CN108026601A - 经涂布钢板及其制造方法 - Google Patents
经涂布钢板及其制造方法 Download PDFInfo
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- CN108026601A CN108026601A CN201680054091.4A CN201680054091A CN108026601A CN 108026601 A CN108026601 A CN 108026601A CN 201680054091 A CN201680054091 A CN 201680054091A CN 108026601 A CN108026601 A CN 108026601A
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- weight
- steel disc
- temperature
- steel billet
- aluminium
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- 229910000831 Steel Inorganic materials 0.000 title claims abstract description 196
- 239000010959 steel Substances 0.000 title claims abstract description 196
- 238000000034 method Methods 0.000 title claims abstract description 39
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 33
- 239000010955 niobium Substances 0.000 claims abstract description 55
- 239000010936 titanium Substances 0.000 claims abstract description 54
- 238000005097 cold rolling Methods 0.000 claims abstract description 34
- 229910052782 aluminium Inorganic materials 0.000 claims abstract description 31
- 229910052710 silicon Inorganic materials 0.000 claims abstract description 30
- 239000011651 chromium Substances 0.000 claims abstract description 29
- 229910052758 niobium Inorganic materials 0.000 claims abstract description 29
- 229910052719 titanium Inorganic materials 0.000 claims abstract description 28
- 239000004411 aluminium Substances 0.000 claims abstract description 27
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims abstract description 27
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims abstract description 26
- 239000010703 silicon Substances 0.000 claims abstract description 26
- 239000011572 manganese Substances 0.000 claims abstract description 25
- GUCVJGMIXFAOAE-UHFFFAOYSA-N niobium atom Chemical compound [Nb] GUCVJGMIXFAOAE-UHFFFAOYSA-N 0.000 claims abstract description 25
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims abstract description 24
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims abstract description 20
- 229910052799 carbon Inorganic materials 0.000 claims abstract description 20
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 claims abstract description 18
- 229910052804 chromium Inorganic materials 0.000 claims abstract description 18
- 238000001816 cooling Methods 0.000 claims abstract description 17
- 238000007598 dipping method Methods 0.000 claims abstract description 16
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 claims abstract description 15
- 229910052748 manganese Inorganic materials 0.000 claims abstract description 15
- 238000005246 galvanizing Methods 0.000 claims abstract description 13
- 239000012535 impurity Substances 0.000 claims abstract description 11
- 238000005098 hot rolling Methods 0.000 claims abstract description 10
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims abstract description 9
- 238000005554 pickling Methods 0.000 claims abstract description 6
- 238000004804 winding Methods 0.000 claims abstract description 6
- 229910001566 austenite Inorganic materials 0.000 claims description 24
- 238000000137 annealing Methods 0.000 claims description 14
- 230000000717 retained effect Effects 0.000 claims description 11
- 229910000859 α-Fe Inorganic materials 0.000 claims description 11
- 229910001563 bainite Inorganic materials 0.000 claims description 10
- 229910000734 martensite Inorganic materials 0.000 claims description 7
- 238000010276 construction Methods 0.000 claims description 6
- 230000006835 compression Effects 0.000 claims description 5
- 238000007906 compression Methods 0.000 claims description 5
- 239000002131 composite material Substances 0.000 claims description 4
- 238000005496 tempering Methods 0.000 claims description 4
- 238000003303 reheating Methods 0.000 abstract description 8
- 239000010960 cold rolled steel Substances 0.000 abstract 1
- 239000002184 metal Substances 0.000 abstract 1
- 229910052751 metal Inorganic materials 0.000 abstract 1
- 238000010438 heat treatment Methods 0.000 description 14
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 11
- 230000000694 effects Effects 0.000 description 9
- 239000000463 material Substances 0.000 description 9
- 230000000052 comparative effect Effects 0.000 description 8
- 230000008569 process Effects 0.000 description 7
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 6
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 6
- 239000005864 Sulphur Substances 0.000 description 6
- 230000008859 change Effects 0.000 description 6
- 229910052757 nitrogen Inorganic materials 0.000 description 6
- 229910052698 phosphorus Inorganic materials 0.000 description 6
- 239000011574 phosphorus Substances 0.000 description 6
- 230000015572 biosynthetic process Effects 0.000 description 5
- 238000010521 absorption reaction Methods 0.000 description 4
- 238000005275 alloying Methods 0.000 description 4
- 239000011248 coating agent Substances 0.000 description 4
- 238000000576 coating method Methods 0.000 description 4
- 239000013078 crystal Substances 0.000 description 4
- 239000013049 sediment Substances 0.000 description 4
- 230000002745 absorbent Effects 0.000 description 3
- 239000002250 absorbent Substances 0.000 description 3
- 150000001722 carbon compounds Chemical class 0.000 description 3
- 230000009467 reduction Effects 0.000 description 3
- 238000005096 rolling process Methods 0.000 description 3
- 238000007493 shaping process Methods 0.000 description 3
- 230000006641 stabilisation Effects 0.000 description 3
- 238000011105 stabilization Methods 0.000 description 3
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 2
- 238000005452 bending Methods 0.000 description 2
- 230000003247 decreasing effect Effects 0.000 description 2
- 239000004744 fabric Substances 0.000 description 2
- 238000005259 measurement Methods 0.000 description 2
- 229920001296 polysiloxane Polymers 0.000 description 2
- 238000010791 quenching Methods 0.000 description 2
- 239000006104 solid solution Substances 0.000 description 2
- 239000003381 stabilizer Substances 0.000 description 2
- 230000009466 transformation Effects 0.000 description 2
- 239000011701 zinc Substances 0.000 description 2
- 229910052725 zinc Inorganic materials 0.000 description 2
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 230000002508 compound effect Effects 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 230000036244 malformation Effects 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 description 1
- 238000010422 painting Methods 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 230000000171 quenching effect Effects 0.000 description 1
- 238000007670 refining Methods 0.000 description 1
- 238000007788 roughening Methods 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 238000010008 shearing Methods 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 230000000087 stabilizing effect Effects 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
Classifications
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- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D9/00—Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor
- C21D9/46—Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor for sheet metals
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- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D1/00—General methods or devices for heat treatment, e.g. annealing, hardening, quenching or tempering
- C21D1/18—Hardening; Quenching with or without subsequent tempering
- C21D1/19—Hardening; Quenching with or without subsequent tempering by interrupted quenching
- C21D1/20—Isothermal quenching, e.g. bainitic hardening
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- C—CHEMISTRY; METALLURGY
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- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D6/00—Heat treatment of ferrous alloys
- C21D6/002—Heat treatment of ferrous alloys containing Cr
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- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D6/00—Heat treatment of ferrous alloys
- C21D6/005—Heat treatment of ferrous alloys containing Mn
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- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
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- C21D6/00—Heat treatment of ferrous alloys
- C21D6/008—Heat treatment of ferrous alloys containing Si
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- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D8/00—Modifying the physical properties by deformation combined with, or followed by, heat treatment
- C21D8/02—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips
- C21D8/0205—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips of ferrous alloys
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- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
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- C21D8/02—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips
- C21D8/0221—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips characterised by the working steps
- C21D8/0226—Hot rolling
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- C21D8/00—Modifying the physical properties by deformation combined with, or followed by, heat treatment
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- C21D8/0221—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips characterised by the working steps
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- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D8/00—Modifying the physical properties by deformation combined with, or followed by, heat treatment
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- C21D8/0284—Application of a separating or insulating coating
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- C22C38/04—Ferrous alloys, e.g. steel alloys containing manganese
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- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
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- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
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- C22C38/26—Ferrous alloys, e.g. steel alloys containing chromium with niobium or tantalum
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- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
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- C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
- C22C38/28—Ferrous alloys, e.g. steel alloys containing chromium with titanium or zirconium
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- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
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- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
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- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
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- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
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- C23C2/0224—Two or more thermal pretreatments
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- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
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- C23C2/34—Hot-dipping or immersion processes for applying the coating material in the molten state without affecting the shape; Apparatus therefor characterised by the shape of the material to be treated
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- C23F—NON-MECHANICAL REMOVAL OF METALLIC MATERIAL FROM SURFACE; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL; MULTI-STEP PROCESSES FOR SURFACE TREATMENT OF METALLIC MATERIAL INVOLVING AT LEAST ONE PROCESS PROVIDED FOR IN CLASS C23 AND AT LEAST ONE PROCESS COVERED BY SUBCLASS C21D OR C22F OR CLASS C25
- C23F17/00—Multi-step processes for surface treatment of metallic material involving at least one process provided for in class C23 and at least one process covered by subclass C21D or C22F or class C25
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Abstract
公开了一种用于制造经涂布钢板的方法。根据本发明的经涂布钢板的制造方法包括:再加热钢坯的步骤,所述钢坯包含0.15‑0.25重量%的碳(C)、大于0重量%但是不大于1.5重量%的硅(Si)、1.5‑2.5重量%的锰(Mn)、大于0重量%但是不大于1.8重量%的铝(Al)、0.3‑1.0重量%的铬(Cr)、大于0重量%但是不大于0.03重量%的钛(Ti)、大于0重量%但是不大于0.03重量%的铌(Nb),余量为铁(Fe)和不可避免的杂质;通过热轧、冷却和卷绕钢坯来制造经热轧钢板的步骤;酸洗经热轧钢板,然后将其冷轧的步骤;在820℃至870℃的温度下使经冷轧钢板退火,然后在350℃至450℃的最终冷却温度下使其冷却的步骤;在450℃至550℃的温度下再次热处理经冷却钢板的步骤;以及对经再次热处理的钢板进行热浸镀锌的步骤。
Description
技术领域
本发明涉及经涂布钢片及其制造方法。更具体地,本发明涉及具有出色的碰撞能量吸收性质和可成形性的经涂布钢片及其制造方法。
背景技术
近几年来,越来越需要具有提高安全性和轻质结构的车辆。响应该需要,已经努力增加应用于车身的材料的强度。然而通常地,随着钢片强度的增加,其伸长减小。因此,当钢片具有一定强度或更高强度时,钢片至拉制部件的形成达到极限。因此,除了上述努力增加钢片强度之外,还努力增加钢片的伸长。该伸长的增加可以扩展拉制部件的应用,并且可以提高拉制部件的冲击能量吸收能力(TS*El),当应用于车身时能提高拉制部件的碰撞能量吸收性质。
与本发明相关的现有技术文献包括韩国未审专利申请公开号2015-0025952(2015年3月11日公开,名称为“高强度的经热轧涂布的钢片及其制造方法”)。
发明内容
技术问题
根据本发明的一个实施方案,提供一种具有出色的机械强度性质(例如碰撞能量吸收性质)的经涂布钢片的制造方法。
根据本发明的另一个实施方案,提供一种具有出色的可成形性的经涂布钢片的制造方法。
根据本发明的又一个实施方案,提供通过上述经涂布钢片的制造方法制得的经涂布钢片。
技术方案
本发明的一方面涉及经涂布钢片的制造方法。在一个实施方案中,经涂布钢片的制造方法包括如下步骤:再加热钢坯,所述钢坯包含0.15-0.25重量%的碳(C)、大于0重量%但是不大于1.5重量%的硅(Si)、1.5-2.5重量%的锰(Mn)、大于0重量%但是不大于1.8重量%的铝(Al)、0.3-1.0重量%的铬(Cr)、大于0重量%但是不大于0.03重量%的钛(Ti)、大于0重量%但是不大于0.03重量%的铌(Nb),余量为铁(Fe)和不可避免的杂质;热轧、冷却和卷绕钢坯,由此制造经热轧钢片;酸洗经热轧钢片,然后冷轧;在820℃和870℃之间的温度下使经冷轧钢片退火,然后在350℃和450℃之间的最终冷却温度下冷却;在450℃和550℃之间的温度下使经冷却钢片回火;并且对经回火钢片进行热浸镀锌。
在一个实施方案中,可以以50-80%的压缩比进行冷轧。
在一个实施方案中,在退火之后可以以10-50℃/秒的冷却速率冷却钢片。
在一个实施方案中,包含的硅(Si)和铝(Al)可以满足如下方程1:
方程1
1.5≤(Si)+(Al)≤3.0
其中Si和Al分别表示钢坯中的硅(Si)和铝(Al)的含量(重量%)。
在一个实施方案中,包含的钛(Ti)和铌(Nb)可以满足如下方程2:
方程2
0.01≤(Ti)+(Nb)≤0.02
其中Ti和Nb分别表示钢坯中的钛(Ti)和铌(Nb)的含量(重量%)。
本发明的又一方面涉及通过上述经涂布钢片的制造方法制造的经涂布钢片。在一个实施方案中,钢片包含0.15-0.25重量%的碳(C)、大于0重量%但是不大于1.5重量%的硅(Si)、1.5-2.5重量%的锰(Mn)、大于0重量%但是不大于1.8重量%的铝(Al)、0.3-1.0重量%的铬(Cr)、大于0重量%但是不大于0.03重量%的钛(Ti)、大于0重量%但是不大于0.03重量%的铌(Nb),余量为铁(Fe)和不可避免的杂质。
在一个实施方案中,经涂布钢片可以具有根据横截面积比包含如下的复合结构:50-70体积%的贝氏体、10-25体积%的铁素体、5-20体积%的马氏体和5-15体积%的残留奥氏体。
在一个实施方案中,经涂布钢片可以具有850-950MPa的拉伸强度(YS)、1180-1350MPa的屈服强度(TS)和10-20%的伸长(EL)。
有益效果
使用根据本发明的经涂布钢片的制造方法制造的经涂布钢片可以具有出色的碰撞能量吸收性质和机械强度,并且还可以具有出色的成形性质,例如弯曲性质和拉制性质。
附图说明
图1显示了根据本发明的实施方案的经涂布钢片的制造方法。
图2为根据本发明的实施方案的第一加热时间表的图。
具体实施方式
下文将详细描述本发明。在如下描述中,当可能不必要地模糊本发明的主题时,将省略相关已知技术或构造的详细描述。
此外,如下说明中使用的术语是考虑其在本发明中的功能而定义的术语,并且可以根据使用者或操作者的意图或者根据惯例进行改变。因此,必须基于说明书中的内容对这些术语进行定义。
本发明的一方面涉及经涂布钢片的制造方法。
图1显示了根据本发明的实施方案的经涂布钢片的制造方法。参考图1,根据一个实施方案的经涂布钢片的制造方法包括:钢坯再加热步骤(S10);热轧步骤(S20);卷绕步骤(S30);冷轧步骤(S40);退火步骤(S50);和热浸镀锌步骤(S60)。
更具体地,经涂布钢片的制造方法的步骤(S10)包括再加热钢坯,所述钢坯包含0.15-0.25重量%的碳(C)、大于0重量%但是不大于1.5重量%的硅(Si)、1.5-2.5重量%的锰(Mn)、大于0重量%但是不大于1.8重量%的铝(Al)、0.3-2.0重量%的铬(Cr)、大于0重量%但是不大于0.03重量%的钛(Ti)、大于0重量%但是不大于0.03重量%的铌(Nb),余量为铁(Fe)和不可避免的杂质。
在步骤(S20)中,在Ar3至Ar3+100℃的终轧温度下热轧钢坯。
在步骤(S30)中,卷绕经热轧钢坯从而制造经热轧卷材。
在步骤(S40)中,经热轧卷材受到解绕和冷轧,从而制造经冷轧钢片。
在步骤(S50)中,经冷轧钢片受到退火、冷却,然后回火。
在一个具体实施方案中,可以在AC1温度和AC3温度之间的两相区域中进行退火,然后可以以例如10℃/秒至50℃/秒的冷却速率冷却经退火钢片。在此,最终冷却温度为Ms温度或更高温度。之后,可以在450℃和550℃之间的温度下使钢片回火。
在步骤(S60)中,对经回火的冷轧钢片进行热浸镀锌。
下文将具体描述根据本发明的经涂布钢片的制造方法的每个步骤。
(S10)再加热钢坯的步骤
该步骤是再加热钢坯的步骤。更具体地,该步骤是再加热钢坯的步骤,所述钢坯包含0.15-0.25重量%的碳(C)、大于0重量%但是不大于1.5重量%的硅(Si)、1.5-2.5重量%的锰(Mn)、大于0重量%但是不大于1.8重量%的铝(Al)、0.3-1.0重量%的铬(Cr)、大于0重量%但是不大于0.03重量%的钛(Ti)、大于0重量%但是不大于0.03重量%的铌(Nb),余量为铁(Fe)和不可避免的杂质。
下文将具体描述钢坯中包含的每种组分的作用和含量。
碳(C)
碳(C)是间隙固溶元素,用于保证残留奥氏体中的碳浓度(Cret:0.6-0.7重量%)从而稳定化奥氏体。基于钢坯的总重量,以0.15-0.25重量%的量包含碳。当以该含量范围包含碳时,其可以具有出色的奥氏体稳定化效果。如果以小于0.15重量%的量包含碳,奥氏体中的碳浓度降低,因此在合金化热处理之后将钢片最终冷却至室温的过程中可能抑制残留奥氏体的形成,如果以大于0.25重量%的量包含碳,钢片的强度和韧度可能降低或者钢片的可焊性可能降低。
硅(Si)
硅(Si)充当稳定化经涂布钢片中的铁素体的元素。硅可以用于细化铁素体从而增加钢片的延展性,并且可以抑制低温碳化物的形成,因此增加奥氏体中的碳浓度。
以钢坯的总重量计,以大于0重量%但是不大于1.5重量%的量包含硅。当以该含量范围包含硅时,其增加奥氏体中的碳浓度并且具有出色的铁素体稳定化效果。如果以大于1.5重量%的量包含硅,其在钢片表面上形成氧化物(例如氧化硅),因此降低热浸镀锌过程中的可涂布性。例如,可以以0.5-1.0重量%的量包含硅。
锰(Mn)
锰(Mn)充当奥氏体稳定化元素,其抑制冷却过程中高温铁素体和低温贝氏体的转化,因此增加冷却过程中马氏体转化的比例。
基于钢坯的总重量,以1.5-2.5重量%的量包含锰。当以该含量范围包含锰时,经涂布钢片的强度和可成形性都很出色。如果以小于1.5重量%的量包含锰,不能保证马氏体转化比例,造成钢片强度的降低,如果以大于2.5重量%的量包含锰,钢片的强度过多增加,因此钢片的伸长降低。
铝(Al)
铝(Al)是铁素体稳定化元素,可以细化铁素体从而增加钢片的延展性。此外,其可以抑制低温碳化物的形成,因此增加奥氏体中的碳浓度。
以钢坯的总重量计,以大于0重量%但是不大于1.8重量%的量包含铝。当以该含量范围包含铝时,根据本发明的钢片具有出色的延展性。如果钢坯不包含铝,在退火过程中两相温度区域中的奥氏体比例迅速降低从而增加钢片的性质变化,并且奥氏体中的碳浓度降低而非增加。如果铝含量大于1.8重量%,会出现如下问题:AC3转化点升高使得第一加热温度升高至高于所需温度的温度,并且促进铁素体晶界处的AlN形成从而造成钢坯脆化。例如,可以以0.5-1.0重量%的量包含铝。
铬(Cr)
铬(Cr)是扩大低温贝氏体面积的元素。加入铬的目的是引发本发明的经涂布钢片中发展板状贝氏体结构并且促进根据本发明的第一次加热、冷却和第二次加热过程中形成稳定化的残留奥氏体。
基于钢坯的总重量,以0.3-2.0重量%的量包含铬。当以该含量范围包含铬时,钢片的强度和可成形性都很出色。如果以小于0.3重量%的量包含铬,难以保证残留奥氏体和强度,如果以大于2.0重量%的量包含铬,由于稳定化低温碳化物而显示出降低钢片延展性的效果。
钛(Ti)和铌(Nb)
钛(Ti)和铌(Nb)可以用于形成TiNbC沉淀物并且细化两相区域热处理过程中的晶粒从而改进可弯曲性。
以钢坯的总重量计,以大于0重量%但是不大于0.03重量%的量包含铌(Nb)和钛(Ti)的每一者。当以该含量范围包含铌(Nb)钛和(Ti)时,具有出色的晶粒细化效果,并且钢片具有出色的可成形性。如果钢坯不包含铌和钛,通过沉淀物细化晶粒的效果不明显,因此降低改进可弯曲性的效果,如果以大于0.03重量%的量包含铌和钛的每一者,会出现由于沉淀物造成钢片伸长减小的问题。
磷(P)和硫(S)
本发明的钢坯中可以包含磷(P)和硫(S)作为不可避免的杂质。磷可以通过固溶增强而增加钢片的强度并且抑制碳化物的形成。
在一个实施方案中,以钢片的总重量计,可以以0.015重量%或更小的量包含磷。当以该含量范围包含磷时,钢片的可焊性和耐腐蚀性都很出色。例如,可以以大于0重量%但是不大于0.015重量%的量包含磷。
硫(S)可以用于形成微细MnS沉淀物从而改进可加工性。在一个实施方案中,以钢片的总重量计,可以以0.002重量%或更小的量包含硫。当以该含量范围包含硫时,钢片具有出色的可弯曲性。例如,可以以大于0重量%但是不大于0.002重量%的量包含硫。
氮(N)
可以包含氮作为不可避免的杂质。氮可以结合至铌等从而形成碳氮化物,因此细化晶粒。然而,可以以0.004重量%或更小的量包含氮。当以该含量范围包含氮时,其可以避免钢片的碰撞能量吸收性能和伸长的减小。例如,可以以大于0重量%但是不大于0.004重量%的量包含氮。
在本发明的一个实施方案中,钢片中包含的硅(Si)和铝(Al)可以满足如下方程1:
方程1
1.5≤(Si)+(Al)≤3.0(重量%),
其中Si和Al分别表示钢坯中的硅(Si)和铝(Al)的含量(重量%)。
当包含的硅(Si)和铝(Al)满足方程1时,容易保证两相区域退火过程中的奥氏体比例,因此获得的钢片具有出色的性质。在一个实施方案中,铝含量可以高于硅含量从而保证涂布性质。
在一个实施方案中,钢片中包含的钛(Ti)和铌(Nb)可以满足如下方程2:
方程2
0.01≤(Ti)+(Nb)≤0.02(重量%),
其中Ti和Nb分别表示钢坯中的钛(Ti)和铌(Nb)的含量(重量%)。
当包含的钛(Ti)和铌(Nb)满足方程2时,显示出两相区域退火过程中出色的细化晶粒效果,因此减轻氢致脆化并且改进可弯曲性。
在一个实施方案中,在1150℃和1250℃之间的钢坯再加热温度(SRT)下再加热钢坯。在该钢坯再加热温度下,分离组分足以形成固溶体,并且容易保证强度。
(S20)热轧步骤
该步骤是在Ar3至Ar3+100℃的终轧温度(FRT)下热轧钢坯的步骤。如果在低于Ar3温度的温度下进行热轧,在两相区域中进行轧制从而造成混晶结构,如果热轧温度高于Ar3+100℃,获得的钢片的物理性质由于晶粒粗化而降低。
在一个实施方案中,可以在850℃和950℃之间的终轧温度下热轧钢坯。当在该终轧温度下进行热轧时,经涂布钢片的刚度和可成形性都很出色。
(S30)卷绕步骤
该步骤是卷绕经热轧钢坯从而制造经热轧卷材的步骤。在一个实施方案中,通过冷却和卷绕经热轧钢坯从而进行卷绕。
在此,为了避免钢坯中包含的组分(例如锰和硅)的表面富集和碳化物的粗化,可以通过剪切淬火法冷却最终热轧的钢坯并且卷绕从而制造经热轧卷材。在一个实施方案中,可以以5℃/秒至100℃/秒的冷却速率冷却经热轧钢坯并且以400℃至550℃的卷绕温度(CT)卷绕经热轧钢坯。当在该温度下进行卷绕时,将抑制晶粒的过快生长,并且获得的钢片具有出色的延展性和可成形性。
(S40)冷轧步骤
该步骤是解绕并且酸洗经热轧卷材的步骤,然后进行冷轧,从而制造经冷轧钢片。进行酸洗的目的是从通过上述热轧过程制造的经热轧卷材上除去轧制鳞皮。
可以以50-80%的压缩比进行冷轧。当以该压缩比进行冷轧时,经热轧结构变形较少,并且容易保证塑性应变比的平面各向异性指数(Δr)值,并且钢片具有出色的伸长和可变形性。
(S50)退火步骤
该步骤是使经冷轧钢片经受退火、淬火然后回火的步骤。图2为根据本发明的实施方案的热处理时间表的图。参考图2,在AC1和AC3之间的两相区域温度下通过第一次加热使经冷轧钢片退火。然后,经退火且经冷轧的钢片淬火至刚刚高于Ms温度的温度,并且在450℃和550℃之间的温度下通过第二次加热使经淬火且经冷轧的钢片回火。
在820至870℃的温度下通过两相区域热处理进行回火。如果退火温度低于820℃,不能获得足够的最初奥氏体比例。另一方面,如果退火温度高于870℃,使用高于所需温度的退火温度,造成经济效率降低。
退火过程之后,将经冷轧钢片冷却至刚刚高于Ms温度(马氏体转换开始温度)的温度。在一个具体实施方案中,在350℃和450℃之间的最终冷却温度下冷却经冷轧钢片。当在该温度下冷却经冷轧钢片时,微结构生长从而避免强度降低。如果最终冷却温度低于350°,钢片具有增加的强度和降低的可加工性,如果最终冷却温度高于450℃,难以保证根据本发明的钢片的拉伸强度。
在一个实施方案中,可以以10至50℃/秒的冷却速率冷却经退火且经冷轧的钢片。在该冷却速率范围内,钢片的性质均匀性出色,并且根据本发明的钢片的刚度和可成形性都很出色。
在450℃和550℃之间的温度下通过第二次加热使经冷却且经冷轧的钢片回火。当进行该回火时,残留奥氏体的比例增加,并且由于结构稳定化使得钢片的机械强度和可成形性都很出色。如果回火温度低于450℃,难以获得贝氏体和残留奥氏体结构,如果回火温度高于550℃,根据本发明的钢片的可成形性降低。
(S60)热浸镀锌步骤
该步骤是对经退火且经回火且经冷轧的钢片进行热浸镀锌的步骤。在一个实施方案中,可以将经冷轧钢片浸入温度为450至510℃的锌浸浴中从而进行热浸镀锌。
在一个实施方案中,热浸镀锌的经冷轧钢片可以进行合金化热处理。合金化热处理可以在475℃至560℃的温度下进行。当合金化热处理在所述温度范围内进行时,热浸镀锌层平稳生长,并且钢片具有出色的涂层粘合。
本发明的另一方面涉及通过经涂布钢片的制造方法制造的经涂布钢片。基于经涂布钢片的总重量,经涂布钢片可以包含0.15-0.25重量%的碳(C)、大于0重量%但是不大于1.5重量%的硅(Si)、1.5-2.5重量%的锰(Mn)、大于0重量%但是不大于1.8重量%的铝(Al)、0.3-2.0重量%的铬(Cr)、大于0重量%但是不大于0.03重量%的钛(Ti)、大于0重量%但是不大于0.03重量%的铌(Nb),余量为铁(Fe)和不可避免的杂质。
在本发明的一个实施方案中,钢坯中包含的硅(Si)和铝(Al)可以满足如下方程1:
方程1
1.5≤(Si)+(Al)≤3.0(重量%),
其中Si和Al分别表示钢坯中的硅(Si)和铝(Al)的含量(重量%)。
当包含的硅(Si)和铝(Al)满足方程1时,经涂布钢片具有出色的性质。在一个实施方案中,铝含量可以高于硅含量从而保证涂布性质。在该情况下,经涂布钢片具有出色的涂层粘合。
在一个实施方案中,钢坯中包含的钛(Ti)和铌(Nb)可以满足如下方程2:
方程2
0.01≤(Ti)+(Nb)≤0.02(重量%),
其中Ti和Nb分别表示钢坯中的钛(Ti)和铌(Nb)的含量(重量%)。
当包含的钛(Ti)和铌(Nb)满足方程2时,其显示出改进经涂布钢片的可弯曲性的出色效果。
在一个实施方案中,经涂布钢片可以保证稳定的残留奥氏体比例,因此具有出色的强度和伸长。经涂布钢片可以包含针状铁素体和贝氏体。
在一个实施方案中,经涂布钢片可以具有根据横截面积比包含如下的复合结构:50-70体积%的贝氏体、10-25体积%的铁素体、5-20体积%的马氏体和5-15体积%的残留奥氏体。
在使用钢坯中的上述铬(Cr)含量和在上述条件下进行的退火过程和回火过程制造的经涂布钢片中,贝氏体中形成片状残留奥氏体。此外,由于铬的作用是扩大贝氏体面积,转化成贝氏体的比例增加,并且残留奥氏体的形状逐渐改变成具有增加的残留奥氏体浓度的薄膜形状,因此钢片具有出色的伸长。
在一个实施方案中,经涂布钢坯可以具有850-950MPa的拉伸强度(YS)、1180-1350MPa的屈服强度(TS)(和权利要求书不一致)、10-20%的伸长(EL)和65-75%的屈服比(YR)。在所述范围内,经涂布钢片的碰撞能量吸收性质、可成形性和刚度都很出色。
使用根据本发明的经涂布钢片的制造方法制造的经涂布钢片在碰撞能量吸收性质、机械强度、可弯曲性和成形性质(例如弯曲性质和拉制性质)方面都很出色。
下文将参考优选实施例进一步详细描述本发明的构造和操作。然而,这些实施例仅为本发明的优选实施例并且不以任何方式限制本发明的范围。
实施例1
在1,220℃的钢坯再加热温度下再加热包含下表1所示量的组分(剩余为铁(Fe)和不可避免的杂质)的钢坯。在860℃的终轧温度下热轧再加热的钢坯,冷却至450℃并且卷绕,由此制造经热轧卷材。经热轧卷材进行解绕、酸洗,然后以70%的压缩比冷轧,由此制造经冷轧钢片。在下表2所示条件下,经冷轧钢片进行退火、淬火和回火。经回火钢片进行热浸镀锌,因此制造经涂布钢片。
实施例2
以与实施例1相同的方式制造经涂布钢片,不同之处在于使用具有表1所示组分和含量的钢坯。
对比实施例1至3
使用包含下表1所示量的组分的钢坯。在下表2所示条件下,对比实施例1至3制得的经冷轧钢片进行退火,然后冷却。只有对比实施例2的钢片进行回火。对比实施例1至3的钢片以与实施例1相同方式进行热浸镀锌,因此制造热浸镀锌的钢片。
对比实施例4
使用包含下表1所示量的组分的钢坯。在下表2所示条件下,经冷轧钢片进行退火,然后冷却。然后在580℃的温度下使钢片回火。然后钢片以与实施例1相同的方式进行热浸镀锌,因此制造热浸镀锌的钢片。
表1
表2
测量实施例1和2和对比实施例1至4中制造的每个经涂布钢片的微观结构分布、拉伸强度(MPa)、屈服强度(MPa)、伸长(%)、屈服比(%)和可弯曲性,测量结果显示于下表3。
表3
通过上表3的结果可见,根据本发明的实施例1和2的经涂布钢片具有的微观结构包含50-70%的贝氏体、10-25%的铁素体、5-20%的马氏体和5-15%的残留奥氏体,并且显示出890MPa或更高的拉伸强度和16%或更高的伸长,表明钢片的冲击强度和可成形性都很出色。然而,在不包含铬的对比实施例1的钢片的情况下,成形性质(例如可弯曲性)比实施例1和2更差,并且拉伸强度也比实施例1和2更低。此外,在不进行退火中的第二次加热过程的对比实施例3的情况下以及在退火中的第二次加热温度超出本发明指明范围的对比实施例4的情况下,钢片的可成形性和刚度降低。
本领域技术人员容易对本发明进行简单修改或变化,并且所述修改或变化全部被视为落入本发明的范围。
Claims (8)
1.一种用于制造经涂布钢片的方法,所述方法包括如下步骤:
(a)再加热钢坯,所述钢坯包含0.15-0.25重量%的碳(C)、大于0重量%但是不大于1.5重量%的硅(Si)、1.5-2.5重量%的锰(Mn)、大于0重量%但是不大于1.8重量%的铝(Al)、0.3-2.0重量%的铬(Cr)、大于0重量%但是不大于0.03重量%的钛(Ti)、大于0重量%但是不大于0.03重量%的铌(Nb),余量为铁(Fe)和不可避免的杂质;
(b)热轧、冷却和卷绕钢坯,由此制造经热轧钢片;
(c)酸洗经热轧钢片,然后冷轧;
(d)在820℃和870℃之间的温度下使经冷轧钢片退火,然后在350℃和450℃之间的最终冷却温度下冷却;
(e)在450℃和550℃之间的温度下使经冷却钢片回火;以及
(f)对经回火钢片进行热浸镀锌。
2.根据权利要求1所述的方法,其中以50-80%的压缩比进行步骤(c)中的冷轧。
3.根据权利要求1所述的方法,其中在步骤(d)的退火之后以10-50℃/秒的冷却速率冷却钢片。
4.根据权利要求1所述的方法,其中包含的硅(Si)和铝(Al)满足如下方程1:
方程1
1.5≤(Si)+(Al)≤3.0(重量%)
其中Si和Al分别表示钢坯中的硅(Si)和铝(Al)的含量(重量%)。
5.根据权利要求1所述的方法,其中包含的钛(Ti)和铌(Nb)满足如下方程2:
方程2
0.01≤(Ti)+(Nb)≤0.02(重量%)
其中Ti和Nb分别表示钢坯中的钛(Ti)和铌(Nb)的含量(重量%)。
6.一种经涂布钢片,其包含:0.15-0.25重量%的碳(C)、大于0重量%但是不大于1.5重量%的硅(Si)、1.5-2.5重量%的锰(Mn)、大于0重量%但是不大于1.8重量%的铝(Al)、0.3-2.0重量%的铬(Cr)、大于0重量%但是不大于0.03重量%的钛(Ti)、大于0重量%但是不大于0.03重量%的铌(Nb),余量为铁(Fe)和不可避免的杂质。
7.根据权利要求6所述的经涂布钢片,其具有复合结构,所述复合结构根据横截面积比包含:50-70体积%的贝氏体、10-25体积%的铁素体、5-20体积%的马氏体和5-15体积%的残留奥氏体。
8.根据权利要求6所述的经涂布钢片,其具有850-950MPa的屈服强度(TS)、1180-1350MPa的拉伸强度(TS)和10-20%的伸长(EL)。
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JP6559886B2 (ja) | 2019-08-14 |
US10941460B2 (en) | 2021-03-09 |
EP3378958A1 (en) | 2018-09-26 |
JP2018529844A (ja) | 2018-10-11 |
US20180265943A1 (en) | 2018-09-20 |
EP3378958A4 (en) | 2019-05-29 |
EP3378958B1 (en) | 2021-08-04 |
WO2017051998A1 (ko) | 2017-03-30 |
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