CN111223777B - GaN-based HEMT device and manufacturing method thereof - Google Patents
GaN-based HEMT device and manufacturing method thereof Download PDFInfo
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Abstract
Description
技术领域Technical field
本发明涉及一种HEMT器件的制作方法,特别涉及一种GaN基HEMT器件及其制作方法,属于半导体技术领域。The present invention relates to a manufacturing method of a HEMT device, in particular to a GaN-based HEMT device and a manufacturing method thereof, and belongs to the field of semiconductor technology.
背景技术Background technique
GaN基HEMT器件是一类新型的HEMT器件,其工作原理主要是由于三族氮化物材料的自发极化和压电极化,导致在异质结构界面上形成二维电子气,具有极高的电子浓度(可达1013/cm2),可通过栅极电压控制电子浓度,从而实现对电流的控制,形成场效应晶体管。但肖特基结构的HEMT栅漏电大,栅压摆幅小(最大栅压1V~2V)。因此需要制备金属-绝缘层-半导体(MIS)结构的HEMT器件,绝缘层的引入可以降低栅漏电,增大摆幅,并且在刻蚀工艺中可以起到保护势垒层的作用。但是一方面,由于GaN材料体系不像Si体系那样,可以通过热氧化获得界面良好、质量优异的天然栅氧化层,只能通过多种薄膜沉积手段获得栅介质层和钝化层。另一方面GaN基HEMT器件由于在势垒层表面存在大量的表面态,所以当器件工作时,这些表面态会俘获大量电子而带负电,从而使得沟道电子浓度降低,导致器件的输出电流大幅度减小,即所谓的电流崩塌现象。表面态是导致HEMT器件电流崩塌效应的重要原因,而表面钝化是解决电流崩塌效应的手段之一。对GaN基HEMT的表面进行介质层钝化,可以减小表面态填充几率,使电流崩塌程度降低。现今研究者多利用SiO2、SiNx、Al2O3、HfO2、Sc2O3等作为HEMT器件的栅介质层,常用的钝化介质有SiO2、Sc2O3、MgO等,一方面这些介质层材料与III族氮化物不匹配,而且介质层和钝化层的生长方法为等离子体增强化学气相淀积法(PECVD)、原子层淀积法(ALD)、等离子体增强原子层淀积法(PE-ALD)等,这些方法的问题在于需要把异质结材料从生长腔室中取出转移到其它的介质层淀积腔室,导致材料的二次污染,使得异质结材料和介质层界面处不可避免地存在大量的界面态,使器件的工作过程中产生阈值电压及电流的回滞现象以及电流崩塌问题,影响器件的推广应用。而原位生长法制作生长介质层可以避免二次污染,但对AlN、BN及所形成的三元四元化合物作为介质层而言,高温原位生长获得的是晶体,其具有很大的自发极化和压电极化,导致HEMT结构与介质层之间的界面处形成二维电子气,此二维电子气的存在使得器件具有了双沟道,且导致栅泄漏电流增加严重,消弱了介质层降低漏电的作用,难以增加栅压摆幅,使介质层失去了其应有的作用。另外由于自发极化和压电极化的作用,通常GaN基HEMT结构的异质结界面具有二维电子气,是一种耗尽型晶体管结构,需要加负向电压才能关断,而增强型器件不需要负向电压,在微波功率放大器和低噪音功率放大器领域降低了电路复杂性和成本;耗尽型器件处于常开状态,在数字快速电路应用领域,增强型器件可形成低功率的互补逻辑,简化电路,而且增强型器件可提高电路安全性,因此增强型器件的研制势在必行。目前多以P型GaN及InGaN作为冒层制备增强型场效应晶体管,但P型GaN及InGaN的受主原子具有较大的激活能且容易被H钝化,掺杂效率只有0.1-1%。而且p型冒层直接生长在势垒层上,在器件制作过程中为了降低电阻率必须刻蚀栅源和栅漏间的p型冒层,刻蚀过程不可避免地对势垒层表面造成损伤和破坏,使得泄漏电流和电流崩塌增大。GaN-based HEMT devices are a new type of HEMT device. Its working principle is mainly due to the spontaneous polarization and piezoelectric polarization of group III nitride materials, resulting in the formation of two-dimensional electron gas on the heterostructure interface. It has extremely high The electron concentration (up to 10 13 /cm 2 ) can be controlled by the gate voltage to control the current and form a field effect transistor. However, the HEMT with Schottky structure has large gate leakage and small gate voltage swing (maximum gate voltage 1V~2V). Therefore, it is necessary to prepare HEMT devices with a metal-insulating layer-semiconductor (MIS) structure. The introduction of the insulating layer can reduce gate leakage, increase the swing, and can play a role in protecting the barrier layer during the etching process. But on the one hand, because the GaN material system is not like the Si system, which can obtain a natural gate oxide layer with good interface and excellent quality through thermal oxidation, the gate dielectric layer and passivation layer can only be obtained through a variety of thin film deposition methods. On the other hand, GaN-based HEMT devices have a large number of surface states on the surface of the barrier layer. Therefore, when the device is working, these surface states will capture a large number of electrons and become negatively charged, thus reducing the channel electron concentration and resulting in a large output current of the device. The amplitude decreases, a phenomenon known as current collapse. Surface states are an important cause of the current collapse effect of HEMT devices, and surface passivation is one of the means to solve the current collapse effect. Passivating the dielectric layer on the surface of GaN-based HEMT can reduce the probability of surface state filling and reduce the degree of current collapse. Nowadays, researchers mostly use SiO 2 , SiNx, Al 2 O 3 , HfO 2 , Sc 2 O 3 , etc. as gate dielectric layers of HEMT devices. Commonly used passivation media include SiO 2 , Sc 2 O 3 , MgO, etc. On the one hand These dielectric layer materials do not match Group III nitrides, and the growth methods of the dielectric layer and passivation layer are plasma enhanced chemical vapor deposition (PECVD), atomic layer deposition (ALD), and plasma enhanced atomic layer deposition. deposition method (PE-ALD), etc. The problem with these methods is that the heterojunction material needs to be taken out of the growth chamber and transferred to other dielectric layer deposition chambers, resulting in secondary contamination of the material, making the heterojunction material and There are inevitably a large number of interface states at the interface of the dielectric layer, which cause hysteresis in threshold voltage and current and current collapse problems during the operation of the device, which affects the promotion and application of the device. The in-situ growth method can avoid secondary pollution when producing a growth medium layer. However, for AlN, BN and the formed ternary quaternary compounds as dielectric layers, high-temperature in-situ growth obtains crystals, which have great spontaneous Polarization and piezoelectric polarization lead to the formation of a two-dimensional electron gas at the interface between the HEMT structure and the dielectric layer. The existence of this two-dimensional electron gas makes the device have dual channels, and causes the gate leakage current to seriously increase and weaken. Without the function of the dielectric layer in reducing leakage, it is difficult to increase the gate voltage swing, causing the dielectric layer to lose its due function. In addition, due to the effects of spontaneous polarization and piezoelectric polarization, the heterojunction interface of the GaN-based HEMT structure usually has a two-dimensional electron gas. It is a depletion-mode transistor structure that requires the application of a negative voltage to turn off, while the enhancement-mode The device does not require a negative voltage, which reduces circuit complexity and cost in the fields of microwave power amplifiers and low-noise power amplifiers; depletion-mode devices are in a normally open state, and in the field of digital fast circuit applications, enhancement-mode devices can form low-power complementarity Logic, simplified circuits, and enhanced devices can improve circuit safety, so the development of enhanced devices is imperative. At present, P-type GaN and InGaN are mostly used as pop-up layers to prepare enhancement-mode field-effect transistors. However, the acceptor atoms of P-type GaN and InGaN have large activation energy and are easily passivated by H, and the doping efficiency is only 0.1-1%. Moreover, the p-type leakage layer grows directly on the barrier layer. In order to reduce the resistivity during the device manufacturing process, the p-type leakage layer between the gate source and the gate drain must be etched. The etching process inevitably causes damage to the surface of the barrier layer. and damage, causing leakage current and current collapse to increase.
发明内容Contents of the invention
本发明的主要目的在于提供一种GaN基HEMT器件及其制作方法,从而克服现有技术中的不足。The main purpose of the present invention is to provide a GaN-based HEMT device and a manufacturing method thereof, thereby overcoming the deficiencies in the prior art.
为实现前述发明目的,本发明采用的技术方案包括:In order to achieve the foregoing invention objectives, the technical solutions adopted by the present invention include:
本发明实施例提供了一种GaN基HEMT器件的制作方法,包括:制作形成异质结的步骤,所述异质结包括第一半导体和第二半导体,所述第二半导体形成在第一半导体上,且具有宽于所述第一半导体的带隙,所述异质结中形成有二维电子气;Embodiments of the present invention provide a method for manufacturing a GaN-based HEMT device, including the step of forming a heterojunction. The heterojunction includes a first semiconductor and a second semiconductor. The second semiconductor is formed on the first semiconductor. and has a band gap wider than that of the first semiconductor, and a two-dimensional electron gas is formed in the heterojunction;
以及制作与异质结配合的源极、漏极的步骤,所述源极与漏极能够通过所述二维电子气电连接;所述的制作方法还包括:And the step of making a source electrode and a drain electrode that cooperate with the heterojunction, the source electrode and the drain electrode can be electrically connected through the two-dimensional electron gas; the manufacturing method also includes:
直接在所述异质结上低温原位生长绝缘层的步骤;The step of growing an insulating layer directly on the heterojunction at low temperature in situ;
直接在所述绝缘层上原位生长第三半导体的步骤,所述第三半导体能够将位于其下方的二维电子气耗尽;The step of growing a third semiconductor in situ directly on the insulating layer, the third semiconductor being able to deplete the two-dimensional electron gas located below it;
以及,制作与所述第三半导体配合的栅极。and making a gate that cooperates with the third semiconductor.
进一步的,所述绝缘层的生长温度低于制作形成异质结的温度。Furthermore, the growth temperature of the insulating layer is lower than the temperature at which the heterojunction is formed.
在一些较为具体的实施方案中,所述的制作方法包括:采用金属有机物化学气相外延的方式生长形成所述绝缘层,所述绝缘层的生长温度为300℃~800℃。In some more specific embodiments, the manufacturing method includes: growing the insulating layer by metal-organic chemical vapor phase epitaxy, and the growth temperature of the insulating layer is 300°C to 800°C.
在一些较为具体的实施方案中,所述的制作方法包括:采用分子束外延的方式生长形成所述绝缘层,所述绝缘层的生长温度为300℃~600℃。In some more specific embodiments, the manufacturing method includes: growing the insulating layer by molecular beam epitaxy, and the growth temperature of the insulating layer is 300°C to 600°C.
在一些较为具体的实施方案中,所述的制作方法包括:采用金属有机物化学气相外延、分子束外延中的任一种方式形成所述的异质结。In some more specific embodiments, the manufacturing method includes: forming the heterojunction using any one of metal-organic chemical vapor phase epitaxy and molecular beam epitaxy.
进一步的,所述绝缘层为无定形结构。Further, the insulating layer has an amorphous structure.
优选的,所述绝缘层的材质选自III族氮化物。Preferably, the material of the insulating layer is selected from group III nitrides.
优选的,所述绝缘层的材质包括AlN、BN、BAlN、BGaN和BAlGaN中的任意一种,但不限于此。Preferably, the material of the insulating layer includes any one of AlN, BN, BAlN, BGaN and BAlGaN, but is not limited thereto.
优选的,所述绝缘层的厚度为5~50nm。Preferably, the thickness of the insulating layer is 5 to 50 nm.
进一步的,所述第三半导体的材质选自P型半导体。Furthermore, the material of the third semiconductor is selected from P-type semiconductors.
优选的,所述P型半导体的材质包括P型BN,但不限于此。Preferably, the material of the P-type semiconductor includes P-type BN, but is not limited thereto.
进一步的,所述第一半导体的材质选自III族氮化物。Further, the material of the first semiconductor is selected from group III nitrides.
优选的,所述第一半导体的材质包括GaN,但不限于此。Preferably, the material of the first semiconductor includes GaN, but is not limited thereto.
进一步的,所述第二半导体的材质选自III族氮化物。Further, the material of the second semiconductor is selected from group III nitrides.
优选的,所述第二半导体的材质包括AlGaN、AlInN、AlInGaN、AlGaN、AlInN和AlInGaN中的任意一种,但不限于此。Preferably, the second semiconductor is made of any one of AlGaN, AlInN, AlInGaN, AlGaN, AlInN and AlInGaN, but is not limited thereto.
在一些较为具体的实施方案中,所述的制作方法包括:至少采用刻蚀或离子注入的方式对所述异质结进行加工处理,以在所述异质结内形成隔离区,进而实现器件间隔离。In some more specific embodiments, the manufacturing method includes: processing the heterojunction by at least etching or ion implantation to form an isolation region within the heterojunction, thereby realizing a device. isolation.
优选的,所述刻蚀的厚度为100-500nm。Preferably, the etching thickness is 100-500 nm.
优选的,所述离子注入的能量为10keV~200keV,注入剂量1013cm-2~1015cm-2。Preferably, the energy of the ion implantation is 10keV-200keV, and the implantation dose is 10 13 cm -2 - 10 15 cm -2 .
本发明实施例还提供了由所述的GaN基HEMT器件的制作方法制作形成的GaN基HEMT器件。Embodiments of the present invention also provide GaN-based HEMT devices manufactured by the manufacturing method of GaN-based HEMT devices.
本发明实施例还提供了一种GaN基HEMT器件,其包括:Embodiments of the present invention also provide a GaN-based HEMT device, which includes:
异质结以及与所述异质结配合源极、漏极和栅极,所述异质结包括第一半导体和第二半导体,所述第二半导体形成在第一半导体上,且具有宽于所述第一半导体的带隙,所述异质结中形成有二维电子气,所述源极与漏极能够通过所述二维电子气电连接;A heterojunction and a source, a drain, and a gate cooperated with the heterojunction. The heterojunction includes a first semiconductor and a second semiconductor. The second semiconductor is formed on the first semiconductor and has a width wider than The band gap of the first semiconductor, a two-dimensional electron gas formed in the heterojunction, and the source and drain can be electrically connected through the two-dimensional electron gas;
以及,形成在异质结上的绝缘层,所述绝缘层形成于源极与漏极之间,在所述绝缘层上还形成有第三半导体,所述第三半导体分布在栅极下方。And, an insulating layer is formed on the heterojunction, the insulating layer is formed between the source electrode and the drain electrode, a third semiconductor is also formed on the insulating layer, and the third semiconductor is distributed under the gate electrode.
进一步的,所述绝缘层为无定形结构。Further, the insulating layer has an amorphous structure.
优选的,所述绝缘层的材质选自III族氮化物。Preferably, the material of the insulating layer is selected from group III nitrides.
优选的,所述绝缘层的材质包括AlN、BN、BAlN、BGaN和BAlGaN中的任意一种,但不限于此。Preferably, the material of the insulating layer includes any one of AlN, BN, BAlN, BGaN and BAlGaN, but is not limited thereto.
优选的,所述绝缘层的厚度为5~50nm。Preferably, the thickness of the insulating layer is 5 to 50 nm.
进一步的,所述第三半导体的材质选自P型半导体。Furthermore, the material of the third semiconductor is selected from P-type semiconductors.
优选的,所述P型半导体的材质包括P型BN,但不限于此。Preferably, the material of the P-type semiconductor includes P-type BN, but is not limited thereto.
进一步的,所述第一半导体的材质选自III族氮化物。Further, the material of the first semiconductor is selected from group III nitrides.
优选的,所述第一半导体的材质包括GaN,但不限于此。Preferably, the material of the first semiconductor includes GaN, but is not limited thereto.
进一步的,所述第二半导体的材质选自III族氮化物。Further, the material of the second semiconductor is selected from group III nitrides.
优选的,所述第二半导体的材质包括AlGaN、AlInN、AlInGaN、AlGaN、AlInN和AlInGaN中的任意一种,但不限于此。Preferably, the second semiconductor is made of any one of AlGaN, AlInN, AlInGaN, AlGaN, AlInN and AlInGaN, but is not limited thereto.
进一步的,在所述第一半导体和第二半导体之间还形成有插入层。Further, an insertion layer is formed between the first semiconductor and the second semiconductor.
优选的,所述插入层的材质包括AlN,但不限于此。Preferably, the material of the insertion layer includes AlN, but is not limited thereto.
进一步的,所述异质结形成在缓冲层上,所述缓冲层形成在衬底上。Further, the heterojunction is formed on the buffer layer, and the buffer layer is formed on the substrate.
进一步的,所述衬底包括同质衬底或异质衬底。Further, the substrate includes a homogeneous substrate or a heterogeneous substrate.
优选的,所述同质衬底的材质包括GaN,但不限于此。Preferably, the material of the homogeneous substrate includes GaN, but is not limited thereto.
优选的,所述异质衬底的材质包括GaN、蓝宝石,Si、碳化硅中的任意一种,但不限于此。Preferably, the material of the heterogeneous substrate includes any one of GaN, sapphire, Si, and silicon carbide, but is not limited thereto.
与现有技术相比,本发明提供的制作方法在外延生长设备中生长形成HEMT器件的基本结构(HEMT器件的基本结构包括异质结)后,降低温度,直接在HEMT器件的基本结构上低温原位生长绝缘层;原位生长可避免材料的二次污染,减小界面态密度,特别是采用低温生长方式还可使得AlN、BN、BAlN、BGaN或BAlGaN等III族氮化物达到无定形状态进而形成无定形结构的绝缘层,利于消除绝缘层材料的自发极化和压电极化,使绝缘层和HEMT器件的势垒层(即第二半导体)界面不存在二维电子气;另外采用原位生长方式形成绝缘层时对器件其它结构的生长不会造成污染;其次,绝缘层同时能起到对势垒层的保护作用,在绝缘层上原位生长P型半导体,在进行刻蚀工艺的时候,不会刻蚀到势垒层,不会造成器件结构损伤;再次,采用低温原位生长的方式形成绝缘层以后再生长p型半导体的HEMT器件结构可以在形成无定形的原位栅介质层和实现原位钝化的同时,又可以调节阈值电压形成增强型器件,并避免了刻蚀损伤,可以有效降低栅漏电,增加栅摆幅和抑制电流崩塌,从而实现HEMT器件综合性能的有效提升。Compared with the existing technology, the manufacturing method provided by the present invention grows and forms the basic structure of the HEMT device in an epitaxial growth equipment (the basic structure of the HEMT device includes a heterojunction), then lowers the temperature and directly grows the basic structure of the HEMT device at low temperature. In-situ growth of the insulating layer; in-situ growth can avoid secondary pollution of materials and reduce the interface state density. Especially the low-temperature growth method can also make Group III nitrides such as AlN, BN, BAlN, BGaN or BAlGaN reach an amorphous state. The insulating layer with an amorphous structure is then formed, which is beneficial to eliminating the spontaneous polarization and piezoelectric polarization of the insulating layer material, so that there is no two-dimensional electron gas at the interface between the insulating layer and the barrier layer (i.e., the second semiconductor) of the HEMT device; in addition, using When the insulating layer is formed by in-situ growth, it will not cause pollution to the growth of other structures of the device; secondly, the insulating layer can also protect the barrier layer. P-type semiconductors are grown in-situ on the insulating layer and are etched. During the process, the barrier layer will not be etched, and the device structure will not be damaged; thirdly, the HEMT device structure using low-temperature in-situ growth to form the insulating layer and then growing the p-type semiconductor can form an amorphous in-situ While achieving in-situ passivation of the gate dielectric layer, the threshold voltage can be adjusted to form an enhancement device and avoid etching damage. It can effectively reduce gate leakage, increase gate swing and suppress current collapse, thereby achieving comprehensive performance of HEMT devices. effective improvement.
附图说明Description of the drawings
为了更清楚地说明本发明实施例或现有技术中的技术方案,下面将对实施例或现有技术描述中所需要使用的附图作简单地介绍,显而易见地,下面描述中的附图仅仅是本发明中记载的一些实施例,对于本领域普通技术人员来讲,在不付出创造性劳动的前提下,还可以根据这些附图获得其它的附图。In order to explain the embodiments of the present invention or the technical solutions in the prior art more clearly, the drawings needed to be used in the description of the embodiments or the prior art will be briefly introduced below. Obviously, the drawings in the following description are only These are some embodiments recorded in the present invention. For those of ordinary skill in the art, other drawings can be obtained based on these drawings without exerting creative efforts.
图1是本发明一典型实施方案中一种GaN基HEMT器件的外延结构示意图;Figure 1 is a schematic diagram of the epitaxial structure of a GaN-based HEMT device in a typical embodiment of the present invention;
图2是本发明一典型实施案例中一种GaN基HEMT器件的结构示意图;Figure 2 is a schematic structural diagram of a GaN-based HEMT device in a typical implementation case of the present invention;
图3是本发明一典型实施案例中另一种GaN基HEMT器件的结构示意图。Figure 3 is a schematic structural diagram of another GaN-based HEMT device in a typical implementation of the present invention.
具体实施方式Detailed ways
鉴于现有技术中的不足,本案发明人经长期研究和大量实践,得以提出本发明的技术方案。如下将对该技术方案、其实施过程及原理等作进一步的解释说明。In view of the deficiencies in the prior art, the inventor of this case was able to propose the technical solution of the present invention after long-term research and extensive practice. The technical solution, its implementation process and principles will be further explained below.
本发明实施例提供了一种GaN基HEMT器件的制作方法,包括:制作形成异质结的步骤,所述异质结包括第一半导体和第二半导体,所述第二半导体形成在第一半导体上,且具有宽于所述第一半导体的带隙,所述异质结中形成有二维电子气;Embodiments of the present invention provide a method for manufacturing a GaN-based HEMT device, including the step of forming a heterojunction. The heterojunction includes a first semiconductor and a second semiconductor. The second semiconductor is formed on the first semiconductor. and has a band gap wider than that of the first semiconductor, and a two-dimensional electron gas is formed in the heterojunction;
以及制作与异质结配合的源极、漏极的步骤,所述源极与漏极能够通过所述二维电子气电连接;所述的制作方法还包括:And the step of making a source electrode and a drain electrode that cooperate with the heterojunction, the source electrode and the drain electrode can be electrically connected through the two-dimensional electron gas; the manufacturing method also includes:
直接在所述异质结上低温原位生长绝缘层的步骤;The step of growing an insulating layer directly on the heterojunction at low temperature in situ;
直接在所述绝缘层上原位生长第三半导体的步骤,所述第三半导体能够将位于其下方的二维电子气耗尽;The step of growing a third semiconductor in situ directly on the insulating layer, the third semiconductor being able to deplete the two-dimensional electron gas located below it;
以及,制作与所述第三半导体配合的栅极。and making a gate that cooperates with the third semiconductor.
进一步的,所述绝缘层的生长温度低于制作形成异质结的温度。Furthermore, the growth temperature of the insulating layer is lower than the temperature at which the heterojunction is formed.
在一些较为具体的实施方案中,所述的制作方法包括:采用金属有机物化学气相外延的方式生长形成所述绝缘层,所述绝缘层的生长温度为300℃~800℃。In some more specific embodiments, the manufacturing method includes: growing the insulating layer by metal-organic chemical vapor phase epitaxy, and the growth temperature of the insulating layer is 300°C to 800°C.
在一些较为具体的实施方案中,所述的制作方法包括:采用分子束外延的方式生长形成所述绝缘层,所述绝缘层的生长温度为300℃~600℃。In some more specific embodiments, the manufacturing method includes: growing the insulating layer by molecular beam epitaxy, and the growth temperature of the insulating layer is 300°C to 600°C.
在一些较为具体的实施方案中,所述的制作方法包括:采用金属有机物化学气相外延、分子束外延中的任一种方式形成所述的异质结。In some more specific embodiments, the manufacturing method includes: forming the heterojunction using any one of metal-organic chemical vapor phase epitaxy and molecular beam epitaxy.
进一步的,所述绝缘层为无定形结构。Further, the insulating layer has an amorphous structure.
优选的,所述绝缘层的材质选自III族氮化物。Preferably, the material of the insulating layer is selected from group III nitrides.
优选的,所述绝缘层的材质包括AlN、BN、BAlN、BGaN和BAlGaN中的任意一种,但不限于此。Preferably, the material of the insulating layer includes any one of AlN, BN, BAlN, BGaN and BAlGaN, but is not limited thereto.
优选的,所述绝缘层的厚度为5~50nm。Preferably, the thickness of the insulating layer is 5 to 50 nm.
进一步的,所述第三半导体的材质选自P型半导体。Furthermore, the material of the third semiconductor is selected from P-type semiconductors.
优选的,所述P型半导体的材质包括P型BN,但不限于此。Preferably, the material of the P-type semiconductor includes P-type BN, but is not limited thereto.
进一步的,所述第一半导体的材质选自III族氮化物。Further, the material of the first semiconductor is selected from group III nitrides.
优选的,所述第一半导体的材质包括GaN,但不限于此。Preferably, the material of the first semiconductor includes GaN, but is not limited thereto.
进一步的,所述第二半导体的材质选自III族氮化物。Further, the material of the second semiconductor is selected from group III nitrides.
优选的,所述第二半导体的材质包括AlGaN、AlInN、AlInGaN、AlGaN、AlInN和AlInGaN中的任意一种,但不限于此。Preferably, the second semiconductor is made of any one of AlGaN, AlInN, AlInGaN, AlGaN, AlInN and AlInGaN, but is not limited thereto.
在一些较为具体的实施方案中,所述的制作方法包括:至少采用刻蚀或离子注入的方式对所述异质结进行加工处理,以在所述异质结内形成隔离区,进而实现器件间隔离。In some more specific embodiments, the manufacturing method includes: processing the heterojunction by at least etching or ion implantation to form an isolation region within the heterojunction, thereby realizing a device. isolation.
优选的,所述刻蚀的厚度为100-500nm。Preferably, the etching thickness is 100-500 nm.
优选的,所述离子注入的能量为10keV~200keV,注入剂量1013cm-2~1015cm-2。Preferably, the energy of the ion implantation is 10keV-200keV, and the implantation dose is 10 13 cm -2 - 10 15 cm -2 .
本发明实施例还提供了由所述的GaN基HEMT器件的制作方法制作形成的GaN基HEMT器件。Embodiments of the present invention also provide GaN-based HEMT devices manufactured by the manufacturing method of GaN-based HEMT devices.
本发明实施例还提供了一种GaN基HEMT器件,其包括:Embodiments of the present invention also provide a GaN-based HEMT device, which includes:
异质结以及与所述异质结配合源极、漏极和栅极,所述异质结包括第一半导体和第二半导体,所述第二半导体形成在第一半导体上,且具有宽于所述第一半导体的带隙,所述异质结中形成有二维电子气,所述源极与漏极能够通过所述二维电子气电连接;A heterojunction and a source, a drain, and a gate cooperated with the heterojunction. The heterojunction includes a first semiconductor and a second semiconductor. The second semiconductor is formed on the first semiconductor and has a width wider than The band gap of the first semiconductor, a two-dimensional electron gas formed in the heterojunction, and the source and drain can be electrically connected through the two-dimensional electron gas;
以及,形成在异质结上的绝缘层,所述绝缘层形成于源极与漏极之间,在所述绝缘层上还形成有第三半导体,所述第三半导体分布在栅极下方。And, an insulating layer is formed on the heterojunction, the insulating layer is formed between the source electrode and the drain electrode, a third semiconductor is also formed on the insulating layer, and the third semiconductor is distributed under the gate electrode.
进一步的,所述绝缘层为无定形结构。Further, the insulating layer has an amorphous structure.
优选的,所述绝缘层的材质选自III族氮化物。Preferably, the material of the insulating layer is selected from group III nitrides.
优选的,所述绝缘层的材质包括AlN、BN、BAlN、BGaN和BAlGaN中的任意一种,但不限于此。Preferably, the material of the insulating layer includes any one of AlN, BN, BAlN, BGaN and BAlGaN, but is not limited thereto.
优选的,所述绝缘层的厚度为5~50nm。Preferably, the thickness of the insulating layer is 5 to 50 nm.
进一步的,所述第三半导体的材质选自P型半导体。Furthermore, the material of the third semiconductor is selected from P-type semiconductors.
优选的,所述P型半导体的材质包括P型BN,但不限于此。Preferably, the material of the P-type semiconductor includes P-type BN, but is not limited thereto.
进一步的,所述第一半导体的材质选自III族氮化物。Further, the material of the first semiconductor is selected from group III nitrides.
优选的,所述第一半导体的材质包括GaN,但不限于此。Preferably, the material of the first semiconductor includes GaN, but is not limited thereto.
进一步的,所述第二半导体的材质选自III族氮化物。Further, the material of the second semiconductor is selected from group III nitrides.
优选的,所述第二半导体的材质包括AlGaN、AlInN、AlInGaN、AlGaN、AlInN和AlInGaN中的任意一种,但不限于此。Preferably, the second semiconductor is made of any one of AlGaN, AlInN, AlInGaN, AlGaN, AlInN and AlInGaN, but is not limited thereto.
进一步的,在所述第一半导体和第二半导体之间还形成有插入层。Further, an insertion layer is formed between the first semiconductor and the second semiconductor.
优选的,所述插入层的材质包括AlN,但不限于此。Preferably, the material of the insertion layer includes AlN, but is not limited thereto.
进一步的,所述异质结形成在缓冲层上,所述缓冲层形成在衬底上。Further, the heterojunction is formed on the buffer layer, and the buffer layer is formed on the substrate.
进一步的,所述衬底包括同质衬底或异质衬底。Further, the substrate includes a homogeneous substrate or a heterogeneous substrate.
优选的,所述同质衬底的材质包括GaN,但不限于此。Preferably, the material of the homogeneous substrate includes GaN, but is not limited thereto.
优选的,所述异质衬底的材质包括GaN、蓝宝石,Si、碳化硅中的任意一种,但不限于此。Preferably, the material of the heterogeneous substrate includes any one of GaN, sapphire, Si, and silicon carbide, but is not limited thereto.
下面将结合附图对本发明的技术方案进行清楚、完整地描述,显然,所描述的实施例是本发明一部分实施例,而不是全部的实施例。基于本发明中的实施例,本领域普通技术人员在没有做出创造性劳动前提下所获得的所有其它实施例,都属于本发明保护的范围。The technical solution of the present invention will be clearly and completely described below with reference to the accompanying drawings. Obviously, the described embodiments are some, not all, of the embodiments of the present invention. Based on the embodiments of the present invention, all other embodiments obtained by those of ordinary skill in the art without creative efforts fall within the scope of protection of the present invention.
在一些较为具体的实施方案中,一种GaN基HEMT器件的制作方法可以包括如下步骤:In some more specific implementations, a method of manufacturing a GaN-based HEMT device may include the following steps:
生长GaN基HEMT器件的基本结构,其GaN基HEMT器件的基本结构包括衬底、形成在衬底上的缓冲层、形成在缓冲层上的异质结(异质结包括沟道层和势垒层);The basic structure of growing GaN-based HEMT devices. The basic structure of GaN-based HEMT devices includes a substrate, a buffer layer formed on the substrate, and a heterojunction formed on the buffer layer (the heterojunction includes a channel layer and a barrier. layer);
在所述GaN基HEMT器件的基本结构生长结束后,在生长GaN基HEMT器件的基本结构的外延生长设备中于GaN基HEMT器件的基本结构上直接低温原位生长形成绝缘层(亦可称为介质层),生长完绝缘层后继续原位生长第三半导体(即p型半导体或称之为p型层或称之为p型冒层);After the growth of the basic structure of the GaN-based HEMT device is completed, in the epitaxial growth equipment for growing the basic structure of the GaN-based HEMT device, an insulating layer (which can also be called dielectric layer), after growing the insulating layer, continue to grow the third semiconductor (i.e., p-type semiconductor or called p-type layer or called p-type leaking layer) in situ;
在绝缘层的源、漏区域加工出窗口,进而利用所述的窗口制作与所述GaN基HEMT器件的基本结构电性接触的源极、漏极;其中,所述的源极、漏极可以通过形成在所述GaN基HEMT器件的基本结构内的二维电子气(2DEG)电连接;Process windows in the source and drain regions of the insulating layer, and then use the windows to make source electrodes and drain electrodes that are in electrical contact with the basic structure of the GaN-based HEMT device; wherein the source electrodes and drain electrodes can Electrical connection through a two-dimensional electron gas (2DEG) formed within the basic structure of the GaN-based HEMT device;
在第三半导体上制作栅极,并刻蚀掉栅极与源极、栅极与漏极之间的第三半导体。Make a gate electrode on the third semiconductor, and etch away the third semiconductor between the gate electrode and the source electrode, and between the gate electrode and the drain electrode.
本发明实施例提供的GaN基HEMT器件的制作方法,利用原位低温方法生长绝缘层作为GaN基HEMT器件的介质层和钝化层,原位生长可避免材料的二次污染,尽量减小界面态密度,特别是采用低温生长方式还可使得AlN、BN、BAlN、BGaN或BAlGaN等绝缘层材料形成无定形结构,利于消除这些材料的自发极化和压电极化,使绝缘层和GaN基HEMT器件的基本结构的势垒层界面不存在二维电子气,另外原位生长绝缘层时对器件结构生长不存在污染;另外在绝缘层上原位生长p型BN用来耗尽二维电子气制备增强型器件,主要优势在于BN比较容易获得p型掺杂的半导体(即p型半导体,或称之为p型层),比如Mg掺杂BN形成p型半导体的激活能很小,而且,采用普通结构的p型GaN冒层制作增强型HEMT器件时对栅极与源极、漏极间p型半导体的刻蚀难免损伤势垒层,造成泄漏电流及电流崩塌等问题;而本发明中所申明的在绝缘层上原位生长p型半导体,可以避免刻蚀工艺直接对HEMT器件的势垒层造成损害,提高器件的电学特性,这种低温原位生长绝缘层以后再生长p型半导体的HEMT器件结构即可以形成无定形的原位栅介质层和实现原位钝化,又可以调节阈值电压形成增强型器件,并避免了刻蚀损伤,可以有效降低栅漏电,增加栅摆幅和抑制电流崩塌,从而实现GaN基HEMT器件综合性能的有效提升。The manufacturing method of a GaN-based HEMT device provided by the embodiment of the present invention uses an in-situ low-temperature method to grow an insulating layer as the dielectric layer and passivation layer of the GaN-based HEMT device. The in-situ growth can avoid secondary pollution of the material and minimize the interface. The density of states, especially the low-temperature growth method, can also make the insulating layer materials such as AlN, BN, BAlN, BGaN or BAlGaN form an amorphous structure, which is conducive to eliminating the spontaneous polarization and piezoelectric polarization of these materials, making the insulating layer and GaN-based There is no two-dimensional electron gas at the barrier layer interface of the basic structure of the HEMT device. In addition, there is no pollution to the growth of the device structure when the insulating layer is grown in situ. In addition, p-type BN is grown in situ on the insulating layer to deplete the two-dimensional electrons. The main advantage of using gas to prepare enhancement-mode devices is that BN is relatively easy to obtain p-type doped semiconductors (i.e., p-type semiconductors, or p-type layers). For example, the activation energy of Mg-doped BN to form a p-type semiconductor is very small, and When using a p-type GaN pop-up layer with a common structure to make an enhancement mode HEMT device, the etching of the p-type semiconductor between the gate, source and drain will inevitably damage the barrier layer, causing problems such as leakage current and current collapse; and the present invention The in-situ growth of p-type semiconductors on the insulating layer as stated in can prevent the etching process from directly damaging the barrier layer of the HEMT device and improve the electrical characteristics of the device. This low-temperature in-situ growth of the insulating layer can later grow the p-type semiconductor. The semiconductor HEMT device structure can not only form an amorphous in-situ gate dielectric layer and achieve in-situ passivation, but also adjust the threshold voltage to form an enhancement device and avoid etching damage, which can effectively reduce gate leakage and increase gate swing. and suppress current collapse, thereby effectively improving the overall performance of GaN-based HEMT devices.
需要说明的是,以上所述实施例的各技术特征可以进行任意的组合,为使描述简洁,未对上述实施例中的各个技术特征所有可能的组合都进行描述,然而,只要这些技术特征的组合不存在矛盾,都应当认为是本说明书记载的范围。It should be noted that the technical features of the above-described embodiments can be combined in any way. To simplify the description, not all possible combinations of the technical features in the above-described embodiments are described. However, as long as these technical features are If there is no contradiction in the combination, it should be considered to be within the scope of this manual.
具体的,一种GaN基HEMT器件的制作方法,包括:Specifically, a method for manufacturing a GaN-based HEMT device includes:
在本发明的一较为具体的实施例中,一种GaN基HEMT的制作工艺包括如下步骤:In a more specific embodiment of the present invention, a GaN-based HEMT manufacturing process includes the following steps:
1)在MOCVD或MBE外延生长设备中生长GaN基HEMT器件的基本结构,GaN基HEMT器件的基本结构包括在同质衬底(如GaN)或者异质衬底(如硅、蓝宝石、碳化硅)上依次生长缓冲层(厚度为20-30nm)、GaN层(即第一半导体或称之为沟道层,厚度为1um-4um)及势垒层(即第二半导体,厚度为10nm-50nm,其中还可以在GaN层和势垒层之间形成AlN插入层,AlN插入层的厚度为0.5nm-2nm);1) The basic structure of GaN-based HEMT devices is grown in MOCVD or MBE epitaxial growth equipment. The basic structure of GaN-based HEMT devices includes growing on a homogeneous substrate (such as GaN) or a heterogeneous substrate (such as silicon, sapphire, silicon carbide) The buffer layer (thickness 20-30nm), GaN layer (i.e. the first semiconductor or channel layer, thickness 1um-4um) and barrier layer (i.e. the second semiconductor, thickness 10nm-50nm) are sequentially grown on the top. An AlN insertion layer can also be formed between the GaN layer and the barrier layer, and the thickness of the AlN insertion layer is 0.5nm-2nm);
2)降低MOCVD或MBE外延生长设备的反应室内的温度并调节温度、气体压力和源流量,原位淀积厚度约为5~50nm的无定形结构的绝缘层(绝缘层的材质包括AlN、BN、BAlN、BGaN、BAlGaN,低温生长方式可使得AlN、BN、BAlN、BGaN或BAlGaN等III族氮化物达到无定形状态),其中在一些更具体的实施例中,本步骤内MOCVD外延生长设备的反应室的温度在300~800℃之间调整,本步骤内MBE方式外延生长设备的反应室温度在300℃~600℃之间调整;2) Reduce the temperature in the reaction chamber of the MOCVD or MBE epitaxial growth equipment and adjust the temperature, gas pressure and source flow, and deposit in situ an insulating layer with an amorphous structure with a thickness of about 5 to 50 nm (the materials of the insulating layer include AlN, BN , BAlN, BGaN, BAlGaN, the low-temperature growth method can make Group III nitrides such as AlN, BN, BAlN, BGaN or BAlGaN reach an amorphous state), where in some more specific embodiments, the MOCVD epitaxial growth equipment in this step The temperature of the reaction chamber is adjusted between 300°C and 800°C. In this step, the temperature of the reaction chamber of the MBE epitaxial growth equipment is adjusted between 300°C and 600°C;
3)生长完绝缘层后继续原位生长第三半导体(例如p型BN),形成如图1所示的GaN基HEMT器件的外延结构;3) After growing the insulating layer, continue to grow the third semiconductor (such as p-type BN) in situ to form the epitaxial structure of the GaN-based HEMT device as shown in Figure 1;
4)光刻保护器件台面,采用刻蚀(刻蚀厚度100-500nm)或者离子注入(离子注入能量10keV-200keV,注入剂量1013cm-2-1015cm-2)的方式在GaN基HEMT器件的基本结构上形成器件隔离区,以实现器件间隔离;刻蚀隔离获得的GaN基HEMT器件结构如图2所示;离子注入隔离获得的GaN基HEMT器件结构如图3所示;4) Photolithography protects the device table, using etching (etching thickness 100-500nm) or ion implantation (ion implantation energy 10keV-200keV, implantation dose 10 13 cm -2 -10 15 cm -2 ) on the GaN-based HEMT A device isolation area is formed on the basic structure of the device to achieve isolation between devices; the GaN-based HEMT device structure obtained by etching isolation is shown in Figure 2; the GaN-based HEMT device structure obtained by ion implantation isolation is shown in Figure 3;
5)通过干法刻蚀或湿法腐蚀的方法刻蚀掉栅极与源极、栅极与漏极之间第三半导体;5) Etch away the third semiconductor between the gate and source, gate and drain by dry etching or wet etching;
6)光刻出源极和漏极图形,然后通过干法刻蚀或湿法腐蚀的方法刻蚀绝缘层,为源极和漏极开孔;6) Photoetch the source and drain patterns, and then etch the insulating layer through dry etching or wet etching to open holes for the source and drain electrodes;
7)在源极、漏极区域,通过电子束蒸发或溅射的方法制备源极和漏极,源极和漏极金属包括钛(Ti)、铝(Al)、镍(Ni)、金(Au)、铂(Pt)等中的一种或多种合金;之后在高温、保护气环境下快速热退火形成欧姆接触;退火温度一般在500-950℃之间,退火时间在10-120秒之间,保护气体包括N2或Ar;7) In the source and drain regions, the source and drain electrodes are prepared by electron beam evaporation or sputtering. The source and drain metals include titanium (Ti), aluminum (Al), nickel (Ni), gold ( One or more alloys such as Au), platinum (Pt), etc.; then rapidly thermally annealed under high temperature and protective gas environment to form ohmic contact; the annealing temperature is generally between 500-950℃, and the annealing time is 10-120 seconds In between, the protective gas includes N 2 or Ar;
8)光刻出栅极图形,通过电子束蒸发或溅射方式在绝缘层(或称之为绝缘介质层或介质层)上淀积金属形成栅极;栅极金属包括镍(Ni)、金(Au)、铂(Pt)、钯(Pd)等一种或多种金属。8) Photo-etch the gate pattern, and deposit metal on the insulating layer (or called the insulating dielectric layer or dielectric layer) through electron beam evaporation or sputtering to form the gate; the gate metal includes nickel (Ni), gold One or more metals such as (Au), platinum (Pt), palladium (Pd), etc.
9)于300-500℃下,利用快速热退火设备处理10分钟。9) Use rapid thermal annealing equipment at 300-500°C for 10 minutes.
与现有技术相比,本发明提供的制作方法在外延生长设备中生长形成HEMT器件的基本结构(HEMT器件的基本结构包括异质结)后,降低温度,直接在HEMT器件的基本结构上低温原位生长绝缘层;原位生长可避免材料的二次污染,减小界面态密度,特别是采用低温生长方式还可使得AlN、BN、BAlN、BGaN或BAlGaN等III族氮化物达到无定形状态进而形成无定形结构的绝缘层,利于消除绝缘层材料的自发极化和压电极化,使绝缘层和HEMT器件的势垒层(即第二半导体)界面不存在二维电子气;另外采用低温原位生长方式形成绝缘层时对器件其它结构的生长不会造成污染;其次,绝缘层同时能起到对势垒层的保护作用,在绝缘层上原位生长P型半导体,在进行刻蚀工艺的时候,不会刻蚀到势垒层,不会造成器件损坏;再次,采用低温原位生长的方式形成绝缘层以后再生长P型半导体的HEMT器件结构可以在形成无定形的原位栅介质层和实现原位钝化的同时,又可以调节阈值电压形成增强型器件,并避免了刻蚀损伤,可以有效降低栅漏电,增加栅摆幅和抑制电流崩塌,从而实现HEMT器件综合性能的有效提升。Compared with the existing technology, the manufacturing method provided by the present invention grows and forms the basic structure of the HEMT device in an epitaxial growth equipment (the basic structure of the HEMT device includes a heterojunction), then lowers the temperature and directly grows the basic structure of the HEMT device at low temperature. In-situ growth of the insulating layer; in-situ growth can avoid secondary pollution of materials and reduce the interface state density. Especially the low-temperature growth method can also make Group III nitrides such as AlN, BN, BAlN, BGaN or BAlGaN reach an amorphous state. The insulating layer with an amorphous structure is then formed, which is beneficial to eliminating the spontaneous polarization and piezoelectric polarization of the insulating layer material, so that there is no two-dimensional electron gas at the interface between the insulating layer and the barrier layer (i.e., the second semiconductor) of the HEMT device; in addition, using When the insulating layer is formed by the low-temperature in-situ growth method, it will not cause pollution to the growth of other structures of the device; secondly, the insulating layer can also protect the barrier layer. P-type semiconductors are grown in-situ on the insulating layer and are etched during engraving. During the etching process, the barrier layer will not be etched, and the device will not be damaged; thirdly, using low-temperature in-situ growth to form the insulating layer and then growing the P-type semiconductor HEMT device structure can form an amorphous in-situ While achieving in-situ passivation of the gate dielectric layer, the threshold voltage can be adjusted to form an enhancement device and avoid etching damage. It can effectively reduce gate leakage, increase gate swing and suppress current collapse, thereby achieving comprehensive performance of HEMT devices. effective improvement.
应当理解,上述实施例仅为说明本发明的技术构思及特点,其目的在于让熟悉此项技术的人士能够了解本发明的内容并据以实施,并不能以此限制本发明的保护范围。凡根据本发明精神实质所作的等效变化或修饰,都应涵盖在本发明的保护范围之内。It should be understood that the above embodiments are only to illustrate the technical concepts and characteristics of the present invention. Their purpose is to enable those familiar with the technology to understand the content of the present invention and implement it accordingly, and cannot limit the scope of protection of the present invention. All equivalent changes or modifications made based on the spirit and essence of the present invention should be included in the protection scope of the present invention.
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