CN111469588B - Neon color gold foil patch and preparation method and application thereof - Google Patents
Neon color gold foil patch and preparation method and application thereof Download PDFInfo
- Publication number
- CN111469588B CN111469588B CN202010258981.5A CN202010258981A CN111469588B CN 111469588 B CN111469588 B CN 111469588B CN 202010258981 A CN202010258981 A CN 202010258981A CN 111469588 B CN111469588 B CN 111469588B
- Authority
- CN
- China
- Prior art keywords
- color
- neon
- gold
- gold foil
- baking
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 title claims abstract description 137
- 229910052754 neon Inorganic materials 0.000 title claims abstract description 111
- GKAOGPIIYCISHV-UHFFFAOYSA-N neon atom Chemical compound [Ne] GKAOGPIIYCISHV-UHFFFAOYSA-N 0.000 title claims abstract description 107
- 238000002360 preparation method Methods 0.000 title claims abstract description 24
- 239000000919 ceramic Substances 0.000 claims abstract description 81
- 239000000049 pigment Substances 0.000 claims abstract description 74
- 239000010931 gold Substances 0.000 claims abstract description 33
- 229910052737 gold Inorganic materials 0.000 claims abstract description 33
- 239000003086 colorant Substances 0.000 claims abstract description 26
- 238000010422 painting Methods 0.000 claims abstract description 26
- 238000000034 method Methods 0.000 claims abstract description 23
- 238000000227 grinding Methods 0.000 claims abstract description 21
- 230000004907 flux Effects 0.000 claims abstract description 20
- 229910001369 Brass Inorganic materials 0.000 claims abstract description 19
- 239000010951 brass Substances 0.000 claims abstract description 19
- ICRFSZUNIIGINI-UHFFFAOYSA-N [Ne].[Au] Chemical compound [Ne].[Au] ICRFSZUNIIGINI-UHFFFAOYSA-N 0.000 claims description 37
- 239000000463 material Substances 0.000 claims description 24
- 238000002156 mixing Methods 0.000 claims description 18
- 239000011521 glass Substances 0.000 claims description 17
- 239000000203 mixture Substances 0.000 claims description 17
- 210000002969 egg yolk Anatomy 0.000 claims description 16
- 239000002184 metal Substances 0.000 claims description 15
- 229910052751 metal Inorganic materials 0.000 claims description 15
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 15
- 238000010438 heat treatment Methods 0.000 claims description 13
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims description 12
- 239000011248 coating agent Substances 0.000 claims description 12
- 238000000576 coating method Methods 0.000 claims description 12
- 238000011049 filling Methods 0.000 claims description 12
- JVTAAEKCZFNVCJ-UHFFFAOYSA-N lactic acid Chemical compound CC(O)C(O)=O JVTAAEKCZFNVCJ-UHFFFAOYSA-N 0.000 claims description 12
- 238000002844 melting Methods 0.000 claims description 12
- 230000008018 melting Effects 0.000 claims description 12
- 239000000155 melt Substances 0.000 claims description 11
- 239000003795 chemical substances by application Substances 0.000 claims description 10
- 239000011889 copper foil Substances 0.000 claims description 10
- 239000003921 oil Substances 0.000 claims description 10
- 238000004040 coloring Methods 0.000 claims description 9
- 238000007598 dipping method Methods 0.000 claims description 9
- 238000003384 imaging method Methods 0.000 claims description 9
- 102000002322 Egg Proteins Human genes 0.000 claims description 8
- 108010000912 Egg Proteins Proteins 0.000 claims description 8
- 235000013345 egg yolk Nutrition 0.000 claims description 8
- 239000011888 foil Substances 0.000 claims description 8
- 235000010855 food raising agent Nutrition 0.000 claims description 8
- 238000001816 cooling Methods 0.000 claims description 7
- 241000196324 Embryophyta Species 0.000 claims description 6
- 229920002472 Starch Polymers 0.000 claims description 6
- 229930006000 Sucrose Natural products 0.000 claims description 6
- CZMRCDWAGMRECN-UGDNZRGBSA-N Sucrose Chemical compound O[C@H]1[C@H](O)[C@@H](CO)O[C@@]1(CO)O[C@@H]1[C@H](O)[C@@H](O)[C@H](O)[C@@H](CO)O1 CZMRCDWAGMRECN-UGDNZRGBSA-N 0.000 claims description 6
- 235000015278 beef Nutrition 0.000 claims description 6
- 238000001035 drying Methods 0.000 claims description 6
- 235000014655 lactic acid Nutrition 0.000 claims description 6
- 239000004310 lactic acid Substances 0.000 claims description 6
- 235000019698 starch Nutrition 0.000 claims description 6
- 239000008107 starch Substances 0.000 claims description 6
- 239000003760 tallow Substances 0.000 claims description 6
- 238000004898 kneading Methods 0.000 claims description 5
- 238000005096 rolling process Methods 0.000 claims description 5
- 238000003756 stirring Methods 0.000 claims description 5
- 238000010008 shearing Methods 0.000 claims description 4
- 238000011068 loading method Methods 0.000 claims description 3
- 238000007789 sealing Methods 0.000 claims description 3
- 244000068988 Glycine max Species 0.000 claims description 2
- 235000010469 Glycine max Nutrition 0.000 claims description 2
- 235000013336 milk Nutrition 0.000 claims description 2
- 239000008267 milk Substances 0.000 claims description 2
- 210000004080 milk Anatomy 0.000 claims description 2
- 238000007670 refining Methods 0.000 claims description 2
- 235000013311 vegetables Nutrition 0.000 claims description 2
- 238000003618 dip coating Methods 0.000 claims 1
- 230000000007 visual effect Effects 0.000 abstract description 7
- 229920006395 saturated elastomer Polymers 0.000 abstract description 5
- 239000002932 luster Substances 0.000 abstract description 2
- 230000015572 biosynthetic process Effects 0.000 abstract 1
- 239000002904 solvent Substances 0.000 description 14
- 239000010410 layer Substances 0.000 description 13
- 238000005034 decoration Methods 0.000 description 6
- 239000003085 diluting agent Substances 0.000 description 6
- 229910052573 porcelain Inorganic materials 0.000 description 6
- 239000013078 crystal Substances 0.000 description 4
- 238000003621 hammer milling Methods 0.000 description 4
- 239000004576 sand Substances 0.000 description 4
- 239000002344 surface layer Substances 0.000 description 4
- 238000004519 manufacturing process Methods 0.000 description 3
- 244000140786 Brassica hirta Species 0.000 description 2
- 235000011371 Brassica hirta Nutrition 0.000 description 2
- 240000002791 Brassica napus Species 0.000 description 2
- 235000004977 Brassica sinapistrum Nutrition 0.000 description 2
- 235000015895 biscuits Nutrition 0.000 description 2
- 239000001342 boswellia carteri birdw. oil Substances 0.000 description 2
- 239000010624 camphor oil Substances 0.000 description 2
- 229960000411 camphor oil Drugs 0.000 description 2
- 229910052802 copper Inorganic materials 0.000 description 2
- 239000010949 copper Substances 0.000 description 2
- 230000007547 defect Effects 0.000 description 2
- 238000010586 diagram Methods 0.000 description 2
- 238000010304 firing Methods 0.000 description 2
- 238000007667 floating Methods 0.000 description 2
- 239000003350 kerosene Substances 0.000 description 2
- 238000005498 polishing Methods 0.000 description 2
- 238000005507 spraying Methods 0.000 description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- WHUUTDBJXJRKMK-UHFFFAOYSA-N Glutamic acid Natural products OC(=O)C(N)CCC(O)=O WHUUTDBJXJRKMK-UHFFFAOYSA-N 0.000 description 1
- WHUUTDBJXJRKMK-VKHMYHEASA-N L-glutamic acid Chemical compound OC(=O)[C@@H](N)CCC(O)=O WHUUTDBJXJRKMK-VKHMYHEASA-N 0.000 description 1
- 239000005862 Whey Substances 0.000 description 1
- 102000007544 Whey Proteins Human genes 0.000 description 1
- 108010046377 Whey Proteins Proteins 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 235000001014 amino acid Nutrition 0.000 description 1
- 150000001413 amino acids Chemical class 0.000 description 1
- 235000013351 cheese Nutrition 0.000 description 1
- 238000005520 cutting process Methods 0.000 description 1
- 235000014113 dietary fatty acids Nutrition 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 229930195729 fatty acid Natural products 0.000 description 1
- 239000000194 fatty acid Substances 0.000 description 1
- 150000004665 fatty acids Chemical class 0.000 description 1
- 238000000855 fermentation Methods 0.000 description 1
- 230000004151 fermentation Effects 0.000 description 1
- 239000012634 fragment Substances 0.000 description 1
- 235000013922 glutamic acid Nutrition 0.000 description 1
- 239000004220 glutamic acid Substances 0.000 description 1
- 238000009499 grossing Methods 0.000 description 1
- 125000001475 halogen functional group Chemical group 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000007591 painting process Methods 0.000 description 1
- 230000003071 parasitic effect Effects 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
Images
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B44—DECORATIVE ARTS
- B44C—PRODUCING DECORATIVE EFFECTS; MOSAICS; TARSIA WORK; PAPERHANGING
- B44C1/00—Processes, not specifically provided for elsewhere, for producing decorative surface effects
- B44C1/10—Applying flat materials, e.g. leaflets, pieces of fabrics
- B44C1/14—Metallic leaves or foils, e.g. gold leaf
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B21—MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
- B21F—WORKING OR PROCESSING OF METAL WIRE
- B21F7/00—Twisting wire; Twisting wire together
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B44—DECORATIVE ARTS
- B44C—PRODUCING DECORATIVE EFFECTS; MOSAICS; TARSIA WORK; PAPERHANGING
- B44C1/00—Processes, not specifically provided for elsewhere, for producing decorative surface effects
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B44—DECORATIVE ARTS
- B44C—PRODUCING DECORATIVE EFFECTS; MOSAICS; TARSIA WORK; PAPERHANGING
- B44C1/00—Processes, not specifically provided for elsewhere, for producing decorative surface effects
- B44C1/10—Applying flat materials, e.g. leaflets, pieces of fabrics
- B44C1/105—Applying flat materials, e.g. leaflets, pieces of fabrics comprising an adhesive layer
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B44—DECORATIVE ARTS
- B44C—PRODUCING DECORATIVE EFFECTS; MOSAICS; TARSIA WORK; PAPERHANGING
- B44C1/00—Processes, not specifically provided for elsewhere, for producing decorative surface effects
- B44C1/18—Applying ornamental structures, e.g. shaped bodies consisting of plastic material
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/45—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
- C04B41/50—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with inorganic materials
- C04B41/5022—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with inorganic materials with vitreous materials
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/80—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone of only ceramics
- C04B41/81—Coating or impregnation
- C04B41/85—Coating or impregnation with inorganic materials
- C04B41/86—Glazes; Cold glazes
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C1/00—Making non-ferrous alloys
- C22C1/02—Making non-ferrous alloys by melting
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C5/00—Alloys based on noble metals
- C22C5/02—Alloys based on gold
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Ceramic Engineering (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Mechanical Engineering (AREA)
- Inorganic Chemistry (AREA)
- Structural Engineering (AREA)
- Metallurgy (AREA)
- Adornments (AREA)
Abstract
The invention provides a neon color gold foil patch and a preparation method and application thereof, wherein the neon color gold foil patch is formed by hammer-grinding a gold foil and seven-color ceramic colored drawing pigment; the gold foil comprises the following components in percentage by mass (8.3-7.3): (1.7-2.7) gold and brass; the colors of the seven-color ceramic colored drawing pigment are red, orange, yellow, green, cyan, blue and purple respectively. Compared with the prior art, the neon color gold foil patch and the medium flux thereof are suitable for neon color painting and neon color set color painting, the finished product has bright and attractive appearance and bright and fine color, and a slight and faint seven-color neon halo is displayed on the inner layer of the gold texture; the method is particularly applied to neon color painting and neon color set color painting of ceramics, and the finished product has bright and bright color pictures, stable and saturated color formation, rich and gorgeous color and luster, clear picture layers and unique neon and gold visual effects, thereby greatly improving the artistic appreciation and commercial value of ceramic vessels.
Description
Technical Field
The invention relates to the technical field of ceramic crafts, in particular to a neon color gold foil patch and a preparation method and application thereof.
Background
The ceramic color painting decoration process can be divided into overglaze color, in-glaze color and underglaze color. The overglaze decoration is one of the main decoration techniques of ceramic handicraft, and is made up by using various special-purpose colour drawing pigments for ceramics to draw various patterns on the surface of fired ceramic ware, then placing the ceramic ware into kiln and baking. The underglaze color method comprises three steps: firstly, colored drawing is carried out on a biscuit, transparent glaze is covered, and porcelain is sintered at high temperature for one time; secondly, glazing the blank, painting the glaze, spraying a layer of thin glaze, and firing at high temperature for one time to obtain porcelain; thirdly, glazing the blank, firstly biscuiting at the temperature of about 800 ℃, painting the biscuit after biscuiting, then spraying a layer of thin glaze, and then firing the porcelain at high temperature. Colored drawing on the glaze surface is also called as in-glaze color.
In the ceramic colored drawing decoration process, a color dissolving agent and a diluent are added into pigments of various colors; the solvent facilitates the color development of the pigment, the pigment is easy to attach to the surface of the ceramic body, and the diluent is used for releasing the pigment, so that the pigment is convenient to draw picture details. The traditional solvent and diluent mainly comprise frankincense oil, camphor oil, water and oil solutions such as alcohol, kerosene and the like, and the existing ceramic floating color painting process in the prior art adopts cheese and whey as the solvent and diluent. In general, the coloring agent and the diluent used for coloring the ceramic also function as a coloring agent and a flux.
The traditional solvent and diluent are simple to prepare and convenient to use, but have some defects. If the oily pigment overflows, the picture layers are blurred, and part of the pigment is not bright enough; the color gradation expression is not rich enough by using pigments such as pastel prepared by water, kerosene and the like; the ceramic floating color process also has certain defects: the ceramic works drawn by using the ceramic painting can form a certain concave-convex color image on the surface of the ceramic after being fired, but the ceramic works can only have a punctiform three-dimensional effect, the painting area is enlarged, and picture cracks can be caused during color baking.
Disclosure of Invention
The neon color gold foil patch is used for ceramic neon color set color painting, and a finished product has bright and bright color pictures, stable and saturated color, rich and gorgeous color and luster, clear picture layers and unique neon color gold visual effect.
The invention provides a neon gold color gold foil patch which is formed by hammer-grinding a gold foil and seven-color ceramic colored drawing pigment;
the gold foil comprises the following components in percentage by mass (8.3-7.3): (1.7-2.7) gold and brass;
the colors of the seven-color ceramic colored drawing pigment are red, orange, yellow, green, cyan, blue and purple respectively.
Preferably, the thickness of the neon color gold foil patch is 0.02 mm-0.08 mm.
The invention also provides a preparation method of the neon color gold foil patch in the technical scheme, which comprises the following steps:
a) grinding gold into gold foil by a hammer and grinding the gold foil into copper foil by a brass hammer, respectively shearing the gold foil and the copper foil, mixing, and putting into a crucible for heating and melting to obtain a melt; then cooling the melt, taking out, and hammer-grinding into gold foil with the thickness of 0.1-0.5 mm;
b) dividing the gold foil obtained in the step a) into seven pieces with the length multiplied by the width of (8-12 cm) multiplied by (4-6 cm), respectively filling seven ceramic colored drawing pigments into the seven pieces of gold foil according to different colors, wrapping, and repeatedly kneading and hammer-rolling to obtain seven colors of metal wires; finally twisting the seven colors of metal wires into a spiral strip shape, and hammering to obtain the neon gold foil patch.
Preferably, the purity of the gold is not lower than 99.9%.
Preferably, the temperature of the heating and melting is 1050-1100 ℃.
Preferably, the loading amount of the color pigment in each piece of gold foil is 1.5 g-2.5 g.
A neon color painting drawing method comprises the following steps:
drawing a pattern on the clean surface of a vessel to be drawn by using a prepared pearl bright material hook line according to the creation requirement; filling glass white water material in the line drawing pattern to ensure that the glass white water material is full and does not overflow outside the line; then, baking the pattern in a kiln at 700-740 ℃, and polishing and forming the patterned surface after cooling;
then, pasting the neon color patch on the surface of the composition; dipping a medium fusing agent by a brush pen and coating the medium fusing agent on the surface of the composition paster to obtain a vessel made of the paster; the neon color patch is the neon color gold foil patch in the technical scheme or the neon color gold foil patch prepared by the preparation method in the technical scheme;
finally, drawing and imaging by using ceramic colored drawing pigment, and baking to obtain a finished product of coloring and painting on the neon glaze;
or after the ceramic colored drawing pigment is used for drawing and imaging, a layer of low-temperature transparent glaze is sprayed on the surface of the ceramic colored drawing pigment, and the ceramic colored drawing pigment is dried and baked to obtain a finished product of the neon under-glaze colored drawing.
Preferably, the solvent is a neon color solvent; the neon light medium flux is prepared from a cooked egg yolk leavening agent and an emulsified oil preparation according to the mass ratio of (35-40): (65-60) stirring and mixing;
the yolk leavening agent is prepared from the following components in percentage by mass of 70: (20-22): (5-7): (2-4) mixing the cooked egg yolk, the plant starch, the white sugar and the lactic acid, and then sealing and fermenting for 70-75 hours to obtain the fermented soybean milk;
the emulsified oil preparation is prepared from the following components in percentage by mass: (89-91) mixing the refined beef tallow and the yellow vegetable seeds, and heating and refining.
Preferably, the baking mode comprises an overglaze neon gold color baking and an overglaze neon gold color baking; the temperature of the on-glaze neon gold color baking is 680-720 ℃, and the time is 5-6 h; the temperature of the under-glaze neon gold color baking is 820-860 ℃, and the time is 7-8 hours.
Preferably, the gold foil used for the over-glaze neon gold color baking is prepared from the following components in percentage by mass of 8.3: 1.7, the gold foil used for the under-glaze neon gold decorating baking color consists of gold and brass in a mass ratio of 7.3: 2.7 gold and brass.
Preferably, the dosage of the dipping coating medium flux has a negative correlation with the baking temperature; coating a medium flux on the on-glaze neon gold color baking color for three times and drying the on-glaze neon gold color baking color each time; and coating a medium flux on the under-glaze neon gold color baking color and drying.
The invention provides a neon color gold foil patch and a preparation method and application thereof, wherein the neon color gold foil patch is formed by hammer-grinding a gold foil and seven-color ceramic colored drawing pigment; the gold foil comprises the following components in percentage by mass (8.3-7.3): (1.7-2.7) gold and brass; the colors of the seven-color ceramic colored drawing pigment are red, orange, yellow, green, cyan, blue and purple respectively. Compared with the prior art, the neon color gold foil patch is suitable for neon color painting and neon color set color painting, the finished product has bright and attractive appearance and bright and fine color, and a hidden seven-color neon halo is displayed on the inner layer of the gold texture; the product has bright color picture, stable and saturated color, rich and gorgeous color and clear picture layer, and has unique neon gold visual effect, greatly raised artistic appreciation and commercial value of ceramic utensil.
In addition, the neon color gold foil patch, the neon color drawing method and the neon color multicolor overprinting drawing method provided by the invention can be applied to ceramic surface layers of various colors, and can also be applied to surface layers made of materials such as purple sand, black pottery, Chengni inkstone, glass, crystal, metal and the like; meanwhile, the neon medium flux with the functions of color development and combustion-supporting melting is selected, so that the temperature of the neon color-coated patch is easy to control when the patch is baked, and the color is brighter after the patch is baked.
Drawings
Fig. 1 to 2 are diagrams of a real object of a painting work of a neon gold color set color "sending love wuchu" formed on a ru porcelain blank by using a neon gold color gold foil patch provided by an embodiment of the present invention.
Detailed Description
The technical solutions of the present invention will be described clearly and completely with reference to the following embodiments of the present invention, and it should be understood that the described embodiments are only a part of the embodiments of the present invention, and not all of the embodiments. All other embodiments, which can be derived by a person skilled in the art from the embodiments given herein without making any creative effort, shall fall within the protection scope of the present invention.
The invention provides a neon gold color gold foil patch which is formed by hammer-grinding a gold foil and seven-color ceramic colored drawing pigment;
the gold foil comprises the following components in percentage by mass (8.3-7.3): (1.7-2.7) gold and brass;
the colors of the seven-color ceramic colored drawing pigment are red, orange, yellow, green, cyan, blue and purple respectively.
In the invention, the neon color gold foil patch is formed by hammer-grinding a gold foil and a seven-color ceramic colored drawing pigment. In the invention, the gold foil is prepared from the following components in percentage by mass (8.3-7.3): (1.7-2.7) gold and brass; the highest temperature of the traditional gold foil decoration baking is 600 ℃, and the baking requirement of the neon gold decoration is difficult to meet; according to the invention, the brass with high melting point is mixed with gold according to a certain proportion, so that the temperature of the baked color can be kept consistent after the obtained gold foil is fused with the ceramic colored drawing pigment. In the invention, when the overglaze color pigment is used, the baking temperature is lower, so the mass ratio of gold to copper for manufacturing the gold foil patch is 8.3: 1.7; when the medium-temperature underglaze color pigment is used, the mass ratio of gold to copper for manufacturing the gold foil patch is 7.3 because the baking temperature is higher: 2.7.
in the invention, the colors of the seven-color ceramic colored drawing pigment are red, orange, yellow, green, cyan, blue and purple respectively; namely, the seven-color ceramic colored drawing pigment comprises a red ceramic colored drawing pigment, an orange ceramic colored drawing pigment, a yellow ceramic colored drawing pigment, a green ceramic colored drawing pigment, a cyan ceramic colored drawing pigment, a blue ceramic colored drawing pigment and a purple ceramic colored drawing pigment; the ceramic colored drawing pigment can be both overglaze color pigment and underglaze color pigment.
The sources of gold, brass and seven-color ceramic color drawing pigments used in the technical scheme are not particularly limited by the invention, and commercial products well known to those skilled in the art can be adopted. The present invention is not limited to the hammer milling tool, and a gold foil hammer milling tool known to those skilled in the art may be used.
In the invention, the thickness of the neon color gold foil patch is preferably 0.02 mm-0.08 mm, and more preferably 0.05 mm.
The neon color gold foil patch is used for neon color painting and a neon color set color drawing method, and a finished product has bright and bright color pictures, stable and saturated color, rich and gorgeous color and clear picture layers, has unique visual effect of neon color gold, and greatly improves the artistic appreciation and commercial value of a vessel after color painting.
The invention also provides a preparation method of the neon color gold foil patch in the technical scheme, which comprises the following steps:
a) grinding gold into gold foil by a hammer and grinding the gold foil into copper foil by a brass hammer, respectively shearing the gold foil and the copper foil, mixing, and putting into a crucible for heating and melting to obtain a melt; then cooling the melt, taking out, and hammer-grinding into gold foil with the thickness of 0.1-0.5 mm;
b) dividing the gold foil obtained in the step a) into seven pieces with the length multiplied by the width of (8-12 cm) multiplied by (4-6 cm), respectively filling seven ceramic colored drawing pigments into the seven pieces of gold foil according to different colors, wrapping, and repeatedly kneading and hammer-rolling to obtain seven colors of metal wires; finally twisting the seven colors of metal wires into a spiral strip shape, and hammering to obtain the neon gold foil patch.
Firstly, grinding gold into gold foil by a hammer and grinding the gold foil into copper foil by a brass hammer, respectively shearing the gold foil and the copper foil, mixing, and putting into a crucible for heating and melting to obtain a melt; and then cooling the melt, taking out, and hammer-grinding into gold foil. In the present invention, the purity of the gold is preferably not less than 99.9%, more preferably 99.99%. The sources of the gold and the brass are not particularly limited in the invention, and commercially available products well known to those skilled in the art can be used.
In the invention, the heating and melting temperature is 1050-1100 ℃, and is preferably 1080 ℃.
In the invention, the thickness of the gold foil rolled by the hammer is 0.1 mm-0.5 mm, and preferably 0.3 mm.
After the gold foil is obtained, the obtained gold foil is divided into seven pieces with the length multiplied by the width of (8 cm-12 cm) × (4 cm-6 cm), then seven ceramic colored drawing pigments are respectively filled into the seven pieces of gold foil according to different colors and are wrapped, and metal wires with seven colors are obtained through repeated kneading and hammer milling; finally twisting the seven colors of metal wires into a spiral strip shape, and hammering to obtain the neon gold foil patch. In the invention, the length multiplied by the width of each piece of gold foil is (8 cm-12 cm) × (4 cm-6 cm), preferably 10cm multiplied by 5 cm; the loading amount of the color pigment in each piece of gold foil is preferably 1.5g to 2.5g, and more preferably 2 g.
In the invention, the preferable process of respectively filling the seven-color ceramic colored drawing pigment into seven gold foils according to different colors is as follows:
2g of red, orange, yellow, green, cyan, blue and purple ceramic color drawing pigments are respectively scooped into the gold foil by using a small spoon, then the gold foil filled with the pigments is respectively rolled into a cylinder shape, and two ends of the cylinder are rolled to obtain seven gold foil pigment bars.
In the invention, the diameter of the metal wire is preferably 0.8 mm-1.2 mm, and more preferably 1 mm.
In the invention, the thickness of the neon gold color foil patch obtained by hammer milling is preferably 0.02 mm-0.08 mm, and more preferably 0.05 mm.
The basic raw materials used by the preparation method provided by the invention, such as gold, brass and various ceramic colored drawing pigments, are easy to purchase; meanwhile, the preparation process is simple and convenient to use.
The invention also provides a drawing method of the neon gold colored drawing, which comprises the following steps:
drawing a pattern on the clean surface of a vessel to be drawn by using a prepared pearl bright material hook line according to the creation requirement; filling glass white water material in the line drawing pattern to ensure that the glass white water material is full and does not overflow outside the line; then, baking the pattern in a kiln at 700-740 ℃, and polishing and forming the patterned surface after cooling;
then, pasting the neon color patch on the surface of the composition; dipping a medium fusing agent by a brush pen and coating the medium fusing agent on the surface of the composition paster to obtain a vessel made of the paster; the neon color patch is the neon color gold foil patch in the technical scheme or the neon color gold foil patch prepared by the preparation method in the technical scheme;
finally, drawing and imaging by using ceramic colored drawing pigment, and baking to obtain a finished product of coloring and painting on the neon glaze;
or after the ceramic colored drawing pigment is used for drawing and imaging, a layer of low-temperature transparent glaze is sprayed on the surface of the ceramic colored drawing pigment, and the ceramic colored drawing pigment is dried and baked to obtain a finished product of the neon under-glaze colored drawing.
Firstly, drawing a pattern on the clean surface of a vessel to be drawn by using a prepared pearl bright material hook line according to the creation requirement; filling glass white water material in the line drawing pattern to ensure that the glass white water material is full and does not overflow outside the line; then, the obtained product is placed into a kiln to be baked at the temperature of 700-740 ℃, and after the product is cooled, the patterned surface is polished and formed.
In the invention, the utensil to be drawn preferably comprises common light-color ceramic utensils, dark-color ceramic utensils such as black and the like, and utensils made of materials such as purple sand, black pottery, Chengni inkstone, glass, crystal, metal and the like. The neon gold foil patch provided by the invention can be applied to common light-colored ceramic utensils to draw works, and can also be applied to various dark-colored ceramics, purple sand, black pottery, clear mud inkstone, glass, crystal, metal and other materials to draw and burn the works into golden and bright works.
In the invention, the clean surface of the vessel to be drawn is preferably obtained by wiping and drying the vessel to be drawn.
In the invention, the prepared pearl bright material is preferably prepared from frankincense oil and ceramic colored drawing pearl bright material diluted by camphor oil; the drawing of the line drawing is preferably performed using a line drawing pen well known to those skilled in the art; the filled (patterned) glass white water is preferably applied using a fountain pen well known to those skilled in the art; the thickness of the glass white water filling material is preferably 0.5 mm-1 mm, so that the glass white water filling material is full and cannot overflow out of a line.
In the invention, the temperature of the baking color is 700-740 ℃, and is preferably 720 ℃.
In the present invention, the sanding process is preferably performed using a tool such as sandpaper, which is well known to those skilled in the art.
Then, pasting the neon color patch on the surface of the composition; dipping a medium fusing agent by a brush pen and coating the medium fusing agent on the surface of the composition paster to obtain a vessel made of the paster; the neon color patch is the neon color gold foil patch in the technical scheme or the neon color gold foil patch prepared by the preparation method in the technical scheme. In the invention, the neon color patch is the neon color gold foil patch in the technical scheme or the neon color gold foil patch prepared by the preparation method in the technical scheme.
In the present invention, the neon color patch is preferably applied to the patterned surface for careful smoothing.
In the invention, the solvent is preferably a neon color solvent; preferably, the neon light medium flux is prepared from a cooked egg yolk leavening agent and an emulsified oil preparation according to the mass ratio of (35-40): (65-60), and more preferably, the cooked egg yolk leavening agent and the emulsified oil preparation are mixed according to the mass ratio of 37: 63, stirring and mixing the components according to the proportion of 63.
In the invention, the egg yolk leavening agent is preferably prepared from the following components in a mass ratio of 70: (20-22): (5-7): (2-4) mixing the cooked yolk, the plant starch, the white sugar and the lactic acid, sealing and fermenting for 70-75 h, more preferably mixing 70wt% of cooked yolk, 21wt% of plant starch, 6wt% of white sugar and 3wt% of lactic acid, stirring uniformly, and then filling into a sealed container for fermenting for 72 h.
In the present invention, the emulsified oil preparation is preferably prepared by mixing, by mass, 10: (89-91) mixing the refined beef tallow and the yellow mustard seeds, and then heating to refine, more preferably mixing 10wt% of refined beef tallow and 90wt% of yellow mustard seeds, and then heating to refine.
The sources of the cooked egg yolk, the plant starch, the white sugar, the lactic acid, the refined beef tallow and the rapeseed are not particularly limited, and commercially available products well known to those skilled in the art can be used.
In the invention, the dosage of the dipping and coating medium fusing agent is preferably in a negative correlation with the subsequent baking temperature; the baking temperature of the on-glaze neon gold color baking is low, the amount of the solvent coated by dipping is large, and the solvent is preferably coated for three times and dried each time; the under-glaze neon color baked color has a high baking temperature, and the amount of the solvent coated by dipping is small, so that the solvent is preferably coated once and dried.
The neon medium flux with the functions of color development and combustion-supporting melting is smeared on the surface of the picture composition patch formed by pasting the neon color gold foil patch, so that the temperature of the neon color patch is easy to control during color baking, and acid substances such as glutamic acid, amino acid, fatty acid and the like contained in a cooked yolk leaven can make a neon color finished product baked with the neon color patch noble and bright in image and have a unique visual effect.
After the utensil made of the paster is obtained, the utensil made of the paster is preferably put into a kiln for baking and coloring, and a finished product of the neon color painting is directly obtained.
In order to obtain a finished product of a neon color set colored drawing, after a vessel made of a patch is obtained, a ceramic colored drawing pigment is used for drawing and imaging, and a finished product of a neon glaze colored drawing is obtained after baking;
or after the ceramic colored drawing pigment is used for drawing and imaging, a layer of low-temperature transparent glaze is sprayed on the surface of the ceramic colored drawing pigment, and the ceramic colored drawing pigment is dried and baked to obtain a finished product of the neon under-glaze colored drawing.
The invention has no special limit to the variety and source of the ceramic colored drawing pigment, and can select different kinds of commercial ceramic colored drawing pigments according to the requirements of different neon colored drawings and neon set colored drawing finished products.
In the invention, the preferred baking modes comprise an overglaze neon coloring and an underglaze neon coloring, different temperatures are required to be set according to different pigment attributes for baking, and the baking temperature and time are in an inverse correlation with the ambient temperature. In the invention, the temperature of the over-glaze neon gold color baking is preferably 680-720 ℃, and more preferably 700 ℃; the time for the neon coloring on the glaze is preferably 5-6 h; the temperature of the under-glaze neon gold color baking is preferably 820-860 ℃, and more preferably 840 ℃; the time for baking the under-glaze neon gold color is preferably 7-8 h.
The method for drawing the neon colors and the neon color set can draw and express more colorful creative themes on the vessel to be drawn and the plates made of corresponding materials; the drawn product has bright and delicate color and presents the golden visual effect of golden texture of a seven-color neon halo mask.
The invention provides a neon color gold foil patch and a preparation method and application thereof, wherein the neon color gold foil patch is formed by hammer-grinding a gold foil and seven-color ceramic colored drawing pigment; the gold foil comprises the following components in percentage by mass (8.3-7.3): (1.7-2.7) gold and brass; the colors of the seven-color ceramic colored drawing pigment are red, orange, yellow, green, cyan, blue and purple respectively. Compared with the prior art, the neon color gold foil patch is suitable for neon color painting and neon color set color painting, the finished product has bright and attractive appearance and bright and fine color, and a hidden seven-color neon halo is displayed on the inner layer of the gold texture; the product has bright color picture, stable and saturated color, rich and gorgeous color and clear picture layer, and has unique neon gold visual effect, greatly raised artistic appreciation and commercial value of ceramic utensil.
In addition, the neon color gold foil patch, the neon color drawing method and the neon color multicolor overprinting drawing method provided by the invention can be applied to ceramic surface layers of various colors, and can also be applied to surface layers made of materials such as purple sand, black pottery, Chengni inkstone, glass, crystal, metal and the like; meanwhile, the neon medium flux with the functions of color development and combustion-supporting melting is selected, so that the temperature of the neon color-coated patch is easy to control when the patch is baked, and the color is brighter after the patch is baked.
To further illustrate the present invention, the following examples are provided for illustration. The solvent used in the following examples of the invention is a neon medium solvent, and a cooked yolk leavening agent and an emulsified oil preparation are used according to the mass ratio of 37: 63, wherein the yolk leaven is prepared by uniformly mixing and stirring 70wt% of cooked yolk, 21wt% of plant starch, 6wt% of white sugar and 3wt% of lactic acid, and then putting the mixture into a sealed container for fermentation for 72 hours, and the emulsified oil preparation is prepared by mixing and heating 10wt% of refined beef tallow and 90wt% of yellow rapeseed.
Examples
(1) Grinding gold with the purity of 99.99% into gold foil by a hammer, grinding the gold foil into copper foil by a hammer, respectively cutting the gold foil and the copper foil into fragments according to the mass ratio of 8.3: 1.7, placing the mixture into a crucible, heating the mixture to 1080 ℃ for melting to obtain a melt, taking the melt out after cooling, and hammering the melt into seven gold foils with the thickness of 0.3mm and the length and the width of 10cm multiplied by 5 cm.
(2) Scooping 2g of red, orange, yellow, green, cyan, blue and purple seven-color ceramic color painting pigments into the gold foil by using a small spoon respectively, rolling the gold foil filled with the pigments into a cylindrical shape respectively, and rolling two ends of the gold foil to obtain seven gold foil pigment bars; then, repeatedly kneading and hammering by using a gold foil hammering tool to manufacture metal wires with the diameters of 1 mm; finally twisting the seven-color metal wires into a spiral strip shape, and then hammering the strip into a neon gold color gold foil patch with the thickness of 0.05 mm.
Application examples
The method comprises the following steps of forming a 'sending love Wuchu' drawing decorated by three-dimensional concave-convex neon gold on a Ru porcelain blank body:
firstly, wiping a ceramic vessel clean, airing, and drawing a pattern on the surface of the vessel by using a prepared pearl material; filling glass white water material in the line drawing pattern to ensure that the glass white water material is full and does not overflow outside the line; then the pattern is put into a kiln to be baked at 720 ℃, and the pattern surface is polished and molded after the pattern is cooled.
Then, the neon color gold foil patch provided by the embodiment of the invention is pasted on the surface of the composition; dipping the medium flux with a brush pen and coating the medium flux on the surface of the pattern composition paster (coating the medium flux for three times and drying the medium flux every time) to obtain the ceramic vessel prepared by the paster.
And finally, according to the creative composition design, drawing and imaging by using ceramic colored drawing pigment, and baking at different temperatures (700 ℃ for 5-6 h) in a kiln according to different pigment attributes to obtain a finished product of the neon gold color set coloring 'sending love Wuchu' painting with the low relief composition.
Referring to fig. 1-2, fig. 1-2 are diagrams of a physical object of a painting work of a neon gold color set color "parasitic wuchu" formed on a ru porcelain blank by using a neon gold color gold foil patch provided by an embodiment of the present invention; the formed picture is concave-convex, bright and fine in color, and the inner layer of the golden texture is provided with unique and invisible seven-color rainbow halo.
The previous description of the disclosed embodiments is provided to enable any person skilled in the art to make or use the present invention. Various modifications to these embodiments will be readily apparent to those skilled in the art, and the generic principles defined herein may be applied to other embodiments without departing from the spirit or scope of the invention. Thus, the present invention is not intended to be limited to the embodiments shown herein but is to be accorded the widest scope consistent with the principles and novel features disclosed herein.
Claims (6)
1. A neon color painting drawing method comprises the following steps:
drawing a pattern on the clean surface of a vessel to be drawn by using a prepared pearl bright material hook line according to the creation requirement; filling glass white water material in the line drawing pattern to ensure that the glass white water material is full and does not overflow outside the line; then the obtained product is put into a kiln to be baked at 700-740 ℃, and after the product is cooled, the surface of the composition is polished and formed;
then, pasting the neon color patch on the surface of the composition; dipping a medium fusing agent by a brush pen and coating the medium fusing agent on the surface of the composition paster to obtain a vessel made of the paster; the neon color patch is a neon color gold foil patch; the neon color gold foil patch is formed by hammer-rolling gold foil and seven-color ceramic colored drawing pigment;
the gold foil comprises the following components in percentage by mass (8.3-7.3): (1.7-2.7) gold and brass; the purity of the gold is not lower than 99.9%;
the colors of the seven-color ceramic colored drawing pigment are red, orange, yellow, green, cyan, blue and purple respectively;
the loading amount of the color pigment in each piece of gold foil is 1.5 g-2.5 g;
the preparation method of the neon color gold foil patch comprises the following steps:
a) grinding gold into gold foil by a hammer and grinding the gold foil into copper foil by a brass hammer, respectively shearing the gold foil and the copper foil, mixing, and putting into a crucible for heating and melting to obtain a melt; then cooling the melt, taking out, and hammer-grinding into gold foil with the thickness of 0.1-0.5 mm;
b) dividing the gold foil obtained in the step a) into seven pieces with the length multiplied by the width of (8-12 cm) multiplied by (4-6 cm), respectively filling seven ceramic colored drawing pigments into the seven pieces of gold foil according to different colors, wrapping, and repeatedly kneading and hammer-grinding to obtain seven colors of metal wires; finally twisting the seven colors of metal wires into a spiral strip shape, and hammering to obtain a neon gold foil patch;
the medium flux is a neon color medium flux; the neon light medium flux is prepared from a cooked egg yolk leavening agent and an emulsified oil preparation according to the mass ratio of (35-40): (65-60) stirring and mixing;
the yolk leavening agent is prepared from the following components in percentage by mass of 70: (20-22): (5-7): (2-4) mixing the cooked egg yolk, the plant starch, the white sugar and the lactic acid, and then sealing and fermenting for 70-75 hours to obtain the fermented soybean milk;
the emulsified oil preparation is prepared from the following components in percentage by mass: (89-91) mixing the refined beef tallow and the yellow vegetable seeds, and heating and refining;
finally, drawing and imaging by using ceramic colored drawing pigment, and baking to obtain a finished product of coloring and painting on the neon glaze;
or after the ceramic colored drawing pigment is used for drawing and imaging, a layer of low-temperature transparent glaze is sprayed on the surface of the ceramic colored drawing pigment, and the ceramic colored drawing pigment is dried and baked to obtain a finished product of the neon under-glaze colored drawing.
2. The neon color drawing method according to claim 1, wherein said neon color gold foil patch has a thickness of 0.02mm to 0.08 mm.
3. The neon color drawing method according to claim 1, wherein said temperature for melting by heating is 1050 ℃ to 1100 ℃.
4. The neon color drawing method according to claim 1, wherein said baking means includes an over-glaze neon color baking and an under-glaze neon color baking; the temperature of the on-glaze neon gold color baking is 680-720 ℃, and the time is 5-6 h; the temperature of the under-glaze neon color baking is 820-860 ℃ and the time is 7-8 h.
5. The neon color drawing method of claim 4, wherein said over-glaze neon baking color is made of gold foil having a mass ratio of 8.3: 1.7, the gold foil used for the under-glaze neon gold decorating baking color consists of gold and brass in a mass ratio of 7.3: 2.7 gold and brass.
6. The neon color drawing method according to claim 4, wherein the amount of the dip coating medium flux is in a negative correlation with the baking temperature; coating a medium flux on the on-glaze neon gold color baking color for three times and drying the on-glaze neon gold color baking color each time; and coating a medium flux on the under-glaze neon gold color baking color and drying.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202010258981.5A CN111469588B (en) | 2020-04-03 | 2020-04-03 | Neon color gold foil patch and preparation method and application thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202010258981.5A CN111469588B (en) | 2020-04-03 | 2020-04-03 | Neon color gold foil patch and preparation method and application thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN111469588A CN111469588A (en) | 2020-07-31 |
| CN111469588B true CN111469588B (en) | 2022-03-01 |
Family
ID=71749795
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN202010258981.5A Active CN111469588B (en) | 2020-04-03 | 2020-04-03 | Neon color gold foil patch and preparation method and application thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN111469588B (en) |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN117986044B (en) * | 2024-04-03 | 2024-06-11 | 山东硅元新型材料股份有限公司 | High-siliceous high-grade daily-use fine porcelain with bucket golden color and preparation method thereof |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2003301280A (en) * | 2002-04-10 | 2003-10-24 | Aida Kagaku Kogyo Kk | Ornament and manufacturing method therefor |
| CN1854102A (en) * | 2005-04-21 | 2006-11-01 | 上海一品国际颜料有限公司 | Method of using pigment in concrete products |
| CN101913914A (en) * | 2010-07-19 | 2010-12-15 | 郑州鸿宾木艺有限公司 | Ceramic silver plating process |
| CN106274244A (en) * | 2016-11-07 | 2017-01-04 | 江苏工程职业技术学院 | A kind of draw craft of tempera painting |
-
2020
- 2020-04-03 CN CN202010258981.5A patent/CN111469588B/en active Active
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2003301280A (en) * | 2002-04-10 | 2003-10-24 | Aida Kagaku Kogyo Kk | Ornament and manufacturing method therefor |
| CN1854102A (en) * | 2005-04-21 | 2006-11-01 | 上海一品国际颜料有限公司 | Method of using pigment in concrete products |
| CN101913914A (en) * | 2010-07-19 | 2010-12-15 | 郑州鸿宾木艺有限公司 | Ceramic silver plating process |
| CN106274244A (en) * | 2016-11-07 | 2017-01-04 | 江苏工程职业技术学院 | A kind of draw craft of tempera painting |
Also Published As
| Publication number | Publication date |
|---|---|
| CN111469588A (en) | 2020-07-31 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN103483010B (en) | Wu-tsai manufacture craft under a kind of stereoscopic glaze | |
| CN101804762B (en) | Manufacturing method of embossment layer halftone and manufacturing method of famille-rose embossment porcelain | |
| CN101879834B (en) | Decoration method capable of forming raised picture on ceramic green body | |
| CN102602216B (en) | Method for manufacturing enamel painted porcelain | |
| CN115583844A (en) | Dark-engraved decorative dry-grain fully-polished ceramic tile and preparation method thereof | |
| CN111469588B (en) | Neon color gold foil patch and preparation method and application thereof | |
| CN101987556A (en) | Surface decoration method of ceramic artwork | |
| CN104496543B (en) | On a kind of ceramic glaze, caidiao opera preparation and glaze float color method for drafting | |
| CN104387120A (en) | Ceramic underglaze five-color silk screen transfer printing method | |
| CN106590036B (en) | It is a kind of for the composition of Ceramic Painting, its preparation method and Ceramic Painting method | |
| CN106083212A (en) | A kind of infiltration ink Novel marble ceramic and preparation method thereof | |
| CN111152346A (en) | Preparation method of gold-jade-embedded ceramic | |
| CN103159506B (en) | High-temperature ceramic grisaille painting decorating method | |
| CN107311613A (en) | A kind of tooth boat pottery underglaze colour manufacture craft | |
| CN113800952B (en) | Glazed tile with artistic effect and preparation method thereof | |
| CN111440009B (en) | Warm-color jade-like crystal paste for ceramic jade bead colored drawing and preparation method and application thereof | |
| CN102161597B (en) | Production method of ceramic with imitated Indian red stone stripe | |
| CN103073274A (en) | Manufacturing method for tiny mosaic electroplated decoration display artistic ceramic | |
| CN111302626B (en) | Ceramic base film molding paste, preparation method thereof and crystal stack color drawing method | |
| CN105541414A (en) | Method for forming hand-painted texture pattern with uneven color depth through transmutation glaze beat-coating with colored glaze | |
| CN102001867B (en) | Manufacturing method of imitated sesame stone ceramic | |
| CN111302628B (en) | Cold-color jade-like crystal paste for ceramic jade bead colored drawing and preparation method and application thereof | |
| CN111348938B (en) | Moyu color painting pigment and preparation method and application thereof | |
| CN106316465B (en) | The high relief Guang colors technique of one kind production | |
| CN108752053A (en) | A kind of high temperature color glaze and blue and white porcelain mixing burn and make new process |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| GR01 | Patent grant | ||
| GR01 | Patent grant |