[go: up one dir, main page]

CN110791179A - Special antistatic coating for cover tape - Google Patents

Special antistatic coating for cover tape Download PDF

Info

Publication number
CN110791179A
CN110791179A CN201810869563.2A CN201810869563A CN110791179A CN 110791179 A CN110791179 A CN 110791179A CN 201810869563 A CN201810869563 A CN 201810869563A CN 110791179 A CN110791179 A CN 110791179A
Authority
CN
China
Prior art keywords
antistatic coating
cover tape
special
antistatic
water
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201810869563.2A
Other languages
Chinese (zh)
Inventor
王悦辉
刘常坤
李晶
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
University of Electronic Science and Technology of China Zhongshan Institute
Original Assignee
University of Electronic Science and Technology of China Zhongshan Institute
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by University of Electronic Science and Technology of China Zhongshan Institute filed Critical University of Electronic Science and Technology of China Zhongshan Institute
Priority to CN201810869563.2A priority Critical patent/CN110791179A/en
Publication of CN110791179A publication Critical patent/CN110791179A/en
Pending legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D165/00Coating compositions based on macromolecular compounds obtained by reactions forming a carbon-to-carbon link in the main chain; Coating compositions based on derivatives of such polymers
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/24Electrically-conducting paints
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
    • C09D7/63Additives non-macromolecular organic
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/65Additives macromolecular
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend

Landscapes

  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Packaging Frangible Articles (AREA)
  • Paints Or Removers (AREA)

Abstract

The invention discloses an antistatic coating special for a cover tape, which comprises the following raw material components in percentage by mass: 10-50% of Poly (3,4-ethylenedioxythiophene) -polystyrene sulfonic acid (Poly (3,4-ethylenedioxythiophene)/Poly (PEDOT/PSS)), 0.05-1.5% of wetting agent, 2-15% of water-based resin, 1-15% of active synergist, 0.05-3% of slipping agent and 50-70% of water, wherein the total content of the components is 100%.

Description

Special antistatic coating for cover tape
Technical Field
The invention relates to an antistatic coating, in particular to an antistatic coating special for an upper cover tape for packaging electronic parts.
Background
The cover tape is a strip product applied to the field of electronic packaging and is matched with a carrier tape for use. The cover tape usually uses a polyester or polypropylene film as a base layer, and is compounded or coated with different functional layers (an antistatic layer, an adhesive layer, etc.), and can be sealed on the surface of the carrier tape under the condition of external force or heating to form a closed space to protect electronic components in pockets of the carrier tape. To prevent electronic components from being electrostatically attracted to the cover tape, the surface of the cover tape is often antistatic. Polymeric antistatic agents are often added to the coating of cover tapes. However, these ionic antistatic agents act by adsorbing water, are greatly affected by air humidity, and have a short antistatic effect.
Aqueous polythiophene (PEDOT/PSS) antistatic agents are novel antistatic agents and do not rely on air humidity. The water-based resin adopted by the common polythiophene antistatic coating comprises polyurethane, acrylic resin, acrylic modified polyurethane and the like. The aqueous resins have good compatibility with polythiophene, good adhesive force and film-forming property on the film, and endow the film with stable and durable antistatic property. However, when the antistatic agent is coated on the surface of the cover tape, the resin layer reduces the adhesive force between the hot melt adhesive of the cover tape and the carrier tape, so that vibration can be generated when the cover tape is peeled off, the stability of the carrier tape is affected, and electronic components are easy to jump out.
The key to solve the problem is to find the water-based resin with good compatibility with the hot melt adhesive of the cover tape. The styrene-butadiene latex is polymer latex prepared by emulsion copolymerization of butadiene and styrene monomers after adding different chemicals and auxiliaries. The styrene-butadiene latex has the characteristics of good conjunctival strength, good binding power, good stability and fluidity, large filling amount, good moldability, excellent mechanical, chemical and freeze-thaw stability, good compatibility with pigment and filler and the like. The styrene-butadiene latex is selected to replace polyurethane and the like, and a proper wetting agent is selected in the coating formula, so that the coating can be uniformly coated on the surface of the cover tape, and the antistatic agent which has lasting antistatic effect and low humidity dependence and does not influence the bonding effect between the hot melt adhesive layer of the cover tape and the carrier tape can be obtained.
Disclosure of Invention
The invention provides an antistatic coating special for an upper cover tape for packaging electronic components according to different application purposes, which overcomes the defects in the prior art. The antistatic coating has a good antistatic effect and low humidity dependence, and can well slow down the vibration generated when the upper cover tape is stripped, so that the stability of the carrier tape is kept.
In order to achieve the purpose, the technical scheme adopted by the invention is as follows:
the antistatic coating special for the upper cover tape for packaging the electronic components comprises the following raw material components in percentage by mass: 10-50% of Poly (3,4-ethylenedioxythiophene) -polystyrene sulfonic acid (Poly (3,4-ethylenedioxythiophene)/Poly (PEDOT/PSS)), 0.05-1.5% of wetting agent, 2-15% of water-based resin, 1-15% of active synergist, 0.05-3% of slipping agent and 50-70% of water, wherein the total content of the components is 100%.
In the present invention, the wetting agent is preferably one of thioether nonionic super wetting agents and acetylene glycol ethoxy compound nonionic super wetting agents.
In the invention, the preferable scheme is that the water-based resin is one of butylbenzene latex and butyronitrile latex
In the invention, the preferable scheme is that the active synergist is one of dimethyl sulfoxide, N-methyl pyrrolidone, sorbitol and glycerol.
In the invention, the preferable scheme is that the slipping agent is a polydimethylsiloxane dispersion with a super molecular weight, and is preferably Dow Corning DC-51.
Compared with the prior art, the invention has the beneficial effects that: according to the antistatic coating special for the cover tape, styrene butadiene latex or butyronitrile latex is selected as bonding resin in the formula components, and a proper wetting agent is matched, so that after the antistatic layer is coated on the surface of the cover tape, the vibration generated when the upper cover tape is stripped can be well slowed down, and the stripping stability of the carrier tape is kept.
Detailed Description
In order to make the objects, technical solutions and advantages of the present invention clearer, the following describes technical solutions in the embodiments of the present invention clearly and completely in combination with the embodiments of the present invention. The described embodiments are only some, but not all embodiments of the invention. All other embodiments, which can be derived by a person skilled in the art from the embodiments given herein without making any creative effort, shall fall within the protection scope of the present invention.
Example 1:
the special antistatic coating for the cover tape comprises the following raw material components in percentage by mass: 20 g of PEDOT/PSS (solid content is 1.3%), 0.5 g of Dynol 604 wetting agent, 10 g of butylbenzene latex (solid content is 30%), 5 g of dimethyl sulfoxide, 0.1 g of Dow Corning DC-51 slipping agent and 64.4 g of water.
And adding PEDOT/PSS into water, fully stirring for 10 minutes, adding a Dynol 604 wetting agent and styrene-butadiene latex into the solution, fully stirring for 15 minutes, adding dimethyl sulfoxide and Dow Corning DC-51 slipping agent into the mixed solution, and fully stirring uniformly for 2 hours to obtain the special antistatic coating for the cover tape. Coating the mixture on the surface of the cover tape with a No. 5 wire bar, drying at 110 ℃, and measuring the antistatic property and the influence on the hot pressing property.
The antistatic performance of the formula is 106Omega/□, and the tensile force influence test after hot pressing at 180 ℃ for 0.05 second shows that the cover tape is free of vibration during stripping, and can keep the stripping smoothness of the carrier tape.
Example 2:
the special antistatic coating for the cover tape comprises the following raw material components in percentage by mass: 27 g of PEDOT/PSS (solid content: 1.3%), 0.4 g of Dynol 604 wetting agent, 8 g of butyronitrile latex (solid content: 30%), 4 g of dimethyl sulfoxide, 0.1 g of Dow Corning DC-51 slipping agent and 60.5 g of water.
And adding PEDOT/PSS into water, fully stirring for 10 minutes, adding a Dynol 604 wetting agent and styrene-butadiene latex into the solution, fully stirring for 15 minutes, adding dimethyl sulfoxide and Dow Corning DC-51 slipping agent into the mixed solution, and fully stirring uniformly for 2 hours to obtain the special antistatic coating for the cover tape. Coating the mixture on the surface of the cover tape with a No. 5 wire bar, drying at 110 ℃, and measuring the antistatic property and the influence on the hot pressing property.
The antistatic performance of the formula is 106Omega/□, and the tensile force influence test after hot pressing at 180 ℃ for 0.05 second shows that the cover tape is free of vibration during stripping, and can keep the stripping smoothness of the carrier tape.
Example 3:
the special antistatic coating for the cover tape comprises the following raw material components in percentage by mass: 21 g of PEDOT/PSS (solid content: 1.3%), 0.6 g of Dynol 604 wetting agent, 11.5 g of butylbenzene latex (solid content: 30%), 5.5 g of dimethyl sulfoxide, 0.2 g of Dow Corning DC-51 slipping agent and 61.5 g of water.
And adding PEDOT/PSS into water, fully stirring for 10 minutes, adding a Dynol 604 wetting agent and styrene-butadiene latex into the solution, fully stirring for 15 minutes, adding dimethyl sulfoxide and Dow Corning DC-51 slipping agent into the mixed solution, and fully stirring uniformly for 2 hours to obtain the special antistatic coating for the cover tape. Coating the mixture on the surface of the cover tape with a No. 5 wire bar, drying at 110 ℃, and measuring the antistatic property and the influence on the hot pressing property.
The antistatic performance of the formula is 106Omega/□, and the tensile force influence test after hot pressing at 180 ℃ for 0.05 second shows that the cover tape is free of vibration during stripping, and can keep the stripping smoothness of the carrier tape.
The applicant states that the present invention is illustrated in detail by the above examples, but the present invention is not limited to the above detailed methods, i.e. it is not meant that the present invention must rely on the above detailed methods for its implementation. It should be understood by those skilled in the art that any modification of the present invention, effective substitution of raw materials and addition of auxiliary components to the product of the present invention, selection of specific modes, etc., are within the scope and disclosure of the present invention.

Claims (5)

1. The special antistatic coating for the cover tape is characterized in that: the material is prepared from the following raw materials in percentage by mass: 10-50% of Poly (3,4-ethylenedioxythiophene) -polystyrene sulfonic acid (Poly (3,4-ethylenedioxythiophene)/Poly (PEDOT/PSS)), 0.05-1.5% of wetting agent, 2-15% of water-based resin, 1-15% of active plasticizer, 0.05-3% of slipping agent and 50-70% of water, wherein the total content of the components is 100%.
2. The antistatic coating special for the cover tape according to claim 1, wherein the antistatic coating comprises: the water-based resin is one of styrene-butadiene latex or butyronitrile latex.
3. The antistatic coating special for the cover tape according to claim 1, wherein the antistatic coating comprises: the wetting agent is one of thioether nonionic super wetting agents and acetylene glycol ethoxy compound nonionic super wetting agents.
4. The antistatic coating special for the cover tape according to claim 1, wherein the antistatic coating comprises: the active synergist is one of dimethyl sulfoxide, N-methyl pyrrolidone, sorbitol and glycerol.
5. The antistatic coating special for the cover tape according to claim 1, wherein the antistatic coating comprises: the slipping agent is a polydimethylsiloxane dispersion with a super molecular weight, and preferably Dow Corning DC-51.
CN201810869563.2A 2018-08-02 2018-08-02 Special antistatic coating for cover tape Pending CN110791179A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201810869563.2A CN110791179A (en) 2018-08-02 2018-08-02 Special antistatic coating for cover tape

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201810869563.2A CN110791179A (en) 2018-08-02 2018-08-02 Special antistatic coating for cover tape

Publications (1)

Publication Number Publication Date
CN110791179A true CN110791179A (en) 2020-02-14

Family

ID=69425181

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201810869563.2A Pending CN110791179A (en) 2018-08-02 2018-08-02 Special antistatic coating for cover tape

Country Status (1)

Country Link
CN (1) CN110791179A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN114133709A (en) * 2021-11-30 2022-03-04 浙江洁美电子科技股份有限公司 Conductive sheet and carrier tape for micro package

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1409666A (en) * 1999-12-16 2003-04-09 咨询卡有限公司 Printed substrate made by transfer of ink jet printed image from printable transfer film
JP2004058648A (en) * 2001-12-06 2004-02-26 Toray Ind Inc Laminated film and manufacturing process thereof
JP2010196022A (en) * 2009-02-27 2010-09-09 Nagase Chemtex Corp Electroconductive coating composition
CN104960292A (en) * 2015-06-17 2015-10-07 浙江洁美电子科技股份有限公司 Packaging tape for carrier belt for electronic components and production method of packaging tape

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1409666A (en) * 1999-12-16 2003-04-09 咨询卡有限公司 Printed substrate made by transfer of ink jet printed image from printable transfer film
JP2004058648A (en) * 2001-12-06 2004-02-26 Toray Ind Inc Laminated film and manufacturing process thereof
JP2010196022A (en) * 2009-02-27 2010-09-09 Nagase Chemtex Corp Electroconductive coating composition
CN104960292A (en) * 2015-06-17 2015-10-07 浙江洁美电子科技股份有限公司 Packaging tape for carrier belt for electronic components and production method of packaging tape

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN114133709A (en) * 2021-11-30 2022-03-04 浙江洁美电子科技股份有限公司 Conductive sheet and carrier tape for micro package

Similar Documents

Publication Publication Date Title
JP4004214B2 (en) Antistatic coating composition
CN1931926B (en) Silicone release compositions and silicone release plastic films coated therewith
CN103289629B (en) Thermosetting adhesive composition, and heat resistant adhesive film and wiring film using the same
JP2012140008A (en) Release film having excellent static electricity proofness, and method of manufacturing same
JP6071688B2 (en) Antistatic release agent composition and antistatic release film
KR20130126498A (en) Removable, water-dispersible acrylic adhesive composition, and adhesive sheet
KR20170096881A (en) Anti-static silicone tight-release coating film
CN109913142A (en) A kind of antistatic property organic pressure-sensitive gel product
CN105637037B (en) Conductive composition, conductor, method for forming conductor, and method for producing polymer
JP7045210B2 (en) Curable composition and antistatic silicone film
CN110791179A (en) Special antistatic coating for cover tape
CN106189904A (en) Anti-acid acrylate pressure-sensitive adhesive protecting film
JP2010265388A (en) Antistatic adhesive and adhesive sheet
JP2010209190A (en) Pressure sensitive adhesive sheet
CN106519876A (en) Hyperbranched polymer modified silicone acrylate containing antiadhesion agent and preparation method thereof
JP2010209189A (en) Pressure sensitive adhesive sheet
JP2011195765A (en) Electroconductive coating material and method for producing electroconductive molding
JP4592334B2 (en) Conductivity imparting agent and conductive resin composition
JP2022529574A (en) Antistatic silicone release film
JP4621950B2 (en) Antistatic coating composition
CN115103888B (en) Silicone composition for producing release paper or release film, and release paper or release film
US20140171569A1 (en) Peelable protective film and composition thereof
JP7269816B2 (en) Conductive release film and manufacturing method thereof
KR101987760B1 (en) Adhesive tape having antistatic function
JP2006193704A (en) Antistatic agent for resin composition

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
WD01 Invention patent application deemed withdrawn after publication

Application publication date: 20200214

WD01 Invention patent application deemed withdrawn after publication