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CN108739844A - A kind of seed treatment compositions of pyraclostrobin-containing and carboxin and Acetamiprid - Google Patents

A kind of seed treatment compositions of pyraclostrobin-containing and carboxin and Acetamiprid Download PDF

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Publication number
CN108739844A
CN108739844A CN201811031466.2A CN201811031466A CN108739844A CN 108739844 A CN108739844 A CN 108739844A CN 201811031466 A CN201811031466 A CN 201811031466A CN 108739844 A CN108739844 A CN 108739844A
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China
Prior art keywords
pyraclostrobin
carboxin
seed treatment
acetamiprid
treatment compositions
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201811031466.2A
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Chinese (zh)
Inventor
蔡丹群
黄卫荣
王世银
彭军
吴光辉
刘世勇
陈锐东
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Guangdong Guangkang Biochemical Polytron Technologies Inc
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Guangdong Guangkang Biochemical Polytron Technologies Inc
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Priority to CN201811031466.2A priority Critical patent/CN108739844A/en
Publication of CN108739844A publication Critical patent/CN108739844A/en
Pending legal-status Critical Current

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    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N47/00Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
    • A01N47/40Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having a double or triple bond to nitrogen, e.g. cyanates, cyanamides
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/02Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms
    • A01N43/24Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with two or more hetero atoms
    • A01N43/32Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with two or more hetero atoms six-membered rings
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N47/00Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
    • A01N47/08Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
    • A01N47/10Carbamic acid derivatives, i.e. containing the group —O—CO—N<; Thio analogues thereof
    • A01N47/24Carbamic acid derivatives, i.e. containing the group —O—CO—N<; Thio analogues thereof containing the groups, or; Thio analogues thereof

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  • Life Sciences & Earth Sciences (AREA)
  • Agronomy & Crop Science (AREA)
  • Pest Control & Pesticides (AREA)
  • Plant Pathology (AREA)
  • Health & Medical Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Dentistry (AREA)
  • General Health & Medical Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Zoology (AREA)
  • Environmental Sciences (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)

Abstract

The invention discloses the seed treatment compositions of a kind of pyraclostrobin-containing and carboxin and Acetamiprid, it is characterized in that, the active constituent of the seed treatment compositions includes pyraclostrobin, carboxin and Acetamiprid, and the wherein weight ratio of pyraclostrobin, carboxin and Acetamiprid is 1-15:1-15:1-30, preferably 1-5:1-5:1-10, further preferably 1.5-5:1.5-4.5:5-10.Seed treatment compositions provided by the invention can effectively prevent stem rot, smut, head smut, southern blight, root rot, damping-off, samping off, banded sclerotial blight, grub, plant hopper, phyllotreta striolata, wireworm, aphid, within the scope of the effective ingredient consumption of recommendation, to crop safety, the rudiment and plant growth of seed can be promoted.

Description

A kind of seed treatment compositions of pyraclostrobin-containing and carboxin and Acetamiprid
Technical field
The invention belongs to agriculture chemical compounding fields, and in particular to a kind of kind of pyraclostrobin-containing and carboxin and Acetamiprid Subprocessing composition further relates to purposes of the composition for preventing diseases and pests of agronomic crop.
Background technology
Pyraclostrobin (pyraclostrobin) belongs to methoxy acrylic bactericide, mainly acts on fungi Mitochondria is mitochondrial respiratory inhibitor, by preventing electronics transfer in being synthesized in cytochromes, has protection, treatment, blade Permeate conduction.Pyraclostrobin can prevent and kill off all types of fungal pathogens, wide sterilization spectrum, to various crop, including wheat Class, grape, fruit tree, the multiple diseases of vegetables are effective.
Carboxin (Carboxin), chemical name:5,6- dihydro -2- Methyl-N-phenyl-Isosorbide-5-Nitraes-oxathiene -3- Formamide, crotonoyl amine selectivity systemic fungicide, it can penetrate into the seed of rudiment and kill intraseminal germ, to load Guiding principle fungi have higher systemic activity, be mainly used for prevention by rest fungus and smut in various crop caused rust and black powder (fringe) disease, it is also effective to cotton seedling blight, verticillium wilt, as sorghum loose smut, head smut, maize head smut, wheat are black Fringe disease, wheat rust, millet smut and disease in cotton seedling stage.Carboxin has stimulation to plant growth, and can make small Wheat is increased production.
Acetamiprid belongs to chlorination nicotimine class efficient pesticides, have tag, stomach toxicity and inner sucting killing insect effect.Its disinfesting machine Reason is unique, mainly acts on the nicotinic acetylcholine receptor of insect nerve system postsynaptic membrane.With common organophosphor, amino Cross resistance is not present in formic acid esters and pyrethroid insecticides, thus can effectively prevent above-mentioned insecticide has been generated it is anti- The pest of property.
Seed and seedling are subject to the harm of underground and aboveground various pests and pathogen and infect, and are process of crop growth The link of middle most fragile;There is sick seedling, seedling death phenomenon by pests, or by pathogen infection in seed, seedling, can reduce unit Effective strain number of area crop causes crop to drop in production over a large area and quality decline.Kind is handled by using seed treatment compositions Son is to protect seed and rudiment plant to be known for a long time from plant pathogenic fungi and pest infestation and be The theme continuously improved.Pyraclostrobin and carboxin and Acetamiprid are carried out ternary built or mixture as kind by the applicant Subprocessing composition, it has surprisingly been found that the composition is for after seed treatment, can effectively prevent various crop seed and Seedling Stage Pest and disease damage, especially have special efficacy to wheat aphid, loose smut of wheat and root rotof flax.
Invention content
The present invention for the above-mentioned prior art the problem of, propose that a kind of control effect is good, production cost is low, crop can be promoted The seed treatment compositions and its preparation of growth.
It is an object of the present invention to provide the application of the seed treatment compositions and its preparation, the seed treatment compositions And/or its preparation is particularly suitable for prevention multiple kinds of crops such as corn, wheat, rice, the grub of peanut and other crops, plant hopper, Huang Cabbage flea beetle, wireworm, aphid etc., and for preventing stem rot, smut, head smut, southern blight, root rot, standing The diseases such as blight, samping off, banded sclerotial blight.
To achieve the goals above, the present invention takes following technical scheme to realize:
The present invention provides a kind of seed treatment compositions, and active constituent includes pyraclostrobin, carboxin and Acetamiprid, institute The weight ratio for stating pyraclostrobin, carboxin and Acetamiprid is 1-15:1-15:1-30.
Further, the weight ratio of the pyraclostrobin, carboxin and Acetamiprid is preferably 1-5:1-5:1-10.
Further, the weight ratio of the pyraclostrobin, carboxin and Acetamiprid is preferably 1.5-5:1.5-4.5:5- 10。
Further, active constituent pyraclostrobin, carboxin and Acetamiprid summation institute in the seed treatment compositions The weight percentage for accounting for composition is 5-65%, preferably 10-50%, remaining is commonly assisted in being processed for seed treatment Ingredient.
The seed treatment compositions of the present invention are prepared into suspension seed-coating agent, at seed with the method well known to pesticide field Manage dispersible pulvis, seed treatment microcapsule suspending agent, Waterless Seed Dressing agent, seed treatment microcapsule suspension-suspendinagent agent, seed treatment liquid Any one of agent, seed treatment emulsion etc..
Further, the dosage form of the seed treatment compositions be preferably suspension seed-coating agent, seed treatment dispersible pulvis, Seed treatment emulsion.
The auxiliary element includes diluent, emulsifier, dispersant, wetting agent, drier, colorant, pigment, defoaming Agent, preservative etc. are beneficial to the known substance that drug effect is stablized and played to active ingredient in the formulation, are commonly used in pesticidal preparations Or allowing the various composition used, specific ingredient and dosage are according to the recipe requirements determined by the test.
The method of application of the seed treatment compositions can be foliar spray, soil pouring, trickle irrigation, seed treatment;Institute It is variant according to its different dosage of process object when stating seed treatment compositions for foliar spray, soil pouring and trickle irrigation, The dosage determines to obtain all in accordance with the ordinary technical knowledge and routine test means of those skilled in the art.
The seed treatment compositions of the present invention can also be applied with other active ingredient combinations, such as expanding activity profile Or it prevents from forming resistance.Other active constituents for example fungicide, bactericide, attractant, insecticide, acaricide, Nematicide, growth regulator, herbicide, safener, fertilizer or semiochemical etc..
Compared with prior art, the present invention at least has the advantages that:
(1) after pyraclostrobin, carboxin and Acetamiprid are carried out compounding or mixture by the present invention, in a certain range to agriculture The prevention of crop disease and insect shows synergistic function;
(2) active constituent pyraclostrobin, the carboxin of seed treatment compositions provided by the invention are mainly used for preventing Various fungal diseases, Acetamiprid have tag, stomach toxicity and systemic action, be mainly used for preventing above and below ground pest, the group of three Close application can controlling disease but also pest control, reduction times for spraying, reduction drug cost, reduce dispenser labour.
(3) seed treatment compositions provided by the invention, within the scope of the effective ingredient consumption of recommendation, to crop safety, It can promote the rudiment and plant growth of seed.
Specific implementation mode
Preferably to describe the present invention, following exemplary embodiment is provided.Content mentioned by embodiment cannot recognize To be limitation of the invention, the selection of material prescription can be according to actual conditions by other equivalent or replacing with similar purpose It is replaced for feature.That is, being such as not particularly limited, each feature is a series of equivalent or similar characteristics a example, this The protection domain of the technical solution of invention is subject to claim and is limited.
One, example of formulations
Embodiment 1:33% pyraclostrobin carboxin Acetamiprid suspension seed-coating agent (10+5+18)
The specific procedure of processing of the composition suspension seed-coating agent is:1. by being formulated pyraclostrobin, carboxin, Acetamiprid Etc. after all materials and part water stirs evenly, pre-processed in next step with colloid mill uniform;2. by the material of the first step successively into Enter a two level sand mill to be sanded;3. second step and material are carried out shearing homogenizing, and the ejected wash water of surplus is added, shearing is equal Even 33% pyraclostrobin carboxin Acetamiprid suspension seed-coating agent to obtain the final product.
Embodiment 2:13% pyraclostrobin carboxin Acetamiprid seed treatment emulsion (3.5+1.5+8)
The specific procedure of processing of the composition seed treatment emulsion is:1. by being formulated pyraclostrobin, carboxin, pyridine worm Amidine etc. puts into reaction kettle, then puts into DMF, dimethyl sulfoxide (DMSO), certain herbaceous plants with big flowers amide, dimethylbenzene equal solvent;2. stirring is all molten to material Solution is to transparent;3. be then added remaining material, such as emulsifier, stirring is withered rust to transparent to get 13% pyraclostrobin Clever Acetamiprid seed treatment emulsion.
Embodiment 3:22.2% pyraclostrobin carboxin Acetamiprid seed treatment liquor (6.5+4.7+11)
The preparation method of the seed treatment liquor is:1. by formula by pyraclostrobin, carboxin, Acetamiprid using molten Agent dimethyl sulfoxide (DMSO), cyclohexanone, certain herbaceous plants with big flowers amide, abscisic acid, DMF, methanol are fully dissolved to transparent;2. emulsifier is then added, stir It is transparent to mix solution;3. then plus water stirring and dissolving is to transparent by polyethylene glycol-6000, proline;4. the water that step 3. is made Phase liquid is added in the liquid that step 2. makes, and stirring can be prepared by 22.2% pyraclostrobin carboxin pyridine worm to transparent Amidine seed treatment liquor.
Embodiment 4:42% pyraclostrobin carboxin Acetamiprid suspension seed-coating agent (12+10+20)
The specific procedure of processing of the composition suspension seed-coating agent is:1. by being formulated pyraclostrobin, carboxin, Acetamiprid Etc. after all materials and part water stirs evenly, pre-processed in next step with colloid mill uniform;2. by the material of the first step successively into Enter a two level sand mill to be sanded;3. second step and material are carried out shearing homogenizing, and the ejected wash water of surplus is added, shearing is equal Even 42% pyraclostrobin carboxin Acetamiprid suspension seed-coating agent to obtain the final product.
Embodiment 5:16% pyraclostrobin carboxin Acetamiprid suspension seed-coating agent (5+5+6)
The specific procedure of processing of the composition suspension seed-coating agent is:1. by being formulated pyraclostrobin, carboxin, Acetamiprid Etc. after all materials and part water stirs evenly, pre-processed in next step with colloid mill uniform;2. by the material of the first step successively into Enter a two level sand mill to be sanded;3. second step and material are carried out shearing homogenizing, and the ejected wash water of surplus is added, shearing is equal Even 16% pyraclostrobin carboxin Acetamiprid suspension seed-coating agent to obtain the final product.
Embodiment 6:28% pyraclostrobin carboxin Acetamiprid seed treatment microcapsule suspending agent (10+8+10)
The specific procedure of processing of the seed treatment microcapsule suspending agent is:1. by being formulated pyraclostrobin, carboxin, pyridine worm Amidine etc. puts into reaction kettle, and capsule material oil phase is then added, and partial emulsifier is added;2. 55-60 DEG C is heated under stiring, until being formed Transparent solution;3. water is then added, 55-60 DEG C of heat preservation is simultaneously stirred under shearing, and water phase and film forming agent is then added, and keeps the temperature 30 points Then clock is cooled to room temperature;3. permanent bordeaux, aluminium-magnesium silicate and partial emulsifier are ground into suspending agent;4. as water was making It is added in journey excessively, partial moisture can be removed after the completion of third walks;5. the 3rd, 4 liang of step material is mixed about 10-20 points of shearing Clock is up to 28% pyraclostrobin carboxin Acetamiprid seed treatment microcapsule suspending agent of pyrrole.
Two, Assays Example
1, controlling object:Wheat aphid, loose smut of wheat, root rotof flax
2, test method:Subjects are arranged in Henan Xinxiang City wheatland and carry out, at the seed of Application Example 1-6 Compositions-treated wheat seed is managed, experiment setting control treatment is as follows:(1) 1 is compareed:24.5% pyraclostrobin carboxin is outstanding Floating seed coat agent (4.5+20);(2) 2 are compareed:16.5% pyraclostrobin Acetamiprid suspension seed-coating agent (4.5+12);(3) it compares 3:25% carboxin Acetamiprid suspension seed-coating agent (15+10);(4) 4 are compareed:18% pyraclostrobin suspension seed-coating agent;(5) right According to 5:30% carboxin suspension seed-coating agent;(6) 6 are compareed:20% Acetamiprid suspension seed-coating agent.Embodiment and control treatment are used respectively The seed treatment of group handles wheat seed, is sowed after drying, test process, dosage and control effect are as shown in table 1, preventive effect meter It is as follows to calculate formula:
Prevention of the 1 different disposal medicament of table to Wheat Diseases And Insect Pests
From the bioassay test result of table 1 it is found that being compounded or being mixed pyraclostrobin, carboxin and Acetamiprid Match, can effectively prevent wheat aphid, loose smut of wheat and root rotof flax, the compositions-treated wheat seed of three, to small Wheat aphid, loose smut of wheat and root rotof flax show apparent synergistic function, and then reduce active ingredient Usage amount reduces drug cost, it is observed that the rudiment and wheat seedling to wheat seed have facilitation, is had no during experiment Poisoning is generated to wheat and other crops, shows that the seed treatment of the present invention is safe to crop;Especially embodiment 4 Seed treatment, significant effect is shown to the prevention of each pest and disease damage, is worth promoting and applying in production.
Based on the above description of the preferred embodiments of the present invention, through the above description, related personnel completely can be with Without departing from the scope of the technological thought of the present invention', various changes and amendments are carried out.The technical scope of this invention It is not limited to the contents of the specification, it is necessary to determine the technical scope according to the scope of the claims.

Claims (9)

1. the seed treatment compositions of a kind of pyraclostrobin-containing and carboxin and Acetamiprid, which is characterized in that the seed The active constituent for the treatment of compositions includes pyraclostrobin, carboxin and Acetamiprid.
2. the seed treatment compositions of a kind of pyraclostrobin-containing and carboxin and Acetamiprid according to claim 1, It is characterized in that:The weight ratio of the pyraclostrobin, carboxin and Acetamiprid is 1-15:1-15:1-30.
3. the seed treatment compositions of a kind of pyraclostrobin-containing and carboxin and Acetamiprid according to claim 1, It is characterized in that:The weight ratio of the pyraclostrobin, carboxin and Acetamiprid is 1-5:1-5:1-10.
4. the seed treatment compositions of a kind of pyraclostrobin-containing and carboxin and Acetamiprid according to claim 1, It is characterized in that:The weight ratio of the pyraclostrobin, carboxin and Acetamiprid is 1.5-5:1.5-4.5:5-10.
5. the seed treatment compositions of a kind of pyraclostrobin-containing and carboxin and Acetamiprid according to claim 1, It is characterized in that:The shared combination of active constituent pyraclostrobin, carboxin and Acetamiprid summation in the seed treatment compositions The weight percentage of object is 5-65%.
6. the seed treatment compositions of a kind of pyraclostrobin-containing and carboxin and Acetamiprid according to claim 1, It is characterized in that:The dosage form of the seed treatment compositions includes suspension seed-coating agent, seed treatment dispersible pulvis, seed treatment Microcapsule suspending agent, Waterless Seed Dressing agent, seed treatment microcapsule suspension-suspendinagent agent, seed treatment liquor, seed treatment emulsion.
7. the seed treatment compositions of a kind of pyraclostrobin-containing and carboxin and Acetamiprid according to claim 1, It is characterized in that:The seed treatment compositions further include auxiliary element, and the auxiliary element is to be beneficial to active ingredient making Stablize and play the known substance of drug effect, including diluent, emulsifier, dispersant, wetting agent, drier, colorant, face in agent Material, antifoaming agent, preservative.
8. seed treatment compositions according to claim 1 are used to prevent the purposes of diseases and pests of agronomic crop.
9. purposes according to claim 8, it is characterised in that:The diseases and pests of agronomic crop is stem rot, smut, silk In smut, southern blight, root rot, damping-off, samping off, banded sclerotial blight, grub, plant hopper, phyllotreta striolata, wireworm, aphid It is any.
CN201811031466.2A 2018-09-05 2018-09-05 A kind of seed treatment compositions of pyraclostrobin-containing and carboxin and Acetamiprid Pending CN108739844A (en)

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Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105875594A (en) * 2016-05-13 2016-08-24 创新美兰(合肥)股份有限公司 Pyraclostrobin, thiamethoxam and carboxin compound suspended seed coating and preparation method thereof

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105875594A (en) * 2016-05-13 2016-08-24 创新美兰(合肥)股份有限公司 Pyraclostrobin, thiamethoxam and carboxin compound suspended seed coating and preparation method thereof

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
姜伟丽等: "不同施药方式下6种药剂对棉蚜的防治效果研究", 《中国棉花》 *

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