CN111534039A - 一种耐候阻燃abs材料及其制备方法 - Google Patents
一种耐候阻燃abs材料及其制备方法 Download PDFInfo
- Publication number
- CN111534039A CN111534039A CN202010416931.5A CN202010416931A CN111534039A CN 111534039 A CN111534039 A CN 111534039A CN 202010416931 A CN202010416931 A CN 202010416931A CN 111534039 A CN111534039 A CN 111534039A
- Authority
- CN
- China
- Prior art keywords
- flame
- weather
- retardant
- parts
- resistant
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 title claims abstract description 67
- 239000003063 flame retardant Substances 0.000 title claims abstract description 65
- 239000000463 material Substances 0.000 title claims abstract description 40
- 238000002360 preparation method Methods 0.000 title claims abstract description 8
- 229920000122 acrylonitrile butadiene styrene Polymers 0.000 claims abstract description 46
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 17
- 239000006057 Non-nutritive feed additive Substances 0.000 claims abstract description 11
- 239000002775 capsule Substances 0.000 claims abstract description 10
- 239000012745 toughening agent Substances 0.000 claims abstract description 10
- 238000001125 extrusion Methods 0.000 claims abstract description 7
- 239000003605 opacifier Substances 0.000 claims abstract description 7
- XECAHXYUAAWDEL-UHFFFAOYSA-N acrylonitrile butadiene styrene Chemical compound C=CC=C.C=CC#N.C=CC1=CC=CC=C1 XECAHXYUAAWDEL-UHFFFAOYSA-N 0.000 claims description 35
- 239000004676 acrylonitrile butadiene styrene Substances 0.000 claims description 33
- -1 polyethylene Polymers 0.000 claims description 23
- 238000001035 drying Methods 0.000 claims description 9
- ADCOVFLJGNWWNZ-UHFFFAOYSA-N antimony trioxide Chemical compound O=[Sb]O[Sb]=O ADCOVFLJGNWWNZ-UHFFFAOYSA-N 0.000 claims description 8
- HQKMJHAJHXVSDF-UHFFFAOYSA-L magnesium stearate Chemical compound [Mg+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O HQKMJHAJHXVSDF-UHFFFAOYSA-L 0.000 claims description 8
- 239000004698 Polyethylene Substances 0.000 claims description 6
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 claims description 6
- LJCFOYOSGPHIOO-UHFFFAOYSA-N antimony pentoxide Chemical compound O=[Sb](=O)O[Sb](=O)=O LJCFOYOSGPHIOO-UHFFFAOYSA-N 0.000 claims description 6
- 239000000835 fiber Substances 0.000 claims description 6
- 238000002156 mixing Methods 0.000 claims description 6
- 239000000203 mixture Substances 0.000 claims description 6
- CTMFECUQKLSOGJ-UHFFFAOYSA-N 4-bromotriazine Chemical compound BrC1=CC=NN=N1 CTMFECUQKLSOGJ-UHFFFAOYSA-N 0.000 claims description 5
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N titanium dioxide Inorganic materials O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 5
- XOOUIPVCVHRTMJ-UHFFFAOYSA-L zinc stearate Chemical compound [Zn+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O XOOUIPVCVHRTMJ-UHFFFAOYSA-L 0.000 claims description 5
- 244000025254 Cannabis sativa Species 0.000 claims description 4
- 239000004743 Polypropylene Substances 0.000 claims description 4
- 229920001807 Urea-formaldehyde Polymers 0.000 claims description 4
- 229920002678 cellulose Polymers 0.000 claims description 4
- 239000001913 cellulose Substances 0.000 claims description 4
- 229920002301 cellulose acetate Polymers 0.000 claims description 4
- MCPKSFINULVDNX-UHFFFAOYSA-N drometrizole Chemical compound CC1=CC=C(O)C(N2N=C3C=CC=CC3=N2)=C1 MCPKSFINULVDNX-UHFFFAOYSA-N 0.000 claims description 4
- 235000019359 magnesium stearate Nutrition 0.000 claims description 4
- 229920000642 polymer Polymers 0.000 claims description 4
- 229920002635 polyurethane Polymers 0.000 claims description 4
- 239000004814 polyurethane Substances 0.000 claims description 4
- 229920000915 polyvinyl chloride Polymers 0.000 claims description 4
- 239000002994 raw material Substances 0.000 claims description 4
- IKEHOXWJQXIQAG-UHFFFAOYSA-N 2-tert-butyl-4-methylphenol Chemical compound CC1=CC=C(O)C(C(C)(C)C)=C1 IKEHOXWJQXIQAG-UHFFFAOYSA-N 0.000 claims description 3
- 230000009471 action Effects 0.000 claims description 3
- CJZGTCYPCWQAJB-UHFFFAOYSA-L calcium stearate Chemical compound [Ca+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O CJZGTCYPCWQAJB-UHFFFAOYSA-L 0.000 claims description 3
- 235000013539 calcium stearate Nutrition 0.000 claims description 3
- 239000008116 calcium stearate Substances 0.000 claims description 3
- 239000006229 carbon black Substances 0.000 claims description 3
- 238000013329 compounding Methods 0.000 claims description 3
- 238000001816 cooling Methods 0.000 claims description 3
- 229920001971 elastomer Polymers 0.000 claims description 3
- 238000005469 granulation Methods 0.000 claims description 3
- 230000003179 granulation Effects 0.000 claims description 3
- 238000002844 melting Methods 0.000 claims description 3
- 230000008018 melting Effects 0.000 claims description 3
- 238000004806 packaging method and process Methods 0.000 claims description 3
- 229920002589 poly(vinylethylene) polymer Polymers 0.000 claims description 3
- 229920000098 polyolefin Polymers 0.000 claims description 3
- 229920001296 polysiloxane Polymers 0.000 claims description 3
- 239000004800 polyvinyl chloride Substances 0.000 claims description 3
- 239000000843 powder Substances 0.000 claims description 3
- 239000005060 rubber Substances 0.000 claims description 3
- 238000010008 shearing Methods 0.000 claims description 3
- 229940037312 stearamide Drugs 0.000 claims description 3
- BIKXLKXABVUSMH-UHFFFAOYSA-N trizinc;diborate Chemical compound [Zn+2].[Zn+2].[Zn+2].[O-]B([O-])[O-].[O-]B([O-])[O-] BIKXLKXABVUSMH-UHFFFAOYSA-N 0.000 claims description 3
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 claims description 3
- 229920002554 vinyl polymer Polymers 0.000 claims description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 3
- 238000005303 weighing Methods 0.000 claims description 3
- 239000011787 zinc oxide Substances 0.000 claims description 3
- BZQKBFHEWDPQHD-UHFFFAOYSA-N 1,2,3,4,5-pentabromo-6-[2-(2,3,4,5,6-pentabromophenyl)ethyl]benzene Chemical compound BrC1=C(Br)C(Br)=C(Br)C(Br)=C1CCC1=C(Br)C(Br)=C(Br)C(Br)=C1Br BZQKBFHEWDPQHD-UHFFFAOYSA-N 0.000 claims description 2
- KXGFMDJXCMQABM-UHFFFAOYSA-N 2-methoxy-6-methylphenol Chemical compound [CH]OC1=CC=CC([CH])=C1O KXGFMDJXCMQABM-UHFFFAOYSA-N 0.000 claims description 2
- VEORPZCZECFIRK-UHFFFAOYSA-N 3,3',5,5'-tetrabromobisphenol A Chemical compound C=1C(Br)=C(O)C(Br)=CC=1C(C)(C)C1=CC(Br)=C(O)C(Br)=C1 VEORPZCZECFIRK-UHFFFAOYSA-N 0.000 claims description 2
- DYIZJUDNMOIZQO-UHFFFAOYSA-N 4,5,6,7-tetrabromo-2-[2-(4,5,6,7-tetrabromo-1,3-dioxoisoindol-2-yl)ethyl]isoindole-1,3-dione Chemical compound O=C1C(C(=C(Br)C(Br)=C2Br)Br)=C2C(=O)N1CCN1C(=O)C2=C(Br)C(Br)=C(Br)C(Br)=C2C1=O DYIZJUDNMOIZQO-UHFFFAOYSA-N 0.000 claims description 2
- 235000012766 Cannabis sativa ssp. sativa var. sativa Nutrition 0.000 claims description 2
- 235000012765 Cannabis sativa ssp. sativa var. spontanea Nutrition 0.000 claims description 2
- 229920000742 Cotton Polymers 0.000 claims description 2
- 229920002292 Nylon 6 Polymers 0.000 claims description 2
- 229920002302 Nylon 6,6 Polymers 0.000 claims description 2
- 229920003171 Poly (ethylene oxide) Polymers 0.000 claims description 2
- 229920002319 Poly(methyl acrylate) Polymers 0.000 claims description 2
- 239000004642 Polyimide Substances 0.000 claims description 2
- 229920002367 Polyisobutene Polymers 0.000 claims description 2
- 239000004793 Polystyrene Substances 0.000 claims description 2
- XBDQKXXYIPTUBI-UHFFFAOYSA-M Propionate Chemical compound CCC([O-])=O XBDQKXXYIPTUBI-UHFFFAOYSA-M 0.000 claims description 2
- UCKMPCXJQFINFW-UHFFFAOYSA-N Sulphide Chemical compound [S-2] UCKMPCXJQFINFW-UHFFFAOYSA-N 0.000 claims description 2
- 239000007983 Tris buffer Substances 0.000 claims description 2
- 229920002522 Wood fibre Polymers 0.000 claims description 2
- GZCGUPFRVQAUEE-SLPGGIOYSA-N aldehydo-D-glucose Chemical compound OC[C@@H](O)[C@@H](O)[C@H](O)[C@@H](O)C=O GZCGUPFRVQAUEE-SLPGGIOYSA-N 0.000 claims description 2
- 229920005549 butyl rubber Polymers 0.000 claims description 2
- 235000009120 camo Nutrition 0.000 claims description 2
- 235000005607 chanvre indien Nutrition 0.000 claims description 2
- 150000001875 compounds Chemical class 0.000 claims description 2
- 229920001577 copolymer Polymers 0.000 claims description 2
- 239000004205 dimethyl polysiloxane Substances 0.000 claims description 2
- 239000003822 epoxy resin Substances 0.000 claims description 2
- HANVTCGOAROXMV-UHFFFAOYSA-N formaldehyde;1,3,5-triazine-2,4,6-triamine;urea Chemical compound O=C.NC(N)=O.NC1=NC(N)=NC(N)=N1 HANVTCGOAROXMV-UHFFFAOYSA-N 0.000 claims description 2
- 239000011487 hemp Substances 0.000 claims description 2
- RKISUIUJZGSLEV-UHFFFAOYSA-N n-[2-(octadecanoylamino)ethyl]octadecanamide Chemical compound CCCCCCCCCCCCCCCCCC(=O)NCCNC(=O)CCCCCCCCCCCCCCCCC RKISUIUJZGSLEV-UHFFFAOYSA-N 0.000 claims description 2
- NFHFRUOZVGFOOS-UHFFFAOYSA-N palladium;triphenylphosphane Chemical compound [Pd].C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1.C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1.C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1.C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1 NFHFRUOZVGFOOS-UHFFFAOYSA-N 0.000 claims description 2
- 229920001568 phenolic resin Polymers 0.000 claims description 2
- 229920000435 poly(dimethylsiloxane) Polymers 0.000 claims description 2
- 229920003229 poly(methyl methacrylate) Polymers 0.000 claims description 2
- 229920002239 polyacrylonitrile Polymers 0.000 claims description 2
- 229920001748 polybutylene Polymers 0.000 claims description 2
- 229920001707 polybutylene terephthalate Polymers 0.000 claims description 2
- 239000004417 polycarbonate Substances 0.000 claims description 2
- 229920000515 polycarbonate Polymers 0.000 claims description 2
- 229920000647 polyepoxide Polymers 0.000 claims description 2
- 229920000728 polyester Polymers 0.000 claims description 2
- 229920000573 polyethylene Polymers 0.000 claims description 2
- 229920000139 polyethylene terephthalate Polymers 0.000 claims description 2
- 239000005020 polyethylene terephthalate Substances 0.000 claims description 2
- 229920001721 polyimide Polymers 0.000 claims description 2
- 239000004926 polymethyl methacrylate Substances 0.000 claims description 2
- 229920006324 polyoxymethylene Polymers 0.000 claims description 2
- 229920001155 polypropylene Polymers 0.000 claims description 2
- 229920002223 polystyrene Polymers 0.000 claims description 2
- 229920002689 polyvinyl acetate Polymers 0.000 claims description 2
- 239000011118 polyvinyl acetate Substances 0.000 claims description 2
- 229920003048 styrene butadiene rubber Polymers 0.000 claims description 2
- 229920000468 styrene butadiene styrene block copolymer Polymers 0.000 claims description 2
- 239000002025 wood fiber Substances 0.000 claims description 2
- 239000004408 titanium dioxide Substances 0.000 claims 1
- 230000002378 acidificating effect Effects 0.000 abstract description 3
- 230000007547 defect Effects 0.000 abstract description 3
- 238000004519 manufacturing process Methods 0.000 abstract description 3
- 238000010924 continuous production Methods 0.000 abstract description 2
- 238000000034 method Methods 0.000 abstract description 2
- 230000008569 process Effects 0.000 abstract description 2
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 8
- 239000004709 Chlorinated polyethylene Substances 0.000 description 6
- 102000029749 Microtubule Human genes 0.000 description 4
- 108091022875 Microtubule Proteins 0.000 description 4
- 230000032683 aging Effects 0.000 description 4
- 210000004688 microtubule Anatomy 0.000 description 4
- LYRFLYHAGKPMFH-UHFFFAOYSA-N octadecanamide Chemical compound CCCCCCCCCCCCCCCCCC(N)=O LYRFLYHAGKPMFH-UHFFFAOYSA-N 0.000 description 4
- 239000000243 solution Substances 0.000 description 4
- YMWUJEATGCHHMB-UHFFFAOYSA-N Dichloromethane Chemical compound ClCCl YMWUJEATGCHHMB-UHFFFAOYSA-N 0.000 description 3
- 239000004611 light stabiliser Substances 0.000 description 3
- 239000003094 microcapsule Substances 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- 244000146553 Ceiba pentandra Species 0.000 description 2
- 235000003301 Ceiba pentandra Nutrition 0.000 description 2
- JKIJEFPNVSHHEI-UHFFFAOYSA-N Phenol, 2,4-bis(1,1-dimethylethyl)-, phosphite (3:1) Chemical compound CC(C)(C)C1=CC(C(C)(C)C)=CC=C1OP(OC=1C(=CC(=CC=1)C(C)(C)C)C(C)(C)C)OC1=CC=C(C(C)(C)C)C=C1C(C)(C)C JKIJEFPNVSHHEI-UHFFFAOYSA-N 0.000 description 2
- BGYHLZZASRKEJE-UHFFFAOYSA-N [3-[3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoyloxy]-2,2-bis[3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoyloxymethyl]propyl] 3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoate Chemical compound CC(C)(C)C1=C(O)C(C(C)(C)C)=CC(CCC(=O)OCC(COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)(COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)=C1 BGYHLZZASRKEJE-UHFFFAOYSA-N 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 238000012545 processing Methods 0.000 description 2
- 238000002791 soaking Methods 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- 239000004801 Chlorinated PVC Substances 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 230000003042 antagnostic effect Effects 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 238000005520 cutting process Methods 0.000 description 1
- 230000008021 deposition Effects 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000005538 encapsulation Methods 0.000 description 1
- 238000011049 filling Methods 0.000 description 1
- 229910052736 halogen Inorganic materials 0.000 description 1
- 150000002367 halogens Chemical class 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 238000012216 screening Methods 0.000 description 1
- 150000003568 thioethers Chemical class 0.000 description 1
- 150000003918 triazines Chemical class 0.000 description 1
- 238000004383 yellowing Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L55/00—Compositions of homopolymers or copolymers, obtained by polymerisation reactions only involving carbon-to-carbon unsaturated bonds, not provided for in groups C08L23/00 - C08L53/00
- C08L55/02—ABS [Acrylonitrile-Butadiene-Styrene] polymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2237—Oxides; Hydroxides of metals of titanium
- C08K2003/2241—Titanium dioxide
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2296—Oxides; Hydroxides of metals of zinc
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/38—Boron-containing compounds
- C08K2003/387—Borates
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/02—Flame or fire retardant/resistant
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
- C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
本发明公开了一种耐候阻燃ABS材料及其制备方法，其中耐候阻燃ABS材料包括以下组分和重量份数：ABS类树脂55‑80、胶囊阻燃剂10‑25、阻燃协效剂3‑8、增韧剂2‑10、遮光剂2‑5、耐候剂0.5‑1.5、加工助剂0.6‑1。本发明的耐候阻燃ABS材料通过改性阻燃剂从而调整了材料的酸性环境，并采用双螺杆挤出工艺制备，具有流程简单、连续、生产效率高、产品质量稳定的优点，显著改善了阻燃ABS材料耐候性能差、冲击强度差的缺陷。
Description
技术领域
本发明属于ABS材料领域，具体涉及一种耐候阻燃ABS材料及其制备方法。
背景技术
ABS是五大通用塑料之一，具有良好的加工性能、电气性能、耐化学药品性能、力学性能，而ABS的易燃、耐候性能差等缺点限制了它的应用。目前，ABS主要的阻燃改性方式主要是通过卤素，从而达到VO级阻燃等级，但材料的耐候性能会显著降低，大幅缩短了材料的使用时间，材料极易老化发黄。而普通的耐候剂在酸性环境下容易失效，因此很难直接加入以满足材料的耐候要求。
发明内容
为解决上述问题，本发明公开了一种耐候阻燃ABS材料及其制备方法，通过改性阻燃剂从而调整了材料的酸性环境，并通过双螺杆挤出制备的耐候阻燃ABS材料，具有流程简单、连续、生产效率高、产品质量稳定的优点，显著改善了阻燃ABS材料耐候性能差、冲击强度差的缺陷。
为达到上述目的，本发明的技术方案如下：
一种耐候阻燃ABS材料，为丙烯腈-丁二烯-苯乙烯三元共聚物，包括以下组分和重量份数：
ABS类树脂 55-80，
胶囊阻燃剂 10-25，
阻燃协效剂 3-8，
增韧剂 2-10，
遮光剂 2-5，
耐候剂 0.5-1.5，
加工助剂 0.6-1。
优选的，所述胶囊阻燃剂，至少由核和包覆所述核的壳组成，所述核为阻燃剂，所述壳为含有天然纤维素的高分子聚合物。
优选的，所述阻燃剂核为溴代三嗪、四溴双酚A、十溴二苯乙烷、BT-93W中的至少一种。
优选的，所述天然纤维素为棉纤维、麻纤维、木纤维、草纤维或醋酸纤维素；所述高分子聚合物为聚乙烯、聚丙烯、聚丁烯、聚苯乙烯、聚氯乙烯、聚异丁烯、聚丙烯腈、聚氨酯、聚甲基丙烯酸甲酯、聚丙烯酸甲酯、聚醋酸乙烯酯、聚对苯二甲酸乙二醇酯、聚对苯二甲酸丁二醇酯、聚碳酸酯、脲醛树脂、三聚氰胺- 甲醛树脂、三聚氰胺脲醛树脂、酚醛树脂、环氧树脂、聚甲醛、聚氧化乙烯、聚己二酰己二胺、聚己内酰胺、聚酰亚胺、聚二甲基硅氧烷、丙烯腈-苯乙烯-丁二烯共聚物、苯乙烯-丁二烯-苯乙烯嵌段共聚物、丁基橡胶或丁二烯异戊二烯共聚物。
优选的，所述阻燃协效剂为三氧化二锑、五氧化二锑、硼酸锌、CPE、PVC中至少一种。
优选的，所述增韧剂为高胶粉、聚氨酯、聚烯烃、聚酯、间规1，2- 聚丁二烯中的至少一种。
优选的，所述遮光剂为金红石型钛白粉、炭黑、氧化锌中的一种。
优选的，所述耐候剂为UV 770、UV329、UV327、UV531、UV328、UV944、UV783、UV-P、UV622中的至少一种。
优选的，所述加工助剂为乙烯基双硬脂酰胺、聚硅氧烷、硬脂酸钙、硬脂酸镁、硬脂酸锌、PE 蜡、PP 蜡、ABS 蜡、乙撑双硬脂酰胺、硬脂酸锌与PE 蜡的复配物中的至少一种；以及三(2,4- 二叔丁基) 亚磷酸苯酯、2，6- 三级丁基-4- 甲基苯酚、双(3，5- 三级丁基-4-羟基苯基) 硫醚、四〔β-(3，5- 三级丁基-4- 羟基苯基) 丙酸〕季戊四醇酯中的至少一种。
一种耐候阻燃ABS材料的制备方法，包括以下步骤：
（1）将ABS 在80℃～85℃下干燥2～4小时，含水率控制在0.03% 以下，干燥后备用；
（2）按重量配比称取胶囊阻燃剂、阻燃协效剂、增韧剂、遮光剂、耐候剂和加工助剂，混合均匀后，再与ABS 的混合物一起加入到混合器中继续混合2～5 分钟；
（3）将上述充分混合好的原料投入双螺杆挤出机，经熔融挤出并造粒，在双螺杆挤出机的输送和剪切作用下，经充分塑化、熔融、复合、机头挤出、拉条、冷却、切粒、烘干和包装，即得一种耐候阻燃ABS材料。
本发明的有益效果是：
通过将阻燃剂胶囊化，降低阻燃剂在生产加工过程中产生的酸性物质，且可防止产生的酸性物质与碱性的光稳剂产生对抗作用，从而提高了受阻胺型光稳剂的活性，使阻燃材料的耐候性能提高，在力学性能、加工性能、阻燃耐候性能上能够满足多领域对原料树脂的要求。
具体实施方式
下面结合具体实施方式，进一步阐明本发明，应理解下述具体实施方式仅用于说明本发明而不用于限制本发明的范围。
先制备胶囊阻燃剂：将1000g 天然木棉纤维用机械外力均匀切短到50-200μm；将切短的天然木棉纤维微管分散于50％ ( 质量百分含量) 的溴代三嗪的丙酮溶液中，超声波中浸泡1.5 小时使微管对溴代三嗪的丙酮溶液的毛细吸收达到平衡，使切短的天然微管内充满溴代三嗪的丙酮溶液，获得阻燃微管；将阻燃微管中的丙酮挥发掉，然后浸渍于浓度为5％ ( 质量百分含量) 的醋酸纤维素的二氯甲烷溶液中，利用界面沉积反应使阻燃微管外包封醋酸纤维素层，获得阻燃微胶囊；
实施例1：ABS 树脂70 份，胶囊阻燃剂11 份，阻燃协效剂三氧化二锑4 份，增韧剂高胶粉HR181取 8份，遮光剂金红石型钛白粉5份，耐候剂UV-P取 1.5 份，加工助剂抗氧剂1010取0.2份、抗氧剂168取0.2份、硬脂酸镁0.3 份、双(3，5- 三级丁基-4- 羟基苯基) 硫醚0.3份。
实施例2：ABS 树脂55份，阻燃微胶囊25 份，阻燃协效剂五氧化二锑4 份和CPE 4份，增韧剂聚烯烃10份，遮光剂炭黑4份，耐候剂UV 770 取0.5 份、UV-P 取0.6 份，加工助剂聚硅氧烷0.3份、硬脂酸钙0.3 份、三(2,4- 二叔丁基) 亚磷酸苯酯0.3 份。
实施例3：ABS 树脂80 份，阻燃微胶囊10 份，阻燃协效剂硼酸锌2 份和CPE 1份，增韧剂间规1，2- 聚丁二烯2份，遮光剂氧化锌2份，耐候剂UV329取0.3 份、UV 531 取0.2份，加工助剂乙烯基双硬脂酰胺0.2份、硬脂酸锌0.1 份、2，6- 三级丁基-4- 甲基苯酚0.3份。
对比例1：ABS 树脂70 份，溴代三嗪16份， CPE 8份，三氧化二锑4 份，抗氧剂1010取0.3份，抗氧剂168取0.3份，硬脂酸镁0.3 份，UV326 0.5 份，光稳定剂770 取0.6 份。
制备方法：
将ABS 在80℃～85℃下干燥2～4小时，含水率控制在0.03% 以下，干燥后备用；
按重量配比称取胶囊阻燃剂、阻燃协效剂、增韧剂、遮光剂、耐候剂和加工助剂，混合均匀后，再与ABS 的混合物一起加入到混合器中继续混合2～5 分钟；
将上述充分混合好的原料投入双螺杆挤出机，经熔融挤出并造粒，在双螺杆挤出机的输送和剪切作用下，经充分塑化、熔融、复合、机头挤出、拉条、冷却、切粒、烘干和包装，即得一种耐候阻燃ABS材料。将所得材料按照垂直燃烧级别 UL-94进行测试，同时将材料根据GB/T14522标准置于紫外老化箱中在UVA340灯光下老化168小时，并测试材料色差变化，实验结果见表1。
表1 UL94垂直燃烧实验与紫外老化实验结果
从表1中可以看出，通过对阻燃剂的胶囊化改性后材料的阻燃性能仍然能达到V0级，与对比例1比较材料的老化性能显著提高，材料的黄变程度显著降低，由此可见材料的老化程度明显降低。
Claims (10)
1.一种耐候阻燃ABS材料，其特征在于，所述的ABS为丙烯腈-丁二烯-苯乙烯三元共聚物，包括以下组分和重量份数：
ABS类树脂 55-80，
胶囊阻燃剂 10-25，
阻燃协效剂 3-8，
增韧剂 2-10，
遮光剂 2-5，
耐候剂 0.5-1.5，
加工助剂 0.6-1。
2.根据权利要求1 所述的一种耐候阻燃ABS材料，其特征在于，所述胶囊阻燃剂，至少由核和包覆所述核的壳组成，所述核为阻燃剂，所述壳为含有天然纤维素的高分子聚合物。
3.根据权利要求2 所述的一种耐候阻燃ABS材料，其特征在于，所述阻燃剂核为溴代三嗪、四溴双酚A、十溴二苯乙烷、BT-93W中的至少一种。
4.根据权利要求2 所述的一种耐候阻燃ABS材料，其特征在于：所述天然纤维素为棉纤维、麻纤维、木纤维、草纤维或醋酸纤维素；所述高分子聚合物为聚乙烯、聚丙烯、聚丁烯、聚苯乙烯、聚氯乙烯、聚异丁烯、聚丙烯腈、聚氨酯、聚甲基丙烯酸甲酯、聚丙烯酸甲酯、聚醋酸乙烯酯、聚对苯二甲酸乙二醇酯、聚对苯二甲酸丁二醇酯、聚碳酸酯、脲醛树脂、三聚氰胺-甲醛树脂、三聚氰胺脲醛树脂、酚醛树脂、环氧树脂、聚甲醛、聚氧化乙烯、聚己二酰己二胺、聚己内酰胺、聚酰亚胺、聚二甲基硅氧烷、丙烯腈-苯乙烯-丁二烯共聚物、苯乙烯-丁二烯-苯乙烯嵌段共聚物、丁基橡胶或丁二烯异戊二烯共聚物。
5.根据权利要求1 所述的一种耐候阻燃ABS材料，其特征在于，所述阻燃协效剂为三氧化二锑、五氧化二锑、硼酸锌、CPE、PVC中至少一种。
6.根据权利要求1 所述的一种耐候阻燃ABS材料，其特征在于，所述增韧剂为高胶粉、聚氨酯、聚烯烃、聚酯、间规1，2- 聚丁二烯中的至少一种。
7.根据权利要求1 所述的一种耐候阻燃ABS材料，其特征在于，所述遮光剂为金红石型钛白粉、炭黑、氧化锌中的一种。
8.根据权利要求1 所述的一种耐候阻燃ABS材料，其特征在于，所述耐候剂为UV 770、UV329、UV327、UV531、UV328、UV944、UV783、UV-P、UV622中的至少一种。
9.根据权利要求1 所述的一种耐候阻燃ABS材料，其特征在于，所述加工助剂为乙烯基双硬脂酰胺、聚硅氧烷、硬脂酸钙、硬脂酸镁、硬脂酸锌、PE 蜡、PP 蜡、ABS 蜡、乙撑双硬脂酰胺、硬脂酸锌与PE 蜡的复配物中的至少一种；以及三(2,4- 二叔丁基) 亚磷酸苯酯、2，6- 三级丁基-4- 甲基苯酚、双(3，5- 三级丁基-4- 羟基苯基) 硫醚、四〔β-(3，5- 三级丁基-4- 羟基苯基) 丙酸〕季戊四醇酯中的至少一种。
10.根据权利要求1 所述的一种耐候阻燃ABS材料的制备方法，其特征在于，包括以下步骤：
（1）将ABS 在80℃～85℃下干燥2～4小时，含水率控制在0.03% 以下，干燥后备用；
（2）按重量配比称取胶囊阻燃剂、阻燃协效剂、增韧剂、遮光剂、耐候剂和加工助剂，混合均匀后，再与ABS 的混合物一起加入到混合器中继续混合2～5 分钟；
（3）将上述充分混合好的原料投入双螺杆挤出机，经熔融挤出并造粒，在双螺杆挤出机的输送和剪切作用下，经充分塑化、熔融、复合、机头挤出、拉条、冷却、切粒、烘干和包装，即得一种耐候阻燃ABS材料。
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202010416931.5A CN111534039A (zh) | 2020-05-18 | 2020-05-18 | 一种耐候阻燃abs材料及其制备方法 |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202010416931.5A CN111534039A (zh) | 2020-05-18 | 2020-05-18 | 一种耐候阻燃abs材料及其制备方法 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN111534039A true CN111534039A (zh) | 2020-08-14 |
Family
ID=71973925
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN202010416931.5A Pending CN111534039A (zh) | 2020-05-18 | 2020-05-18 | 一种耐候阻燃abs材料及其制备方法 |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN111534039A (zh) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN114230860A (zh) * | 2021-11-23 | 2022-03-25 | 金发科技股份有限公司 | 一种阻燃十溴二苯乙烷复合物及其制备方法 |
| CN114230865A (zh) * | 2021-11-23 | 2022-03-25 | 金发科技股份有限公司 | 一种具有高光稳定性的十溴二苯乙烷复合物及其制备方法 |
| CN114806068A (zh) * | 2022-04-25 | 2022-07-29 | 万华化学(四川)有限公司 | 一种高强度高刚性的环保耐候abs树脂及其制备方法 |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1962751A (zh) * | 2005-11-07 | 2007-05-16 | 上海金发科技发展有限公司 | 一种耐热阻燃abs类树脂及其制备方法 |
| CN101191005A (zh) * | 2006-11-21 | 2008-06-04 | 上海普利特复合材料有限公司 | 一种阻燃抗紫外型abs组合物 |
| US20100285313A1 (en) * | 2009-05-11 | 2010-11-11 | Eternal Chemical Co., Ltd. | Microencapsulated fire retardants and the uses thereof |
| TW201117877A (en) * | 2009-11-25 | 2011-06-01 | Eternal Chemical Co Ltd | Microencapsulated fire retardants and the uses thereof |
| CN102775676A (zh) * | 2011-05-11 | 2012-11-14 | 上海安凸塑料添加剂有限公司 | 一种用于注塑有优良耐候性的体育场阻燃塑料座椅的材料 |
-
2020
- 2020-05-18 CN CN202010416931.5A patent/CN111534039A/zh active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1962751A (zh) * | 2005-11-07 | 2007-05-16 | 上海金发科技发展有限公司 | 一种耐热阻燃abs类树脂及其制备方法 |
| CN101191005A (zh) * | 2006-11-21 | 2008-06-04 | 上海普利特复合材料有限公司 | 一种阻燃抗紫外型abs组合物 |
| US20100285313A1 (en) * | 2009-05-11 | 2010-11-11 | Eternal Chemical Co., Ltd. | Microencapsulated fire retardants and the uses thereof |
| TW201117877A (en) * | 2009-11-25 | 2011-06-01 | Eternal Chemical Co Ltd | Microencapsulated fire retardants and the uses thereof |
| CN102775676A (zh) * | 2011-05-11 | 2012-11-14 | 上海安凸塑料添加剂有限公司 | 一种用于注塑有优良耐候性的体育场阻燃塑料座椅的材料 |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN114230860A (zh) * | 2021-11-23 | 2022-03-25 | 金发科技股份有限公司 | 一种阻燃十溴二苯乙烷复合物及其制备方法 |
| CN114230865A (zh) * | 2021-11-23 | 2022-03-25 | 金发科技股份有限公司 | 一种具有高光稳定性的十溴二苯乙烷复合物及其制备方法 |
| CN114230860B (zh) * | 2021-11-23 | 2023-09-12 | 金发科技股份有限公司 | 一种阻燃十溴二苯乙烷复合物及其制备方法 |
| CN114230865B (zh) * | 2021-11-23 | 2023-11-03 | 金发科技股份有限公司 | 一种具有高光稳定性的十溴二苯乙烷复合物及其制备方法 |
| CN114806068A (zh) * | 2022-04-25 | 2022-07-29 | 万华化学(四川)有限公司 | 一种高强度高刚性的环保耐候abs树脂及其制备方法 |
| CN114806068B (zh) * | 2022-04-25 | 2024-02-27 | 万华化学(四川)有限公司 | 一种高强度高刚性的环保耐候abs树脂及其制备方法 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN111534039A (zh) | 一种耐候阻燃abs材料及其制备方法 | |
| KR101205126B1 (ko) | 난연성 중합체 조성물 | |
| CN102585378B (zh) | 一种高耐热玻纤增强无卤阻燃聚丙烯及其生产方法 | |
| CN105385028A (zh) | 一种高阻燃聚丙烯材料及其制备方法 | |
| CN108017868B (zh) | 一种增强阻燃聚丙烯复合材料及其制备方法 | |
| EP2397510A1 (en) | High concentration pelletized additive concentrates for polymer | |
| CN102516732A (zh) | 聚碳酸酯树脂/ abs合金及其制备方法 | |
| CN112646310A (zh) | 一种pc/abs复合材料及其制备方法和应用 | |
| CN111621088A (zh) | 一种导电聚丙烯材料及其制备方法 | |
| CN108424642A (zh) | 一种可激光雕刻阻燃尼龙pa66材料及其制备方法 | |
| CN113462067A (zh) | 无卤阻燃eva电缆料复合材料及其制备方法 | |
| CN104356538B (zh) | 一种阻燃消烟的聚氯乙烯电线电缆料 | |
| CN110305440B (zh) | 一种环保阻燃abs复合材料及其制备方法 | |
| CN107189393A (zh) | 一种无卤阻燃增强pc/aes合金及其制备方法 | |
| CN108976752B (zh) | 一种提高聚碳酸酯薄壁制件阻燃性的方法 | |
| CN112724574B (zh) | 一种阻燃高刚性acs复合材料及其制备方法和应用 | |
| CN103044796B (zh) | 一种环氧树脂增强聚苯乙烯无卤阻燃材料及其制备方法 | |
| CN114685930A (zh) | 一种高刚耐候阻燃abs染色料及制备方法 | |
| CN105419044A (zh) | 一种用于塑料编织袋的无卤阻燃母料 | |
| CN110003630B (zh) | 一种透明的耐磨阻燃抗菌塑料及其制备方法 | |
| US5002702A (en) | Stabilizer compositions comprising a thiophosphate and an organo tin compound | |
| CN114230932A (zh) | 一种阻燃填充聚丙烯材料及其制备方法与应用 | |
| CN104356467A (zh) | 一种聚乙烯组合物及其制备方法和制品 | |
| KR0175720B1 (ko) | 난연성 폴리프로필렌 수지조성물 | |
| CN112724588A (zh) | 一种abs高效阻燃增韧母粒的制备方法和应用 |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20200814 |
|
| RJ01 | Rejection of invention patent application after publication |