CN106045579A - Celeste ceramic with ripple glaze and firing method of ceramic - Google Patents
Celeste ceramic with ripple glaze and firing method of ceramic Download PDFInfo
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- CN106045579A CN106045579A CN201610400599.7A CN201610400599A CN106045579A CN 106045579 A CN106045579 A CN 106045579A CN 201610400599 A CN201610400599 A CN 201610400599A CN 106045579 A CN106045579 A CN 106045579A
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- 238000000034 method Methods 0.000 title claims abstract description 50
- 239000000919 ceramic Substances 0.000 title claims abstract description 20
- 238000010304 firing Methods 0.000 title abstract description 16
- 239000011521 glass Substances 0.000 claims abstract description 28
- 239000000463 material Substances 0.000 claims abstract description 22
- 235000019353 potassium silicate Nutrition 0.000 claims abstract description 16
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 claims abstract description 16
- 210000003298 dental enamel Anatomy 0.000 claims description 89
- 229910052573 porcelain Inorganic materials 0.000 claims description 76
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 69
- 239000004575 stone Substances 0.000 claims description 39
- 239000002994 raw material Substances 0.000 claims description 36
- 239000004927 clay Substances 0.000 claims description 33
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicon dioxide Inorganic materials O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 30
- 239000003513 alkali Substances 0.000 claims description 29
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 claims description 26
- 235000012239 silicon dioxide Nutrition 0.000 claims description 25
- 229940036811 bone meal Drugs 0.000 claims description 21
- 239000002374 bone meal Substances 0.000 claims description 21
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 20
- 238000005245 sintering Methods 0.000 claims description 16
- 239000005995 Aluminium silicate Substances 0.000 claims description 15
- 235000012211 aluminium silicate Nutrition 0.000 claims description 15
- 238000000498 ball milling Methods 0.000 claims description 15
- 238000001035 drying Methods 0.000 claims description 15
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 claims description 15
- 238000002360 preparation method Methods 0.000 claims description 15
- 239000010453 quartz Substances 0.000 claims description 15
- 235000019013 Viburnum opulus Nutrition 0.000 claims description 14
- 244000071378 Viburnum opulus Species 0.000 claims description 14
- 238000010411 cooking Methods 0.000 claims description 14
- 239000011787 zinc oxide Substances 0.000 claims description 13
- 230000003647 oxidation Effects 0.000 claims description 12
- 238000007254 oxidation reaction Methods 0.000 claims description 12
- GFQYVLUOOAAOGM-UHFFFAOYSA-N zirconium(iv) silicate Chemical compound [Zr+4].[O-][Si]([O-])([O-])[O-] GFQYVLUOOAAOGM-UHFFFAOYSA-N 0.000 claims description 11
- 239000000292 calcium oxide Substances 0.000 claims description 9
- ODINCKMPIJJUCX-UHFFFAOYSA-N calcium oxide Inorganic materials [Ca]=O ODINCKMPIJJUCX-UHFFFAOYSA-N 0.000 claims description 9
- 238000001816 cooling Methods 0.000 claims description 9
- BRPQOXSCLDDYGP-UHFFFAOYSA-N calcium oxide Chemical compound [O-2].[Ca+2] BRPQOXSCLDDYGP-UHFFFAOYSA-N 0.000 claims description 8
- 238000002156 mixing Methods 0.000 claims description 8
- 239000006004 Quartz sand Substances 0.000 claims description 7
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 claims description 7
- 238000003618 dip coating Methods 0.000 claims description 7
- 229910052742 iron Inorganic materials 0.000 claims description 7
- 239000007788 liquid Substances 0.000 claims description 7
- 238000010298 pulverizing process Methods 0.000 claims description 7
- 238000003756 stirring Methods 0.000 claims description 7
- -1 wherein Substances 0.000 claims description 7
- 235000012222 talc Nutrition 0.000 claims description 6
- 239000000454 talc Substances 0.000 claims description 6
- 229910052623 talc Inorganic materials 0.000 claims description 6
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 5
- 229910052760 oxygen Inorganic materials 0.000 claims description 5
- 239000001301 oxygen Substances 0.000 claims description 5
- 229910021532 Calcite Inorganic materials 0.000 claims description 4
- 229910052925 anhydrite Inorganic materials 0.000 claims description 4
- OSGAYBCDTDRGGQ-UHFFFAOYSA-L calcium sulfate Chemical compound [Ca+2].[O-]S([O-])(=O)=O OSGAYBCDTDRGGQ-UHFFFAOYSA-L 0.000 claims description 4
- 229910052845 zircon Inorganic materials 0.000 claims description 4
- 229910001719 melilite Inorganic materials 0.000 claims description 2
- 238000007654 immersion Methods 0.000 claims 1
- IMNMWKFKHDPTSB-UHFFFAOYSA-N silicic acid zirconium Chemical compound [Zr].[Si](O)(O)(O)O IMNMWKFKHDPTSB-UHFFFAOYSA-N 0.000 claims 1
- 239000003086 colorant Substances 0.000 abstract description 6
- 239000002932 luster Substances 0.000 abstract description 4
- 210000000988 bone and bone Anatomy 0.000 abstract 1
- 239000000843 powder Substances 0.000 abstract 1
- 239000011044 quartzite Substances 0.000 abstract 1
- 239000002002 slurry Substances 0.000 description 11
- 208000031481 Pathologic Constriction Diseases 0.000 description 5
- 210000001215 vagina Anatomy 0.000 description 5
- 238000002485 combustion reaction Methods 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- 238000005516 engineering process Methods 0.000 description 4
- 239000010432 diamond Substances 0.000 description 3
- 229910003460 diamond Inorganic materials 0.000 description 3
- 230000010412 perfusion Effects 0.000 description 3
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 2
- 229910052681 coesite Inorganic materials 0.000 description 2
- 229910052593 corundum Inorganic materials 0.000 description 2
- 229910052906 cristobalite Inorganic materials 0.000 description 2
- 239000000446 fuel Substances 0.000 description 2
- 238000002386 leaching Methods 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 239000000377 silicon dioxide Substances 0.000 description 2
- 229910052682 stishovite Inorganic materials 0.000 description 2
- 229910052905 tridymite Inorganic materials 0.000 description 2
- 229910001845 yogo sapphire Inorganic materials 0.000 description 2
- 241001271907 Baphia racemosa Species 0.000 description 1
- FUJCRWPEOMXPAD-UHFFFAOYSA-N Li2O Inorganic materials [Li+].[Li+].[O-2] FUJCRWPEOMXPAD-UHFFFAOYSA-N 0.000 description 1
- 235000008708 Morus alba Nutrition 0.000 description 1
- 240000000249 Morus alba Species 0.000 description 1
- KKCBUQHMOMHUOY-UHFFFAOYSA-N Na2O Inorganic materials [O-2].[Na+].[Na+] KKCBUQHMOMHUOY-UHFFFAOYSA-N 0.000 description 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- 239000003245 coal Substances 0.000 description 1
- 239000006184 cosolvent Substances 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 208000004042 dental fluorosis Diseases 0.000 description 1
- XUCJHNOBJLKZNU-UHFFFAOYSA-M dilithium;hydroxide Chemical compound [Li+].[Li+].[OH-] XUCJHNOBJLKZNU-UHFFFAOYSA-M 0.000 description 1
- KZHJGOXRZJKJNY-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Si]=O.O=[Al]O[Al]=O.O=[Al]O[Al]=O.O=[Al]O[Al]=O KZHJGOXRZJKJNY-UHFFFAOYSA-N 0.000 description 1
- 239000000428 dust Substances 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 239000003864 humus Substances 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 1
- 239000004922 lacquer Substances 0.000 description 1
- 239000007791 liquid phase Substances 0.000 description 1
- 229910052863 mullite Inorganic materials 0.000 description 1
- 238000009377 nuclear transmutation Methods 0.000 description 1
- 230000001590 oxidative effect Effects 0.000 description 1
- 230000000149 penetrating effect Effects 0.000 description 1
- 230000035699 permeability Effects 0.000 description 1
- 238000007493 shaping process Methods 0.000 description 1
- 238000002791 soaking Methods 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N titanium dioxide Inorganic materials O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/80—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone of only ceramics
- C04B41/81—Coating or impregnation
- C04B41/89—Coating or impregnation for obtaining at least two superposed coatings having different compositions
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C8/00—Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
- C03C8/02—Frit compositions, i.e. in a powdered or comminuted form
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B35/00—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
- C04B35/622—Forming processes; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
- C04B35/64—Burning or sintering processes
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/45—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
- C04B41/52—Multiple coating or impregnating multiple coating or impregnating with the same composition or with compositions only differing in the concentration of the constituents, is classified as single coating or impregnation
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/65—Aspects relating to heat treatments of ceramic bodies such as green ceramics or pre-sintered ceramics, e.g. burning, sintering or melting processes
- C04B2235/66—Specific sintering techniques, e.g. centrifugal sintering
- C04B2235/661—Multi-step sintering
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Ceramic Engineering (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Structural Engineering (AREA)
- Manufacturing & Machinery (AREA)
- Life Sciences & Earth Sciences (AREA)
- General Chemical & Material Sciences (AREA)
- Geochemistry & Mineralogy (AREA)
- Inorganic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Spark Plugs (AREA)
Abstract
The invention discloses celeste ceramic with ripple glaze and a firing method of the ceramic. The ceramic comprises celeste ground glaze and surface glaze which are applied to a ceramic green body sequentially, the dilatation coefficient of the ground glaze is smaller than that of the surface glaze by controlling the content of quartzite, glass frit and bone powder in the ground glaze and the surface glaze, and ripples are formed on the surface of the ceramic in the firing process; a water glass layer is arranged between the ground glaze and the surface glaze. According to the celeste ceramic with the ripple glaze and the firing method of the ceramic, the glazing mode, the glaze material formula and the matched firing process are all improved, the purpose of firing the celeste ceramic with the ripple glaze is achieved, the fired ceramic has bright and smooth color and luster, the ripples are seemingly formed in the glaze, the glaze surface touches smooth and mild, the glaze is in quiet colors, quietly elegant, meaningful and attractive, the ceramic as the characteristic of China also represents the advanced level of a workmanship in China, and the social value of the ceramic is improved.
Description
Technical field
The present invention relates to pottery manufacture field, a kind of Celeste porcelain with water ripples glaze and the side of firing thereof
Method.
Background technology
Porcelain is to be fired by porcelain stone, Kaolin, quartz, mullite etc. to form, and outer top application has nature of glass glaze or colored drawing
Sundries.The shaping of porcelain to be passed through through high-temperature firing in kiln, and the glaze colours on porcelain surface is understood the difference because of temperature thus sent out
Raw various chemical changes.The porcelain tire of sintering normally only containing 3% less than ferrum element, and waterproof, because of the cost that it is the cheapest
The common people the most all over the world are used with wear-resisting fluid-tight characteristic, are the rarities of the bright displaying of Chinese.
Porcelain is originated in the Eastern Han Dynasty, the treasure in tradition technology in producing porcelain, is referred to as national treasure, rarity.Making porcelain when,
Although present technology has been achieved for remarkable progress, but there are some defects, porcelain in manufacturing process from selecting materials
Fire finished product, period experience multiple working procedure, use raw material plastotype and fire element tire, being stained with ground-coat enamel, be stained with mottled enamels, fire and grow up to be a useful person, any
The error of one procedure operation all can affect the quality burning till porcelain, and this is also the reason that porcelain yield all the time is extremely low.Porcelain
The most critical of device is the preparation of enamel and fires, and enamel transmutation chatoyance after being fired determines the value of porcelain, glaze
The difference of plasmogamy side, the color burnt out is the most variant, and traditional porcelain white glaze mostly is the iron-holder reduced in glaze, ferrum
Element can produce black or the color of yellow green tea-dust glaze according to the different of combustion atmosphere during firing, and works as glaze
In iron-holder when being reduced to less than 0.75%, the glaze colours burnt out close to translucent, element tire background color thoroughly on be white glaze.
Existing porcelain is during firing, and the color and luster that porcelain presents is all the color and luster of glaze itself, ornamental value
Limited, it is proposed that a kind of difference utilizing two kinds of glaze coefficients of expansion during firing and present the glaze of ripples grain pattern
Color.
Summary of the invention
In order to solve, traditional lacquer glaze colours is single, wayward fires the problems such as effect in normal complexion, and the present invention proposes one
There is Celeste porcelain and the method for cooking thereof of water ripples glaze, by glazing mode, glaze formula and burning process are changed
Enter, it is achieved on porcelain, burn out the purpose of specific glaze normal complexion effect of decorative patterns.
The present invention is in order to realize above-mentioned technique effect, and the technical scheme taked is:
A kind of Celeste porcelain with water ripples glaze, is included in Pre-sintered porcelain body surface and applies Celeste ground-coat enamel and cover successively
Glaze, by controlling quartz, glass frit and the content of bone meal in ground-coat enamel and cover glaze, so that the coefficient of expansion of ground-coat enamel is less than
The coefficient of expansion of cover glaze, to produce water ripples at ceramic surface in sintering process.
Waterglass layer it is provided with between described ground-coat enamel and cover glaze.
According to weight ratio, the raw material forming described ground-coat enamel is the white Anhydrite of 42-50 part, 10-20 part quartz, 10-20 part side
Xie Shi, 3-8 part zircon, 0.2-1.3 part iron ore, 5-8 part calcium oxide, 1-5 part zinc oxide, 1-3 part bone meal, 1-5 part glass
Frit, 3-8 part alkali stone and 1-5 part Talcum；Form the raw material of described cover glaze be 48-53 part melilite, 10-15 part quartz,
The white Anhydrite of 5-10 part, 2-8 part Zirconium orthosilicate., 10-15 part calcite, 7-13 part glass frit, 0.5-1.5 part stannum oxide, 1-5 part oxygen
Changing zinc and 1-3 part bone meal, wherein, alkali stone takes from Jiaxian County, Pingdingshan City, Henan Province Shen Zhen.
There is the method for cooking of the Celeste porcelain of water ripples glaze, first by carcass raw material pulverizing plastotype and fire element tire,
Burning till thickness and need to be less than 2mm of element tire, then immerses element tire glazing in the slip of ground-coat enamel, treats the material of plain tire surface attachment ground-coat enamel
After slurry dries, holding element tire and quickly soak in the water glass solution that concentration is 0.8% and take out, the surplus liquid of attachment is fallen in drip, dries in the air
Again at the slip of its surface dip-coating cover glaze after Gan, fire in putting it into kiln after drying, must have the sky of water ripples glaze
Cyan porcelain, described sintering procedure is four sections and fires:
One, pre-burned
To complete glazing and kiln put into by the plain tire that dries, keep wicket to crack 2cm, then igniting is fired, and makes in-furnace temperature
In 1.5h, uniformly it is increased to 325-335 DEG C from room temperature, then closes wicket tight；
Two, reducing atmosphere I is fired
Make in-furnace temperature uniformly be increased to 910-920 DEG C from 325-335 DEG C in 6.2h, and in this stage makes kiln, keep oxygen
Change atmosphere；
Three, reducing atmosphere II is fired
Make in-furnace temperature uniformly be increased to 1280-1290 DEG C from 910-920 DEG C in 2.8h, and keep in this stage makes kiln
Oxidation atmosphere；
Four, cooling
Control in-furnace temperature and be down to 100 DEG C from 1280-1290 DEG C in 50h, the porcelain fired is taken out, obtains described having
The Celeste porcelain of water ripples glaze.
During firing, when the i.e. oxygen of oxidizing atmosphere used provides sufficient, the fire under the complete combustion case of fuel
Flame atmosphere, when the i.e. oxygen of reducing atmosphere used provides inadequate, the flame atmosphere in the case of non-complete combustion of fuel, the present invention
Described combustion atmosphere is reducing atmosphere, and component relatively low for fusing point in glaze is melted by reducing atmosphere I stage, makes glaze from solid
Being fused into liquid phase mutually, now the lines of ripples grain pattern starts appearance；Reducing atmosphere II stage is the colour developing stage of glaze, ground-coat enamel
Quality element is ferrum, fires in reducing atmosphere, shows Celeste, compares Traditional Firing Craft of Red in the time that cooling stage uses
The time of upper use is long, and traditional cooling is it is generally required to 24h, and the present invention proposes is 50h, determines whether porcelain glaze hacks
It is crucial that the coefficient of expansion between glaze and carcass is poor, and glaze of the present invention scribbles two-layer, and two kinds of glaze is swollen
Swollen coefficient difference is relatively big, lowers the temperature more slowly, it is possible to avoid glaze to hack as far as possible, the Celeste water being fired into raising
The artistry of ripple porcelain.
According to weight ratio, described carcass raw material is by 65 parts of Kaolin, 20 parts of alkali stones, 8 parts of kibushi clay and 7 parts of quartz sand groups
Become；Wherein, Kaolin, alkali stone, kibushi clay and quartz sand are taken from ecliptic town, Jiaxian County, Pingdingshan City, Henan Province.Wherein, alkali stone
For taking from a kind of caesious building stones in locality, ecliptic town, Jiaxian County, Pingdingshan City, Henan Province, belonging to flint clay class, quality is superfine, originates in
Anthracites, two folding in coal measures bottom, the percentage composition of main component is Al2O3Account for 38.79%, SiO2Account for 45.65%, TiO2Account for
0.47%、Fe2O3Account for 0.35%, CaO accounts for 0.38%, Na2O accounts for 0.05%, MgO accounts for 0.15%, Li2O accounts for 0.08%, impurity accounts for 14.08%.
Kibushi clay is to take from the camwood knag that ecliptic town, Jiaxian County, Pingdingshan City, Henan Province is local, outward appearance be typically mulberry,
Brown or bronzing, can improve chinaware body intensity, improve slip fluidity, and the percentage composition of main component is SiO2Account for
60%、Al2O3Account for 28-33%, carbonaceous humus accounts for 7-12%.
The burning process of described element tire is for becoming fineness to be 100-200 mesh the mass mixing stirring ball-millings such as carcass raw material and water
Mud, then use mud plastotype to become unpainted clay idol, unpainted clay idol stands after drying and enters kiln biscuiting 10-12h at 900-920 DEG C, with
Stove is cooled to room temperature, obtains plain tire.Wherein, the plastotype mode of unpainted clay idol has perfusion and pulls two kinds, and perfusion plastotype can be in the short time
In the identical unpainted clay idol of a large amount of outputs, then each is the most incomplete same to pull the unpainted clay idol of plastotype output, and more artistry, due to this
Burning process described in invention is strict to the thickness requirement of element tire, and element tire when being formed the endocorpuscular arrangement mode of tire to the later stage
Artistic effect have an impact, therefore the present invention selects the mode of perfusion to mould tire.
The preparation process of described ground-coat enamel be the constitutive material of ground-coat enamel is mixed after, the water elder generation ball milling of quality such as be added thereto to
35-40h, makes fineness and reaches the slip of 400-450 mesh, and adjusting water content is 55%, obtains ground-coat enamel.
The preparation process of described cover glaze be the constitutive material of ground-coat enamel is mixed after, the water elder generation ball of quality such as be added thereto to
Mill 35-40h, makes fineness and reaches the slip of 400-450 mesh, and adjusting water content is 52%, obtains cover glaze.
Owing to Celeste water ripples glaze of the present invention needs superposition both sides glaze on relatively thin carcass, ground-coat enamel contains
Ferrum element less than 2%, with substantial amounts of calcium oxide as cosolvent, the glaze colours burnt out in reducing atmosphere is Celeste, celeste glaze
Bit bluish, glaze is thin and hard, and jade-like stone profit is bright and clean, deep and remote light meaningful, introduces into victory；And cover glaze controls the content of ferrum element, ferrum
The content of element, below 0.5%, improves the content of glass frit simultaneously, uses Zirconium orthosilicate. to assist and improves the penetrating of glaze colours
Property, reducing atmosphere burns out the clear frit that permeability is the highest, texture is gentle pure.
During the tire glazing of actual element, ground-coat enamel quartz and content of glass frit accounting are high, ground-coat enamel glaze slip water content
The highest, leaching glaze is taken out after 2 seconds immediately, dries rear ground-coat enamel thickness and is only 1mm, and glass frit accounting relatively low one in cover glaze
A bit, when soaking glaze, the water content of the time of staying slightly length and cover glaze glaze is more relatively low, and leaching glaze was taken out after 4 seconds, and glazing is thick
Degree is between 2-4mm；During kiln-firing, firing under reducing atmosphere, ground-coat enamel shows Celeste, and cover glaze shows transparent
Color, owing in ground-coat enamel, the accounting of quartz and glass frit, far above the accounting of glass frit in cover glaze, therefore occurs in that two
Person's coefficient of expansion is different, and the coefficient of expansion of the ground-coat enamel that compares is higher, and during firing, two-layer glaze mutually extrudes, and is i.e. formed
The lines of water ripples shapes, again because the two in sintering procedure in molten condition, in order to avoid both the when of extruding mutually
Mixing, water ripples DeGrain, with the addition of one layer of high temperature resistant stable in properties between and on glaze colour developing without impact
Waterglass layer, again because the thickness between two-layer glaze there are differences so that cover glaze outer surface sense of touch after firing is smooth.
The beneficial effect of the invention:
A kind of Celeste porcelain with water ripples glaze of the present invention and method for cooking thereof, breach general at porcelain glaze
On present decorative pattern needs method of carving or putting glazing layer on element tire, in glazing mode, glaze formula and supporting burning
Improvement has all been made, it is achieved that burn out the purpose of Celeste water ripples glaze porcelain, the porcelain color and luster jade-like stone burnt out in technique processed
Profit, seemingly has water ripples in glaze and that glaze touches is bright and clean gentle, deep and remote light meaningful, introduces into victory, porcelain as the characteristic of China, also generation
The advanced level of Biao Liao China processing technology, improves the social value of porcelain.
Detailed description of the invention
In conjunction with specific examples below, the present invention is described in further detail, and protection scope of the present invention is not limited to
In following example.Implement the process of the present invention, condition, reagent, experimental technique etc., outside the lower content mentioned specially,
Being universal knowledege and the common knowledge of this area, the present invention is not particularly limited content.
Embodiment 1
A kind of Celeste porcelain with water ripples glaze, is included in Pre-sintered porcelain body surface and applies Celeste ground-coat enamel and cover successively
Glaze, by controlling quartz, glass frit and the content of bone meal in ground-coat enamel and cover glaze, so that the coefficient of expansion of ground-coat enamel is less than
The coefficient of expansion of cover glaze, to produce water ripples at ceramic surface in sintering process.
Waterglass layer it is provided with between described ground-coat enamel and cover glaze.
According to weight ratio, the raw material forming described ground-coat enamel is 42 parts of white Anhydrites, 10 parts of quartzs, 10 parts of calcites, 3 parts of zirconiums
Diamond stone, 0.2 part of iron ore, 5 parts of calcium oxide, 1 part of zinc oxide, 1 part of bone meal, 1 part of glass frit, 3 parts of alkali stones and 1 part of Talcum；Group
Become the raw material of described cover glaze be 48 parts of melilites, 10 parts of quartzs, 5 parts of white Anhydrites, 2 parts of Zirconium orthosilicate .s, 10 parts of calcites, 7 parts
Glass frit, 0.5 part of stannum oxide, 1 part of zinc oxide and 1 part of bone meal, wherein, alkali stone takes from Jiaxian County, Pingdingshan City, Henan Province god
Town.
There is the method for cooking of the Celeste porcelain of water ripples glaze, first by carcass raw material pulverizing plastotype and fire element tire,
Burning till thickness and need to be less than 2mm of element tire, then immerses element tire glazing in the slip of ground-coat enamel, treats the material of plain tire surface attachment ground-coat enamel
After slurry dries, holding element tire and quickly soak in the water glass solution that concentration is 0.8% and take out, the surplus liquid of attachment is fallen in drip, dries in the air
Again at the slip of its surface dip-coating cover glaze after Gan, fire in putting it into kiln after drying, must have the sky of water ripples glaze
Cyan porcelain, described sintering procedure is four sections and fires:
One, pre-burned
To complete glazing and kiln put into by the plain tire that dries, keep wicket to crack 2cm, then igniting is fired, and makes in-furnace temperature
In 1.5h, uniformly it is increased to 325 DEG C from room temperature, then closes wicket tight；
Two, reducing atmosphere I is fired
Make in-furnace temperature uniformly be increased to 910 DEG C from 325 DEG C in 6.2h, and in this stage makes kiln, keep oxidation atmosphere；
Three, reducing atmosphere II is fired
Make in-furnace temperature uniformly be increased to 1280 DEG C from 910 DEG C in 2.8h, and in this stage makes kiln, keep oxidation atmosphere；
Four, cooling
Control in-furnace temperature and be down to 100 DEG C from 1280 DEG C in 50h, the porcelain that fire is taken out, obtain and described there are ripples
The Celeste porcelain of stricture of vagina glaze.
According to weight ratio, described carcass raw material is by 65 parts of Kaolin, 20 parts of alkali stones, 8 parts of kibushi clay and 7 parts of quartz sand groups
Become；Wherein, Kaolin, alkali stone, kibushi clay and quartz sand are taken from ecliptic town, Jiaxian County, Pingdingshan City, Henan Province.
The burning process of described element tire is the mud becoming fineness to be 100 mesh the mass mixing stirring ball-millings such as carcass raw material and water
Slurry, then uses mud plastotype to become unpainted clay idol, and unpainted clay idol stands after drying and enters kiln biscuiting 10h at 900 DEG C, often cools to the furnace
Temperature, obtains plain tire.
The preparation process of described ground-coat enamel be the constitutive material of ground-coat enamel is mixed after, the water elder generation ball milling of quality such as be added thereto to
35h, makes fineness and reaches the slip of 400 mesh, and adjusting water content is 55%, obtains ground-coat enamel.
The preparation process of described cover glaze be the constitutive material of ground-coat enamel is mixed after, the water elder generation ball of quality such as be added thereto to
Mill 35h, makes fineness and reaches the slip of 400 mesh, and adjusting water content is 52%, obtains cover glaze.
Embodiment 2
A kind of Celeste porcelain with water ripples glaze, is included in Pre-sintered porcelain body surface and applies Celeste ground-coat enamel and cover successively
Glaze, by controlling quartz, glass frit and the content of bone meal in ground-coat enamel and cover glaze, so that the coefficient of expansion of ground-coat enamel is less than
The coefficient of expansion of cover glaze, to produce water ripples at ceramic surface in sintering process.
Waterglass layer it is provided with between described ground-coat enamel and cover glaze.
According to weight ratio, form the raw material of described ground-coat enamel be 44 parts of white Anhydrites, 12 parts of quartzs, 12 parts of calcites, 3.5 parts
Zircon, 0.4 part of iron ore, 5.5 parts of calcium oxide, 2 parts of zinc oxide, 1.2 parts of bone meal, 2 parts of glass frits, 3.5 parts of alkali stones and 2 parts
Talcum；The raw material forming described cover glaze is 49 parts of melilites, 11 parts of quartzs, 6 parts of white Anhydrites, 3 parts of Zirconium orthosilicate .s, 11 parts of side's solutions
Stone, 9 parts of glass frits, 0.7 part of stannum oxide, 2 parts of zinc oxide and 1.2 parts of bone meal, wherein, alkali stone takes from Pingdingshan City, Henan Province Jia
Xian Shen town.
There is the method for cooking of the Celeste porcelain of water ripples glaze, first by carcass raw material pulverizing plastotype and fire element tire,
Burning till thickness and need to be less than 2mm of element tire, then immerses element tire glazing in the slip of ground-coat enamel, treats the material of plain tire surface attachment ground-coat enamel
After slurry dries, holding element tire and quickly soak in the water glass solution that concentration is 0.8% and take out, the surplus liquid of attachment is fallen in drip, dries in the air
Again at the slip of its surface dip-coating cover glaze after Gan, fire in putting it into kiln after drying, must have the sky of water ripples glaze
Cyan porcelain, described sintering procedure is four sections and fires:
One, pre-burned
To complete glazing and kiln put into by the plain tire that dries, keep wicket to crack 2cm, then igniting is fired, and makes in-furnace temperature
In 1.5h, uniformly it is increased to 327 DEG C from room temperature, then closes wicket tight；
Two, reducing atmosphere I is fired
Make in-furnace temperature uniformly be increased to 912 DEG C from 327 DEG C in 6.2h, and in this stage makes kiln, keep oxidation atmosphere；
Three, reducing atmosphere II is fired
Make in-furnace temperature uniformly be increased to 1282 DEG C from 912 DEG C in 2.8h, and in this stage makes kiln, keep oxidation atmosphere；
Four, cooling
Control in-furnace temperature and be down to 100 DEG C from 1282 DEG C in 50h, the porcelain that fire is taken out, obtain and described there are ripples
The Celeste porcelain of stricture of vagina glaze.
According to weight ratio, described carcass raw material is by 65 parts of Kaolin, 20 parts of alkali stones, 8 parts of kibushi clay and 7 parts of quartz sand groups
Become；Wherein, Kaolin, alkali stone, kibushi clay and quartz sand are taken from ecliptic town, Jiaxian County, Pingdingshan City, Henan Province.
The burning process of described element tire is the mud becoming fineness to be 120 mesh the mass mixing stirring ball-millings such as carcass raw material and water
Slurry, then uses mud plastotype to become unpainted clay idol, and unpainted clay idol stands after drying and enters kiln biscuiting 10.5h at 905 DEG C, often cools to the furnace
Temperature, obtains plain tire.
The preparation process of described ground-coat enamel be the constitutive material of ground-coat enamel is mixed after, the water elder generation ball milling of quality such as be added thereto to
36h, makes fineness and reaches the slip of 410 mesh, and adjusting water content is 55%, obtains ground-coat enamel.
The preparation process of described cover glaze be the constitutive material of ground-coat enamel is mixed after, the water elder generation ball of quality such as be added thereto to
Mill 36h, makes fineness and reaches the slip of 410 mesh, and adjusting water content is 52%, obtains cover glaze.
Embodiment 3
A kind of Celeste porcelain with water ripples glaze, is included in Pre-sintered porcelain body surface and applies Celeste ground-coat enamel and cover successively
Glaze, by controlling quartz, glass frit and the content of bone meal in ground-coat enamel and cover glaze, so that the coefficient of expansion of ground-coat enamel is less than
The coefficient of expansion of cover glaze, to produce water ripples at ceramic surface in sintering process.
Waterglass layer it is provided with between described ground-coat enamel and cover glaze.
According to weight ratio, the raw material forming described ground-coat enamel is 46 parts of white Anhydrites, 15 parts of quartzs, 15 parts of calcites, 6 parts of zirconiums
Diamond stone, 0.8 part of iron ore, 6.5 parts of calcium oxide, 2.5 parts of zinc oxide, 2 parts of bone meal, 2.5 parts of glass frits, 6 parts of alkali stones and 2.5 parts
Talcum；Form the raw material of described cover glaze be 50 parts of melilites, 12.5 parts of quartzs, 7 parts of white Anhydrites, 5 parts of Zirconium orthosilicate .s, 12.5 parts
Calcite, 10 parts of glass frits, 1 part of stannum oxide, 2.5 parts of zinc oxide and 2 parts of bone meal, wherein, alkali stone takes from Pingdingshan
Jiaxian County, city Shen Zhen.
There is the method for cooking of the Celeste porcelain of water ripples glaze, first by carcass raw material pulverizing plastotype and fire element tire,
Burning till thickness and need to be less than 2mm of element tire, then immerses element tire glazing in the slip of ground-coat enamel, treats the material of plain tire surface attachment ground-coat enamel
After slurry dries, holding element tire and quickly soak in the water glass solution that concentration is 0.8% and take out, the surplus liquid of attachment is fallen in drip, dries in the air
Again at the slip of its surface dip-coating cover glaze after Gan, fire in putting it into kiln after drying, must have the sky of water ripples glaze
Cyan porcelain, described sintering procedure is four sections and fires:
One, pre-burned
To complete glazing and kiln put into by the plain tire that dries, keep wicket to crack 2cm, then igniting is fired, and makes in-furnace temperature
In 1.5h, uniformly it is increased to 330 DEG C from room temperature, then closes wicket tight；
Two, reducing atmosphere I is fired
Make in-furnace temperature uniformly be increased to 915 DEG C from 330 DEG C in 6.2h, and in this stage makes kiln, keep oxidation atmosphere；
Three, reducing atmosphere II is fired
Make in-furnace temperature uniformly be increased to 1285 DEG C from 915 DEG C in 2.8h, and in this stage makes kiln, keep oxidation atmosphere；
Four, cooling
Control in-furnace temperature and be down to 100 DEG C from 1285 DEG C in 50h, the porcelain that fire is taken out, obtain and described there are ripples
The Celeste porcelain of stricture of vagina glaze.
According to weight ratio, described carcass raw material is by 65 parts of Kaolin, 20 parts of alkali stones, 8 parts of kibushi clay and 7 parts of quartz sand groups
Become；Wherein, Kaolin, alkali stone, kibushi clay and quartz sand are taken from ecliptic town, Jiaxian County, Pingdingshan City, Henan Province.
The burning process of described element tire is the mud becoming fineness to be 150 mesh the mass mixing stirring ball-millings such as carcass raw material and water
Slurry, then uses mud plastotype to become unpainted clay idol, and unpainted clay idol stands after drying and enters kiln biscuiting 11h at 910 DEG C, often cools to the furnace
Temperature, obtains plain tire.
The preparation process of described ground-coat enamel be the constitutive material of ground-coat enamel is mixed after, the water elder generation ball milling of quality such as be added thereto to
37.5h, makes fineness and reaches the slip of 425 mesh, and adjusting water content is 55%, obtains ground-coat enamel.
The preparation process of described cover glaze be the constitutive material of ground-coat enamel is mixed after, the water elder generation ball of quality such as be added thereto to
Mill 37.5h, makes fineness and reaches the slip of 425 mesh, and adjusting water content is 52%, obtains cover glaze.
Embodiment 4
A kind of Celeste porcelain with water ripples glaze, is included in Pre-sintered porcelain body surface and applies Celeste ground-coat enamel and cover successively
Glaze, by controlling quartz, glass frit and the content of bone meal in ground-coat enamel and cover glaze, so that the coefficient of expansion of ground-coat enamel is less than
The coefficient of expansion of cover glaze, to produce water ripples at ceramic surface in sintering process.
Waterglass layer it is provided with between described ground-coat enamel and cover glaze.
According to weight ratio, form the raw material of described ground-coat enamel be 49 parts of white Anhydrites, 18 parts of quartzs, 18 parts of calcites, 7.5 parts
Zircon, 1.1 parts of iron ores, 7 parts of calcium oxide, 4 parts of zinc oxide, 2.5 parts of bone meal, 4 parts of glass frits, 7 parts of alkali stones and 4 parts of cunnings
Stone；The raw material forming described cover glaze is 50 parts of melilites, 13 parts of quartzs, 8 parts of white Anhydrites, 7 parts of Zirconium orthosilicate .s, 13 parts of side's solutions
Stone, 11 parts of glass frits, 1.2 parts of stannum oxide, 4 parts of zinc oxide and 2.5 parts of bone meal, wherein, alkali stone takes from Pingdingshan City, Henan Province
Jiaxian County Shen Zhen.
There is the method for cooking of the Celeste porcelain of water ripples glaze, first by carcass raw material pulverizing plastotype and fire element tire,
Burning till thickness and need to be less than 2mm of element tire, then immerses element tire glazing in the slip of ground-coat enamel, treats the material of plain tire surface attachment ground-coat enamel
After slurry dries, holding element tire and quickly soak in the water glass solution that concentration is 0.8% and take out, the surplus liquid of attachment is fallen in drip, dries in the air
Again at the slip of its surface dip-coating cover glaze after Gan, fire in putting it into kiln after drying, must have the sky of water ripples glaze
Cyan porcelain, described sintering procedure is four sections and fires:
One, pre-burned
To complete glazing and kiln put into by the plain tire that dries, keep wicket to crack 2cm, then igniting is fired, and makes in-furnace temperature
In 1.5h, uniformly it is increased to 330 DEG C from room temperature, then closes wicket tight；
Two, reducing atmosphere I is fired
Make in-furnace temperature uniformly be increased to 918 DEG C from 330 DEG C in 6.2h, and in this stage makes kiln, keep oxidation atmosphere；
Three, reducing atmosphere II is fired
Make in-furnace temperature uniformly be increased to 1288 DEG C from 918 DEG C in 2.8h, and in this stage makes kiln, keep oxidation atmosphere；
Four, cooling
Control in-furnace temperature and be down to 100 DEG C from 1288 DEG C in 50h, the porcelain that fire is taken out, obtain and described there are ripples
The Celeste porcelain of stricture of vagina glaze.
According to weight ratio, described carcass raw material is by 65 parts of Kaolin, 20 parts of alkali stones, 8 parts of kibushi clay and 7 parts of quartz sand groups
Become；Wherein, Kaolin, alkali stone, kibushi clay and quartz sand are taken from ecliptic town, Jiaxian County, Pingdingshan City, Henan Province.
The burning process of described element tire is the mud becoming fineness to be 180 mesh the mass mixing stirring ball-millings such as carcass raw material and water
Slurry, then uses mud plastotype to become unpainted clay idol, and unpainted clay idol stands after drying and enters kiln biscuiting 11.5h at 915 DEG C, often cools to the furnace
Temperature, obtains plain tire.
The preparation process of described ground-coat enamel be the constitutive material of ground-coat enamel is mixed after, the water elder generation ball milling of quality such as be added thereto to
39h, makes fineness and reaches the slip of 440 mesh, and adjusting water content is 55%, obtains ground-coat enamel.
The preparation process of described cover glaze be the constitutive material of ground-coat enamel is mixed after, the water elder generation ball of quality such as be added thereto to
Mill 39h, makes fineness and reaches the slip of 430 mesh, and adjusting water content is 52%, obtains cover glaze.
Embodiment 5
A kind of Celeste porcelain with water ripples glaze, is included in Pre-sintered porcelain body surface and applies Celeste ground-coat enamel and cover successively
Glaze, by controlling quartz, glass frit and the content of bone meal in ground-coat enamel and cover glaze, so that the coefficient of expansion of ground-coat enamel is less than
The coefficient of expansion of cover glaze, to produce water ripples at ceramic surface in sintering process.
Waterglass layer it is provided with between described ground-coat enamel and cover glaze.
According to weight ratio, the raw material forming described ground-coat enamel is 50 parts of white Anhydrites, 20 parts of quartzs, 20 parts of calcites, 8 parts of zirconiums
Diamond stone, 1.3 parts of iron ores, 8 parts of calcium oxide, 5 parts of zinc oxide, 3 parts of bone meal, 5 parts of glass frits, 8 parts of alkali stones and 1-5 part Talcum；
Form the raw material of described cover glaze be 53 parts of melilites, 15 parts of quartzs, 10 parts of white Anhydrites, 8 parts of Zirconium orthosilicate .s, 15 parts of calcites,
13 parts of glass frits, 1.5 parts of stannum oxide, 5 parts of zinc oxide and 3 parts of bone meal, wherein, alkali stone takes from Jiaxian County, Pingdingshan City, Henan Province god
Town.
There is the method for cooking of the Celeste porcelain of water ripples glaze, first by carcass raw material pulverizing plastotype and fire element tire,
Burning till thickness and need to be less than 2mm of element tire, then immerses element tire glazing in the slip of ground-coat enamel, treats the material of plain tire surface attachment ground-coat enamel
After slurry dries, holding element tire and quickly soak in the water glass solution that concentration is 0.8% and take out, the surplus liquid of attachment is fallen in drip, dries in the air
Again at the slip of its surface dip-coating cover glaze after Gan, fire in putting it into kiln after drying, must have the sky of water ripples glaze
Cyan porcelain, described sintering procedure is four sections and fires:
One, pre-burned
To complete glazing and kiln put into by the plain tire that dries, keep wicket to crack 2cm, then igniting is fired, and makes in-furnace temperature
In 1.5h, uniformly it is increased to 335 DEG C from room temperature, then closes wicket tight；
Two, reducing atmosphere I is fired
Make in-furnace temperature uniformly be increased to 920 DEG C from 335 DEG C in 6.2h, and in this stage makes kiln, keep oxidation atmosphere；
Three, reducing atmosphere II is fired
Make in-furnace temperature uniformly be increased to 1290 DEG C from 920 DEG C in 2.8h, and in this stage makes kiln, keep oxidation atmosphere；
Four, cooling
Control in-furnace temperature and be down to 100 DEG C from 1290 DEG C in 50h, the porcelain that fire is taken out, obtain and described there are ripples
The Celeste porcelain of stricture of vagina glaze.
According to weight ratio, described carcass raw material is by 65 parts of Kaolin, 20 parts of alkali stones, 8 parts of kibushi clay and 7 parts of quartz sand groups
Become；Wherein, Kaolin, alkali stone, kibushi clay and quartz sand are taken from ecliptic town, Jiaxian County, Pingdingshan City, Henan Province.
The burning process of described element tire is the mud becoming fineness to be 200 mesh the mass mixing stirring ball-millings such as carcass raw material and water
Slurry, then uses mud plastotype to become unpainted clay idol, and unpainted clay idol stands after drying and enters kiln biscuiting 12h at 920 DEG C, often cools to the furnace
Temperature, obtains plain tire.
The preparation process of described ground-coat enamel be the constitutive material of ground-coat enamel is mixed after, the water elder generation ball milling of quality such as be added thereto to
40h, makes fineness and reaches the slip of 450 mesh, and adjusting water content is 55%, obtains ground-coat enamel.
The preparation process of described cover glaze be the constitutive material of ground-coat enamel is mixed after, the water elder generation ball of quality such as be added thereto to
Mill 40h, makes fineness and reaches the slip of 450 mesh, and adjusting water content is 52%, obtains cover glaze.
Claims (8)
1. there is a Celeste porcelain for water ripples glaze, be included in Pre-sintered porcelain body surface and apply Celeste ground-coat enamel and cover successively
Glaze, it is characterised in that: by controlling quartz, glass frit and the content of bone meal in ground-coat enamel and cover glaze, so that ground-coat enamel
The coefficient of expansion is less than the coefficient of expansion of cover glaze, to produce water ripples at ceramic surface in sintering process.
A kind of Celeste porcelain with water ripples glaze, it is characterised in that: described ground-coat enamel and cover
Waterglass layer it is provided with between cover-coat enamel.
A kind of Celeste porcelain with water ripples glaze, it is characterised in that: according to weight ratio, group
The raw material becoming described ground-coat enamel is the white Anhydrite of 42-50 part, 10-20 part quartz, 10-20 part calcite, 3-8 part zircon, 0.2-
1.3 parts of iron ores, 5-8 part calcium oxide, 1-5 part zinc oxide, 1-3 part bone meal, 1-5 part glass frit, 3-8 part alkali stone and 1-5 part
Talcum；The raw material forming described cover glaze is 48-53 part melilite, 10-15 part quartz, the white Anhydrite of 5-10 part, 2-8 part silicic acid
Zirconium, 10-15 part calcite, 7-13 part glass frit, 0.5-1.5 part stannum oxide, 1-5 part zinc oxide and 1-3 part bone meal, wherein,
Alkali stone takes from Jiaxian County, Pingdingshan City, Henan Province Shen Zhen.
4. the method for cooking of the Celeste porcelain with water ripples glaze as described in claim 1-3 any bar, first by carcass
Raw material pulverizing plastotype also fires element tire, burning till thickness and need to be less than 2mm of element tire, then will execute in the slip of element tire immersion ground-coat enamel
Glaze, after the slip of element tire surface attachment ground-coat enamel dries, holds element tire and quickly soaks also in the water glass solution that concentration is 0.8%
Taking out, the surplus liquid of attachment is fallen in drip, again at the slip of its surface dip-coating cover glaze after drying, puts it in kiln after drying
Fire, must have the Celeste porcelain of water ripples glaze, it is characterised in that: described sintering procedure is four sections and fires:
One, pre-burned
To complete glazing and kiln put into by the plain tire that dries, keep wicket to crack 2cm, then igniting is fired, and makes in-furnace temperature
In 1.5h, uniformly it is increased to 325-335 DEG C from room temperature, then closes wicket tight；
Two, reducing atmosphere I is fired
Make in-furnace temperature uniformly be increased to 910-920 DEG C from 325-335 DEG C in 6.2h, and in this stage makes kiln, keep oxygen
Change atmosphere；
Three, reducing atmosphere II is fired
Make in-furnace temperature uniformly be increased to 1280-1290 DEG C from 910-920 DEG C in 2.8h, and keep in this stage makes kiln
Oxidation atmosphere；
Four, cooling
Control in-furnace temperature and be down to 100 DEG C from 1280-1290 DEG C in 50h, the porcelain fired is taken out, obtains described having
The Celeste porcelain of water ripples glaze.
There is the method for cooking of the Celeste porcelain of water ripples glaze the most as claimed in claim 4, it is characterised in that: according to weight
Ratio, described carcass raw material is made up of 65 parts of Kaolin, 20 parts of alkali stones, 8 parts of kibushi clay and 7 parts of quartz sands；Wherein, Kaolin,
Alkali stone, kibushi clay and quartz sand are taken from ecliptic town, Jiaxian County, Pingdingshan City, Henan Province.
There is the method for cooking of the Celeste porcelain of water ripples glaze the most as claimed in claim 4, it is characterised in that: described element tire
Burning process be the mud becoming fineness to be 100-200 mesh with mass mixing stirring ball-millings such as water carcass raw material, then use
Mud plastotype becomes unpainted clay idol, and unpainted clay idol stands after drying and enters kiln biscuiting 10-12h at 900-920 DEG C, cools to room temperature with the furnace, i.e.
Obtain plain tire.
There is the method for cooking of the Celeste porcelain of water ripples glaze the most as claimed in claim 4, it is characterised in that: described ground-coat enamel
Preparation process be the constitutive material of ground-coat enamel is mixed after, the water elder generation ball milling 35-40h of quality such as be added thereto to, make fineness
Reaching the slip of 400-450 mesh, adjusting water content is 55%, obtains ground-coat enamel.
There is the method for cooking of the Celeste porcelain of water ripples glaze the most as claimed in claim 4, it is characterised in that: described cover
The preparation process of glaze be the constitutive material of ground-coat enamel is mixed after, the water elder generation ball milling 35-40h of quality such as be added thereto to, make thin
Degree reaches the slip of 400-450 mesh, and adjusting water content is 52%, obtains cover glaze.
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| CN201610400599.7A CN106045579A (en) | 2016-06-08 | 2016-06-08 | Celeste ceramic with ripple glaze and firing method of ceramic |
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| CN201610400599.7A CN106045579A (en) | 2016-06-08 | 2016-06-08 | Celeste ceramic with ripple glaze and firing method of ceramic |
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| CN87100727A (en) * | 1987-02-14 | 1988-07-13 | 佛山市石湾东平陶瓷厂 | Printing technology in the wall ground brick glaze |
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