CN107621317A - A surface acoustic wave high temperature pressure sensor chip based on SOI and piezoelectric film and its preparation method - Google Patents
A surface acoustic wave high temperature pressure sensor chip based on SOI and piezoelectric film and its preparation method Download PDFInfo
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Abstract
Description
技术领域technical field
本发明属于半导体设计及制造技术领域,涉及MEMS传感器,具体涉及一种基于SOI和压电薄膜的声表面波高温压力传感器芯片及其制备方法。The invention belongs to the technical field of semiconductor design and manufacture, relates to MEMS sensors, in particular to a surface acoustic wave high-temperature pressure sensor chip based on SOI and a piezoelectric film and a preparation method thereof.
背景技术Background technique
高温环境下的压力测量是测控技术的重点、难点之一。在航空航天、国防军工、石油化工、汽车工业等领域,常常需要在高温环境下进行压力的测量与控制,高性能的高温压力传感器是上述领域中的关键器件之一。Pressure measurement in high temperature environment is one of the key points and difficulties of measurement and control technology. In the fields of aerospace, national defense, petrochemical, and automobile industries, it is often necessary to measure and control pressure in a high-temperature environment. High-performance high-temperature pressure sensors are one of the key components in the above-mentioned fields.
目前广泛使用的硅压阻式压力传感器,采用P-N结隔离应变电桥与应变膜,其工艺成熟且性能优异,但是P-N结漏电随着温度升高而急剧增大,当温度超过120℃时,传感器的性能会严重恶化甚至失效,另外,硅在600℃时会发生塑性变形和电流泄漏,导致信号处理系统和电路的极度失调。以石英为基底的声表面波压力传感器技术已经相当成熟,但其工作温度一般为-20℃-100 ℃,不宜在高于200℃的环境下使用。The silicon piezoresistive pressure sensor widely used at present uses a P-N junction to isolate the strain bridge and the strain film. Its technology is mature and its performance is excellent. , the performance of the sensor will seriously deteriorate or even fail. In addition, silicon will undergo plastic deformation and current leakage at 600 ° C, resulting in extreme imbalance of the signal processing system and circuit. The surface acoustic wave pressure sensor technology based on quartz is quite mature, but its working temperature is generally -20°C-100°C, and it is not suitable for use in an environment higher than 200°C.
中国专利CN 1514219提供了一种固态压阻式耐高温压力传感器,实现了 200℃以上恶劣环境的温度测量,但此传感器仍需电源供电,需要导线传输信号,难以胜任500℃以上高温要求。中国专利CN101775657涉及到了硅酸镓镧高温应用零温度补偿切型,但没有具体针对此晶体在传感器方面做深入的工作。Chinese patent CN 1514219 provides a solid-state piezoresistive high-temperature resistant pressure sensor, which realizes temperature measurement in harsh environments above 200°C. However, this sensor still needs power supply and wires to transmit signals, so it is difficult to meet the high temperature requirements above 500°C. The Chinese patent CN101775657 relates to the zero temperature compensation cutting type for high temperature application of gallium lanthanum silicate, but does not specifically do in-depth work on the sensor for this crystal.
发明内容Contents of the invention
本发明旨在解决现有技术中存在的技术问题,特别创新地提出了一种基于SOI和压电薄膜的声表面波高温压力传感器芯片及其制备方法。The invention aims to solve the technical problems existing in the prior art, and particularly innovatively proposes a surface acoustic wave high-temperature pressure sensor chip based on SOI and a piezoelectric film and a preparation method thereof.
为了实现本发明的上述目的,根据本发明的第一个方面,本发明提供了一种基于SOI和压电薄膜的声表面波高温压力传感器芯片,其包括SOI芯片基底,所述SOI芯片基底上的二氧化硅层及其上的器件层共同构成SOI压力敏感层,所述SOI压力敏感层上形成有压电薄膜,在所述压电薄膜之上形成有叉指换能器和反射栅;在SOI芯片基底内从SOI芯片基底底面延伸至压力敏感层形成有检测压力时提供参考压力的腔室。所述SOI芯片基底之下也可以具有第二芯片基底,在SOI芯片基底内从第二芯片基底延伸至压力敏感层之间形成有高真空密封腔室。In order to achieve the above object of the present invention, according to the first aspect of the present invention, the present invention provides a surface acoustic wave high-temperature pressure sensor chip based on SOI and piezoelectric thin film, which includes an SOI chip substrate, on which The silicon dioxide layer and the device layer thereon together constitute an SOI pressure-sensitive layer, a piezoelectric film is formed on the SOI pressure-sensitive layer, and an interdigital transducer and a reflective grid are formed on the piezoelectric film; Extending from the bottom surface of the SOI chip substrate to the pressure sensitive layer in the SOI chip substrate, a chamber for providing reference pressure when detecting pressure is formed. There may also be a second chip substrate under the SOI chip substrate, and a high vacuum sealed chamber is formed in the SOI chip substrate extending from the second chip substrate to the pressure sensitive layer.
本发明的声表面波高温压力传感器芯片体积小,工作在射频段可实现无线收发,测量方式灵活,因而在高温压力测量领域具有非常大的应用潜力。The chip of the surface acoustic wave high-temperature pressure sensor of the present invention is small in size, can realize wireless transmission and reception when working in the radio frequency section, and has flexible measurement methods, so it has great application potential in the field of high-temperature pressure measurement.
在本发明的一种优选实施方式中,采用SOI制备形成SOI芯片基底和压力敏感层,SOI器件层的电阻率≥5kΩ。制备的传感器芯片高温性能好,保证芯片质量;用SOI的加工工艺成熟,成品率高。In a preferred embodiment of the present invention, the SOI chip substrate and the pressure sensitive layer are formed by using SOI, and the resistivity of the SOI device layer is ≥5 kΩ. The prepared sensor chip has good high-temperature performance and ensures chip quality; the processing technology using SOI is mature and the yield is high.
在本发明的另一种优选实施方式中,所述压电薄膜为晶粒呈c轴取向的纯 AlN压电薄膜或掺杂10at%-43at%钪元素的AlN压电薄膜,保证高温时的检测效果。In another preferred embodiment of the present invention, the piezoelectric film is a pure AlN piezoelectric film whose crystal grains are c-axis oriented or an AlN piezoelectric film doped with 10at%-43at% scandium element, so as to ensure the Detection effect.
在本发明的另一种优选实施方式中,叉指换能器和反射栅在压电薄膜上方呈平行设置,所述叉指换能器和反射栅材料为同一种材料。In another preferred embodiment of the present invention, the interdigital transducer and the reflection grid are arranged in parallel above the piezoelectric film, and the material of the interdigital transducer and the reflection grid is the same material.
在本发明的另一种优选实施方式中,所述叉指换能器和反射栅的材料为铝、金、钼、铂、铱或其合金,能够满足多种温度传感器的要求。In another preferred embodiment of the present invention, the materials of the interdigital transducer and the reflection grid are aluminum, gold, molybdenum, platinum, iridium or their alloys, which can meet the requirements of various temperature sensors.
例如在200℃以下选择铝;在600℃以下选择金;在800℃以下选择钼;在1000℃以下选择铂;在1200℃以下选择铱。For example, aluminum is selected below 200°C; gold is selected below 600°C; molybdenum is selected below 800°C; platinum is selected below 1000°C; iridium is selected below 1200°C.
在本发明的另一种优选实施方式中,在压力敏感层与压电薄膜之间形成有底电极,所述底电极可引出并接地,也可不引出。In another preferred embodiment of the present invention, a bottom electrode is formed between the pressure-sensitive layer and the piezoelectric film, and the bottom electrode may be drawn out and grounded, or may not be drawn out.
在本发明的另一种优选实施方式中,可以在压力敏感层上方形成有二氧化硅平铺层,或者在压力敏感层上方形成有二氧化硅立体结构与多晶硅立体结构交叉分布的周期性阵列平铺层,补偿抵消环境温度的变化导致的测压误差。In another preferred embodiment of the present invention, a silicon dioxide flat layer may be formed above the pressure sensitive layer, or a periodic array of silicon dioxide three-dimensional structures and polycrystalline silicon three-dimensional structures may be formed above the pressure sensitive layer. Tiling layer, compensate and offset the pressure measurement error caused by the change of ambient temperature.
为了实现本发明的上述目的,根据本发明的第二个方面,本发明提供了一种制备声表面波高温压力传感器芯片的方法,其包括如下步骤:In order to achieve the above object of the present invention, according to a second aspect of the present invention, the present invention provides a method for preparing a surface acoustic wave high-temperature pressure sensor chip, which includes the following steps:
S1,提供SOI,所述SOI器件层的电阻率≥5kΩ;S1, providing SOI, the resistivity of the SOI device layer is ≥5kΩ;
S2,在所述SOI正面淀积形成压电薄膜;S2, depositing and forming a piezoelectric film on the front side of the SOI;
S3,在所述压电薄膜之上淀积形成叉指换能器和反射栅;S3, depositing an interdigital transducer and a reflective grid on the piezoelectric film;
S4,淀积形成绝缘保护层;S4, depositing and forming an insulating protection layer;
S5,光刻,刻蚀绝缘保护层和压电薄膜层,开窗口;S5, photolithography, etch the insulating protective layer and the piezoelectric film layer, and open the window;
S6,淀积导电金属层,光刻,刻蚀,形成信号引出盘;S6, depositing a conductive metal layer, photolithography, etching, forming a signal lead-out disk;
S7,光刻,在所述SOI背面刻蚀,直至SOI的隔离层暴露形成压力敏感层;S7, photolithography, etching on the back of the SOI until the isolation layer of the SOI is exposed to form a pressure sensitive layer;
具有或不具有的步骤S8,将SOI背面与第二芯片基底键合形成高真空密封腔室。Step S8 with or without, bonding the back of the SOI to the second chip substrate to form a high-vacuum sealed chamber.
本发明的制备方法结构简单,其形成的声表面波高温压力传感器芯片体积小,其压电特性使其无需外接电源,工作在射频段可实现无线收发,测量方式灵活,因而在高温压力测量领域具有非常大的应用潜力。The preparation method of the present invention has a simple structure, and the surface acoustic wave high-temperature pressure sensor chip formed by it has a small volume, and its piezoelectric characteristics make it unnecessary to connect an external power supply, and can realize wireless transmission and reception in the radio frequency section, and the measurement method is flexible, so it is widely used in the field of high-temperature pressure measurement. It has great application potential.
在本发明的另一种优选实施方式中,所述步骤S2为:在所述SOI正面淀积形成底电极,然后在所述底电极之上淀积形成压电薄膜;In another preferred embodiment of the present invention, the step S2 is: depositing and forming a bottom electrode on the front side of the SOI, and then depositing and forming a piezoelectric film on the bottom electrode;
或者步骤S2为:在所述SOI正面淀积形成二氧化硅平铺层或者淀积形成二氧化硅立体结构与多晶硅立体结构交叉分布的周期性阵列平铺层,然后在所述平铺层之上淀积形成压电薄膜;Or step S2 is: depositing and forming a silicon dioxide tiled layer on the front side of the SOI or depositing and forming a periodic array tiled layer with a silicon dioxide three-dimensional structure intersecting with a polysilicon three-dimensional structure, and then depositing on the front side of the said flat layer Deposit to form a piezoelectric film;
或者步骤S2为:在所述SOI正面淀积形成二氧化硅平铺层或者淀积形成二氧化硅立体结构与多晶硅立体结构交叉分布的周期性阵列平铺层,然后淀积形成底电极,在所述底电极之上淀积形成压电薄膜。Or step S2 is: depositing and forming a silicon dioxide tiled layer on the front side of the SOI or depositing and forming a periodic array tiled layer with a silicon dioxide three-dimensional structure intersecting with a polysilicon three-dimensional structure, and then depositing and forming a bottom electrode. A piezoelectric thin film is deposited on the bottom electrode.
在本发明的一种优选实施方式中,一种利用基于SOI和压电薄膜的声表面波高温压力传感器芯片的应用结构,其采用如下结构之一:In a preferred embodiment of the present invention, an application structure utilizing a surface acoustic wave high-temperature pressure sensor chip based on SOI and a piezoelectric film adopts one of the following structures:
结构一:同时使用两个谐振器或两个延迟线形式的双通道补偿方式补偿抵消环境温度的变化导致的测压误差,所述两个谐振器或两个延迟线由于位置不同或结构参数不同而具有不同的温度敏感性能和/或压力敏感性能;Structure 1: Simultaneously use two resonators or two delay lines in the form of dual-channel compensation to compensate for pressure measurement errors caused by changes in ambient temperature. The two resonators or two delay lines are due to different positions or different structural parameters. And have different temperature sensitive properties and/or pressure sensitive properties;
结构二:如所述芯片中存在两种或两种以上的对温度和压力敏感的声波模态,同时使用两种声波模态信号补偿方式补偿抵消环境温度的变化导致的测压误差,所述两种声波模态具有不同的温度敏感性能和/或压力敏感性能。Structure 2: If there are two or more acoustic wave modes sensitive to temperature and pressure in the chip, and the two acoustic wave mode signal compensation methods are used to compensate and offset the pressure measurement error caused by the change of the ambient temperature, the The two acoustic modes have different temperature sensitivity and/or pressure sensitivity.
本发明的附加方面和优点将在下面的描述中部分给出,部分将从下面的描述中变得明显,或通过本发明的实践了解到。Additional aspects and advantages of the invention will be set forth in the description which follows, and in part will be obvious from the description, or may be learned by practice of the invention.
附图说明Description of drawings
本发明的上述和/或附加的方面和优点从结合下面附图对实施例的描述中将变得明显和容易理解,其中:The above and/or additional aspects and advantages of the present invention will become apparent and comprehensible from the description of the embodiments in conjunction with the following drawings, wherein:
图1是本发明一种优选实施例中基于SOI和压电薄膜的声表面波高温压力传感器差压式芯片的制备流程图,其中,图1-1为SOI的示意图;图1-2为在SOI正面淀积形成压电薄膜的示意图;图1-3是在压电薄膜之上淀积形成叉指换能器和反射栅的示意图;图1-4是淀积形成绝缘保护层的示意图;图1-5为开窗口至底电极的示意图;图1-6为开窗口至叉指换能器的示意图;图1-7为淀积导电金属层的示意图;图1-8为在SOI背面刻蚀直至SOI的隔离层暴露形成压力敏感层的示意图;Fig. 1 is the preparation flowchart of the surface acoustic wave high-temperature pressure sensor differential pressure chip based on SOI and piezoelectric film in a preferred embodiment of the present invention, wherein, Fig. 1-1 is the schematic diagram of SOI; Fig. 1-2 is in A schematic diagram of SOI front deposition to form a piezoelectric film; Fig. 1-3 is a schematic diagram of depositing and forming an interdigital transducer and a reflective grid on a piezoelectric film; Fig. 1-4 is a schematic diagram of depositing and forming an insulating protective layer; Figure 1-5 is a schematic diagram of opening a window to the bottom electrode; Figure 1-6 is a schematic diagram of opening a window to an interdigital transducer; Figure 1-7 is a schematic diagram of depositing a conductive metal layer; Figure 1-8 is a schematic diagram of the SOI backside Schematic diagram of etching until the isolation layer of SOI is exposed to form a pressure sensitive layer;
图2是本发明一种优选实施例中基于SOI和压电薄膜的声表面波高温压力传感器绝压式芯片的制备流程图,其中,图2-1为提供SOI的示意图;图2-2为在SOI正面淀积形成压电薄膜的示意图;图2-3为在压电薄膜之上淀积形成叉指换能器和反射栅的示意图;图2-4为淀积形成绝缘保护层的示意图;图2-5为开窗口至底电极的示意图;图2-6为开窗口至叉指换能器的示意图;图2-7为淀积导电金属层的示意图;图2-8为在SOI背面刻蚀直至SOI的隔离层暴露形成压力敏感层的示意图;图2-9为将SOI背面与第二芯片基底键合形成高真空密封腔室的示意图;Fig. 2 is a flow chart of the preparation of the absolute pressure chip of the surface acoustic wave high-temperature pressure sensor based on SOI and piezoelectric film in a preferred embodiment of the present invention, wherein Fig. 2-1 is a schematic diagram of providing SOI; Fig. 2-2 is A schematic diagram of depositing and forming a piezoelectric film on the front side of SOI; Figure 2-3 is a schematic diagram of depositing and forming an interdigital transducer and a reflective gate on a piezoelectric film; Figure 2-4 is a schematic diagram of depositing and forming an insulating protective layer ; Fig. 2-5 is a schematic diagram of opening a window to the bottom electrode; Fig. 2-6 is a schematic diagram of opening a window to an interdigital transducer; Fig. 2-7 is a schematic diagram of depositing a conductive metal layer; A schematic diagram of etching the back of the SOI until the isolation layer of the SOI is exposed to form a pressure-sensitive layer; Figure 2-9 is a schematic diagram of bonding the back of the SOI to the second chip substrate to form a high-vacuum sealed chamber;
图3是本发明另一种优选实施例中基于SOI和压电薄膜的声表面波高温压力传感器绝压式芯片的制备流程图(与图2不同之处在于:高真空密封腔室的制作工艺不再采用硅-玻璃阳极键合工艺,而是采用硅-硅键合工艺),其中,图3-1为提供SOI的示意图;图3-2为在SOI正面淀积形成压电薄膜的示意图;图3-3为在压电薄膜之上淀积形成叉指换能器和反射栅的示意图;图3-4为淀积形成绝缘保护层的示意图;图3-5为开窗口至底电极的示意图;图3-6为开窗口至叉指换能器的示意图;图3-7为淀积导电金属层的示意图;图3-8为在SOI背面刻蚀直至SOI的隔离层暴露形成压力敏感层的示意图;图3-9为将SOI 背面与硅基底键合形成高真空密封腔室的示意图;Fig. 3 is a flow chart of the preparation of the absolute pressure chip of the surface acoustic wave high temperature pressure sensor based on SOI and piezoelectric thin film in another preferred embodiment of the present invention (the difference from Fig. 2 is: the manufacturing process of the high vacuum sealed chamber The silicon-glass anode bonding process is no longer used, but the silicon-silicon bonding process is used), among which, Figure 3-1 is a schematic diagram of providing SOI; Figure 3-2 is a schematic diagram of forming a piezoelectric film deposited on the front side of SOI ; Figure 3-3 is a schematic diagram of depositing and forming an interdigital transducer and a reflective grid on a piezoelectric film; Figure 3-4 is a schematic diagram of depositing and forming an insulating protective layer; Figure 3-5 is opening a window to the bottom electrode Figure 3-6 is a schematic diagram of opening a window to an interdigital transducer; Figure 3-7 is a schematic diagram of depositing a conductive metal layer; Figure 3-8 is etching on the back of SOI until the isolation layer of SOI is exposed to form a pressure A schematic diagram of the sensitive layer; Figure 3-9 is a schematic diagram of bonding the back of the SOI to a silicon substrate to form a high-vacuum sealed chamber;
图4(a)是本发明另一种优选实施例中传感器芯片不带底电极的结构示意图;图4(b)是本发明另一种优选实施例中传感器芯片带底电极的结构示意图;Fig. 4 (a) is a schematic structural view of a sensor chip without a bottom electrode in another preferred embodiment of the present invention; Fig. 4 (b) is a structural schematic view of a sensor chip with a bottom electrode in another preferred embodiment of the present invention;
图5是本发明一种优选实施例中在传感器芯片中加入一定厚度的二氧化硅立体结构与多晶硅立体结构交叉分布的周期性阵列平铺层示意图;Fig. 5 is a schematic diagram of a periodic array tiling layer in which a certain thickness of silicon dioxide three-dimensional structure and polysilicon three-dimensional structure are added to the sensor chip in a preferred embodiment of the present invention;
图6是本发明一种优选实施例中使用两个谐振器形式的双通道补偿方式补偿抵消环境温度的变化导致的测压误差示意图,其中,图6(a)为响应信号的变化只反映环境温度变化的谐振器结构示意图,图6(b)为响应信号的变化反映环境温度变化和待测压力变化的双重作用的谐振器结构示意图。Fig. 6 is a schematic diagram of pressure measurement errors caused by the use of two resonator-type dual-channel compensation methods in a preferred embodiment of the present invention to compensate and offset changes in ambient temperature, wherein Fig. 6(a) shows that changes in the response signal only reflect the environment Schematic diagram of the structure of the resonator with temperature changes. Figure 6(b) is a schematic diagram of the structure of the resonator that reflects the dual effects of changes in the ambient temperature and pressure to be measured by changes in the response signal.
附图标记:Reference signs:
1 SOI基底层;2 SOI隔离层;3 SOI器件层;4 底电极;1 SOI base layer; 2 SOI isolation layer; 3 SOI device layer; 4 Bottom electrode;
5 压电层;6 二氧化硅绝缘保护层;7 叉指换能器;8 叉指换能器;5 piezoelectric layer; 6 silicon dioxide insulating protective layer; 7 interdigital transducer; 8 interdigital transducer;
9 叉指换能器;10 信号引出盘。9 Interdigital transducer; 10 Signal lead-out plate.
具体实施方式detailed description
下面详细描述本发明的实施例,所述实施例的示例在附图中示出,其中自始至终相同或类似的标号表示相同或类似的元件或具有相同或类似功能的元件。下面通过参考附图描述的实施例是示例性的,仅用于解释本发明,而不能理解为对本发明的限制。Embodiments of the present invention are described in detail below, examples of which are shown in the drawings, wherein the same or similar reference numerals designate the same or similar elements or elements having the same or similar functions throughout. The embodiments described below by referring to the figures are exemplary only for explaining the present invention and should not be construed as limiting the present invention.
在本发明的描述中,需要理解的是,术语“纵向”、“横向”、“上”、“下”、“前”、“后”、“左”、“右”、“竖直”、“水平”、“顶”、“底”“内”、“外”等指示的方位或位置关系为基于附图所示的方位或位置关系,仅是为了便于描述本发明和简化描述,而不是指示或暗示所指的装置或元件必须具有特定的方位、以特定的方位构造和操作,因此不能理解为对本发明的限制。In describing the present invention, it should be understood that the terms "longitudinal", "transverse", "upper", "lower", "front", "rear", "left", "right", "vertical", The orientation or positional relationship indicated by "horizontal", "top", "bottom", "inner", "outer", etc. are based on the orientation or positional relationship shown in the drawings, and are only for the convenience of describing the present invention and simplifying the description, rather than Nothing indicating or implying that a referenced device or element must have a particular orientation, be constructed, and operate in a particular orientation should therefore not be construed as limiting the invention.
在本发明的描述中,除非另有规定和限定,需要说明的是,术语“安装”、“相连”、“连接”应做广义理解,例如,可以是机械连接或电连接,也可以是两个元件内部的连通,可以是直接相连,也可以通过中间媒介间接相连,对于本领域的普通技术人员而言,可以根据具体情况理解上述术语的具体含义。In the description of the present invention, unless otherwise specified and limited, it should be noted that the terms "installation", "connection" and "connection" should be understood in a broad sense, for example, it can be mechanical connection or electrical connection, or two The internal communication of each element may be directly connected or indirectly connected through an intermediary. Those skilled in the art can understand the specific meanings of the above terms according to specific situations.
图4(a)是本发明第一种优选实施例的声表面波高温压力传感器芯片的剖视图,图中仅仅是示意的给出了各区域的尺寸,具体的尺寸可以根据器件参数的要求进行设计。Fig. 4(a) is a cross-sectional view of the surface acoustic wave high-temperature pressure sensor chip of the first preferred embodiment of the present invention. The size of each area is only schematically shown in the figure, and the specific size can be designed according to the requirements of device parameters .
从图4(a)中可见,声表面波高温压力传感器芯片包括:SOI芯片基底, SOI芯片基底上形成有压力敏感层,在本实施方式中,采用SOI(Silicon On Insulator,绝缘体上硅)制备形成压力敏感层,SOI器件层的电阻率≥5kΩ。SOI 中隔离层2(二氧化硅)和其上的器件层3共同形成SOI压力敏感层,SOI隔离层之下的基底层1为SOI芯片基底,在SOI芯片基底内从SOI芯片基底底面延伸至压力敏感层形成有检测压力时提供参考压力的腔室。It can be seen from Fig. 4(a) that the surface acoustic wave high-temperature pressure sensor chip includes: an SOI chip substrate on which a pressure-sensitive layer is formed. In this embodiment, SOI (Silicon On Insulator, silicon on insulator) is used to prepare A pressure sensitive layer is formed, and the resistivity of the SOI device layer is greater than or equal to 5kΩ. The isolation layer 2 (silicon dioxide) in SOI and the device layer 3 thereon form the SOI pressure sensitive layer together, and the base layer 1 under the SOI isolation layer is the SOI chip base, which extends from the bottom surface of the SOI chip base to the SOI chip base in the SOI chip base. The pressure sensitive layer is formed with a cavity that provides a reference pressure when detecting pressure.
压力敏感层上形成有压电薄膜,在本实施方式中,压电薄膜为晶粒呈c 轴取向的纯AlN压电层5或掺杂10at%-43at%钪元素的AlN压电薄膜5。在压电薄膜之上形成有叉指换能器7、8、9和反射栅。叉指换能器7、8、9和反射栅在压电薄膜上方呈平行设置,所述叉指换能器和反射栅材料为同一种材料。优选地叉指换能器和反射栅的材料为铝、金、钼、铂、铱或其合金。A piezoelectric thin film is formed on the pressure sensitive layer. In this embodiment, the piezoelectric thin film is a pure AlN piezoelectric layer 5 with c-axis oriented crystal grains or an AlN piezoelectric thin film 5 doped with 10at%-43at% scandium. Interdigital transducers 7, 8, 9 and reflective grids are formed on the piezoelectric film. The interdigital transducers 7, 8, 9 and the reflection grid are arranged in parallel above the piezoelectric film, and the materials of the interdigital transducers and the reflection grid are the same material. Preferably, the material of the interdigital transducer and the reflection grid is aluminum, gold, molybdenum, platinum, iridium or alloys thereof.
在本实施方式中,叉指换能器和反射栅可以组成声表面波单端谐振器、声表面波双端谐振器或声表面波延迟线。具体地,声表面波单端谐振器的结构为两个反射栅之间放置一个叉指换能器,声表面波双端谐振器的结构为两个反射栅之间放置两个叉指换能器或两个叉指换能器之间放置两个反射栅,声表面波延迟线的结构为两个或多个叉指换能器呈平行设置。In this implementation manner, the interdigital transducer and the reflective grating may form a surface acoustic wave single-ended resonator, a surface acoustic wave double-ended resonator, or a surface acoustic wave delay line. Specifically, the structure of the surface acoustic wave single-ended resonator is to place an interdigital transducer between two reflection gratings, and the structure of the surface acoustic wave double-terminal resonator is to place two interdigital transducers between two reflection gratings. Two reflection gratings are placed between two interdigital transducers or two interdigital transducers, and the structure of the surface acoustic wave delay line is that two or more interdigital transducers are arranged in parallel.
在本实施方式中,在SOI芯片基底内从基底底面延伸至压力敏感层之间形成有检测压力时提供参考压力的腔室,如图1-8所示,在差压结构中腔室为开放结构,并不是密封腔室。在本发明另外的优选实施方式中,SOI芯片基底之下为第二芯片基底,在SOI芯片基底内从第二芯片基底延伸至压力敏感层之间形成有检测压力时提供参考压力的高真空密封腔室,如图2-9所示,在绝压结构中腔室为高真空密封腔室。In this embodiment, a chamber that provides a reference pressure when detecting pressure is formed in the SOI chip substrate extending from the bottom surface of the substrate to the pressure sensitive layer. As shown in Figures 1-8, the chamber is open in the differential pressure structure structure, not a sealed chamber. In another preferred embodiment of the present invention, under the SOI chip substrate is a second chip substrate, and a high vacuum seal that provides a reference pressure when detecting pressure is formed between the SOI chip substrate extending from the second chip substrate to the pressure sensitive layer The chamber, as shown in Figure 2-9, is a high vacuum sealed chamber in the absolute pressure structure.
本发明提供了一种制备基于SOI和压电薄膜的声表面波高温压力传感器芯片的方法,如图1-8所示的差压式结构,其包括如下步骤:The present invention provides a method for preparing a surface acoustic wave high-temperature pressure sensor chip based on SOI and a piezoelectric film, the differential pressure structure shown in Figure 1-8, which includes the following steps:
S1,如图1-1所示,提供SOI,所述SOI器件层的电阻率≥5kΩ。S1, as shown in FIG. 1-1, provides SOI, and the resistivity of the SOI device layer is ≥5kΩ.
S2,如图1-2所示,在所述SOI正面淀积形成压电薄膜,在本实施方式中,压电薄膜为晶粒呈c轴取向的纯AlN压电薄膜或掺杂10at%-43at%钪元素的 AlN压电薄膜。S2, as shown in Figure 1-2, a piezoelectric film is deposited on the front side of the SOI to form a piezoelectric film. In this embodiment, the piezoelectric film is a pure AlN piezoelectric film whose crystal grains are c-axis oriented or doped with 10at%- AlN piezoelectric film with 43at% scandium element.
S3,如图1-3所示,在压电薄膜之上淀积形成叉指换能器和反射栅,最后形成的结构如图4(a)所示。S3, as shown in Fig. 1-3, deposit and form interdigital transducers and reflective grids on the piezoelectric film, and finally form the structure as shown in Fig. 4(a).
在本发明另外的优选实施方式中,如图1-2所示,步骤S2为在SOI正面淀积形成底电极,具体底电极的材料优选为Ti/Pt材料,在所述底电极之上淀积形成压电薄膜;如图1-3所示,在压电薄膜之上淀积形成叉指换能器和反射栅,最后形成的结构如图4(b)所示。叉指换能器和反射栅的材料为铝、金、钼、铂、铱或其合金,在本实施方式中,叉指换能器和反射栅的材料优选为钼。In another preferred embodiment of the present invention, as shown in Fig. 1-2, step S2 is to deposit and form a bottom electrode on the front side of the SOI, and the material of the bottom electrode is preferably Ti/Pt material, and deposit Piezoelectric film is formed by deposition; as shown in Figure 1-3, interdigital transducers and reflective grids are deposited on the piezoelectric film, and the final structure is shown in Figure 4(b). The material of the interdigital transducer and the reflection grid is aluminum, gold, molybdenum, platinum, iridium or their alloys. In this embodiment, the material of the interdigital transducer and the reflection grid is preferably molybdenum.
S4,如图1-4所示,淀积形成绝缘保护层6,具体材料优选为二氧化硅。S4, as shown in FIGS. 1-4 , deposit and form an insulating protection layer 6 , and the specific material is preferably silicon dioxide.
S5,如图1-5和1-6所示,光刻,刻蚀绝缘保护层和压电薄膜层;在本实施方式中,图1-5为开窗口至底电极,图1-6为开窗口至叉指换能器。S5, as shown in Figures 1-5 and 1-6, photolithography, etch the insulating protective layer and the piezoelectric film layer; in this embodiment, Figure 1-5 shows opening the window to the bottom electrode, Figure 1-6 shows Open the window to the interdigital transducer.
S6,如图1-7所示,淀积导电金属层,光刻,刻蚀,形成信号引出盘10,引出盘的材料为金属,优选为金。S6, as shown in FIGS. 1-7 , deposit a conductive metal layer, perform photolithography, and etch to form a signal lead-out plate 10, and the material of the lead-out plate is metal, preferably gold.
S7,光刻,如图1-8所示,在所述SOI背面刻蚀,直至SOI的隔离层暴露形成压力敏感层。S7, photolithography, as shown in FIG. 1-8, etching on the back of the SOI until the isolation layer of the SOI is exposed to form a pressure sensitive layer.
图2-1至图2-9是本发明一种优选实施例中基于SOI和压电薄膜的声表面波高温压力传感器绝压式芯片流程图,其包括如下步骤:Fig. 2-1 to Fig. 2-9 are flow charts of the absolute pressure chip of the surface acoustic wave high temperature pressure sensor based on SOI and piezoelectric film in a preferred embodiment of the present invention, which includes the following steps:
S1,如图2-1所示,提供SOI,所述SOI器件层的电阻率≥5kΩ。S1, as shown in Figure 2-1, provides SOI, and the resistivity of the SOI device layer is ≥5kΩ.
S2,如图2-2所示,在所述SOI正面淀积形成压电薄膜,在本实施方式中,压电薄膜为晶粒呈c轴取向的纯AlN压电薄膜或掺杂10at%-43at%钪元素的 AlN压电薄膜。S2, as shown in Figure 2-2, a piezoelectric film is deposited on the front side of the SOI to form a piezoelectric film. In this embodiment, the piezoelectric film is a pure AlN piezoelectric film whose crystal grains are c-axis oriented or doped with 10at%- AlN piezoelectric film with 43at% scandium element.
S3,如图2-3所示,在压电薄膜之上淀积形成叉指换能器和反射栅;在本发明另外的优选实施方式中,如图2-2所示,步骤S2为在SOI正面淀积形成底电极,具体底电极的材料优选为Ti/Pt材料,在所述底电极之上淀积形成压电薄膜;如图1-3所示,在压电薄膜之上淀积形成叉指换能器和反射栅,叉指换能器和反射栅的材料为铝、金、钼、铂、铱或其合金,在本实施方式中,叉指换能器和反射栅的材料优选为钼。S3, as shown in Figure 2-3, depositing and forming an interdigital transducer and a reflective grid on the piezoelectric film; in another preferred embodiment of the present invention, as shown in Figure 2-2, step S2 is The bottom electrode is deposited on the front side of SOI, and the material of the bottom electrode is preferably Ti/Pt material, and a piezoelectric film is deposited on the bottom electrode; as shown in Figure 1-3, a piezoelectric film is deposited on the piezoelectric film Form the interdigital transducer and the reflective grid, the materials of the interdigital transducer and the reflective grid are aluminum, gold, molybdenum, platinum, iridium or their alloys, in this embodiment, the material of the interdigital transducer and the reflective grid Molybdenum is preferred.
S4,如图2-4所示,淀积形成绝缘保护层,具体材料优选为二氧化硅。S4, as shown in FIG. 2-4, deposit and form an insulating protective layer, and the specific material is preferably silicon dioxide.
S5,如图2-5和2-6所示,光刻,刻蚀绝缘保护层和压电薄膜层;在本实施方式中,图2-5为开窗口至底电极,图2-6为开窗口至叉指换能器。S5, as shown in Figures 2-5 and 2-6, photolithography, etch the insulating protective layer and the piezoelectric film layer; in this embodiment, Figure 2-5 shows opening the window to the bottom electrode, Figure 2-6 shows Open the window to the interdigital transducer.
S6,如图2-7所示,淀积导电金属层,光刻,刻蚀,形成信号引出盘,引出盘的材料为金属,优选为金。S6, as shown in FIG. 2-7, deposit a conductive metal layer, perform photolithography, and etch to form a signal lead-out disk, and the material of the lead-out disk is metal, preferably gold.
S7,如图2-8所示,光刻,在所述SOI背面刻蚀,直至SOI的隔离层暴露形成压力敏感层。S7, as shown in FIG. 2-8, photolithography, etch on the back of the SOI until the isolation layer of the SOI is exposed to form a pressure sensitive layer.
S8,如图2-9所示,将SOI背面与第二芯片基底键合形成高真空密封腔室。在本实施方式中,采用的第二芯片基底为玻璃。在本实施方式中,在抽真空的条件下进行键合,具体采用的真空等级可根据具体实验确定,优选高真空。S8, as shown in FIGS. 2-9 , bonding the back of the SOI to the second chip substrate to form a high-vacuum sealed chamber. In this embodiment, the second chip substrate used is glass. In this embodiment, the bonding is carried out under vacuum conditions, and the specific vacuum level used can be determined according to specific experiments, preferably high vacuum.
图3-1至图3-9是本发明另一种优选实施例中基于SOI和压电薄膜的声表面波高温压力传感器绝压式芯片流程图,与图2-9不同之处在于:高真空密封腔室的制作工艺不再采用硅-玻璃阳极键合工艺,而是采用硅-硅键合工艺,如图3-9所示。Figure 3-1 to Figure 3-9 are flow charts of the absolute pressure chip of the surface acoustic wave high temperature pressure sensor based on SOI and piezoelectric thin film in another preferred embodiment of the present invention, the difference from Figure 2-9 is that: The manufacturing process of the vacuum-sealed chamber no longer uses the silicon-glass anode bonding process, but the silicon-silicon bonding process, as shown in Figure 3-9.
如图5所示,在SOI正面先淀积形成二氧化硅平铺层,或者在SOI正面先淀积形成二氧化硅立体结构与多晶硅立体结构交叉分布的周期性阵列平铺层,再形成其他的结构。例如再淀积形成底电极和压电薄膜,在所述压电薄膜上淀积形成叉指换能器和反射栅。As shown in Figure 5, a silicon dioxide tile layer is first deposited on the front of the SOI, or a periodic array tile layer with a silicon dioxide three-dimensional structure intersecting with a polysilicon three-dimensional structure is deposited on the front side of the SOI, and then other layers are formed. Structure. For example, the bottom electrode and the piezoelectric film are deposited to form the bottom electrode and the piezoelectric film, and the interdigital transducer and the reflective grid are formed by depositing on the piezoelectric film.
在本实施方式中,叉指换能器和反射栅可以组成声表面波单端谐振器、声表面波双端谐振器或声表面波延迟线。In this implementation manner, the interdigital transducer and the reflective grating may form a surface acoustic wave single-ended resonator, a surface acoustic wave double-ended resonator, or a surface acoustic wave delay line.
图6(a)和图6(b)是本发明一种优选实施例中使用两个谐振器形式的双通道补偿方式补偿抵消环境温度的变化导致的测压误差示意图。在本实施方式中,也可使用两个延迟线形式的双通道补偿方式补偿抵消环境温度的变化导致的测压误差。由于结构参数不同,图6(a)中的谐振器响应信号的变化只反映环境温度变化,图6(b)中的谐振器响应信号的变化则反映环境温度变化和待测压力变化的双重作用。Fig. 6(a) and Fig. 6(b) are schematic diagrams of a preferred embodiment of the present invention using a dual-channel compensation method in the form of two resonators to compensate and offset pressure measurement errors caused by changes in ambient temperature. In this embodiment, a dual-channel compensation method in the form of two delay lines may also be used to compensate and offset pressure measurement errors caused by changes in ambient temperature. Due to the different structural parameters, the change of the resonator response signal in Figure 6(a) only reflects the change of the ambient temperature, while the change of the resonator response signal in Figure 6(b) reflects the dual effects of the change of the ambient temperature and the change of the pressure to be measured .
如果所述芯片中存在两种或两种以上的对温度和压力敏感的声波模态,也可同时使用两种声波模态信号补偿方式补偿抵消环境温度的变化导致的测压误差,所述两种声波模态具有不同的温度敏感性能和(或)压力敏感性能。If there are two or more acoustic wave modes sensitive to temperature and pressure in the chip, the two acoustic wave mode signal compensation methods can also be used at the same time to compensate and offset the pressure measurement error caused by the change of the ambient temperature. Each acoustic wave mode has different temperature sensitivity and/or pressure sensitivity.
本发明的基于SOI和压电薄膜的声表面波高温压力传感器芯片能实现高温环境下的压力测量。在本实施方式中,压电薄膜通过磁控溅射技术在压力敏感层上沉积形成,叉指换能器和反射栅通过MEMS工艺在压电薄膜上制作,传感器芯片利用压电效应和逆压电效应进行声表面波的激发和接收。叉指换能器在压电薄膜表面激发出声表面波,该声表面波向两侧的反射栅处传播,传播至反射栅的位置后被反射返回。反射回的声表面波又通过叉指换能器重新转换成电磁波信号,即响应信号。当待测压力作用在压电薄膜和压力敏感层上,导致该复合膜发生形变,声表面波传播的速度发生变化,进而响应信号发生变化,该电磁波响应信号经过特定的信号处理分析,实现压力测量。该传感器芯片可以做成差压结构,也可以通过真空密封键合工艺做成绝压结构。本发明结构简单、体积小、重量轻、精度高,可以应用于航空航天、石油化工、核工业等高温环境下压力参数的测量。The surface acoustic wave high temperature pressure sensor chip based on SOI and piezoelectric thin film of the invention can realize pressure measurement under high temperature environment. In this embodiment, the piezoelectric film is deposited on the pressure-sensitive layer by magnetron sputtering technology, the interdigital transducer and the reflective grid are fabricated on the piezoelectric film by MEMS technology, and the sensor chip utilizes piezoelectric effect and inverse pressure Electric effects carry out excitation and reception of surface acoustic waves. The interdigital transducer excites the surface acoustic wave on the surface of the piezoelectric film, and the surface acoustic wave propagates to the reflection grids on both sides, propagates to the position of the reflection grid and is reflected back. The reflected surface acoustic wave is converted into an electromagnetic wave signal again through the interdigital transducer, that is, the response signal. When the pressure to be measured acts on the piezoelectric film and the pressure-sensitive layer, the composite film is deformed, the propagation speed of the surface acoustic wave changes, and the response signal changes. The electromagnetic wave response signal is analyzed by specific signal processing to realize the pressure Measurement. The sensor chip can be made into a differential pressure structure, or can be made into an absolute pressure structure through a vacuum-tight bonding process. The invention has the advantages of simple structure, small size, light weight and high precision, and can be applied to the measurement of pressure parameters in high-temperature environments such as aerospace, petrochemical and nuclear industries.
需要说明的是,说明书附图中图下面的小方框为材料说明。It should be noted that the small boxes below the figures in the drawings of the specification are material descriptions.
在本说明书的描述中,参考术语“一个实施例”、“一些实施例”、“示例”、“具体示例”或“一些示例”等的描述意指结合该实施例或示例描述的具体特征、结构、材料或者特点包含于本发明的至少一个实施例或示例中。在本说明书中,对上述术语的示意性表述不一定指的是相同的实施例或示例。而且,描述的具体特征、结构、材料或者特点可以在任何的一个或多个实施例或示例中以合适的方式结合。In the description of this specification, descriptions referring to the terms "one embodiment", "some embodiments", "example", "specific examples" or "some examples" mean specific features described in connection with the embodiment or example, A structure, material or characteristic is included in at least one embodiment or example of the invention. In this specification, schematic representations of the above terms do not necessarily refer to the same embodiment or example. Furthermore, the specific features, structures, materials or characteristics described may be combined in any suitable manner in any one or more embodiments or examples.
尽管已经示出和描述了本发明的实施例,本领域的普通技术人员可以理解:在不脱离本发明的原理和宗旨的情况下可以对这些实施例进行多种变化、修改、替换和变型,本发明的范围由权利要求及其等同物限定。Although the embodiments of the present invention have been shown and described, those skilled in the art can understand that various changes, modifications, substitutions and modifications can be made to these embodiments without departing from the principle and spirit of the present invention. The scope of the invention is defined by the claims and their equivalents.
Claims (10)
- A kind of 1. surface acoustic wave chip of high-temp pressure sensor based on SOI and piezoelectric membrane, it is characterised in that including:It is quick that soi chip substrate, the silicon dioxide layer in the soi chip substrate and device layer thereon collectively form SOI pressure Layer is felt, formed with piezoelectric membrane on the SOI pressure sensitive layers, formed with interdigital transducer and anti-on the piezoelectric membrane Penetrate grid;Reference is provided when extending to pressure sensitive layer formed with detection pressure from soi chip substrate bottom surface in soi chip substrate The chamber of pressure.
- 2. the surface acoustic wave chip of high-temp pressure sensor based on SOI and piezoelectric membrane, its feature exist as claimed in claim 1 In resistivity >=5k Ω of SOI device layer;And/or the piezoelectric membrane is pure AlN piezoelectric membrane or doping 10at%-43at% scandium element of the crystal grain in c-axis orientation AlN piezoelectric membranes.
- 3. the surface acoustic wave chip of high-temp pressure sensor based on SOI and piezoelectric membrane, its feature exist as claimed in claim 1 In interdigital transducer and reflecting grating are set in parallel above piezoelectric membrane, and the interdigital transducer and reflection grid material are same A kind of material.
- 4. the surface acoustic wave chip of high-temp pressure sensor based on SOI and piezoelectric membrane as described in claim 1 or 3, it is special Sign is that the material of the interdigital transducer and reflecting grating is aluminium, gold, molybdenum, platinum, iridium or its alloy.
- 5. the surface acoustic wave chip of high-temp pressure sensor based on SOI and piezoelectric membrane, its feature exist as claimed in claim 1 In being the second chip base under the soi chip substrate, pressure extended to from the second chip base in soi chip substrate Formed with high vacuum seal chamber between sensitive layer.
- 6. the surface acoustic wave chip of high-temp pressure sensor based on SOI and piezoelectric membrane, its feature exist as claimed in claim 1 In can draw and be grounded, can also be not brought up formed with hearth electrode, the hearth electrode between pressure sensitive layer and piezoelectric membrane.
- 7. the surface acoustic wave chip of high-temp pressure sensor based on SOI and piezoelectric membrane as described in claim 1 or 6, it is special Sign is, formed with silica tiling layer between pressure sensitive layer and hearth electrode, or in pressure sensitive layer and hearth electrode Between the cyclic array formed with silica stereochemical structure and polysilicon stereochemical structure cross-distribution tile layer;Or pressing Formed with silica tiling layer between power sensitive layer and piezoelectric membrane, or formed between pressure sensitive layer and piezoelectric membrane There is the cyclic array tiling layer of silica stereochemical structure and polysilicon stereochemical structure cross-distribution.
- A kind of 8. method for preparing the surface acoustic wave chip of high-temp pressure sensor based on SOI and piezoelectric membrane, it is characterised in that Comprise the following steps:S1, there is provided SOI, resistivity >=5k Ω of SOI device layer;S2, piezoelectric membrane is formed in the deposit of SOI fronts;S3, deposited on the piezoelectric membrane and form interdigital transducer and reflecting grating;S4, deposit form insulating protective layer;S5, photoetching, etch insulating protective layer and piezoelectric thin film layer, windowing;S6, conductive metal layer is deposited, photoetching, etching, signal is formed and draws disk;S7, photoetching, in the SOI back-etchings, until the separation layer on SOI exposes to form pressure sensitive layer;With or without step S8, the SOI back sides and the second chip base are bonded together to form into high vacuum seal chamber.
- 9. the side of the surface acoustic wave chip of high-temp pressure sensor based on SOI and piezoelectric membrane is prepared as claimed in claim 8 Method, it is characterised in that the step S2 is:Hearth electrode is formed in the deposit of SOI fronts, is then formed sediment on the hearth electrode Product forms piezoelectric membrane;Or step S2 is:Silica tiling layer is formed in the deposit of SOI fronts or deposit forms silica solid The cyclic array tiling layer of structure and polysilicon stereochemical structure cross-distribution, then deposit forms pressure on the tiling layer Conductive film;Or step S2 is:Silica tiling layer is formed in the deposit of SOI fronts or deposit forms silica solid The cyclic array tiling layer of structure and polysilicon stereochemical structure cross-distribution, then deposit forms hearth electrode, in bottom electricity Deposit forms piezoelectric membrane on pole.
- A kind of 10. application knot of the surface acoustic wave chip of high-temp pressure sensor based on SOI and piezoelectric membrane described in claim 1 Structure, it is characterised in that using one of following structure:Structure one:Simultaneously counteracting environment temperature is compensated using the two-channel compensation mode of two resonators or two delay line forms Change caused by pressure measurement error, described two resonators or two delay lines have because position is different or structural parameters are different There are different temperature sensitivity energy and/or pressure-sensitivity characteristic;Structure two:As two or more the sound wave modal sensitive to temperature and pressure in the chip be present, make simultaneously Pressure measurement error caused by compensating the change for offsetting environment temperature with two kinds of sound wave modal signal compensation modes, described two sound wave moulds State has different temperature sensitivity energy and/or pressure-sensitivity characteristic.
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