CN107892589A - A kind of sheen glaze being used in ceramic thin plate - Google Patents
A kind of sheen glaze being used in ceramic thin plate Download PDFInfo
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- CN107892589A CN107892589A CN201810009285.3A CN201810009285A CN107892589A CN 107892589 A CN107892589 A CN 107892589A CN 201810009285 A CN201810009285 A CN 201810009285A CN 107892589 A CN107892589 A CN 107892589A
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- coat enamel
- thin plate
- ceramic thin
- sheen
- weight percentage
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- 239000000919 ceramic Substances 0.000 title claims abstract description 25
- 210000003298 dental enamel Anatomy 0.000 claims abstract description 28
- 230000000694 effects Effects 0.000 claims abstract description 15
- 239000002689 soil Substances 0.000 claims abstract description 15
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 claims abstract description 14
- AYJRCSIUFZENHW-UHFFFAOYSA-L barium carbonate Chemical compound [Ba+2].[O-]C([O-])=O AYJRCSIUFZENHW-UHFFFAOYSA-L 0.000 claims abstract description 14
- 239000000454 talc Substances 0.000 claims abstract description 14
- 235000012222 talc Nutrition 0.000 claims abstract description 14
- 229910052623 talc Inorganic materials 0.000 claims abstract description 14
- 229910052656 albite Inorganic materials 0.000 claims abstract description 13
- GFQYVLUOOAAOGM-UHFFFAOYSA-N zirconium(iv) silicate Chemical compound [Zr+4].[O-][Si]([O-])([O-])[O-] GFQYVLUOOAAOGM-UHFFFAOYSA-N 0.000 claims abstract description 12
- 239000005995 Aluminium silicate Substances 0.000 claims abstract description 8
- 235000012211 aluminium silicate Nutrition 0.000 claims abstract description 8
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 claims abstract description 8
- 229910021532 Calcite Inorganic materials 0.000 claims abstract description 7
- 239000006004 Quartz sand Substances 0.000 claims abstract description 7
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 7
- 239000010434 nepheline Substances 0.000 claims abstract description 7
- 229910052664 nepheline Inorganic materials 0.000 claims abstract description 7
- 239000000843 powder Substances 0.000 claims abstract description 7
- 239000011787 zinc oxide Substances 0.000 claims abstract description 7
- 239000010427 ball clay Substances 0.000 claims abstract description 6
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims 1
- 239000010433 feldspar Substances 0.000 claims 1
- 229910052708 sodium Inorganic materials 0.000 claims 1
- 239000011734 sodium Substances 0.000 claims 1
- 238000010304 firing Methods 0.000 abstract description 4
- 238000002791 soaking Methods 0.000 abstract description 2
- 239000000758 substrate Substances 0.000 abstract description 2
- 230000000007 visual effect Effects 0.000 abstract description 2
- 238000003701 mechanical milling Methods 0.000 description 6
- 238000000498 ball milling Methods 0.000 description 4
- 238000000227 grinding Methods 0.000 description 4
- 239000000463 material Substances 0.000 description 4
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 4
- 235000019832 sodium triphosphate Nutrition 0.000 description 4
- 230000008719 thickening Effects 0.000 description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 4
- 238000005516 engineering process Methods 0.000 description 3
- 239000002994 raw material Substances 0.000 description 3
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 2
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 description 2
- 230000008901 benefit Effects 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 229910052710 silicon Inorganic materials 0.000 description 2
- 239000010703 silicon Substances 0.000 description 2
- 229910052726 zirconium Inorganic materials 0.000 description 2
- 238000010521 absorption reaction Methods 0.000 description 1
- 239000004927 clay Substances 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 238000005265 energy consumption Methods 0.000 description 1
- 230000003628 erosive effect Effects 0.000 description 1
- 239000000686 essence Substances 0.000 description 1
- 238000003837 high-temperature calcination Methods 0.000 description 1
- 239000007769 metal material Substances 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 229910052573 porcelain Inorganic materials 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- 238000001179 sorption measurement Methods 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/80—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone of only ceramics
- C04B41/81—Coating or impregnation
- C04B41/89—Coating or impregnation for obtaining at least two superposed coatings having different compositions
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C8/00—Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
- C03C8/14—Glass frit mixtures having non-frit additions, e.g. opacifiers, colorants, mill-additions
- C03C8/20—Glass frit mixtures having non-frit additions, e.g. opacifiers, colorants, mill-additions containing titanium compounds; containing zirconium compounds
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/45—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
- C04B41/52—Multiple coating or impregnating multiple coating or impregnating with the same composition or with compositions only differing in the concentration of the constituents, is classified as single coating or impregnation
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Ceramic Engineering (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Structural Engineering (AREA)
- Life Sciences & Earth Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Geochemistry & Mineralogy (AREA)
- Glass Compositions (AREA)
- Compositions Of Oxide Ceramics (AREA)
Abstract
The invention discloses a kind of sheen glaze being used in ceramic thin plate, it includes cover-coat enamel and ground-coat enamel：By weight percentage, cover-coat enamel includes following effect components：High temperature Matt frit 18% ~ 22%, air knife soil 8% ~ 12%, calcite 14% ~ 18%, albite 19% ~ 23%, burning talcum 9% ~ 12%, zirconium silicate 5% ~ 9%, zinc oxide 3% ~ 6% and barium carbonate 9% ~ 12%.By weight percentage, ground-coat enamel includes following effect components：Quartz sand 22% ~ 26%, air knife soil 8% ~ 11%, ball clay 5% ~ 8%, burning talcum 7% ~ 11%, albite 13% ~ 16%, nepheline powder 10% ~ 14%, zirconium silicate 8% ~ 12% and calcined kaolin 11% ~ 15%.Firing temperature of the sheen glaze on ceramic wafer is 1,180 1200 DEG C, and firing period is 60 65 min, soaking time 15min.The glossiness of sheen glaze is than milder, and for its glossiness generally between 30 60 °, glossiness is to be more conform with the comfortable scope of human visual.By the sheen glaze for applying this case on ceramic thin plate base substrate so that the smooth exquisiteness in its surface, it is very soft, without light pollution, there is extraordinary decorative effect.
Description
Technical field
The invention belongs to ceramic thin plate glaze technical field, and in particular to a kind of sheen glaze being used in ceramic thin plate.
Background technology
Ceramic thin plate is one kind by kaolin clay and other inorganic non-metallic materials, shaped, 1200 degree of high-temperature calcinations
Etc. plate ceramic products made of production technology.With the development of economic technology, market is increasing to big specification ceramic tile demand.
Conventional process techniques and equipment are difficult to meet needed for production.Common ceramic tile serious waste of resources, energy consumption is very high, and building bears a heavy burden
Greatly, transport, operating expenses is high.
Generally there is rough surface without glaze product, easily pollution, easy moisture absorption, the defects of easily erosion.And ceramic thin plate is as dress
Ornaments, glazing is necessary on idiosome.But existing glaze aspect of performance need to be improved.
The content of the invention
The present invention proposes a kind of sheen glaze being used in ceramic thin plate, by applying this case on ceramic thin plate base substrate
Sheen glaze so that the smooth exquisiteness in its surface, it is very soft, without light pollution, there is extraordinary decorative effect.
The technical proposal of the invention is realized in this way：
A kind of sheen glaze being used in ceramic thin plate, it includes cover-coat enamel and ground-coat enamel：
By weight percentage, the cover-coat enamel includes following effect components：High temperature Matt frit 18%~22%,
Air knife soil 8%~12%, calcite 14%~18%, albite 19%~23%, burning talcum 9%~12%, zirconium silicate 5%
~9%, zinc oxide 3%~6% and barium carbonate 9%~12%；
By weight percentage, the ground-coat enamel includes following effect components：Quartz sand 22%~26%, air knife soil
8%~11%, ball clay 5%~8%, burning talcum 7%~11%, albite 13%~16%, nepheline powder 10%~14%, silicon
Sour zirconium 8%~12% and calcined kaolin 11%~15%.
In being used in the sheen glaze in ceramic thin plate for the present invention, by weight percentage, described cover-coat enamel includes as follows
Effect components：High temperature Matt frit 20.00%, air knife soil 10.54%, calcite 16.98%, albite 20.19%, burning
Talcum 10.12%, zirconium silicate 7.16%, zinc oxide 4.68% and barium carbonate 10.33%.
In being used in the sheen glaze in ceramic thin plate for the present invention, by weight percentage, described ground-coat enamel includes as follows
Effect components：Quartz sand 24.24%, air knife soil 9.16%, ball clay 6.68%, burning talcum 9.19%, albite
14.87%th, nepheline powder 12.46%, zirconium silicate 10.14% and calcined kaolin 13.26%.
Implement this sheen glaze being used in ceramic thin plate of the present invention, have the advantages that：By in ceramic thin
Apply the sheen glaze of this case on slab body so that the smooth exquisiteness in its surface, it is very soft, without light pollution, have extraordinary
Decorative effect, and the ceramic thin plate product after glazing is non-hygroscopic, spot adsorption capacity is weak, is readily cleaned, and substantially increases pottery
The competitiveness of porcelain light sheet products, there is very high economic benefit.
Embodiment
The technical scheme in the embodiment of the present invention will be clearly and completely described below.
This sheen glaze being used in ceramic thin plate of the present invention, it includes cover-coat enamel and ground-coat enamel：
By weight percentage, the cover-coat enamel includes following effect components：High temperature Matt frit 18%~22%,
Air knife soil 8%~12%, calcite 14%~18%, albite 19%~23%, burning talcum 9%~12%, zirconium silicate 5%
~9%, zinc oxide 3%~6% and barium carbonate 9%~12%.
When preparing cover-coat enamel, it is necessary to take various materials to be well mixed above-mentioned weight percent proportioning, it is put into ball milling and carries out
Crush, it is necessary to add methyl and sodium tripolyphosphate in mechanical milling process, play a part of dispergation, thickening, and in mechanical milling process
Need to be continuously added water, improve grinding efficiency.
By weight percentage, the ground-coat enamel includes following effect components：Quartz sand 22%~26%, air knife soil
8%~11%, ball clay 5%~8%, burning talcum 7%~11%, albite 13%~16%, nepheline powder 10%~14%, silicon
Sour zirconium 8%~12% and calcined kaolin 11%~15%.
When preparing ground-coat enamel, it is necessary to take various materials to be well mixed above-mentioned weight percent proportioning, it is put into ball milling and carries out
Crush, it is necessary to add methyl and sodium tripolyphosphate in mechanical milling process, play a part of dispergation, thickening, and in mechanical milling process
Need to be continuously added water, improve grinding efficiency.
Firing temperature of the sheen glaze on ceramic wafer is 1180-1200 DEG C, firing period 60-65min, and soaking time is
15min.The glossiness of sheen glaze, i.e., will not be too bright than milder, also will not too dumb light, its glossiness generally 30-60 ° it
Between, glossiness is to be more conform with the comfortable scope of human visual.
The constituent of various raw material is as shown in the table：
Embodiment one：
If various raw material gross weights are 4000kg, by weight percentage, described cover-coat enamel includes following effective group
Into composition：High temperature Matt frit 20.00%, air knife soil 10.54%, calcite 16.98%, albite 20.19%, burning talcum
10.12%th, zirconium silicate 7.16%, zinc oxide 4.68% and barium carbonate 10.33%.
When preparing cover-coat enamel, it is necessary to take various materials to be well mixed above-mentioned weight percent proportioning, it is put into ball milling and carries out
Crush, it is necessary to add 4kg methyl and 12kg sodium tripolyphosphates in mechanical milling process, play a part of dispergation, thickening, and in ball
Need to add the water that total amount is 1560kg during mill, improve grinding efficiency.Last obtained cover-coat enamel：Proportion 1.80-1.83,
Flow velocity 45s-65s, screen over-size are 0.3-0.5.
If various raw material gross weights are 4000kg, by weight percentage, described ground-coat enamel includes following effective group
Into composition：Quartz sand 24.24%, air knife soil 9.16%, ball clay 6.68%, burning talcum 9.19%, albite 14.87%, nepheline
Powder 12.46%, zirconium silicate 10.14% and calcined kaolin 13.26%.
When preparing ground-coat enamel, it is necessary to take various materials to be well mixed above-mentioned weight percent proportioning, it is put into ball milling and carries out
Crush, it is necessary to add 4kg methyl and 16kg sodium tripolyphosphates in mechanical milling process, play a part of dispergation, thickening, and in ball
Need to add the water that total amount is 1250kg during mill, improve grinding efficiency.Last obtained ground-coat enamel：Proportion 1.85-1.91, stream
Fast 45s-65s, screen over-size are 0.3-0.5.
So far, the object of the invention is accomplished.
The foregoing is merely illustrative of the preferred embodiments of the present invention, is not intended to limit the invention, all essences in the present invention
God any modification, equivalent substitution and improvements made etc., should be included in the scope of the protection with principle.
Claims (3)
1. a kind of sheen glaze being used in ceramic thin plate, it is characterised in that the sheen glaze includes cover-coat enamel and ground-coat enamel：
By weight percentage, the cover-coat enamel includes following effect components：High temperature Matt frit 18% ~ 22%, air knife soil 8% ~
12%th, calcite 14% ~ 18%, albite 19% ~ 23%, burning talcum 9% ~ 12%, zirconium silicate 5% ~ 9%, zinc oxide 3% ~ 6% and barium carbonate
9%~12%；
By weight percentage, the ground-coat enamel includes following effect components：Quartz sand 22% ~ 26%, air knife soil 8% ~ 11%, ball
Soil 5% ~ 8%, burning talcum 7% ~ 11%, albite 13% ~ 16%, nepheline powder 10% ~ 14%, zirconium silicate 8% ~ 12% and calcined kaolin 11% ~
15%。
2. the sheen glaze according to claim 1 being used in ceramic thin plate, it is characterised in that by weight percentage, institute
The cover-coat enamel stated includes following effect components：High temperature Matt frit 20.00%, air knife soil 10.54%, calcite 16.98%, sodium
Feldspar 20.19%, burn talcum 10.12%, zirconium silicate 7.16%, zinc oxide 4.68% and barium carbonate 10.33%.
3. the sheen glaze according to claim 1 being used in ceramic thin plate, it is characterised in that by weight percentage, institute
The ground-coat enamel stated includes following effect components：Quartz sand 24.24%, air knife soil 9.16%, ball clay 6.68%, burn talcum 9.19%,
Albite 14.87%, nepheline powder 12.46%, zirconium silicate 10.14% and calcined kaolin 13.26%.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810009285.3A CN107892589A (en) | 2018-01-05 | 2018-01-05 | A kind of sheen glaze being used in ceramic thin plate |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810009285.3A CN107892589A (en) | 2018-01-05 | 2018-01-05 | A kind of sheen glaze being used in ceramic thin plate |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN107892589A true CN107892589A (en) | 2018-04-10 |
Family
ID=61808952
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201810009285.3A Pending CN107892589A (en) | 2018-01-05 | 2018-01-05 | A kind of sheen glaze being used in ceramic thin plate |
Country Status (1)
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| CN (1) | CN107892589A (en) |
Cited By (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108793949A (en) * | 2018-06-12 | 2018-11-13 | 佛山市华强协兴陶瓷有限公司 | A kind of sheen glaze in ceramic thin plate |
| CN109970343A (en) * | 2019-04-24 | 2019-07-05 | 佛山市东鹏陶瓷有限公司 | A kind of antifouling dry granular glaze of dumb light and glaze slip preparation method, ceramic tile and preparation method |
| CN110255902A (en) * | 2019-05-27 | 2019-09-20 | 湖北杭瑞陶瓷有限责任公司 | A kind of overglaze being rapidly fired to suitable for glazed tile, glazed tile and preparation method thereof |
| CN110510876A (en) * | 2019-09-16 | 2019-11-29 | 东莞市唯美陶瓷工业园有限公司 | A kind of matting glaze and preparation method thereof |
| CN110550958A (en) * | 2019-09-17 | 2019-12-10 | 广东新润成陶瓷有限公司 | Fine, soft and matte black brick and preparation method thereof |
| CN110627532A (en) * | 2019-11-01 | 2019-12-31 | 江西省建筑卫生陶瓷质量监督检验中心 | Large-size ceramic rock plate and production process thereof |
| CN111875415A (en) * | 2020-08-11 | 2020-11-03 | 佛山市三水新明珠建陶工业有限公司 | Method for manufacturing soft glazed ceramic chip |
| WO2020234676A1 (en) * | 2019-05-20 | 2020-11-26 | Haji Aboutalebi Hamid | Producing composite glaze ceramic tiles |
| CN112358188A (en) * | 2020-10-27 | 2021-02-12 | 东莞市唯美陶瓷工业园有限公司 | Ceramic sheet ink-jet underglaze color decorative glaze and preparation method thereof, and ceramic sheet |
| CN113305993A (en) * | 2021-06-24 | 2021-08-27 | 广东协进陶瓷有限公司 | Engraved mercerized glazed tile and production method thereof |
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Cited By (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108793949A (en) * | 2018-06-12 | 2018-11-13 | 佛山市华强协兴陶瓷有限公司 | A kind of sheen glaze in ceramic thin plate |
| CN109970343A (en) * | 2019-04-24 | 2019-07-05 | 佛山市东鹏陶瓷有限公司 | A kind of antifouling dry granular glaze of dumb light and glaze slip preparation method, ceramic tile and preparation method |
| CN109970343B (en) * | 2019-04-24 | 2021-11-02 | 佛山市东鹏陶瓷有限公司 | Matte antifouling dry-particle glaze and glaze slip preparation method, ceramic tile and preparation method |
| WO2020234676A1 (en) * | 2019-05-20 | 2020-11-26 | Haji Aboutalebi Hamid | Producing composite glaze ceramic tiles |
| CN110255902A (en) * | 2019-05-27 | 2019-09-20 | 湖北杭瑞陶瓷有限责任公司 | A kind of overglaze being rapidly fired to suitable for glazed tile, glazed tile and preparation method thereof |
| CN110510876A (en) * | 2019-09-16 | 2019-11-29 | 东莞市唯美陶瓷工业园有限公司 | A kind of matting glaze and preparation method thereof |
| CN110550958A (en) * | 2019-09-17 | 2019-12-10 | 广东新润成陶瓷有限公司 | Fine, soft and matte black brick and preparation method thereof |
| CN110627532A (en) * | 2019-11-01 | 2019-12-31 | 江西省建筑卫生陶瓷质量监督检验中心 | Large-size ceramic rock plate and production process thereof |
| CN111875415A (en) * | 2020-08-11 | 2020-11-03 | 佛山市三水新明珠建陶工业有限公司 | Method for manufacturing soft glazed ceramic chip |
| CN112358188A (en) * | 2020-10-27 | 2021-02-12 | 东莞市唯美陶瓷工业园有限公司 | Ceramic sheet ink-jet underglaze color decorative glaze and preparation method thereof, and ceramic sheet |
| CN113305993A (en) * | 2021-06-24 | 2021-08-27 | 广东协进陶瓷有限公司 | Engraved mercerized glazed tile and production method thereof |
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Application publication date: 20180410 |