CN108977240A - A kind of energy-saving environmental-protection petrol additive and preparation method thereof - Google Patents
A kind of energy-saving environmental-protection petrol additive and preparation method thereof Download PDFInfo
- Publication number
- CN108977240A CN108977240A CN201810941194.3A CN201810941194A CN108977240A CN 108977240 A CN108977240 A CN 108977240A CN 201810941194 A CN201810941194 A CN 201810941194A CN 108977240 A CN108977240 A CN 108977240A
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- parts
- energy
- additive
- saving environmental
- acid
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- 239000000654 additive Substances 0.000 title claims abstract description 47
- 230000000996 additive effect Effects 0.000 title claims abstract description 45
- 238000002360 preparation method Methods 0.000 title claims abstract description 10
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 claims abstract description 57
- -1 isooctyl Chemical group 0.000 claims abstract description 57
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims abstract description 51
- 239000003112 inhibitor Substances 0.000 claims abstract description 41
- BZLVMXJERCGZMT-UHFFFAOYSA-N Methyl tert-butyl ether Chemical compound COC(C)(C)C BZLVMXJERCGZMT-UHFFFAOYSA-N 0.000 claims abstract description 38
- 229940051841 polyoxyethylene ether Drugs 0.000 claims abstract description 33
- 229920000056 polyoxyethylene ether Polymers 0.000 claims abstract description 33
- 239000000203 mixture Substances 0.000 claims abstract description 31
- 238000002485 combustion reaction Methods 0.000 claims abstract description 30
- 229910052746 lanthanum Inorganic materials 0.000 claims abstract description 29
- FZLIPJUXYLNCLC-UHFFFAOYSA-N lanthanum atom Chemical compound [La] FZLIPJUXYLNCLC-UHFFFAOYSA-N 0.000 claims abstract description 29
- 239000002904 solvent Substances 0.000 claims abstract description 25
- 150000004702 methyl esters Chemical class 0.000 claims abstract description 23
- 239000002671 adjuvant Substances 0.000 claims abstract description 22
- 239000007866 anti-wear additive Substances 0.000 claims abstract description 22
- 238000005260 corrosion Methods 0.000 claims abstract description 22
- 230000007797 corrosion Effects 0.000 claims abstract description 22
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 claims abstract description 21
- 239000002253 acid Substances 0.000 claims abstract description 20
- 150000002148 esters Chemical class 0.000 claims abstract description 20
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims abstract description 20
- RSWGJHLUYNHPMX-UHFFFAOYSA-N Abietic-Saeure Natural products C12CCC(C(C)C)=CC2=CCC2C1(C)CCCC2(C)C(O)=O RSWGJHLUYNHPMX-UHFFFAOYSA-N 0.000 claims abstract description 19
- 241000237858 Gastropoda Species 0.000 claims abstract description 19
- 229910002651 NO3 Inorganic materials 0.000 claims abstract description 19
- NHNBFGGVMKEFGY-UHFFFAOYSA-N Nitrate Chemical compound [O-][N+]([O-])=O NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 claims abstract description 19
- KHPCPRHQVVSZAH-HUOMCSJISA-N Rosin Natural products O(C/C=C/c1ccccc1)[C@H]1[C@H](O)[C@@H](O)[C@@H](O)[C@@H](CO)O1 KHPCPRHQVVSZAH-HUOMCSJISA-N 0.000 claims abstract description 19
- IEJIGPNLZYLLBP-UHFFFAOYSA-N dimethyl carbonate Chemical compound COC(=O)OC IEJIGPNLZYLLBP-UHFFFAOYSA-N 0.000 claims abstract description 19
- 229920001971 elastomer Polymers 0.000 claims abstract description 19
- 239000005060 rubber Substances 0.000 claims abstract description 19
- 239000003381 stabilizer Substances 0.000 claims abstract description 19
- 230000008961 swelling Effects 0.000 claims abstract description 19
- KHPCPRHQVVSZAH-UHFFFAOYSA-N trans-cinnamyl beta-D-glucopyranoside Natural products OC1C(O)C(O)C(CO)OC1OCC=CC1=CC=CC=C1 KHPCPRHQVVSZAH-UHFFFAOYSA-N 0.000 claims abstract description 19
- WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 claims abstract description 18
- LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 claims abstract description 18
- QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Natural products CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 claims abstract description 18
- 240000001548 Camellia japonica Species 0.000 claims abstract description 18
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 claims abstract description 18
- 239000005642 Oleic acid Substances 0.000 claims abstract description 18
- ZQPPMHVWECSIRJ-UHFFFAOYSA-N Oleic acid Natural products CCCCCCCCC=CCCCCCCCC(O)=O ZQPPMHVWECSIRJ-UHFFFAOYSA-N 0.000 claims abstract description 18
- 235000019482 Palm oil Nutrition 0.000 claims abstract description 18
- 235000018597 common camellia Nutrition 0.000 claims abstract description 18
- 239000002270 dispersing agent Substances 0.000 claims abstract description 18
- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 claims abstract description 18
- 229910052748 manganese Inorganic materials 0.000 claims abstract description 18
- 239000011572 manganese Substances 0.000 claims abstract description 18
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 claims abstract description 18
- 239000002540 palm oil Substances 0.000 claims abstract description 18
- 235000015112 vegetable and seed oil Nutrition 0.000 claims abstract description 18
- LQZZUXJYWNFBMV-UHFFFAOYSA-N dodecan-1-ol Chemical class CCCCCCCCCCCCO LQZZUXJYWNFBMV-UHFFFAOYSA-N 0.000 claims abstract description 15
- ILRSCQWREDREME-UHFFFAOYSA-N dodecanamide Chemical compound CCCCCCCCCCCC(N)=O ILRSCQWREDREME-UHFFFAOYSA-N 0.000 claims abstract description 15
- LZZYPRNAOMGNLH-UHFFFAOYSA-M Cetrimonium bromide Chemical compound [Br-].CCCCCCCCCCCCCCCC[N+](C)(C)C LZZYPRNAOMGNLH-UHFFFAOYSA-M 0.000 claims abstract description 7
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 18
- 239000003502 gasoline Substances 0.000 claims description 12
- 239000003795 chemical substances by application Substances 0.000 claims description 8
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 claims description 7
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 claims description 7
- VBICKXHEKHSIBG-UHFFFAOYSA-N 1-monostearoylglycerol Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCC(O)CO VBICKXHEKHSIBG-UHFFFAOYSA-N 0.000 claims description 6
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 claims description 6
- POULHZVOKOAJMA-UHFFFAOYSA-N dodecanoic acid Chemical compound CCCCCCCCCCCC(O)=O POULHZVOKOAJMA-UHFFFAOYSA-N 0.000 claims description 6
- MMXKVMNBHPAILY-UHFFFAOYSA-N ethyl laurate Chemical compound CCCCCCCCCCCC(=O)OCC MMXKVMNBHPAILY-UHFFFAOYSA-N 0.000 claims description 6
- 239000000706 filtrate Substances 0.000 claims description 6
- IGUXCTSQIGAGSV-UHFFFAOYSA-K indium(iii) hydroxide Chemical compound [OH-].[OH-].[OH-].[In+3] IGUXCTSQIGAGSV-UHFFFAOYSA-K 0.000 claims description 6
- ZXEKIIBDNHEJCQ-UHFFFAOYSA-N isobutanol Chemical group CC(C)CO ZXEKIIBDNHEJCQ-UHFFFAOYSA-N 0.000 claims description 6
- ANBZTKMYPDMODS-YPKPFQOOSA-N (z)-n,n-diethyloctadec-9-enamide Chemical compound CCCCCCCC\C=C/CCCCCCCC(=O)N(CC)CC ANBZTKMYPDMODS-YPKPFQOOSA-N 0.000 claims description 5
- ZAFNJMIOTHYJRJ-UHFFFAOYSA-N Diisopropyl ether Chemical compound CC(C)OC(C)C ZAFNJMIOTHYJRJ-UHFFFAOYSA-N 0.000 claims description 4
- GHVNFZFCNZKVNT-UHFFFAOYSA-N decanoic acid Chemical group CCCCCCCCCC(O)=O GHVNFZFCNZKVNT-UHFFFAOYSA-N 0.000 claims description 4
- QMMJWQMCMRUYTG-UHFFFAOYSA-N 1,2,4,5-tetrachloro-3-(trifluoromethyl)benzene Chemical compound FC(F)(F)C1=C(Cl)C(Cl)=CC(Cl)=C1Cl QMMJWQMCMRUYTG-UHFFFAOYSA-N 0.000 claims description 3
- VILCJCGEZXAXTO-UHFFFAOYSA-N 2,2,2-tetramine Chemical compound NCCNCCNCCN VILCJCGEZXAXTO-UHFFFAOYSA-N 0.000 claims description 3
- FEWJPZIEWOKRBE-JCYAYHJZSA-N Dextrotartaric acid Chemical compound OC(=O)[C@H](O)[C@@H](O)C(O)=O FEWJPZIEWOKRBE-JCYAYHJZSA-N 0.000 claims description 3
- 239000002202 Polyethylene glycol Substances 0.000 claims description 3
- 229920001214 Polysorbate 60 Polymers 0.000 claims description 3
- FEWJPZIEWOKRBE-UHFFFAOYSA-N Tartaric acid Natural products [H+].[H+].[O-]C(=O)C(O)C(O)C([O-])=O FEWJPZIEWOKRBE-UHFFFAOYSA-N 0.000 claims description 3
- 150000001408 amides Chemical class 0.000 claims description 3
- ZRNCNTSXSYXHOW-UHFFFAOYSA-N butyl decanoate Chemical compound CCCCCCCCCC(=O)OCCCC ZRNCNTSXSYXHOW-UHFFFAOYSA-N 0.000 claims description 3
- JRBPAEWTRLWTQC-UHFFFAOYSA-N dodecylamine Chemical compound CCCCCCCCCCCCN JRBPAEWTRLWTQC-UHFFFAOYSA-N 0.000 claims description 3
- 229940075507 glyceryl monostearate Drugs 0.000 claims description 3
- 239000001788 mono and diglycerides of fatty acids Substances 0.000 claims description 3
- 230000010355 oscillation Effects 0.000 claims description 3
- 229920001223 polyethylene glycol Polymers 0.000 claims description 3
- 239000001818 polyoxyethylene sorbitan monostearate Substances 0.000 claims description 3
- 235000010989 polyoxyethylene sorbitan monostearate Nutrition 0.000 claims description 3
- 229940113124 polysorbate 60 Drugs 0.000 claims description 3
- JEXVQSWXXUJEMA-UHFFFAOYSA-N pyrazol-3-one Chemical compound O=C1C=CN=N1 JEXVQSWXXUJEMA-UHFFFAOYSA-N 0.000 claims description 3
- 235000019832 sodium triphosphate Nutrition 0.000 claims description 3
- 238000003756 stirring Methods 0.000 claims description 3
- 239000011975 tartaric acid Substances 0.000 claims description 3
- 235000002906 tartaric acid Nutrition 0.000 claims description 3
- 229960001124 trientine Drugs 0.000 claims description 3
- 238000002604 ultrasonography Methods 0.000 claims description 3
- 239000005632 Capric acid (CAS 334-48-5) Substances 0.000 claims description 2
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 claims description 2
- BAECOWNUKCLBPZ-HIUWNOOHSA-N Triolein Natural products O([C@H](OCC(=O)CCCCCCC/C=C\CCCCCCCC)COC(=O)CCCCCCC/C=C\CCCCCCCC)C(=O)CCCCCCC/C=C\CCCCCCCC BAECOWNUKCLBPZ-HIUWNOOHSA-N 0.000 claims description 2
- PHYFQTYBJUILEZ-UHFFFAOYSA-N Trioleoylglycerol Natural products CCCCCCCCC=CCCCCCCCC(=O)OCC(OC(=O)CCCCCCCC=CCCCCCCCC)COC(=O)CCCCCCCC=CCCCCCCCC PHYFQTYBJUILEZ-UHFFFAOYSA-N 0.000 claims description 2
- PHYFQTYBJUILEZ-IUPFWZBJSA-N triolein Chemical compound CCCCCCCC\C=C/CCCCCCCC(=O)OCC(OC(=O)CCCCCCC\C=C/CCCCCCCC)COC(=O)CCCCCCC\C=C/CCCCCCCC PHYFQTYBJUILEZ-IUPFWZBJSA-N 0.000 claims description 2
- 235000005979 Citrus limon Nutrition 0.000 claims 1
- 244000131522 Citrus pyriformis Species 0.000 claims 1
- 239000005977 Ethylene Substances 0.000 claims 1
- 240000007594 Oryza sativa Species 0.000 claims 1
- 235000007164 Oryza sativa Nutrition 0.000 claims 1
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 claims 1
- 125000000217 alkyl group Chemical group 0.000 claims 1
- 235000019864 coconut oil Nutrition 0.000 claims 1
- 239000003240 coconut oil Substances 0.000 claims 1
- 235000014113 dietary fatty acids Nutrition 0.000 claims 1
- MJEMIOXXNCZZFK-UHFFFAOYSA-N ethylone Chemical compound CCNC(C)C(=O)C1=CC=C2OCOC2=C1 MJEMIOXXNCZZFK-UHFFFAOYSA-N 0.000 claims 1
- 239000000194 fatty acid Substances 0.000 claims 1
- 229930195729 fatty acid Natural products 0.000 claims 1
- FQPSGWSUVKBHSU-UHFFFAOYSA-N methacrylamide Chemical compound CC(=C)C(N)=O FQPSGWSUVKBHSU-UHFFFAOYSA-N 0.000 claims 1
- 235000009566 rice Nutrition 0.000 claims 1
- 239000000295 fuel oil Substances 0.000 abstract description 11
- 239000000446 fuel Substances 0.000 abstract description 5
- 230000008901 benefit Effects 0.000 abstract description 4
- 239000003254 gasoline additive Substances 0.000 description 16
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 12
- 230000031709 bromination Effects 0.000 description 12
- 238000005893 bromination reaction Methods 0.000 description 12
- 125000000913 palmityl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 12
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 6
- 238000000034 method Methods 0.000 description 5
- 239000006185 dispersion Substances 0.000 description 4
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 3
- 150000001336 alkenes Chemical class 0.000 description 3
- 239000002283 diesel fuel Substances 0.000 description 3
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- 244000060011 Cocos nucifera Species 0.000 description 2
- 235000013162 Cocos nucifera Nutrition 0.000 description 2
- 244000147568 Laurus nobilis Species 0.000 description 2
- 235000017858 Laurus nobilis Nutrition 0.000 description 2
- 229920002367 Polyisobutene Polymers 0.000 description 2
- 235000005212 Terminalia tomentosa Nutrition 0.000 description 2
- 238000006471 dimerization reaction Methods 0.000 description 2
- 238000004134 energy conservation Methods 0.000 description 2
- 150000002193 fatty amides Chemical class 0.000 description 2
- 239000003747 fuel oil additive Substances 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- JGHZJRVDZXSNKQ-UHFFFAOYSA-N methyl octanoate Chemical compound CCCCCCCC(=O)OC JGHZJRVDZXSNKQ-UHFFFAOYSA-N 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 239000003921 oil Substances 0.000 description 2
- 235000019198 oils Nutrition 0.000 description 2
- 239000000047 product Substances 0.000 description 2
- 238000011160 research Methods 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 239000004215 Carbon black (E152) Substances 0.000 description 1
- 150000003851 azoles Chemical class 0.000 description 1
- 239000003225 biodiesel Substances 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 125000002915 carbonyl group Chemical group [*:2]C([*:1])=O 0.000 description 1
- 239000003245 coal Substances 0.000 description 1
- 238000004939 coking Methods 0.000 description 1
- 239000000084 colloidal system Substances 0.000 description 1
- 239000010779 crude oil Substances 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000004945 emulsification Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 239000013067 intermediate product Substances 0.000 description 1
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 230000000505 pernicious effect Effects 0.000 description 1
- 230000035484 reaction time Effects 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- 230000002195 synergetic effect Effects 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- 239000002341 toxic gas Substances 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L1/00—Liquid carbonaceous fuels
- C10L1/10—Liquid carbonaceous fuels containing additives
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L1/00—Liquid carbonaceous fuels
- C10L1/04—Liquid carbonaceous fuels essentially based on blends of hydrocarbons
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L10/00—Use of additives to fuels or fires for particular purposes
- C10L10/04—Use of additives to fuels or fires for particular purposes for minimising corrosion or incrustation
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L10/00—Use of additives to fuels or fires for particular purposes
- C10L10/18—Use of additives to fuels or fires for particular purposes use of detergents or dispersants for purposes not provided for in groups C10L10/02 - C10L10/16
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L1/00—Liquid carbonaceous fuels
- C10L1/10—Liquid carbonaceous fuels containing additives
- C10L1/12—Inorganic compounds
- C10L1/1233—Inorganic compounds oxygen containing compounds, e.g. oxides, hydroxides, acids and salts thereof
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L1/00—Liquid carbonaceous fuels
- C10L1/10—Liquid carbonaceous fuels containing additives
- C10L1/14—Organic compounds
- C10L1/16—Hydrocarbons
- C10L1/1616—Hydrocarbons fractions, e.g. lubricants, solvents, naphta, bitumen, tars, terpentine
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L1/00—Liquid carbonaceous fuels
- C10L1/10—Liquid carbonaceous fuels containing additives
- C10L1/14—Organic compounds
- C10L1/18—Organic compounds containing oxygen
- C10L1/1802—Organic compounds containing oxygen natural products, e.g. waxes, extracts, fatty oils
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L1/00—Liquid carbonaceous fuels
- C10L1/10—Liquid carbonaceous fuels containing additives
- C10L1/14—Organic compounds
- C10L1/18—Organic compounds containing oxygen
- C10L1/182—Organic compounds containing oxygen containing hydroxy groups; Salts thereof
- C10L1/1822—Organic compounds containing oxygen containing hydroxy groups; Salts thereof hydroxy group directly attached to (cyclo)aliphatic carbon atoms
- C10L1/1824—Organic compounds containing oxygen containing hydroxy groups; Salts thereof hydroxy group directly attached to (cyclo)aliphatic carbon atoms mono-hydroxy
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L1/00—Liquid carbonaceous fuels
- C10L1/10—Liquid carbonaceous fuels containing additives
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Abstract
The present invention provides a kind of energy-saving environmental-protection petrol additives and preparation method thereof, the energy-saving environmental-protection petrol additive includes methanol, methyl tertiary butyl ether(MTBE), cetyl trimethylammonium bromide, camellia seed oil, palm oil, lauric acid amide of ethanol, dimethyl carbonate, isooctyl ester nitrate, oleic acid, naphtha, rosin extracting solution, Nanometer hydroxide, combustion adjuvant, the mixture of organic RE lanthanum and isooctyl acid methyl esters, solubilizer, corrosion inhibitor, air-dried snail, alkyl phenol polyoxyethylene ether, heterogeneous ten alcohol polyoxyethylene ether, ethoxylated dodecyl alcohol, the dilute manganese tricarbonyl of methyl ring penta 2, detergent-dispersant additive, antiwear additive, stabilizer and rubber swelling inhibitor.It is acted synergistically by the resulting energy-saving environmental-protection petrol additive each component of the present invention, the combustibility of fuel oil can be improved, improved the burning velocity of fuel combustion efficiency and fuel oil, effectively reduce pollution emission, there is good economic and social benefit.
Description
Technical field
The invention belongs to gasoline fields, and in particular to a kind of energy-saving environmental-protection petrol additive and preparation method thereof.
Background technique
With the high speed development of national economy and the increasingly raising of living standards of the people, increasingly to the demand of the energy
Greatly, the disposable energy such as crude oil, coal substantially appreciates.Therefore, energy saving and tap a new source of energy and have become state basic policy.Wherein, it saves
About the energy is mainly reflected in the improvement of burner structure or process modification, the research and use of heat-barrier material, and in diesel oil
Or suitable quantity of water is added in gasoline, prepare diesel oil emulsification, biodiesel or clean gasoline etc..
Numerous studies are arranged in engine combustion room with extremely short moment burning it has been shown that fuel such as gasoline or diesel oil
Out, not fully, the utilization rate of fuel reduces such fuel, can also make a large amount of pernicious gas, such as hydrocarbon and
The unburnt intermediate product of fuel oil is discharged into air, pollutes environment.Additive is introduced in fuel oil to exist to improve fuel oil
The method of efficiency of combustion has been widely developed and has applied in internal-combustion engines engine combustion room, although having multiple types on the market
Fuel oil additive exist, but develop the energy saving and environment friendly fuel oil additive of high-efficiency and economic, it is insufficient and give off to solve burning
A large amount of toxic gases make fuel oil full combustion and improve its effective rate of utilization to be still current gasoline area research hot spot.
Summary of the invention
The present invention protects environment in order to energy saving, provides that one kind has good burning performance, power performance is good and energy conservation and environmental protection
Gasoline additive.
To achieve the object of the present invention, according to parts by weight, energy-saving environmental-protection petrol additive of the invention includes: methanol
30-40 parts, 10-15 parts of methyl tertiary butyl ether(MTBE), 6-9 parts of cetyl trimethylammonium bromide, 7-10 parts of camellia seed oil, palm oil 5-
8 parts, 3-5 parts of lauric acid amide of ethanol, 5-8 parts of dimethyl carbonate, 5-8 parts of isooctyl ester nitrate, 3-7 parts of oleic acid, naphtha 12-
15 parts, 7-10 parts of rosin extracting solution, 6-10 parts of Nanometer hydroxide, 12-16 parts of combustion adjuvant, organic RE lanthanum and isooctyl acid methyl esters
7-10 parts of mixture, 9-13 parts of solubilizer, 7-10 parts of corrosion inhibitor, 7-13 parts air-dried of snail, alkylphenol-polyethenoxy
3-5 parts of ether, 3-5 parts of heterogeneous ten alcohol polyoxyethylene ether, 3-5 parts of ethoxylated dodecyl alcohol, the dilute manganese tricarbonyl 5-7 of methyl ring penta 2
Part, 7-12 parts of detergent-dispersant additive, 5-10 parts of antiwear additive, 5-10 parts of stabilizer and 1-2 parts of rubber swelling inhibitor.
In the present invention, the Nanometer hydroxide includes nanometer indium hydroxide and nano-aluminum hydroxide, nanometer indium hydroxide
Mass ratio with nano-aluminum hydroxide can be 1:1~3.
In the present invention, the combustion adjuvant can be made of Di Iso Propyl Ether and hydrogen peroxide by the mass ratio of 2:3~5.
In the present invention, the content of lanthanum is by percentage to the quality in the mixture of the organic RE lanthanum and isooctyl acid methyl esters
15-18%.
In the present invention, the solubilizer can be isobutanol, No. 200 solvent naphthas of n-hexane and polysorbate60 according to mass fraction
It is formed than 1:3~5:2~4.
In the present invention, the corrosion inhibitor may include citric acid, tartaric acid, pyrazolone, methyl benzotriazazole and
One of butyl stearate is a variety of.
In the present invention, the stabilizer can be one of polyethylene glycol, sodium tripolyphosphate and n-butanol or a variety of.
In the present invention, the detergent-dispersant additive can be dimerization oxyethylated fatty amide, oleic acid diethyl amide, lauryl amine
It is one or more in polyoxyethylene ether, glyceryl monostearate, trien and polyisobutene amide.
In the present invention, the antiwear additive can be capric acid, capric acid butyl ester, dodecanoic acid, ethyl laurate, three oil of glycerol
It is one or more in acid esters.
Energy-saving environmental-protection petrol additive of the invention can be reconciled with gasoline in 1 ‰~6% ratio, and difference is prepared
Grade, different desired motor petrol.
The present invention also provides a kind of preparation method of energy-saving environmental-protection petrol additive, the preparation method may include with
Lower step:
(1) air-dried snail is cleaned and crushes, solubilizer is added, is placed in supersonic oscillations instrument, 20~25min of ultrasound,
It filters to get filtrate；
(2) by methanol, methyl tertiary butyl ether(MTBE), naphtha, cetyl trimethylammonium bromide, camellia seed oil, palm oil, coconut palm
After oleic acid diethyl amide, dimethyl carbonate, isooctyl ester nitrate, oleic acid and rosin extracting solution are mixed with filtrate obtained by step (1),
30-45min is stirred under the conditions of 30~40 DEG C, standing obtains mixture；
(3) alkyl phenol polyoxyethylene ether, heterogeneous ten alcohol polyoxyethylene ether, laurel is added in the mixture obtained by step (2)
Alcohol polyoxyethylene ether, the dilute manganese tricarbonyl of methyl ring penta 2 and detergent-dispersant additive stir 40~55min under the conditions of 40~50 DEG C,
Add the mixture of Nanometer hydroxide, combustion adjuvant, organic RE lanthanum and isooctyl acid methyl esters, corrosion inhibitor, antiwear additive, steady
Determine agent and rubber swelling inhibitor, is stood after being thoroughly mixed uniformly up to energy-saving environmental-protection petrol additive.
Above-mentioned preparation method is only a kind of preparation method of energy-saving environmental-protection petrol additive of the present invention, art technology
Personnel can be adjusted material sequence, reaction time and temperature etc. under the premise of guaranteeing the additive effectiveness, appropriate to add
Enter other supplies.
Energy-saving environmental-protection petrol additive each component synergistic effect provided by the invention, can be mixed to prepare mixed with various gasoline
It closes fuel directly to use, which has good detergency, can obviously reduce the portions such as automobile nozzle, air throttle, combustion chamber
The colloid and carbon distribution coking of position, combustion-supporting, energy conservation can promote fuel oil completely burned, improve the combustibility of fuel oil, improve fuel oil
The burning velocity of efficiency of combustion and fuel oil improves the efficiency of engine, effectively reduces pollution emission, better meets fuel oil
The requirement of economy, dynamic property, emission performance has good economic and social benefit.
Specific embodiment
In order to make the objectives, technical solutions, and advantages of the present invention clearer, with reference to embodiments, to the present invention
It is further elaborated.Additional aspect and advantage of the invention will be set forth in part in the description, partially will be under
Become obvious in the description in face, or practice through the invention is recognized.It is only used to explain this hair it should be appreciated that being described below
It is bright, it is not intended to limit the present invention.
To achieve the object of the present invention, according to parts by weight, energy-saving environmental-protection petrol additive of the invention includes: methanol
30-40 parts, 10-15 parts of methyl tertiary butyl ether(MTBE), 6-9 parts of cetyl trimethylammonium bromide, 7-10 parts of camellia seed oil, palm oil 5-
8 parts, 3-5 parts of lauric acid amide of ethanol, 5-8 parts of dimethyl carbonate, 5-8 parts of isooctyl ester nitrate, 3-7 parts of oleic acid, naphtha 12-
15 parts, 7-10 parts of rosin extracting solution, 6-10 parts of Nanometer hydroxide, 12-16 parts of combustion adjuvant, organic RE lanthanum and isooctyl acid methyl esters
7-10 parts of mixture, 9-13 parts of solubilizer, 7-10 parts of corrosion inhibitor, 7-13 parts air-dried of snail, alkylphenol-polyethenoxy
3-5 parts of ether, 3-5 parts of heterogeneous ten alcohol polyoxyethylene ether, 3-5 parts of ethoxylated dodecyl alcohol, the dilute manganese tricarbonyl 5-7 of methyl ring penta 2
Part, 7-12 parts of detergent-dispersant additive, 5-10 parts of antiwear additive, 5-10 parts of stabilizer and 1-2 parts of rubber swelling inhibitor.
Unless otherwise instructed, in the present invention, the Nanometer hydroxide includes nanometer indium hydroxide and nano-aluminum hydroxide,
The mass ratio of nanometer indium hydroxide and nano-aluminum hydroxide can be 1:1~3；The combustion adjuvant can by more Di Iso Propyl Ethers and
Hydrogen peroxide is formed by the mass ratio of 2:3~5；The content of lanthanum is in the mixture of the organic RE lanthanum and isooctyl acid methyl esters with matter
Amount percentages are 15-18%；The solubilizer can be isobutanol, No. 200 solvent naphthas of n-hexane and polysorbate60 according to quality
Portion rate 1:3~5:2~4 is formed；The corrosion inhibitor may include citric acid, tartaric acid, pyrazolone, three nitrogen of methyl benzo
One of azoles and butyl stearate are a variety of；The stabilizer can be in polyethylene glycol, sodium tripolyphosphate and n-butanol
It is one or more；The detergent-dispersant additive can be dimerization oxyethylated fatty amide, oleic acid diethyl amide, lauryl amine polyoxy second
It is one or more in alkene ether, glyceryl monostearate, trien and polyisobutene amide；The antiwear additive can be the last of the ten Heavenly stems
It is one or more in acid, capric acid butyl ester, dodecanoic acid, ethyl laurate, glycerol trioleate.
Energy-saving environmental-protection petrol additive of the invention can be reconciled with gasoline in 1 ‰~6% ratio, and difference is prepared
Grade, different desired motor petrol.
The preparation method of energy-saving environmental-protection petrol additive of the invention may include following steps:
(1) air-dried snail is cleaned and crushes, solubilizer is added, is placed in supersonic oscillations instrument, 20~25min of ultrasound,
It filters to get filtrate；
(2) by methanol, methyl tertiary butyl ether(MTBE), naphtha, cetyl trimethylammonium bromide, camellia seed oil, palm oil, coconut palm
After oleic acid diethyl amide, dimethyl carbonate, isooctyl ester nitrate, oleic acid and rosin extracting solution are mixed with filtrate obtained by step (1),
30-45min is stirred under the conditions of 30~40 DEG C, standing obtains mixture；
(3) alkyl phenol polyoxyethylene ether, heterogeneous ten alcohol polyoxyethylene ether, laurel is added in the mixture obtained by step (2)
Alcohol polyoxyethylene ether, the dilute manganese tricarbonyl of methyl ring penta 2 and detergent-dispersant additive stir 40~55min under the conditions of 40~50 DEG C,
Add the mixture of Nanometer hydroxide, combustion adjuvant, organic RE lanthanum and isooctyl acid methyl esters, corrosion inhibitor, antiwear additive, steady
Determine agent and rubber swelling inhibitor, is stood after being thoroughly mixed uniformly up to energy-saving environmental-protection petrol additive.
Term "comprising" used in the present invention, " comprising ", " having ", " containing " or its any other deformation, it is intended that cover
Lid non-exclusionism includes.For example, composition, step, method, product or device comprising listed elements are not necessarily limited to those
Element, but may include that not expressly listed other elements or such composition, step, method, product or device institute are intrinsic
Element.
Equivalent, concentration or other values or parameter are excellent with range, preferred scope or a series of upper limit preferred values and lower limit
When the Range Representation that choosing value limits, this should be understood as specifically disclosing by any range limit or preferred value and any range
Any pairing of lower limit or preferred value is formed by all ranges, regardless of whether the range separately discloses.For example, when open
When range " 1 to 5 ", described range should be interpreted as including range " 1 to 4 ", " 1 to 3 ", " 1 to 2 ", " 1 to 2 and 4 to
5 ", " 1 to 3 and 5 " etc..When numberical range is described herein, unless otherwise stated, otherwise the range is intended to include its end
Value and all integers and score in the range.
Indefinite article "an" before element or component of the present invention (goes out the quantitative requirement of element or component with "one"
Occurrence number) unrestriction.Therefore "one" or "an" should be read as including one or at least one, and singular
Element or component also include plural form, unless the quantity obviously only refers to singular.
Moreover, technical characteristic involved in each embodiment of the present invention as long as they do not conflict with each other can
To be combined with each other.
Embodiment 1
The gasoline additive of the present embodiment includes: 35 parts of methanol, 13 parts of methyl tertiary butyl ether(MTBE), cetyl trimethyl bromination
8 parts of ammonium, 8 parts of camellia seed oil, 7 parts of palm oil, 4 parts of lauric acid amide of ethanol, 7 parts of dimethyl carbonate, 6 parts of isooctyl ester nitrate,
5 parts of oleic acid, 13 parts of naphtha, 9 parts of rosin extracting solution, 8 parts of Nanometer hydroxide, 14 parts of combustion adjuvant, organic RE lanthanum and different pungent
8 parts of 11 parts of 9 parts of mixture, solubilizer, the corrosion inhibitor of sour methyl esters, 10 parts air-dried of snail, alkyl phenol polyoxyethylene ether 4
Part, 4 parts of heterogeneous ten alcohol polyoxyethylene ether, 4 parts of ethoxylated dodecyl alcohol, penta 26 parts of dilute manganese tricarbonyl of methyl ring, peace and quiet dispersion
10 parts of agent, 8 parts of antiwear additive, 8 parts of stabilizer and 1 part of rubber swelling inhibitor.
Embodiment 2
The gasoline additive of the present embodiment includes: 30 parts of methanol, 10 parts of methyl tertiary butyl ether(MTBE), cetyl trimethyl bromination
6 parts of ammonium, 7 parts of camellia seed oil, 5 parts of palm oil, 3 parts of lauric acid amide of ethanol, 5 parts of dimethyl carbonate, 5 parts of isooctyl ester nitrate,
3 parts of oleic acid, 12 parts of naphtha, 7 parts of rosin extracting solution, 6 parts of Nanometer hydroxide, 12 parts of combustion adjuvant, organic RE lanthanum and different pungent
7 parts of 9 parts of 7 parts of mixture, solubilizer, the corrosion inhibitor of sour methyl esters, 7 parts air-dried of snail, 3 parts of alkyl phenol polyoxyethylene ether,
3 parts of heterogeneous ten alcohol polyoxyethylene ether, 3 parts of ethoxylated dodecyl alcohol, penta 25 parts of dilute manganese tricarbonyl of methyl ring, detergent-dispersant additive 7
Part, 5 parts of antiwear additive, 5 parts of stabilizer and 1 part of rubber swelling inhibitor.
Embodiment 3
The gasoline additive of the present embodiment includes: 40 parts of methanol, 15 parts of methyl tertiary butyl ether(MTBE), cetyl trimethyl bromination
9 parts of ammonium, 10 parts of camellia seed oil, 8 parts of palm oil, 5 parts of lauric acid amide of ethanol, 8 parts of dimethyl carbonate, 8 parts of isooctyl ester nitrate,
7 parts of oleic acid, 15 parts of naphtha, 10 parts of rosin extracting solution, 10 parts of Nanometer hydroxide, 16 parts of combustion adjuvant, organic RE lanthanum and different
10 parts of 13 parts of 10 parts of mixture, solubilizer, the corrosion inhibitor of methyl caprylate, 13 parts air-dried of snail, alkylphenol-polyethenoxy
It is 5 parts of ether, 5 parts of heterogeneous ten alcohol polyoxyethylene ether, 5 parts of ethoxylated dodecyl alcohol, penta 27 parts of dilute manganese tricarbonyl of methyl ring, peace and quiet
12 parts of dispersing agent, 10 parts of antiwear additive, 10 parts of stabilizer and 2 parts of rubber swelling inhibitor.
Embodiment 4
The gasoline additive of the present embodiment includes: 50 parts of methanol, 5 parts of methyl tertiary butyl ether(MTBE), cetyl trimethyl bromination
18 parts of ammonium, 10 parts of camellia seed oil, 8 parts of palm oil, 5 parts of lauric acid amide of ethanol, 15 parts of dimethyl carbonate, isooctyl ester nitrate 8
Part, 7 parts of oleic acid, 15 parts of naphtha, 10 parts of rosin extracting solution, 10 parts of Nanometer hydroxide, 16 parts of combustion adjuvant, organic RE lanthanum and
10 parts of 13 parts of 10 parts of mixture, solubilizer, the corrosion inhibitor of isooctyl acid methyl esters, 13 parts air-dried of snail, alkyl phenol polyoxy second
10 parts of alkene ether, 10 parts of heterogeneous ten alcohol polyoxyethylene ether, 10 parts of ethoxylated dodecyl alcohol, penta 27 parts of dilute manganese tricarbonyl of methyl ring,
12 parts of detergent-dispersant additive, 10 parts of antiwear additive, 10 parts of stabilizer and 2 parts of rubber swelling inhibitor.
Embodiment 5
The gasoline additive of the present embodiment includes: 35 parts of methanol, 13 parts of methyl tertiary butyl ether(MTBE), cetyl trimethyl bromination
8 parts of ammonium, 7 parts of dimethyl carbonate, 6 parts of isooctyl ester nitrate, 5 parts of oleic acid, 13 parts of naphtha, 9 part, nanometer hydroxide of rosin extracting solution
8 parts of object, 14 parts of combustion adjuvant, organic RE lanthanum and isooctyl acid methyl esters 8 parts of 11 parts of 9 parts of mixture, solubilizer, corrosion inhibitor,
Air-dried 10 parts of snail, 4 parts of alkyl phenol polyoxyethylene ether, 4 parts of heterogeneous ten alcohol polyoxyethylene ether, 4 parts of ethoxylated dodecyl alcohol,
Penta 26 parts of dilute manganese tricarbonyl of methyl ring, 10 parts of detergent-dispersant additive, 8 parts of antiwear additive, 8 parts of stabilizer and rubber swelling inhibitor 1
Part.
Embodiment 6
The gasoline additive of the present embodiment includes: 35 parts of methanol, 13 parts of methyl tertiary butyl ether(MTBE), cetyl trimethyl bromination
8 parts of ammonium, 8 parts of camellia seed oil, 7 parts of palm oil, 4 parts of lauric acid amide of ethanol, 7 parts of dimethyl carbonate, 6 parts of isooctyl ester nitrate,
9 parts of mixture, the increasing of 9 parts of rosin extracting solution, 8 parts of Nanometer hydroxide, 14 parts of combustion adjuvant, organic RE lanthanum and isooctyl acid methyl esters
11 parts of solvent, 8 parts of corrosion inhibitor, 10 parts air-dried of snail, 4 parts of alkyl phenol polyoxyethylene ether, heterogeneous ten alcohol polyoxyethylene ether 4
Part, penta 26 parts of dilute manganese tricarbonyl of methyl ring, 10 parts of detergent-dispersant additive, 8 parts of antiwear additive, is stablized 4 parts of ethoxylated dodecyl alcohol
8 parts and 1 part of rubber swelling inhibitor of agent.
Embodiment 7
The gasoline additive of the present embodiment includes: 35 parts of methanol, 13 parts of methyl tertiary butyl ether(MTBE), cetyl trimethyl bromination
8 parts of ammonium, 8 parts of camellia seed oil, 7 parts of palm oil, 4 parts of lauric acid amide of ethanol, 7 parts of dimethyl carbonate, 6 parts of isooctyl ester nitrate,
5 parts of oleic acid, 13 parts of naphtha, 9 parts of rosin extracting solution, 14 parts of combustion adjuvant, organic RE lanthanum and isooctyl acid methyl esters mixture 9
Part, 11 parts of solubilizer, 8 parts of corrosion inhibitor, 10 parts air-dried of snail, 4 parts of alkyl phenol polyoxyethylene ether, ten alcohol polyoxy second of isomery
4 parts of alkene ether, 4 parts of ethoxylated dodecyl alcohol, penta 26 parts of dilute manganese tricarbonyl of methyl ring, 10 parts of detergent-dispersant additive, 8 parts of antiwear additive,
8 parts and 1 part of rubber swelling inhibitor of stabilizer.
Embodiment 8
The gasoline additive of the present embodiment includes: 35 parts of methanol, 13 parts of methyl tertiary butyl ether(MTBE), cetyl trimethyl bromination
8 parts of ammonium, 8 parts of camellia seed oil, 7 parts of palm oil, 4 parts of lauric acid amide of ethanol, 7 parts of dimethyl carbonate, 6 parts of isooctyl ester nitrate,
5 parts of oleic acid, 13 parts of naphtha, 9 parts of rosin extracting solution, 8 parts of Nanometer hydroxide, 14 parts of combustion adjuvant, organic RE lanthanum and different pungent
8 parts of 11 parts of 9 parts of mixture, solubilizer, the corrosion inhibitor of sour methyl esters, 10 parts air-dried of snail, alkyl phenol polyoxyethylene ether 4
Part, 4 parts of heterogeneous ten alcohol polyoxyethylene ether, 4 parts of ethoxylated dodecyl alcohol, penta 26 parts of dilute manganese tricarbonyl of methyl ring, peace and quiet dispersion
10 parts of agent, 8 parts of antiwear additive, 8 parts of stabilizer and 1 part of rubber swelling inhibitor, wherein the organic RE lanthanum and isooctyl acid methyl esters
Mixture in the content of lanthanum be by percentage to the quality 10%.
Embodiment 9
The gasoline additive of the present embodiment includes: 35 parts of methanol, 13 parts of methyl tertiary butyl ether(MTBE), cetyl trimethyl bromination
8 parts of ammonium, 8 parts of camellia seed oil, 7 parts of palm oil, 4 parts of lauric acid amide of ethanol, 7 parts of dimethyl carbonate, 6 parts of isooctyl ester nitrate,
5 parts of oleic acid, 13 parts of naphtha, 9 parts of rosin extracting solution, 8 parts of Nanometer hydroxide, 14 parts of combustion adjuvant, organic RE lanthanum and different pungent
8 parts of 11 parts of 9 parts of mixture, solubilizer, the corrosion inhibitor of sour methyl esters, 10 parts air-dried of snail, alkyl phenol polyoxyethylene ether 4
Part, 4 parts of heterogeneous ten alcohol polyoxyethylene ether, 4 parts of ethoxylated dodecyl alcohol, penta 26 parts of dilute manganese tricarbonyl of methyl ring, peace and quiet dispersion
10 parts of agent, 8 parts of antiwear additive, 8 parts of stabilizer and 1 part of rubber swelling inhibitor, wherein the organic RE lanthanum and isooctyl acid methyl esters
Mixture in the content of lanthanum be by percentage to the quality 25%.
Embodiment 10
The gasoline additive of the present embodiment includes: 35 parts of methanol, 13 parts of methyl tertiary butyl ether(MTBE), cetyl trimethyl bromination
8 parts of ammonium, 8 parts of camellia seed oil, 7 parts of palm oil, 4 parts of lauric acid amide of ethanol, 7 parts of dimethyl carbonate, 6 parts of isooctyl ester nitrate,
5 parts of oleic acid, 13 parts of naphtha, 9 parts of rosin extracting solution, 8 parts of Nanometer hydroxide, 14 parts of combustion adjuvant, organic RE lanthanum and different pungent
8 parts of 11 parts of 9 parts of mixture, solubilizer, the corrosion inhibitor of sour methyl esters, 10 parts air-dried of snail, dilute three carbonyl of methyl ring penta 2
6 parts of manganese, 10 parts of detergent-dispersant additive, 8 parts of antiwear additive, 8 parts of stabilizer and 1 part of rubber swelling inhibitor.
Embodiment 11
The gasoline additive of the present embodiment includes: 35 parts of methanol, 13 parts of methyl tertiary butyl ether(MTBE), cetyl trimethyl bromination
8 parts of ammonium, 8 parts of camellia seed oil, 7 parts of palm oil, 4 parts of lauric acid amide of ethanol, 7 parts of dimethyl carbonate, 6 parts of isooctyl ester nitrate,
The mixing of 5 parts of oleic acid, 13 parts of naphtha, 9 parts of rosin extracting solution, 8 parts of Nanometer hydroxide, organic RE lanthanum and isooctyl acid methyl esters
9 parts of object, 11 parts of solubilizer, 8 parts of corrosion inhibitor, 10 parts air-dried of snail, 4 parts of alkyl phenol polyoxyethylene ether, ten alcohol of isomery are poly-
4 parts of ethylene oxide ether, 4 parts of ethoxylated dodecyl alcohol, penta 26 parts of dilute manganese tricarbonyl of methyl ring, 10 parts of detergent-dispersant additive, antiwear additive
8 parts, 8 parts of stabilizer and 1 part of rubber swelling inhibitor.
Embodiment 12
The gasoline additive of the present embodiment includes: 35 parts of methanol, 13 parts of methyl tertiary butyl ether(MTBE), cetyl trimethyl bromination
8 parts of ammonium, 8 parts of camellia seed oil, 7 parts of palm oil, 4 parts of lauric acid amide of ethanol, 7 parts of dimethyl carbonate, 6 parts of isooctyl ester nitrate,
5 parts of oleic acid, 13 parts of naphtha, 9 parts of rosin extracting solution, 8 parts of Nanometer hydroxide, 14 parts of combustion adjuvant, organic RE lanthanum and different pungent
8 parts of 11 parts of 9 parts of mixture, solubilizer, the corrosion inhibitor of sour methyl esters, 10 parts air-dried of snail, alkyl phenol polyoxyethylene ether 4
Part, 4 parts of heterogeneous ten alcohol polyoxyethylene ether, 4 parts of ethoxylated dodecyl alcohol, penta 26 parts of dilute manganese tricarbonyl of methyl ring, peace and quiet dispersion
10 parts of agent, 8 parts of antiwear additive, 8 parts of stabilizer and 1 part of rubber swelling inhibitor, wherein the combustion adjuvant is by Di Iso Propyl Ether and mistake
Hydrogen oxide is formed by the mass ratio of 2:1.
Effect example
The gasoline additive of above-described embodiment 1 to 12 and gasoline are reconciled in 3% ratio, by GB/T19233-2008
The gasoline for being added to above-mentioned gasoline additive is examined with the gasoline per 100 km oil consumption and exhaust emissions for being not added with gasoline additive
It surveys, wherein (same engine, identical mileage travelled 20km, identical speed 90km/h) is compared under identical use condition
Compared with, each group of data take the average value of ten tests, as a result as follows:
As it will be easily appreciated by one skilled in the art that the foregoing is merely illustrative of the preferred embodiments of the present invention, not to
The limitation present invention, any modifications, equivalent substitutions and improvements made within the spirit and principles of the present invention should all include
Within protection scope of the present invention.
Claims (10)
1. a kind of energy-saving environmental-protection petrol additive, which is characterized in that according to parts by weight, the energy-saving environmental-protection petrol additive packet
Contain: 30-40 parts of methanol, 10-15 parts of methyl tertiary butyl ether(MTBE), 6-9 parts of cetyl trimethylammonium bromide, 7-10 parts of camellia seed oil,
5-8 parts of palm oil, 3-5 parts of lauric acid amide of ethanol, 5-8 parts of dimethyl carbonate, 5-8 parts of isooctyl ester nitrate, 3-7 parts of oleic acid,
12-15 parts of naphtha, 7-10 parts of rosin extracting solution, 6-10 parts of Nanometer hydroxide, 12-16 parts of combustion adjuvant, organic RE lanthanum and
7-10 parts of 9-13 parts of 7-10 parts of mixture, solubilizer, the corrosion inhibitor of isooctyl acid methyl esters, 7-13 parts air-dried of snail, alkyl
3-5 parts of phenol polyethenoxy ether, 3-5 parts of heterogeneous ten alcohol polyoxyethylene ether, 3-5 parts of ethoxylated dodecyl alcohol, methyl ring penta 2 are dilute
5-7 parts of manganese tricarbonyl, 7-12 parts of detergent-dispersant additive, 5-10 parts of antiwear additive, 5-10 parts of stabilizer and rubber swelling inhibitor 1-2
Part.
2. energy-saving environmental-protection petrol additive according to claim 1, which is characterized in that the Nanometer hydroxide includes to receive
The mass ratio of rice indium hydroxide and nano-aluminum hydroxide, nanometer indium hydroxide and nano-aluminum hydroxide is 1:1~3.
3. energy-saving environmental-protection petrol additive according to claim 1, which is characterized in that the combustion adjuvant is by Di Iso Propyl Ether
It is formed with hydrogen peroxide by the mass ratio of 2:3~5.
4. energy-saving environmental-protection petrol additive according to claim 1, which is characterized in that the organic RE lanthanum and isooctyl acid
The content of lanthanum is 15-18% by percentage to the quality in the mixture of methyl esters.
5. energy-saving environmental-protection petrol additive according to claim 1, which is characterized in that the solubilizer is isobutanol, just
No. 200 solvent naphthas of hexane and polysorbate60 are formed according to mass parts ratio 1:3~5:2~4.
6. energy-saving environmental-protection petrol additive according to claim 1, which is characterized in that the corrosion inhibitor includes lemon
One of acid, tartaric acid, pyrazolone, methyl benzotriazazole and butyl stearate are a variety of.
7. energy-saving environmental-protection petrol additive according to claim 1, which is characterized in that the stabilizer be polyethylene glycol,
One of sodium tripolyphosphate and n-butanol are a variety of.
8. energy-saving environmental-protection petrol additive according to claim 1, which is characterized in that the detergent-dispersant additive is two polyoxies
Ethylene fatty acid amide, oleic acid diethyl amide, lauryl amine polyoxyethylene ether, glyceryl monostearate, trien and poly-
It is one or more in methacrylamide.
9. energy-saving environmental-protection petrol additive according to claim 1, which is characterized in that the antiwear additive is capric acid, capric acid
Butyl ester, dodecanoic acid, ethyl laurate, one or more in glycerol trioleate, the preferred energy-saving environmental-protection petrol adds
Agent and gasoline is added to be reconciled in 1 ‰~6% ratio.
10. the preparation method of -9 described in any item energy-saving environmental-protection petrol additives according to claim 1, which can be with
It comprises the steps of:
(1) air-dried snail is cleaned and crushes, solubilizer is added, is placed in supersonic oscillations instrument, 20~25min of ultrasound, filter
Obtain filtrate；
(2) by methanol, methyl tertiary butyl ether(MTBE), naphtha, cetyl trimethylammonium bromide, camellia seed oil, palm oil, coconut oil
After diglycollic amide, dimethyl carbonate, isooctyl ester nitrate, oleic acid and rosin extracting solution are mixed with filtrate obtained by step (1), 30
30-45min is stirred under the conditions of~40 DEG C, standing obtains mixture；
(3) alkyl phenol polyoxyethylene ether, heterogeneous ten alcohol polyoxyethylene ether, laruyl alcohol are added in the mixture obtained by step (2) to gather
Ethylene oxide ether, the dilute manganese tricarbonyl of methyl ring penta 2 and detergent-dispersant additive, 40~55min of stirring under the conditions of 40~50 DEG C, then plus
Enter mixture, corrosion inhibitor, antiwear additive, the stabilizer of Nanometer hydroxide, combustion adjuvant, organic RE lanthanum and isooctyl acid methyl esters
And rubber swelling inhibitor, it is stood after being thoroughly mixed uniformly up to energy-saving environmental-protection petrol additive.
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| CN115029166A (en) * | 2021-03-04 | 2022-09-09 | 吴勇 | Efficient energy-saving environment-friendly combustion improver |
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Application publication date: 20181211 |