CN109715131A - 低粘度毛发护理组合物 - Google Patents
低粘度毛发护理组合物 Download PDFInfo
- Publication number
- CN109715131A CN109715131A CN201780058070.4A CN201780058070A CN109715131A CN 109715131 A CN109715131 A CN 109715131A CN 201780058070 A CN201780058070 A CN 201780058070A CN 109715131 A CN109715131 A CN 109715131A
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- CN
- China
- Prior art keywords
- weight
- sodium
- hair care
- care composition
- sulfate
- Prior art date
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- 239000000203 mixture Substances 0.000 title claims abstract description 209
- 125000000217 alkyl group Chemical group 0.000 claims abstract description 53
- 239000004094 surface-active agent Substances 0.000 claims abstract description 48
- 239000003945 anionic surfactant Substances 0.000 claims abstract description 39
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 37
- 239000002904 solvent Substances 0.000 claims abstract description 32
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 claims abstract description 18
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims abstract description 16
- -1 Methylsiloxane Chemical class 0.000 claims description 208
- 239000011734 sodium Substances 0.000 claims description 43
- 229910052708 sodium Inorganic materials 0.000 claims description 42
- 229920001296 polysiloxane Polymers 0.000 claims description 35
- PMZURENOXWZQFD-UHFFFAOYSA-L sodium sulphate Substances [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 claims description 34
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 33
- 125000004432 carbon atom Chemical group C* 0.000 claims description 30
- 239000002253 acid Substances 0.000 claims description 29
- 244000303965 Cyamopsis psoralioides Species 0.000 claims description 28
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 21
- 229910052938 sodium sulfate Inorganic materials 0.000 claims description 17
- 235000011152 sodium sulphate Nutrition 0.000 claims description 17
- 125000002252 acyl group Chemical group 0.000 claims description 16
- 150000003839 salts Chemical class 0.000 claims description 16
- 229920006317 cationic polymer Polymers 0.000 claims description 15
- 230000003750 conditioning effect Effects 0.000 claims description 15
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 14
- 229920003171 Poly (ethylene oxide) Polymers 0.000 claims description 14
- 125000000129 anionic group Chemical group 0.000 claims description 13
- 125000000400 lauroyl group Chemical group O=C([*])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 claims description 13
- QXNVGIXVLWOKEQ-UHFFFAOYSA-N Disodium Chemical compound [Na][Na] QXNVGIXVLWOKEQ-UHFFFAOYSA-N 0.000 claims description 12
- 150000001450 anions Chemical class 0.000 claims description 12
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 claims description 11
- 150000003242 quaternary ammonium salts Chemical class 0.000 claims description 11
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 10
- 230000008859 change Effects 0.000 claims description 9
- 125000003438 dodecyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 claims description 9
- 244000147568 Laurus nobilis Species 0.000 claims description 8
- 235000017858 Laurus nobilis Nutrition 0.000 claims description 8
- 229920000289 Polyquaternium Polymers 0.000 claims description 8
- 235000005212 Terminalia tomentosa Nutrition 0.000 claims description 8
- 239000003205 fragrance Substances 0.000 claims description 8
- OYINQIKIQCNQOX-UHFFFAOYSA-M 2-hydroxybutyl(trimethyl)azanium;chloride Chemical compound [Cl-].CCC(O)C[N+](C)(C)C OYINQIKIQCNQOX-UHFFFAOYSA-M 0.000 claims description 7
- 150000001335 aliphatic alkanes Chemical class 0.000 claims description 7
- 229940045998 sodium isethionate Drugs 0.000 claims description 7
- FXALIOUHXMVTMJ-UHFFFAOYSA-N CCCCCCCCCCCC([Na])=O Chemical compound CCCCCCCCCCCC([Na])=O FXALIOUHXMVTMJ-UHFFFAOYSA-N 0.000 claims description 6
- 150000001336 alkenes Chemical class 0.000 claims description 6
- 239000004530 micro-emulsion Substances 0.000 claims description 6
- FSYKKLYZXJSNPZ-UHFFFAOYSA-N sarcosine Chemical compound C[NH2+]CC([O-])=O FSYKKLYZXJSNPZ-UHFFFAOYSA-N 0.000 claims description 6
- WQZGKKKJIJFFOK-GASJEMHNSA-N Glucose Natural products OC[C@H]1OC(O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-GASJEMHNSA-N 0.000 claims description 5
- 235000019082 Osmanthus Nutrition 0.000 claims description 5
- 241000333181 Osmanthus Species 0.000 claims description 5
- 230000003213 activating effect Effects 0.000 claims description 5
- BFNBIHQBYMNNAN-UHFFFAOYSA-N ammonium sulfate Chemical compound N.N.OS(O)(=O)=O BFNBIHQBYMNNAN-UHFFFAOYSA-N 0.000 claims description 5
- 150000001732 carboxylic acid derivatives Chemical class 0.000 claims description 5
- 239000008103 glucose Substances 0.000 claims description 5
- 229950001046 piroctone Drugs 0.000 claims description 5
- OTYBMLCTZGSZBG-UHFFFAOYSA-L potassium sulfate Chemical compound [K+].[K+].[O-]S([O-])(=O)=O OTYBMLCTZGSZBG-UHFFFAOYSA-L 0.000 claims description 5
- 229910052939 potassium sulfate Inorganic materials 0.000 claims description 5
- 235000011151 potassium sulphates Nutrition 0.000 claims description 5
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 claims description 5
- QTUIJRIDZOSXHJ-UHFFFAOYSA-M tridecyl sulfate Chemical compound CCCCCCCCCCCCCOS([O-])(=O)=O QTUIJRIDZOSXHJ-UHFFFAOYSA-M 0.000 claims description 5
- 208000001840 Dandruff Diseases 0.000 claims description 4
- 150000001412 amines Chemical class 0.000 claims description 4
- 229910052921 ammonium sulfate Inorganic materials 0.000 claims description 4
- 235000011130 ammonium sulphate Nutrition 0.000 claims description 4
- 239000002280 amphoteric surfactant Substances 0.000 claims description 4
- 229940079840 cocoyl isethionate Drugs 0.000 claims description 4
- 235000013905 glycine and its sodium salt Nutrition 0.000 claims description 4
- 239000004247 glycine and its sodium salt Substances 0.000 claims description 4
- YGSDEFSMJLZEOE-UHFFFAOYSA-N salicylic acid Chemical compound OC(=O)C1=CC=CC=C1O YGSDEFSMJLZEOE-UHFFFAOYSA-N 0.000 claims description 4
- 229940029258 sodium glycinate Drugs 0.000 claims description 4
- 229940048109 sodium methyl cocoyl taurate Drugs 0.000 claims description 4
- SLBXZQMMERXQAL-UHFFFAOYSA-M sodium;1-dodecoxy-4-hydroxy-1,4-dioxobutane-2-sulfonate Chemical compound [Na+].CCCCCCCCCCCCOC(=O)C(S(O)(=O)=O)CC([O-])=O SLBXZQMMERXQAL-UHFFFAOYSA-M 0.000 claims description 4
- OWEGWHBOCFMBLP-UHFFFAOYSA-N 1-(4-chlorophenoxy)-1-(1H-imidazol-1-yl)-3,3-dimethylbutan-2-one Chemical compound C1=CN=CN1C(C(=O)C(C)(C)C)OC1=CC=C(Cl)C=C1 OWEGWHBOCFMBLP-UHFFFAOYSA-N 0.000 claims description 3
- LKVZSCFGTYHYBT-UHFFFAOYSA-N S(=O)(=O)(O)O.C(CCCCCCCCCCC)(=O)[Na] Chemical compound S(=O)(=O)(O)O.C(CCCCCCCCCCC)(=O)[Na] LKVZSCFGTYHYBT-UHFFFAOYSA-N 0.000 claims description 3
- HREUQCWXLFXWGA-UHFFFAOYSA-N S(=O)(=O)([O-])[O-].C(CCCCCCCCCCC)(=O)[NH3+].C(CCCCCCCCCCC)(=O)[NH3+] Chemical compound S(=O)(=O)([O-])[O-].C(CCCCCCCCCCC)(=O)[NH3+].C(CCCCCCCCCCC)(=O)[NH3+] HREUQCWXLFXWGA-UHFFFAOYSA-N 0.000 claims description 3
- VMHLLURERBWHNL-UHFFFAOYSA-M Sodium acetate Chemical compound [Na+].CC([O-])=O VMHLLURERBWHNL-UHFFFAOYSA-M 0.000 claims description 3
- YGUMNXUBAJCWHV-UHFFFAOYSA-L [Na+].[Na+].[O-]S([O-])(=O)=O.CCCCCCCCCCCC(=O)OCC(O)CO Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O.CCCCCCCCCCCC(=O)OCC(O)CO YGUMNXUBAJCWHV-UHFFFAOYSA-L 0.000 claims description 3
- BTBJBAZGXNKLQC-UHFFFAOYSA-N ammonium lauryl sulfate Chemical compound [NH4+].CCCCCCCCCCCCOS([O-])(=O)=O BTBJBAZGXNKLQC-UHFFFAOYSA-N 0.000 claims description 3
- MKHVZQXYWACUQC-UHFFFAOYSA-N bis(2-hydroxyethyl)azanium;dodecyl sulfate Chemical compound OCCNCCO.CCCCCCCCCCCCOS(O)(=O)=O MKHVZQXYWACUQC-UHFFFAOYSA-N 0.000 claims description 3
- 229960003344 climbazole Drugs 0.000 claims description 3
- 239000001632 sodium acetate Substances 0.000 claims description 3
- 235000017281 sodium acetate Nutrition 0.000 claims description 3
- 229940079862 sodium lauryl sarcosinate Drugs 0.000 claims description 3
- LIFHMKCDDVTICL-UHFFFAOYSA-N 6-(chloromethyl)phenanthridine Chemical compound C1=CC=C2C(CCl)=NC3=CC=CC=C3C2=C1 LIFHMKCDDVTICL-UHFFFAOYSA-N 0.000 claims description 2
- YBESMQHGHZRDRO-TYOUJGAFSA-N N[C@@H](C)C(=O)O.C(CCCCCCCCCCC)(=O)[Na] Chemical compound N[C@@H](C)C(=O)O.C(CCCCCCCCCCC)(=O)[Na] YBESMQHGHZRDRO-TYOUJGAFSA-N 0.000 claims description 2
- 108010077895 Sarcosine Proteins 0.000 claims description 2
- ULUAUXLGCMPNKK-UHFFFAOYSA-N Sulfobutanedioic acid Chemical compound OC(=O)CC(C(O)=O)S(O)(=O)=O ULUAUXLGCMPNKK-UHFFFAOYSA-N 0.000 claims description 2
- 229940071124 cocoyl glutamate Drugs 0.000 claims description 2
- KMSXHXLZXWCJIO-DTUYJQALSA-L disodium (4S)-4-amino-5-dodecanoyloxy-5-oxopentanoate Chemical compound N[C@@H](CCC(=O)[O-])C(=O)OC(CCCCCCCCCCC)=O.[Na+].[Na+].C(CCCCCCCCCCC)(=O)OC([C@@H](N)CCC(=O)[O-])=O KMSXHXLZXWCJIO-DTUYJQALSA-L 0.000 claims description 2
- MOTZDAYCYVMXPC-UHFFFAOYSA-N dodecyl hydrogen sulfate Chemical compound CCCCCCCCCCCCOS(O)(=O)=O MOTZDAYCYVMXPC-UHFFFAOYSA-N 0.000 claims description 2
- 229940043264 dodecyl sulfate Drugs 0.000 claims description 2
- QVBODZPPYSSMEL-UHFFFAOYSA-N dodecyl sulfate;2-hydroxyethylazanium Chemical compound NCCO.CCCCCCCCCCCCOS(O)(=O)=O QVBODZPPYSSMEL-UHFFFAOYSA-N 0.000 claims description 2
- SFNALCNOMXIBKG-UHFFFAOYSA-N ethylene glycol monododecyl ether Chemical compound CCCCCCCCCCCCOCCO SFNALCNOMXIBKG-UHFFFAOYSA-N 0.000 claims description 2
- LPUQAYUQRXPFSQ-DFWYDOINSA-M monosodium L-glutamate Chemical compound [Na+].[O-]C(=O)[C@@H](N)CCC(O)=O LPUQAYUQRXPFSQ-DFWYDOINSA-M 0.000 claims description 2
- FJKROLUGYXJWQN-UHFFFAOYSA-N papa-hydroxy-benzoic acid Natural products OC(=O)C1=CC=C(O)C=C1 FJKROLUGYXJWQN-UHFFFAOYSA-N 0.000 claims description 2
- 229960004889 salicylic acid Drugs 0.000 claims description 2
- 229940080272 sodium coco-sulfate Drugs 0.000 claims description 2
- 229940079781 sodium cocoyl glutamate Drugs 0.000 claims description 2
- 235000019333 sodium laurylsulphate Nutrition 0.000 claims description 2
- ZEZSZCSSTDPVDM-DKWTVANSSA-M sodium;(2s)-2-aminopropanoate Chemical compound [Na+].C[C@H](N)C([O-])=O ZEZSZCSSTDPVDM-DKWTVANSSA-M 0.000 claims description 2
- WUWHFEHKUQVYLF-UHFFFAOYSA-M sodium;2-aminoacetate Chemical compound [Na+].NCC([O-])=O WUWHFEHKUQVYLF-UHFFFAOYSA-M 0.000 claims description 2
- KRTNITDCKAVIFI-UHFFFAOYSA-N tridecyl benzenesulfonate Chemical compound CCCCCCCCCCCCCOS(=O)(=O)C1=CC=CC=C1 KRTNITDCKAVIFI-UHFFFAOYSA-N 0.000 claims description 2
- FZGRPBJBMUNMQH-UHFFFAOYSA-N trimethyl-$l^{3}-chlorane Chemical compound CCl(C)C FZGRPBJBMUNMQH-UHFFFAOYSA-N 0.000 claims description 2
- RTVVXRKGQRRXFJ-UHFFFAOYSA-N sodium;2-sulfobutanedioic acid Chemical compound [Na].OC(=O)CC(C(O)=O)S(O)(=O)=O RTVVXRKGQRRXFJ-UHFFFAOYSA-N 0.000 claims 2
- KHBQMWCZKVMBLN-UHFFFAOYSA-N Benzenesulfonamide Chemical compound NS(=O)(=O)C1=CC=CC=C1 KHBQMWCZKVMBLN-UHFFFAOYSA-N 0.000 claims 1
- 240000002853 Nelumbo nucifera Species 0.000 claims 1
- 235000006508 Nelumbo nucifera Nutrition 0.000 claims 1
- 235000006510 Nelumbo pentapetala Nutrition 0.000 claims 1
- QYKIQEUNHZKYBP-UHFFFAOYSA-N Vinyl ether Chemical compound C=COC=C QYKIQEUNHZKYBP-UHFFFAOYSA-N 0.000 claims 1
- PCHPORCSPXIHLZ-UHFFFAOYSA-N diphenhydramine hydrochloride Chemical compound [Cl-].C=1C=CC=CC=1C(OCC[NH+](C)C)C1=CC=CC=C1 PCHPORCSPXIHLZ-UHFFFAOYSA-N 0.000 claims 1
- 230000005611 electricity Effects 0.000 claims 1
- 229940045944 sodium lauroyl glutamate Drugs 0.000 claims 1
- KSAVQLQVUXSOCR-UHFFFAOYSA-M sodium lauroyl sarcosinate Chemical compound [Na+].CCCCCCCCCCCC(=O)N(C)CC([O-])=O KSAVQLQVUXSOCR-UHFFFAOYSA-M 0.000 claims 1
- ZDQYSKICYIVCPN-UHFFFAOYSA-L sodium succinate (anhydrous) Chemical compound [Na+].[Na+].[O-]C(=O)CCC([O-])=O ZDQYSKICYIVCPN-UHFFFAOYSA-L 0.000 claims 1
- IWIUXJGIDSGWDN-UQKRIMTDSA-M sodium;(2s)-2-(dodecanoylamino)pentanedioate;hydron Chemical compound [Na+].CCCCCCCCCCCC(=O)N[C@H](C([O-])=O)CCC(O)=O IWIUXJGIDSGWDN-UQKRIMTDSA-M 0.000 claims 1
- 125000002889 tridecyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 claims 1
- SZXQTJUDPRGNJN-UHFFFAOYSA-N dipropylene glycol Chemical compound OCCCOCCCO SZXQTJUDPRGNJN-UHFFFAOYSA-N 0.000 abstract description 5
- 125000002091 cationic group Chemical group 0.000 description 78
- 229920000642 polymer Polymers 0.000 description 71
- 239000002585 base Substances 0.000 description 63
- 239000000178 monomer Substances 0.000 description 53
- 239000006260 foam Substances 0.000 description 43
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 40
- 229920000926 Galactomannan Polymers 0.000 description 31
- 229920002472 Starch Polymers 0.000 description 29
- 235000019698 starch Nutrition 0.000 description 29
- OMDQUFIYNPYJFM-XKDAHURESA-N (2r,3r,4s,5r,6s)-2-(hydroxymethyl)-6-[[(2r,3s,4r,5s,6r)-4,5,6-trihydroxy-3-[(2s,3s,4s,5s,6r)-3,4,5-trihydroxy-6-(hydroxymethyl)oxan-2-yl]oxyoxan-2-yl]methoxy]oxane-3,4,5-triol Chemical compound O[C@@H]1[C@@H](O)[C@@H](O)[C@@H](CO)O[C@@H]1OC[C@@H]1[C@@H](O[C@H]2[C@H]([C@@H](O)[C@H](O)[C@@H](CO)O2)O)[C@H](O)[C@H](O)[C@H](O)O1 OMDQUFIYNPYJFM-XKDAHURESA-N 0.000 description 27
- 239000008107 starch Substances 0.000 description 27
- 150000001768 cations Chemical class 0.000 description 26
- 239000000463 material Substances 0.000 description 23
- 125000001453 quaternary ammonium group Chemical group 0.000 description 20
- 229920002907 Guar gum Polymers 0.000 description 18
- 229920000881 Modified starch Polymers 0.000 description 18
- 235000019426 modified starch Nutrition 0.000 description 18
- 239000003921 oil Substances 0.000 description 18
- 235000019198 oils Nutrition 0.000 description 18
- 239000004368 Modified starch Substances 0.000 description 17
- 235000019441 ethanol Nutrition 0.000 description 17
- 239000000665 guar gum Substances 0.000 description 17
- 235000010417 guar gum Nutrition 0.000 description 17
- 229960002154 guar gum Drugs 0.000 description 17
- 244000060011 Cocos nucifera Species 0.000 description 16
- 235000013162 Cocos nucifera Nutrition 0.000 description 16
- 229930195733 hydrocarbon Natural products 0.000 description 16
- 150000002430 hydrocarbons Chemical class 0.000 description 16
- 239000004215 Carbon black (E152) Substances 0.000 description 14
- 241001597008 Nomeidae Species 0.000 description 14
- 239000007788 liquid Substances 0.000 description 14
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 14
- CERQOIWHTDAKMF-UHFFFAOYSA-N alpha-methacrylic acid Natural products CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 13
- 229920003118 cationic copolymer Polymers 0.000 description 13
- 150000002148 esters Chemical class 0.000 description 13
- 239000006210 lotion Substances 0.000 description 13
- 238000000034 method Methods 0.000 description 12
- 239000000443 aerosol Substances 0.000 description 11
- 125000000118 dimethyl group Chemical group [H]C([H])([H])* 0.000 description 11
- HRPVXLWXLXDGHG-UHFFFAOYSA-N Acrylamide Chemical group NC(=O)C=C HRPVXLWXLXDGHG-UHFFFAOYSA-N 0.000 description 10
- WQZGKKKJIJFFOK-QTVWNMPRSA-N D-mannopyranose Chemical compound OC[C@H]1OC(O)[C@@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-QTVWNMPRSA-N 0.000 description 10
- BAPJBEWLBFYGME-UHFFFAOYSA-N Methyl acrylate Chemical compound COC(=O)C=C BAPJBEWLBFYGME-UHFFFAOYSA-N 0.000 description 10
- 229910052799 carbon Inorganic materials 0.000 description 10
- 239000000047 product Substances 0.000 description 10
- 150000001875 compounds Chemical class 0.000 description 9
- 239000000126 substance Substances 0.000 description 9
- KAESVJOAVNADME-UHFFFAOYSA-N Pyrrole Chemical compound C=1C=CNC=1 KAESVJOAVNADME-UHFFFAOYSA-N 0.000 description 8
- 229920013822 aminosilicone Polymers 0.000 description 8
- 150000001721 carbon Chemical group 0.000 description 8
- 150000002500 ions Chemical class 0.000 description 8
- 238000005259 measurement Methods 0.000 description 8
- YPHQUSNPXDGUHL-UHFFFAOYSA-N n-methylprop-2-enamide Chemical compound CNC(=O)C=C YPHQUSNPXDGUHL-UHFFFAOYSA-N 0.000 description 8
- 125000002811 oleoyl group Chemical group O=C([*])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])/C([H])=C([H])\C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 8
- 239000002245 particle Substances 0.000 description 8
- 229920005573 silicon-containing polymer Polymers 0.000 description 8
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 7
- 150000003863 ammonium salts Chemical class 0.000 description 7
- 239000004088 foaming agent Substances 0.000 description 7
- 229910052736 halogen Inorganic materials 0.000 description 7
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 7
- 238000012986 modification Methods 0.000 description 7
- 230000004048 modification Effects 0.000 description 7
- 238000006467 substitution reaction Methods 0.000 description 7
- HIXDQWDOVZUNNA-UHFFFAOYSA-N 2-(3,4-dimethoxyphenyl)-5-hydroxy-7-methoxychromen-4-one Chemical compound C=1C(OC)=CC(O)=C(C(C=2)=O)C=1OC=2C1=CC=C(OC)C(OC)=C1 HIXDQWDOVZUNNA-UHFFFAOYSA-N 0.000 description 6
- HZAXFHJVJLSVMW-UHFFFAOYSA-N 2-Aminoethan-1-ol Chemical compound NCCO HZAXFHJVJLSVMW-UHFFFAOYSA-N 0.000 description 6
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 6
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- 239000002537 cosmetic Substances 0.000 description 6
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- 229930182478 glucoside Natural products 0.000 description 6
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 5
- PUAQLLVFLMYYJJ-UHFFFAOYSA-N 2-aminopropiophenone Chemical compound CC(N)C(=O)C1=CC=CC=C1 PUAQLLVFLMYYJJ-UHFFFAOYSA-N 0.000 description 5
- NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonia chloride Chemical compound [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 description 5
- 240000003183 Manihot esculenta Species 0.000 description 5
- 235000016735 Manihot esculenta subsp esculenta Nutrition 0.000 description 5
- 150000001298 alcohols Chemical class 0.000 description 5
- 125000003545 alkoxy group Chemical group 0.000 description 5
- 230000000845 anti-microbial effect Effects 0.000 description 5
- XJMWHXZUIGHOBA-UHFFFAOYSA-N azane;propanoic acid Chemical compound N.CCC(O)=O XJMWHXZUIGHOBA-UHFFFAOYSA-N 0.000 description 5
- NBMKJKDGKREAPL-DVTGEIKXSA-N beclomethasone Chemical compound C1CC2=CC(=O)C=C[C@]2(C)[C@]2(Cl)[C@@H]1[C@@H]1C[C@H](C)[C@@](C(=O)CO)(O)[C@@]1(C)C[C@@H]2O NBMKJKDGKREAPL-DVTGEIKXSA-N 0.000 description 5
- 229940092705 beclomethasone Drugs 0.000 description 5
- 230000015572 biosynthetic process Effects 0.000 description 5
- 230000015556 catabolic process Effects 0.000 description 5
- 238000006243 chemical reaction Methods 0.000 description 5
- NEHMKBQYUWJMIP-UHFFFAOYSA-N chloromethane Chemical class ClC NEHMKBQYUWJMIP-UHFFFAOYSA-N 0.000 description 5
- 239000003599 detergent Substances 0.000 description 5
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- SZYJELPVAFJOGJ-UHFFFAOYSA-N trimethylamine hydrochloride Chemical compound Cl.CN(C)C SZYJELPVAFJOGJ-UHFFFAOYSA-N 0.000 description 1
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- 150000003722 vitamin derivatives Chemical class 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- 239000002023 wood Substances 0.000 description 1
- 229920001285 xanthan gum Polymers 0.000 description 1
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Abstract
本发明涉及稳定的低粘度毛发护理组合物,所述毛发护理组合物具有高表面活性剂含量,所述表面活性剂包含直链硫酸盐(具有C12和以上的烷基尾部)和支链的硫酸盐(具有C12和以上的烷基尾部)、水混溶性溶剂,诸如双丙二醇或甘油。合适的组合物具有约0.2至约5的(直链的阴离子表面活性剂/支链的阴离子表面活性剂)/可混溶溶剂的比率和在26.5℃下小于约500cP的粘度。
Description
技术领域
本发明涉及浓缩的、低粘度毛发护理组合物,该组合物稳定并且还能够以包括泡沫形式在内的各种形式递送至毛发。
背景技术
本文所述的是浓缩的、低粘度毛发护理组合物,该组合物稳定并且还能够以包括泡沫形式在内的各种形式递送至毛发。消费者期望以泡沫形式递送清洁组合物。泡沫的低密度使高表面活性剂组合物成为必要,以便消费者在一个剂量的实际产品体积中获得适当水平的清洁。然而,通常高表面活性剂液体清洁组合物表现出高粘度,这使得难以通过泵式泡沫分配器、挤压泡沫分配器或气溶胶泡沫分配器递送。因此,通过包含高浓度清洁表面活性剂的低粘度组合物来促进作为泡沫的递送。
用于个人清洁范畴的机械或泵式泡沫代表对于消费者有吸引力的形式。通过泡沫递送的毛发护理产品易于铺展在毛发上并且能够使毛发清洁,而不在毛发上留下显著的残留物,因为泡沫的结构化效果能够使用不含聚合物或蜡质结构剂的组合物。由于泡沫的低密度,需要高浓度的表面活性剂以递送足够量的去污表面活性剂以供每次使用。然而,高表面活性剂液体清洁组合物通常表现出高粘度,这使其难以用典型的泵式泡沫分配器来递送。高表面活性剂液体清洁组合物可变得不稳定和相分离。基于前文所述,存在对于低粘度、稳定、浓缩的液体清洁组合物作为泡沫递送的需要。此外,澄清的产品在透明容器中的组合是视觉上吸引人的。因此,存在开发透明或半透明组合物的需要。高含量表面活性剂组合物可通过使用具有带短烷基链(10至11个碳原子)的尾部的表面活性剂来制备。该方法可导致较少的温和组合物。因此,存在制备具有低含量表面活性剂的温和表面活性剂组合物的需要,所述表面活性剂带有具有烷基链的尾部,所述烷基链具有10或11(或更低)个碳原子。
已令人惊讶地发现,具有高表面活性剂含量的澄清、稳定、低粘度组合物可通过使用直链硫酸盐(具有12个或超过12个碳原子的烷基尾部)和支链硫酸盐(具有12个或超过12个碳原子的烷基尾部)、水混溶性溶剂,诸如双丙二醇或甘油来制备。合适的组合物具有小于约0.2的(直链的阴离子表面活性剂/支链的阴离子表面活性剂)/可混溶溶剂的比率和小于约5的(支链的阴离子表面活性剂/可混溶溶剂)的比率。
发明内容
本发明涉及稳定的浓缩毛发护理组合物,该组合物包含约20重量%至约45重量%的总表面活性剂;约6重量%至约30重量%的带有具有烷基链的尾部的支链的阴离子表面活性剂,该烷基链具有12至18个碳原子;约0.1重量%至约20重量%的带有具有烷基链的尾部的直链的阴离子表面活性剂,该烷基链具有12至18个碳原子;约2重量%至约12重量%的水混溶性溶剂;和约35重量%至约78重量%的水;其中该浓缩的毛发护理具有小于约0.2的(直链的阴离子表面活性剂/支链的阴离子表面活性剂)/可混溶溶剂的比率;并且其中该支链的阴离子表面活性剂/可混溶溶剂的比率小于约5;并且其中该浓缩的毛发护理在26.5℃下具有小于500cP的粘度。
本发明还涉及稳定的浓缩毛发护理组合物,该组合物包含约20重量%至约45重量%的总表面活性剂;约6重量%至约30重量%的带有具有烷基链的尾部的支链的阴离子表面活性剂,该烷基链具有12至18个碳原子;约2重量%至约12重量%的水混溶性溶剂;和约35重量%至约78重量%的水;并且其中(直链的阴离子表面活性剂/支链的阴离子表面活性剂)/可混溶溶剂的比率小于约0.2;并且其中该支链的阴离子表面活性剂/可混溶溶剂的比率小于约5;并且其中该浓缩的毛发护理组合物在26.5℃下具有小于500cP的粘度;并且其中该组合物具有约0重量%的带有具有烷基链的尾部的直链的阴离子表面活性剂,该烷基链具有12至18个碳原子。
具体实施方式
如本文所用,当用于权利要求中时,包括“一个”和“一种”的冠词应被理解为是指一种或多种受权利要求书保护或所描述的物质。
如本文所用,“包括/包含”是指可加入不影响最终结果的其它步骤和其它成分。该术语涵盖术语“由……组成”和“基本上由……组成”。
如本文所用,“混合物”旨在包括物质的简单组合以及由它们的组合所可能产生的任何化合物。
如本文所用,除非另行指出,“分子量”或“M.Wt.”是指重均分子量。分子量使用工业标准方法、凝胶渗透色谱法(“GPC”)测量。
如本文所用,“个人护理组合物”包括诸如洗发剂、沐浴凝胶、液体手清洁剂、毛发着色剂、面部清洁剂、衣物洗涤剂、餐具洗涤剂和其它基于表面活性剂的液体组合物。
如本文所用,术语“包括”、“包含”和“含有”旨在是非限制性的,并且理解为分别是指“具有”、“具备”和“涵盖”。
除非另外说明,否则所有百分比、份数和比率均基于本发明组合物的总重量。所有涉及所列成分的这些重量均基于活性物质的含量,因此不包括可能被包含在可商购获得的物质中的载体或副产物。
除非另外指明,否则所有组分或组合物水平均是就该组分或组合物的活性部分而言,且不包括可能存在于此类组分或组合物的可商购获得的来源中的杂质,例如残余溶剂或副产物。
应当理解,贯穿本说明书给出的每一最大数值限度包括每一较低数值限度,如同该较低数值限度在本文中明确写出。贯穿本说明书给出的每一最小数值限度将包括每一较高数值限度,如同该较高数值限度在本文中明确写出。贯穿本说明书给出的每一数值范围将包括落在该较大数值范围内的每一更窄的数值范围,如同该更窄的数值范围全部在本文中明确写出。
本文所述的毛发护理组合物是稳定的,并且具有低粘度的同时,还具有高表面活性剂含量。该表面活性剂体系包含直链的硫酸盐(具有12个或超过12个碳原子的烷基尾部)和支链的硫酸盐(具有12个或超过12个碳原子的烷基尾部)、水混溶性溶剂,包括但不限于双丙二醇和/或甘油。合适的组合物具有小于约0.2的(直链的阴离子表面活性剂/支链的阴离子表面活性剂)/可混溶溶剂的比率和小于约5的(支链的阴离子表面活性剂/可混溶溶剂)的比率。该毛发护理组合物可为洗发剂。毛发护理组合物可为澄清的,并且它们可为浓缩和/或致密制剂。
A.表面活性剂
该毛发护理组合物可包含按重量计约20%至约45%,按重量计约25%至约45%,按重量计约25%至约40%,按重量计约30%至约40%,按重量计约30%至约35%的总表面活性剂含量。总表面活性剂可包括但不限于两性、支链的阴离子表面活性剂、直链的阴离子表面活性剂以及它们的组合。
1.支链的阴离子表面活性剂
该毛发护理组合物可包含按重量计约6%至约30%,按重量计约6%至约28%,按重量计约6%至约24%,以及按重量计约8%至约24%的支链的阴离子表面活性剂,其带有具有烷基链的尾部,该烷基链具有12个碳原子或更高、或者约12至约18个碳原子。
带有具有烷基链的尾部(烷基链具有12个碳原子或更高)的合适的支链的阴离子表面活性剂,包括但不限于下列表面活性剂:十三烷基聚氧乙烯醚硫酸钠、十三烷基硫酸钠、C12-13烷基硫酸钠、C12-15烷基硫酸钠、C12-18烷基硫酸钠、C12-13烷基聚氧乙烯醚硫酸钠、C12-13烷基聚氧乙烯醚-n硫酸钠、C12-14烷基聚氧乙烯醚-n硫酸钠以及它们的组合。所有上述表面活性剂的其他盐均是可用的,诸如TEA盐、DEA盐、氨盐、钾盐。可用的烷氧基化物包括环氧乙烷、环氧丙烷和EO/PO混合的烷氧基化物。由支链醇制得的磷酸盐、羧酸盐和磺酸盐也是可用的阴离子支链的表面活性剂。支链的表面活性剂可衍生自诸如得自由费舍尔-托普希(Fischer-Tropsch)压缩合成气产生的液态烃的伯醇的合成醇类,例如购自德克萨斯州休斯顿市的萨索尔北美公司(Sasol North America,Houston,Tex)的SafolTM 23醇;可衍生自诸如购自美国壳牌化学(Shell Chemicals,USA)的NeodolTM 23 Alcohol的合成醇类;可衍生自合成制备的醇类,诸如2002年1月1日授予Coffindaffer等人的美国专利6,335,312中所述的那些。醇类的合适示例为SafolTM 23和NeodolTM 23。烷氧基化的醇类的合适的示例为SafolTM 23-3和NeodolTM 23-3。另一个合适的示例为Exaal-13,得自埃克森美孚北美公司(ExxonMobil North America)。硫酸盐可由硫基SO3气流工艺、氯磺酸工艺、硫酸工艺或发烟硫酸工艺通过常规方法制备成高纯度。在降膜反应器中经由气流制备是优选的硫酸盐化方法。该阴离子表面活性剂还可为STnS,其中n可定义为乙氧基化的平均摩尔数。n可在约0至约3.5、约0.5至约3.5、约1.1至约2.5、约1.8至约2.2的范围内、或n可为约2。
2.直链的阴离子表面活性剂
该毛发护理组合物可包含按重量计约0%至约20%、按重量计约1%至约20%、按重量计约2%至约20%、按重量计约3%至约20%和按重量计约4%至约15%的直链的阴离子表面活性剂,其带有具有烷基链的尾部,该烷基链具有12个碳原子或更高、或者约12至约18个碳原子。
用于在本文组合物中使用的合适阴离子去污表面活性剂组分包括已知用于毛发护理或其它个人护理洗发剂组合物中的那些。阴离子去污表面活性剂可为月桂基硫酸钠和月桂基聚氧乙烯醚n-硫酸钠的组合。另选地,阴离子去污表面活性剂可以是具有平均1摩尔乙氧基化物的月桂基聚氧乙烯醚硫酸钠。阴离子表面活性剂组分在组合物中的浓度应足以提供期望的清洁和起泡性能。
适用于本文的阴离子表面活性剂包括具有式ROSO3M和RO(C2H4O)xSO3M的烷基硫酸盐和烷基醚硫酸盐,其中R为具有约8至约18个碳原子的烷基或烯基,x为1至10,并且M为水溶性阳离子如铵、钠、钾和三乙醇胺阳离子,或具有两个阴离子表面活性剂阴离子的二价镁离子的盐。烷基醚硫酸盐可作为环氧乙烷和具有约8至约24个碳原子的一元醇的缩合产物制备。醇可衍生自脂肪,诸如椰子油、棕榈油、棕榈仁油或牛脂,或可为合成的。
表1:典型的烷基硫酸盐和烷基醚硫酸盐的示例
直链的表面活性剂的一些非限制性示例为:
烷基硫酸盐
其中R为C12-C18烷基(直链的、饱和或不饱和的)或它们的混合物,并且M+是一价阳离子。示例包括月桂基硫酸钠(其中R是C12烷基,并且M+是Na+)、月桂基硫酸铵(其中R是C12烷基,并且M+是NH3 +)、以及椰油硫酸钠(其中R是椰油烷基,并且M+是Na+);
烷基醚硫酸盐
其中R为C12-C18烷基(直链的、饱和或不饱和的)或它们的混合物,n=1-12,并且M+是一价阳离子。示例包括月桂基聚氧乙烯醚硫酸钠(其中R为C12烷基且M+为Na+,n=1-3)、月桂基聚氧乙烯醚硫酸铵(其中R为C12烷基,M+为NH3 +,n=1-3)、以及十三烷基聚氧乙烯醚硫酸钠(其中R是C13烷基,M+为Na+,并且n=1-4)。
磺酸盐表面活性剂的一些非限制性示例为:
烷基甘油醚磺酸盐:
其中R=C12-C18烷基(直链的、饱和或不饱和的)或它们的混合物,并且M+=一价阳离子,诸如椰油甘油醚磺酸钠
(R=椰油烷基,M+=Na+);
通过磺化长链α-烯烃制备的α-烯烃磺酸盐。由烯烃磺酸盐的混合物组成的α-烯烃磺酸盐,
其中R=C8-C18烷基或它们的混合物,并且M+=一价阳离子;
羟烷基磺酸盐,
其中R=C8-C18烷基或它们的混合物,并且M+=一价阳离子。示例包括C12-14烯烃磺酸钠(R=C8-C10烷基,M+=Na+)和C 14-16烯烃磺酸钠(R=C10-C12烷基,M+=Na+)。
适用于本文的附加阴离子表面活性剂的示例包括但不限于月桂基硫酸铵、月桂基聚氧乙烯醚硫酸铵、月桂基硫酸三乙基胺、月桂基聚氧乙烯醚硫酸三乙基胺、月桂基硫酸三乙醇胺、月桂基聚氧乙烯醚硫酸三乙醇胺、月桂基硫酸单乙醇胺、月桂基聚氧乙烯醚硫酸单乙醇胺、月桂基硫酸二乙醇胺、月桂基聚氧乙烯醚硫酸二乙醇胺、月桂酸甘油单酯硫酸钠、月桂基硫酸钠、月桂基聚氧乙烯醚硫酸钠、月桂基聚氧乙烯醚硫酸钾、月桂基肌氨酸钠、月桂酰肌氨酸钠、月桂基肌氨酸、椰油基肌氨酸、椰油基硫酸铵、月桂酰基硫酸铵、椰油基硫酸钠、月桂酰硫酸钠、椰油基硫酸钾、月桂基硫酸钾、椰油酰硫酸单乙醇胺、十三烷基聚氧乙烯醚-1硫酸钠,硫酸盐、十三烷基聚氧乙烯醚-2硫酸钠,硫酸盐、十三烷基聚氧乙烯醚-3硫酸钠、十三烷基硫酸钠、甲基月桂酰牛磺酸钠、甲基椰油基牛磺酸钠、月桂酰羟乙基磺酸钠、椰油基羟乙基磺酸钠、月桂基聚氧乙烯醚磺基琥珀酸钠、月桂基磺基琥珀酸钠、十三烷基苯磺酸钠、十二烷基苯磺酸钠、以及它们的混合物。
适用于本文的另外的阴离子表面活性剂包括但不限于酰基羟乙基磺酸盐、酰基甲基羟乙基磺酸盐、酰基谷氨酸盐、酰基甘氨酸盐、酰基肌氨酸盐、酰基丙氨酸盐、酰基牛磺酸盐、磺基琥珀酸盐、烷基苯磺酸盐、烷基醚羧酸盐、烷基两性基乙酸盐、α-烯烃磺酸盐以及它们的混合物。此类合适的阴离子表面活性剂的示例包括但不限于椰油基羟乙基磺酸钠、月桂酰羟乙基磺酸钠、月桂酰甲基羟乙基磺酸钠、椰油基谷氨酸钠、椰油基谷氨酸二钠、月桂酰谷氨酸钠、月桂酰谷氨酸二钠、椰油基丙氨酸钠、月桂酰丙氨酸钠、月桂酰甘氨酸钠、椰油基甘氨酸钠、月桂基聚氧乙烯醚磺基琥珀酸钠、月桂基聚氧乙烯醚磺基琥珀酸二钠、月桂基磺基琥珀酸钠、月桂基磺基琥珀酸二钠、月桂基葡萄糖羧酸钠、椰油基葡萄糖羧酸钠、椰油两性乙酸钠、月桂酰两性乙酸钠、甲基椰油基牛磺酸钠、以及它们的混合物。
3.辅助表面活性剂
该毛发护理组合物包含按重量计约0%至约10%,按重量计约0.5%至约10%,按重量计约1%至约8%,和按重量计约2%至约8%的一种或多种辅助表面活性剂,所述辅助表面活性剂选自由以下项组成的组:两性表面活性剂、两性离子表面活性剂、非离子表面活性剂以及它们的混合物。去污表面活性剂的各种示例和描述示于美国专利8,440,605;美国专利申请公布2009/155383;和美国专利申请公布2009/0221463中,这些文献全文以引用方式并入本文。
适用于毛发护理组合物中的两性去污表面活性剂包括被广泛地描述为脂族仲胺和叔胺的衍生物的那些表面活性剂,其中脂族基团可为直链或支链,并且其中脂族取代基中的一个包含约8至约18个碳原子,并且一个脂族取代基包含阴离子基团诸如羧基、磺酸根、硫酸根、磷酸根或膦酸根。在本发明毛发护理组合物中使用的合适的两性去污表面活性剂包括椰油酰两性基乙酸钠、椰油酰两性基二乙酸钠、月桂酰两性基乙酸钠、月桂酰两性基二乙酸钠、椰油基氨基丙酸钠、椰油基氨基二丙酸钠、椰油酰两性基羟丙基磺酸钠、椰油酰两性基丙酸钠、玉米油酰两性基丙酸钠、月桂氨基丙酸钠、月桂酰两性基乙酸钠、月桂酰两性基羟丙基磺酸钠、月桂酰两性基丙酸钠、玉米油酰两性基丙酸钠、月桂亚氨基二丙酸钠、椰油基氨基丙酸铵、椰油基氨基二丙酸铵、椰油酰两性基乙酸铵、椰油酰两性基羟丙基磺酸铵、椰油酰两性基丙酸铵、玉米油酰两性基丙酸铵、月桂氨基丙酸铵、月桂酰两性基乙酸铵、月桂酰两性基羟丙基磺酸铵、月桂酰两性基丙酸铵、玉米油酰两性基丙酸铵、月桂亚氨基二丙酸铵、椰油基氨基丙酸三乙醇胺、椰油基氨基二丙酸三乙醇胺、椰油酰两性基乙酸三乙醇胺、椰油酰两性基羟丙基磺酸三乙醇胺、椰油酰两性基丙酸三乙醇胺、玉米油酰两性基丙酸三乙醇胺、月桂氨基丙酸三乙醇胺、月桂酰两性基乙酸三乙醇胺、月桂酰两性基羟丙基磺酸三乙醇胺、月桂酰两性基丙酸三乙醇胺、玉米油酰两性基丙酸三乙醇胺、月桂亚氨基二丙酸三乙醇胺、椰油酰两性基二丙酸、癸酰两性基二乙酸二钠、癸酰两性基二丙酸二钠、辛酰两性基二乙酸二钠、辛酰两性基二丙酸二钠、椰油酰两性基羧乙基羟丙基磺酸二钠、椰油酰两性基二乙酸二钠、椰油酰两性基二丙酸二钠、二羧乙基椰油基丙二胺二钠、月桂基聚氧乙烯醚-5羧基两性基二乙酸二钠、月桂亚氨基二丙酸二钠、月桂酰两性基二丙酸二钠、油基两性基二丙酸二钠、PPG-2-异癸醇聚醚-7羧基两性基二乙酸二钠、月桂基氨基丙酸、月桂酰两性基二丙酸、月桂基氨丙基甘氨酸、月桂基二亚乙基二氨基甘氨酸,以及它们的混合物。另外合适的两性表面活性剂包括酰氨基甜菜碱和酰氨基磺基甜菜碱,其中R为C11-C17烷基的其中RCONH(CH2)3,与甜菜碱的氮原子相连,并且也可用于本发明中。
合适的非离子表面活性剂可选自由以下项构成的组:椰油酰胺、椰油酰胺甲基MEA、椰油酰胺DEA、椰油酰胺MEA、椰油酰胺MIPA、月桂酰胺DEA、月桂酰胺MEA、月桂酰胺MIPA、十四酰胺DEA、十四酰胺MEA、PEG-20椰油酰胺MEA、PEG-2椰油酰胺、PEG-3椰油酰胺、PEG-4椰油酰胺、PEG-5椰油酰胺、PEG-6椰油酰胺、PEG-7椰油酰胺、PEG-3月桂酰胺、PEG-5月桂酰胺、PEG-3油酰胺、PPG-2椰油酰胺、PPG-2羟乙基椰油酰胺、以及它们的混合物。
供使用的合适的非离子表面活性剂包括McCutcheon的《洗涤剂和乳化剂》“Detergents and Emulsifiers”北美版(1986年),Allured Publishing Corp.和McCutcheon的《功能性材料》“Functional Materials”北美版(1992)中描述的那些。适用的毛发护理组合物中的非离子表面活性剂包括但不限于聚氧乙烯烷基酚、聚氧乙烯醇、聚氧乙烯聚丙二醇、链烷酸甘油酯、链烷酸聚甘油酯、链烷酸丙二醇酯、链烷酸山梨醇酯、链烷酸聚氧乙烯山梨醇酯、链烷酸聚氧乙二醇酯、聚氧乙烯链烷酸、链烷醇酰胺、N-烷基吡咯烷酮、烷基糖苷、烷基多葡糖苷、烷基胺氧化物、和聚氧乙烯硅氧烷
B.与水混溶的溶剂
该毛发护理组合物包含水混溶性溶剂或水混溶性溶剂的组合。水混溶性溶剂的含量为约2重量%至约12重量%、约3重量%至约10重量%、约4重量%至约8重量%。合适的与水混溶的溶剂包括但不限于双丙二醇、三丙二醇、二甘醇、乙二醇、丙二醇、甘油、1,3-丙二醇、2,2-丙二醇、1,2-丁二醇、1,3-丁二醇、1,4-丁二醇、2,3-丁二醇、2-甲基-2,4-戊二醇以及它们的混合物。毛发护理组合物可包含两种或更多种与水混溶的溶剂,其中该溶剂中的至少一种是双丙二醇。
该毛发护理组合物在25℃下可具有约2至约10范围内的pH。另选地,该毛发护理组合物具有约4至约7范围内的pH,这可有助于增溶已沉积在毛发上的矿物和氧化还原金属。因此,毛发护理组合物还可有效洗出已存在的矿物和氧化还原金属沉积物,这可降低表皮失真,从而减少表皮破损和损伤。
该毛发护理组合物还可包含水溶助长剂或水溶助长剂的混合物。合适的水溶助长剂包括但不限于低级烷基苯磺酸盐的碱金属盐或铵盐,诸如二甲苯磺酸钠(SXS)、异丙基苯磺酸钠、甲苯磺酸钠以及它们的混合物。
C.水载体
该组合物可包含按重量计约35%至约78%、按重量计约40%至约78%、按重量计约45%至约78%、约50%至约75%、约55%至约70%的水、约60%至约68%的水。
D.阳离子聚合物
毛发护理组合物还包含阳离子聚合物。这些阳离子聚合物可包括以下中的至少一种:(a)阳离子瓜尔胶聚合物,(b)阳离子非瓜尔型半乳甘露聚糖聚合物,(c)阳离子木薯聚合物,(d)丙烯酰胺单体和阳离子单体的阳离子共聚物,和/或(e)合成的非交联阳离子聚合物,其在与去污表面活性剂混合后可形成或可不形成溶致液晶,(f)阳离子纤维素聚合物。另外地,阳离子聚合物可为阳离子聚合物的混合物。
毛发护理组合物可包含阳离子瓜尔胶聚合物,其为阳离子取代的半乳甘露聚糖(瓜尔)树胶衍生物。用于制备这些瓜尔胶衍生物的瓜尔胶通常以天然存在的得自瓜尔胶植物种子的材料形式获得。瓜尔胶分子自身为直链甘露聚糖,其在规则间隔处支化,在交替的甘露糖单元上具有单节半乳糖单元。甘露糖单元经由β(1-4)糖苷键连接基彼此连接。经由α(1-6)键,发生半乳糖支化。通过聚半乳甘露聚糖的羟基与反应性季铵化合物之间的反应,来获得瓜尔胶的阳离子衍生物。阳离子基团到瓜尔胶结构上的取代度应足以提供上文所述的所需阳离子电荷密度。
根据一个实施方案,该阳离子聚合物包括但不限于阳离子瓜尔胶聚合物,阳离子瓜尔胶聚合物具有小于1,000,000g/mol、或约10,000g/mol至约1,000,000g/mol、或约25,000g/mol至约1,000,000g/mol、或约50,000g/mol至约1,000,000g/mol、或约100,000g/mol至约1,000,000g/mol的分子量。在一个实施方案中,阳离子瓜尔胶聚合物具有约0.2meq/g至约2.2meq/g、或约0.3meq/g至约2.0meq/g、或约0.4meq/g至约1.8meq/g;或约0.5meq/g至约1.7meq/g的电荷密度。
根据一个实施方案,阳离子瓜尔胶聚合物具有小于约1,000,000g/mol的重均分子量,并且具有约0.1meq/g至约2.5meq/g的电荷密度。在一个实施方案中,阳离子瓜尔胶聚合物具有小于950,000g/mol、或约10,000g/mol至约900,000g/mol、或约25,000g/mol至约900,000g/mol、或约50,000g/mol至约900,000g/mol、或约100,000g/mol至约900,000g/mol、约150,000g/mol至约800,000g/mol的重均分子量。在一个实施方案中,阳离子瓜尔胶聚合物具有约0.2meq/g至约2.2meq/g、或约0.3meq/g至约2.0meq/g、或约0.4meq/g至约1.8meq/g;或约0.5meq/g至约1.5meq/g的电荷密度。
毛发护理组合物可包含按组合物的总重量计约0.05%至小于约1%,约0.05%至约0.9%,约0.1%至约0.8%,或约0.2%至约0.7%的阳离子聚合物(a)。
阳离子瓜尔胶聚合物可由季铵化合物形成。在一个实施方案中,用于形成阳离子瓜尔胶聚合物的季铵化合物符合通式1:
其中R3、R4和R5为甲基或乙基基团;R6为具有通式2的环氧烷基基团:
或R6为具有通式3的卤代醇基团:
其中R7为C1至C3亚烷基;X为氯或溴,并且Z为阴离子,诸如Cl-、Br-、I-或HSO4-。
在一个实施方案中,阳离子瓜尔胶聚合物符合通式4:
其中R8为瓜尔胶;并且其中R4、R5、R6和R7如上所定义;并且其中Z为卤素。在一个实施方案中,阳离子瓜尔胶聚合物符合式5:
合适的阳离子瓜尔胶聚合物包括阳离子瓜尔胶衍生物,诸如瓜尔羟丙基三甲基氯化铵。在一个实施方案中,阳离子瓜尔胶聚合物为瓜尔羟丙基三甲基氯化铵。瓜尔羟丙基三甲基氯化铵的具体示例包括可从Rhone-Poulenc Incorporated商购获得的系列,例如可从Rhodia商购获得的 C-500。 C-500具有0.8meq/g的电荷密度和500,000g/mol的分子量。其它合适的瓜尔羟丙基三甲基氯化铵为:具有约1.1meq/g的电荷密度和约500,000g/mol的分子量并且得自ASI的瓜尔羟丙基三甲基氯化铵,具有约1.5meq/g的电荷密度和约500,000g/mol的分子量并且得自ASI的瓜尔羟丙基三甲基氯化铵。其他合适的瓜尔羟丙基三甲基氯化铵为:Hi-Care 1000,其具有约0.7meq/g的电荷密度和约600,000g/摩尔的分子量,并且购自罗迪亚(Rhodia);N-Hance 3269和N-Hance 3270具有约0.7meq/g的电荷密度和约425,000g/mol的分子量并且购自ASIAquaCat,CG518具有约0.9meq/g的电荷密度和约50,000g/mol的分子量并且购自ASI。BF-13,其为具有约1.1meq/g的电荷密度和约800,000的分子量的无硼酸盐(硼)的瓜尔胶,以及BF-17,其为具有约1.7meq/g的电荷密度和约800,000的M.W.t的无硼酸盐(硼)的瓜尔胶,二者均得自ASI。
毛发护理组合物可包含半乳甘露聚糖聚合物衍生物,以单体对单体计,半乳甘露聚糖聚合物衍生物具有的甘露糖与半乳糖的比率大于2:1,半乳甘露聚糖聚合物衍生物选自:阳离子半乳甘露聚糖聚合物衍生物和具有净正电荷的两性半乳甘露聚糖聚合物衍生物。如本文所用,术语“阳离子半乳甘露聚糖”是指向其中添加阳离子基团的半乳甘露聚糖聚合物。术语“两性半乳甘露聚糖”是指向其中添加阳离子基团和阴离子基团以使得聚合物具有净正电荷的半乳甘露聚糖聚合物。
半乳甘露聚糖聚合物存在于豆科种子胚乳中。半乳甘露聚糖聚合物由甘露糖单体和半乳糖单体的组合构成。半乳甘露聚糖分子为按规则的间隔在特定甘露糖单元上以单节半乳糖单元支链的直链甘露聚糖。甘露糖单元经由β(1-4)糖苷键彼此连接。经由α(1-6)键产生半乳糖支化。甘露糖单体与半乳糖单体的比率根据植物的品种而改变,并且还受气候的影响。以单体对单体计,适用的非瓜尔胶半乳甘露聚糖聚合物衍生物可具有大于2:1的甘露糖与半乳糖的比率。合适的甘露糖与半乳糖的比率可大于约3:1,并且甘露糖与半乳糖的比率可大于约4:1。甘露糖与半乳糖比率的分析是本领域熟知的,并且通常基于半乳糖含量的测量。
用于制备非瓜尔胶半乳甘露聚糖聚合物衍生物的树胶通常以天然存在的材料形式获得,诸如来自植物的种子或豆形果实。多种非瓜尔胶半乳甘露聚糖聚合物的示例包括但不限于刺云豆胶(3份甘露糖/1份半乳糖)、长角豆胶或角豆胶(4份甘露糖/1份半乳糖)和肉桂胶(5份甘露糖/1份半乳糖)。
在本发明的一个实施方案中,非瓜尔胶半乳甘露聚糖聚合物衍生物具有约1,000至约1,000,000、和/或约5,000至约900,000的分子量。
本发明的毛发护理组合物还可包含半乳甘露聚糖聚合物衍生物,其具有约0.5meq/g至约7meq/g的阳离子电荷密度。该半乳甘露聚糖聚合物衍生物可具有约1meq/g至约5meq/g的阳离子电荷密度。半乳甘露聚糖结构上的阳离子基团的取代度应足以提供所需的阳离子电荷密度。
半乳甘露聚糖聚合物衍生物可为非瓜尔胶半乳甘露聚糖聚合物的阳离子衍生物,该衍生物由聚半乳甘露聚糖聚合物的羟基基团与反应性季铵化合物之间的反应获得。适用于形成阳离子半乳甘露聚糖聚合物衍生物的季铵化合物包括符合如上定义的通式1-5的那些。
由上述试剂形成的阳离子非瓜尔胶半乳甘露聚糖聚合物衍生物由通式6表示:
其中R为树胶。阳离子半乳甘露聚糖衍生物可为树胶羟丙基三甲基氯化铵,其可更具体地由通式7表示:
另选地,半乳甘露聚糖聚合物衍生物可为具有净正电荷的两性半乳甘露聚糖聚合物衍生物,当阳离子半乳甘露聚糖聚合物衍生物还包含阴离子基团时,获得两性半乳甘露聚糖聚合物衍生物。
阳离子非瓜尔胶半乳甘露聚糖可具有大于约4:1的甘露糖与半乳糖的比率,约50,000g/mol至约1,000,000g/mol、和/或约100,000g/mol至约900,000g/mol的分子量,以及约1meq/g至约5meq/g、和/或2meq/g至约4meq/g的阳离子电荷密度,并且还可来源于肉桂植物。
毛发护理组合物可包含按组合物的重量计至少约0.05%的半乳甘露聚糖聚合物衍生物,或者按组合物的重量计约0.05%至约2%的半乳甘露聚糖聚合物衍生物。
毛发护理组合物可包含水溶性阳离子改性淀粉聚合物。如本文所用,术语“阳离子改性淀粉”是指在使淀粉降解至具有较小分子量之前向其中添加阳离子基团的淀粉,或在使淀粉改性以获得期望的分子量之后向其中添加阳离子基团的淀粉。术语“阳离子改性淀粉”的定义还包括两性改性淀粉。术语“两性改性淀粉”是指向其中添加阳离子基团和阴离子基团的淀粉水解产物。
毛发护理组合物可包含按组合物的重量计约0.01%至约10%,和/或约0.05%至约5%范围内的阳离子改性淀粉聚合物。
本文公开的阳离子改性淀粉聚合物具有约0.5%至约4%的结合氮百分比。
用于毛发护理组合物中的阳离子改性淀粉聚合物可具有约50,000g/mol至约1,000,000g/mol、和/或约100,000g/mol至约1,000,000g/mol的分子量。
毛发护理组合物可包含阳离子改性淀粉聚合物,其具有约0.2meq/g至约5meq/g、和/或约0.2meq/g至约2meq/g的电荷密度。获得此类电荷密度的化学改性包括但不限于向淀粉分子中加入氨基和/或铵基团。这些铵基团的非限制性示例可包括取代基,诸如羟丙基三甲基氯化铵、三甲基羟丙基氯化铵、二甲基硬脂基羟丙基氯化铵和二甲基十二烷基羟丙基氯化铵。参见Solarek,D.B.,Cationic Starches in Modified Starches:Propertiesand Uses(Wurzburg,O.B.编辑,CRC Press,Inc.,Boca Raton,Fla.1986,第113-125页)。可将阳离子基团在淀粉降解至具有较小分子量之前添加到淀粉中,或可将阳离子基团在此类改性之后添加到其中。
阳离子改性淀粉聚合物通常具有约0.2至约2.5的阳离子基团取代度。如本文所用,阳离子改性淀粉聚合物的“取代度”是每个由取代基衍生的葡糖酐单元上羟基数的平均量度。由于每个葡糖酐单元具有三个可被取代的羟基,所以最大可能的取代度为3。以摩尔平均计,取代度表示为每摩尔葡糖酐单元具有的取代基摩尔数。取代度能够用本领域熟知的质子核磁共振光谱(“sup.1H NMR”)方法测定。合适的.sup.1H NMR技术包括描述于“Observation on NMR Spectra of Starches in Dimethyl Sulfoxide,Iodine-Complexing,and Solvating in Water-Dimethyl Sulfoxide”Qin-Ji Peng和ArthurS.Perlin,碳水化合物研究(Carbohydrate Research),160(1987),57-72;以及“AnApproach to the Structural Analysis of Oligosaccharides by NMR Spectroscopy”,J.Howard Bradbury和J.Grant Collins,碳水化合物研究(Carbohydrate Research),71,(1979),15-25中。
在化学改性之前的淀粉来源可选自多种来源,例如块茎、豆类、谷类和粮食。这种来源的淀粉的非限制性示例可包括玉米淀粉、小麦淀粉、稻米淀粉、蜡质玉米淀粉、燕麦淀粉、木薯淀粉(cassaya starch)、蜡质大麦淀粉、蜡质稻米淀粉、麸质稻米淀粉、糯米淀粉、支链淀粉、马铃薯淀粉、木薯淀粉(tapioca starch)、燕麦淀粉、西米淀粉、甜稻米淀粉、或它们的混合物。
阳离子改性淀粉聚合物可选自降解的阳离子玉米淀粉、阳离子木薯、阳离子马铃薯淀粉以及它们的混合物。另选地,阳离子改性淀粉聚合物为阳离子玉米淀粉和阳离子木薯。
在降解至具有较小分子量之前或在改性至具有较小分子量之后,淀粉可包含一种或多种附加的改性。例如,这些改性可包括交联、稳定化反应、磷酸化和水解。稳定性反应可包括烷基化和酯化。
阳离子改性淀粉聚合物可以水解淀粉(例如酸、酶或碱降解)、氧化淀粉(例如过氧化物、过酸、次氯酸盐、碱或任何其它氧化剂)、物理/机械降解淀粉(例如经由处理设备的热机械能输入)或它们组合的形式掺入所述组合物中。
淀粉的最佳形式是一种易于溶解于水中并且在水中形成基本上澄清(600nm下的透射%.gtoreq.80)溶液的形式。组合物的透明度通过紫外/可见(UV/VIS)分光光度测定法来测定,其使用Gretag Macbeth Colorimeter Color i 5根据相关指导说明,测定样品对UV/VIS射线的吸收或透过。已示出,600nm的光波长足以表征化妆品组合物的透明度。
适用于毛发护理组合物中的阳离子改性淀粉可购自已知的淀粉供应商。还适用于毛发护理组合物中的是非离子改性淀粉,如本领域所已知的,非离子改性淀粉可被进一步衍生为阳离子改性淀粉。如本领域已知的是,其它合适的改性淀粉原料可被季铵化以产生适用于毛发护理组合物中的阳离子改性淀粉聚合物。
淀粉降解过程:通过在水中混合颗粒状淀粉,可制得淀粉浆液。将温度升至约35℃。然后加入按淀粉计约50ppm浓度的高锰酸钾水溶液。用氢氧化钠将pH升至约11.5,并且将浆液充分搅拌,以防止淀粉沉降。然后加入在水中稀释的约30%的过氧化氢溶液,使过氧化物的含量基于淀粉计为约1%。然后通过加入附加的氢氧化钠,将pH恢复至约11.5。将反应在约1至约20小时的时段内完成。然后将该混合物用稀盐酸中和。通过过滤接着洗涤并干燥来重新获得降解淀粉。
毛发护理组合物可包含丙烯酰胺单体和阳离子单体的阳离子共聚物,其中共聚物具有约1.0meq/g至约3.0meq/g的电荷密度。阳离子共聚物可为丙烯酰胺单体和阳离子单体的合成阳离子共聚物。
阳离子共聚物可包含:
(i)具有下式AM的丙烯酰胺单体:
其中R9为H或C1-4烷基;并且R10和R11独立地选自由以下项组成的组:H、C1-4烷基、CH2OCH3、CH2OCH2CH(CH3)2和苯基,或合在一起为C3-6环烷基;并且
(ii)符合式CM的阳离子单体:
其中k=1,v、v'和v”中的每一个独立地为1至6的整数,w为零或1至10的整数,并且X-为阴离子。
阳离子单体可符合式CM,并且其中k=1,v=3并且w=0,z=1,并且X-为Cl-,以形成以下结构:
上述结构可被称为二季铵盐。另选地,阳离子单体可符合式CM,并且其中v和v”各自为3,v'=1,w=1,y=1,并且X-为Cl-,如:
上述结构可被称为三季铵盐。
合适的丙烯酰胺单体包括但不限于丙烯酰胺或甲基丙烯酰胺。
在一个另选的实施方案中,该阳离子共聚物为丙烯酰胺单体和阳离子单体,其中该阳离子单体选自由以下项构成的组:(甲基)丙烯酸二甲基氨基乙酯、(甲基)丙烯酸二甲基氨基丙酯、(甲基)丙烯酸二叔丁基氨基乙酯、二甲基氨甲基(甲基)丙烯酰胺、二甲基氨丙基(甲基)丙烯酰胺;乙烯亚胺、乙烯胺、2-乙烯基吡啶、4-乙烯基吡啶;三甲基(甲基)丙烯酰氧乙基氯化铵、三甲基(甲基)丙烯酰氧乙基甲酯硫酸铵、二甲基铵(甲基)丙烯酰氧乙基苄基氯化铵、4-苯甲酰基苄基二甲基丙烯酰氧乙基氯化铵、三甲基(甲基)丙烯酰胺基乙基氯化铵、三甲基(甲基)丙烯酰胺基丙基氯化铵、乙烯基苄基三甲基氯化铵、二烯丙基二甲基氯化铵、以及它们的混合物。
阳离子共聚物可包含阳离子单体,阳离子单体选自:阳离子单体包括三甲基(甲基)丙烯酰氧乙基氯化铵、三甲基(甲基)丙烯酰氧乙基甲酯硫酸铵、二甲基(甲基)丙烯酰氧乙基苄基氯化铵、4-苯甲酰基苄基二甲基丙烯酰氧乙基氯化铵、三甲基(甲基)丙烯酰胺基乙基氯化铵、三甲基(甲基)丙烯酰胺基丙基氯化铵、乙烯基苄基三甲基氯化铵、以及它们的混合物。
阳离子共聚物可为水溶性的。阳离子共聚物由以下形成:(1)(甲基)丙烯酰胺和基于(甲基)丙烯酰胺的阳离子单体和/或水解稳定的阳离子单体的共聚物,(2)(甲基)丙烯酰胺、基于阳离子(甲基)丙烯酸酯的单体、和基于(甲基)丙烯酰胺的单体、和/或水解稳定的阳离子单体的三聚物。基于阳离子(甲基)丙烯酸酯的单体可为包含季铵化N原子的(甲基)丙烯酸的阳离子化酯。在一个实施方案中,包含季铵化N原子的(甲基)丙烯酸的阳离子化酯为烷基和亚烷基基团中具有C1-C3的季铵化(甲基)丙烯酸二烷基氨基烷基酯。合适的包含季铵化N原子的(甲基)丙烯酸的阳离子化酯可选自:(甲基)丙烯酸二甲基氨基甲酯的铵盐、(甲基)丙烯酸二甲基氨基乙酯的铵盐、(甲基)丙烯酸二甲基氨基丙酯的铵盐、(甲基)丙烯酸二乙基氨基甲酯的铵盐、(甲基)丙烯酸二乙基氨基乙酯的铵盐;以及(甲基)丙烯酸二乙基氨基丙酯的铵盐。在一个实施方案中,包含季铵化N原子的(甲基)丙烯酸的阳离子化酯为用卤代烷或用氯甲烷或苄氯或硫酸二甲酯季铵化的丙烯酸二甲基氨基乙酯(ADAME-Quat)。当基于(甲基)丙烯酰胺时,阳离子单体可为烷基和亚烷基基团中具有C1至C3的季铵化二烷基氨基烷基(甲基)丙烯酰胺,或二甲基氨基丙基丙烯酰胺,其用卤代烷或用氯甲烷或苄氯或硫酸二甲酯季铵化。
合适的基于(甲基)丙烯酰胺的阳离子单体包括在烷基和亚烷基基团中具有C1-C3的季铵化二烷基氨基烷基(甲基)丙烯酰胺。基于(甲基)丙烯酰胺的阳离子单体可为二甲基氨基丙基丙烯酰胺,其用卤代烷(尤其是氯甲烷)或苄基氯或硫酸二甲酯季铵化。
阳离子单体可为水解稳定的阳离子单体。除了二烷基氨基烷基(甲基)丙烯酰胺以外,水解稳定的阳离子单体还可为OECD水解测试可以认为稳定的所有单体。阳离子单体可为水解稳定的,并且水解稳定的阳离子单体可选自:二烯丙基二甲基氯化铵和水溶性阳离子苯乙烯衍生物。
阳离子共聚物可为丙烯酰胺、用氯甲烷季铵化的(甲基)丙烯酸2-二甲基铵乙酯(ADAME-Q)、和用氯甲烷季铵化的3-二甲基铵丙基(甲基)丙烯酰胺(DIMAPA-Q)的三元共聚物。阳离子共聚物可由丙烯酰胺和丙烯酰胺基丙基三甲基氯化铵形成,其中丙烯酰胺基丙基三甲基氯化铵具有约1.0meq/g至约3.0meq/g的电荷密度。
阳离子共聚物可具有约1.1meq/g至约2.5meq/g、或约1.1meq/g至约2.3meq/g、或约1.2meq/g至约2.2meq/g、或约1.2meq/g至约2.1meq/g、或约1.3meq/g至约2.0meq/g、或约1.3meq/g至约1.9meq/g的电荷密度。
阳离子共聚物可具有约10,000g/mol至约1,000,000g/mol、或约25,000g/mol至约1,000,000g/mol、或约50,000g/mol至约1,000,000g/mol、或约100,000g/mol至约1,000,000g/mol、或约150,000g/mol至约1,000,000g/mol的分子量。
(a)阳离子合成聚合物
毛发护理组合物可包含可由以下形成的阳离子合成聚合物
i)一种或多种阳离子单体单元,和任选的
ii)一种或多种带有负电荷的单体单元,和/或
iii)非离子单体,
其中共聚物的随后电荷是正的。三种类型的单体的比率以“m”、“p”和“q”给出,其中“m”为阳离子单体的数目,“p”为带有负电荷的单体的数目,并且“q”为非离子单体的数目
阳离子聚合物可为具有以下结构的水溶性或水可分散的非交联并且合成的阳离子聚合物:
其中A可为以下阳离子部分中的一种或多种:
其中@=酰胺基、烷基酰胺基、酯、醚、烷基、或烷基芳基;
其中Y=C1-C22烷基、烷氧基、烷叉基、烷基或芳氧基;
其中ψ=C1-C22烷基、烷氧基、烷基芳基、或烷基芳氧基;。
其中Z=C1-C22烷基、烷氧基、芳基、或芳氧基;
其中R1=H、C1-C4直链或支链烷基;
其中s=0或1,n=0或≥1;
其中T和R7=C1-C22烷基;并且
其中X-=卤素、氢氧根、链烷醇根、硫酸根或烷基硫酸根。
其中带有负电荷的单体由以下定义:R2’=H、C1-C4直链或支链烷基,并且R3为:
其中D=O、N、或S;
其中Q=NH2或O;
其中u=1-6;
其中t=0-1;并且
其中J=包含以下元素P、S、C的氧化官能团。
其中非离子单体由以下定义:R2”=H、C1-C4直链或支链烷基,R6=直链或支链烷基、烷基芳基、芳氧基、烷氧基、烷基芳氧基,并且β定义为
其中G‘和G”彼此独立地为O、S或N-H,并且L=0或1。
阳离子单体的示例包括(甲基)丙烯酸氨基烷基酯、(甲基)氨基烷基(甲基)丙烯酰胺;包含至少一个仲、叔或季铵官能团,或包含氮原子的杂环基团、乙烯胺或乙烯亚胺的单体;二烯丙基二烷基铵盐;它们的混合物、它们的盐以及从它们衍生出的大分子单体。
阳离子单体的另外示例包括(甲基)丙烯酸二甲氨基乙酯、(甲基)丙烯酸二甲氨基丙酯、(甲基)丙烯酸二叔丁基氨乙酯、二甲氨基甲基(甲基)丙烯酰胺、二甲氨基丙基(甲基)丙烯酰胺、乙烯亚胺、乙烯胺、2-乙烯基吡啶、4-乙烯基吡啶、(甲基)丙烯酸三甲基氯化铵乙酯、(甲基)丙烯酸三甲基甲基硫酸铵乙酯、(甲基)丙烯酸二甲基苄基氯化铵乙酯、丙烯酸-4-苯甲酰基苄基二甲基氯化铵乙酯、三甲基氯化铵乙基(甲基)丙烯酰胺、三甲基氯化铵丙基(甲基)丙烯酰胺、乙烯基苄基三甲基氯化铵、二烯丙基二甲基氯化铵。
合适的阳离子单体包括包含式-NR3 +的季铵基团的那些,其中R相同或不同,代表氢原子、包含1至10个碳原子的烷基,或苄基,任选带有羟基,并且包含阴离子(抗衡离子)。阴离子的示例为卤离子(如氯离子、溴离子)、硫酸根、硫酸氢根、烷基硫酸根(例如,包含1至6个碳原子)、磷酸根、柠檬酸根、甲酸根和乙酸根。
合适的阳离子单体包括(甲基)丙烯酰氧乙基三甲基氯化铵、(甲基)丙烯酰氧乙基三甲基甲酯硫酸铵、(甲基)丙烯酰氧乙基苄基二甲基氯化铵、丙烯酰氧乙基4-苯甲酰基苄基二甲基氯化铵、(甲基)丙烯酰胺基乙基三甲基氯化铵、(甲基)丙烯酰胺基丙基三甲基氯化铵、乙烯基苄基三甲基氯化铵。
其它合适的阳离子单体包括(甲基)丙烯酰胺基丙基三甲基氯化铵。
带有负电荷的单体的示例包括包含磷酸根或膦酸根基团的α-烯键式不饱和单体、α-烯键式不饱和一元羧酸、α-烯键式不饱和二元羧酸的单烷基酯、α-烯键式不饱和二元羧酸的单烷基酰胺、包含磺酸基团的α-烯键式不饱和化合物、以及包含磺酸基团的α-烯键式不饱和化合物的盐。
具有负电荷的合适单体包括丙烯酸、甲基丙烯酸、乙烯基磺酸、乙烯基磺酸的盐、乙烯基苯磺酸、乙烯基苯磺酸的盐、α-丙烯酰胺基甲基丙磺酸、α-丙烯酰胺基甲基丙磺酸的盐、甲基丙烯酸2-磺基乙酯、甲基丙烯酸2-磺基乙酯的盐、丙烯酰胺基-2-甲基丙磺酸(AMPS)、丙烯酰胺基-2-甲基丙磺酸的盐、以及苯乙烯磺酸盐(SS)。
非离子单体的示例包括乙酸乙烯酯、α-烯键式不饱和羧酸的酰胺、具有氢化或氟化醇的α-烯键式不饱和一元羧酸的酯、聚环氧乙烷(甲基)丙烯酸酯(即,聚乙氧基化的(甲基)丙烯酸)、α-烯键式不饱和二元羧酸的单烷基酯、α-烯键式不饱和二元羧酸的单烷基酰胺、乙烯基腈、乙烯胺酰胺、乙烯醇、乙烯基吡咯烷酮和乙烯基芳族化合物。
合适的非离子单体包括苯乙烯、丙烯酰胺、甲基丙烯酰胺、丙烯腈、丙烯酸甲酯、丙烯酸乙酯、丙烯酸正丙酯、丙烯酸正丁酯、甲基丙烯酸甲酯、甲基丙烯酸乙酯、甲基丙烯酸正丙酯、甲基丙烯酸正丁酯、丙烯酸2-乙基己酯、甲基丙烯酸2-乙基己酯、丙烯酸2-羟乙酯、以及甲基丙烯酸2-羟乙酯。
与合成阳离子聚合物缔合的阴离子抗衡离子(X-)可为任何已知的抗衡离子,只要聚合物在水中、在毛发护理组合物中、或在毛发护理组合物中的凝聚层相中保持可溶解或可分散,并且只要抗衡离子与毛发护理组合物的基本组分在物理上和化学上是相容的,或不会另外不当地破坏产品的性能、稳定性或美观性。此类抗衡离子的非限制性示例包括卤离子(例如,氯、氟、溴、碘)、硫酸根和甲硫酸根。
阳离子聚合物的浓度按毛发护理组合物的重量计在约0.025%至约5%、约0.1%至约3%、和/或约0.2%至约1%的范围内。
合适的阳离子纤维素聚合物为与三甲基铵取代的环氧化物反应的羟乙基纤维素的盐,工业上(CTFA)称作聚季铵盐10,并且可以它们的Polymer LR、JR和KG聚合物系列购自Dow/Amerchol Corp.(Edison,N.J.,USA)。阳离子纤维素的其他合适类型包括羟乙基纤维素与月桂基二甲基铵取代的环氧化物反应而生成的聚合物季铵盐,其在工业上(CTFA)内被命名为聚季铵盐24。这些材料可以商品名Polymer LM-200购自陶氏/爱美高公司(Dow/Amerchol Corp.)。其它合适类型的阳离子纤维素包括羟乙基纤维素与月桂基二甲基铵取代的环氧化物以及三甲基铵取代的环氧化物反应所得的聚合季铵盐,其在工业领域(CTFA)内被称为聚季铵盐67。这些材料以商品名SoftCAT Polymer SL-5、SoftCAT Polymer SL-30、Polymer SL-60、Polymer SL-100、Polymer SK-L、Polymer SK-M、Polymer SK-MH、和Polymer SK-H购自Dow/Amerchol Corp.。
E.调理剂
毛发护理组合物可以包含一种或多种调理剂。调理剂包括用于向毛发和/或皮肤提供特定调理有益效果的物质。可用于本发明的毛发护理组合物中的调理剂通常包括水不溶性、水可分散性、非挥发性、可形成乳化的液体颗粒的液体。用于毛发护理组合物中的合适的调理剂是通常特征为有机硅(例如硅油、阳离子有机硅、硅橡胶纯胶料、高折射有机硅和有机硅树脂)、有机调理油(例如烃油、聚烯烃和脂肪酸酯)或它们的组合的那些调理剂,或在含水表面活性剂基质中以其它方式形成液体分散颗粒的那些调理剂。
1.硅氧烷调理剂
该毛发护理组合物可包含按重量计约0%至约20%,或者按重量计约6%约18%;以及作为另外一种选择,按重量计约8%至约16%的一种或多种硅氧烷,其具有小于约300nm,或者小于约200nm,并且或者小于约100nm的粒度。该硅氧烷可为纳米乳液的形式。
可由动态光散射(DLS)来测量该一种或多种硅氧烷的粒度。使用He-Ne激光器633nm的Malvern Zetasizer Nano ZEN3600系统(www.malvern.com)可用于在25℃下的测量。
可使用由Malvern Instruments提供的Zetasizer软件来分析自相关函数,其使用Stokes-Einstein公式确定有效的流体动力学半径:
其中kB为Boltzmann常数,T为绝对温度,η为介质的粘度,D为散射物质的平均扩散系数,并且R为颗粒的流体动力学半径。
粒度(即流体动力学半径)可通过将由于布朗运动引起的观察到的散斑图案与解出Stokes-Einstein方程相关联来获得,所述方程将粒度与测量的扩散常数相关联,如本领域中已知的。
对于每个样品,可进行3次测量,并且Z平均值可报告为粒度。
在一个实施方案中,所述一种或多种硅氧烷可以呈纳米乳液的形式。纳米乳液可包含适用于施用到皮肤或毛发上的任何硅氧烷。
在一个实施方案中,所述一种或多种硅氧烷可在其分子结构中包含极性官能团诸如Si-OH(以聚二甲基硅氧烷醇形式存在)、伯胺、仲胺、叔胺和季铵盐。所述一种或多种硅氧烷可选自氨基硅氧烷、侧链季铵硅氧烷、末端季铵硅氧烷、氨基聚环氧烷硅氧烷、季铵聚环氧烷硅氧烷、和氨基吗啉硅氧烷。
所述一个或多种硅氧烷可包含:
(a)至少一种对应于式(V)的氨基硅氧烷:
R'aG3-a—Si(OSiG2)n—(OSiGbR'2-b)m—O—SiG3-a—R'a (I)
其中:
G选自氢原子、苯基基团、OH基团和C1-C8烷基基团,例如甲基,
a为0至3范围内的整数,并且在一个实施方案中a为0,
b选自0和1,并且在一个实施方案中b为1,
m和n为使得总和(n+m)可在例如1至2 000的范围内的数,诸如例如50至150,其中n可例如选自在0至1999范围内的数,诸如例如49至149,并且其中m可选自例如在1至2000范围内的数,诸如例如1至10;
R'是式—CqH2qL的一价基团,其中q为2至8的数,并且L为选自以下基团的任选的季铵化胺基团:
—NR"—CH2—CH2—N'(R1)2,
—N(R")2,
—N+(R")3A-,
—N+H(R")2A-,
—N+H2(R")A-,和
—N(R")—CH2—CH2—N+R"H2A-,
其中R"可选自氢原子、苯基基团、苄基基团和基于饱和一价烃的基团,诸如例如包含1至20个碳原子的烷基基团,并且A-选自卤离子,诸如例如氟离子、氯离子、溴离子和碘离子。
在一个实施方案中,一种或多种硅氧烷可包括对应于式(1)的那些,其中a=0,G=甲基,m和n为使得总和(n+m)可在例如1至2000的范围内的数,诸如例如50至150,其中n可例如选自在0至1999范围内的数,诸如例如49至149,并且其中m可选自在例如1至2000范围内的数,诸如例如1至10;并且L为–N(CH3)2或–NH2,或者–NH2。
另外所述至少一种本发明的氨基硅氧烷包括:
(b)具有式(VII)的侧链季铵硅氧烷:
其中:
R5选自包含1至18个碳原子的基于一价烃的基团,诸如C1-C18烷基基团和C2-C18烯基基团,例如甲基;
R6选自基于二价烃的基团,诸如二价C1-C18亚烷基基团和二价C1-C18亚烷氧基基团,例如C1-C8亚烷氧基基团,其中所述R6通过SiC键键合到Si;
Q-为阴离子,其可例如选自卤离子,诸如氯离子和有机酸盐(诸如乙酸盐);
r为在2至20范围内的平均统计值,诸如2至8;
s为在20至200范围内的统计平均值,优选20至50。
此类氨基硅氧烷更具体地描述于美国专利4,185,087中,其公开内容以引用方式并入本文。
属于此类的硅氧烷是由公司Union Carbide以名称“Ucar Silicone ALE 56”销售的硅氧烷。
所述至少一种氨基硅氧烷的另外的示例包括:
c)具有式(VIIb)的季铵硅氧烷:
其中:
基团R7可以相同或不同,其各自选自包含1至18个碳原子的基于一价烃的基团,诸如C1-C18烷基基团,例如甲基、C2-C18烯基基团,和包含5或6个碳原子的环;
R6选自基于二价烃的基团,诸如二价C1-C18亚烷基基团和二价C1-C18亚烷氧基基团,例如通过SiC键连接到Si的C1-C8基团;
R8可以相同或不同,其表示氢原子、包含1至18个碳原子的基于一价烃的基团,并且具体地讲C1-C18烷基基团、C2-C18烯基基团或基团—R6—NHCOR7;
X-为阴离子诸如卤离子,具体地讲氯离子,或有机酸盐(乙酸盐等);
r表示2至200的统计平均值,并且具体地讲5至100。
此类硅氧烷描述于例如专利申请EP-A-0 530 974中,其公开内容以引用方式并入本文。
属于此类的硅氧烷是由赢创公司(Eovnik)以商品名Abil Quat 3270、Abil Quat3272、Abil Quat 3474和Abil ME 45出售的硅氧烷。所述至少一种氨基硅氧烷的另外的示例包括:
d)季铵和聚环氧烷硅氧烷
其中所述季氮基团位于聚硅氧烷主链中、末端处或上述两者。
此类硅氧烷描述于PCT专利公布WO 2002/010257中,其公开内容以引用方式并入本文中。
属于此类的硅氧烷是由迈图公司(Momentive)以名称Silsoft Q出售的硅氧烷。
(e)氨基官能化硅氧烷,其具有式(V)的吗啉代基团:
其中
A表示经由—O—键合的结构单元(I)、(II)或(III)
或低聚或聚合物残基,其经由—O—键合,包含式(I)、(II)或(III)的结构单元,或对结构单元(III)的连接氧原子的一半,或表示—OH,
*表示对结构单元(I)、(II)或(III)中的一个的键,或表示末端基团B(Si-键合的)或D(O-键合的)
B表示—OH、—O—Si(CH3)3、—O—Si(CH3)2OH、—O—Si(CH3)2OCH3基团,
D表示—H、—Si(CH3)3、—Si(CH3)2OH、—Si(CH3)2OCH3基团,
a、b和c表示0至1000的整数,前提条件是a+b+c>0,
m、n和o表示1至1000的整数。
这类氨基官能化硅氧烷具有INCI名称:氨基封端的聚二甲基硅氧烷/吗啉代甲基倍半硅氧烷共聚物。特别合适的氨基封端的聚二甲基硅氧烷是具有商品名Wacker ADM 8301E的产品。
此类硅氧烷的示例购自以下供应商:
由道康宁(Dow Corning)公司提供的:流体:2-8566、AP 6087、AP 6088、DC 8040流体、流体8822A DC、DC 8803和8813聚合物、7-6030、AP-8104、AP 8201;乳液:CE-8170 AF微乳液、2-8177、2-8194微乳液、9224乳液、939、949、959、DC 5-7113 Quat微乳液、DC 5-7070乳液、DC CE-8810、CE 8401乳液、CE 1619、Dow Corning Toray SS-3551、Dow CorningToray SS-3552;
由瓦克(Wacker)公司提供的:Wacker Belsil ADM 652、ADM 656、1100、1600、1650(流体)ADM 6060(直链氨基封端的聚二甲基硅氧烷)乳液;ADM 6057 E(支链氨基封端的聚二甲基硅氧烷)乳液;ADM 8020 VP(微乳液);SLM 28040(微乳液);
由迈图(Momentive)公司提供的:Silsoft 331、SF1708、SME 253和254(乳液)、SM2125(乳液)、SM 2658(乳液)、Silsoft Q(乳液)
由信越(Shin-Etsu)公司提供的:KF-889、KF-867S、KF-8004、X-52-2265(乳液);
由斯泰硅氧烷公司(Siltech Silicones)提供的:Siltech E-2145、E-Siltech2145-35;
由赢创工业(Evonik Industries)提供的:Abil T Quat 60th
一些氨基硅氧烷的非限制性示例包括具有以下INCI名称的化合物:聚硅氧烷季铵盐-1、聚硅氧烷季铵盐-2、聚硅氧烷季铵盐-3、聚硅氧烷季铵盐-4、聚硅氧烷季铵盐-5、聚硅氧烷季铵盐-6、聚硅氧烷季铵盐-7、聚硅氧烷季铵盐-8、聚硅氧烷季铵盐-9、聚硅氧烷季铵盐-10、聚硅氧烷季铵盐-11、聚硅氧烷季铵盐-12、聚硅氧烷季铵盐-15、聚硅氧烷季铵盐-16、聚硅氧烷季铵盐-17、聚硅氧烷季铵盐-18、聚硅氧烷季铵盐-20、聚硅氧烷季铵盐-21、聚硅氧烷季铵盐-22、聚硅氧烷季铵盐-80、以及聚硅氧烷季铵盐-2泛醇琥珀酸酯和聚硅氧烷季铵盐-16/缩水甘油基聚二甲基硅氧烷交联聚合物。
氨基硅氧烷能够以纳米乳液的形式提供,并且包括MEM 9049、MEM 8177、MEM0959、MEM 8194、SME 253和Silsoft Q。
该一种或多种硅氧烷可包括聚二甲基硅氧烷和/或聚二甲基硅氧烷醇。聚二甲基硅氧烷醇是由以下化学通式表示的羟基封端的聚二甲基硅氧烷
并且
其中R为烷基基团(优选R为甲基或乙基,更优选甲基),并且x为至多约500的整数,其被选择以获得期望的分子量。商业聚二甲基硅氧烷醇典型作为与聚二甲基硅氧烷或环状聚甲基硅氧烷的混合物出售(例如, (Dow )1401、1402和1403流体)。
2.非硅氧烷调理剂
本文所述毛发护理组合物中的调理剂还可包含至少一种有机调理剂,其单独使用或与其他调理剂如上述硅氧烷组合使用。有机调理剂的非限制性示例描述于下文中。
a.烃油
用作毛发护理组合物中的调理剂的合适的有机调理剂包括但不限于具有至少约10个碳原子的烃油,诸如环烃、直链脂族烃(饱和或不饱和的)、和支链脂族烃(饱和或不饱和的),包括聚合物以及它们的混合物。直链烃油可为约C12至约C19。支链烃油(包括烃聚合物)典型地将包含多于19个碳原子。
b.聚烯烃
用于本文所述毛发护理组合物中的有机调理剂还可包括液体聚烯烃,其包括液体聚-α-烯烃和/或氢化的液体聚-α-烯烃。用于本文的聚烯烃通过C4至约C14,并且在一个实施方案中约C6至约C12烯烃单体的聚合反应来制备。
c.脂肪酸酯
适用作本文所述毛发护理组合物中调理剂的其他有机调理剂包括具有至少10个碳原子的脂肪酸酯。这些脂肪酸酯包括具有烃基链的酯,该烃基链衍生自脂肪酸或醇。脂肪酸酯的烃基基团可包括或具有与其共价键合的其它相容官能团,诸如酰胺和烷氧基部分(例如乙氧基或醚键等)。由不饱和甘油酯制备的其他低聚物或聚合物酯也可被用作调理物质。
d.氟化调理化合物
适用于向毛发递送调理效果的用作有机调理剂的氟化化合物包括全氟聚醚、全氟化烯烃、可为与前述有机硅流体类似的流体或弹性体形式的基于氟的特定聚合物、和全氟化聚二甲基硅氧烷。
e.脂肪醇
适用于本文所述毛发护理组合物中的其他有机调理油包括但不限于具有至少约10个碳原子,约10至约22个碳原子,并且在一个实施方案中约12至约16个碳原子的脂肪醇。
f.烷基葡糖苷和烷基葡糖苷衍生物
适用于本文所述毛发护理组合物中的有机调理油包括但不限于烷基葡糖苷和烷基葡糖苷衍生物。合适的烷基葡糖苷和烷基葡糖苷衍生物的具体非限制性示例包括可从Amerchol商购获得的Glucam E-10、Glucam E-20、Glucam P-10和Glucquat 125。
g.聚乙二醇
可用于本文作为调理剂的附加化合物包括具有至多约2,000,000的分子量的聚乙二醇和聚丙二醇,诸如CTFA命名为PEG-200、PEG-400、PEG-600、PEG-1000、PEG-2M、PEG-7M、PEG-14M、PEG-45M的那些、以及它们的混合物。
F.机械泡沫分配器
本文所述的机械泡沫分配器可选自由以下项组成的组:挤压泡沫分配器、泵式泡沫分配器、其他机械泡沫分配器以及它们的组合。在一个实施方案中,机械泡沫分配器是挤压泡沫分配器。合适的泵式分配器的非限制性示例包括在WO 2004/078903、WO 2004/078901和WO 2005/078063中描述的那些,并可由阿尔伯特(Albea)(美国康涅狄格州托马斯顿06787,电动大街60号(60 Electric Ave.,Thomaston,CT 06787 USA)供应或雷基包装系统(Rieke Packaging Systems)(印第安纳州奥本46706,西第七街500号(500West SeventhSt.,Auburn,Indiana 46706))。
机械泡沫分配器可包含用于保持毛发护理组合物的贮存器。贮存器可由任何合适的材料制得,所述材料选自塑料、金属、合金、层合体以及它们的组合。贮存器可为可再填充的贮存器,诸如注入型或螺口型贮存器,或者贮存器可以是一次性使用的。贮存器也可从机械式泡沫分配器中取出。另选地,贮存器可与机械式泡沫分配器成一体。在一个实施方案中,可能存在两个或更多个贮存器。
贮存器可由选自刚性材料、柔性材料以及它们的组合的材料组成。当对贮存器施加内部部分真空时,如果其在外部大气压下不塌缩,则贮存器可由刚性材料组成。
G.气溶胶泡沫分配器
气溶胶泡沫分配器可包含用于保持毛发处理组合物的贮存器。贮存器可由任何合适的材料制得,所述材料选自塑料、金属、合金、层合体以及它们的组合。在一个实施方案中,贮存器可用于一次使用。在一个实施方案中,贮存器可从气溶胶泡沫分配器中取出。另选地,贮存器可与气溶胶泡沫分配器成一体。在一个实施方案中,可能存在两个或更多个贮存器。
贮存器可由选自刚性材料、柔性材料以及它们的组合的材料组成。当对贮存器施加内部部分真空时,如果其在外部大气压下不塌缩,则贮存器可由刚性材料组成。
H.发泡剂
本文所述的毛发护理组合物可包含按所述毛发护理组合物的重量计约1%至约10%的推进剂,或者约2%至约9%的推进剂,或者约3%至约8%的推进剂。
发泡剂可包含一种或多种挥发性物质,挥发性物质呈气态,可承载呈颗粒或液滴形式的毛发护理组合物的其他组分。该发泡剂可具有在约-45℃至约5℃范围内的沸点。当在压力下被封装在常规气溶胶容器中时,该发泡剂可被液化。发泡剂在离开气溶胶泡沫分配器时的快速沸腾可有助于毛发护理组合物的其他组分的雾化。
可用于毛发护理组合物中的气溶胶发泡剂可包含化学惰性的烃类诸如丙烷、正丁烷、异丁烷、环丙烷、以及它们的混合物,以及卤代烃类诸如二氯二氟甲烷、1,1-二氯-1,1,2,2-四氟乙烷、1-氯-1,1-二氟-2,2-三氟乙烷、1-氯-1,1-二氟乙烯、1,1-二氟乙烷、二甲基醚、一氯二氟甲烷、反式-1,3,3,3-四氟丙烯、以及它们的混合物。推进剂可包含烃类,诸如异丁烷、丙烷和丁烷,并且这些物质可用于其低臭氧反应性,并且可用作单独的组分,其中它们在21.1℃下的蒸气压在约1.17巴至约7.45巴、或者约1.17巴至约4.83巴、或者约2.14巴至约3.79巴的范围内。发泡剂可为氢氟烯烃(HFOs)。
I.粘度
如本文所定义的在26.5℃下测量,该毛发护理组合物可具有约1厘泊(cP)至500cP,或者约5cP厘泊至约500cP,或者约10cP厘泊至约500cP,或者约20cP至约500厘泊的液相粘度。该粘度通过马萨诸塞州斯托顿市博勒飞工程实验室(Brookfield EngineeringLaboratories,Stoughton,MA)的锥和板控制应力布鲁克菲尔德流变仪R/S Plus测量。使用的锥体(主轴C-75-1)具有75mm的直径和1°的角度。粘度使用稳态流动实验在2s-1的恒定剪切速率,在26.5℃的温度下测定。样品尺寸为2.5ml,并且总测量读数时间为3分钟。
J.香料
毛发护理组合物可包含按所述毛发护理组合物的重量计约0.5%至约7%,或者约1%至约6%,或者约2%至约5%的香料。
该毛发护理组合物可具有约95:5至约50:50,或者约90:10至约60:40,和或者约85:15至约70:30的硅氧烷与香料的重量比。
合适香料的示例可在CTFA(化妆品、盥洗品和芳香剂协会)1992年国际买家指南中提供,其由CFTA出版物和OPD 1993年化学品买家名录第80期年鉴公布,由Schnell出版公司出版。多种香料组分可存在于毛发护理组合物中。
K.任选成分
本文所述毛发调理组合物可任选包含一种或多种已知用于护发或个人护理产品的附加组分,前提条件是该附加组分与本文所述基本组分物理和化学地相容,或不会不适当地损害产品的稳定性、美观性或性能。上述任选成分最典型地为那些被认可用于化妆品中并描述于参考书诸如“CTFA Cosmetic Ingredient Handbook”第二版(The Cosmetic,Toiletries,and Fragrance Association,Inc.1988,1992)中的材料。此类附加组分的各个浓度按所述调理组合物的重量计可在约0.001重量%至约10重量%的范围内。
适于作为本文任选成分的乳化剂包括甘油一酯和甘油二酯、脂肪醇、聚甘油酯、丙二醇酯、脱水山梨糖醇酯、以及已知的或常用于稳定空气界面的其他乳化剂,例如在充气食品如糕饼和其他烤焙物以及蜜饯产品制备期间或在稳定化妆品如毛发摩丝期间使用的那些。
此类任选成分的其它非限制性示例包括防腐剂、香料或芳香剂、阳离子聚合物、粘度调节剂、着色剂或染料、调理剂、毛发漂白剂、增稠剂、保湿剂、发泡剂、附加的表面活性剂或非离子辅助表面活性剂、润肤剂、药物活性物质、维生素或营养物质、防晒剂、除臭剂、感觉剂、植物提取物、营养物质、收敛剂、化妆品颗粒、吸收剂颗粒、粘合剂颗粒、固发剂、纤维、反应剂、亮肤剂、皮肤美黑剂、去头皮屑剂、香料、剥脱剂、酸、碱、保湿剂、酶、悬浮剂、pH调节剂、毛发着色剂、烫发剂、颜料颗粒、抗痤疮剂、抗微生物剂、防晒剂、美黑剂、剥脱颗粒、毛发生长剂或恢复剂、驱虫剂、剃须洗剂、非挥发性溶剂或稀释剂(水溶性和水不溶性)、共溶剂或其它附加溶剂、以及类似的其它材料。
去头皮屑剂的非限制性示例包括一种材料或混合物,所述混合物选自由以下项构成的组:唑类,诸如氯咪巴唑、酮康唑、伊曲康唑、益康唑和新康唑;羟基吡啶酮类化合物,诸如羟甲辛吡酮(羟甲辛吡酮乙醇胺)、环吡酮、利洛吡司和MEA-羟基辛氧基吡啶酮;角质层分离剂,诸如水杨酸和其他羟基酸;甲氧基丙烯酸酯类,诸如嘧菌酯和金属螯合剂,诸如1,10-菲咯啉。在另一个实施方案中,所述唑类抗微生物剂为咪唑,其选自:苯并咪唑、苯并噻唑、联苯苄唑、丁康唑硝酸盐、咪菌酮、克霉唑、克鲁康唑、依柏康唑、益康唑、新康唑、芬替康唑、氟康唑、10氟三唑、异康唑、酮康唑、兰诺康唑、甲硝唑、咪康唑、奈康唑、奥莫康唑、奥昔康唑硝酸盐、舍他康唑、硝酸硫康唑、噻康唑、噻唑、以及它们的混合物,或所述唑类抗微生物剂为三唑,其选自:特康唑、伊曲康唑、以及它们的混合物。在一个实施方案中,唑类抗微生物活性物质为酮康唑。在一个实施方案中,唯一的抗微生物活性物质为酮康唑。
处理毛发的方法
本文所述的处理毛发的方法包括(1)提供如本文所描述的毛发护理组合物,(2)使用机械泡沫分配器或气溶胶泡沫分配器分配为液体形式或泡沫形式的该毛发护理组合物;(3)将该组合物施用到毛发上;以及(4)从毛发上漂洗组合物。该毛发护理组合物可形成稳定的泡沫。当分配至其应用至毛发上的时间,它基本上保持其体积时,泡沫是稳定的。当从气溶胶泡沫分配器分配时,该泡沫可具有约0.03g/mL至约0.35g/mL的密度。泡沫还可具有约0.05g/cm3至约0.35g/cm3、或者约0.08g/cm3至约0.25g/cm3、或者约0.08g/cm3至约0.2g/cm3、或者约0.08g/cm3至约0.18g/cm3、或者约0.08g/cm3至约0.15g/cm3、或者约0.08g/cm3至约0.12g/cm3的泡沫密度;或者约0.1g/cm3至约0.12g/cm3、或者约0.12g/cm3至约0.2g/cm3、或者约0.15g/cm3至约0.2g/cm3。
泡沫密度测定方法
通过将100mL烧杯放置在质量天平上,去除烧杯质量皮重,然后从气溶胶容器分配产品到100ml烧杯中,直至泡沫体积超过容器边缘,来测定泡沫密度。通过刮刀横扫刮擦烧杯的顶部做出泡沫水平。然后将所得的100ml泡沫的质量除以体积(100)以确定以g/ml为单位的泡沫密度。
实施例
以下实施例示出本文所述的毛发护理组合物。示例性的组合物可通过常规制剂和混合技术来制备。应当理解,在不脱离本发明的实质和范围的情况下,毛发护理制剂领域内的技术人员可对本发明进行其它的修改。除非另外指明,否则本文中所有份数、百分比和比率均按重量计。一些组分可作为稀释溶液来自供应商。除非另外指明,否则所示量反映了活性材料的重量百分比。
以下为本文所述的毛发护理组合物的非限制性实施例。
示例和结果
具有低粘度的致密、澄清的毛发护理组合物
比较例
1.月桂基聚氧乙烯醚(1摩尔亚乙基氧)硫酸钠,70%活性物质,供应商:StephanCo
2.十三烷基醚硫酸钠(2摩尔环氧乙烷),Stepan ST2S-65(Steol-TD 402 65)65%活性物质,供应商:Stephan Co
3.Amphosol HCA,得自Stepan Company
4.得自Clariant的羟甲辛吡酮(羟甲辛吡酮乙醇胺)
段落A:稳定的浓缩毛发护理组合物,其包含:
a)约20重量%至约45重量%的总表面活性剂;
c)约6重量%至约30重量%的带有具有烷基链的尾部的支链的阴离子表面活性剂,该基链具有12至18个碳原子;
d)约0.1重量%至约20重量%的带有具有烷基链的尾部的直链的阴离子表面活性剂,该基链具有12至18个碳原子;
e)约2重量%至约12重量%的水混溶性溶剂;和
f)约35重量%至约78重量%的水;
其中该浓缩的毛发护理具有小于约0.2的(直链的阴离子表面活性剂/支链的阴离子表面活性剂)/可混溶溶剂的比率,并且其中该支链的阴离子表面活性剂/可混溶溶剂的比率小于约5,并且其中该浓缩的毛发护理具有在26.5℃下约5至约500cP的粘度。
段落B:段落A的毛发护理组合物,其在26.5℃下具有约1至约500cP的粘度。
段落C:段落A-B所述的毛发护理组合物,其中该组合物还包含约0.1重量%至约10重量%的两性表面活性剂。
段落D:段落A-C所述的毛发护理组合物,其中该毛发护理组合物还包含约0.05至5重量%的硅氧烷调理剂。
段落E:段落A-D所述的毛发护理组合物,其中该硅氧烷调理剂在其分子结构中包含多种季铵盐中的一个。
段落F:段落A-E所述的毛发护理组合物,其中该硅氧烷调理剂为聚二甲基硅氧烷醇微乳液。
段落G:段落A-F所述的毛发护理组合物,其中该毛发护理组合物还包含约0.05重量%至约2重量%的毛发护理组合物的一种或多种阳离子聚合物。
段落H:段落A-G所述的毛发护理组合物,其中该阳离子聚合物的浓度为所述组合物的约0.05至约1重量%。
段落I:段落A-H所述的毛发护理组合物,其中该阳离子聚合物选自由以下项组成的组:瓜尔羟丙基三甲基氯化铵、聚季铵盐-6、聚季铵盐-7、聚季铵盐-10、聚季铵盐-39、聚季铵盐-67、以及它们的混合物。
段落J:段落A-I所述的毛发护理组合物,其中瓜尔羟丙基三甲基氯化铵具有小于约1,000,000g/mol的重均分子量。
段落K:段落A-J所述的毛发护理组合物,其中瓜尔胶羟基丙基三甲基氯化铵具有小于约800,000g/mol的重均分子量。
段落L:段落A-K所述的毛发护理组合物,其中瓜尔胶羟基丙基三甲基氯化铵具有约100,000至约900,000g/m的重均分子量。
段落M:段落A-L所述的毛发护理组合物,其中总表面活性剂含量按重量计约20%至约45%。
段落N:段落A-M所述的毛发护理组合物,其中总表面活性剂含量按重量计约25%至约35%。
段落O:段落A-N所述的毛发护理组合物,其中支链的阴离子表面活性剂选自由以下项组成的组:十三烷基聚氧乙烯醚硫酸钠、十三烷基硫酸钠、C12-13烷基硫酸钠、C12-15烷基硫酸钠、C12-18烷基硫酸钠、C12-13烷基聚氧乙烯醚硫酸钠、C12-13烷基聚氧乙烯醚-n硫酸钠、C12-14烷基聚氧乙烯醚-n硫酸钠、以及它们的组合。
段落P:段落A-O所述的毛发护理组合物,其中直链的阴离子表面活性剂选自由以下项组成的组:月桂基硫酸铵、月桂基聚氧乙烯醚硫酸铵、月桂基硫酸三乙基胺、月桂基聚氧乙烯醚硫酸三乙基胺、月桂基硫酸三乙醇胺、月桂基聚氧乙烯醚硫酸三乙醇胺、月桂基硫酸单乙醇胺、月桂基聚氧乙烯醚硫酸单乙醇胺、月桂基硫酸二乙醇胺、月桂基聚氧乙烯醚硫酸二乙醇胺、月桂酸甘油单酯硫酸钠、月桂基硫酸钠、月桂基聚氧乙烯醚硫酸钠、月桂基聚氧乙烯醚硫酸钾、月桂基肌氨酸钠、月桂酰肌氨酸钠、月桂基肌氨酸、椰油基肌氨酸、椰油基硫酸铵、月桂酰基硫酸铵、椰油基硫酸钠、月桂酰硫酸钠、椰油基硫酸钾、月桂基硫酸钾、椰油酰硫酸单乙醇胺、十三烷基聚氧乙烯醚-1硫酸钠,硫酸盐、十三烷基聚氧乙烯醚-2硫酸钠,硫酸盐、十三烷基聚氧乙烯醚-3硫酸钠、十三烷基硫酸钠、甲基月桂酰牛磺酸钠、甲基椰油基牛磺酸钠、月桂酰羟乙基磺酸钠、椰油基羟乙基磺酸钠、月桂基聚氧乙烯醚磺基琥珀酸钠、月桂基磺基琥珀酸钠、十三烷基苯磺酸钠、十二烷基苯磺酸钠、以及它们的混合物。
段落Q:段落A-P所述的毛发护理组合物,其中该毛发护理组合物还包含约0.5至7重量%的香料。
段落R:稳定的浓缩毛发护理组合物,其包含:
a)约20重量%至约45重量%的总表面活性剂;
b)约6重量%至约30重量%的带有具有烷基链的尾部的支链的阴离子表面活性剂,该基链具有12个碳原子或更高;
c)约2重量%至约12重量%的水混溶性溶剂;和
d)约35重量%至约78重量%的水;
并且其中支链的阴离子表面活性剂/可混溶溶剂的比率小于约5,并且其中浓缩的毛发护理具有在26.5℃下小于500cP的粘度,并且其中组合物具有约0重量%的带有具有烷基链的尾部的直链的阴离子表面活性剂,该烷基链具有12至18个碳原子。
段落S:段落A-R所述的毛发护理组合物,其中所述组合物在26.5℃下具有约10至约500cP的粘度。
本文所公开的量纲和值不应理解为严格限于所引用的精确数值。相反,除非另外指明,否则每个此类量纲旨在表示所述值以及围绕该值功能上等同的范围。例如,公开为“40mm”的量纲旨在表示“约40mm”。
除非明确排除或以其它方式限制,本文中引用的每一篇文献,包括任何交叉引用或相关专利或专利申请以及本申请对其要求优先权或其有益效果的任何专利申请或专利,均据此全文以引用方式并入本文。对任何文献的引用不是对其作为与本发明的任何所公开或本文受权利要求书保护的现有技术的认可,或不是对其自身或与任何一个或多个参考文献的组合提出、建议或公开任何此类发明的认可。此外,当本发明中术语的任何含义或定义与以引用方式并入的文献中相同术语的任何含义或定义矛盾时,应当服从在本发明中赋予该术语的含义或定义。
虽然已举例说明和描述了本发明的具体实施方案,但是对于本领域技术人员来说显而易见的是,在不脱离本发明的实质和范围的情况下可作出多个其它变化和修改。因此,本文旨在于所附权利要求中涵盖属于本发明范围内的所有此类变化和修改。
Claims (15)
1.一种稳定的浓缩毛发护理组合物,包含:
a)约20重量%至约45重量%的总表面活性剂;
b)约6重量%至约30重量%的带有具有烷基链的尾部的支链的阴离子表面活性剂,所述烷基链具有12至18个碳原子;
c)约0.1重量%至约20重量%的带有具有烷基链的尾部的直链的阴离子表面活性剂,所述烷基链具有12至18个碳原子;
d)约2重量%至约12重量%的水混溶性溶剂;和
e)约35重量%至约78重量%的水;
其中所述浓缩的毛发护理具有小于约0.2的(直链的阴离子表面活性剂/支链的阴离子表面活性剂)/可混溶溶剂的比率,并且其中该支链的阴离子表面活性剂/可混溶溶剂的所述比率小于约5,并且其中所述浓缩的毛发护理具有在26.5℃下小于500cP的粘度。
2.根据前述权利要求中任一项所述的毛发护理组合物,在26.5℃下具有约1cP至约500cP的粘度,优选地其中所述组合物在26.5℃下具有约5cP至约500cP的粘度,更优选其中所述组合物在26.5℃下具有约10cP至约500cP的粘度。
3.根据前述权利要求中任一项所述的毛发护理组合物,其中所述组合物还包含约0.1重量%至约10重量%的两性表面活性剂。
4.根据前述权利要求中任一项所述的毛发护理组合物,其中所述毛发护理组合物还包含约0.05重量%至5重量%的硅氧烷调理剂。
5.根据前述权利要求中任一项所述的毛发护理组合物,其中所述硅氧烷调理剂在其分子结构中包含多种季铵盐中的一种。
6.根据前述权利要求中任一项所述的毛发调理组合物,其中所述硅氧烷调理剂为聚二甲基硅氧烷醇微乳液。
7.根据前述权利要求中任一项所述的毛发护理组合物,其中所述组合物还包含约0.1重量%至约5重量%的一种或多种去头皮屑活性物质,优选地其中所述去头皮屑活性物质选自包含以下的组:羟甲辛吡酮乙醇胺、氯咪巴唑和水杨酸以及它们的混合物。
8.根据前述权利要求中任一项所述的毛发护理组合物,其中所述毛发护理组合物还包含所述毛发护理组合物的约0.05重量%至约2重量%的一种或多种阳离子聚合物,优选地其中所述阳离子聚合物选自由以下项组成的组:瓜尔羟丙基三甲基氯化铵、聚季铵盐-6、聚季铵盐-7、聚季铵盐-10、聚季铵盐-39、聚季铵盐-67、以及它们的混合物。
9.根据前述权利要求中任一项所述的毛发护理组合物,其中所述瓜尔羟丙基三甲基氯化铵具有约100,000g/m至约2,000,000g/m的重均分子量和约0.2meg/g至约2.2meg/g的电荷密度。
10.根据前述权利要求中任一项所述的毛发护理组合物,其中所述总表面活性剂含量按重量计为约20%至约45%,优选地其中所述总表面活性剂含量按重量计为约25%至约35%。
11.根据前述权利要求中任一项所述的毛发护理组合物,其中所述支链的阴离子表面活性剂选自由以下项组成的组:十三烷基聚氧乙烯醚硫酸钠、十三烷基硫酸钠、C12-13烷基硫酸钠、C12-15烷基硫酸钠、C12-18烷基硫酸钠、C12-13烷基聚氧乙烯醚硫酸钠、C12-13烷基聚氧乙烯醚-n硫酸钠、C12-14烷基聚氧乙烯醚-n硫酸钠、以及它们的组合。
12.根据前述权利要求中任一项所述的毛发护理组合物,其中所述直链的阴离子表面活性剂选自由以下项组成的组:月桂基硫酸铵、月桂基聚氧乙烯醚硫酸铵、月桂基硫酸三乙基胺、月桂基聚氧乙烯醚硫酸三乙基胺、月桂基硫酸三乙醇胺、月桂基聚氧乙烯醚硫酸三乙醇胺、月桂基硫酸单乙醇胺、月桂基聚氧乙烯醚硫酸单乙醇胺、月桂基硫酸二乙醇胺、月桂基聚氧乙烯醚硫酸二乙醇胺、月桂酸甘油单酯硫酸钠、月桂基硫酸钠、月桂基聚氧乙烯醚硫酸钠、月桂基聚氧乙烯醚硫酸钾、月桂基肌氨酸钠、月桂酰肌氨酸钠、月桂基肌氨酸、椰油基肌氨酸、椰油基硫酸铵、月桂酰基硫酸铵、椰油基硫酸钠、月桂酰硫酸钠、椰油基硫酸钾、月桂基硫酸钾、椰油酰硫酸单乙醇胺、十三烷基聚氧乙烯醚-1硫酸钠,硫酸盐、十三烷基聚氧乙烯醚-2硫酸钠,硫酸盐、十三烷基聚氧乙烯醚-3硫酸钠、十三烷基硫酸钠、甲基月桂酰牛磺酸钠、甲基椰油基牛磺酸钠、月桂酰羟乙基磺酸钠、椰油基羟乙基磺酸钠、月桂基聚氧乙烯醚磺基琥珀酸钠、月桂基磺基琥珀酸钠、十三烷基苯磺酸钠、十二烷基苯磺酸钠、以及它们的混合物。
13.根据前述权利要求中任一项所述的毛发护理组合物,其中所述直链的阴离子表面活性剂选自由以下项组成的组:酰基羟乙基磺酸盐、酰基甲基羟乙基磺酸盐、酰基谷氨酸盐、酰基甘氨酸盐、酰基肌氨酸盐、酰基丙氨酸盐、酰基牛磺酸盐、磺基琥珀酸盐、烷基苯磺酸盐、烷基醚羧酸盐、烷基两性基乙酸盐、α-烯烃磺酸盐、以及它们的混合物。此类合适的阴离子表面活性剂的示例包括但不限于椰油基羟乙基磺酸钠、月桂酰羟乙基磺酸钠、月桂酰甲基羟乙基磺酸钠、椰油基谷氨酸钠、椰油基谷氨酸二钠、月桂酰谷氨酸钠、月桂酰谷氨酸二钠、椰油基丙氨酸钠、月桂酰丙氨酸钠、月桂酰甘氨酸钠、椰油基甘氨酸钠、月桂基聚氧乙烯醚磺基琥珀酸钠、月桂基聚氧乙烯醚磺基琥珀酸二钠、月桂基磺基琥珀酸钠、月桂基磺基琥珀酸二钠、月桂基葡萄糖羧酸钠、椰油基葡萄糖羧酸钠、椰油两性乙酸钠、月桂酰两性乙酸钠、甲基椰油基牛磺酸钠、以及它们的混合物。
14.根据前述权利要求中任一项所述的毛发护理组合物,其中所述毛发护理组合物还包含约0.5重量%至7重量%的香料。
15.一种稳定的浓缩毛发护理组合物,包含:
a)约20重量%至约45重量%的总表面活性剂;
b)约6重量%至约30重量%的带有具有烷基链的尾部的支链的阴离子表面活性剂,所述烷基链具有12个碳原子或更高;
c)约2重量%至约12重量%的水混溶性溶剂;和
d)约35重量%至约78重量%的水;
并且其中所述支链的阴离子表面活性剂/可混溶溶剂的比率小于约5,并且其中所述浓缩的毛发护理在26.5℃下具有小于500cP、优选地在26.5℃下约5cP至约500cP的粘度,并且其中所述组合物具有约0重量%的带有具有烷基链的尾部的直链的阴离子表面活性剂,所述烷基链具有12至18个碳原子。
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