;当LNG汽化量较大时,调节方法相反,使流入浮动盘管式换热器的丙烷流量增大,流入丙烷储液器的丙烷流量减小,从而满足不同的LNG汽化量的需要。When the amount of LNG vaporization is small, adjust the three-way valve II to reduce the flow of propane flowing into the floating coil heat exchanger and increase the flow of propane flowing into the propane accumulator; when the amount of vaporization of LNG is large, the adjustment method is opposite , so that the flow of propane flowing into the floating coil heat exchanger is increased, and the flow of propane flowing into the propane accumulator is reduced, so as to meet the needs of different LNG vaporization volumes.
S5 LNG再热:汽化后的LNG送入空温式再热器中进行再次升温至5℃左右,升温后的气态LNG再送入储液罐中,完成LNG的再汽化。S5 LNG reheating: The vaporized LNG is sent to the air-temperature reheater for reheating to about 5°C, and the heated gaseous LNG is sent to the liquid storage tank to complete the re-vaporization of LNG.
在气态LNG送入空温式再热器的过程中,利用背压阀自带的内置弹簧来进行压力调整,当微通道汽化器与空温式再热器之间的管道内的压力比设定压力小时,背压阀的膜片在弹簧弹力的作用下,堵塞管路,形成憋压,使空温式再热器的进口压力达到设定压力;当管道内的压力比设定压力大时,膜片压缩弹簧,管路接通,以此稳定微通道汽化器的出口压力。In the process of feeding gaseous LNG into the air-temperature reheater, the built-in spring of the back pressure valve is used to adjust the pressure. When the pressure ratio in the pipeline between the micro-channel vaporizer and the air-temperature reheater is set When the pressure is small, the diaphragm of the back pressure valve blocks the pipeline under the action of the elastic force of the spring, forming a pressure hold, so that the inlet pressure of the air temperature reheater reaches the set pressure; when the pressure in the pipeline is greater than the set pressure , the diaphragm compresses the spring, and the pipeline is connected to stabilize the outlet pressure of the microchannel vaporizer.
当气态LNG的汽化量较大时,空温式再热器中的气态LNG直接通过排空管进入排空系统进行排空。When the vaporized amount of gaseous LNG is large, the gaseous LNG in the air-temperature reheater directly enters the evacuation system through the evacuation pipe for evacuation.
本行业的技术人员应该了解,本发明不受上述实施例的限制,上述实施例和说明书中描述的只是说明本发明的原理,在不脱离本发明精神和范围的前提下,本发明还会有各种变化和改进,这些变化和改进都落入要求保护的本发明范围内。本发明要求保护范围由所附的权利要求书及其等效物界定。Those skilled in the art should understand that the present invention is not limited by the above-mentioned embodiments, and the descriptions in the above-mentioned embodiments and the description are only to illustrate the principle of the present invention. Without departing from the spirit and scope of the present invention, the present invention will have Various changes and modifications fall within the scope of the claimed invention. The claimed scope of the present invention is defined by the appended claims and their equivalents.
Claims (8)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN202010562756.0A CN111692524A (en) | 2020-06-19 | 2020-06-19 | LNG regasification experimental system and experimental method |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN202010562756.0A CN111692524A (en) | 2020-06-19 | 2020-06-19 | LNG regasification experimental system and experimental method |
Publications (1)
Publication Number | Publication Date |
---|---|
CN111692524A true CN111692524A (en) | 2020-09-22 |
Family
ID=72481869
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN202010562756.0A Pending CN111692524A (en) | 2020-06-19 | 2020-06-19 | LNG regasification experimental system and experimental method |
Country Status (1)
Country | Link |
---|---|
CN (1) | CN111692524A (en) |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN114112463A (en) * | 2021-11-12 | 2022-03-01 | 沪东中华造船(集团)有限公司 | Novel installation and debugging method for compact efficient heat exchanger |
CN115382585A (en) * | 2022-08-30 | 2022-11-25 | 合肥通用机械研究院有限公司 | Low-temperature vacuum composite experimental device |
CN118167923A (en) * | 2024-05-14 | 2024-06-11 | 浙江浙能航天氢能技术有限公司 | Air temperature type vaporizer with defrosting function |
Citations (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS5875691A (en) * | 1981-10-29 | 1983-05-07 | Toagosei Chem Ind Co Ltd | Heat-exchanging method |
US20040065085A1 (en) * | 2002-10-04 | 2004-04-08 | Madsen Per Helge | Regasification system and method |
CN103764986A (en) * | 2012-05-14 | 2014-04-30 | 现代重工业株式会社 | Method and system for treating liquefied gas |
CN106402650A (en) * | 2016-11-14 | 2017-02-15 | 航天晨光股份有限公司 | Air-temperature type combined LNG gasification system and gasification method |
CN207407068U (en) * | 2017-10-24 | 2018-05-25 | 辰一(上海)石油天然气工程技术有限公司 | A kind of LNG gasification system |
CN109357159A (en) * | 2018-11-14 | 2019-02-19 | 江苏科技大学 | A cryogenic supercritical fluid regasification experimental system and working method |
CN109630877A (en) * | 2018-11-14 | 2019-04-16 | 江苏科技大学 | A kind of LNG regas system and working method |
-
2020
- 2020-06-19 CN CN202010562756.0A patent/CN111692524A/en active Pending
Patent Citations (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS5875691A (en) * | 1981-10-29 | 1983-05-07 | Toagosei Chem Ind Co Ltd | Heat-exchanging method |
US20040065085A1 (en) * | 2002-10-04 | 2004-04-08 | Madsen Per Helge | Regasification system and method |
CN103764986A (en) * | 2012-05-14 | 2014-04-30 | 现代重工业株式会社 | Method and system for treating liquefied gas |
CN106402650A (en) * | 2016-11-14 | 2017-02-15 | 航天晨光股份有限公司 | Air-temperature type combined LNG gasification system and gasification method |
CN207407068U (en) * | 2017-10-24 | 2018-05-25 | 辰一(上海)石油天然气工程技术有限公司 | A kind of LNG gasification system |
CN109357159A (en) * | 2018-11-14 | 2019-02-19 | 江苏科技大学 | A cryogenic supercritical fluid regasification experimental system and working method |
CN109630877A (en) * | 2018-11-14 | 2019-04-16 | 江苏科技大学 | A kind of LNG regas system and working method |
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN114112463A (en) * | 2021-11-12 | 2022-03-01 | 沪东中华造船(集团)有限公司 | Novel installation and debugging method for compact efficient heat exchanger |
CN115382585A (en) * | 2022-08-30 | 2022-11-25 | 合肥通用机械研究院有限公司 | Low-temperature vacuum composite experimental device |
CN115382585B (en) * | 2022-08-30 | 2023-10-24 | 合肥通用机械研究院有限公司 | Low-temperature vacuum composite experimental device |
CN118167923A (en) * | 2024-05-14 | 2024-06-11 | 浙江浙能航天氢能技术有限公司 | Air temperature type vaporizer with defrosting function |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
CN111692524A (en) | LNG regasification experimental system and experimental method | |
CN103328877B (en) | Apparatus for pressurizing delivery of low-temperature liquefied material | |
CN109357159B (en) | A cryogenic supercritical fluid regasification experimental system and working method | |
CN216480236U (en) | Hydrogen cooling system of hydrogenation and liquefied natural gas combined station | |
CN104832232A (en) | Gradient heat exchange organic Rankine cycle power generation system and power generation method thereof | |
US3726101A (en) | Method of continuously vaporizing and superheating liquefied cryogenic fluid | |
WO2019205509A1 (en) | Integral intermediate medium vaporiser with lng cold energy utilisation function, and power-generating system | |
KR101405271B1 (en) | Instant hot water possible Heat pump type hot water supplier | |
KR100831946B1 (en) | Regasification method and equipment of liquefied natural gas | |
KR20080099209A (en) | Fuel gas supply system of the LNC carrier | |
CN118375852A (en) | Liquid hydrogen rapid pre-cooling system and method using non-condensable gas | |
JP5462607B2 (en) | Gas supply device | |
CN217465005U (en) | A pressurized cold storage device | |
CN214467841U (en) | Natural gas supply station | |
CN116972340A (en) | Integrated management system and method for liquid hydrogen aircraft | |
CN113915523B (en) | BOG heating utilization and LNG regasification system and control method thereof | |
CN112761745B (en) | Hot water energy storage system and method for thermal generator set | |
CN205690744U (en) | A high temperature steam heat pump system | |
CN112856222A (en) | Natural gas supply station | |
CN113606067A (en) | High-precision supply system and method for low-temperature incoming flow working medium | |
CN112384731A (en) | Fluid tank with internal evaporator | |
RU2747470C1 (en) | Regasification system | |
CN210601547U (en) | Thermal energy storage system based on solar energy | |
CN219530811U (en) | Energy storage and heat supply device | |
CN215411395U (en) | Container formula LNG storage tank and integrative sled integrated device of gasification pressure regulating |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
PB01 | Publication | ||
PB01 | Publication | ||
SE01 | Entry into force of request for substantive examination | ||
SE01 | Entry into force of request for substantive examination | ||
RJ01 | Rejection of invention patent application after publication |
Application publication date: 20200922 |
|
RJ01 | Rejection of invention patent application after publication |