A kind of multifunctional bio mechanics collection of energy textile and its preparation method and application
Technical field
The invention belongs to the wearable energy and its preparation and application field, in particular to a kind of multifunctional bio mechanics energy
Collect textile and its preparation method and application.
Background technique
The fast development of wearable electronic product is causing the change of human society life, and people are to the wearable energy
Demand increasingly increases.However, traditional rechargeable battery is since its capacity is limited, flexibility is poor, tensility is poor and biological
Poor compatibility and being difficult to meet wearable electronic Lightness, flexibility and in terms of requirement.Therefore, it can hold
Continuous and self-contained electric system exploitation is very important for wearable electronic.Biomethanics energy is that the mankind are daily
One of most common and the most abundant mechanical energy that can produce, the biomethanics energy that waste is collected from human motion facilitate
Solve wearable electronic demand in terms of the energy.
The final goal of wearable electronic product first is that combined with textile and clothing, make electronic equipment that there is fabric
The advantages of, such as softness, gas permeability, comfort, safety and sustainability.The appearance of friction nanometer generating technology is to realize to wear
The combination of wearing electronic product and fabric provides a kind of method that height is feasible, economical and practical.However, existing for collecting life
The output performance of the friction electric equipment of material resources energy still have it is to be hoisted, as using polyimides and copper as friction material
It rubs nanometer generating textile (Adv.Mater.2016,28,10267-10274) and is sent out using the mixing nanometer of different mechanical energy
Motor (ACS Nano 2014,8,10674-10681).In order to realize sustainable and self-powered application, it is necessary to develop large area
Wearable energy gathering devices, to extract energy from human motion.
Summary of the invention
Technical problem to be solved by the invention is to provide a kind of multifunctional bio mechanics collection of energy textile and its systems
Preparation Method and application, to overcome the defect lacked in the prior art for collecting the friction electric equipment of biomethanics energy.
A kind of preparation method of multifunctional bio mechanics collection of energy textile of the invention, comprising:
(1) modified Modacrylic fibers and conductive yarn plying, twisting are obtained into primary helix yarn, then will be at the beginning of two
Grade yarn helix plying, twisting obtain multiple coil yarn;
(2) conductive yarn is inserted into rubber tube, stretches rubber tube, utilizes the frictional force between rubber tube and conductive yarn
And the compressing force of rubber tube terminal, so that serpentine configuration is presented in conductive yarn in rubber tube, then seal rubber pipe both ends,
Obtain the electric yarn that rubs;
(3) electric yarn is rubbed using multiple coil yarn in step (1) as warp thread, in step (2) as weft yarn, is carried out flat
Line braiding, obtains multifunctional bio mechanics collection of energy textile.
Modified Modacrylic fibers surface can be lower in the step (1), and hydrophobicity is preferable.
The twist of primary helix yarn is 400-800 twirl/m in the step (1);The twist of multiple coil yarn is 300-
600 twirls/m.
It is twisted twice in the step (1) contrary.
Seal rubber pipe both ends are using bi-component epoxide-resin glue in the step (2).
Conductive yarn is as friction positive electrode and electrode material in the step (2), and rubber tube is as friction cathode material
Material and hydrophobic material, serpentine configuration to rub electric yarn with excellent tensile property.
Plain weave in the step (3) are as follows: plain weave is carried out using braider, firstly, the position of adjustment heald frame, and
Parameter is set on clipboard screen;Then, the multiple coil yarn after warpage is fixed on to the rear portion of heald frame using thread-carrier rod;
Finally, be incorporated into the electric yarn of friction with interweaving on multiple coil yarn, and warp thread and latitude are adjusted by the back rest in the weaving process
The tension of yarn.
The operating air pressure of the braider is 0.4-0.6MPa, and sorting amount per minute is 50-70 times.
The curve height of the electric yarn of friction is equal to zero in the step (3), and the curve height of multiple coil yarn, which is equal to, to rub
Wipe the sum of the diameter of electric yarn and multiple coil yarn.
In the step (3) there are two types of the generation modes of multifunctional bio mechanics collection of energy textile, first is that utilizing warp
The contact separation of yarn and weft yarn and produce electricl energy, second is that the contact point using the conductive yarn for the electric yarn interior that rubs with rubber tube
From and produce electricl energy.
Multifunctional bio mechanics collection of energy textile has two kinds of operating modes of stretching and compression in the step (3), often
Kind operating mode includes following four circuit connection mode: being connected single electrode mode, latitude connects single electrode mode, and longitude and latitude connects
Order electrode mode and bipolar electrode mode.
The present invention provides a kind of multifunctional bio mechanics collection of energy textile of above method preparation.
The present invention also provides a kind of applications of the multifunctional bio mechanics collection of energy textile of above method preparation.Example
Such as, it is power electronic equipment, or can be used as the energy and sensor of self-power wireless monitoring system.
The present invention relies on Weaving device, has carried out serialization braiding to multiple coil yarn and the electric yarn that rubs, has realized
The integrated design of textile and energy device.
Beneficial effect
(1) manufacture craft of the present invention is simple, and material therefor is business raw material cheap and easy to get;
(2) the collection of energy textile that the present invention is prepared has excellent tensile property, can satisfy the big of human body
Amplitude deformation;
(3) the collection of energy textile that the present invention is prepared has excellent hydrophobic performance;
(4) the collection of energy textile that the present invention is prepared can be power electronic equipment, can also be used as self-powered
The energy and sensor of wireless monitor system.
Detailed description of the invention
Fig. 1 is the preparation flow figure of collection of energy textile of the present invention;
Fig. 2 is the water contact angle photo of rubber tube in embodiment 1;
Fig. 3 is the optical photograph (a) and water contact angle photo (b) of modified polyacrylonitrile yarn in embodiment 1;
Fig. 4 is the photo that collection of energy textile stretches front and back in embodiment 1;
Fig. 5 is two kinds of operating modes (i-iii) of collection of energy textile and four kinds of circuit connection modes in embodiment 1
(a-d);
Fig. 6 is operation machine of the collection of energy textile during stretching in embodiment 1 in the case where longitude and latitude connects single electrode mode
Reason figure;
Fig. 7 is the photo that collection of energy textile is electronic watch power supply in embodiment 1;
Fig. 8 is the collection of energy schematic diagram used for textiles in wireless monitor system in embodiment 1;
Fig. 9 is output electricity of the collection of energy textile during stretching in embodiment 1 in the case where longitude and latitude connects single electrode mode
Pressure;
Figure 10 is output of the collection of energy textile during stretching in embodiment 2 in the case where longitude and latitude connects single electrode mode
Voltage;
Figure 11 is output of the collection of energy textile during stretching in embodiment 3 in the case where longitude and latitude connects single electrode mode
Voltage.
Specific embodiment
Present invention will be further explained below with reference to specific examples.It should be understood that these embodiments are merely to illustrate the present invention
Rather than it limits the scope of the invention.In addition, it should also be understood that, after reading the content taught by the present invention, those skilled in the art
Member can make various changes or modifications the present invention, and such equivalent forms equally fall within the application the appended claims and limited
Range.
Embodiment 1
(1) Modacrylic fibers of silicon fluoride graft modification and conductive yarn plying, twisting are obtained into 800 twirls/m primary
Yarn helix, then two primary helix yarn plying, twisting are obtained into 600 twirls/m multiple coil yarn, the side twisted twice
To opposite.
(2) conductive yarn is inserted into rubber tube, stretches rubber tube, utilizes the frictional force between rubber tube and conductive yarn
And then the compressing force of rubber tube terminal uses bi-component epoxy so that serpentine configuration is presented in conductive yarn in rubber tube
Resin glue seal rubber pipe both ends, obtain the electric yarn that rubs.
(3) electric yarn is rubbed using multiple coil yarn in step (1) as warp thread, in step (2) as weft yarn, uses volume
Loom carries out plain weave.Firstly, the position of adjustment heald frame, and parameter is set on clipboard screen, operating air pressure is set as
0.6MPa, sorting amount per minute are set as 70 times;Then, the multiple coil yarn after warpage is fixed on using thread-carrier rod comprehensive
The rear portion of frame;Finally, be incorporated into the electric yarn of friction with interweaving on multiple coil yarn, and adjusted in the weaving process by the back rest
The tension of warp thread and weft yarn, to obtain collection of energy textile.
Fig. 2 shows: rubber tube has preferable hydrophobicity.
Fig. 3 shows: modified polyacrylonitrile yarn has preferable hydrophobicity.
Fig. 4 shows: collection of energy textile has good tensile property.
Fig. 6 shows: original state each frictional layer contact is good, and electronics is from friction positive electrode to friction negative electrode material surface
Transfer;Frictional layer is initially separated under tensional state, generates positive charge trap on the electrode, and electronics flows to electricity through external circuit from the earth
Pole;Frictional layer is contacted again under retracted state, and extra electronics flows back to the earth on electrode.
Fig. 8 shows: collection of energy textile had both been used as the energy to charge to lithium battery, also as sensor monitoring human body fortune
It is dynamic.
Fig. 9 shows: when the twist of multiple coil yarn is larger, yarn is tightly combined, the output of energy collection textile
It can be higher.
Embodiment 2
It is changed to " obtain the primary spiral shell of 600 twirls/m by " 800 twirls/m primary helix yarn is obtained " in 1 step of embodiment (1)
Revolve yarn ", " obtaining 600 twirls/m multiple coil yarn " is changed to " obtaining 450 twirls/m multiple coil yarn ", by step (2)
In " operating air pressure is set as 0.6MPa, and sorting amount per minute is set as 70 times " be changed to that " operating air pressure is set as 0.5MPa, often
The sorting amount of minute is set as 60 times ", remaining is same as Example 1, obtains collection of energy textile.
Figure 10 shows: the twist of multiple coil yarn reduces, and the output performance of energy collection textile reduces.
Embodiment 3
It is changed to " obtain the primary spiral shell of 400 twirls/m by " 800 twirls/m primary helix yarn is obtained " in 1 step of embodiment (1)
Yarn is revolved, " obtaining 600 twirls/m multiple coil yarn " is changed to " obtaining 300 twirls/m multiple coil yarn ", will be in step (2)
" operating air pressure is set as 0.6MPa, and sorting amount per minute is set as 70 times " be changed to " operating air pressure is set as 0.4MPa, every point
The sorting amount of clock is set as 50 times, remaining is same as Example 1, obtains collection of energy textile.
Figure 11 shows: as the twist of multiple coil yarn reduces, yarn, which combines, becomes loose, energy collection textile
Output performance reduces.
Comparative example 1
The researcher of Peking University deposits copper respectively on spun polyester thread and polyimides obtain friction positive electrode and
Rub negative electrode material, and using the positive electrode that rubs as warp thread, for the negative electrode material that rubs as weft yarn, braiding obtains friction nanometer generating
Textile (Adv.Mater.2016,28,10267-10274).Since the separating distance of the friction nanometer generating textile is smaller
And yarn combination is not close, leading to its maximum output voltage is only 5 volts, this is much smaller than collection of energy textile in the present invention
Close to 20 volts of output voltage.In addition, the tensile property of the friction nanometer generating textile is poor, almost compared with the present invention
It is difficult to stretch.