CN112226836A - Chamomile fiber containing blue fragrant oil azulene and capable of promoting sleep and beautifying features and preparation method of chamomile fiber - Google Patents
Chamomile fiber containing blue fragrant oil azulene and capable of promoting sleep and beautifying features and preparation method of chamomile fiber Download PDFInfo
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- CN112226836A CN112226836A CN202011102527.7A CN202011102527A CN112226836A CN 112226836 A CN112226836 A CN 112226836A CN 202011102527 A CN202011102527 A CN 202011102527A CN 112226836 A CN112226836 A CN 112226836A
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- chamomile
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- cyclodextrin
- beautifying
- ion exchange
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- 240000003538 Chamaemelum nobile Species 0.000 title claims abstract description 119
- 235000007866 Chamaemelum nobile Nutrition 0.000 title claims abstract description 119
- 235000007232 Matricaria chamomilla Nutrition 0.000 title claims abstract description 118
- 239000000835 fiber Substances 0.000 title claims abstract description 65
- CUFNKYGDVFVPHO-UHFFFAOYSA-N azulene Chemical compound C1=CC=CC2=CC=CC2=C1 CUFNKYGDVFVPHO-UHFFFAOYSA-N 0.000 title claims abstract description 42
- 239000000341 volatile oil Substances 0.000 title claims abstract description 25
- 238000002360 preparation method Methods 0.000 title claims abstract description 23
- 230000001737 promoting effect Effects 0.000 title claims description 3
- 238000009987 spinning Methods 0.000 claims abstract description 60
- 239000011550 stock solution Substances 0.000 claims abstract description 22
- 239000004753 textile Substances 0.000 claims abstract description 12
- 229920000858 Cyclodextrin Polymers 0.000 claims description 64
- NWUYHJFMYQTDRP-UHFFFAOYSA-N 1,2-bis(ethenyl)benzene;1-ethenyl-2-ethylbenzene;styrene Chemical compound C=CC1=CC=CC=C1.CCC1=CC=CC=C1C=C.C=CC1=CC=CC=C1C=C NWUYHJFMYQTDRP-UHFFFAOYSA-N 0.000 claims description 39
- 239000003456 ion exchange resin Substances 0.000 claims description 39
- 229920003303 ion-exchange polymer Polymers 0.000 claims description 39
- HFHDHCJBZVLPGP-UHFFFAOYSA-N schardinger α-dextrin Chemical compound O1C(C(C2O)O)C(CO)OC2OC(C(C2O)O)C(CO)OC2OC(C(C2O)O)C(CO)OC2OC(C(O)C2O)C(CO)OC2OC(C(C2O)O)C(CO)OC2OC2C(O)C(O)C1OC2CO HFHDHCJBZVLPGP-UHFFFAOYSA-N 0.000 claims description 32
- 239000002002 slurry Substances 0.000 claims description 29
- 239000002608 ionic liquid Substances 0.000 claims description 28
- 239000000243 solution Substances 0.000 claims description 28
- 239000000843 powder Substances 0.000 claims description 25
- 229910052613 tourmaline Inorganic materials 0.000 claims description 25
- 239000011032 tourmaline Substances 0.000 claims description 25
- 229940070527 tourmaline Drugs 0.000 claims description 25
- 239000003921 oil Substances 0.000 claims description 21
- 229920000742 Cotton Polymers 0.000 claims description 20
- 239000002304 perfume Substances 0.000 claims description 20
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 20
- 238000003756 stirring Methods 0.000 claims description 18
- 229920001450 Alpha-Cyclodextrin Polymers 0.000 claims description 16
- 239000001116 FEMA 4028 Substances 0.000 claims description 16
- HFHDHCJBZVLPGP-RWMJIURBSA-N alpha-cyclodextrin Chemical compound OC[C@H]([C@H]([C@@H]([C@H]1O)O)O[C@H]2O[C@@H]([C@@H](O[C@H]3O[C@H](CO)[C@H]([C@@H]([C@H]3O)O)O[C@H]3O[C@H](CO)[C@H]([C@@H]([C@H]3O)O)O[C@H]3O[C@H](CO)[C@H]([C@@H]([C@H]3O)O)O3)[C@H](O)[C@H]2O)CO)O[C@@H]1O[C@H]1[C@H](O)[C@@H](O)[C@@H]3O[C@@H]1CO HFHDHCJBZVLPGP-RWMJIURBSA-N 0.000 claims description 16
- 229940043377 alpha-cyclodextrin Drugs 0.000 claims description 16
- WHGYBXFWUBPSRW-FOUAGVGXSA-N beta-cyclodextrin Chemical compound OC[C@H]([C@H]([C@@H]([C@H]1O)O)O[C@H]2O[C@@H]([C@@H](O[C@H]3O[C@H](CO)[C@H]([C@@H]([C@H]3O)O)O[C@H]3O[C@H](CO)[C@H]([C@@H]([C@H]3O)O)O[C@H]3O[C@H](CO)[C@H]([C@@H]([C@H]3O)O)O[C@H]3O[C@H](CO)[C@H]([C@@H]([C@H]3O)O)O3)[C@H](O)[C@H]2O)CO)O[C@@H]1O[C@H]1[C@H](O)[C@@H](O)[C@@H]3O[C@@H]1CO WHGYBXFWUBPSRW-FOUAGVGXSA-N 0.000 claims description 16
- 235000011175 beta-cyclodextrine Nutrition 0.000 claims description 16
- 229960004853 betadex Drugs 0.000 claims description 16
- 239000000203 mixture Substances 0.000 claims description 15
- 229920001285 xanthan gum Polymers 0.000 claims description 15
- 239000000230 xanthan gum Substances 0.000 claims description 15
- 229940082509 xanthan gum Drugs 0.000 claims description 15
- 235000010493 xanthan gum Nutrition 0.000 claims description 15
- SIWVGXQOXWGJCI-UHFFFAOYSA-N 1,2-bis(ethenyl)benzene;2-ethenylbenzenesulfonic acid Chemical compound C=CC1=CC=CC=C1C=C.OS(=O)(=O)C1=CC=CC=C1C=C SIWVGXQOXWGJCI-UHFFFAOYSA-N 0.000 claims description 14
- GDSRMADSINPKSL-HSEONFRVSA-N gamma-cyclodextrin Chemical compound OC[C@H]([C@H]([C@@H]([C@H]1O)O)O[C@H]2O[C@@H]([C@@H](O[C@H]3O[C@H](CO)[C@H]([C@@H]([C@H]3O)O)O[C@H]3O[C@H](CO)[C@H]([C@@H]([C@H]3O)O)O[C@H]3O[C@H](CO)[C@H]([C@@H]([C@H]3O)O)O[C@H]3O[C@H](CO)[C@H]([C@@H]([C@H]3O)O)O[C@H]3O[C@H](CO)[C@H]([C@@H]([C@H]3O)O)O3)[C@H](O)[C@H]2O)CO)O[C@@H]1O[C@H]1[C@H](O)[C@@H](O)[C@@H]3O[C@@H]1CO GDSRMADSINPKSL-HSEONFRVSA-N 0.000 claims description 13
- 229940080345 gamma-cyclodextrin Drugs 0.000 claims description 13
- 238000001816 cooling Methods 0.000 claims description 12
- 238000002156 mixing Methods 0.000 claims description 12
- 239000002245 particle Substances 0.000 claims description 10
- MDICIVRGHCTEQJ-UHFFFAOYSA-N 1-methyl-1,2-dihydropyridin-1-ium iodide Chemical compound [I-].C[NH+]1CC=CC=C1 MDICIVRGHCTEQJ-UHFFFAOYSA-N 0.000 claims description 8
- 238000002166 wet spinning Methods 0.000 claims description 8
- 230000029087 digestion Effects 0.000 claims description 6
- 238000010438 heat treatment Methods 0.000 claims description 6
- 238000000034 method Methods 0.000 claims description 6
- 239000004744 fabric Substances 0.000 claims description 5
- 230000008569 process Effects 0.000 claims description 5
- 239000011261 inert gas Substances 0.000 claims description 4
- 239000002537 cosmetic Substances 0.000 claims description 3
- 150000001545 azulenes Chemical class 0.000 claims 5
- 230000000147 hypnotic effect Effects 0.000 claims 2
- 230000000694 effects Effects 0.000 abstract description 13
- 239000002657 fibrous material Substances 0.000 abstract description 8
- 230000002401 inhibitory effect Effects 0.000 abstract description 7
- 241000894006 Bacteria Species 0.000 abstract description 6
- 206010061218 Inflammation Diseases 0.000 abstract description 6
- 230000003467 diminishing effect Effects 0.000 abstract description 6
- 230000004054 inflammatory process Effects 0.000 abstract description 6
- 210000005036 nerve Anatomy 0.000 abstract description 6
- 210000004911 serous fluid Anatomy 0.000 abstract 1
- 230000000052 comparative effect Effects 0.000 description 7
- 238000012360 testing method Methods 0.000 description 7
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 6
- 240000007019 Oxalis corniculata Species 0.000 description 5
- 229910052500 inorganic mineral Inorganic materials 0.000 description 5
- 239000011707 mineral Substances 0.000 description 5
- 239000012153 distilled water Substances 0.000 description 4
- 238000001035 drying Methods 0.000 description 4
- 238000012545 processing Methods 0.000 description 4
- 238000005406 washing Methods 0.000 description 4
- 229910052786 argon Inorganic materials 0.000 description 3
- 229940097362 cyclodextrins Drugs 0.000 description 3
- 238000011161 development Methods 0.000 description 3
- 230000036541 health Effects 0.000 description 3
- -1 1-butyl-3-methylpyridine iodide salt Chemical compound 0.000 description 2
- 241000196324 Embryophyta Species 0.000 description 2
- JUJWROOIHBZHMG-UHFFFAOYSA-N Pyridine Chemical compound C1=CC=NC=C1 JUJWROOIHBZHMG-UHFFFAOYSA-N 0.000 description 2
- 230000009471 action Effects 0.000 description 2
- 230000000844 anti-bacterial effect Effects 0.000 description 2
- 239000011248 coating agent Substances 0.000 description 2
- 238000000576 coating method Methods 0.000 description 2
- 125000002791 glucosyl group Chemical group C1([C@H](O)[C@@H](O)[C@H](O)[C@H](O1)CO)* 0.000 description 2
- 239000001307 helium Substances 0.000 description 2
- 229910052734 helium Inorganic materials 0.000 description 2
- SWQJXJOGLNCZEY-UHFFFAOYSA-N helium atom Chemical compound [He] SWQJXJOGLNCZEY-UHFFFAOYSA-N 0.000 description 2
- 150000002500 ions Chemical class 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 239000011148 porous material Substances 0.000 description 2
- 241000208838 Asteraceae Species 0.000 description 1
- 241000178280 Aureococcus Species 0.000 description 1
- 241000588724 Escherichia coli Species 0.000 description 1
- 229910006069 SO3H Inorganic materials 0.000 description 1
- 235000009499 Vanilla fragrans Nutrition 0.000 description 1
- 244000263375 Vanilla tahitensis Species 0.000 description 1
- 235000012036 Vanilla tahitensis Nutrition 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- 239000010692 aromatic oil Substances 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 150000004292 cyclic ethers Chemical class 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 229930003935 flavonoid Natural products 0.000 description 1
- 150000002215 flavonoids Chemical class 0.000 description 1
- 235000017173 flavonoids Nutrition 0.000 description 1
- 239000003205 fragrance Substances 0.000 description 1
- 230000002538 fungal effect Effects 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- 239000011630 iodine Substances 0.000 description 1
- 229910052740 iodine Inorganic materials 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 229910052754 neon Inorganic materials 0.000 description 1
- GKAOGPIIYCISHV-UHFFFAOYSA-N neon atom Chemical compound [Ne] GKAOGPIIYCISHV-UHFFFAOYSA-N 0.000 description 1
- 239000004745 nonwoven fabric Substances 0.000 description 1
- UMJSCPRVCHMLSP-UHFFFAOYSA-N pyridine Natural products COC1=CC=CN=C1 UMJSCPRVCHMLSP-UHFFFAOYSA-N 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 235000013599 spices Nutrition 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 125000001424 substituent group Chemical group 0.000 description 1
- 230000002195 synergetic effect Effects 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- 239000002759 woven fabric Substances 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F2/00—Monocomponent artificial filaments or the like of cellulose or cellulose derivatives; Manufacture thereof
- D01F2/02—Monocomponent artificial filaments or the like of cellulose or cellulose derivatives; Manufacture thereof from solutions of cellulose in acids, bases or salts
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F1/00—General methods for the manufacture of artificial filaments or the like
- D01F1/02—Addition of substances to the spinning solution or to the melt
- D01F1/10—Other agents for modifying properties
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F1/00—General methods for the manufacture of artificial filaments or the like
- D01F1/02—Addition of substances to the spinning solution or to the melt
- D01F1/10—Other agents for modifying properties
- D01F1/103—Agents inhibiting growth of microorganisms
Landscapes
- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Textile Engineering (AREA)
- Manufacturing & Machinery (AREA)
- Cosmetics (AREA)
- Artificial Filaments (AREA)
Abstract
The invention discloses a chamomile fiber containing blue fragrant oil azulene and capable of improving sleep and beautifying and a preparation method thereof, wherein the chamomile fiber comprises chamomile serous fluid and spinning stock solution; according to the weight portion, the chamomile size is 5-15 portions, and the spinning stock solution is 85-95 portions. The chamomile is applied to the fiber material, so that the fiber has certain effects of soothing the nerves, helping sleep, beautifying the skin, protecting the skin, diminishing inflammation and inhibiting bacteria, and the fiber material has higher application value. The textile prepared from the chamomile fiber has the characteristics of soft texture, wear resistance, difficulty in pilling and the like, and also has the effects of soothing nerves, helping sleep, beautifying, protecting skin, diminishing inflammation and inhibiting bacteria.
Description
Technical Field
The invention relates to the technical field of fibers and textiles, in particular to a sleeping and beautifying chamomile fiber containing blue fragrant oil azulene and a preparation method thereof.
Background
With the rapid development of scientific technology in China, the market consumption trend of consumers on textile products is gradually developing towards health care, more and more attention is paid to pursuing high-quality life, the market is opened for novel health care fibers, the fibers can be rapidly developed in China, different health care fibers are produced at once, different functions are shown, and with continuous updating and perfecting of production technology, fiber functions are continuously improved, developed products have larger development space and are favored by consumers.
Chamomile is a vanilla plant, also called chamomile, is a chamomile of the family Compositae, is an annual or perennial herb, has the fragrance of the whole herb, contains volatile aromatic oil, and is a spice plant with great development value; the chamomile contains cyclic ethers, flavonoids and total volatile oil, and has different inhibiting effects on fungal growth. The chamomile is applied to the fiber material, so that the fiber has certain effects of soothing the nerves, helping sleep, beautifying the skin, diminishing inflammation and inhibiting bacteria, and the fiber material has higher application value.
At present, chamomile essential oil is mainly applied to cosmetics or skin care products to achieve the effects of beautifying and protecting the skin. However, it is not uncommon to combine chamomile with fibers to make textile products, mainly because chamomile has a weak binding force with fibers.
Disclosure of Invention
In order to solve the problems, the invention provides a sleeping beauty chamomile fiber containing blue perfume oil azulene, which comprises chamomile slurry and spinning stock solution.
As a preferable technical scheme, the chamomile size is 5-15 parts by weight, and the spinning solution is 85-95 parts by weight.
As a preferable technical scheme, the chamomile slurry is prepared from the following components in percentage by weight: 20-40% of chamomile essential oil, 10-15% of cyclodextrin, 5-8% of xanthan gum, 5-10% of ion exchange resin, 3-5% of tourmaline powder and the balance of water.
As a preferable technical scheme, the cyclodextrin is a mixture of alpha cyclodextrin, beta cyclodextrin and gamma cyclodextrin, and the mass ratio of the alpha cyclodextrin to the beta cyclodextrin is 0.5: 1-2: 0.5 to 0.8.
As a preferable technical scheme, the particle size of the tourmaline powder is 10000-13000 meshes.
As a preferred technical scheme, the ion exchange resin is a mixture of Amberlyst 15 ion exchange resin and AMBERJET 1200H ion exchange resin, and the mass ratio of the Amberlyst 15 ion exchange resin to the AMBERJET 1200H ion exchange resin is 1: 0.3 to 0.6.
As a preferable technical scheme, the spinning solution comprises color cotton fiber and ionic liquid, and the weight ratio of the color cotton fiber to the ionic liquid is 60-70: 30-40.
In a preferred embodiment, the ionic liquid is 1-methylpyridine iodide.
The second aspect of the invention also provides a preparation method of the sleeping and beautifying chamomile fiber containing the blue perfume oil azulene, which comprises the following steps:
s1, preparation of chamomile slurry: adding cyclodextrin and water into a container, heating to 60-70 deg.C, and stirring to dissolve; cooling to normal temperature, adding chamomile essential oil, xanthan gum, ion exchange resin and tourmaline powder, and stirring at room temperature for 2-5 hours to obtain chamomile slurry;
s2, preparation of spinning solution: adding colored cotton fiber and ionic liquid into a high-pressure digestion tank, introducing inert gas for 25-40 minutes, reacting for 8-12 hours at 80-120 ℃, and then cooling to room temperature to obtain spinning stock solution;
s3, mixing: and (3) stirring and mixing the chamomile slurry and the spinning stock solution for 0.5-1 h to obtain a mixed spinning solution, and then preparing the chamomile fiber according to a wet spinning process.
The third aspect of the invention also provides application of the chamomile fiber containing the blue perfume oil azulene and capable of improving sleep and beautifying, and the chamomile fiber can be applied to the field of textile fabrics.
Has the advantages that:
1. the chamomile is applied to the fiber material, so that the fiber has certain effects of soothing the nerves, helping sleep, beautifying the skin, protecting the skin, diminishing inflammation and inhibiting bacteria, and the fiber material has higher application value.
2. According to the invention, the cyclodextrin is selected from a mixture of alpha cyclodextrin, beta cyclodextrin and gamma cyclodextrin, and the cyclodextrins of three different glucose units are mixed together, so that the coating effect of the cyclodextrin on chamomile essential oil is enhanced, and the effect is more durable.
3. The addition of tourmaline powder can not only make the chamomile fiber have the function of continuously releasing negative ions, but also act together with chamomile to enhance the sleep-aiding effect and improve the wear resistance of the fabric.
4. The use of the ion exchange resin enhances the toughness of the chamomile fiber, so that the chamomile fiber has excellent mechanical properties.
5. The textile prepared from the chamomile fiber has the characteristics of soft texture, wear resistance, difficulty in pilling and the like, and also has the effects of soothing nerves, helping sleep, beautifying, protecting skin, diminishing inflammation and inhibiting bacteria.
Detailed Description
The disclosure may be understood more readily by reference to the following detailed description of preferred embodiments of the invention and the examples included therein. Unless defined otherwise, all technical and scientific terms used herein have the same meaning as commonly understood by one of ordinary skill in the art to which this invention belongs. In case of conflict, the present specification, including definitions, will control.
In order to solve the problems, the invention provides a sleeping beauty chamomile fiber containing blue perfume oil azulene, which comprises chamomile slurry and spinning stock solution.
In some preferred embodiments, the chamomile slurry is 5 to 15 parts by weight and the spin dope is 85 to 95 parts by weight.
In some preferred embodiments, the chamomile slurry consists of, by weight: 20-40% of chamomile essential oil, 10-15% of cyclodextrin, 5-8% of xanthan gum, 5-10% of ion exchange resin, 3-5% of tourmaline powder and the balance of water.
In the invention, the chamomile is applied to the fiber material, so that the fiber has certain effects of soothing the nerves, helping sleep, beautifying the skin, protecting the skin, diminishing inflammation and inhibiting bacteria, and the fiber material has higher application value. Generally speaking, the functional material and the fiber have weak bonding force, so that the action effect is weakened, and in the system, the functional material and the spinning solution can be well combined together due to the combined action of the ion exchange resin and the ionic liquid; in addition, due to the presence of cyclodextrin and xanthan gum, the chamomile essential oil can be coated, so that the effect is more durable.
The chamomile essential oil used in the embodiment of the invention is obtained in the market and can be purchased from Shenzhen austin trade Limited company, and the product category is Roman chamomile;
in some preferred embodiments, the cyclodextrin is a mixture of α -cyclodextrin, β -cyclodextrin and γ -cyclodextrin, and the mass ratio of the three is 0.5: 1-2: 0.5 to 0.8. According to the invention, the cyclodextrin is selected from a mixture of alpha cyclodextrin, beta cyclodextrin and gamma cyclodextrin, the cyclodextrins of three different glucose units are mixed together, so that the coating effect of the cyclodextrin on chamomile essential oil is enhanced, and in the system, due to the existence of xanthan gum, the influence of strong acid ion exchange resin on the cyclodextrin is reduced, so that the cyclodextrin can stably react with the chamomile essential oil; in addition, the mass ratio of the three is selected from 0.5: 1-2: 0.5-0.8, because the synergistic effect of the three cyclodextrins in the range can reach the best.
The alpha cyclodextrin, the beta cyclodextrin and the gamma cyclodextrin can be obtained from markets, such as all the alpha cyclodextrin, the beta cyclodextrin and the gamma cyclodextrin can be purchased from Jiangsu Fengyuan biotechnology limited company;
the xanthan gum of the present invention is available from humanization products of Henan Xin, Inc.;
in some preferred embodiments, the particle size of the tourmaline powder is 10000 to 13000 meshes. The invention has the advantages that tourmaline powder is added into chamomile slurry, on one hand, the prepared chamomile fiber has the function of releasing negative ions and has a beneficial effect on a human body when being applied to textiles, on the other hand, although the color cotton fiber is soft in texture and the woven fabric is elastic, the spinning quality is poor, and the invention finds that when a certain amount of tourmaline powder is added into the slurry, the wear resistance of the fabric can be improved, and the spinning quality can also be improved. The reason why the particle size of the tourmaline powder is selected to be 10000-13000 meshes is that the inventor finds that when the particle size is less than 10000 meshes, the compatibility in a system is poor, and when the particle size is more than 13000 meshes, the wear resistance of a textile woven by the fiber is reduced.
The tourmaline powder is purchased from mineral processing factories of the Hualian union in Lingshou county;
in some preferred embodiments, the ion exchange resin is a mixture of Amberlyst 15 ion exchange resin and AMBERJET 1200H ion exchange resin in a mass ratio of 1: 0.3 to 0.6. The ion exchange resin is a mixture of Amberlyst 15 ion exchange resin and AMBERJET 1200H ion exchange resin, so that the mechanical property of the chamomile fiber is improved, and the woven textile has better elasticity and is not easy to ball; the reason is that the mixed ion exchange resin has better pore structure and large specific surface area, so that tourmaline powder can be better adsorbed on the surface and in pore channels and is not easy to fall off; in addition, in the system, the spinning stock solution contains the ionic liquid, the prepared chamomile slurry contains the mixed ion exchange resin, the mixed ion exchange resin has strong acidity, an acidic site can be used as a substituent, and the molecular skeleton of the 1-butyl-3-methylpyridine iodide salt is alkaline due to pyridine, so that the mixed ion exchange resin and the ionic liquid can be stably combined together, and the problem that the binding force of chamomile essential oil and colored cotton fibers is weak is solved.
The Amberlyst 15 ion exchange resin is purchased from Shanghai Kay chemical company Limited, and has a product number of: 523532, respectively; the AMBERJET 1200H ion exchange resin is purchased from Shanghai Kay chemical Co., Ltd, and has the model number: AMBERJET 1200H;
in some preferred embodiments, the spinning dope comprises colored cotton fiber and ionic liquid in a weight ratio of 60 to 70: 30-40.
The colored cotton fibers of the invention are purchased from Shaoxing Korotko Tengtong textile Co., Ltd;
in some preferred embodiments, the ionic liquid is 1-methylpyridine iodide (CAS number: 930-73-4). The ionic liquid in the present invention is selected from 1-methylpyridine iodide because the ion exchange resin in the present system contains-SO3H group, hydroxyl group contained in cyclodextrin, ion exchange resin and cyclodextrin, and H2A net structure can be formed between the O and the N-acetyl-D-methyl pyridine iodine salt in a hydrogen bond mode, and then a pseudo-net structure is formed by the O and the 1-butyl-3-methylpyridine iodine salt, so that the prepared chamomile fiber has stronger mechanical property.
The second aspect of the invention also provides a preparation method of the sleeping and beautifying chamomile fiber containing the blue perfume oil azulene, which comprises the following steps:
s1, preparation of chamomile slurry: adding cyclodextrin and water into a container, heating to 60-70 deg.C, and stirring to dissolve; cooling to normal temperature, adding chamomile essential oil, xanthan gum, ion exchange resin and tourmaline powder, and stirring at room temperature for 2-5 hours to obtain chamomile slurry;
s2, preparation of spinning solution: adding colored cotton fiber and ionic liquid into a high-pressure digestion tank, introducing inert gas for 25-40 minutes, reacting for 8-12 hours at 80-120 ℃, and then cooling to room temperature to obtain spinning stock solution;
s3, mixing: and (3) stirring and mixing the chamomile slurry and the spinning stock solution for 0.5-1 h to obtain a mixed spinning solution, and then preparing the chamomile fiber according to a wet spinning process.
The inert gas is selected from helium, neon and argon.
The wet spinning process is a conventional preparation process and comprises the following specific steps: adding the mixed spinning solution into an injector of a wet spinning machine, controlling the spinning speed to be 1.5mL/h by using a flow pump, spinning the spinning solution into distilled water at 60 ℃ under the conditions of 0.2MPa pressure and 115 ℃, naturally solidifying for 30s, and finally washing, oiling and drying to obtain the chamomile fiber.
The third aspect of the invention also provides application of the chamomile fiber containing the blue perfume oil azulene and capable of improving sleep and beautifying, and the chamomile fiber can be applied to the field of textile fabrics.
Examples
The technical solution of the present invention is described in detail by the following examples, but the scope of the present invention is not limited to the examples. Unless otherwise specified, all the raw materials in the present invention are commercially available.
Example 1
Embodiment 1 provides a sleeping and beautifying chamomile fiber containing azulene of blue perfume oil, which comprises 5 parts by weight of chamomile pulp and 95 parts by weight of spinning stock solution.
The chamomile pulp comprises the following components in percentage by weight: 20% of chamomile essential oil, 10% of cyclodextrin, 5% of xanthan gum, 5% of ion exchange resin, 3% of tourmaline powder and the balance of water.
The cyclodextrin is a mixture of alpha cyclodextrin, beta cyclodextrin and gamma cyclodextrin, and the mass ratio of the alpha cyclodextrin to the beta cyclodextrin to the gamma cyclodextrin is 0.5: 1: 0.5 (all purchased from Jiangsu Fengyuan biotechnology limited).
The particle size of the tourmaline powder is 10000 meshes (purchased from mineral processing factory of Hua union in Lingshou county, cargo number: 8955).
The ion exchange resin is a mixture of Amberlyst 15 ion exchange resin (purchased from Shanghai Kay chemical Co., Ltd., product number: 523532) and AMBERJET 1200H ion exchange resin (purchased from Shanghai Kay chemical Co., Ltd., product number: AMBERJET 1200H), and the mass ratio of the Amberlyst 15 ion exchange resin to the AMBERJET 1200H is 1: 0.3.
the spinning solution comprises colored cotton fibers and ionic liquid, and the weight ratio of the colored cotton fibers to the ionic liquid is 60: 40.
The ionic liquid is 1-methylpyridine iodide salt.
The embodiment also provides a preparation method of the sleeping beauty chamomile fiber containing the blue perfume oil azulene, which comprises the following steps:
s1, preparation of chamomile slurry: adding the cyclodextrin and the water in the weight percentage into a container, heating to 60 ℃, and stirring to dissolve the cyclodextrin and the water; cooling to normal temperature, adding the chamomile essential oil, the xanthan gum, the ion exchange resin and the tourmaline powder in the weight percentage, and stirring for 2 hours at room temperature to obtain chamomile slurry;
s2, preparation of spinning solution: adding the colored cotton fiber and the ionic liquid into a high-pressure digestion tank according to the weight ratio, introducing helium for 25 minutes, reacting for 8 hours at 80 ℃, and then cooling to room temperature to obtain spinning stock solution;
s3, mixing: and (2) stirring and mixing the chamomile slurry and the spinning stock solution for 0.5h to obtain a mixed spinning solution, adding the mixed spinning solution into an injector of a wet spinning machine, controlling the spinning speed to be 1.5mL/h by using a flow pump, spinning the spinning solution into distilled water at 60 ℃ under the conditions of 0.2MPa pressure and 115 ℃, naturally solidifying for 30s, and finally washing, oiling and drying to obtain the chamomile fiber.
Example 2
Embodiment 2 provides a sleeping and beautifying chamomile fiber containing azulene of blue perfume oil, which comprises 15 parts of chamomile pulp and 85 parts of spinning stock solution by weight.
The chamomile pulp comprises the following components in percentage by weight: 40% of chamomile essential oil, 15% of cyclodextrin, 8% of xanthan gum, 10% of ion exchange resin, 5% of tourmaline powder and the balance of water.
The cyclodextrin is a mixture of alpha cyclodextrin, beta cyclodextrin and gamma cyclodextrin, and the mass ratio of the alpha cyclodextrin to the beta cyclodextrin to the gamma cyclodextrin is 0.5: 2: 0.8 (all purchased from Jiangsu Fengyuan biotechnology, Inc.).
The particle size of the tourmaline powder is 13000 meshes (purchased from mineral processing factory of Hua Union of Lingshou prefecture, custom).
The ion exchange resin is a mixture of Amberlyst 15 ion exchange resin (purchased from Shanghai Kay chemical Co., Ltd., product number: 523532) and AMBERJET 1200H ion exchange resin (purchased from Shanghai Kay chemical Co., Ltd., product number: AMBERJET 1200H), and the mass ratio of the Amberlyst 15 ion exchange resin to the AMBERJET 1200H is 1: 0.6.
the spinning solution comprises colored cotton fibers and ionic liquid, and the weight ratio of the colored cotton fibers to the ionic liquid is 70: 30.
The ionic liquid is 1-methylpyridine iodide salt.
The embodiment also provides a preparation method of the sleeping beauty chamomile fiber containing the blue perfume oil azulene, which comprises the following steps:
s1, preparation of chamomile slurry: adding the cyclodextrin and the water in the weight percentage into a container, heating to 70 ℃, and stirring to dissolve the cyclodextrin and the water; cooling to normal temperature, adding the chamomile essential oil, the xanthan gum, the ion exchange resin and the tourmaline powder in the weight percentage, and stirring for 5 hours at room temperature to obtain chamomile slurry;
s2, preparation of spinning solution: adding the colored cotton fiber and the ionic liquid into a high-pressure digestion tank according to the weight ratio, introducing argon for 40 minutes, reacting for 12 hours at 120 ℃, and then cooling to room temperature to obtain spinning stock solution;
s3, mixing: and (2) stirring and mixing the chamomile slurry and the spinning stock solution for 1h to obtain a mixed spinning solution, adding the mixed spinning solution into an injector of a wet spinning machine, controlling the spinning speed to be 1.5mL/h by using a flow pump, spinning the spinning solution into distilled water at 60 ℃ under the conditions of 0.2MPa pressure and 115 ℃, naturally solidifying for 30s, and finally washing, oiling and drying to obtain the chamomile fiber.
Example 3
Embodiment 3 provides a sleeping and beautifying chamomile fiber containing azulene of blue perfume oil, which comprises 10 parts by weight of chamomile pulp and 90 parts by weight of spinning stock solution.
The chamomile pulp comprises the following components in percentage by weight: 30% of chamomile essential oil, 10% of cyclodextrin, 6% of xanthan gum, 7% of ion exchange resin, 4% of tourmaline powder and the balance of water.
The cyclodextrin is a mixture of alpha cyclodextrin, beta cyclodextrin and gamma cyclodextrin, and the mass ratio of the alpha cyclodextrin to the beta cyclodextrin to the gamma cyclodextrin is 0.5: 1.5: 0.6 (all purchased from Jiangsu Fengyuan biotechnology limited).
The particle size of the tourmaline powder is 12000 meshes (purchased from mineral processing factory of Hua union in Lingshou county, custom).
The ion exchange resin is a mixture of Amberlyst 15 ion exchange resin (purchased from Shanghai Kay chemical Co., Ltd., product number: 523532) and AMBERJET 1200H ion exchange resin (purchased from Shanghai Kay chemical Co., Ltd., product number: AMBERJET 1200H), and the mass ratio of the Amberlyst 15 ion exchange resin to the AMBERJET 1200H is 1: 0.4.
the spinning solution comprises colored cotton fibers and ionic liquid, and the weight ratio of the colored cotton fibers to the ionic liquid is 65: 35.
The ionic liquid is 1-methylpyridine iodide salt.
The embodiment also provides a preparation method of the sleeping beauty chamomile fiber containing the blue perfume oil azulene, which comprises the following steps:
s1, preparation of chamomile slurry: adding the cyclodextrin and the water in percentage by weight into a container, heating to 65 ℃, and stirring to dissolve the cyclodextrin and the water; cooling to normal temperature, adding the chamomile essential oil, the xanthan gum, the ion exchange resin and the tourmaline powder in the weight percentage, and stirring for 4 hours at room temperature to obtain chamomile slurry;
s2, preparation of spinning solution: adding the colored cotton fiber and the ionic liquid into a high-pressure digestion tank according to the weight ratio, introducing argon for 35 minutes, reacting for 10 hours at 100 ℃, and then cooling to room temperature to obtain spinning stock solution;
s3, mixing: and (2) stirring and mixing the chamomile slurry and the spinning stock solution for 45min to obtain a mixed spinning solution, adding the mixed spinning solution into an injector of a wet spinning machine, controlling the spinning speed to be 1.5mL/h by using a flow pump, spinning the spinning solution into distilled water at 60 ℃ under the conditions of 0.2MPa pressure and 115 ℃, naturally solidifying for 30s, and finally washing, oiling and drying to obtain the chamomile fiber.
Comparative example 1
The cyclodextrin was changed to a single alpha cyclodextrin as in example 3;
comparative example 2
The cyclodextrin was changed to a single beta cyclodextrin as in example 3;
comparative example 3
The particle size of the tourmaline powder was changed to 1250 mesh (manufacturer: Shijiazhuang Hualang mineral products trade Co., Ltd.), and the rest was the same as in example 3;
comparative example 4
The ion exchange resin was changed to a single Amberlyst 15 ion exchange resin (manufactured by Shanghai Kaiyn chemical Co., Ltd., product number: 523532), and the rest was the same as in example 3;
comparative example 5
The ionic liquid 1-methylpyridine iodide salt was changed to water as in example 3;
performance testing
1. Respectively carrying out antibacterial test on the chamomile fibers obtained in the embodiments 1 to 3 and the comparative examples 1 to 5, and testing the antibacterial performance of the chamomile fibers according to the hygienic standard of GB15979-2002 disposable hygienic products by using an oscillating flask method, wherein the strains are escherichia coli and aureococcus aureum, and the results are shown in Table 1;
2. mechanical property tests are respectively carried out on the chamomile fibers prepared in the embodiments 1-3 and the comparative examples 1-5 of the invention, and the test method refers to GB/T-24218.3-2010 part 3 of the experimental method of textiles and non-woven fabrics: determination of breaking strength and breaking elongation, the strength performance of the test samples is determined by adopting a FAVIMAT-B0B0T2 full-automatic single fiber universal tester, the number of the test samples is not less than 30, the average value of the test is taken, and the result is shown in Table 1;
Claims (10)
1. a chamomile fiber containing blue fragrant oil azulene and capable of promoting sleep and beautifying features that the chamomile fiber contains chamomile slurry and spinning stock solution.
2. The sleeping and beautifying chamomile fiber containing the azulenes of the blue perfume oil according to claim 1, wherein the chamomile slurry comprises 5-15 parts by weight, and the spinning stock solution comprises 85-95 parts by weight.
3. The sleeping and beautifying chamomile fiber containing the blue perfume oil azulene according to the claim 1 or 2, characterized in that the chamomile slurry is prepared from the following components in percentage by weight: 20-40% of chamomile essential oil, 10-15% of cyclodextrin, 5-8% of xanthan gum, 5-10% of ion exchange resin, 3-5% of tourmaline powder and the balance of water.
4. The sleeping and beautifying chamomile fiber containing the azulenes of blue perfume oil according to claim 3, wherein the cyclodextrin is a mixture of alpha cyclodextrin, beta cyclodextrin and gamma cyclodextrin, and the mass ratio of the alpha cyclodextrin to the beta cyclodextrin is 0.5: 1-2: 0.5 to 0.8.
5. The sleeping and beautifying chamomile fiber containing the azulenes of the blue perfume oil according to claim 3, wherein the particle size of the tourmaline powder is 10000-13000 meshes.
6. The sleeping and beautifying chamomile fiber containing the azulenes of the blue perfume oil according to claim 3, characterized in that the ion exchange resin is a mixture of Amberlyst 15 ion exchange resin and AMBERJET 1200H ion exchange resin, and the mass ratio of the Amberlyst 15 ion exchange resin to the AMBERJET 1200H ion exchange resin is 1: 0.3 to 0.6.
7. The sleeping and beautifying chamomile fiber containing the blue perfume oil azulene according to claim 1 or 2, characterized in that the spinning solution comprises color cotton fiber and ionic liquid, and the weight ratio of the color cotton fiber to the ionic liquid is 60-70: 30-40.
8. The sleeping and beautifying chamomile fiber containing the azulenes of blue perfume oils according to claim 7, characterized in that the ionic liquid is 1-methylpyridine iodide salt.
9. A process for the preparation of a hypnotic and cosmetic chamomile fiber containing blue oil azulene according to any one of claims 1 to 8, characterized in that it comprises the following steps:
s1, preparation of chamomile slurry: adding cyclodextrin and water into a container, heating to 60-70 deg.C, and stirring to dissolve; cooling to normal temperature, adding chamomile essential oil, xanthan gum, ion exchange resin and tourmaline powder, and stirring at room temperature for 2-5 hours to obtain chamomile slurry;
s2, preparation of spinning solution: adding colored cotton fiber and ionic liquid into a high-pressure digestion tank, introducing inert gas for 25-40 minutes, reacting for 8-12 hours at 80-120 ℃, and then cooling to room temperature to obtain spinning stock solution;
s3, mixing: and (3) stirring and mixing the chamomile slurry and the spinning stock solution for 0.5-1 h to obtain a mixed spinning solution, and then preparing the chamomile fiber according to a wet spinning process.
10. Use of a hypnotic and cosmetic chamomile fiber containing an azulene from a blue perfume oil according to any of claims 1 to 8, characterized in that the chamomile fiber can be used in the field of textile fabrics.
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Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102851992A (en) * | 2012-08-29 | 2013-01-02 | 昆山铁牛衬衫厂 | Fragrant fabric and its production method |
| CN106676670A (en) * | 2016-12-09 | 2017-05-17 | 天长市天龙泵阀成套设备厂 | Hyaluronic acid/silk fibroin nano-fibre and preparation method thereof |
| CN106929930A (en) * | 2015-12-31 | 2017-07-07 | 上海水星家用纺织品股份有限公司 | A kind of preparation method of the viscose rayon for loading chamomile essential oil |
| CN108950809A (en) * | 2018-08-20 | 2018-12-07 | 浙江理工大学 | A kind of fabric with environment-protecting health-care skin makeup complex function |
| CN109984950A (en) * | 2018-12-06 | 2019-07-09 | 上海益好纳米科技有限公司 | A series of disposable hypersorption type nanofiber functional masks and preparation method thereof |
| CN111621873A (en) * | 2020-07-08 | 2020-09-04 | 深圳千维生态纺织有限公司 | Hyaluronic acid fiber and preparation method and application thereof |
-
2020
- 2020-10-15 CN CN202011102527.7A patent/CN112226836A/en not_active Withdrawn
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102851992A (en) * | 2012-08-29 | 2013-01-02 | 昆山铁牛衬衫厂 | Fragrant fabric and its production method |
| CN106929930A (en) * | 2015-12-31 | 2017-07-07 | 上海水星家用纺织品股份有限公司 | A kind of preparation method of the viscose rayon for loading chamomile essential oil |
| CN106676670A (en) * | 2016-12-09 | 2017-05-17 | 天长市天龙泵阀成套设备厂 | Hyaluronic acid/silk fibroin nano-fibre and preparation method thereof |
| CN108950809A (en) * | 2018-08-20 | 2018-12-07 | 浙江理工大学 | A kind of fabric with environment-protecting health-care skin makeup complex function |
| CN109984950A (en) * | 2018-12-06 | 2019-07-09 | 上海益好纳米科技有限公司 | A series of disposable hypersorption type nanofiber functional masks and preparation method thereof |
| CN111621873A (en) * | 2020-07-08 | 2020-09-04 | 深圳千维生态纺织有限公司 | Hyaluronic acid fiber and preparation method and application thereof |
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Application publication date: 20210115 |