CN110993759B - Ultraviolet light emitting device using composite electron blocking layer and preparation method thereof - Google Patents
Ultraviolet light emitting device using composite electron blocking layer and preparation method thereof Download PDFInfo
- Publication number
- CN110993759B CN110993759B CN201911215981.0A CN201911215981A CN110993759B CN 110993759 B CN110993759 B CN 110993759B CN 201911215981 A CN201911215981 A CN 201911215981A CN 110993759 B CN110993759 B CN 110993759B
- Authority
- CN
- China
- Prior art keywords
- layer
- type
- ultraviolet light
- emitting device
- electron blocking
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- 230000000903 blocking effect Effects 0.000 title claims abstract description 51
- 239000002131 composite material Substances 0.000 title claims abstract description 44
- 238000002360 preparation method Methods 0.000 title abstract description 9
- 239000000758 substrate Substances 0.000 claims abstract description 12
- 229910002704 AlGaN Inorganic materials 0.000 claims description 28
- 230000004888 barrier function Effects 0.000 claims description 28
- 239000000203 mixture Substances 0.000 claims description 15
- 238000004519 manufacturing process Methods 0.000 claims 1
- 238000002347 injection Methods 0.000 abstract description 27
- 239000007924 injection Substances 0.000 abstract description 27
- 230000006798 recombination Effects 0.000 abstract description 12
- 238000005215 recombination Methods 0.000 abstract description 12
- 230000005855 radiation Effects 0.000 abstract description 11
- 230000000670 limiting effect Effects 0.000 abstract description 4
- 239000004065 semiconductor Substances 0.000 abstract description 4
- 239000010410 layer Substances 0.000 description 210
- 239000000463 material Substances 0.000 description 8
- 230000000694 effects Effects 0.000 description 7
- 239000000969 carrier Substances 0.000 description 6
- 238000000034 method Methods 0.000 description 5
- 239000000243 solution Substances 0.000 description 5
- 238000002474 experimental method Methods 0.000 description 4
- 230000004913 activation Effects 0.000 description 3
- 230000009286 beneficial effect Effects 0.000 description 2
- 238000004891 communication Methods 0.000 description 2
- 238000010586 diagram Methods 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 230000006872 improvement Effects 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 230000010287 polarization Effects 0.000 description 2
- 101001121408 Homo sapiens L-amino-acid oxidase Proteins 0.000 description 1
- 102100026388 L-amino-acid oxidase Human genes 0.000 description 1
- 238000003848 UV Light-Curing Methods 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 238000004020 luminiscence type Methods 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 231100000252 nontoxic Toxicity 0.000 description 1
- 230000003000 nontoxic effect Effects 0.000 description 1
- 238000005036 potential barrier Methods 0.000 description 1
- 238000000746 purification Methods 0.000 description 1
- 239000002356 single layer Substances 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10H—INORGANIC LIGHT-EMITTING SEMICONDUCTOR DEVICES HAVING POTENTIAL BARRIERS
- H10H20/00—Individual inorganic light-emitting semiconductor devices having potential barriers, e.g. light-emitting diodes [LED]
- H10H20/80—Constructional details
- H10H20/81—Bodies
- H10H20/816—Bodies having carrier transport control structures, e.g. highly-doped semiconductor layers or current-blocking structures
-
- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10H—INORGANIC LIGHT-EMITTING SEMICONDUCTOR DEVICES HAVING POTENTIAL BARRIERS
- H10H20/00—Individual inorganic light-emitting semiconductor devices having potential barriers, e.g. light-emitting diodes [LED]
- H10H20/01—Manufacture or treatment
- H10H20/011—Manufacture or treatment of bodies, e.g. forming semiconductor layers
- H10H20/013—Manufacture or treatment of bodies, e.g. forming semiconductor layers having light-emitting regions comprising only Group III-V materials
- H10H20/0137—Manufacture or treatment of bodies, e.g. forming semiconductor layers having light-emitting regions comprising only Group III-V materials the light-emitting regions comprising nitride materials
Landscapes
- Led Devices (AREA)
Abstract
Description
技术领域Technical Field
本发明涉及半导体技术领域,具体而言,涉及一种采用复合电子阻挡层的紫外发光器件及其制备方法。The invention relates to the field of semiconductor technology, and in particular to an ultraviolet light-emitting device using a composite electron blocking layer and a preparation method thereof.
背景技术Background technique
因为紫外发光二极管具有环保无毒、耗电低、体积小以及寿命长等优点,符合环保、节能等要求。在紫外固化、空气与水净化、生物医疗、高密度储存、安全与保密通讯等领域,具有重要应用价值。Because UV LEDs are environmentally friendly, non-toxic, low power consumption, small size and long life, they meet the requirements of environmental protection and energy saving. They have important application value in the fields of UV curing, air and water purification, biomedicine, high-density storage, security and confidentiality communications, etc.
目前,紫外发光二极管技术面临的首要问题是其光效低。波长365nm的紫外发光二极管的输出功率仅为输入功率的5%-8%。对于波长385nm以上的紫外发光二极管的光电转化效率相对于短波长有明显提高,但输出功率只有输入功率的15%。如何有效提高紫外发光二极管的光效成为大家关注的焦点问题。At present, the primary problem facing UV LED technology is its low light efficiency. The output power of UV LEDs with a wavelength of 365nm is only 5%-8% of the input power. The photoelectric conversion efficiency of UV LEDs with a wavelength of more than 385nm is significantly improved compared to those with shorter wavelengths, but the output power is only 15% of the input power. How to effectively improve the light efficiency of UV LEDs has become a focus of attention.
因此,设计一种紫外发光器件及其制备方法,能够有效地增加电子限制效果、增强空穴注入效率,以及载流子注入时的电流扩展能力,从而提高紫外发光二极管的在量子阱中的辐射复合速率,改善器件的发光效率,这是目前急需解决的技术问题。Therefore, designing an ultraviolet light-emitting device and its preparation method can effectively increase the electron confinement effect, enhance the hole injection efficiency, and the current expansion capability during carrier injection, thereby increasing the radiation recombination rate of the ultraviolet light-emitting diode in the quantum well and improving the luminescence efficiency of the device. This is a technical problem that urgently needs to be solved.
发明内容Summary of the invention
本发明的目的在于提供一种采用复合电子阻挡层的紫外发光器件及其制备方法,能够有效地增加电子限制效果、增强空穴注入效率,以及载流子注入时的电流扩展能力,从而提高紫外发光二极管的在量子阱中的辐射复合速率,改善器件的发光效率。The object of the present invention is to provide an ultraviolet light-emitting device using a composite electron blocking layer and a preparation method thereof, which can effectively increase the electron confinement effect, enhance the hole injection efficiency, and the current expansion capability during carrier injection, thereby increasing the radiation recombination rate of the ultraviolet light-emitting diode in the quantum well and improving the luminous efficiency of the device.
第一方面,本发明提供一种技术方案:In a first aspect, the present invention provides a technical solution:
一种采用复合电子阻挡层的紫外发光器件包括衬底和在所述衬底上依次生长的低温缓冲层、高温层、n型AlmGa1-mN层、发光有源区、p型复合电子阻挡层、p型AlnGa1-nN层和接触层;其中,所述p型复合电子阻挡层包括沿生长方向依次形成的p型L1层和p型L2层。An ultraviolet light-emitting device using a composite electron blocking layer comprises a substrate and a low-temperature buffer layer, a high-temperature layer, an n-type Al m Ga 1-m N layer, a light-emitting active region, a p-type composite electron blocking layer, a p-type Al n Ga 1-n N layer and a contact layer sequentially grown on the substrate; wherein the p-type composite electron blocking layer comprises a p-type L1 layer and a p-type L2 layer sequentially formed along a growth direction.
在本发明较佳的实施例中,所述p型L1层采用p-AlInGaN形成,所述p型L2层采用p-AlGaN/AlInGaN超晶格形成。In a preferred embodiment of the present invention, the p-type L1 layer is formed of p-AlInGaN, and the p-type L2 layer is formed of p-AlGaN/AlInGaN superlattice.
在本发明较佳的实施例中,所述p型L1层采用p-AlInGaN形成,所述p型L2层采用p-AlGaN形成。In a preferred embodiment of the present invention, the p-type L1 layer is formed of p-AlInGaN, and the p-type L2 layer is formed of p-AlGaN.
在本发明较佳的实施例中,所述p型L1层采用p-AlGaN形成,所述p型L2层采用p-AlGaN/AlInGaN超晶格形成。In a preferred embodiment of the present invention, the p-type L1 layer is formed of p-AlGaN, and the p-type L2 layer is formed of p-AlGaN/AlInGaN superlattice.
在本发明较佳的实施例中,所述p型L1层采用p-AlGaN形成,所述p型L2层采用p-AlInGaN形成。In a preferred embodiment of the present invention, the p-type L1 layer is formed of p-AlGaN, and the p-type L2 layer is formed of p-AlInGaN.
在本发明较佳的实施例中,所述p型L1层的厚度范围为:5nm~30nm,所述p型L2层的厚度范围为:5nm~30nm。In a preferred embodiment of the present invention, the thickness of the p-type L1 layer is in the range of 5 nm to 30 nm, and the thickness of the p-type L2 layer is in the range of 5 nm to 30 nm.
在本发明较佳的实施例中,所述p型L1层和所述p型L2层中的p-AlGaN或者p-AlInGaN的Al组分值、In组分值在各自单层中是固定不变的,或者是线性渐变的。In a preferred embodiment of the present invention, the Al composition value and the In composition value of the p-AlGaN or p-AlInGaN in the p-type L1 layer and the p-type L2 layer are fixed or linearly gradient in their respective single layers.
在本发明较佳的实施例中,所述发光有源区由量子阱层和量子垒层交替生长而成。In a preferred embodiment of the present invention, the light emitting active region is formed by alternating growth of quantum well layers and quantum barrier layers.
在本发明较佳的实施例中,所述p型L1层中的Al组分值和所述p型L2层中的Al组分值均大于所述量子垒层中的Al组分值。In a preferred embodiment of the present invention, the Al composition value in the p-type L1 layer and the Al composition value in the p-type L2 layer are both greater than the Al composition value in the quantum barrier layer.
在本发明较佳的实施例中,所述p型L1层中的In组分值和所述p型L2层中的In组分值均大于所述量子阱层中的In组分值。In a preferred embodiment of the present invention, the In composition value in the p-type L1 layer and the In composition value in the p-type L2 layer are both greater than the In composition value in the quantum well layer.
第二方面,本发明提供一种技术方案:In a second aspect, the present invention provides a technical solution:
一种采用复合电子阻挡层的紫外发光器件的制备方法,包括:在所述衬底上依次生长的低温缓冲层、高温层、n型AlmGa1-mN层、发光有源区、p型复合电子阻挡层、p型AlnGa1-nN层和接触层;其中,所述p型复合电子阻挡层包括沿生长方向依次形成的p型L1层和p型L2层。A method for preparing an ultraviolet light-emitting device using a composite electron blocking layer comprises: a low-temperature buffer layer, a high-temperature layer, an n-type Al m Ga 1-m N layer, a light-emitting active region, a p-type composite electron blocking layer, a p-type Al n Ga 1-n N layer and a contact layer grown sequentially on the substrate; wherein the p-type composite electron blocking layer comprises a p-type L1 layer and a p-type L2 layer sequentially formed along the growth direction.
本发明提供的采用复合电子阻挡层的紫外发光器件及其制备方法的有益效果是:The beneficial effects of the ultraviolet light-emitting device using a composite electron blocking layer and the preparation method thereof provided by the present invention are:
在紫外发光器件中引入p型复合电子阻挡层,p型L1层的主要作用是与量子阱层的晶格进行匹配和调节最后一个量子垒层的能带,有效降低量子阱层中的电子泄露。p型L2层的主要作用是提高电子阻挡效应、增强空穴注入效率,以及载流子注入时的电流扩展能力,让载流子能更有效地、均匀地、注入器件的发光有源区,进行辐射复合,提高紫外发光器件的光效。Introducing a p-type composite electron blocking layer in the ultraviolet light-emitting device, the main function of the p-type L1 layer is to match the lattice of the quantum well layer and adjust the energy band of the last quantum barrier layer, effectively reducing the electron leakage in the quantum well layer. The main function of the p-type L2 layer is to improve the electron blocking effect, enhance the hole injection efficiency, and the current expansion capability during carrier injection, so that the carriers can be more effectively and evenly injected into the light-emitting active area of the device for radiation recombination, thereby improving the light efficiency of the ultraviolet light-emitting device.
附图说明BRIEF DESCRIPTION OF THE DRAWINGS
为了更清楚地说明本发明实施例的技术方案,下面将对实施例中所需要使用的附图作简单地介绍,应当理解,以下附图仅示出了本发明的某些实施例,因此不应被看作是对范围的限定,对于本领域普通技术人员来讲,在不付出创造性劳动的前提下,还可以根据这些附图获得其他相关的附图。In order to more clearly illustrate the technical solutions of the embodiments of the present invention, the drawings required for use in the embodiments are briefly introduced below. It should be understood that the following drawings only show certain embodiments of the present invention and therefore should not be regarded as limiting the scope. For ordinary technicians in this field, other related drawings can be obtained based on these drawings without creative work.
图1为本发明第一实施例提供的紫外发光器件的结构示意图。FIG1 is a schematic structural diagram of an ultraviolet light emitting device provided in a first embodiment of the present invention.
图2为本发明第五实施例提供的紫外发光器件的制备方法的流程图。FIG. 2 is a flow chart of a method for preparing an ultraviolet light-emitting device provided in a fifth embodiment of the present invention.
图3和图4为紫外发光器件制备过程的结构示意图。3 and 4 are schematic diagrams of the structure of the ultraviolet light emitting device preparation process.
图标:100-紫外发光器件;110-衬底;120-低温缓冲层;130-高温层;140-n型AlmGa1-mN层;150-发光有源区;160-p型复合电子阻挡层;161-p型L1层;162-p型L2层;170-p型AlnGa1-nN层;180-接触层。Icon: 100-ultraviolet light-emitting device; 110-substrate; 120-low-temperature buffer layer; 130-high-temperature layer; 140-n-type Al m Ga 1-m N layer; 150-light-emitting active region; 160-p-type composite electron blocking layer; 161-p-type L1 layer; 162-p-type L2 layer; 170-p-type Al n Ga 1-n N layer; 180-contact layer.
具体实施方式Detailed ways
为使本发明实施例的目的、技术方案和优点更加清楚,下面将结合本发明实施例中的附图,对本发明实施例中的技术方案进行清楚、完整地描述,显然,所描述的实施例是本发明一部分实施例,而不是全部的实施例。通常在此处附图中描述和示出的本发明实施例的组件可以以各种不同的配置来布置和设计。In order to make the purpose, technical solutions and advantages of the embodiments of the present invention clearer, the technical solutions in the embodiments of the present invention will be clearly and completely described below in conjunction with the drawings in the embodiments of the present invention. Obviously, the described embodiments are part of the embodiments of the present invention, not all of the embodiments. Generally, the components of the embodiments of the present invention described and shown in the drawings here can be arranged and designed in various different configurations.
因此,以下对在附图中提供的本发明的实施例的详细描述并非旨在限制要求保护的本发明的范围,而是仅仅表示本发明的选定实施例。基于本发明中的实施例,本领域普通技术人员在没有作出创造性劳动前提下所获得的所有其他实施例,都属于本发明保护的范围。Therefore, the following detailed description of the embodiments of the present invention provided in the accompanying drawings is not intended to limit the scope of the invention claimed for protection, but merely represents selected embodiments of the present invention. Based on the embodiments of the present invention, all other embodiments obtained by ordinary technicians in this field without creative work are within the scope of protection of the present invention.
应注意到:相似的标号和字母在下面的附图中表示类似项,因此,一旦某一项在一个附图中被定义,则在随后的附图中不需要对其进行进一步定义和解释。It should be noted that similar reference numerals and letters denote similar items in the following drawings, and therefore, once an item is defined in one drawing, it does not require further definition and explanation in the subsequent drawings.
在本发明的描述中,需要理解的是,术语“中心”、“上”、“下”、“左”、“右”、“竖直”、“水平”、“内”、“外”等指示的方位或位置关系为基于附图所示的方位或位置关系,或者是该发明产品使用时惯常摆放的方位或位置关系,或者是本领域技术人员惯常理解的方位或位置关系,仅是为了便于描述本发明和简化描述,而不是指示或暗示所指的设备或元件必须具有特定的方位、以特定的方位构造和操作,因此不能理解为对本发明的限制。In the description of the present invention, it should be understood that the terms "center", "up", "down", "left", "right", "vertical", "horizontal", "inside", "outside" and the like indicate orientations or positional relationships based on the orientations or positional relationships shown in the accompanying drawings, or are the orientations or positional relationships in which the inventive product is conventionally placed when in use, or are the orientations or positional relationships conventionally understood by those skilled in the art. They are only for the convenience of describing the present invention and simplifying the description, and do not indicate or imply that the device or element referred to must have a specific orientation, be constructed and operated in a specific orientation, and therefore should not be understood as a limitation on the present invention.
此外,术语“第一”、“第二”、“第三”等仅用于区分描述,而不能理解为指示或暗示相对重要性。Furthermore, the terms “first”, “second”, “third”, etc. are merely used for distinguishing descriptions and are not to be understood as indicating or implying relative importance.
在本发明的描述中,还需要说明的是,除非另有明确的规定和限定,术语“设置”、“安装”、“相连”、“连接”应做广义理解,例如,可以是固定连接,也可以是可拆卸连接,或一体地连接;可以是机械连接,也可以是电连接;可以是直接相连,也可以通过中间媒介间接相连,可以是两个元件内部的连通。对于本领域的普通技术人员而言,可以具体情况理解上述术语在本发明中的具体含义。In the description of the present invention, it is also necessary to explain that, unless otherwise clearly specified and limited, the terms "set", "install", "connect", and "connect" should be understood in a broad sense, for example, it can be a fixed connection, a detachable connection, or an integral connection; it can be a mechanical connection or an electrical connection; it can be a direct connection, or it can be indirectly connected through an intermediate medium, or it can be the internal communication of two elements. For ordinary technicians in this field, the specific meanings of the above terms in the present invention can be understood according to specific circumstances.
限制紫外发光二极管的光效的一个关键因素,就是空穴注入不足及电子泄漏。因为Mg在GaN中的激活能在200meV左右,在高Al组分的p-AlGaN中激活能更高(在AlN中达到630meV),能够热激活的空穴浓度更低,引起空穴注入的严重不足,导致大量电子从有源区泄漏到p型区损耗掉;Si在GaN中的激活能仅为15meV,在AlN中也高达282meV。A key factor limiting the light efficiency of ultraviolet light-emitting diodes is insufficient hole injection and electron leakage. Because the activation energy of Mg in GaN is about 200meV, and the activation energy in p-AlGaN with a high Al content is higher (reaching 630meV in AlN), the concentration of holes that can be thermally activated is lower, causing a serious lack of hole injection, resulting in a large number of electrons leaking from the active region to the p-type region and being lost; the activation energy of Si in GaN is only 15meV, and it is as high as 282meV in AlN.
无论是N型掺杂,还是P型掺杂,杂质在宽禁带AlGaN中的掺杂效率是非常低的。对于极性面生长的紫外发光二极管,极化效应会进一步加重电子电流泄漏。这些泄漏的电子不能有效发光,其能量只能以发热的形式耗散掉。Whether it is N-type doping or P-type doping, the doping efficiency of impurities in wide bandgap AlGaN is very low. For ultraviolet light-emitting diodes grown on polar surfaces, the polarization effect will further aggravate the leakage of electron current. These leaked electrons cannot emit light effectively, and their energy can only be dissipated in the form of heat.
为减少电子电流泄漏,在器件结构中最后一个量子垒(LQB)后引入了电子阻挡层(EBL),利用LQB/EBL界面的导带阶阻挡电子泄漏。一般蓝光发光二极管通常采用GaN作为LQB,AlGaN作为EBL;紫外发光二极管通常采用Al组分恒定的AlGaN作为LQB,较高Al组分的AlGaN作为EBL。然而,如此获得的结构又会使价带上移,对空穴形成势垒,使得空穴注入更为不足,从而不利于辐射复合,同时空穴注入的不足,又会诱发更大的电子泄漏。因此,如何有效地提高紫外光半导体发光二极管的载流子注入效率,直接影响到其内量子效率和发光效率的提升。In order to reduce the leakage of electron current, an electron blocking layer (EBL) is introduced after the last quantum barrier (LQB) in the device structure, and the conduction band step of the LQB/EBL interface is used to block the electron leakage. Generally, blue light emitting diodes usually use GaN as LQB and AlGaN as EBL; ultraviolet light emitting diodes usually use AlGaN with a constant Al component as LQB and AlGaN with a higher Al component as EBL. However, the structure obtained in this way will cause the valence band to move up, forming a potential barrier for holes, making hole injection more insufficient, which is not conducive to radiative recombination. At the same time, the insufficient hole injection will induce greater electron leakage. Therefore, how to effectively improve the carrier injection efficiency of ultraviolet semiconductor light emitting diodes directly affects the improvement of their internal quantum efficiency and luminous efficiency.
本发明的以下实施例提供一种采用复合电子阻挡层的紫外发光器件及其制备方法,在紫外发光二极管中引入复合电子阻挡层结构,优化器件的能带结构,能有效地增加电子限制效果、增强空穴注入效率,以及载流子注入时的电流扩展能力,从而提高紫外发光二极管的在量子阱中的辐射复合速率,改善器件的发光效率。The following embodiments of the present invention provide an ultraviolet light-emitting device using a composite electron blocking layer and a preparation method thereof. The composite electron blocking layer structure is introduced into the ultraviolet light-emitting diode to optimize the energy band structure of the device, which can effectively increase the electron confinement effect, enhance the hole injection efficiency, and the current expansion capability during carrier injection, thereby increasing the radiation recombination rate of the ultraviolet light-emitting diode in the quantum well and improving the luminous efficiency of the device.
第一实施例First embodiment
请参阅图1,本实施例提供了一种采用复合电子阻挡层的紫外发光器件100,所述紫外发光器件100包括衬底110和在所述衬底110上依次生长的低温缓冲层120、高温层130、n型AlmGa1-mN层140、发光有源区150、p型复合电子阻挡层160、p型AlnGa1-nN层170和接触层180。Referring to FIG. 1 , this embodiment provides an ultraviolet light-emitting device 100 using a composite electron blocking layer, wherein the ultraviolet light-emitting device 100 includes a substrate 110 and a low-temperature buffer layer 120 , a high-temperature layer 130 , an n-type Al m Ga 1-m N layer 140 , a light-emitting active region 150 , a p-type composite electron blocking layer 160 , a p-type Al n Ga 1-n N layer 170 and a contact layer 180 sequentially grown on the substrate 110 .
其中,发光有源区150包括InxGa1-xN和AlyGa1-yN,0.001≤x<y≤1。所述发光有源区150由量子阱层和量子垒层交替生长而成。所述量子阱层的厚度范围为:1.5nm~10nm,所述量子垒层的厚度范围为:4nm~20nm。The light emitting active region 150 includes InxGa1 -xN and AlyGa1 -yN , 0.001≤x<y≤1. The light emitting active region 150 is formed by alternating growth of quantum well layers and quantum barrier layers. The thickness of the quantum well layers ranges from 1.5nm to 10nm, and the thickness of the quantum barrier layers ranges from 4nm to 20nm.
所述p型复合电子阻挡层160包括沿生长方向依次形成的p型L1层161和p型L2层162。所述p型L1层161采用p-AlInGaN形成,所述p型L1层161的厚度范围为:5nm~30nm。所述p型L1层161中的Al组分值可以超过所述量子垒层中的Al组分值,也可以超过量子阱层中的Al组分值。所述p型L1层161中的In组分值可以超过所述量子垒层中的In组分值,也可以超过量子阱层中的In组分值。p型L1层161的主要作用是与量子阱层的晶格进行匹配和调节最后一个量子垒层的能带,有效降低量子阱层中的电子泄露。The p-type composite electron blocking layer 160 includes a p-type L1 layer 161 and a p-type L2 layer 162 sequentially formed along the growth direction. The p-type L1 layer 161 is formed of p-AlInGaN, and the thickness of the p-type L1 layer 161 ranges from 5nm to 30nm. The Al component value in the p-type L1 layer 161 may exceed the Al component value in the quantum barrier layer, or may exceed the Al component value in the quantum well layer. The In component value in the p-type L1 layer 161 may exceed the In component value in the quantum barrier layer, or may exceed the In component value in the quantum well layer. The main function of the p-type L1 layer 161 is to match the lattice of the quantum well layer and adjust the energy band of the last quantum barrier layer, effectively reducing the electron leakage in the quantum well layer.
所述p型L2层162采用p-AlGaN/AlInGaN超晶格形成,p-AlGaN/AlInGaN超晶格是指采用AlGaN和AlInGaN依次层叠生长,并进行p型掺杂。所述p型L2层162的厚度范围为:5nm~30nm。所述p型L2层162中的Al组分值可以超过所述量子垒层中的Al组分值,也可以超过量子阱层中的Al组分值。所述p型L2层162中的In组分值可以超过所述量子垒层中的In组分值,也可以超过量子阱层中的In组分值。p型L2层162的主要作用是提高电子阻挡效应、增强空穴注入效率,以及载流子注入时的电流扩展能力,让载流子能更有效地、均匀地、注入器件的发光有源区150,进行辐射复合,提高紫外发光器件100的光效。The p-type L2 layer 162 is formed by p-AlGaN/AlInGaN superlattice, which refers to the use of AlGaN and AlInGaN stacked and grown in sequence, and p-type doping is performed. The thickness range of the p-type L2 layer 162 is: 5nm to 30nm. The Al component value in the p-type L2 layer 162 can exceed the Al component value in the quantum barrier layer, and can also exceed the Al component value in the quantum well layer. The In component value in the p-type L2 layer 162 can exceed the In component value in the quantum barrier layer, and can also exceed the In component value in the quantum well layer. The main function of the p-type L2 layer 162 is to improve the electron blocking effect, enhance the hole injection efficiency, and the current expansion capability during carrier injection, so that the carriers can be more effectively and uniformly injected into the light-emitting active area 150 of the device, perform radiation recombination, and improve the light efficiency of the ultraviolet light-emitting device 100.
本实施例提供的紫外发光器件100的有益效果:The beneficial effects of the ultraviolet light emitting device 100 provided in this embodiment are as follows:
在紫外发光器件100中引入p型复合电子阻挡层160,优化器件的能带结构,能有效地增加电子限制效果、增强空穴注入效率,以及载流子注入时的电流扩展能力,从而提高紫外发光器件100的在量子阱层中的辐射复合速率,改善器件的发光效率。Introducing a p-type composite electron blocking layer 160 into the ultraviolet light-emitting device 100 and optimizing the energy band structure of the device can effectively increase the electron confinement effect, enhance the hole injection efficiency, and the current expansion capability during carrier injection, thereby increasing the radiation recombination rate of the ultraviolet light-emitting device 100 in the quantum well layer and improving the luminous efficiency of the device.
第二实施例Second embodiment
本实施例提供了一种采用复合电子阻挡层的紫外发光器件100,其与第一实施例中的结构相近,不同之处在于:本实施例中的p型复合电子阻挡层160的材料组成不同。This embodiment provides an ultraviolet light emitting device 100 using a composite electron blocking layer, which has a similar structure to that of the first embodiment, except that the material composition of the p-type composite electron blocking layer 160 in this embodiment is different.
所述p型复合电子阻挡层160包括沿生长方向依次形成的p型L1层161和p型L2层162。所述p型L1层161采用p-AlInGaN形成,所述p型L1层161的厚度范围为:5nm~30nm。所述p型L1层161中的Al组分值可以超过所述量子垒层中的Al组分值,也可以超过量子阱层中的Al组分值。所述p型L1层161中的In组分值可以超过所述量子垒层中的In组分值,也可以超过量子阱层中的In组分值。p型L1层161的主要作用是与量子阱层的晶格进行匹配和调节最后一个量子垒层的能带,有效降低量子阱层中的电子泄露。The p-type composite electron blocking layer 160 includes a p-type L1 layer 161 and a p-type L2 layer 162 sequentially formed along the growth direction. The p-type L1 layer 161 is formed of p-AlInGaN, and the thickness of the p-type L1 layer 161 ranges from 5nm to 30nm. The Al component value in the p-type L1 layer 161 may exceed the Al component value in the quantum barrier layer, or may exceed the Al component value in the quantum well layer. The In component value in the p-type L1 layer 161 may exceed the In component value in the quantum barrier layer, or may exceed the In component value in the quantum well layer. The main function of the p-type L1 layer 161 is to match the lattice of the quantum well layer and adjust the energy band of the last quantum barrier layer, effectively reducing the electron leakage in the quantum well layer.
所述p型L2层162采用p-AlGaN形成,所述p型L2层162的厚度范围为:5nm~30nm。所述p型L2层162中的Al组分值可以超过所述量子垒层中的Al组分值,也可以超过量子阱层中的Al组分值。p型L2层162的主要作用是提高电子阻挡效应、增强空穴注入效率,以及载流子注入时的电流扩展能力,让载流子能更有效地、均匀地、注入器件的发光有源区150,进行辐射复合,提高紫外发光器件100的光效。The p-type L2 layer 162 is formed of p-AlGaN, and the thickness of the p-type L2 layer 162 is in the range of 5nm to 30nm. The Al component value in the p-type L2 layer 162 can exceed the Al component value in the quantum barrier layer, and can also exceed the Al component value in the quantum well layer. The main function of the p-type L2 layer 162 is to improve the electron blocking effect, enhance the hole injection efficiency, and the current expansion capability during carrier injection, so that the carriers can be more effectively and uniformly injected into the light-emitting active area 150 of the device, perform radiation recombination, and improve the light efficiency of the ultraviolet light-emitting device 100.
第三实施例Third embodiment
本实施例提供了一种采用复合电子阻挡层的紫外发光器件100,其与第一实施例中的结构相近,不同之处在于:本实施例中的p型复合电子阻挡层160的材料组成不同。This embodiment provides an ultraviolet light emitting device 100 using a composite electron blocking layer, which has a similar structure to that of the first embodiment, except that the material composition of the p-type composite electron blocking layer 160 in this embodiment is different.
所述p型复合电子阻挡层160包括沿生长方向依次形成的p型L1层161和p型L2层162。所述p型L1层161采用p-AlGaN形成,所述p型L1层161的厚度范围为:5nm~30nm。所述p型L1层161中的Al组分值可以超过所述量子垒层中的Al组分值,也可以超过量子阱层中的Al组分值。p型L1层161的主要作用是与量子阱层的晶格进行匹配和调节最后一个量子垒层的能带,有效降低量子阱层中的电子泄露。The p-type composite electron blocking layer 160 includes a p-type L1 layer 161 and a p-type L2 layer 162 sequentially formed along the growth direction. The p-type L1 layer 161 is formed of p-AlGaN, and the thickness of the p-type L1 layer 161 ranges from 5nm to 30nm. The Al component value in the p-type L1 layer 161 may exceed the Al component value in the quantum barrier layer, and may also exceed the Al component value in the quantum well layer. The main function of the p-type L1 layer 161 is to match the lattice of the quantum well layer and adjust the energy band of the last quantum barrier layer, effectively reducing the electron leakage in the quantum well layer.
所述p型L2层162采用p-AlGaN/AlInGaN超晶格形成,所述p型L2层162的厚度范围为:5nm~30nm。所述p型L2层162中的Al组分值可以超过所述量子垒层中的Al组分值,也可以超过量子阱层中的Al组分值。所述p型L2层162中的In组分值可以超过所述量子垒层中的In组分值,也可以超过量子阱层中的In组分值。p型L2层162的主要作用是提高电子阻挡效应、增强空穴注入效率,以及载流子注入时的电流扩展能力,让载流子能更有效地、均匀地、注入器件的发光有源区150,进行辐射复合,提高紫外发光器件100的光效。The p-type L2 layer 162 is formed by p-AlGaN/AlInGaN superlattice, and the thickness of the p-type L2 layer 162 ranges from 5nm to 30nm. The Al component value in the p-type L2 layer 162 can exceed the Al component value in the quantum barrier layer, and can also exceed the Al component value in the quantum well layer. The In component value in the p-type L2 layer 162 can exceed the In component value in the quantum barrier layer, and can also exceed the In component value in the quantum well layer. The main function of the p-type L2 layer 162 is to improve the electron blocking effect, enhance the hole injection efficiency, and the current expansion capability during carrier injection, so that the carriers can be more effectively and uniformly injected into the light-emitting active area 150 of the device, perform radiation recombination, and improve the light efficiency of the ultraviolet light-emitting device 100.
第四实施例Fourth embodiment
本实施例提供了一种采用复合电子阻挡层的紫外发光器件100,其与第一实施例中的结构相近,不同之处在于:本实施例中的p型复合电子阻挡层160的材料组成不同。This embodiment provides an ultraviolet light emitting device 100 using a composite electron blocking layer, which has a similar structure to that of the first embodiment, except that the material composition of the p-type composite electron blocking layer 160 in this embodiment is different.
所述p型复合电子阻挡层160包括沿生长方向依次形成的p型L1层161和p型L2层162。所述p型L1层161采用p-AlGaN形成,所述p型L1层161的厚度范围为:5nm~30nm。所述p型L1层161中的Al组分值可以超过所述量子垒层中的Al组分值,也可以超过量子阱层中的Al组分值。p型L1层161的主要作用是与量子阱层的晶格进行匹配和调节最后一个量子垒层的能带,有效降低量子阱层中的电子泄露。The p-type composite electron blocking layer 160 includes a p-type L1 layer 161 and a p-type L2 layer 162 sequentially formed along the growth direction. The p-type L1 layer 161 is formed of p-AlGaN, and the thickness of the p-type L1 layer 161 ranges from 5nm to 30nm. The Al component value in the p-type L1 layer 161 may exceed the Al component value in the quantum barrier layer, and may also exceed the Al component value in the quantum well layer. The main function of the p-type L1 layer 161 is to match the lattice of the quantum well layer and adjust the energy band of the last quantum barrier layer, effectively reducing the electron leakage in the quantum well layer.
所述p型L2层162采用p-AlInGaN形成,所述p型L2层162的厚度范围为:5nm~30nm。所述p型L2层162中的Al组分值可以超过所述量子垒层中的Al组分值,也可以超过量子阱层中的Al组分值。所述p型L2层162中的In组分值可以超过所述量子垒层中的In组分值,也可以超过量子阱层中的In组分值。p型L2层162的主要作用是提高电子阻挡效应、增强空穴注入效率,以及载流子注入时的电流扩展能力,让载流子能更有效地、均匀地、注入器件的发光有源区150,进行辐射复合,提高紫外发光器件100的光效。The p-type L2 layer 162 is formed of p-AlInGaN, and the thickness of the p-type L2 layer 162 is in the range of 5nm to 30nm. The Al component value in the p-type L2 layer 162 may exceed the Al component value in the quantum barrier layer, and may also exceed the Al component value in the quantum well layer. The In component value in the p-type L2 layer 162 may exceed the In component value in the quantum barrier layer, and may also exceed the In component value in the quantum well layer. The main function of the p-type L2 layer 162 is to improve the electron blocking effect, enhance the hole injection efficiency, and the current expansion capability during carrier injection, so that the carriers can be more effectively and uniformly injected into the light-emitting active area 150 of the device, perform radiation recombination, and improve the light efficiency of the ultraviolet light-emitting device 100.
第五实施例Fifth embodiment
请参阅图2,本实施例提供一种采用复合电子阻挡层的紫外发光器件100的制备方法,这里的制备方法主要运用于制备第一实施例至第四实施例中任一种的紫外发光器件100。Please refer to FIG. 2 . This embodiment provides a method for preparing an ultraviolet light-emitting device 100 using a composite electron blocking layer. The preparation method here is mainly used to prepare any one of the ultraviolet light-emitting devices 100 in the first to fourth embodiments.
采用复合电子阻挡层的紫外发光器件100的制备方法包括以下步骤:The method for preparing the ultraviolet light emitting device 100 using the composite electron blocking layer comprises the following steps:
S1:请参阅图3,在所述衬底110上依次生长低温缓冲层120、高温层130、n型AlmGa1-mN层140、发光有源区150。S1: Please refer to FIG. 3 . A low-temperature buffer layer 120 , a high-temperature layer 130 , an n-type Al m Ga 1-m N layer 140 , and a light-emitting active region 150 are sequentially grown on the substrate 110 .
其中,发光有源区150包括InxGa1-xN和AlyGa1-yN,0.001≤x<y≤1。所述发光有源区150由量子阱层和量子垒层交替生长而成。所述量子阱层的厚度范围为:1.5nm~10nm,所述量子垒层的厚度范围为:4nm~20nm。The light emitting active region 150 includes InxGa1 -xN and AlyGa1 -yN , 0.001≤x<y≤1. The light emitting active region 150 is formed by alternating growth of quantum well layers and quantum barrier layers. The thickness of the quantum well layers ranges from 1.5nm to 10nm, and the thickness of the quantum barrier layers ranges from 4nm to 20nm.
S2:请参阅图4,在发光有源区150上生长p型复合电子阻挡层160,其中,所述p型复合电子阻挡层160包括沿生长方向依次形成的p型L1层161和p型L2层162。S2: Please refer to FIG. 4 , a p-type composite electron blocking layer 160 is grown on the light emitting active region 150 , wherein the p-type composite electron blocking layer 160 includes a p-type L1 layer 161 and a p-type L2 layer 162 sequentially formed along a growth direction.
若要制备第一实施例中的紫外发光器件100,则所述p型L1层161采用p-AlInGaN形成,所述p型L1层161的厚度范围为:5nm~30nm。所述p型L2层162采用p-AlGaN/AlInGaN超晶格形成,所述p型L2层162的厚度范围为:5nm~30nm。To prepare the ultraviolet light emitting device 100 in the first embodiment, the p-type L1 layer 161 is formed of p-AlInGaN, and the thickness of the p-type L1 layer 161 is in the range of 5 nm to 30 nm. The p-type L2 layer 162 is formed of p-AlGaN/AlInGaN superlattice, and the thickness of the p-type L2 layer 162 is in the range of 5 nm to 30 nm.
若要制备第二实施例中的紫外发光器件100,则所述p型L1层161采用p-AlInGaN形成,所述p型L1层161的厚度范围为:5nm~30nm。所述p型L2层162采用p-AlGaN形成,所述p型L2层162的厚度范围为:5nm~30nm。To prepare the ultraviolet light emitting device 100 in the second embodiment, the p-type L1 layer 161 is formed of p-AlInGaN, and the thickness of the p-type L1 layer 161 is in the range of 5 nm to 30 nm. The p-type L2 layer 162 is formed of p-AlGaN, and the thickness of the p-type L2 layer 162 is in the range of 5 nm to 30 nm.
若要制备第三实施例中的紫外发光器件100,则所述p型L1层161采用p-AlGaN形成,所述p型L1层161的厚度范围为:5nm~30nm。所述p型L2层162采用p-AlGaN/AlInGaN超晶格形成,所述p型L2层162的厚度范围为:5nm~30nm。To prepare the ultraviolet light emitting device 100 in the third embodiment, the p-type L1 layer 161 is formed of p-AlGaN, and the thickness of the p-type L1 layer 161 is in the range of 5 nm to 30 nm. The p-type L2 layer 162 is formed of p-AlGaN/AlInGaN superlattice, and the thickness of the p-type L2 layer 162 is in the range of 5 nm to 30 nm.
若要制备第四实施例中的紫外发光器件100,则所述p型L1层161采用p-AlGaN形成,所述p型L1层161的厚度范围为:5nm~30nm。所述p型L2层162采用p-AlInGaN形成,所述p型L2层162的厚度范围为:5nm~30nm。To prepare the ultraviolet light emitting device 100 in the fourth embodiment, the p-type L1 layer 161 is formed of p-AlGaN, and the thickness of the p-type L1 layer 161 is in the range of 5 nm to 30 nm. The p-type L2 layer 162 is formed of p-AlInGaN, and the thickness of the p-type L2 layer 162 is in the range of 5 nm to 30 nm.
p型L1层161的主要作用是与量子阱层的晶格进行匹配和调节最后一个量子垒层的能带,有效降低量子阱层中的电子泄露。p型L2层162的主要作用是提高电子阻挡效应、增强空穴注入效率,以及载流子注入时的电流扩展能力,让载流子能更有效地、均匀地、注入器件的发光有源区150,进行辐射复合,提高紫外发光器件100的光效。The main function of the p-type L1 layer 161 is to match the lattice of the quantum well layer and adjust the energy band of the last quantum barrier layer, effectively reducing the electron leakage in the quantum well layer. The main function of the p-type L2 layer 162 is to improve the electron blocking effect, enhance the hole injection efficiency, and the current expansion capability during carrier injection, so that the carriers can be more effectively and evenly injected into the light-emitting active area 150 of the device for radiation recombination, thereby improving the light efficiency of the ultraviolet light-emitting device 100.
此外,所述p型L1层161和p型L2层162中的AlInGaN的In组分值可以高于量子阱层中的In组分值,具有调节极化强度及方向等作用。In addition, the In composition value of AlInGaN in the p-type L1 layer 161 and the p-type L2 layer 162 may be higher than the In composition value in the quantum well layer, which has the function of adjusting the polarization intensity and direction.
S3:请参阅图1,在p型复合电子阻挡层160上依次生长p型AlnGa1-nN层170和接触层180。S3 : Referring to FIG. 1 , a p-type Al n Ga 1-n N layer 170 and a contact layer 180 are sequentially grown on the p-type composite electron blocking layer 160 .
本申请中只详细介绍了将p型复合电子阻挡层160运用于紫外发光器件100的例子,本申请提供的p型复合电子阻挡层160当然还可以运用到其它结构形式的半导体器件中,在这里不再赘述,只要运用了本申请中提供的p型复合电子阻挡层160的构思,都应该属于本申请要求保护的范围。This application only introduces in detail the example of applying the p-type composite electron blocking layer 160 to the ultraviolet light-emitting device 100. The p-type composite electron blocking layer 160 provided in this application can of course also be applied to semiconductor devices of other structural forms, which will not be repeated here. As long as the concept of the p-type composite electron blocking layer 160 provided in this application is used, it should fall within the scope of protection required by this application.
需要说明的是,本申请中提到的数值,包括厚度的取值等,都只是申请人通过实验和测算获得的较为可靠的数值,而不是严格限定对应的参数只能是这些取值。本领域的技术人员可能会在本申请的方案的基础上,做进一步的实验,获得其他效果相近的取值,这些取值也没有脱离本申请的核心,也应该属于本申请要求保护的范围。It should be noted that the values mentioned in this application, including the values of thickness, are only relatively reliable values obtained by the applicant through experiments and measurements, rather than strictly limiting the corresponding parameters to only these values. Those skilled in the art may conduct further experiments based on the scheme of this application to obtain other values with similar effects, and these values do not deviate from the core of this application and should also fall within the scope of protection claimed in this application.
本申请中各个层结构采用的材料,都只是申请人通过实验获得的较为可靠材料,而不是严格限定只能采用这些材料。本领域的技术人员可能会在本申请的方案的基础上,做进一步的实验,获得其他效果相近的材料,这些材料也没有脱离本申请的核心,也应该属于本申请要求保护的范围。The materials used in each layer structure in this application are only relatively reliable materials obtained by the applicant through experiments, and are not strictly limited to these materials. Those skilled in the art may conduct further experiments based on the scheme of this application to obtain other materials with similar effects. These materials do not deviate from the core of this application and should also fall within the scope of protection claimed in this application.
以上所述仅为本发明的优选实施例而已,并不用于限制本发明,对于本领域的技术人员来说,本发明可以有各种更改和变化。凡在本发明的精神和原则之内,所作的任何修改、等同替换、改进等,均应包含在本发明的保护范围之内。The above description is only a preferred embodiment of the present invention and is not intended to limit the present invention. For those skilled in the art, the present invention may have various modifications and variations. Any modification, equivalent replacement, improvement, etc. made within the spirit and principle of the present invention shall be included in the protection scope of the present invention.
Claims (8)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201911215981.0A CN110993759B (en) | 2019-12-02 | 2019-12-02 | Ultraviolet light emitting device using composite electron blocking layer and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201911215981.0A CN110993759B (en) | 2019-12-02 | 2019-12-02 | Ultraviolet light emitting device using composite electron blocking layer and preparation method thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN110993759A CN110993759A (en) | 2020-04-10 |
| CN110993759B true CN110993759B (en) | 2024-05-17 |
Family
ID=70089411
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201911215981.0A Active CN110993759B (en) | 2019-12-02 | 2019-12-02 | Ultraviolet light emitting device using composite electron blocking layer and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN110993759B (en) |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2010205767A (en) * | 2009-02-27 | 2010-09-16 | Institute Of Physical & Chemical Research | Optical semiconductor element and method of manufacturing the same |
| CN105977356A (en) * | 2016-05-17 | 2016-09-28 | 东南大学 | UV light emitting diode with compound electronic barrier layer structure |
| CN211350680U (en) * | 2019-12-02 | 2020-08-25 | 广东省半导体产业技术研究院 | Ultraviolet light-emitting device adopting novel electron blocking layer |
-
2019
- 2019-12-02 CN CN201911215981.0A patent/CN110993759B/en active Active
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2010205767A (en) * | 2009-02-27 | 2010-09-16 | Institute Of Physical & Chemical Research | Optical semiconductor element and method of manufacturing the same |
| CN105977356A (en) * | 2016-05-17 | 2016-09-28 | 东南大学 | UV light emitting diode with compound electronic barrier layer structure |
| CN211350680U (en) * | 2019-12-02 | 2020-08-25 | 广东省半导体产业技术研究院 | Ultraviolet light-emitting device adopting novel electron blocking layer |
Also Published As
| Publication number | Publication date |
|---|---|
| CN110993759A (en) | 2020-04-10 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN107275450B (en) | A kind of ultraviolet LED epitaxial structure | |
| CN108231960B (en) | An AlGaN-based semiconductor ultraviolet device that improves light efficiency and its preparation method | |
| CN110752279B (en) | A UV light emitting diode with an ultra-thin aluminum indium nitrogen insertion layer and a method for preparing the same | |
| CN105870283B (en) | A kind of light emitting diode with combined polarity face electronic barrier layer | |
| JP4110222B2 (en) | Light emitting diode | |
| CN104538517B (en) | LED epitaxial structure with n-type superlattice structure and growth method of LED epitaxial structure | |
| CN105449051B (en) | One kind is using MOCVD technologies in GaN substrate or GaN/Al2O3The method that high brightness homogeneity LED is prepared in compound substrate | |
| CN101728472A (en) | Multilayer LED chip structure and preparation method thereof | |
| CN109004074A (en) | LED epitaxial structure and preparation method thereof | |
| CN106229398A (en) | A kind of red-light LED epitaxial structure of high uniformity and preparation method thereof | |
| CN105957934B (en) | N-SiC substrate AlGaN-based vertical structure resonant cavity ultraviolet L ED chip and preparation method thereof | |
| CN112701196B (en) | AlGaN-based semiconductor ultraviolet device and its preparation method | |
| CN102185058B (en) | Nitride light-emitting diode (LED) structure and preparation method thereof | |
| CN102142492B (en) | Multiple quantum well structure, manufacturing method thereof and light emitting diode | |
| CN105742430A (en) | LED epitaxial structure and preparation method therefor | |
| CN101281945A (en) | GaN-based LED epitaxial wafer capable of simultaneously emitting light of different wavelengths and preparation method thereof | |
| CN207381425U (en) | A kind of ultraviolet LED epitaxial structure | |
| CN102332510A (en) | Method for growing light-emitting diodes with high antistatic ability by using metal organic compound vapor phase epitaxy technology | |
| CN207624727U (en) | Light emitting diode | |
| CN102148300A (en) | Manufacturing method of ultraviolet LED (light-emitting diode) | |
| CN102931302B (en) | Blue and green diode epitaxial slice and manufacturing method thereof | |
| CN111029448B (en) | A kind of near-ultraviolet LED using MOCVD technology and preparation method thereof | |
| CN110993759B (en) | Ultraviolet light emitting device using composite electron blocking layer and preparation method thereof | |
| CN110047980B (en) | Ultraviolet LED epitaxial structure and preparation method thereof | |
| CN211350680U (en) | Ultraviolet light-emitting device adopting novel electron blocking layer |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| GR01 | Patent grant | ||
| GR01 | Patent grant |