CN106675209A - Pigment pencil for ceramic underglaze painting and application method thereof - Google Patents

Abstract

The invention relates to a pigment pencil for ceramic under-glaze color painting and an application method thereof, wherein the pigment pencil for ceramic under-glaze color painting comprises a pencil holder and a pencil lead; the refill is prepared from the following materials in percentage by weight: 70-90% of ceramic high-temperature underglaze color pigment; 5-30% of paraffin and 2-8% of clay. The pigment pencil for ceramic under-glaze color painting of the invention is a pencil lead structure which is convenient for operation and is processed by traditional ceramic under-glaze color paint, improves the difficult-to-master mode of writing brush painting under-glaze color painting into the common mode of pencil painting in daily life, and enriches the material types and the expression modes of ceramic under-glaze color painting. The pigment pencil for ceramic under-glaze color painting is more convenient to use in ceramic foundation teaching, has wide popularization rate, is simple, convenient, smooth and clear in operation, is not easy to drop, has lasting stability, and realizes the conversion of the complicated operation process of dipping the pigment soft pen in the ceramic under-glaze color painting from the writing brush to the convenient operation process of the hard pen of the pigment pencil for ceramic under-glaze color painting.

Description

Pigment pencil for ceramic underglaze painting and application method thereof

technical field

The invention relates to the innovation of tools and materials used for ceramic underglaze painting, and belongs to the technical field of ceramic painting.

Background technique

Ceramics has a long history in China and has been the crystallization of the wisdom of the Chinese nation since ancient times. Ceramic underglaze painting, as an important part of the field of ceramic painting, has recorded human civilization in the long river of history. The traditional underglaze painting of ceramics uses soft pens such as brushes to draw corresponding pictures, and its artistic characteristics are closely related to the way of drawing. With the progress and development of society, and the continuous improvement of people's requirements for individual painting, the public's demand for ceramics is more artistic, diverse and innovative. Ceramic hard pen underglaze painting is an innovative ceramic decoration technique summed up through continuous exploration and practice in the process of ceramic art creation.

Due to the complicated operation steps of water-based materials and high technical requirements, the underglaze painting by the traditional brush method can no longer meet the diverse requirements of different levels of people for ceramic underglaze painting. After careful market research Many people hope that there will be a ceramic underglaze painting material that is easier to operate. Therefore, the pencil refill material has become the focus of our research and development because of its superior and convenient operation method. Pencil is a painting material that can be carried around and is easy to operate. Painters have more choices of expression methods, so that ceramic underglaze paintings can be presented in the form of pencil drawings.

Contents of the invention

The purpose of the present invention is to innovate the complicated operation process when using a traditional writing brush for ceramic underglaze painting, and to provide a ceramic hard pen for underglaze painting, which has the same shape as a pencil and whose pen core uses ceramic high-temperature underglaze pigments as the main component. paint pencils. Pigment pencils for ceramic underglaze painting can be used to hold the pen for writing or sketching. The tip of the pen is thin, which can express the painting object delicately. Pigment pencils for ceramic underglaze painting can allow more people who love ceramic art to participate, express the picture they want with this portable ceramic underglaze painting paint pencil, and keep their works for a long time after firing down.

In order to solve the problems of the technologies described above, the purpose of the present invention is achieved through the following technical solutions:

The pigment pencil for ceramic underglaze painting is composed of a pen holder and a pen core; the pen core is mainly composed of ceramic high-temperature underglaze color pigments.

The refill material and weight percentage of the pigment pencil for ceramic underglaze painting are as follows: 70-90% of ceramic high-temperature underglaze color pigment; 5-30% of paraffin wax and 2-8% of clay.

The lead material and weight percentage of the pigment pencil for ceramic underglaze painting are as follows: 80% of ceramic high-temperature underglaze color pigment; 15% of paraffin wax and 5% of clay.

The color classification and composition of the ceramic high-temperature underglaze color pigment and its weight percentage are:

The composition and weight percentage of peacock blue: 15-30% of aluminum oxide, 1-3% of magnesium oxide, 10-20% of barium oxide, 25-50% of chromium oxide, 15-35% of cobalt oxide;

The composition and weight percentage of sky blue: chromium oxide 30-50%, cobalt oxide 20-35%, nickel oxide 5-15%, iron oxide 15-30%;

Yellow ingredients and their weight percentages: silicon oxide 20-40%, sulfur oxide 5-15%, cadmium oxide 15-35%, zirconium oxide 30-50%;

Red ingredients and their weight percentages: silicon oxide 20-35%, selenium oxide 4-10%, sulfur oxide 15-30%, zirconium silicate 30-45%, cadmium oxide 4-8%;

Purple composition and its weight percentage: silicon oxide 13-30%, aluminum oxide 10-30%, sodium oxide 0.5-1.5%, zinc oxide 1-5%, zirconium oxide 20-30%, cadmium oxide 10-25%, Cobalt oxide 5-15%, selenium oxide 2-8%, sulfur oxide 1-5%;

Orange composition and weight percentage: silicon oxide 20-30%, zirconium oxide 25-45%, selenium oxide 4-8%, sulfur oxide 5-15%, cadmium oxide 10-30%;

Brown ingredients and their weight percentages: zinc oxide 28-45%, chromium oxide 25-35%, iron oxide 22-40%;

Grass green composition and its weight percentage: silicon oxide 30-40%, sodium oxide 0.5-1.5%, zirconium oxide 48-60%, praseodymium oxide 2-8%, vanadium oxide 1-5%;

The composition and weight percentage of cobalt blue: aluminum oxide 50-70%, zinc oxide 8-15%, cobalt oxide 20-40%;

Dark green composition and weight percentage: silicon oxide 28-37%, sodium oxide 0.2-0.8%, potassium oxide 0.2-0.8%, zirconium oxide 53-65%, praseodymium oxide 0.5-3%, vanadium oxide 2-6% ;

Black composition and weight percentage: chromium oxide 30-50%, cobalt oxide 20-40%, nickel oxide 5-15%, iron oxide 15-30%;

Light green components and their weight percentages: silicon oxide 25-40%, sodium oxide 0.2-0.8%, potassium oxide 0.2-0.8%, zirconium oxide 50-65%, praseodymium oxide 1-3%, vanadium oxide 2-7% .

Further, the color classification and composition of the ceramic high-temperature underglaze color pigment and its weight percentage are:

The composition and weight percentage of peacock blue: aluminum oxide 21.01%, magnesium oxide 1.67%, barium oxide 15.71%, chromium oxide 36.28%, cobalt oxide 25.33%;

The composition and weight percentage of sky blue: chromium oxide 40.17%, cobalt oxide 27.76%, nickel oxide 9.83%, iron oxide 22.24%;

Yellow ingredients and their weight percentages: silicon oxide 28.14%, sulfur oxide 7.67%, cadmium oxide 21.22%, zirconium oxide 42.97%;

Red composition and its weight percentage: silicon oxide 27.11%, selenium oxide 7.80%, sulfur oxide 20.28%, zirconium silicate 38.19%, cadmium oxide 6.62%;

Purple composition and its weight percentage: silicon oxide 17.36%, aluminum oxide 16.32%, sodium oxide 0.84%, zinc oxide 3.41%, zirconium oxide 26.18%, cadmium oxide 14.49%, cobalt oxide 10.27%, selenium oxide 6.72%, sulfur oxide 4.41%;

The composition and weight percentage of orange: silicon oxide 24.80%, zirconium oxide 39.30%, selenium oxide 6.60%, sulfur oxide 9.20%, cadmium oxide 20.10%;

Brown ingredients and their weight percentages: zinc oxide 39.17%, chromium oxide 32.49%, iron oxide 28.34%;

Grass green composition and weight percentage: silicon oxide 35.52%, sodium oxide 1.07%, zirconium oxide 56.17%, praseodymium oxide 5.21%, vanadium oxide 2.03%;

The composition and weight percentage of cobalt blue: aluminum oxide 60.31%, zinc oxide 11.26%, cobalt oxide 28.43%;

The composition and weight percentage of dark green: silicon oxide 33.98%, sodium oxide 0.57%, potassium oxide 0.48%, zirconium oxide 58.24%, praseodymium oxide 1.96%, vanadium oxide 4.77%;

Black composition and weight percentage: chromium oxide 40.17%, cobalt oxide 27.76%, nickel oxide 9.83%, iron oxide 22.24%;

Light green components and their weight percentages: silicon oxide 33.98%, sodium oxide 0.57%, potassium oxide 0.48%, zirconium oxide 58.24%, praseodymium oxide 1.96%, vanadium oxide 4.77%.

An application method of a pigment pencil for underglaze painting of ceramics. Writing, drawing and painting are performed on the surface of a dry or bisque ceramic body by using the pigment pencil for underglaze painting of ceramics. Through vivid and smooth line changes and rich and varied stroke changes, a unique hard pen underglaze painting style is formed.

Use the pigment pencil for ceramic underglaze painting to write, draw, and draw on the surface of the dry or bisque ceramic body. The tolerance temperature of the pigment pencil for ceramic underglaze painting is not lower than the glaze firing temperature. Firing production process.

Apply transparent glaze on the surface of the already painted green tire, and carry out high-temperature firing in the kiln at a firing temperature of 1200-1300°C. After firing, a colorful painting surface will be presented, so that pencil-style hard strokes can be painted on the surface. presented on ceramics.

By combining hard pen painting and soft pen painting, that is, on the basis of using the pigment pencil for ceramic underglaze painting to outline the main lines, and then filling in large areas with traditional soft brushes to enrich its layering , three-dimensional sense, forming the artistic effect of the fusion of various ceramic decoration techniques.

The pigment pencils for underglaze painting of ceramics according to the present invention are divided into 12 colors, and the pencils of the corresponding colors can be selected for detailed painting according to the needs of the picture when painting. Write, draw, paint. It can achieve rich layers, smooth lines, uniform color effect, and unique ceramic hard pen underglaze painting style.

The pigment pencil for ceramic underglaze painting of the present invention changes the cumbersomeness and inconvenience of traditional painting with a brush dipped in ceramic underglaze paint, and changes the original soft pen water-based material into a hard pen refill for ceramic underglaze painting The material is more suitable for beginners of pottery art and popular teaching of pottery art, so that learners of pottery underglaze painting techniques have more choices of pencil drawing.

Compared with the prior art, the present invention has the following beneficial effects:

(1) When the pigment pencil for ceramic underglaze painting is used for drawing, the strokes are uniform, easy to grasp, easy to deepen, easy to modify, rich in expressive force, low in cost, clean and hygienic, round and full in traces, and can distinguish color levels, which is better Expressing the relationship between light and dark space, the thickness can be adjusted, making artistic creation complete in one go;

(2) The application of the pigment pencil for ceramic underglaze painting to ceramic painting is realized by writing, drawing and drawing on the surface of a dry or bisque ceramic body with the pigment pencil for ceramic underglaze painting. Through vivid and smooth line changes and rich and varied stroke changes, a unique hard pen underglaze painting style is formed.

detailed description

The present invention will be described in further detail below: the present embodiment is implemented on the premise of the technical solution of the present invention, and detailed implementation is provided, but the protection scope of the present invention is not limited to the following examples.

The pigment pencil for ceramic underglaze painting is composed of a pen holder and a pen core; the pen core is mainly composed of ceramic high-temperature underglaze color pigments.

The material and weight percentage of the pen core of the pigment pencil for ceramic underglaze painting are as follows: 70-90% of ceramic high-temperature underglaze color pigment; 5-30% of paraffin wax and 2-8% of clay.

Further, the material and weight percentage of the refill of the pigment pencil for ceramic underglaze painting are as follows: 80% of ceramic high-temperature underglaze color pigment; 15% of paraffin wax and 5% of clay.

The ceramic high-temperature underglaze color pigment is artificially synthesized ceramic pigment or pigment.

The color classification and composition of the ceramic high-temperature underglaze color pigment and its weight percentage are:

The composition and weight percentage of peacock blue: 15-30% of aluminum oxide, 1-3% of magnesium oxide, 10-20% of barium oxide, 25-50% of chromium oxide, 15-35% of cobalt oxide;

The composition and weight percentage of sky blue: chromium oxide 30-50%, cobalt oxide 20-35%, nickel oxide 5-15%, iron oxide 15-30%;

Yellow ingredients and their weight percentages: silicon oxide 20-40%, sulfur oxide 5-15%, cadmium oxide 15-35%, zirconium oxide 30-50%;

Red ingredients and their weight percentages: silicon oxide 20-35%, selenium oxide 4-10%, sulfur oxide 15-30%, zirconium silicate 30-45%, cadmium oxide 4-8%;

Purple composition and its weight percentage: silicon oxide 13-30%, aluminum oxide 10-30%, sodium oxide 0.5-1.5%, zinc oxide 1-5%, zirconium oxide 20-30%, cadmium oxide 10-25%, Cobalt oxide 5-15%, selenium oxide 2-8%, sulfur oxide 1-5%;

Orange composition and weight percentage: silicon oxide 20-30%, zirconium oxide 25-45%, selenium oxide 4-8%, sulfur oxide 5-15%, cadmium oxide 10-30%;

Brown ingredients and their weight percentages: zinc oxide 28-45%, chromium oxide 25-35%, iron oxide 22-40%;

Grass green composition and its weight percentage: silicon oxide 30-40%, sodium oxide 0.5-1.5%, zirconium oxide 48-60%, praseodymium oxide 2-8%, vanadium oxide 1-5%;

The composition and weight percentage of cobalt blue: aluminum oxide 50-70%, zinc oxide 8-15%, cobalt oxide 20-40%;

Dark green composition and weight percentage: silicon oxide 28-37%, sodium oxide 0.2-0.8%, potassium oxide 0.2-0.8%, zirconium oxide 53-65%, praseodymium oxide 0.5-3%, vanadium oxide 2-6% ;

Black composition and weight percentage: chromium oxide 30-50%, cobalt oxide 20-40%, nickel oxide 5-15%, iron oxide 15-30%;

Light green components and their weight percentages: silicon oxide 25-40%, sodium oxide 0.2-0.8%, potassium oxide 0.2-0.8%, zirconium oxide 50-65%, praseodymium oxide 1-3%, vanadium oxide 2-7% .

Further, the color classification and composition of the ceramic high-temperature underglaze color pigment and its weight percentage are:

The composition and weight percentage of peacock blue: aluminum oxide 21.01%, magnesium oxide 1.67%, barium oxide 15.71%, chromium oxide 36.28%, cobalt oxide 25.33%;

The composition and weight percentage of sky blue: chromium oxide 40.17%, cobalt oxide 27.76%, nickel oxide 9.83%, iron oxide 22.24%;

Yellow ingredients and their weight percentages: silicon oxide 28.14%, sulfur oxide 7.67%, cadmium oxide 21.22%, zirconium oxide 42.97%;

Red composition and its weight percentage: silicon oxide 27.11%, selenium oxide 7.80%, sulfur oxide 20.28%, zirconium silicate 38.19%, cadmium oxide 6.62%;

Purple composition and its weight percentage: silicon oxide 17.36%, aluminum oxide 16.32%, sodium oxide 0.84%, zinc oxide 3.41%, zirconium oxide 26.18%, cadmium oxide 14.49%, cobalt oxide 10.27%, selenium oxide 6.72%, sulfur oxide 4.41%;

The composition and weight percentage of orange: silicon oxide 24.80%, zirconium oxide 39.30%, selenium oxide 6.60%, sulfur oxide 9.20%, cadmium oxide 20.10%;

Brown ingredients and their weight percentages: zinc oxide 39.17%, chromium oxide 32.49%, iron oxide 28.34%;

Grass green composition and weight percentage: silicon oxide 35.52%, sodium oxide 1.07%, zirconium oxide 56.17%, praseodymium oxide 5.21%, vanadium oxide 2.03%;

The composition and weight percentage of cobalt blue: aluminum oxide 60.31%, zinc oxide 11.26%, cobalt oxide 28.43%;

The composition and weight percentage of dark green: silicon oxide 33.98%, sodium oxide 0.57%, potassium oxide 0.48%, zirconium oxide 58.24%, praseodymium oxide 1.96%, vanadium oxide 4.77%;

Black composition and weight percentage: chromium oxide 40.17%, cobalt oxide 27.76%, nickel oxide 9.83%, iron oxide 22.24%;

Light green components and their weight percentages: silicon oxide 33.98%, sodium oxide 0.57%, potassium oxide 0.48%, zirconium oxide 58.24%, praseodymium oxide 1.96%, vanadium oxide 4.77%.

An application method of a pigment pencil for ceramic underglaze painting: use the pigment pencil for ceramic underglaze painting to perform underglaze painting on the surface of a dry or bisque ceramic body.

Use the pigment pencil for ceramic underglaze painting to write, draw, and draw on the surface of the dry or bisque ceramic body. The tolerance temperature of the pigment pencil for ceramic underglaze painting is not lower than the glaze firing temperature. Firing production process.

Apply transparent glaze on the surface of the already painted green tire, and carry out high-temperature firing in the kiln at a firing temperature of 1200-1300°C. After firing, a colorful painting surface will be presented, so that pencil-style hard strokes can be painted on the surface. presented on ceramics.

By combining hard pen painting and soft pen painting, that is, on the basis of using the pigment pencil for ceramic underglaze painting to outline the main lines, and then filling a large area with traditional soft brushes, the underglaze painting painting.

Example 1

Demonstrate the painting method in a step-by-step demonstration method of "starting line drawing→fine line drawing→laying out large tones→detailing details→drawing the background→adjusting effects→glazing→firing the kiln".

The carrier for color painting is selected from the fully dried ceramic body, and the picture style is set as underglaze color with black and white hard pen color painting surface pattern. The corresponding process is as follows:

(1) Clean the surface of the above-mentioned ceramic green body carrier that has been fully dried, and wipe the surface of the green body with a sponge dipped in water.

(2) Select the black ceramic underglaze painting pigment pencil required for the picture, draw the picture on the green body, first start the line draft and then refine the line draft; The form of the line deepens the corresponding position to achieve the effect of enriching the layering of the picture and increasing the artistry of the picture; the details are further described according to the needs, and the overall effect is adjusted after the background of the picture is perfected.

(3) Glaze the painted ceramic body, and cover the surface of the body with a layer of transparent glaze by blowing glaze with a glaze blower.

(4) Fired in a gas kiln to a high temperature of 1250°C. After cooling, open the kiln and take out the work. The black and white picture painted on the surface of the work is fully presented. The lines are clear and smooth, and the picture is rich in layers. It is a good ceramic glaze. A new form of representation has been added to the lower painted field.

Example 2

Demonstrate the painting method in a step-by-step demonstration method of "starting line drawing→fine line drawing→laying out large tones→color adjustment→detail drawing→drawing background→adjusting effect→glazing→firing the kiln".

The carrier for painting is selected from the ceramic body that has been bisque-fired at 750°C, and the picture style is set as the underglaze color of the picture pattern painted with colored hard pens. The corresponding procedures are as follows:

(1) Clean the surface of the ceramic green body after 750°C, and wipe the surface of the green body with a sponge dipped in water.

(2) Select the pigment pencil for color ceramic underglaze painting required by the picture, and draw the picture on the green body, first start the line draft and then refine the line draft; when laying large tones and color adjustments, you can according to the color requirements of the picture Use pigment pencils for ceramic underglaze painting of different colors to add color to the corresponding position in the form of sketching lines, so that different colors can be skillfully blended into the same picture, so as to achieve the effect of enriching the layering of the picture and increasing the artistry of the picture; the details can be adjusted according to the needs After further characterization, the overall effect is adjusted after perfecting the background of the picture.

(3) Glaze the painted ceramic body, and cover the surface of the body with a layer of transparent glaze by blowing glaze with a glaze blower.

(4) Fired in a gas kiln to a high temperature of 1250°C. After cooling, the kiln is opened to take out the work. The color picture painted on the surface of the work is fully presented. The lines are clear and smooth, and the picture is rich in layers. It is very good for ceramic underglaze painting. Field adds a new form of representation.

Example 3

Demonstrate the painting method in a step-by-step demonstration method of "starting line drawing→fine line drawing→soft pen coloring→color adjustment→detail drawing→drawing the background→adjusting the effect→glazing→firing the kiln".

The carrier for painting is selected from the ceramic body that has been bisque fired at 750°C, and the style of the picture is defined as underglaze color with color hard pen and soft pen painting combined with picture patterns. The corresponding procedures are as follows:

(1) Clean the surface of the ceramic green body after 750°C, and wipe the surface of the green body with a sponge dipped in water.

(2) Select the pigment pencil for color ceramic underglaze painting required by the picture, and draw the picture on the green body, first start the line draft and then refine the line draft; when laying the color with the soft pen, you can use a brush according to the color requirements of the picture The form of water-filling paint is added to the corresponding position, so that different colors are skillfully blended in the same picture, achieving the effect of increasing the layering of the picture and increasing the artistry of the picture; after adjusting the color effect, the details are further described according to the needs; perfect the background of the picture Then adjust the overall effect.

(3) Glaze the painted ceramic body, and cover the surface of the body with a layer of transparent glaze by blowing glaze with a glaze blower.

(4) Fired in a gas kiln to a high temperature of 1250°C. After cooling, the kiln is opened to take out the work. The color picture painted on the surface of the work is fully presented. The lines are clear and smooth, and the picture is rich in layers. It is very good for ceramic underglaze painting. Field adds a new form of representation.

The above are only preferred specific implementations of the present invention. These specific implementations are all based on different implementations under the overall concept of the present invention, and the scope of protection of the present invention is not limited thereto. Anyone familiar with the technical field Within the technical scope disclosed in the present invention, any changes or substitutions that can be easily conceived by a skilled person shall fall within the protection scope of the present invention.

Claims (10)

1. colored drawing pigment pencil under ceramic glaze, it is characterised in that：

Colored drawing pigment pencil is made up of penholder and pen core under the ceramic glaze；The pen core is made by color painting under ceramic high-temperature glaze It is main component.

2. colored drawing pigment pencil under ceramic glaze according to claim 1, it is characterised in that：

The material and its percentage by weight of the pen core of colored drawing pigment pencil are under the ceramic glaze：By ceramic high temperature underglaze colour face Material 70-90%；Paraffin 5-30% and clay 2-8% is constituted.

3. colored drawing pigment pencil under ceramic glaze according to claim 2, it is characterised in that：

The material and its percentage by weight of the pen core of colored drawing pigment pencil are under the ceramic glaze：By ceramic high temperature underglaze colour face Material 80%；Paraffin 15% and clay 5% are constituted.

4. colored drawing pigment pencil under ceramic glaze according to claim 3, it is characterised in that：

Color painting is artificial synthesized ceramic paint or colorant under the ceramic high-temperature glaze.

5. colored drawing pigment pencil under ceramic glaze according to claim 4, it is characterised in that：

The color classification and composition and its percentage by weight of color painting are under the ceramic high-temperature glaze：

The composition and its percentage by weight of peacock blue：Aluminum oxide 15-30%, magnesia 1-3%, barium monoxide 10-20%, oxidation Chromium 25-50%, cobalt oxide 15-35%；

Sapphire composition and its percentage by weight：Chromium oxide 30-50%, cobalt oxide 20-35%, nickel oxide 5-15%, oxidation Iron 15-30%；

The composition and its percentage by weight of yellow：Oxidation silicon 20-40%, sulfur oxide 5-15%, cadmium oxide 15-35%, zirconium oxide 30-50%；

Red composition and its percentage by weight：Oxidation silicon 20-35%, selenium oxide 4-10%, sulfur oxide 15-30%, silicon acid zirconium 30-45%, cadmium oxide 4-8%；

The composition and its percentage by weight of purple：Oxidation silicon 13-30%, aluminum oxide 10-30%, sodium oxide molybdena 0.5-1.5%, oxidation Zinc 1-5%, zirconium oxide 20-30%, cadmium oxide 10-25%, cobalt oxide 5-15%, selenium oxide 2-8%, sulfur oxide 1-5%；

Orange composition and its percentage by weight：Oxidation silicon 20-30%, zirconium oxide 25-45%, selenium oxide 4-8%, sulfur oxide 5- 15%th, cadmium oxide 10-30%；

Coffee-like composition and its percentage by weight：Zinc oxide 28-45%, chromium oxide 25-35%, iron oxide 22-40%；

The composition and its percentage by weight of grass green：Oxidation silicon 30-40%, sodium oxide molybdena 0.5-1.5%, zirconium oxide 48-60%, oxygen Change praseodymium 2-8%, vanadium oxide 1-5%；

The composition and its percentage by weight of cobalt blue：Aluminum oxide 50-70%, zinc oxide 8-15%, cobalt oxide 20-40%；

Blackish green composition and its percentage by weight：Oxidation silicon 28-37%, sodium oxide molybdena 0.2-0.8%, potassium oxide 0.2-0.8%, Zirconium oxide 53-65%, praseodymium oxide 0.5-3%, vanadium oxide 2-6%；

The composition and its percentage by weight of black：Chromium oxide 30-50%, cobalt oxide 20-40%, nickel oxide 5-15%, iron oxide 15-30%；

Jade-green composition and its percentage by weight：Oxidation silicon 25-40%, sodium oxide molybdena 0.2-0.8%, potassium oxide 0.2-0.8%, Zirconium oxide 50-65%, praseodymium oxide 1-3%, vanadium oxide 2-7%.

6. colored drawing pigment pencil under ceramic glaze according to claim 5, it is characterised in that：

The color classification and composition and its percentage by weight of color painting are under the ceramic high-temperature glaze：

The composition and its percentage by weight of peacock blue：Aluminum oxide 21.01%, magnesia 1.67%, barium monoxide 15.71%, oxygen Change chromium 36.28%, cobalt oxide 25.33%；

Sapphire composition and its percentage by weight：Chromium oxide 40.17%, cobalt oxide 27.76%, nickel oxide 9.83%, oxidation Iron 22.24%；

The composition and its percentage by weight of yellow：Oxidation silicon 28.14%, sulfur oxide 7.67%, cadmium oxide 21.22%, zirconium oxide 42.97%；

Red composition and its percentage by weight：Oxidation silicon 27.11%, selenium oxide 7.80%, sulfur oxide 20.28%, silicon acid zirconium 38.19%th, cadmium oxide 6.62%；

The composition and its percentage by weight of purple：Oxidation silicon 17.36%, aluminum oxide 16.32%, sodium oxide molybdena 0.84%, zinc oxide 3.41%th, zirconium oxide 26.18%, cadmium oxide 14.49%, cobalt oxide 10.27%, selenium oxide 6.72%, sulfur oxide 4.41%；

Orange composition and its percentage by weight：Oxidation silicon 24.80%, zirconium oxide 39.30%, selenium oxide 6.60%, sulfur oxide 9.20%th, cadmium oxide 20.10%；

Coffee-like composition and its percentage by weight：Zinc oxide 39.17%, chromium oxide 32.49%, iron oxide 28.34%；

The composition and its percentage by weight of grass green：Oxidation silicon 35.52%, sodium oxide molybdena 1.07%, zirconium oxide 56.17%, oxidation Praseodymium 5.21%, vanadium oxide 2.03%；

The composition and its percentage by weight of cobalt blue：Aluminum oxide 60.31%, zinc oxide 11.26%, cobalt oxide 28.43%；

Blackish green composition and its percentage by weight：Oxidation silicon 33.98%, sodium oxide molybdena 0.57%, potassium oxide 0.48%, zirconium oxide 58.24%th, praseodymium oxide 1.96%, vanadium oxide 4.77%；

The composition and its percentage by weight of black：Chromium oxide 40.17%, cobalt oxide 27.76%, nickel oxide 9.83%, iron oxide 22.24%；

Jade-green composition and its percentage by weight：Oxidation silicon 33.98%, sodium oxide molybdena 0.57%, potassium oxide 0.48%, zirconium oxide 58.24%th, praseodymium oxide 1.96%, vanadium oxide 4.77%.

7. the colored drawing application process of pigment pencil under the ceramic glaze described in a kind of claim 2, it is characterised in that：

Underglaze colour drawing is carried out on the ceramic mold surface of dry or biscuiting with pigment pencil by colored drawing under described ceramic glaze.

8. the colored drawing application process of pigment pencil under ceramic glaze according to claim 7, it is characterised in that：

Dried or the ceramic mold surface of biscuiting is write, draws, made with pigment pencil using colored drawing under the ceramic glaze Draw, the tolerable temperature of colored drawing pigment pencil is not less than temperature of glaze firing under ceramic glaze, the production burnt till using glazing after first colored drawing Technique.

9. the colored drawing application process of pigment pencil under ceramic glaze according to claim 8, it is characterised in that：

Clear frit is imposed on the good mold surface of colored drawing, is carried out into kiln high-temperature firing, firing temperature is 1200~1300 DEG C, burn till end and will show colourful colored drawing picture, drawing pencil formula hard-tipped pen can show on ceramics.

10. the colored drawing application process of pigment pencil under ceramic glaze according to claim 7, it is characterised in that：

By way of hard-tipped pen colored drawing and soft colored drawing are combined, i.e., hooked with pigment pencil using colored drawing under the ceramic glaze On the basis of strangling main line bar, then carry out large area and color in by the form that traditional banister bruss adds coloured silk, carry out underglaze colour drawing.