CN106083212A - A kind of infiltration ink Novel marble ceramic and preparation method thereof - Google Patents
A kind of infiltration ink Novel marble ceramic and preparation method thereof Download PDFInfo
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- CN106083212A CN106083212A CN201610393997.0A CN201610393997A CN106083212A CN 106083212 A CN106083212 A CN 106083212A CN 201610393997 A CN201610393997 A CN 201610393997A CN 106083212 A CN106083212 A CN 106083212A
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- Prior art keywords
- irregularly shaped
- starch adhesive
- marble ceramic
- ink
- ceramic
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- 239000000919 ceramic Substances 0.000 title claims abstract description 50
- 239000004579 marble Substances 0.000 title claims abstract description 38
- 230000008595 infiltration Effects 0.000 title claims abstract description 30
- 238000001764 infiltration Methods 0.000 title claims abstract description 30
- 238000002360 preparation method Methods 0.000 title claims abstract description 9
- 229920002472 Starch Polymers 0.000 claims abstract description 34
- 239000008107 starch Substances 0.000 claims abstract description 34
- 235000019698 starch Nutrition 0.000 claims abstract description 34
- 230000000994 depressogenic effect Effects 0.000 claims abstract description 20
- 239000010410 layer Substances 0.000 claims abstract description 17
- 238000004519 manufacturing process Methods 0.000 claims abstract description 16
- 238000007639 printing Methods 0.000 claims abstract description 14
- 239000002994 raw material Substances 0.000 claims abstract description 14
- 239000007921 spray Substances 0.000 claims abstract description 13
- 239000012790 adhesive layer Substances 0.000 claims abstract description 12
- 238000000034 method Methods 0.000 claims description 34
- 239000000853 adhesive Substances 0.000 claims description 22
- 230000001070 adhesive effect Effects 0.000 claims description 22
- 239000003292 glue Substances 0.000 claims description 16
- 239000000758 substrate Substances 0.000 claims description 13
- 239000000047 product Substances 0.000 claims description 11
- 238000007650 screen-printing Methods 0.000 claims description 9
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 claims description 8
- 239000000203 mixture Substances 0.000 claims description 8
- 239000002002 slurry Substances 0.000 claims description 8
- 230000005540 biological transmission Effects 0.000 claims description 7
- 238000005498 polishing Methods 0.000 claims description 7
- 239000011265 semifinished product Substances 0.000 claims description 7
- 238000013461 design Methods 0.000 claims description 6
- 238000007688 edging Methods 0.000 claims description 5
- 229910052573 porcelain Inorganic materials 0.000 claims description 5
- 239000005543 nano-size silicon particle Substances 0.000 claims description 4
- 239000000843 powder Substances 0.000 claims description 4
- 239000011787 zinc oxide Substances 0.000 claims description 4
- GFQYVLUOOAAOGM-UHFFFAOYSA-N zirconium(iv) silicate Chemical compound [Zr+4].[O-][Si]([O-])([O-])[O-] GFQYVLUOOAAOGM-UHFFFAOYSA-N 0.000 claims description 4
- 230000001788 irregular Effects 0.000 claims description 3
- 238000010020 roller printing Methods 0.000 claims description 3
- ODIGIKRIUKFKHP-UHFFFAOYSA-N (n-propan-2-yloxycarbonylanilino) acetate Chemical compound CC(C)OC(=O)N(OC(C)=O)C1=CC=CC=C1 ODIGIKRIUKFKHP-UHFFFAOYSA-N 0.000 claims description 2
- JPVYNHNXODAKFH-UHFFFAOYSA-N Cu2+ Chemical compound [Cu+2] JPVYNHNXODAKFH-UHFFFAOYSA-N 0.000 claims description 2
- 229910001430 chromium ion Inorganic materials 0.000 claims description 2
- 229910001431 copper ion Inorganic materials 0.000 claims description 2
- 230000008878 coupling Effects 0.000 claims description 2
- 238000010168 coupling process Methods 0.000 claims description 2
- 238000005859 coupling reaction Methods 0.000 claims description 2
- 239000006071 cream Substances 0.000 claims description 2
- 150000002148 esters Chemical class 0.000 claims description 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N iron Substances [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 2
- 229910052742 iron Inorganic materials 0.000 claims description 2
- -1 iron ion Chemical class 0.000 claims description 2
- 241000790917 Dioxys <bee> Species 0.000 claims 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims 1
- 239000010941 cobalt Substances 0.000 claims 1
- 229910017052 cobalt Inorganic materials 0.000 claims 1
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 claims 1
- 239000010936 titanium Substances 0.000 claims 1
- 229910052719 titanium Inorganic materials 0.000 claims 1
- 239000004575 stone Substances 0.000 abstract description 3
- 230000000694 effects Effects 0.000 description 16
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 13
- 239000000463 material Substances 0.000 description 11
- PNEYBMLMFCGWSK-UHFFFAOYSA-N Alumina Chemical compound [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 6
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 6
- 238000005516 engineering process Methods 0.000 description 6
- 235000012239 silicon dioxide Nutrition 0.000 description 6
- BRPQOXSCLDDYGP-UHFFFAOYSA-N calcium oxide Chemical compound [O-2].[Ca+2] BRPQOXSCLDDYGP-UHFFFAOYSA-N 0.000 description 4
- 239000000292 calcium oxide Substances 0.000 description 4
- ODINCKMPIJJUCX-UHFFFAOYSA-N calcium oxide Inorganic materials [Ca]=O ODINCKMPIJJUCX-UHFFFAOYSA-N 0.000 description 4
- 239000012535 impurity Substances 0.000 description 4
- 239000000395 magnesium oxide Substances 0.000 description 4
- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 4
- AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 description 4
- CHWRSCGUEQEHOH-UHFFFAOYSA-N potassium oxide Chemical compound [O-2].[K+].[K+] CHWRSCGUEQEHOH-UHFFFAOYSA-N 0.000 description 4
- 229910001950 potassium oxide Inorganic materials 0.000 description 4
- 239000000377 silicon dioxide Substances 0.000 description 4
- 229910001948 sodium oxide Inorganic materials 0.000 description 4
- KKCBUQHMOMHUOY-UHFFFAOYSA-N sodium oxide Chemical compound [O-2].[Na+].[Na+] KKCBUQHMOMHUOY-UHFFFAOYSA-N 0.000 description 4
- 210000003298 dental enamel Anatomy 0.000 description 3
- 238000011161 development Methods 0.000 description 3
- 229910052751 metal Inorganic materials 0.000 description 3
- 239000002184 metal Substances 0.000 description 3
- 238000012545 processing Methods 0.000 description 3
- 239000004576 sand Substances 0.000 description 3
- 239000004408 titanium dioxide Substances 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- 239000005995 Aluminium silicate Substances 0.000 description 2
- 208000013668 Facial cleft Diseases 0.000 description 2
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 2
- 229910052782 aluminium Inorganic materials 0.000 description 2
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 2
- 235000012211 aluminium silicate Nutrition 0.000 description 2
- 229910052925 anhydrite Inorganic materials 0.000 description 2
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 2
- 230000009286 beneficial effect Effects 0.000 description 2
- OSGAYBCDTDRGGQ-UHFFFAOYSA-L calcium sulfate Chemical compound [Ca+2].[O-]S([O-])(=O)=O OSGAYBCDTDRGGQ-UHFFFAOYSA-L 0.000 description 2
- 238000005034 decoration Methods 0.000 description 2
- 230000007613 environmental effect Effects 0.000 description 2
- 238000010304 firing Methods 0.000 description 2
- 238000009472 formulation Methods 0.000 description 2
- 238000000227 grinding Methods 0.000 description 2
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 229910052760 oxygen Inorganic materials 0.000 description 2
- 239000001301 oxygen Substances 0.000 description 2
- 230000035515 penetration Effects 0.000 description 2
- 239000010453 quartz Substances 0.000 description 2
- 239000002918 waste heat Substances 0.000 description 2
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 description 1
- 238000005299 abrasion Methods 0.000 description 1
- 229910052787 antimony Inorganic materials 0.000 description 1
- WATWJIUSRGPENY-UHFFFAOYSA-N antimony atom Chemical compound [Sb] WATWJIUSRGPENY-UHFFFAOYSA-N 0.000 description 1
- 239000002928 artificial marble Substances 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 238000009954 braiding Methods 0.000 description 1
- 239000011449 brick Substances 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 229910001429 cobalt ion Inorganic materials 0.000 description 1
- XLJKHNWPARRRJB-UHFFFAOYSA-N cobalt(2+) Chemical compound [Co+2] XLJKHNWPARRRJB-UHFFFAOYSA-N 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 238000009792 diffusion process Methods 0.000 description 1
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 1
- 229910052737 gold Inorganic materials 0.000 description 1
- 239000010931 gold Substances 0.000 description 1
- 230000010354 integration Effects 0.000 description 1
- 230000009191 jumping Effects 0.000 description 1
- 239000007791 liquid phase Substances 0.000 description 1
- 229910052750 molybdenum Inorganic materials 0.000 description 1
- 239000011733 molybdenum Substances 0.000 description 1
- 238000000465 moulding Methods 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- 238000007665 sagging Methods 0.000 description 1
- 238000005245 sintering Methods 0.000 description 1
- 238000004513 sizing Methods 0.000 description 1
- 230000036548 skin texture Effects 0.000 description 1
- 239000002344 surface layer Substances 0.000 description 1
- 229910052720 vanadium Inorganic materials 0.000 description 1
- LEONUFNNVUYDNQ-UHFFFAOYSA-N vanadium atom Chemical compound [V] LEONUFNNVUYDNQ-UHFFFAOYSA-N 0.000 description 1
- 230000000007 visual effect Effects 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/45—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
- C04B41/52—Multiple coating or impregnating multiple coating or impregnating with the same composition or with compositions only differing in the concentration of the constituents, is classified as single coating or impregnation
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B33/00—Clay-wares
- C04B33/02—Preparing or treating the raw materials individually or as batches
- C04B33/04—Clay; Kaolin
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B33/00—Clay-wares
- C04B33/02—Preparing or treating the raw materials individually or as batches
- C04B33/13—Compounding ingredients
- C04B33/131—Inorganic additives
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/80—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone of only ceramics
- C04B41/81—Coating or impregnation
- C04B41/89—Coating or impregnation for obtaining at least two superposed coatings having different compositions
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
- C04B2235/30—Constituents and secondary phases not being of a fibrous nature
- C04B2235/32—Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
- C04B2235/3201—Alkali metal oxides or oxide-forming salts thereof
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
- C04B2235/30—Constituents and secondary phases not being of a fibrous nature
- C04B2235/32—Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
- C04B2235/3205—Alkaline earth oxides or oxide forming salts thereof, e.g. beryllium oxide
- C04B2235/3206—Magnesium oxides or oxide-forming salts thereof
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
- C04B2235/30—Constituents and secondary phases not being of a fibrous nature
- C04B2235/32—Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
- C04B2235/3205—Alkaline earth oxides or oxide forming salts thereof, e.g. beryllium oxide
- C04B2235/3208—Calcium oxide or oxide-forming salts thereof, e.g. lime
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
- C04B2235/30—Constituents and secondary phases not being of a fibrous nature
- C04B2235/32—Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
- C04B2235/3217—Aluminum oxide or oxide forming salts thereof, e.g. bauxite, alpha-alumina
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
- C04B2235/30—Constituents and secondary phases not being of a fibrous nature
- C04B2235/34—Non-metal oxides, non-metal mixed oxides, or salts thereof that form the non-metal oxides upon heating, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
- C04B2235/3418—Silicon oxide, silicic acids or oxide forming salts thereof, e.g. silica sol, fused silica, silica fume, cristobalite, quartz or flint
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Ceramic Engineering (AREA)
- Materials Engineering (AREA)
- Structural Engineering (AREA)
- Organic Chemistry (AREA)
- Dispersion Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Finishing Walls (AREA)
- Printing Methods (AREA)
Abstract
The present invention relates to a kind of infiltration ink Novel marble ceramic and preparation method thereof, wherein marble ceramic comprises green body layer and top layer, top layer is containing the starch adhesive layer being formed multicolour pattern by infiltration ink, it is characterized in that: described product surface has length, width, recessed linear slit not of uniform size and/or irregularly shaped depressed area, the lower recess seam of every square metre of area and/or the quantity of irregularly shaped depressed area are more than or equal to 10, lower recess seam and/or irregularly shaped depressed area length are more than or equal to 10mm, the width of lower recess seam and/or irregularly shaped depressed area is less than or equal to 1mm.Achieve the surface at blank raw material, have digital spray printing to copy the natural pattern of stone texture, and some fine linear slit texture and/or the parian pattern texture Ceramic Tiles goods in irregularly shaped recess patterns district and production methods of sinking.
Description
Technical field
The present invention relates to building ceramic tiles field, particularly relate to a kind of infiltration ink Novel marble ceramic and system thereof
Make method.
Background technology
In modern architecture finishing, rank the ornament materials of top fitting position, no more than high-grade lithotome, pattern shape
State is natural, and especially such as high-grade marble, texture is the most resistance to be seen.But along with people's attention to scarce resource, the attention to environmental protection,
In construction and decoration, people are intended to selection, and to have environmental protection "dead" and meet modern society low-carbon green economic development tide
Stream, can there is again the durability ornament materials that the decoration of fine household is enjoyed, particularly through the Ceramic Tiles of high-temperature firing
Goods.
Along with the current Ceramic Tiles in market copies the prevailing of Natural stone material product, the grade of consumer the most increasingly improves, people
It is not only required more preferably from the rich colors of vision, but also require that it has the aesthetic effect of three-dimensional concavo-convex level,
The marbling effect of careful linear slit texture, even has the effect requirements of sense of touch.
To this end, the developer in building ceramic tiles field, it is all that the marble ceramic of imitated fine textures is doing
Effort.
The practice that existing Ceramic Tiles technique is current is that to use male and female mold be directly concave-convex effect or green compact to green brick forming
Just producing predetermined concave-convex effect moulding during grinding and polishing, insider knows, uses press directly to use formed in mould method, by
The demoulding is needed to enter subsequent processing, if the concaveconvex shape of mould is narrow after great tonnage press is suppressed, it is easy to viscous
Mould, so it is hardly formed tiny linear slit and region, particularly in the depression being even less than about 1mm width less than 2mm
Linear slit district is difficulty with especially.And the method using green compact grinding and polishing, it is the mode of machinery, one, the linear slit of formation is with irregular
The texture of shape is single, the most stiff, and green compact will be caused certain external force to damage by its two mechanical system, and breakage rate will
The highest, this is also unsuitable for industrialized great production.So, prior art directly forms sagging linear slit with irregular in billet surface
The effect in recess patterns district, the finest, Shortcomings.
Other common methods forming irregularly shaped depressed area and linear slit texture are, by lower collapsible ink or glaze
The method of subregion superposition or spray printing glue burn the mode of mistake volatilization to be carried out.Middle promulgated by the State Council such as Publication No. CN104309223
Described in bright patent application " a kind of Ceramic Tiles with braiding skin texture and production method thereof ", by the ink of high temperature low surface tension
Underwater gold belongs to the compound of vanadium (or molybdenum or nickel or antimony) and cover-coat enamel and has the difference of suitable high temperature viscosity and interfacial tension, from
And the liquid phase making the ink that high temperature viscosity is low be formed is absorbed in the cover-coat enamel that surface tension is big dissolving and diffusion package is trapped among around cover-coat enamel
Form concave affect；And the open a kind of Ceramics Ceramic glaze generation of Chinese invention patent application of publication number CN1587145
The method of granular relief, it uses the method for glaze subregion superposition；Also having one is at billet surface spray printing glue
Forming texture, the mode forming sink linear slit and irregularly shaped pattern district when high temperature after the mistake volatilization of these glue burning is carried out.
The above method, it is all the goods at conventional impermeable ink, and comes real by the marzacotto surface that routine is general
Existing.Insider both knows about, and translucent and marzacotto surface is all the most wear-resisting.So so that answering of these goods
Also great limitation is received in.
Summary of the invention
Because the problems referred to above existing for prior art, especially in the effect of the fine textures making marble products
It is difficult to, or is capable of but is limited by the limitation of the physicochemical properties such as product surface is the most wear-resisting that frit material is formed and asks
Topic, the present invention provides a kind of infiltration ink Novel marble ceramic and preparation method thereof, it is achieved that matching with base substrate
Fine linear slit texture and/or the irregularly shaped depression figure of sinking of top layer starch adhesive layer generation being formed pattern by infiltration ink of character
The artificial marble ceramic glazed tile goods in case district, because the raw material of top layer starch adhesive layer is the base substrate composition being matched with under it forms high temperature burning
Knot, surface is not conventional glaze layer, so, product of the present invention has more high abrasion, high rigidity physicochemical property.
For solving above-mentioned technical problem, the invention provides a kind of infiltration ink Novel marble ceramic, its feature
Being that marble ceramic comprises green body layer and top layer, top layer is containing the starch adhesive layer being formed multicolour pattern by infiltration ink,
It is characterized in that: described product surface has length, width, recessed linear slit not of uniform size and/or irregularly shaped depressed area, often
The lower recess seam of square metre area and/or the quantity of irregularly shaped depressed area more than or equal to 10, lower recess seam and/or do not advise
Then shaped depressions section length is more than or equal to 10mm, and the width of lower recess seam and/or irregularly shaped depressed area is less than or equal to 1mm..
Preferably, above-mentioned marble ceramic, it is characterised in that green body layer is formed by different colour porcelain powders
The green body layer of entire body pattern.
Preferably, above-mentioned marble ceramic, it is characterised in that recessed linear slit and/or irregularly shaped depressed area are recessed
The state of falling into.
Preferably, above-mentioned marble ceramic, it is characterised in that recessed linear slit and/or irregularly shaped depressed area are portion
Point or be all filled in glaze, clear frit, dry granular, the colored slurry prepared in advance one or more.
Preferably, above-mentioned marble ceramic, it is characterised in that infiltration ink be by or iron ion or cobalt ion or
Acylate that chromium ion or copper ion are formed and the mixture of ester.
Preferably, above-mentioned marble ceramic, it is characterised in that the thickness of starch adhesive layer is 0.1mm-1mm.
Preferably, above-mentioned marble ceramic, it is characterised in that in starch adhesive layer raw material containing zinc oxide, titanium dioxide,
At least one in Zirconium orthosilicate. or nano silicon.
Preferably, above-mentioned marble ceramic, it is characterised in that in starch adhesive layer containing white, redness, black, yellow,
Two or more in orange, blue or other color slips.
Present invention also offers the manufacture method of above-mentioned marble ceramic, it is characterised in that the method includes following step
Rapid:
(1) the mesh numeral system passed through by design and coupling slurry is standby containing length, width, lower recess not of uniform size seam
And/or the enclosed area of irregularly shaped depressed area, other region is the silk screen by district；
(2) technique and raw material are prepared base substrate and are dried routinely；
(3) preparation starch adhesive；
(4) use the silk screen of step (1) that the starch adhesive of step (3) is executed the billet surface being dried being printed on step (2)；
(5) adobe after applying starch adhesive carries out second time and is dried；
(6) layout spray printing infiltration ink is pressed；
(7) enter into highest temperature district to reach in the kiln of 1180 DEG C-1240 DEG C and fire, obtain permeating ink marmorean half and become
Product；
(8) semi-finished product are carried out soft throwing/or full polishing, edging, i.e. prepares marble ceramic.
Preferably, in above-mentioned manufacture method, between step (6) and (7), also include through no less than 10 minutes, not surpassing
Cross the transmission time course on the pipeline of 2 hours；
Preferably, in above-mentioned manufacture method, in the starch adhesive of step (3) possibly together be suitable for silk screen printing conventional stamp-pad ink,
Print cream or glue.
Preferably, in above-mentioned manufacture method, after step (4) silk-screen or after step (6) before step (7),
Carry out being coated with the print glaze of different color, translucent dry granular or frit to the lower recess seam formed and/or irregularly shaped depressed area
Raw material, is formed and fills.
Preferably, in above-mentioned manufacture method, step (4) is pressed layout and is used digital spray printing, silk screen printing or roller print
Brush mode is printed glue and is formed some lower recess seam of projection and/or irregularly shaped texture, then drenches the starch adhesive executing step (3).
Preferably, in above-mentioned manufacture method, described silk screen printing changes roller printing into.
Beneficial effects of the present invention is as described below:
First, the present invention proposes a kind of infiltration ink Novel marble ceramic and preparation method thereof pioneeringly, real
Show the surface at blank raw material, have digital spray printing to copy the natural pattern of stone texture, and some fine linear slits that sink
The parian pattern texture Ceramic Tiles goods in texture and/or irregularly shaped recess patterns district and production method.
Second, due to top layer of the present invention starch adhesive use be matched with lower floor's porcelain body recipe mud sand material preparation former
Material carries out manufacturing, the unification of upper and lower formula, is provided with preferably sintering and vitreous characteristic, breaches existing Ceramic Tiles system
Product the most simply use carry out on transparent glaze cave in connection with production of structures to copy the limitation of the technical method of natural marble, also break through
The limitation that the surface of traditional glaze process product is the most wear-resisting.
3rd, the bulk pattern that the present invention uses is that infiltration ink spray printing is formed, and ink is to be seeped into from billet surface
In base substrate, it is not necessary to apply the process of glaze protection on surface；This can only need in billet surface by spray printing with conventional ceramic ink
It is different that glaze to be applied carries out protecting.The present invention is the pattern formed in the billet surface of vitreous, and texture texture is more aobvious
Natural, as interior growth forms.
4th, present invention employs entire body pattern feed dividing-distributing technology so that product is more complete in the structure from face to base substrate
There is to face the effect of imitated lithotome.
The present invention, based on the slurry of body recipe, innovatively have employed infiltration ink, spray printing/silk-screen/or roller print
The integration of technology, it is achieved that produce on base substrate quality surface and such as the marmorean fine depression linear slit texture of glaze technique and do not advise
The then goods of the effect of shaped depressions pattern and manufacture method, this is that prior art does not the most disclose and proposes, be non-aobvious and
It is clear to, there is significant novelty and practicality and creativeness.
Hereinafter, by specific embodiment so that the present invention and concrete grammar thereof are better described.
Embodiment 1
(1) selecting the mud sand plain material such as Kaolin, Anhydrite, quartz, ceramic process prepares base substrate porcelain powder routinely, formula
Percentage by weight consist of silicon dioxide 67%, aluminium oxide 21%, potassium oxide+sodium oxide 6%, calcium oxide+magnesium oxide 1.5%,
Other is igloss and trace impurity, standby；
(2) by being matched with the recipe requirements of above-mentioned blank raw material, formulation weight percentage ratio consists of silicon dioxide 70%, oxygen
Change aluminum 20%, potassium oxide+sodium oxide 8%, calcium oxide+magnesium oxide 0.5%, other be igloss and trace impurity, at this slurry
In add in zinc oxide, titanium dioxide, Zirconium orthosilicate. or nano silicon by proper ratio again at least one promote ink
The requirement of water color development, pressed 200 mesh screen residues within 0.5%, and proportion is at 1.80g/3, prepare starch adhesive, the present embodiment uses
It is the mode of silk screen printing, so, it is furthermore preferred that be deployed into the conventional stamp-pad ink used as medium in starch adhesive again, it is allowed to
Certain viscosity, is beneficial to silk screen printing or the control of roller printing, standby；
(3) by design containing some length, width, not of uniform size irregularly shaped for enclosed area, other is
Mesh number is that 100 purposes pass through district, prepares silk screen stand-by；
(4) ceramic tile blank of above-mentioned blank raw material being produced in conventional fashion and is dried, baking temperature is at 80 DEG C-250
DEG C, dry out the transmission of backward subsequent processing；
(5) the dry base come when transmission cools to 50 DEG C-80 DEG C, and the present embodiment is when 60 DEG C-70 DEG C, uses step
(3) starch adhesive of step (2) is executed and is printed on step (4) base temperature afterwards on the dry base substrate surface of 60 DEG C-70 DEG C by silk screen, thus is formed
By fine depression linear slit texture and the irregularly shaped recess patterns district of design on slurry surface layer, starch adhesive weight about reaches 1.3
㎏/㎡；
(6) adobe after applying starch adhesive is input into and is dried into second time；Here the temperature of redrying is carried out at 40 DEG C-180
DEG C, it is highly preferred that control to keep about 35 minutes at 130 DEG C-160 DEG C, redrying uses the waste heat of kiln to utilize, with more
Save the consumption of the energy, if the being dried the step for of not carrying out, actual production can be easy to matter such as producing facial cleft, limit is split
Amount problem；
(7) to be applied and the starch adhesive that defines fine depression texture adobe transmission arrives ink jet printer and base temperature 40
Under conditions of DEG C about-50 DEG C, by layout spray printing infiltration ink and permeation-promoter, and enter in the glaze line of a segment distance and reach
To the time course of about 40 minutes, so that being seeped in base under infiltration ink；
(8) through the pattern base substrate of about 40 minutes times of penetration, enter into highest temperature district and reach the kiln of 1180 DEG C-1240 DEG C
In fire, i.e. prepare the infiltration ink with fine depression linear slit and/or irregularly shaped pattern district texture marmorean half and become
Product.
(9) semi-finished product are carried out soft throwing/or full polishing, edging, i.e. prepares the infiltration ink Novel marble of the present invention
Or sheen or the goods of light.
Embodiment 2
(1) selecting the mud sand plain material such as Kaolin, Anhydrite, quartz, ceramic process prepares base substrate porcelain powder routinely, formula
Percentage by weight consist of silicon dioxide 67%, aluminium oxide 21%, potassium oxide+sodium oxide 6%, calcium oxide+magnesium oxide 1.5%,
Other is igloss and trace impurity, standby；
(2) by being matched with the recipe requirements of above-mentioned blank raw material, formulation weight percentage ratio consists of silicon dioxide 70%, oxygen
Change aluminum 20%, potassium oxide+sodium oxide 8%, calcium oxide+magnesium oxide 0.5%, other be igloss and trace impurity, at this slurry
In add in zinc oxide, titanium dioxide, Zirconium orthosilicate. or nano silicon by proper ratio again at least one promote ink
The requirement of water color development, pressed 200 mesh screen residues within 0.5%, and proportion is at 1.80g/3, prepare starch adhesive；Get routine ready simultaneously
For silk screen printing and glue that mistake can be burnt in high temperature burns till, as medium, standby；
(3) by design containing some length, width, linear slit not of uniform size be mesh number be 140 mesh by district, its
Its enclosed area, prepares silk screen stand-by；
(4) ceramic tile blank of above-mentioned blank raw material being produced in conventional fashion and is dried, baking temperature is at 80 DEG C-250
DEG C, dry out the transmission of backward subsequent processing；
(5) the dry base come when transmission cools to 50 DEG C-80 DEG C, and the present embodiment is when 60 DEG C-70 DEG C, uses step
(3) glue of step (2) is executed and is printed on step (4) base temperature afterwards and forms projection on the dry base substrate surface of 60 DEG C-70 DEG C by silk screen
Texture, enter into pouring sizing process with that, the starch adhesive of step (2) is executed pouring having the billet surface of glue raised textural, from
And define containing by the fine linear slit texture formed by glue of design and the starch adhesive floor in irregularly shaped pattern district, execute
The weight drenching starch adhesive is about 1.3/；
(6) adobe after applying starch adhesive is input into and is dried into second time；Here the temperature of redrying is carried out at 40 DEG C-180
DEG C, it is highly preferred that control to keep about 35 minutes at 130 DEG C-160 DEG C, redrying uses the waste heat of kiln to utilize, with more
Save the consumption of the energy, if the being dried the step for of not carrying out, actual production can be easy to matter such as producing facial cleft, limit is split
Amount problem；
(7), under conditions of redrying adobe out cools to 40 DEG C about-50 DEG C base temperature, ooze by layout spray printing
Strike through water and permeation-promoter, and enter into the time course reaching about 40 minutes in the glaze line of a segment distance, so that under infiltration ink
It is seeped in base；
(8) through the pattern base substrate of about 40 minutes times of penetration, enter into highest temperature district and reach the kiln of 1180 DEG C-1240 DEG C
In fire, during high-temperature firing, the glue of low temperature composition can burn mistake, thus defines in the former position being printed on glue recessed
Fall into, i.e. prepare with fine depression linear slit and/or the marmorean semi-finished product of infiltration ink of irregularly shaped pattern district texture.
(9) semi-finished product are carried out soft throwing/or full polishing, edging, i.e. prepares the infiltration ink Novel marble of the present invention
Or sheen or the goods of light.
It is furthermore preferred that in the present embodiment, it is also possible to use interpolation in glue to be deployed into dry granular, metal glaze, frit
Material composition, defines after the glue of low temperature composition burns mistake, creates with dry granular, metal glaze in the former position being printed on glue
Semi-finished product are carried out soft throwing/or full polishing, edging by material, the grain effect of frit material characteristic, i.e. prepare a kind of infiltration of the present invention
Ink Novel marble or sheen or the goods of light.
Embodiment 3
To embodiment 1 after step (5) silk-screen or before the entrance kiln of step (7) step (8) afterwards burns till,
That the linear slit of some depressions formed and/or irregularly shaped depressed area carry out being coated with print different color or glaze or translucent
Dry granular or frit raw material, formed and fill, and also can be in the way of using jumping version commonly used in the trade, it will makes depression texture shape
Become more rich containing metal glaze effect, clear frit effect, transparent texture effect.
The marble ceramic that embodiment 1-3 prepares is because being provided with lower recess by the starch adhesive layer of infiltration ink
Seam or irregularly shaped depressed area, it not only realizes the marbling effect on ceramic surface, and because uses infiltration ink
The visual effect achieving lower recess seam or irregularly shaped depressed area is the most true to nature, in gap and the color coordination of infiltration ink
Aspect completely outstripped the simple effect permeating ink, enhances the third dimension of color, and also enhances gap or fill seam
The sense of reality of gap, the combination of two kinds of technology makes marbling effect be greatly improved.
The above, merely to the preferable preferred embodiment of the explanation present invention, but it is not to the present invention
Protection domain have any restriction, anyone familiar with this technology is changed possibly also with the technology contents of the disclosure above
Or it is modified to the Equivalent embodiments of equivalent variations, one infiltration ink Novel marble can be implemented by difference requirement and performance
Ceramic and preparation method thereof.Visible, within every content without departing from technical solution of the present invention, especially claim
Hold, any simple modification above example made according to the technical spirit of the present invention, equivalent variations and modification, the most still belong to this
In the range of inventive technique scheme.
Claims (14)
1. an infiltration ink Novel marble ceramic, it is characterised in that marble ceramic comprises green body layer and table
Layer, top layer is containing the starch adhesive layer being formed multicolour pattern by infiltration ink, it is characterised in that: described product surface has length, width
Recessed linear slit narrow, not of uniform size and/or irregularly shaped depressed area, the lower recess of every square metre of area is stitched and/or irregular
The quantity in shaped depressions district is more than or equal to 10, and lower recess seam and/or irregularly shaped depressed area length are more than or equal to 10mm, under
The width of depression seam and/or irregularly shaped depressed area is less than or equal to 1mm.
Marble ceramic the most according to claim 1, it is characterised in that green body layer is by different colour porcelain powders
The green body layer of the entire body pattern formed.
Marble ceramic the most according to claim 1, it is characterised in that recessed linear slit and/or irregularly shaped depression
District is etat lacunaire.
Marble ceramic the most according to claim 1, it is characterised in that recessed linear slit and/or irregularly shaped depression
District is partly or entirely to be filled in glaze, clear frit, dry granular, the colored slurry prepared in advance one or more.
Marble ceramic the most according to claim 1, it is characterised in that infiltration ink be by or iron ion or cobalt from
Acylate that son or chromium ion or copper ion are formed and the mixture of ester.
Marble ceramic the most according to claim 1, it is characterised in that the thickness of starch adhesive layer is 0.1mm-1mm.
Marble ceramic the most according to claim 1, it is characterised in that containing zinc oxide, dioxy in starch adhesive layer raw material
Change at least one in titanium, Zirconium orthosilicate. or nano silicon.
Marble ceramic the most according to claim 1, it is characterised in that in starch adhesive layer containing white, redness, black,
Two or more in yellow, orange, blue or other color slips.
The manufacture method of marble ceramic the most according to claim 1, it is characterised in that the method includes following step
Rapid:
(1) by design and the coupling mesh numeral system passed through of slurry standby containing length, width, lower recess not of uniform size seam and/
Or the enclosed area of irregularly shaped depressed area, other region is the silk screen by district；
(2) technique and raw material are prepared base substrate and are dried routinely；
(3) preparation starch adhesive；
(4) use the silk screen of step (1) that the starch adhesive of step (3) is executed the billet surface being dried being printed on step (2)；
(5) adobe after applying starch adhesive carries out second time and is dried；
(6) layout spray printing infiltration ink is pressed；
(7) enter into highest temperature district to reach in the kiln of 1180 DEG C-1240 DEG C and fire, obtain permeating the marmorean semi-finished product of ink；
(8) semi-finished product are carried out soft throwing/or full polishing, edging, i.e. prepares marble ceramic.
Method the most according to claim 9, it is characterised in that: between step (6) and (7), also include through being no less than
10 minutes, the transmission time course on the pipeline less than 2 hours.
11. methods according to claim 9, it is characterised in that: possibly together with being suitable for silk screen printing in the starch adhesive of step (3)
Conventional stamp-pad ink, print cream or glue.
12. methods according to claim 9, it is characterised in that: after step (4) silk-screen or after step (6)
Before step (7), the lower recess seam formed and/or irregularly shaped depressed area are carried out being coated with the glaze, semi-transparent of print different color
Bright dry granular or frit raw material, formed and fill.
13. methods according to claim 9, it is characterised in that: step (4) is pressed layout and is used digital spray printing, silk screen
Printing or roller mode of printing are printed glue and are formed some lower recess seam of projection and/or irregularly shaped texture, then step is executed in pouring
Suddenly the starch adhesive of (3).
14. methods according to claim 13, it is characterised in that: described silk screen printing changes roller printing into.
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Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107599138A (en) * | 2017-10-12 | 2018-01-19 | 清远市简陶瓷有限公司 | A kind of manufacture method of three-dimensional entire body texture ceramic tile |
| CN108394008A (en) * | 2018-03-23 | 2018-08-14 | 广东萨米特陶瓷有限公司 | Big plate of ceramics of anhydrous glaze line full digital code jet printing technique and preparation method thereof |
| CN108706964A (en) * | 2018-04-28 | 2018-10-26 | 湖北省当阳豪山建材有限公司 | Self-cleaning polished bricks of entire body texture high abrasion and preparation method thereof |
| CN109382898A (en) * | 2017-08-12 | 2019-02-26 | 主父春霖 | A kind of production technology of spun gold marble tile product |
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| IT202000021376A1 (en) * | 2020-09-10 | 2020-12-10 | Ri_Crea S R L S | Process for the creation of artistic works as an expression of the conformation of the architectural space on a ceramic support |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102795892A (en) * | 2012-09-10 | 2012-11-28 | 杭州诺贝尔陶瓷有限公司 | Soluble salt ceramic tile and production method thereof |
| CN104591804A (en) * | 2015-01-26 | 2015-05-06 | 佛山市东鹏陶瓷有限公司 | Preparation method of ceramic brick with stereoscopic decorative effects |
| CN104609895A (en) * | 2015-01-26 | 2015-05-13 | 佛山市东鹏陶瓷有限公司 | Manufacturing method for ceramic thin plate with three-dimensional decorative effect |
| CN105175027A (en) * | 2015-09-11 | 2015-12-23 | 蒙娜丽莎集团股份有限公司 | Ceramic with three-dimensional decoration effect and preparation method thereof |
-
2016
- 2016-06-06 CN CN201610393997.0A patent/CN106083212B/en active Active
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102795892A (en) * | 2012-09-10 | 2012-11-28 | 杭州诺贝尔陶瓷有限公司 | Soluble salt ceramic tile and production method thereof |
| CN104591804A (en) * | 2015-01-26 | 2015-05-06 | 佛山市东鹏陶瓷有限公司 | Preparation method of ceramic brick with stereoscopic decorative effects |
| CN104609895A (en) * | 2015-01-26 | 2015-05-13 | 佛山市东鹏陶瓷有限公司 | Manufacturing method for ceramic thin plate with three-dimensional decorative effect |
| CN105175027A (en) * | 2015-09-11 | 2015-12-23 | 蒙娜丽莎集团股份有限公司 | Ceramic with three-dimensional decoration effect and preparation method thereof |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109382898A (en) * | 2017-08-12 | 2019-02-26 | 主父春霖 | A kind of production technology of spun gold marble tile product |
| CN107599138A (en) * | 2017-10-12 | 2018-01-19 | 清远市简陶瓷有限公司 | A kind of manufacture method of three-dimensional entire body texture ceramic tile |
| CN108394008A (en) * | 2018-03-23 | 2018-08-14 | 广东萨米特陶瓷有限公司 | Big plate of ceramics of anhydrous glaze line full digital code jet printing technique and preparation method thereof |
| CN108706964A (en) * | 2018-04-28 | 2018-10-26 | 湖北省当阳豪山建材有限公司 | Self-cleaning polished bricks of entire body texture high abrasion and preparation method thereof |
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Application publication date: 20161109 Assignee: Guangdong Summit Ceramics Co., Ltd. Assignor: Guangdong Xinmingzhu Ceramic Group Co., Ltd.|Guangdong Gelaisi Ceramics Co., Ltd. Contract record no.: 2019440000125 Denomination of invention: Marble ceramic product containing penetrating ink and manufacturing method of novel marble ceramic product Granted publication date: 20180921 License type: Common License Record date: 20190621 Application publication date: 20161109 Assignee: Foshan Sanshuiguanzhu Ceramics Co., Ltd. Assignor: Guangdong Gelaisi Ceramics Co., Ltd.|Guangdong Xinmingzhu Ceramic Group Co., Ltd. Contract record no.: 2019440000124 Denomination of invention: Marble ceramic product containing penetrating ink and manufacturing method of novel marble ceramic product Granted publication date: 20180921 License type: Common License Record date: 20190621 |
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Address after: 528061 1st floor, No.18 taobo Avenue, Huaxia Ceramics Expo City, Nanzhuang Town, Chancheng District, Foshan City, Guangdong Province Patentee after: New Pearl Group Co.,Ltd. Address before: 528061 1st floor, No.18 taobo Avenue, Huaxia Ceramics Expo City, Nanzhuang Town, Chancheng District, Foshan City, Guangdong Province Patentee before: GUANGDONG NEWPEARL CERAMIC GROUP Co.,Ltd. |
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