CN105265429B - A kind of Pesticidal combination containing flonicamid and safener - Google Patents
A kind of Pesticidal combination containing flonicamid and safener Download PDFInfo
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- CN105265429B CN105265429B CN201510730166.3A CN201510730166A CN105265429B CN 105265429 B CN105265429 B CN 105265429B CN 201510730166 A CN201510730166 A CN 201510730166A CN 105265429 B CN105265429 B CN 105265429B
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- Prior art keywords
- flonicamid
- safener
- parts
- pesticidal combination
- active ingredient
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- 239000005900 Flonicamid Substances 0.000 title claims abstract description 139
- RLQJEEJISHYWON-UHFFFAOYSA-N flonicamid Chemical compound FC(F)(F)C1=CC=NC=C1C(=O)NCC#N RLQJEEJISHYWON-UHFFFAOYSA-N 0.000 title claims abstract description 139
- 230000000361 pesticidal effect Effects 0.000 title claims abstract description 95
- 230000000749 insecticidal effect Effects 0.000 claims abstract description 85
- 239000004480 active ingredient Substances 0.000 claims abstract description 70
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 claims abstract description 46
- 229910052801 chlorine Inorganic materials 0.000 claims abstract description 46
- 239000000460 chlorine Substances 0.000 claims abstract description 46
- PYKLUAIDKVVEOS-RAXLEYEMSA-N (e)-n-(cyanomethoxy)benzenecarboximidoyl cyanide Chemical compound N#CCO\N=C(\C#N)C1=CC=CC=C1 PYKLUAIDKVVEOS-RAXLEYEMSA-N 0.000 claims abstract description 42
- 229930191978 Gibberellin Natural products 0.000 claims abstract description 38
- ODFJOVXVLFUVNQ-UHFFFAOYSA-N acetarsol Chemical group CC(=O)NC1=CC([As](O)(O)=O)=CC=C1O ODFJOVXVLFUVNQ-UHFFFAOYSA-N 0.000 claims abstract description 38
- IXORZMNAPKEEDV-UHFFFAOYSA-N gibberellic acid GA3 Natural products OC(=O)C1C2(C3)CC(=C)C3(O)CCC2C2(C=CC3O)C1C3(C)C(=O)O2 IXORZMNAPKEEDV-UHFFFAOYSA-N 0.000 claims abstract description 38
- 239000003448 gibberellin Substances 0.000 claims abstract description 38
- ITGSCCPVERXFGN-UHFFFAOYSA-N isoxadifen Chemical compound C1C(C(=O)O)=NOC1(C=1C=CC=CC=1)C1=CC=CC=C1 ITGSCCPVERXFGN-UHFFFAOYSA-N 0.000 claims abstract description 36
- NRFQZTCQAYEXEE-UHFFFAOYSA-N Fenclorim Chemical compound ClC1=CC(Cl)=NC(C=2C=CC=CC=2)=N1 NRFQZTCQAYEXEE-UHFFFAOYSA-N 0.000 claims abstract description 25
- MCNOFYBITGAAGM-UHFFFAOYSA-N 2,2-dichloro-1-[5-(furan-2-yl)-2,2-dimethyl-1,3-oxazolidin-3-yl]ethanone Chemical compound C1N(C(=O)C(Cl)Cl)C(C)(C)OC1C1=CC=CO1 MCNOFYBITGAAGM-UHFFFAOYSA-N 0.000 claims abstract description 20
- HJSRGOVAIOPERP-UHFFFAOYSA-N 5-chloroquinoline Chemical compound C1=CC=C2C(Cl)=CC=CC2=N1 HJSRGOVAIOPERP-UHFFFAOYSA-N 0.000 claims abstract description 20
- -1 ethoxyacetic acid ester Chemical class 0.000 claims abstract description 19
- GRSMWKLPSNHDHA-UHFFFAOYSA-N Naphthalic anhydride Chemical compound C1=CC(C(=O)OC2=O)=C3C2=CC=CC3=C1 GRSMWKLPSNHDHA-UHFFFAOYSA-N 0.000 claims abstract description 15
- HKELWJONQIFBPO-UHFFFAOYSA-N 1-(2,4-dichlorophenyl)-5-(trichloromethyl)-1,2,4-triazole-3-carboxylic acid Chemical compound N1=C(C(=O)O)N=C(C(Cl)(Cl)Cl)N1C1=CC=C(Cl)C=C1Cl HKELWJONQIFBPO-UHFFFAOYSA-N 0.000 claims abstract description 13
- 150000001412 amines Chemical class 0.000 claims abstract description 12
- PFJJMJDEVDLPNE-UHFFFAOYSA-N Benoxacor Chemical compound C1=CC=C2N(C(=O)C(Cl)Cl)C(C)COC2=C1 PFJJMJDEVDLPNE-UHFFFAOYSA-N 0.000 claims abstract description 11
- 239000000203 mixture Substances 0.000 claims description 81
- JUJWROOIHBZHMG-UHFFFAOYSA-N Pyridine Chemical compound C1=CC=NC=C1 JUJWROOIHBZHMG-UHFFFAOYSA-N 0.000 claims description 70
- 150000001408 amides Chemical class 0.000 claims description 37
- 239000011737 fluorine Substances 0.000 claims description 35
- 229910052731 fluorine Inorganic materials 0.000 claims description 35
- UMJSCPRVCHMLSP-UHFFFAOYSA-N pyridine Natural products COC1=CC=CN=C1 UMJSCPRVCHMLSP-UHFFFAOYSA-N 0.000 claims description 35
- 244000025254 Cannabis sativa Species 0.000 claims description 5
- 239000002253 acid Substances 0.000 claims 2
- NRNITHABNQZDAT-UHFFFAOYSA-N n-(1,2-oxazol-3-yl)benzenesulfonamide Chemical compound C=1C=CC=CC=1S(=O)(=O)NC=1C=CON=1 NRNITHABNQZDAT-UHFFFAOYSA-N 0.000 claims 2
- OFUFXTHGZWIDDB-UHFFFAOYSA-N 2-chloroquinoline Chemical compound C1=CC=CC2=NC(Cl)=CC=C21 OFUFXTHGZWIDDB-UHFFFAOYSA-N 0.000 claims 1
- PXGOKWXKJXAPGV-UHFFFAOYSA-N Fluorine Chemical compound FF PXGOKWXKJXAPGV-UHFFFAOYSA-N 0.000 claims 1
- 150000003217 pyrazoles Chemical class 0.000 claims 1
- 241000238631 Hexapoda Species 0.000 abstract description 49
- OPGCOAPTHCZZIW-UHFFFAOYSA-N diethyl 1-(2,4-dichlorophenyl)-5-methyl-4h-pyrazole-3,5-dicarboxylate Chemical group CCOC(=O)C1(C)CC(C(=O)OCC)=NN1C1=CC=C(Cl)C=C1Cl OPGCOAPTHCZZIW-UHFFFAOYSA-N 0.000 abstract description 12
- 241000607479 Yersinia pestis Species 0.000 abstract description 7
- 238000010899 nucleation Methods 0.000 abstract description 5
- 241000254173 Coleoptera Species 0.000 abstract description 3
- 241000255925 Diptera Species 0.000 abstract description 3
- 241000258937 Hemiptera Species 0.000 abstract description 3
- 241000255777 Lepidoptera Species 0.000 abstract description 3
- 241000244206 Nematoda Species 0.000 abstract description 3
- YZGQDNOIGFBYKF-UHFFFAOYSA-N Ethoxyacetic acid Natural products CCOCC(O)=O YZGQDNOIGFBYKF-UHFFFAOYSA-N 0.000 abstract 1
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 description 34
- 239000000243 solution Substances 0.000 description 18
- 241000196324 Embryophyta Species 0.000 description 17
- 235000001169 Brassica oleracea var oleracea Nutrition 0.000 description 10
- 239000003795 chemical substances by application Substances 0.000 description 10
- 150000001875 compounds Chemical class 0.000 description 9
- 239000003995 emulsifying agent Substances 0.000 description 9
- 235000006008 Brassica napus var napus Nutrition 0.000 description 8
- 241001674939 Caulanthus Species 0.000 description 8
- 238000002474 experimental method Methods 0.000 description 8
- 239000002904 solvent Substances 0.000 description 8
- 239000002917 insecticide Substances 0.000 description 7
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 6
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 6
- 241001124076 Aphididae Species 0.000 description 5
- 241000500437 Plutella xylostella Species 0.000 description 5
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 5
- 150000005655 5-chloroquinolines Chemical class 0.000 description 4
- GLUUGHFHXGJENI-UHFFFAOYSA-N Piperazine Chemical compound C1CNCCN1 GLUUGHFHXGJENI-UHFFFAOYSA-N 0.000 description 4
- 235000014113 dietary fatty acids Nutrition 0.000 description 4
- 239000000194 fatty acid Substances 0.000 description 4
- 229930195729 fatty acid Natural products 0.000 description 4
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicon dioxide Inorganic materials O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 4
- 241000272639 Brachycaudus mimeuri Species 0.000 description 3
- YMWUJEATGCHHMB-UHFFFAOYSA-N Dichloromethane Chemical compound ClCCl YMWUJEATGCHHMB-UHFFFAOYSA-N 0.000 description 3
- 239000000843 powder Substances 0.000 description 3
- 238000002360 preparation method Methods 0.000 description 3
- 230000002195 synergetic effect Effects 0.000 description 3
- WCXDHFDTOYPNIE-RIYZIHGNSA-N (E)-acetamiprid Chemical compound N#C/N=C(\C)N(C)CC1=CC=C(Cl)N=C1 WCXDHFDTOYPNIE-RIYZIHGNSA-N 0.000 description 2
- 239000005875 Acetamiprid Substances 0.000 description 2
- 240000007124 Brassica oleracea Species 0.000 description 2
- 235000003899 Brassica oleracea var acephala Nutrition 0.000 description 2
- 235000011301 Brassica oleracea var capitata Nutrition 0.000 description 2
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 description 2
- BAOWVDHYZBLYMB-UHFFFAOYSA-N [F].C1=CC=NC=C1 Chemical compound [F].C1=CC=NC=C1 BAOWVDHYZBLYMB-UHFFFAOYSA-N 0.000 description 2
- 150000003851 azoles Chemical class 0.000 description 2
- MVPPADPHJFYWMZ-UHFFFAOYSA-N chlorobenzene Chemical compound ClC1=CC=CC=C1 MVPPADPHJFYWMZ-UHFFFAOYSA-N 0.000 description 2
- 239000003086 colorant Substances 0.000 description 2
- 239000002552 dosage form Substances 0.000 description 2
- 239000003814 drug Substances 0.000 description 2
- 239000000839 emulsion Substances 0.000 description 2
- 150000002240 furans Chemical class 0.000 description 2
- 238000011835 investigation Methods 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- 239000002245 particle Substances 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- 239000000375 suspending agent Substances 0.000 description 2
- 229920002994 synthetic fiber Polymers 0.000 description 2
- 239000002562 thickening agent Substances 0.000 description 2
- IIZPXYDJLKNOIY-JXPKJXOSSA-N 1-palmitoyl-2-arachidonoyl-sn-glycero-3-phosphocholine Chemical compound CCCCCCCCCCCCCCCC(=O)OC[C@H](COP([O-])(=O)OCC[N+](C)(C)C)OC(=O)CCC\C=C/C\C=C/C\C=C/C\C=C/CCCCC IIZPXYDJLKNOIY-JXPKJXOSSA-N 0.000 description 1
- CFWRDBDJAOHXSH-SECBINFHSA-N 2-azaniumylethyl [(2r)-2,3-diacetyloxypropyl] phosphate Chemical compound CC(=O)OC[C@@H](OC(C)=O)COP(O)(=O)OCCN CFWRDBDJAOHXSH-SECBINFHSA-N 0.000 description 1
- 244000215068 Acacia senegal Species 0.000 description 1
- 239000005995 Aluminium silicate Substances 0.000 description 1
- 241001609695 Anoplophora glabripennis Species 0.000 description 1
- 241000982105 Brevicoryne brassicae Species 0.000 description 1
- 229920002134 Carboxymethyl cellulose Polymers 0.000 description 1
- 241000917107 Eriosoma lanigerum Species 0.000 description 1
- 229920000084 Gum arabic Polymers 0.000 description 1
- 241001465754 Metazoa Species 0.000 description 1
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 description 1
- 239000004372 Polyvinyl alcohol Substances 0.000 description 1
- 241000193943 Pratylenchus Species 0.000 description 1
- 241000201375 Radopholus similis Species 0.000 description 1
- 241000254179 Sitophilus granarius Species 0.000 description 1
- 244000061456 Solanum tuberosum Species 0.000 description 1
- 235000002595 Solanum tuberosum Nutrition 0.000 description 1
- 241000255588 Tephritidae Species 0.000 description 1
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 1
- BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 description 1
- 239000000205 acacia gum Substances 0.000 description 1
- 235000010489 acacia gum Nutrition 0.000 description 1
- 239000003905 agrochemical Substances 0.000 description 1
- 235000012211 aluminium silicate Nutrition 0.000 description 1
- 150000003863 ammonium salts Chemical class 0.000 description 1
- 150000001450 anions Chemical class 0.000 description 1
- 229960000892 attapulgite Drugs 0.000 description 1
- 239000012752 auxiliary agent Substances 0.000 description 1
- 239000000987 azo dye Substances 0.000 description 1
- 239000001768 carboxy methyl cellulose Substances 0.000 description 1
- 235000010948 carboxy methyl cellulose Nutrition 0.000 description 1
- 239000008112 carboxymethyl-cellulose Substances 0.000 description 1
- 239000004927 clay Substances 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 239000012895 dilution Substances 0.000 description 1
- 238000010790 dilution Methods 0.000 description 1
- 238000007598 dipping method Methods 0.000 description 1
- 230000000857 drug effect Effects 0.000 description 1
- 239000000428 dust Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 150000004665 fatty acids Chemical class 0.000 description 1
- 210000003608 fece Anatomy 0.000 description 1
- 239000003337 fertilizer Substances 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 235000011389 fruit/vegetable juice Nutrition 0.000 description 1
- 239000003630 growth substance Substances 0.000 description 1
- 125000004836 hexamethylene group Chemical group [H]C([H])([*:2])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[*:1] 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 238000011081 inoculation Methods 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- 239000001023 inorganic pigment Substances 0.000 description 1
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 1
- 239000000787 lecithin Substances 0.000 description 1
- 235000010445 lecithin Nutrition 0.000 description 1
- 229940067606 lecithin Drugs 0.000 description 1
- 231100000053 low toxicity Toxicity 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 239000003094 microcapsule Substances 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 229940042880 natural phospholipid Drugs 0.000 description 1
- 150000002825 nitriles Chemical class 0.000 description 1
- 239000012860 organic pigment Substances 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 1
- 229910052625 palygorskite Inorganic materials 0.000 description 1
- 239000012188 paraffin wax Substances 0.000 description 1
- 239000000825 pharmaceutical preparation Substances 0.000 description 1
- 239000001007 phthalocyanine dye Substances 0.000 description 1
- IBBMAWULFFBRKK-UHFFFAOYSA-N picolinamide Chemical class NC(=O)C1=CC=CC=N1 IBBMAWULFFBRKK-UHFFFAOYSA-N 0.000 description 1
- 230000008654 plant damage Effects 0.000 description 1
- 239000011118 polyvinyl acetate Substances 0.000 description 1
- 229920002689 polyvinyl acetate Polymers 0.000 description 1
- 229920002451 polyvinyl alcohol Polymers 0.000 description 1
- 235000019422 polyvinyl alcohol Nutrition 0.000 description 1
- 230000002265 prevention Effects 0.000 description 1
- 239000010453 quartz Substances 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 239000002689 soil Substances 0.000 description 1
- 239000004550 soluble concentrate Substances 0.000 description 1
- 241000894007 species Species 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 229920001059 synthetic polymer Polymers 0.000 description 1
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 1
- 239000004563 wettable powder Substances 0.000 description 1
Landscapes
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
This application discloses a kind of insecticidal active ingredient of the Pesticidal combination containing flonicamid and safener to be made up of flonicamid and safener, and described safener is at least one of cloquitocet_mexyl, fenchlorazole, isoxadifen, mefenpyrdiethyl, furilazole, fenclorim, naphthalic anhydride, chlorine oxalene peace, benoxacor, cyometrinil, solution careless amine, MG191, the ethoxyacetic acid ester of 5 chloroquinoline 8 and gibberellin；The Pesticidal combination is used to prevent and treat the various pests such as Homoptera, coleoptera, Lepidoptera, Diptera and nematode；Pesticidal combination has good insecticidal activity, while has good plant tolerance, available for the insect prevented and treated in various crops；The Pesticidal combination of the present invention plant emergence phase and can go out postemergence application, be particularly suitable for use in and carry out seed treatment prior to seeding, protected seed using the Pesticidal combination of the present invention and just had especially great meaning in the plant of rudiment.
Description
Technical field
The present invention relates to technical field of insecticide, and in particular to a kind of Insecticidal combinations containing flonicamid and safener
Thing.
Background technology
Flonicamid is a kind of novel low-toxicity picolinamide class insect growth regulator, IGR insecticides, and flonicamid has
There are interior suction and conductibility, the sucking pest such as plant leaf blade, aphid feeding suction can be transmitted to by plant roots, stem
After water with flonicamid, it can prevent to inhale juice by rapid, occur completely without excreta within an hour, finally
It is dead because hungry.
But the tolerance of crop is poor during flonicamid exclusive use, and insecticidal activity compares during its exclusive use
Difference, when the concentration of pharmaceutical preparation is higher, although the death rate of insect can be improved, easily remained in crop；And medicine
When the concentration of preparation is relatively low, and the death rate of insect is relatively low.
The content of the invention
To solve the above problems, it is an object of the invention to provide a kind of Insecticidal combinations containing flonicamid and safener
Thing, Pesticidal combination of the invention are used to prevent and treat the various pests such as Homoptera, coleoptera, Lepidoptera, Diptera and nematode.
The present invention to achieve the above object, is achieved through the following technical solutions：
A kind of insecticidal active ingredient of the Pesticidal combination containing flonicamid and safener is by flonicamid and peace
Full agent composition, described safener be cloquitocet_mexyl, fenchlorazole, isoxadifen, mefenpyrdiethyl, furilazole, fenclorim,
Naphthalic anhydride, chlorine oxalene peace, benoxacor, cyometrinil, the careless amine of solution, MG191,5- chloroquinolines -8- ethoxyacetic acids ester and red mould
At least one of element；The mass ratio of flonicamid and safener is 1: 0.001 ~ 1.
Further to realize the purpose of the present invention, following technical scheme can also be used：
Preferably, safener be cloquitocet_mexyl, fenchlorazole, isoxadifen, mefenpyrdiethyl, furilazole, fenclorim,
Naphthalic anhydride, chlorine oxalene peace, benoxacor, cyometrinil, the careless amine of solution, MG191,5- chloroquinolines -8- ethoxyacetic acids ester and red mould
At least three kinds in element；The mass ratio of flonicamid and safener is 1: 0.01 ~ 0.7.
Preferably, the mass ratio of flonicamid and safener is 1: 0.1 ~ 0.5.
Preferably, the mass ratio of flonicamid and safener is 1: 0.3.
Preferably, a kind of insecticidal active ingredient of the Pesticidal combination containing flonicamid and safener, with parts by weight
Meter, is consisted of the following composition：10 ~ 50 parts of flonicamid, 0.1 ~ 2 part of chlorine oxalene peace, 0.1 ~ 2 part of cyometrinil and gibberellin
0.1 ~ 2 part.
Preferably, a kind of insecticidal active ingredient of the Pesticidal combination containing flonicamid and safener, with parts by weight
Meter, is consisted of the following composition：1 part of 10 parts of flonicamid, 1 part of chlorine oxalene peace, 1 part of cyometrinil and gibberellin.
Preferably, a kind of insecticidal active ingredient of the Pesticidal combination containing flonicamid and safener, with parts by weight
Meter, is consisted of the following composition：10 ~ 50 parts of flonicamid, 0.1 ~ 1 part of cloquitocet_mexyl, 0.1 ~ 1 part of isoxadifen, chlorine oxalene peace
0.1 ~ 1 part of 0.1 ~ 1 part, 0.1 ~ 1 part of cyometrinil and gibberellin.
Preferably, a kind of insecticidal active ingredient of the Pesticidal combination containing flonicamid and safener, with parts by weight
Meter, is consisted of the following composition：10 ~ 50 parts of flonicamid, 0.1 ~ 1 part of cloquitocet_mexyl, 0.1 ~ 1 part of isoxadifen, furans solution grass
0.1 ~ 0.5 part of azoles, 0.1 ~ 0.5 part of fenclorim, chlorine oxalene pacify 0.1 ~ 1 part, 0.1 ~ 1 part of cyometrinil, 0.1 ~ 0.5 part of MG191,
0.1 ~ 1 part of 0.1 ~ 0.5 part of 5- chloroquinoline -8- ethoxyacetic acids ester and gibberellin.
Preferably, a kind of insecticidal active ingredient of the Pesticidal combination containing flonicamid and safener, with parts by weight
Meter, is consisted of the following composition：10 parts of flonicamid, 0.6 part of cloquitocet_mexyl, 0.6 part of isoxadifen, chlorine oxalene pacify 0.6 part, solution
0.6 part of 0.6 part of careless amine nitrile and gibberellin.
Preferably, a kind of insecticidal active ingredient of the Pesticidal combination containing flonicamid and safener, with parts by weight
Meter, is consisted of the following composition：15 parts of flonicamid, 0.7 part of cloquitocet_mexyl, 0.8 part of isoxadifen, 0.2 part of furilazole,
0.3 part of fenclorim, 0.7 part of chlorine oxalene peace, 0.8 part of cyometrinil, 0.2 part of MG191,5- chloroquinoline -8- ethoxyacetic acids ester 0.3
0.5 part of part and gibberellin.
The advantage of the invention is that：
Pesticidal combination obtained by the flonicamid and safener combination of the present invention has good insecticidal activity, simultaneously
With good plant tolerance, available for the insect prevented and treated in various crops；The Pesticidal combination of the present invention can go out in plant
Seedling stage and go out postemergence application, be particularly suitable for use in and carry out seed treatment prior to seeding, because seed is sown into what is grown after soil
The root and bud of plant are especially sensitive, though the death for also resulting in whole plant is injured by very little, therefore using suitable
Pesticidal combination protects seed and just has especially great meaning in the plant of rudiment.
Pesticidal combination obtained by flonicamid and safener combination of the present invention has special absorbability energy, using this
Pesticidal combination processing seed can not only protect seed in itself, and the plant that grows up to can be protected after emergence from pest attacks,
Therefore the processing to crop in the at seeding time or hereafter short period can be saved.
Safener can improve the insecticidal activity of flonicamid, fluorine pyridine worm of the invention in the Pesticidal combination of the present invention
Acid amides has compared with each individually reactive compound in safener and cooperates with increased insecticidal activity, and suppress fluorine pyridine
Insect amide to just rudiment plant injury.
The Pesticidal combination content of the type of service prepared by commercial preparation can change in wider scope.Type of service
Pesticidal combination concentration can be 0.0000001 to 95 weight %, preferably 0.0001 to 1 weight %.
Embodiment
A kind of insecticidal active ingredient of the Pesticidal combination containing flonicamid and safener is by flonicamid and peace
Full agent composition, described safener be cloquitocet_mexyl, fenchlorazole, isoxadifen, mefenpyrdiethyl, furilazole, fenclorim,
Naphthalic anhydride, chlorine oxalene peace, benoxacor, cyometrinil, the careless amine of solution, MG191,5- chloroquinolines -8- ethoxyacetic acids ester and red mould
At least one of element；The mass ratio of flonicamid and safener is 1: 0.001 ~ 1.
Further to realize the purpose of the present invention, following technical scheme can also be used：
Preferably, safener be cloquitocet_mexyl, fenchlorazole, isoxadifen, mefenpyrdiethyl, furilazole, fenclorim,
Naphthalic anhydride, chlorine oxalene peace, benoxacor, cyometrinil, the careless amine of solution, MG191,5- chloroquinolines -8- ethoxyacetic acids ester and red mould
At least three kinds in element；The mass ratio of flonicamid and safener is 1: 0.01 ~ 0.7, currently preferred flonicamid
The killing ability of flonicamid can be greatly improved than scope with the quality of safener.
Preferably, the mass ratio of flonicamid and safener be 1: 0.1 ~ 0.5, currently preferred flonicamid and
The mass ratio of safener can not only improve the killing ability of flonicamid, and have good Plant Tolerance after crop use
Property.
Preferably, the mass ratio of flonicamid and safener is 1: 0.3, currently preferred flonicamid and safety
The mass ratio of agent, it is particluarly suitable for the processing of seeds before seeding, seed can not only be protected in itself, and length after emergence can be protected
Into plant from pest attacks, can save at seeding time or the hereafter processing in the short period to crop.
Preferably, a kind of insecticidal active ingredient of the Pesticidal combination containing flonicamid and safener, with parts by weight
Meter, is consisted of the following composition：10 ~ 50 parts of flonicamid, 0.1 ~ 2 part of chlorine oxalene peace, 0.1 ~ 2 part of cyometrinil and gibberellin
0.1 ~ 2 part, the Insecticidal combinations compositions of preferred ingredient of the present invention are each single wherein in flonicamid and safener
Reactive compound is compared, and has the most significant increased insecticidal effect of collaboration, and can reduce the concentration of flonicamid, is subtracted
Its few residual in crop.
Preferably, a kind of insecticidal active ingredient of the Pesticidal combination containing flonicamid and safener, with parts by weight
Meter, is consisted of the following composition：1 part of 10 parts of flonicamid, 1 part of chlorine oxalene peace, 1 part of cyometrinil and gibberellin.
Preferably, a kind of insecticidal active ingredient of the Pesticidal combination containing flonicamid and safener, with parts by weight
Meter, is consisted of the following composition：10 ~ 50 parts of flonicamid, 0.1 ~ 1 part of cloquitocet_mexyl, 0.1 ~ 1 part of isoxadifen, chlorine oxalene peace
0.1 ~ 1 part of 0.1 ~ 1 part, 0.1 ~ 1 part of cyometrinil and gibberellin.
Preferably, a kind of insecticidal active ingredient of the Pesticidal combination containing flonicamid and safener, with parts by weight
Meter, is consisted of the following composition：10 ~ 50 parts of flonicamid, 0.1 ~ 1 part of cloquitocet_mexyl, 0.1 ~ 1 part of isoxadifen, furans solution grass
0.1 ~ 0.5 part of azoles, 0.1 ~ 0.5 part of fenclorim, chlorine oxalene pacify 0.1 ~ 1 part, 0.1 ~ 1 part of cyometrinil, 0.1 ~ 0.5 part of MG191,
0.1 ~ 1 part of 0.1 ~ 0.5 part of 5- chloroquinoline -8- ethoxyacetic acids ester and gibberellin.
Preferably, a kind of insecticidal active ingredient of the Pesticidal combination containing flonicamid and safener, with parts by weight
Meter, is consisted of the following composition：10 parts of flonicamid, 0.6 part of cloquitocet_mexyl, 0.6 part of isoxadifen, chlorine oxalene pacify 0.6 part, solution
0.6 part of 0.6 part of careless amine nitrile and gibberellin.
Preferably, a kind of insecticidal active ingredient of the Pesticidal combination containing flonicamid and safener, with parts by weight
Meter, is consisted of the following composition：15 parts of flonicamid, 0.7 part of cloquitocet_mexyl, 0.8 part of isoxadifen, 0.2 part of furilazole,
0.3 part of fenclorim, 0.7 part of chlorine oxalene peace, 0.8 part of cyometrinil, 0.2 part of MG191,5- chloroquinoline -8- ethoxyacetic acids ester 0.3
Part and 0.5 part of gibberellin, specific composition and its ratio, can bring up to the insecticidal activity of flonicamid in the preferred compositions
Optimal value, its optimal Synergistic insecticidal activity can be played between each component.
The insecticidal active ingredient of Pesticidal combination of the present invention is made up of flonicamid and safener, the insecticidal active ingredient
The auxiliary agents such as existing surfactant, assistant agent solvent, solid carrier, emulsifying agent, thickener and coloring agent can be selected, with existing
Mode be prepared into soluble concentrate, emulsion, wettable powder, suspending agent, pulvis, powder agent, paste, soluble powder, particle
The agricultural chemicals such as the microcapsule formulations in agent, outstanding newborn concentrating agents, natural and synthetic material, and polymer through reactive compound dipping
Common dosage forms.
Water can be used as solvent in the insecticidal active ingredient of Pesticidal combination of the present invention, and uses following organic solvent conducts
Secondary solvent, suitable secondary solvent mainly have dimethylbenzene, toluene, chlorobenzene, vinyl chloride, dichloromethane, hexamethylene, paraffin, low
Level alcohol compound and alkanones compound.Solid carrier mainly includes ammonium salt, the natural minerals crushed, such as clay, quartz
Powder, kaolin, attapulgite or diatomite；The synthetic material of crushing, such as high dispersive silica, aluminum oxide and silicate.
Suitable emulsifying agent such as nonionic or anion emulsifier, such as polyoxyethylene fatty acid ester, polyoxyethylene aliphatic alcohol ether class chemical combination
Thing, thickener mainly include carboxymethyl cellulose, gum arabic, polyvinyl alcohol and polyvinyl acetate and natural phospholipid, such as
Cephalin and lecithin；Coloring agent is mainly inorganic pigment and organic pigment, such as iron oxide, titanium oxide, azo dyes and metal
Phthalocyanine dye.
The insecticidal active ingredient of Pesticidal combination of the present invention can with itself, its dosage form or by the preparation enter one
The type of service use of prepared by step dilution, such as ready to use solution agent, suspending agent, seed coat agent, emulsion, pulvis, paste and particle
Agent.It may be carried out by conventional means administration, such as pouring, spraying, atomizing, dust, seed treatment or spread fertilizer over the fields.
The rate of application of the insecticidal active ingredient of Pesticidal combination of the present invention can change within the specific limits；In various factors
In, rate of application depends primarily on weather and edphic factor.In general, rate of application is 0.005 to 5kg per hectares, preferably 0.01 ~
2kg per hectares, particularly preferred 0.05 to 1.0kg per hectares.
The insecticidal active ingredient of Pesticidal combination of the present invention can handle all plants and plant parts, exist suitable for preventing and treating
The animal pest run into agricultural, preferably Homoptera, coleoptera, Lepidoptera, Diptera pest and nematode.Above-mentioned insect includes
Such as wild cabbage aleyrodid, cabbage aphid, eriosoma lanigerum, colorado potato bug, grain weevil category kind, diamond-back moth, black-tailed fruit flies, Pratylenchus
Kind, Radopholus similis Throne etc., insecticidal range is wide.
Embodiment 1
A kind of insecticidal active ingredient of the Pesticidal combination containing flonicamid and safener, in parts by weight, by fluorine
0.001 part of 1 part of pyridine insect amide, cloquitocet_mexyl composition.
Embodiment 2
A kind of insecticidal active ingredient of the Pesticidal combination containing flonicamid and safener, in parts by weight, by fluorine
0.001 part of 1 part of pyridine insect amide, isoxadifen composition.
Embodiment 3
A kind of insecticidal active ingredient of the Pesticidal combination containing flonicamid and safener, in parts by weight, by fluorine
1 part of pyridine insect amide, chlorine oxalene pacify 1 part of composition.
Embodiment 4
A kind of insecticidal active ingredient of the Pesticidal combination containing flonicamid and safener, in parts by weight, by fluorine
1 part of 1 part of pyridine insect amide, cyometrinil composition.
Embodiment 5
A kind of insecticidal active ingredient of the Pesticidal combination containing flonicamid and safener, in parts by weight, by fluorine
0.01 part of 1 part of pyridine insect amide, MG191 composition.
Embodiment 6
A kind of insecticidal active ingredient of the Pesticidal combination containing flonicamid and safener, in parts by weight, by fluorine
0.7 part of 1 part of pyridine insect amide, 5- chloroquinoline -8- ethoxyacetic acids ester composition.
Embodiment 7
A kind of insecticidal active ingredient of the Pesticidal combination containing flonicamid and safener, in parts by weight, by fluorine
0.001 part of 1 part of pyridine insect amide, 0.001 part of cloquitocet_mexyl and furilazole composition.
Embodiment 8
A kind of insecticidal active ingredient of the Pesticidal combination containing flonicamid and safener, in parts by weight, by fluorine
0.001 part of 1 part of pyridine insect amide, 0.001 part of fenchlorazole and isoxadifen composition.
Embodiment 9
A kind of insecticidal active ingredient of the Pesticidal combination containing flonicamid and safener, in parts by weight, by fluorine
0.5 part of 1 part of pyridine insect amide, 0.5 part of fenclorim and benoxacor composition.
Embodiment 10
A kind of insecticidal active ingredient of the Pesticidal combination containing flonicamid and safener, in parts by weight, by fluorine
0.5 part of 1 part of pyridine insect amide, 0.5 part of cyometrinil and MG191 composition.
Embodiment 11
A kind of insecticidal active ingredient of the Pesticidal combination containing flonicamid and safener, in parts by weight, by fluorine
1 part of pyridine insect amide, 0.05 part of naphthalic anhydride and chlorine oxalene pacify 0.05 part of composition.
Embodiment 12
A kind of insecticidal active ingredient of the Pesticidal combination containing flonicamid and safener, in parts by weight, by fluorine
0.004 part of 1 part of pyridine insect amide, 0.003 part of cloquitocet_mexyl, 0.003 part of fenchlorazole and isoxadifen composition.
Embodiment 13
A kind of insecticidal active ingredient of the Pesticidal combination containing flonicamid and safener, in parts by weight, by fluorine
0.006 part of 1 part of pyridine insect amide, 0.002 part of mefenpyrdiethyl, 0.002 part of furilazole and fenclorim composition.
Embodiment 14
A kind of insecticidal active ingredient of the Pesticidal combination containing flonicamid and safener, in parts by weight, by fluorine
1 part of pyridine insect amide, 0.2 part of naphthalic anhydride, chlorine oxalene pacify 0.3 part and 0.2 part of composition of benoxacor.
Embodiment 15
A kind of insecticidal active ingredient of the Pesticidal combination containing flonicamid and safener, in parts by weight, by fluorine
0.1 part of 1 part of pyridine insect amide, 0.2 part of MG191,0.4 part of 5- chloroquinoline -8- ethoxyacetic acids ester and gibberellin composition.
Embodiment 16
A kind of insecticidal active ingredient of the Pesticidal combination containing flonicamid and safener, in parts by weight, by fluorine
0.008 part of 1 part of pyridine insect amide, 0.002 part of cloquitocet_mexyl, 0.02 part of isoxadifen and naphthalic anhydride composition.
Embodiment 17
A kind of insecticidal active ingredient of the Pesticidal combination containing flonicamid and safener, in parts by weight, by fluorine
1 part of pyridine insect amide, 0.01 part of fenchlorazole, chlorine oxalene pacify 0.01 part of 0.01 part, 5- chloroquinoline -8- ethoxyacetic acids ester composition.
Embodiment 18
A kind of insecticidal active ingredient of the Pesticidal combination containing flonicamid and safener, in parts by weight, by fluorine
0.002 part of 1 part of pyridine insect amide, 0.002 part of cloquitocet_mexyl, 0.003 part of naphthalic anhydride, 0.003 part of cyometrinil and gibberellin group
Into.
Embodiment 19
A kind of insecticidal active ingredient of the Pesticidal combination containing flonicamid and safener, in parts by weight, by fluorine
1 part of pyridine insect amide, 0.002 part of isoxadifen, 0.002 part of mefenpyrdiethyl, 0.002 part of fenclorim, careless 0.002 part of the amine of solution,
0.002 part of composition of 5- chloroquinoline -8- ethoxyacetic acids ester.
Embodiment 20
A kind of insecticidal active ingredient of the Pesticidal combination containing flonicamid and safener, in parts by weight, by fluorine
1 part of pyridine insect amide, 0.1 part of fenchlorazole, 0.2 part of fenclorim, chlorine oxalene pacify 0.1 part, 0.1 part of cyometrinil, 0.1 part of MG191 and
0.1 part of composition of gibberellin.
Embodiment 21
A kind of insecticidal active ingredient of the Pesticidal combination containing flonicamid and safener, in parts by weight, by fluorine
1 part of pyridine insect amide, 0.1 part of cloquitocet_mexyl, 0.1 part of isoxadifen, 0.1 part of furilazole, 0.1 part of naphthalic anhydride, solution grass
0.1 part of 0.1 part of piperazine, 0.1 part of the careless amine of solution and 5- chloroquinoline -8- ethoxyacetic acids ester composition.
Embodiment 22
A kind of insecticidal active ingredient of the Pesticidal combination containing flonicamid and safener, in parts by weight, by fluorine
1 part of pyridine insect amide, 0.01 part of fenchlorazole, 0.02 part of mefenpyrdiethyl, 0.03 part of fenclorim, chlorine oxalene pacify 0.04 part, the careless amine of solution
0.08 part of 0.05 part of nitrile, 0.06 part of MG191,0.07 part of 5- chloroquinoline -8- ethoxyacetic acids ester and gibberellin composition.
Embodiment 23
A kind of insecticidal active ingredient of the Pesticidal combination containing flonicamid and safener, in parts by weight, by fluorine
1 part of pyridine insect amide, 0.09 part of cloquitocet_mexyl, 0.08 part of isoxadifen, 0.07 part of furilazole, 0.06 part of fenclorim, solution grass
0.05 part of piperazine, solution careless 0.01 part of 0.04 part of amine, 0.03 part of MG191,0.02 part of 5- chloroquinoline -8- ethoxyacetic acids ester and gibberellin
Composition.
Embodiment 24
A kind of insecticidal active ingredient of the Pesticidal combination containing flonicamid and safener, in parts by weight, by fluorine
0.01 part of 1 part of pyridine insect amide, 0.01 part of isoxadifen, 0.05 part of mefenpyrdiethyl, 0.03 part of furilazole and fenclorim
Composition.
Embodiment 25
A kind of insecticidal active ingredient of the Pesticidal combination containing flonicamid and safener, in parts by weight, by fluorine
1 part of pyridine insect amide, 0.1 part of fenclorim, 0.1 part of naphthalic anhydride, 0.1 part of chlorine oxalene peace, 0.1 part of benoxacor and cyometrinil
0.1 part of composition.
Embodiment 26
A kind of insecticidal active ingredient of the Pesticidal combination containing flonicamid and safener, in parts by weight, by fluorine
1 part of pyridine insect amide, solution careless 0.1 part of amine, 0.1 part of MG191,0.1 part of 5- chloroquinoline -8- ethoxyacetic acids ester and 0.1 part of group of gibberellin
Into.
Embodiment 27
A kind of insecticidal active ingredient of the Pesticidal combination containing flonicamid and safener, in parts by weight, by fluorine
0.1 part of 1 part of pyridine insect amide, 0.1 part of cloquitocet_mexyl, 0.1 part of fenchlorazole and isoxadifen composition.
Embodiment 28
A kind of insecticidal active ingredient of the Pesticidal combination containing flonicamid and safener, in parts by weight, by fluorine
1 part of pyridine insect amide, 0.06 part of mefenpyrdiethyl, 0.06 part of furilazole, 0.06 part of fenclorim, 0.06 part of naphthalic anhydride and
Chlorine oxalene pacifies 0.06 part of composition.
Embodiment 29
A kind of insecticidal active ingredient of the Pesticidal combination containing flonicamid and safener, in parts by weight, by fluorine
1 part of pyridine insect amide, 0.05 part of chlorine oxalene peace, 0.05 part of benoxacor, 0.05 part of cyometrinil, careless 0.05 part of the amine of solution, MG191
0.05 part and 0.05 part of composition of 5- chloroquinoline -8- ethoxyacetic acids ester.
Embodiment 30
A kind of insecticidal active ingredient of the Pesticidal combination containing flonicamid and safener, in parts by weight, by fluorine
0.1 part of 1 part of pyridine insect amide, 0.1 part of fenchlorazole, 0.05 part of benoxacor, 0.05 part of cyometrinil and gibberellin composition.
Embodiment 31
A kind of insecticidal active ingredient of the Pesticidal combination containing flonicamid and safener, in parts by weight, by fluorine
10 parts of pyridine insect amide, chlorine oxalene pacify 0.1 part of 0.1 part, 0.1 part of cyometrinil and gibberellin composition.
Embodiment 32
A kind of insecticidal active ingredient of the Pesticidal combination containing flonicamid and safener, in parts by weight, by fluorine
50 parts of pyridine insect amide, chlorine oxalene pacify 2 parts of 2 parts, 2 parts of cyometrinil and gibberellin compositions.
Embodiment 33
A kind of insecticidal active ingredient of the Pesticidal combination containing flonicamid and safener, in parts by weight, by fluorine
30 parts of pyridine insect amide, chlorine oxalene pacify 1 part of 1 part, 1 part of cyometrinil and gibberellin composition.
Embodiment 34
A kind of insecticidal active ingredient of the Pesticidal combination containing flonicamid and safener, in parts by weight, by fluorine
10 parts of pyridine insect amide, chlorine oxalene pacify 1 part of 1 part, 1 part of cyometrinil and gibberellin composition.
Embodiment 35
A kind of insecticidal active ingredient of the Pesticidal combination containing flonicamid and safener, in parts by weight, by with
Lower composition composition：50 parts of flonicamid, 0.1 part of cloquitocet_mexyl, 0.1 part of isoxadifen, chlorine oxalene pacify 0.1 part, cyometrinil
0.1 part and 0.1 part of gibberellin.
Embodiment 36
A kind of insecticidal active ingredient of the Pesticidal combination containing flonicamid and safener, in parts by weight, by with
Lower composition composition：10 parts of flonicamid, 1 part of cloquitocet_mexyl, 1 part of isoxadifen, chlorine oxalene pacify 1 part, 1 part of cyometrinil and red
1 part of mycin.
Embodiment 37
A kind of insecticidal active ingredient of the Pesticidal combination containing flonicamid and safener, in parts by weight, by with
Lower composition composition：20 parts of flonicamid, 0.1 part of cloquitocet_mexyl, 1 part of isoxadifen, chlorine oxalene pacify 1 part, 1 part of cyometrinil and
0.1 part of gibberellin.
Embodiment 38
A kind of insecticidal active ingredient of the Pesticidal combination containing flonicamid and safener, in parts by weight, by with
Lower composition composition：20 parts of flonicamid, 0.4 part of cloquitocet_mexyl, 0.1 part of isoxadifen, chlorine oxalene pacify 0.5 part, cyometrinil
0.5 part and 1 part of gibberellin.
Embodiment 39
A kind of insecticidal active ingredient of the Pesticidal combination containing flonicamid and safener, in parts by weight, by with
Lower composition composition：10 parts of flonicamid, 0.6 part of cloquitocet_mexyl, 0.6 part of isoxadifen, chlorine oxalene pacify 0.6 part, cyometrinil
0.6 part and 0.6 part of gibberellin.
Embodiment 40
A kind of insecticidal active ingredient of the Pesticidal combination containing flonicamid and safener, in parts by weight, by with
Lower composition composition：50 parts of flonicamid, 0.1 part of cloquitocet_mexyl, 0.1 part of isoxadifen, 0.1 part of furilazole, fenclorim
0.1 part, chlorine oxalene pacify 0.1 part, 0.1 part of cyometrinil, 0.1 part of MG191,0.1 part of 5- chloroquinoline -8- ethoxyacetic acids ester and red
0.1 part of mycin.
Embodiment 41
A kind of insecticidal active ingredient of the Pesticidal combination containing flonicamid and safener, in parts by weight, by with
Lower composition composition：10 parts of flonicamid, 1 part of cloquitocet_mexyl, 1 part of isoxadifen, 0.5 part of furilazole, fenclorim 0.5
1 part of part, 1 part of chlorine oxalene peace, 1 part of cyometrinil, 0.5 part of MG191,0.5 part of 5- chloroquinoline -8- ethoxyacetic acids ester and gibberellin.
Embodiment 42
A kind of insecticidal active ingredient of the Pesticidal combination containing flonicamid and safener, in parts by weight, by with
Lower composition composition：30 parts of flonicamid, 0.3 part of cloquitocet_mexyl, 0.5 part of isoxadifen, 0.3 part of furilazole, fenclorim
0.2 part, chlorine oxalene pacify 0.4 part, 0.6 part of cyometrinil, 0.2 part of MG191,0.3 part of 5- chloroquinoline -8- ethoxyacetic acids ester and red
0.7 part of mycin.
Embodiment 43
A kind of insecticidal active ingredient of the Pesticidal combination containing flonicamid and safener, in parts by weight, by with
Lower composition composition：15 parts of flonicamid, 0.7 part of cloquitocet_mexyl, 0.8 part of isoxadifen, 0.2 part of furilazole, fenclorim
0.3 part, chlorine oxalene pacify 0.7 part, 0.8 part of cyometrinil, 0.2 part of MG191,0.3 part of 5- chloroquinoline -8- ethoxyacetic acids ester and red
0.5 part of mycin.
1. black peach aphid is tested
Solvent：The toluene of 7 parts by weight, emulsifying agent：The polyoxyethylene fatty acid ester of 2 parts by weight.
To prepare the active insecticidal components of the Pesticidal combination of suitable concn, by the active compound of 1 parts by weight with it is described
Solvent and emulsifying agent mixing, and dope is diluted to required concentration with the water containing emulsifying agent.
Handled in the Pesticidal combination of concentration needed for being immersed by the cabbage leaves of black peach aphid serious infringement.
After required time, per cent death loss is determined, 100% represents to kill all aphids；0% indicates that no aphid is killed
Extremely.
In this experiment, the following reactive compound of the application is relative to being administered alone it can be seen from the experimental result of table 1
Flonicamid show obvious synergistic function：
The result of the black peach aphid of table 1 experiment
| Use composition | Application dosage | The death rate after 1 day（%） |
| Flonicamid | 1ppm | 60 |
| Cloquitocet_mexyl | 0.001ppm | 1 |
| Flonicamid+cloquitocet_mexyl（1：0.001） | 1.001ppm | 80 |
| Isoxadifen | 0.002ppm | 1 |
| Flonicamid+isoxadifen（1：0.002） | 1.002ppm | 78 |
| Mefenpyrdiethyl | 1ppm | 2 |
| Flonicamid+mefenpyrdiethyl（1：1） | 2ppm | 79 |
| Naphthalic anhydride | 0.1ppm | 1 |
| Flonicamid+naphthalic anhydride（1：0.1） | 1.1ppm | 81 |
| Cyometrinil | 0.5ppm | 4 |
| Flonicamid+cyometrinil（1：0.5） | 1.5ppm | 85 |
| MG191 | 0.3ppm | 3 |
| Flonicamid+MG191（1：0.3） | 1.3ppm | 83 |
| Gibberellin | 0.2ppm | 2 |
| Flonicamid+gibberellin（1：0.2） | 1.2ppm | 82 |
2. diamondback moth is tested
Solvent：The dimethylbenzene of 7 parts by weight, emulsifying agent：The polyoxyethylene fatty acid ester of 2 parts by weight.
To prepare the active insecticidal components of the Pesticidal combination of suitable concn, by the active compound of 1 parts by weight with it is described
Solvent and emulsifying agent mixing, and dope is diluted to required concentration with the water containing emulsifying agent.
By cabbage leaves immerse needed for concentration Pesticidal combination in handle, and access diamondback moth when leaf still moistens
（Plutella xylostella, resistant strain）Larva.
After required time, per cent death loss is determined, 100% represents to kill all aphids；0% indicates that no aphid is killed
Extremely.
In this experiment, the following reactive compound of the application is relative to being administered alone it can be seen from the experimental result of table 2
Flonicamid show obvious synergistic function：
The diamondback moth of table 2（Resistant strain）The result of experiment
3. pair embodiment of the present invention carries out wild cabbage aleyrodid crop field containing the Pesticidal combination of flonicamid and safener
Experiment.
By 600m2Experimental plot be divided into 30 cells, the area of each cell is 20m2, planted in each cell
40 plants of wild cabbages, experimental plot surrounding set protection row.
The proportioning for the insecticide that embodiment 1 ~ 43 uses：The polyoxyethylene fatty acid of the parts by weight of dimethylbenzene+2 of 7 parts by weight
The active component of the active compound of the embodiment 1 ~ 43 of the parts by weight of ester+1.Gained insecticide enters according to the usage amount of 0.1kg/ mus
Row field experiment.Insecticide is configured to 1000 times of liquid and carries out field control.
5% acetamiprid insecticidal agent is configured to 1000 times of liquid and carries out field control by comparative example.
The temperature on average on the experiment same day is 28.1 DEG C, and maximum temperature is 32.2 DEG C, and 23.5 DEG C of the lowest temperature, weather is fine,
1 grade of wind-force.
During experiment（In 10 days）Temperature on average be 28.5 DEG C, maximum temperature is 32.8 DEG C, and 23.3 DEG C of the lowest temperature is cloudy
It 3 days, weather condition was good, and drug effect is brought into normal play.
Investigation method：Dispenser is carried out when the quantity of field wild cabbage aleyrodid is more than 100 heads/plant, such as the quantity of wild cabbage aleyrodid
During less than 100 heads/plant, Artificial Inoculation of Anoplophora glabripennis is needed.Before dispenser, each 5 plants of wild cabbage aleyrodid mouth number more than 100 heads/plant of cell selection enter
The listed fixed point investigation of row, singling investigate the insect population and dispenser 1, the work insect population number of 3,5 days of wild cabbage aleyrodid, calculate insect population decline
Rate.
Revision insect recluced rate=（Insect population number after insect population number-dispenser before dispenser）Insect population number × 100% before ÷ dispensers；
Prevention effect of the Pesticidal combination of 3 different embodiments of table to wild cabbage aleyrodid
As can be seen from Table 3, compared to existing acetamiprid insecticidal agent, made using the flonicamid and safener of the present invention
For the active component of Pesticidal combination, Revision insect recluced rate significantly increases, and the insecticidal activity of Pesticidal combination of the present invention with
Safener species increases and increased, and can suitably reduce the concentration of flonicamid in use, to reduce it in agriculture
Medicament residue in crop.
Claims (8)
- A kind of 1. Pesticidal combination containing flonicamid and safener, it is characterised in that：The desinsection of the Pesticidal combination Active component is made up of flonicamid and safener, and described safener is cloquitocet_mexyl, fenchlorazole, isoxadifen, pyrazoles Cloquitocet_mexyl, furilazole, fenclorim, naphthalic anhydride, chlorine oxalene peace, benoxacor, cyometrinil, the careless amine of solution, MG191,5- At least three kinds in chloroquinoline -8- ethoxyacetic acids ester and gibberellin；The mass ratio of flonicamid and safener be 1: 0.1 ~ 0.5。
- 2. the Pesticidal combination according to claim 1 containing flonicamid and safener, it is characterised in that：Fluorine pyridine worm The mass ratio of acid amides and safener is 1: 0.3.
- 3. the Pesticidal combination according to claim 1 containing flonicamid and safener, it is characterised in that：It is described to kill The insecticidal active ingredient of worm composition in parts by weight, consists of the following composition：10 ~ 50 parts of flonicamid, chlorine oxalene peace 0.1 0.1 ~ 2 part of ~ 2 parts, 0.1 ~ 2 part of cyometrinil and gibberellin.
- 4. the Pesticidal combination according to claim 3 containing flonicamid and safener, it is characterised in that：It is described to kill The insecticidal active ingredient of worm composition in parts by weight, consists of the following composition：10 parts of flonicamid, chlorine oxalene pacify 1 part, solution 1 part of 1 part of careless amine nitrile and gibberellin.
- 5. the Pesticidal combination according to claim 1 containing flonicamid and safener, it is characterised in that：It is described to kill The insecticidal active ingredient of worm composition in parts by weight, consists of the following composition：10 ~ 50 parts of flonicamid, cloquitocet_mexyl 0.1 ~ 1 0.1 ~ 1 part of part, 0.1 ~ 1 part of 0.1 ~ 1 part of isoxadifen, chlorine oxalene peace, 0.1 ~ 1 part of cyometrinil and gibberellin.
- 6. the Pesticidal combination according to claim 5 containing flonicamid and safener, it is characterised in that：It is described to kill The insecticidal active ingredient of worm composition in parts by weight, consists of the following composition：It is 10 parts of flonicamid, 0.6 part of cloquitocet_mexyl, double 0.6 part of 0.6 part of isoxazolyl benzenesulfonamide acid, 0.6 part of chlorine oxalene peace, 0.6 part of cyometrinil and gibberellin.
- 7. the Pesticidal combination according to claim 1 containing flonicamid and safener, it is characterised in that：It is described to kill The insecticidal active ingredient of worm composition in parts by weight, consists of the following composition：10 ~ 50 parts of flonicamid, cloquitocet_mexyl 0.1 ~ 1 Part, 0.1 ~ 1 part of isoxadifen, 0.1 ~ 0.5 part of furilazole, 0.1 ~ 0.5 part of fenclorim, chlorine oxalene pacify 0.1 ~ 1 part, solution grass 0.1 ~ 1 part of 0.1 ~ 1 part of amine nitrile, 0.1 ~ 0.5 part of MG191,0.1 ~ 0.5 part of 5- chloroquinoline -8- ethoxyacetic acids ester and gibberellin.
- 8. the Pesticidal combination according to claim 7 containing flonicamid and safener, it is characterised in that：It is described to kill The insecticidal active ingredient of worm composition in parts by weight, consists of the following composition：It is 15 parts of flonicamid, 0.7 part of cloquitocet_mexyl, double 0.8 part of isoxazolyl benzenesulfonamide acid, 0.2 part of furilazole, 0.3 part of fenclorim, 0.7 part of chlorine oxalene peace, 0.8 part of cyometrinil, MG191 0.5 part of 0.2 part, 0.3 part of 5- chloroquinoline -8- ethoxyacetic acids ester and gibberellin.
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510730166.3A CN105265429B (en) | 2015-08-14 | 2015-11-02 | A kind of Pesticidal combination containing flonicamid and safener |
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| CN115281187B (en) * | 2022-08-11 | 2023-11-24 | 北京广源益农化学有限责任公司 | Stable pesticide synergist and preparation method thereof |
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| CN101562968A (en) * | 2006-08-05 | 2009-10-21 | 拜尔作物科学股份公司 | New microemulsion concentrates |
| US20110067612A1 (en) * | 2007-08-10 | 2011-03-24 | Kumiai Chemical Industry Co., Ltd. | Pesticidal composition and method for controlling pest |
| CN104488873A (en) * | 2010-02-19 | 2015-04-08 | 陶氏益农公司 | Synergistic Herbicide/insecticide Composition Containing Certain Pyridine Carboxylic Acids And Certain Insecticides |
| WO2015061171A1 (en) * | 2013-10-22 | 2015-04-30 | Dow Agrosciences Llc | Synergistic pesticidal compositions and related methods |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN101562968A (en) * | 2006-08-05 | 2009-10-21 | 拜尔作物科学股份公司 | New microemulsion concentrates |
| US20110067612A1 (en) * | 2007-08-10 | 2011-03-24 | Kumiai Chemical Industry Co., Ltd. | Pesticidal composition and method for controlling pest |
| CN104488873A (en) * | 2010-02-19 | 2015-04-08 | 陶氏益农公司 | Synergistic Herbicide/insecticide Composition Containing Certain Pyridine Carboxylic Acids And Certain Insecticides |
| WO2015061171A1 (en) * | 2013-10-22 | 2015-04-30 | Dow Agrosciences Llc | Synergistic pesticidal compositions and related methods |
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| WO2021161201A1 (en) | 2020-02-12 | 2021-08-19 | Upl Limited | Method of improving plant growth |
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