CN106676670A - Hyaluronic acid/silk fibroin nano-fibre and preparation method thereof - Google Patents
Hyaluronic acid/silk fibroin nano-fibre and preparation method thereof Download PDFInfo
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- CN106676670A CN106676670A CN201611126194.5A CN201611126194A CN106676670A CN 106676670 A CN106676670 A CN 106676670A CN 201611126194 A CN201611126194 A CN 201611126194A CN 106676670 A CN106676670 A CN 106676670A
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- hyaluronic acid
- silk fibroin
- essential oil
- fiber
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- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F8/00—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof
- D01F8/02—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from cellulose, cellulose derivatives, or proteins
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F1/00—General methods for the manufacture of artificial filaments or the like
- D01F1/02—Addition of substances to the spinning solution or to the melt
- D01F1/10—Other agents for modifying properties
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F8/00—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof
- D01F8/18—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from other substances
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- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Textile Engineering (AREA)
- Manufacturing & Machinery (AREA)
- Health & Medical Sciences (AREA)
- Toxicology (AREA)
- Cosmetics (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
Abstract
The invention belongs to the field of novel fibre materials, and particularly relates to a hyaluronic acid/silk fibroin nano-fibre and a preparation method thereof. According to the preparation method, hyaluronic acid and silk fibroin are prepared into an electrostatic spinning mixed solution; essential oil and vitamin C are added for performing blending to obtain the hyaluronic acid/silk fibroin nano-fibre which can slowly release the essential oil and the vitamin C; the hyaluronic acid/silk fibroin nano-fibre has high-quality skin-friendly, skin-care and skin-beatifying effects; the hyaluronic acid/silk fibroin nano-fibre prepared with the preparation method can be used for textile fabrics, such as facial mask tissue, underwear, scarves, socks and the like.
Description
Technical field
The invention belongs to new fiber materials field, more particularly to a kind of hyaluronic acid/silk fibroin nano-fiber and its
Preparation method.
Background technology
Fiber refers to the material being made up of continuous or discrete filament.Play important in weaving, military, medicine and other fields
Effect.In recent years, synthetic fibers turn into the study hotspot of Material Field, if any the carbon fiber of good reputation etc. of black gold.
Hyaluronic acid is a kind of acid mucopolysaccharide, is shown in body with its unique molecular structure and physicochemical property many
Important physiological function, such as lubricating joint are planted, the permeability of vascular wall, regulatory protein matter, Water-Electrolyte diffusion and operating is adjusted,
Promote wound healing etc..Particular, it is important that hyaluronic acid has special water retention, it is guarantor in the nature having now been found that
Moist best material, is referred to as preferable NMF.Hyaluronic acid is a kind of multi-functional matrix, and hyaluronic acid is extensive
It is distributed in partes corporis humani position.Wherein skin also contains substantial amounts of hyaluronic acid.Human skin is ripe and ageing process is also with saturating
Content and the metabolism of the acid of bright matter and change, it can improve skin-nourishing and be metabolized, and make that skin is tender, smooth, go to wrinkle, increase
Elasticity, prevent aging, be again good skin penetration enhancer while moisturizing.Used cooperatively with other nutritional ingredients, can
Promote the more preferable effect of nutrient absorption to play.
Fibroin albumen, is the natural polymer fibrin extracted from silk, and content accounts for the 70%~80% of silk, is had
Standby good pliability and tensile strength, breathable moisture permeability, slow release and biocompatibility.Fibroin albumen can increase skin angle
The water content of matter layer, promotes collagen synthesis, strengthens the tension force and elasticity of skin, promotes pigment to decompose, even skin tone.
Electrostatic spinning is a kind of special fiber fabrication process, and polymer solution carries out jet spinning in highfield.
Under electric field action, the drop at syringe needle can be changed into cone from spherical, and obtain fiber filaments from conical tip extension.This side
Formula can produce the polymer filaments of nanometer grade diameter.
The content of the invention
The present invention is the technical problem for solving existing fibroin fiber unitary function, there is provided a kind of hyaluronic acid/fibroin
Protein nano fiber, and add appropriate vitamin C and the essential oil to carry out electrostatic spinning, prepare a kind of pro-skin, moisturizing and tool
The fiber of standby slow-release function.
To solve the above problems, technical scheme is as follows：
A kind of hyaluronic acid/silk fibroin nano-fiber, including following components：
Fibroin albumen：35-45 parts；
Hyaluronic acid：35-45 parts；
Essential oil：5-10 parts；
Vitamin C：5-10 parts.
Fibroin albumen contains 18 kinds of amino acid and various trace elements, has stronger affinity with human body skin, is easy to
Absorbed by human skin, nanometer fibrous more soft easy absorption；Hyaluronic acid has special water retention, is to send out at present
The best material of moisture retention in existing nature, can improve skin-nourishing metabolism, make that skin is tender, smooth, go to wrinkle, increase bullet
Property, aging is prevented, be again good skin penetration enhancer while moisturizing；Hyaluronic acid combines to form multiple with fibroin albumen
Nanofiber is closed, the more preferable effect for promoting nutrient absorption can be played；Essential oil and vitamin C are added in spinning solution, and formation is received
After rice fiber, it is dispersed in nanofiber system to stable and uniform, rather than simple suction-operated, therefore can be by fiber holes
Sustained release, long-time doing the trick are realized in road diffusion.
As a modification of the present invention, the essential oil in the hyaluronic acid/silk fibroin nano-fiber is Rosa Damascana,
Lavender, flores aurantii essential oil, Geranium Essential, chamomile essential oil, Cananga odorata quintessence oil, honeysuckle essential oil, tea tree ethereal oil, Archangelica officinalis Hoffmann
One or more of essential oil, primrose essential oil, Bergamot.Can be selected according to different demands such as fragrance, skin cares.
Used as a modification of the present invention, the hyaluronic acid in the hyaluronic acid/silk fibroin nano-fiber includes dividing
Son amount is one kind or several of 1800000~2200000,1000000~1800000,400000~1000000 hyaluronic acid
Kind.Macromolecular hyaluronic acid（Molecular weight ranges 1800000~2200000）One layer of ventilative film can be formed in skin surface,
Skin smooth is moistened, and the intrusion of alien bacteria, dust, ultraviolet can be intercepted, protect the skin from infringement；Middle molecule is transparent
Matter acid（Molecular weight ranges 1000000~1800000）Can be compacted skin, permanent moisturizing；Micromolecule hyaluronic acid（Molecular weight model
Enclose 400 000~1 000000）Corium can be penetrated into, with mild dilation capillary, increased blood circulation, improved middle generation
Thank, promote skin-nourishing absorption, with stronger wrinkle-chasing function, skin elasticity can be increased, delay skin aging is comprised only
The skin care item effect of unimodal molecular weight hyaluronic acid composition is limited, can not play the optimal skin-care effect of hyaluronic acid, therefore
Hyaluronic acid containing three kinds of molecular weight is optimal.
A kind of preparation method of hyaluronic acid/silk fibroin nano-fiber, comprises the following steps：
A. it is 1 fibroin albumen to be dissolved in into volume ratio:In 2 glacial acetic acid, DMA mixed solvent, ultrasound 1 is small
When, it is the fibroin albumen spinning solution of 2%-90% that mass fraction is obtained；
B. it is 1 hyaluronic acid to be dissolved in into volume ratio:In 2 glacial acetic acid, DMA mixed solvent, ultrasound 1 is small
When, it is the hyaluronic acid spinning solution of 2%-90% that mass fraction is obtained；
C. step A and step B resulting solutions are mixed, adds essential oil and vitamin C, stirred 1 hour at 10-15 DEG C, be made
Electrostatic spinning mixed liquor；
D. electrostatic spinning mixed liquor is added into electrostatic spinning machine, hyaluronic acid/silk fibroin nano-fiber is obtained.
As a modification of the present invention, in the preparation method of the hyaluronic acid/silk fibroin nano-fiber, the silk
Fibroin, hyaluronic acid, essential oil, the mass ratio of vitamin C addition are：7:7:1:1.
As a modification of the present invention, in the preparation method of the hyaluronic acid/silk fibroin nano-fiber, the silk
Fibroin, hyaluronic acid, essential oil, the mass ratio of vitamin C addition are：5:5:1:1.
Relative to prior art, advantages of the present invention is as follows,
Preparation method of the invention is convenient and simple, and reaction condition is gentle；Due to raw material excellent properties in itself, and by Static Spinning
Prepared hyaluronic acid/fibroin albumen the composite nano fiber of silk so that both advantages are combined, thus its have more high-quality pro-skin,
Skin care, the effect of skin makeup, by adding essential oil and vitamin C in spinning solution, formation can be sustained essential oil and ascorbic fibre
Dimension, makes it have long-lasting.Hyaluronic acid/fibroin albumen composite nano fiber obtained by the present invention can be used for face paper, patch
The yarn fabrics such as body clothing, silk scarf, socks.
Specific embodiment
Embodiment 1：
A kind of hyaluronic acid/silk fibroin nano-fiber, including following components：
Fibroin albumen：35-45 parts；
Hyaluronic acid：35-45 parts；
Essential oil：5-10 parts；
Vitamin C：5-10 parts.
As a modification of the present invention, the essential oil in the hyaluronic acid/silk fibroin nano-fiber is Rosa Damascana,
Lavender, flores aurantii essential oil, Geranium Essential, chamomile essential oil, Cananga odorata quintessence oil, honeysuckle essential oil, tea tree ethereal oil, Archangelica officinalis Hoffmann
One or more of essential oil, primrose essential oil, Bergamot.Can be selected according to different demands such as fragrance, skin cares.
Used as a modification of the present invention, the hyaluronic acid in the hyaluronic acid/silk fibroin nano-fiber includes dividing
Son amount is one kind or several of 1800000~2200000,1000000~1800000,400000~1000000 hyaluronic acid
Kind.Macromolecular hyaluronic acid（Molecular weight ranges 1800000~2200000）One layer of ventilative film can be formed in skin surface,
Skin smooth is moistened, and the intrusion of alien bacteria, dust, ultraviolet can be intercepted, protect the skin from infringement；Middle molecule is transparent
Matter acid（Molecular weight ranges 1000000~1800000）Can be compacted skin, permanent moisturizing；Micromolecule hyaluronic acid（Molecular weight model
Enclose 400 000~1 000000）Corium can be penetrated into, with mild dilation capillary, increased blood circulation, improved middle generation
Thank, promote skin-nourishing absorption, with stronger wrinkle-chasing function, skin elasticity can be increased, delay skin aging is comprised only
The skin care item effect of unimodal molecular weight hyaluronic acid composition is limited, can not play the optimal skin-care effect of hyaluronic acid, therefore
Hyaluronic acid containing three kinds of molecular weight is optimal.
Embodiment 2：
A kind of preparation method of hyaluronic acid/silk fibroin nano-fiber, comprises the following steps：
A. it is 1 fibroin albumen to be dissolved in into volume ratio:In 2 glacial acetic acid, DMA mixed solvent, ultrasound 1 is small
When, it is 2% fibroin albumen spinning solution that mass fraction is obtained；
B. it is 1 hyaluronic acid to be dissolved in into volume ratio:In 2 glacial acetic acid, DMA mixed solvent, ultrasound 1 is small
When, prepared mass fraction is 2% hyaluronic acid spinning solution；
C. step A and step B resulting solutions are mixed, adds essential oil and vitamin C, stirred 1 hour at 10-15 DEG C, be made
Electrostatic spinning mixed liquor；
D. electrostatic spinning mixed liquor is added into electrostatic spinning machine, hyaluronic acid/silk fibroin nano-fiber is obtained.
As a modification of the present invention, in the preparation method of the hyaluronic acid/silk fibroin nano-fiber, the silk
Fibroin, hyaluronic acid, essential oil, the mass ratio of vitamin C addition are：5:5:1:1.
Spinning is preferably provided with parameter：Under room temperature condition, spinning voltage is 35kV, and spinning speed is 2 mL/h.Spinning nozzle is arrived
Receiver board distance is 25cm.
Embodiment 3：
A kind of preparation method of hyaluronic acid/silk fibroin nano-fiber, comprises the following steps：
A. it is 1 fibroin albumen to be dissolved in into volume ratio:In 2 glacial acetic acid, DMA mixed solvent, ultrasound 1 is small
When, prepared mass fraction is 30% fibroin albumen spinning solution；
B. it is 1 hyaluronic acid to be dissolved in into volume ratio:In 2 glacial acetic acid, DMA mixed solvent, ultrasound 1 is small
When, prepared mass fraction is 30% hyaluronic acid spinning solution；
C. step A and step B resulting solutions are mixed, adds essential oil and vitamin C, stirred 1 hour at 10-15 DEG C, be made
Electrostatic spinning mixed liquor；
D. electrostatic spinning mixed liquor is added into electrostatic spinning machine, hyaluronic acid/silk fibroin nano-fiber is obtained.
As a modification of the present invention, in the preparation method of the hyaluronic acid/silk fibroin nano-fiber, the silk
Fibroin, hyaluronic acid, essential oil, the mass ratio of vitamin C addition are：5:5:1:1.
Spinning is preferably provided with parameter：Under room temperature condition, spinning voltage is 28kV, and spinning speed is 1.5 mL/h.Spinning nozzle
It is 18cm to receiver board distance.
Embodiment 4：
A kind of preparation method of hyaluronic acid/silk fibroin nano-fiber, comprises the following steps：
A. it is 1 fibroin albumen to be dissolved in into volume ratio:In 2 glacial acetic acid, DMA mixed solvent, ultrasound 1 is small
When, prepared mass fraction is 60% fibroin albumen spinning solution；
B. it is 1 hyaluronic acid to be dissolved in into volume ratio:In 2 glacial acetic acid, DMA mixed solvent, ultrasound 1 is small
When, prepared mass fraction is 60% hyaluronic acid spinning solution；
C. step A and step B resulting solutions are mixed, adds essential oil and vitamin C, stirred 1 hour at 10-15 DEG C, system
Into electrostatic spinning mixed liquor；
D. electrostatic spinning mixed liquor is added into electrostatic spinning machine, hyaluronic acid/silk fibroin nano-fiber is obtained.
As a modification of the present invention, in the preparation method of the hyaluronic acid/silk fibroin nano-fiber, the silk
Fibroin, hyaluronic acid, essential oil, the mass ratio of vitamin C addition are：7:7:1:1.
Spinning is preferably provided with parameter：Under room temperature condition, spinning voltage is 22kV, and spinning speed is 1 mL/h.Spinning nozzle is arrived
Receiver board distance is 15cm.
Embodiment 5：
A kind of preparation method of hyaluronic acid/silk fibroin nano-fiber, comprises the following steps：
A. it is 1 fibroin albumen to be dissolved in into volume ratio:In 2 glacial acetic acid, DMA mixed solvent, ultrasound 1 is small
When, prepared mass fraction is 90% fibroin albumen spinning solution；
B. it is 1 hyaluronic acid to be dissolved in into volume ratio:In 2 glacial acetic acid, DMA mixed solvent, ultrasound 1 is small
When, prepared mass fraction is 90% hyaluronic acid spinning solution；
C. step A and step B resulting solutions are mixed, adds essential oil and vitamin C, stirred 1 hour at 10-15 DEG C, system
Into electrostatic spinning mixed liquor；
D. electrostatic spinning mixed liquor is added into electrostatic spinning machine, hyaluronic acid/silk fibroin nano-fiber is obtained.
As a modification of the present invention, in the preparation method of the hyaluronic acid/silk fibroin nano-fiber, the silk
Fibroin, hyaluronic acid, essential oil, the mass ratio of vitamin C addition are：7:7:1:1.
Spinning is preferably provided with parameter：Under room temperature condition, spinning voltage is 15kV, and spinning speed is 1 mL/h.Spinning nozzle is arrived
Receiver board distance is 10cm.
Hyaluronic acid/fibroin albumen composite nano fiber obtained by the present invention can be used for face paper, personal clothing, silk
The yarn fabrics such as towel, socks.
It should be noted that above-described embodiment is only presently preferred embodiments of the present invention, it is not of the invention for limiting
Protection domain, the equivalent made on the basis of the above or replacement belong to protection scope of the present invention.
Claims (6)
1. a kind of hyaluronic acid/silk fibroin nano-fiber, it is characterised in that including following components：
Fibroin albumen：35-45 parts；
Hyaluronic acid：35-45 parts；
Essential oil：5-10 parts；
Vitamin C：5-10 parts.
2. hyaluronic acid/silk fibroin nano-fiber as claimed in claim 1, it is characterised in that the essential oil is rhodamine toner
Oil, Lavender, flores aurantii essential oil, Geranium Essential, chamomile essential oil, Cananga odorata quintessence oil, honeysuckle essential oil, tea tree ethereal oil, Europe
One or more of root of Dahurain angelica essential oil, primrose essential oil, Bergamot.
3. hyaluronic acid/silk fibroin nano-fiber as claimed in claim 1, it is characterised in that the hyaluronic acid includes
Molecular weight is one kind of 1800000~2200000,1000000~1800000,400000~1000000 hyaluronic acid or several
Kind.
4. a kind of preparation method of hyaluronic acid/silk fibroin nano-fiber, it is characterised in that comprise the following steps：
A. it is 1 fibroin albumen to be dissolved in into volume ratio:In 2 glacial acetic acid, DMA mixed solvent, ultrasound 1 is small
When, it is the fibroin albumen spinning solution of 2%-90% that mass fraction is obtained；
B. it is 1 hyaluronic acid to be dissolved in into volume ratio:In 2 glacial acetic acid, DMA mixed solvent, ultrasound 1 is small
When, it is the hyaluronic acid spinning solution of 2%-90% that mass fraction is obtained；
C. step A and step B resulting solutions are mixed, adds essential oil and vitamin C, stirred 1 hour at 10-15 DEG C, be made
Electrostatic spinning mixed liquor；
Electrostatic spinning mixed liquor is added into electrostatic spinning machine, hyaluronic acid/silk fibroin nano-fiber is obtained.
5. the preparation method of hyaluronic acid/silk fibroin nano-fiber as claimed in claim 4, it is characterised in that the silk
Fibroin, hyaluronic acid, essential oil, the mass ratio of vitamin C addition are：7:7:1:1.
6. the preparation method of the hyaluronic acid/silk fibroin nano-fiber described in claim 4, it is characterised in that the fibroin
Albumen, hyaluronic acid, essential oil, the mass ratio of vitamin C addition are：5:5:1:1.
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Cited By (5)
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|---|---|---|---|---|
| CN108283607A (en) * | 2018-01-22 | 2018-07-17 | 广西科学院 | A kind of spinning liquid, i.e. spinning nanometer facial mask and preparation method thereof |
| CN108635288A (en) * | 2018-05-31 | 2018-10-12 | 东莞市亿茂滤材有限公司 | A kind of filiform gel mask and preparation method thereof |
| CN109573322A (en) * | 2019-01-10 | 2019-04-05 | 广东工业大学 | A kind of gelatin/chamomile essential oil nanofiber biological dressing and edible packaging and preparation method thereof |
| CN112226836A (en) * | 2020-10-15 | 2021-01-15 | 深圳千维生态纺织有限公司 | Chamomile fiber containing blue fragrant oil azulene and capable of promoting sleep and beautifying features and preparation method of chamomile fiber |
| CN114209869A (en) * | 2022-01-14 | 2022-03-22 | 北京极暖网络科技有限公司 | Self-heating hyaluronic acid material, preparation method and pants-type sanitary towel |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN108283607A (en) * | 2018-01-22 | 2018-07-17 | 广西科学院 | A kind of spinning liquid, i.e. spinning nanometer facial mask and preparation method thereof |
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| CN108635288A (en) * | 2018-05-31 | 2018-10-12 | 东莞市亿茂滤材有限公司 | A kind of filiform gel mask and preparation method thereof |
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| CN109573322A (en) * | 2019-01-10 | 2019-04-05 | 广东工业大学 | A kind of gelatin/chamomile essential oil nanofiber biological dressing and edible packaging and preparation method thereof |
| CN112226836A (en) * | 2020-10-15 | 2021-01-15 | 深圳千维生态纺织有限公司 | Chamomile fiber containing blue fragrant oil azulene and capable of promoting sleep and beautifying features and preparation method of chamomile fiber |
| CN114209869A (en) * | 2022-01-14 | 2022-03-22 | 北京极暖网络科技有限公司 | Self-heating hyaluronic acid material, preparation method and pants-type sanitary towel |
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Application publication date: 20170517 |